High-wear resistant Ti (C, N)-base ceramet tool bit and preparation thereof

A technology of ceramic cutting tools and base metals, which is applied in the field of high wear-resistant Ti-based cermet cutting tools and its preparation, can solve the problems of difficult to control uniform dispersion, high cost, and limited wide use, and achieve the goal of anti-oxidative wear and anti-diffusion wear Increased capacity, reduced cutting costs, and facilitated mass production

Inactive Publication Date: 2008-11-12
HUNAN UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional WC-based cemented carbide has low wear resistance and short life when cutting carbon steel and cast iron at high speed; while ceramic tools such as Al 2 o 3 (Al2O3), CBN (cubic boron nitride), artificial diamond and other tools, due to their high brittleness, high cost, and easy chipping during cutting, etc., limit their wide use in industry.
Although the existing TiC-based cermet tools have high hardness, they have low bending strength, poor red hardness, oxidation resistance and high-temperature creep resistance, and cannot meet the requirements of high-speed cutting; while Ti(C,N)-based metal Ceramic tools such as NT series have poor resistance to oxidation wear and diffusion wear during high-speed cutting, which seriously affects the service life of the tool, and high-nitrogen alloys such as Ti(C 0.5 N 0.5 )-based cermets have the problem of many pores
In addition, Chinese Patent Publication No. CN1477222A discloses TiC or Ti(C, N)-based cermet cutters modified with nano-TiN, the preparation process of the cutter and the use method of the cutter. The added nano-TiC not only increases the cost of raw materials, Moreover, it is difficult to control its uniform dispersion and other defects.

Method used

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  • High-wear resistant Ti (C, N)-base ceramet tool bit and preparation thereof
  • High-wear resistant Ti (C, N)-base ceramet tool bit and preparation thereof
  • High-wear resistant Ti (C, N)-base ceramet tool bit and preparation thereof

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Experimental program
Comparison scheme
Effect test

Embodiment approach

[0117] Sub-implementation mode (divided into high-nitrogen alloy preparation process and low-nitrogen alloy preparation process according to the amount of nitrogen content)

[0118] Referring to the accompanying drawings, it is prepared by powder metallurgy process, with Ni and Co as the binder phase, and adding Ti(C x , N 1-x ) or (TiC) x +(TiN) 1-x At least one carbonitride is a highly wear-resistant Ti(C,N)-based cermet tool with a basic coordination composition, wherein the X value of the carbonitride added is: 0.4≤X≤0.5 or 0.5

[0119] The preparation process is divided into high nitrogen alloy preparation process and low nitrogen alloy preparation process according to the nitrogen content:

[0120] (a) When containing Ti(C x , N 1-x ) or (TiC) x +(TiN) 1-x When at least one carbonitride is the nitrogen content in the basic batch, the X value of the nitrogen content is 0.4≤X≤0.5 (X≤0.5) (called high-nitrogen alloy), and the nitrogen pressure sintering process ...

no. 1 approach 0

[0124] First Embodiment [0.50.5)]

[0125] For Ti(C x , N 1-x ) or (TiC) x +(TiN) 1-x In the base cermet, this embodiment is adopted when the X value of the nitrogen content of at least one carbonitride is 0.50.5).

[0126] In the present invention, the TiCN-based cermet cutting tool refers to a sintered body of compacted powder having the following basic composition. The basic composition of the compact contains at least:

[0127] WC 10~20wt%

[0128] Mo 2 C 5~15wt%

[0129] Co 5~15wt%

[0130] Ni 5~10wt%

[0131] ZrC 0.1~2wt%

[0132] Cr 3 C 2 0.1~2wt%

[0133] VC 0.1~2wt%

[0134] At the same time, the compressed powder should also contain at least one of the following compounds:

[0135] TaC 0.1~15wt%

[0136] NbC 0.1~15wt%

[0137] The margin is:

[0138] Ti(C x , N 1-x ) or (TiC) x +(TiN) 1-x Wherein, the value of nitrogen content X is: 0.50.5)

Embodiment approach 1

[0141] WC 10~20wt% TaC 5~15wt%

[0142] Mo 2 C 5~15wt% or (Mo 4.7~14.1wt%+C0.3~0.9wt%)

[0143] Co 5~15wt% Ni 5~10wt% ZrC 0.1~2wt%

[0144] Cr 3 C 2 0.1~2wt% VC 0.1~2wt%

[0145] Balance Ti(C x , N 1-x ) or (TiC) x +(TiN) 1-x Wherein, the value of nitrogen content X is: 0.50.5)

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Abstract

The invention provides a high-abrasion Ti(C, N) based metal ceramic tool and a preparation thereof. The Ti(C, N) based metal ceramic tool uses Ni and Co as a binder phase, is added with at least one carbonitride of Ti(Cx, N1-x) or (TiC)x plus (TiN)1-x as a basic batch, and consists of at least one composition of WC, Mo2C, Co, Ni, ZrC, Cr3C2, VC, TaC and NbC, and the balance being Ti(Cx, N1-x) or (TiC)x plus (TiN)1-x, wherein, an X value for adding the carbonitride of the Ti(C, N) based metal ceramic tool is as follows: X is less than or equal to 0.5 and more than or equal to 0.4, or the X is more than 0.5 and less than or equal to 0.7. The Ti(C, N) based metal ceramic tool is prepared according to the content of nitrogen by nitrogen pressure sintering or vacuum sintering combined with hot isostatic pressing treatment, thereby preventing nitrogen from escaping during the process of sintering high-nitrogen alloy, so that the high-nitrogen-carbon ratio in matrix and material hardness can be reliably guaranteed, and anti-oxidative abrasion property and anti-diffusive abrasion property of the material can be obviously increased through adding slight ZrC, Cr3C2, VC and other carbides into the basic batch; meanwhile, compactability and buckling strength of a low-nitrogen alloy structure can be obviously improved through optimally distributing each composition and content. The Ti(C, N) based metal ceramic tool is widely suitable for high-speed cutting tools of medium-low carbon steel and low alloy steel.

Description

technical field [0001] The invention relates to a Ti(C,N)-based cermet cutter, in particular to a highly wear-resistant Ti(C,N)-based cermet cutter and its preparation. Background technique [0002] Ti(C, N) (titanium carbonitride)-based cermets were developed on the basis of TiC (titanium carbide)-based cermets in the early 1970s, with Ti(C, N) as the main hard phase, nickel, molybdenum Tool material for the binder phase. Because of its high hardness, high red hardness, high oxidation resistance and corrosion resistance, and high resistance to adhesive wear and diffusion wear during cutting, it fills the gap between WC (tungsten carbide)-based cemented carbide and ceramics, especially Suitable for semi-finishing and finishing machining of steel and cast iron. At present, the amount of foreign cutting tool materials has accounted for 10% to 30% of the total amount of cutting tool materials. In China, cutting tools are still mostly made of WC-based cemented carbide or cera...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C29/04B23P15/28B22F3/12
Inventor 张厚安唐思文颜建辉许剑光李颂文李鹏南严迪科古思勇
Owner HUNAN UNIV OF SCI & TECH
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