The invention provides
base metal modified
powder for a photovoltaic
cell, a preparation method, conductive
silver paste and application, and the preparation method comprises the following steps: mixing a composite
metal oxide with a core-shell structure with a
coupling agent, adding
organic acid salt and / or inorganic oxyacid, stirring, filtering and
drying to obtain the
base metal modified
powder, according to the composite
metal oxide with the core-shell structure,
base metal powder serves as a core, a
metal oxide serves as a shell, and the base
metal powder comprises one or more of Ni, Cu, Al, W and
alloy powder of Ni, Cu, Al and W. The prepared base metal modified powder is used for replacing part of silver powder to be applied to the conductive
silver paste, the cost is remarkably reduced, meanwhile, the defect that the conductive performance is hindered due to the fact that base metal is prone to oxidation during high-temperature
sintering is overcome, and the
electrical performance of the prepared conductive
silver paste is equivalent to or even better than that of pure silver conductive silver paste. When the
solar cell is applied to a photovoltaic
cell, the contact performance of an
electrode and a
silicon substrate is improved, and the
photoelectric conversion efficiency of the photovoltaic
cell, especially a TOPCon cell, is stably improved.