872 results about "Selective adsorption" patented technology

The invention discloses an efficient combined regulator for easily-argillized copper oxide cobalt ore and a beneficiation method. The efficient combined regulator comprises the following components in parts by weight: 250-350 parts of sodium citrate and 1100-1200 parts of sodium hydrosulfide. Sodium citrate has high dispersing capacity, and the efficiency of selective adsorption between the argillization copper-cobalt ore and the medicament can be improved; meanwhile, the complexing ability of sodium citrate on ions, such as Fe, Ca and Mg, influencing agent adsorption on the surface of the ore is high, in addition, products obtained after complexing of the Fe, Ca and Mg ions can be dissolved in water, and action sites are provided for selective adsorption of a vulcanizing agent (NaHS) and a collecting agent amyl xanthate (PAX). According to the combined regulator and the beneficiation method provided by the invention, the problem of poor reagent selectivity in the flotation process of the argillization copper-cobalt ore can be obviously improved, the vulcanization effect of a vulcanizing agent is enhanced, and selective adsorption of a collecting agent is promoted, so that the recovery rate of copper and cobalt metals in the copper-cobalt oxide ore under the condition of serious ore argillization is improved.

The invention discloses a recovery treatment process of heavy metal production wastewater, and relates to the technical field of wastewater treatment. Adjusting the pH value of the wastewater through pretreatment and stirring; 5%-10% of nanometer seed crystals are added in the seed crystal reinforced vulcanization process, a vulcanizing agent is controllably added, and large-particle-size precipitates are generated through pulse stirring; magnetic field separation is performed after magnetic microsphere adsorption; carrying out selective adsorption and acid regeneration on the chitosan-based magnetic resin; micro pollutants are removed through cooperation of the three-dimensional electrode and photocatalysis; concentrating 10-20 times by membrane distillation to enrich heavy metals; metal simple substances with the purity larger than or equal to 99.5% are recycled through pulse electrodeposition; and after deep treatment, the wastewater reaches the standard to be discharged or recycled (the recycling rate is greater than or equal to 70%). The process innovation comprises the steps of enhancing the seed crystal to improve the vulcanization efficiency by 30%, realizing rapid separation by a magnetic material, reducing the energy consumption by 40% by a three-dimensional electrode coupling membrane method, and constructing a vulcanizing agent regeneration (the regeneration rate is greater than or equal to 85%) and heavy metal closed-loop recovery system. Compared with a traditional process, the heavy metal removal rate is larger than or equal to 99.8%, the treatment cost of each ton of water is reduced by 25%-30%, and the method has the advantages of high efficiency, low consumption, environmental protection and recycling and is suitable for multi-metal complex wastewater.

The invention provides a synthesis method of a bromide ion adsorbent for salt lake bromine extraction, and belongs to the technical field of adsorbent preparation, a mixed solution of strontium chloride and manganese chloride and a mixed solution of sodium phosphate and sodium hydroxide are subjected to precipitation reaction to obtain A-Sr4Mn6 (PO4) 6 (OH) 2; the preparation method comprises the following steps: reacting A-Sr4Mn6 (PO4) 6 (OH) 2 with a sodium bromide solution to obtain B-Sr4Mn6 (PO4) 6Br2; and reacting the B-Sr4Mn6 (PO4) 6Br2 with a sodium hydroxide solution to obtain Sr4Mn6 (PO4) 6 (OH) 2, namely the bromide ion adsorbent. The prepared adsorbent can selectively adsorb bromide ions from high-salt brine, and has the advantages of high adsorption capacity, high selectivity, high recyclability and the like; in brine with extremely high chloride ion concentration, low-concentration bromide ions can be selectively adsorbed without being influenced by high-concentration chloride ions; in a high-salt water body, the adsorption capacity on bromide ions is higher; the selective adsorption separation of the chloride ions and the bromide ions is realized.

The present application relates to wastewater treatment technical field, specifically to a kind of ammonia nitrogen wastewater treatment method, the composite modified zeolite material in the present application has excellent physical adsorption capacity to ammonia nitrogen by virtue of its unique pore structure and surface properties, ammonia nitrogen molecules in wastewater can be quickly captured, then through the synergistic effect of composite photocatalyst under light and ultrasonic, strong oxidizing free radicals are generated, ammonia nitrogen molecules not completely adsorbed by zeolite material are deeply degraded, through the synergistic effect of adsorption and photocatalysis, the removal efficiency of ammonia nitrogen is significantly improved;After adsorption and photocatalytic treatment, the ammonia nitrogen concentration in wastewater has been greatly reduced, and resin adsorption treatment is used as a subsequent step, which can selectively adsorb residual trace amounts of ammonia nitrogen and other impurities, thereby realizing deep purification of wastewater and ensuring that the effluent quality meets or exceeds relevant discharge standards.

The invention discloses a selective desiliconization method for alkaline vanadium liquid. According to the process, magnesium-aluminum hydrotalcite prepared in advance is introduced into the alkaline vanadium liquid, the pH does not need to be regulated and controlled, silicon can be selectively adsorbed, desilicication slag is desorbed and then recycled as a desilicication agent, and a sodium silicate-containing solution can be used for preparing a water glass product. According to the method for deeply adsorbing silicon in the alkaline vanadium liquid by adopting the magnesium-aluminum hydrotalcite, various conditions of an existing process are not greatly changed, disturbance to existing industrial production is small, meanwhile, the problems that the desilicication limit of the alkaline vanadium liquid is insufficient and vanadium loss is high at present can be solved, silicon in the alkaline vanadium liquid can be reduced to 30 mg / L or below, and the requirements of vanadium products are met.

The invention provides a method for preparing high-purity phosphatidylserine by a batch enzyme catalysis method based on dynamic choline removal, and belongs to the technical field of enzymatic reaction. According to the method disclosed by the invention, in a reaction system for preparing phosphatidylserine, a byproduct choline is selectively adsorbed by adopting resin. Choline in a reaction system is removed in real time through the integrated adsorption separation module, the enzyme inhibition problem is solved, and meanwhile, the PC conversion rate is larger than or equal to 98% and the PS purity is larger than or equal to 96% in combination with the immobilized enzyme circulation technology; the enzyme can be reused for more than or equal to 20 times (activity retention is more than or equal to 90%); and the choline residual concentration is less than or equal to 0.5 mM (an inhibition threshold value or less).

The invention discloses a protein-based adsorbent capable of efficiently adsorbing perfluorinated compounds and application of the protein-based adsorbent. The adsorbent is obtained by coating polyethyleneimine in a phase transition aggregate formed by unfolding protein through a disulfide bond reducing agent. The use method of the adsorbent comprises the step of feeding the adsorbent into a solution containing the perfluorinated compound to realize efficient adsorption of the perfluorinated compound. The adsorbent has the advantages of being low in cost, efficient, easy to operate, environmentally friendly, free of secondary pollution, good in biocompatibility and the like, efficient selective adsorption of perfluorinated compounds can be achieved through the adsorbent, the adsorbent can be repeatedly used, and industrial application and popularization are easy.

The invention relates to the technical field of wastewater treatment, in particular to an ammonia-nitrogen wastewater treatment method.A composite modified zeolite material has excellent physical adsorption capacity on ammonia nitrogen by means of the unique pore structure and surface property of the composite modified zeolite material, ammonia nitrogen molecules in wastewater can be rapidly captured, and the ammonia nitrogen wastewater treatment effect is improved. Then, under the synergistic effect of illumination and ultrasonic waves, free radicals with strong oxidizing property are generated through the composite photocatalyst, ammonia nitrogen molecules which are not completely adsorbed by the zeolite material are deeply degraded, and the removal efficiency of ammonia nitrogen is remarkably improved through the synergistic effect of adsorption and photocatalysis; after adsorption and photocatalysis treatment, the concentration of ammonia nitrogen in the wastewater is greatly reduced, then resin adsorption treatment is adopted as a subsequent step, and residual trace ammonia nitrogen and other impurities can be selectively adsorbed, so that deep purification of the wastewater is realized, and the effluent quality is ensured to reach or be superior to related emission standards.

The invention belongs to the technical field of power equipment state monitoring, and discloses a transformer oil dissolved gas surface enhanced Raman spectrum in-situ monitoring method and a transformer oil dissolved gas surface enhanced Raman spectrum in-situ monitoring system. The system comprises a membrane degassing unit, a Raman sensing unit, a light path unit, a data processing unit and a calibration early warning unit, the method comprises the following steps: firstly preparing a gold nanostar array sensing substrate with bifunctional groups to realize selective adsorption and signal enhancement of characteristic gas, then completing in-situ oil-gas separation through the membrane degassing unit, collecting a Raman spectrum through the light path unit, and calculating the Raman spectrum of the gold nanostar array sensing substrate according to the Raman spectrum. Spectral analysis and quantification are completed based on multiple algorithms, and fault early warning is achieved in combination with temperature and pressure compensation and an industrial standard threshold value. According to the scheme, the problems of lagging, weak interference resistance and the like of traditional monitoring are solved, high sensitivity and high specificity are achieved, full-process automatic closed-loop monitoring can be achieved, and accurate data support is provided for operation and maintenance of the transformer.

The invention relates to the technical field of purification, and discloses a hydrogen purification method based on a magnesium-based solid hydrogen storage material, which comprises the following steps: S11, packaging the magnesium-based solid hydrogen storage material into a plurality of purification units, connecting the two purification units in parallel, and arranging a thermal interaction unit between the two parallel purification units to form a primary purification module; and S2, purification: introducing the low-purity hydrogen into the purification module, so that the low-purity hydrogen is respectively subjected to a hydrogen absorption reaction and a hydrogen desorption reaction for multiple times in the purification units connected in parallel, the low-purity hydrogen is purified, heat is supplied to the purification units which are subjected to the hydrogen desorption reaction through the heat interaction unit, and heat energy released by the hydrogen absorption reaction is stored. Based on the selective adsorption capacity of the solid hydrogen storage material to hydrogen, the solid hydrogen storage material is used for adsorbing hydrogen and discharging impurity gas, so that the purity of hydrogen is improved, and the heat interaction unit is used for storing heat energy released by a hydrogen absorption reaction and applying the heat energy to a hydrogen desorption reaction, so that the energy consumption in the purification process is reduced.

The invention provides a high-quality potassium hydroxide refining and impurity removal process, belongs to the field of potassium hydroxide impurity removal, and aims to overcome the defect that the purity of a potassium hydroxide product is reduced due to defects in removal precision and process stability during potassium hydroxide impurity removal in the prior art. The method comprises the following steps: carrying out oxidation decomposition on organic matters and precipitating calcium and magnesium ions, carrying out coarse filtration to remove large-particle impurities, carrying out graded filtration by adopting a three-stage series inorganic membrane module, carrying out efficient interception on impurities with different particle sizes by accurately controlling the pressure, temperature and flow rate of each membrane layer, and carrying out hydrochloric acid neutralization and potassium sulfite dechlorination to optimize the indexes of the brine. And finally, trace calcium and magnesium ions are deeply removed by utilizing the selective adsorption characteristics of the chelate resin and the strong acid cation resin, and after the resin is saturated, the resin is eluted, regenerated and recycled through acid and alkali with specific concentration, so that the impurity removal effect of potassium hydroxide is improved.

The invention provides a method for accurately regulating and controlling pores of an MXene material by utilizing a phosphonic acid ligand, which mainly comprises the following key steps of: directionally removing a main group element (A) layer of an MAX precursor by wet etching to obtain lamellar MXene, and then introducing a protonated quaternary amine compound intercalator to strip the MXene. And finally, carrying out functional modification and conversion by adopting a phosphonic acid ligand, and stably introducing phosphonic acid groups between layers and on the surface of MXene through solvothermal reaction to realize accurate regulation and control of interlayer spacing. The prepared material can realize efficient adsorption of uranyl in an acidic environment, shows high selectivity, high adsorption capacity and good acid stability and regeneration capacity to uranyl, provides a stable and efficient selective adsorption solution for treating high-acidity uranium-containing nuclear wastewater, and has a remarkable industrial application prospect.

The invention discloses an intelligent modified atmosphere packaging film with gas selectivity and pH / humidity double response as well as a preparation method and application of the intelligent modified atmosphere packaging film. The preparation method comprises the following steps: mixing thymol emulsion and graphene oxide dispersion liquid, and stirring and reacting at room temperature in a dark place to prepare graphene oxide-thymol; the preparation method comprises the following steps: dissolving chitosan in an acetic acid aqueous solution, then adding graphene oxide-thymol and a plasticizer, and carrying out ultrasonic dispersion treatment to form a film-forming solution; and carrying out film forming treatment on the film forming solution by adopting a casting method to prepare the intelligent modified atmosphere packaging film with gas selectivity and pH / humidity double response. The prepared intelligent modified atmosphere packaging film can be modified automatically, is uniform and stable in structure, high in encapsulation efficiency, close in coordination, good in antibacterial and antioxidant activity and excellent in mechanical property and gas barrier property, can realize selective adsorption of gas, controls release of thymol by responding to changes of the pH value and humidity in the environment, and has a good application prospect. The method has a good application prospect in the field of fruit and vegetable preservation.

The invention discloses a deep fluorine removal agent and application thereof in wastewater in the photovoltaic industry, and belongs to the technical field of fluorine-containing wastewater treatment.The deep fluorine removal agent is obtained by conducting coordination on cross-linked hybrid chitosan microspheres and lanthanum ions to obtain composite microspheres and then synthesizing zirconium-based MOF on the composite microspheres through a hydrothermal synthesis method. The pore channels of the MOF facilitate the passing of fluorine ions but not the passing of sulfate ions, play a certain barrier role, facilitate the enrichment of the fluorine ions on the surfaces of the composite microspheres and the selective adsorption of the lanthanum ions on the fluorine ions, so that the fluorine ions are fixed, and the combination stability of the fluorine ions and the lanthanum ions is greater than that of the sulfate ions. The sulfate ions are in disadvantage when competitive adsorption with the fluorine ions, the selectivity of the deep fluorine removal agent to the fluorine ions is improved, the magnesium ions can be combined with the fluorine ions to generate complexes and can be combined with the sulfate ions to generate soluble magnesium sulfate, and interference of the sulfate ions is reduced through cooperation of the magnesium ions and the sulfate ions.

The invention belongs to the technical field of organic matter extraction, and particularly relates to a green directional extraction and purification method for haematococcus astaxanthin, which comprises the following steps: (1) mixing dried haematococcus powder and a composite pretreatment agent according to a mass ratio of 1: (8-15), and stirring to obtain a pretreated algae solution; (2) treating the pretreated algae liquid through ultrahigh-pressure microjet equipment to obtain wall-broken slurry; (3) mixing the wall-broken slurry and a composite extraction agent according to a volume ratio of 1: 3-1: 5, and performing extraction separation to obtain an astaxanthin extraction phase; (4) carrying out selective adsorption on the astaxanthin extraction phase through an adsorption column filled with a molecular imprinting adsorbent; (5) collecting eluent by adopting a gradient elution method; and (6) performing vacuum concentration on the eluent, and performing spray drying to obtain an astaxanthin product. According to the method, the astaxanthin extraction efficiency and the product purity are remarkably improved, meanwhile, the energy consumption is reduced to the maximum extent, toxic solvent residues are avoided, and the stability of the astaxanthin is effectively protected.

The invention discloses a method for treating heavy metal wastewater by using a bimetal MOFs (Metal-Organic Frameworks) derived carbon-porous carbon composite electrode material. The method comprises the following steps: preparing the bimetal MOFs derived carbon-porous carbon into a composite electrode material, and assembling the composite electrode material as a working electrode into a capacitive deionization device; and carrying out electro-adsorption treatment on the heavy metal wastewater by utilizing the capacitive deionization device to finish treatment on the heavy metal wastewater. According to the present invention, the bimetallic MOFs derived carbon-porous carbon assembled capacitive deionization device is utilized to treat the heavy metal wastewater, such that the characteristics of high adsorption capacity and selective adsorption are provided while the heavy metal ions are efficiently and rapidly removed so as to achieve the efficient removal of the heavy metals in the wastewater, and the selective recovery of the toxic and harmful metals can be performed; the method has the advantages of being low in cost, simple in process, convenient to operate, high in treatment efficiency, good in removal effect, environmentally friendly and the like, and has high application value and wide application prospects in the aspect of heavy metal polluted water treatment.

The invention relates to the field of industrial silicon melt purification, and discloses an industrial silicon melt purification method based on directional solidification and composite adsorption, which comprises the following steps: S1, multi-stage directional solidification pre-enrichment: carrying out primary directional solidification treatment on an industrial silicon melt, and controlling the solidification rate to be 0.5-5mm / min and the temperature gradient parameter, most of metal impurities in the melt are pre-enriched in a specific area; s2, dynamic targeted adsorption: in or after the primary directional solidification process, an efficient composite adsorbent is dynamically and continuously added into an impurity-rich area of the melt or the whole melt in batches, and the composite adsorbent has selective adsorption capacity for different impurities; and S3, intelligent regulation and control: constructing a full-flow adaptive intelligent dynamic regulation and control system based on digital twinning and AI algorithms. Compared with the prior art, the method has the advantages that the impurities are efficiently and stably removed, the grain structure is accurately modified, and meanwhile, the green and low-carbon production target is achieved.

The invention discloses a rapid enrichment-atomic absorption spectrum analysis method for low-content gold in gold ore, and relates to the technical field of gold ore analysis and detection.The rapid enrichment-atomic absorption spectrum analysis method comprises the following steps that an ore sample and a solid composite additive are mixed and roasted at the low temperature of 500-650 DEG C, and the additive contains alkali metal carbonate and zinc oxide; sulfur fixation, catalytic oxidation of organic carbon and stabilization of volatile elements can be synchronously realized; the method comprises the following steps: roasting gold-loaded activated carbon, dissolving the gold-loaded activated carbon in aqua regia to obtain a to-be-enriched solution, enabling the solution to pass through an adsorption column filled with modified activated carbon, pretreating the activated carbon with a 1-10% ammonium citrate solution to improve the selective adsorption capacity of the activated carbon on gold chloride complex ions, ashing the gold-loaded activated carbon, dissolving residues, fixing the volume, and measuring by using an atomic absorption spectrometry. According to the rapid enrichment-atomic absorption spectrum analysis method for the low-content gold in the gold ore, through cooperation of low-temperature roasting of the composite additive and selective adsorption of the modified activated carbon, the decomposition efficiency and enrichment selectivity of the ore difficult to treat are improved.

The invention discloses a modified polyferric coagulant and a preparation method thereof, and belongs to the technical field of papermaking wastewater treatment.The polyferric sulfate serves as a main chain and then is combined with carboxylated polyvinyl alcohol, the carboxylated polyvinyl alcohol contains a large number of carboxyl groups, and the carboxylated polyvinyl alcohol and iron ions in polyferric molecules can form stable complexing coordination bonds; kH-570 can generate a polyhydroxy complex after hydrolysis, and active silanol on the surface of the hydrolysis product serves as a carrier with a larger surface area, can be combined with polyferric sulfate and can be subjected to a condensation reaction with hydroxyl and amino on chitosan, so that the molecular weight of the polymer is increased. Compared with a conventional coagulant, the prepared modified polyferric coagulant has the advantages that the selective adsorption performance is increased, the characteristic that PFS carries a large number of positive charges is reserved, meanwhile, molecular chains are increased, the speed of net capturing, sweeping and floc forming is increased, and the coagulation effect is higher.

The present invention provides a hydrogenation catalyst for petroleum resin, the hydrogenation catalyst comprises a catalyst, the catalyst contains an active component main body expressed as a general formula of M1-M2 / SiO2-Al2O3, M1 is an alloy of Ni and Co, and the atomic ratio of Ni to Co is 2: 1-4: 1; m2 is a composite oxide of Mo and W, and the molar ratio of Mo to W is 1: 1-3: 1; and SiO2-Al2O3 is used as an aluminum silicate precursor and is subjected to hydrolytic condensation to form a composite carrier with a three-dimensional silicon-aluminum bond network structure. The invention relates to the technical field of petroleum resin catalysts. The surface of the carrier is anchored with double active components, namely nickel-cobalt alloy capable of efficiently cracking hydrogen and generating active hydrogen atoms and molybdenum-tungsten composite oxide capable of selectively adsorbing aromatic rings and sulfide molecules; and cracked hydrogen atoms can be quickly migrated to adsorption sites through the surface of the carrier, and aromatic ring hydrogenation saturation and deep removal of sulfur impurities can be synchronously realized, so that the working efficiency of the hydrogenation catalyst is effectively improved.

The invention belongs to the technical field of ceramic slurry, and particularly relates to ceramic slurry and a preparation method and application thereof.The ceramic slurry comprises inorganic components and organic components, the inorganic components comprise inorganic additives and glass powder, the inorganic additives comprise Al2O3, ZrO2 and Y2O3, and the organic components comprise modified acrylic resin, organic solvent and auxiliaries. By controlling the relative content of carboxyl and ester groups in the modified acrylic resin and utilizing the polarity difference of functional groups, selective adsorption of inorganic powder is realized, so that the dispersion uniformity of the powder in the ceramic slurry is remarkably improved, segregation of yttrium oxide is effectively inhibited, and the service life of the ceramic slurry is prolonged. Therefore, monoclinic-phase zirconium oxide, tetragonal-phase zirconium oxide and cubic-phase zirconium oxide with a proper proportion can be formed in the sintered ceramic substrate, further the bending strength of the ceramic substrate is remarkably improved, and the ceramic substrate is particularly suitable for manufacturing miniaturized and thin electronic components.

The invention belongs to the technical field of mineral flotation separation, and particularly relates to a complexing inhibitor and application thereof in mineral flotation separation of smithsonite and calcium-containing gangue. The complexing inhibitor provided by the invention is prepared by complexing a flavonoid organic compound and aluminum ions, is used for flotation separation of smithsonite and calcium-containing gangue minerals, can be selectively adsorbed on the surface of the calcium-containing gangue, effectively inhibits the floatability of the calcium-containing gangue, and has the advantages that compared with a traditional agent, the complexing inhibitor is simple in preparation method and low in cost; the method has the advantages of being high in separation efficiency, small in reagent dosage, environmentally friendly and the like, the grade and the recovery rate of smithsonite can be remarkably improved, and the method has important significance on efficient recycling of zinc oxide resources.

The invention belongs to the field of phosphorus chemical industry, and particularly relates to a method for synchronously preparing type II anhydrite in a semi-hydrated-dihydrated wet-process phosphoric acid process and the type II anhydrite. The method comprises the following steps: carrying out slurry premixing, semi-hydrated crystallization, dihydrate conversion and dihydrate filtration to obtain dihydrate gypsum, after the semi-hydrated crystallization step, leading out a part of slurry, adding a lattice orientation agent and a crystal face selective adsorbent into an intermediate pretreatment tank for pretreatment, and adding concentrated sulfuric acid into an anhydrous crystallization reactor for anhydrous crystallization, and finally, carrying out solid-liquid separation, washing and drying to obtain the type II anhydrite. The method is simple in process, energy-saving and environment-friendly, co-production of the phosphoric acid product and the high-added-value II type anhydrous gypsum is realized, and the product yield is gt; therefore, the method has remarkable economic benefits and environmental benefits.

The invention relates to the technical field of water treatment, in particular to a leachate treatment system and method.The system comprises an oxidation module, a hardness removal module, a first adsorption module, a second adsorption module and a monitoring module, and the oxidation module is used for degrading macromolecular organic matter and comprises a Fenton reactor, an ozone generator and an electrocatalytic oxidation device; the hardness removal module is used for removing heavy metals, fluorosilicone and suspended matters, and comprises a dual-alkali reaction tank and a tubular ultrafiltration membrane; the first adsorption module is used for adsorbing organic matters in the leachate through activated carbon; the second adsorption module comprises a first resin exchange tower for selectively adsorbing residual hardness and heavy metal and a second resin exchange tower for adsorbing fluoride and silicate; the monitoring module comprises a group of flow velocity sensors and a group of voiceprint collectors which are respectively arranged on a pipeline in the liquid inlet direction of the tubular ultrafiltration membrane and a pipeline in the liquid outlet direction of the first adsorption module; and the processing quality is effectively improved by comparing the voiceprint with the monitoring processing process under the characteristic flow rate.

The invention relates to the technical field of environmental engineering, and particularly discloses an underground water remediation and activity monitoring system based on a zero-valent iron-based nano material, which comprises composite nano particles consisting of a zero-valent iron core, a ferrous sulfide / humic acid dynamic compensation layer and a temperature-sensitive polymer, through a crack self-adaptive regulation and control module driven by a sensor array and a temperature difference driving migration module based on an underground water temperature gradient, the system can realize automatic circulation of selective adsorption, desorption and degradation of pollutants under different temperature conditions through the combined action of a phase change behavior of a temperature-sensitive polymer and a dynamic compensation layer; the stability and the repair efficiency of the nanoparticles are improved; compared with a traditional scheme, the method has the advantages that on-demand response activity adjusting capacity and an accurate injection path guiding mechanism are achieved, the technical bottlenecks that in the groundwater heterogeneous environment, migration of a repairing agent is uncontrollable, and adsorption selectivity is poor are avoided, and good engineering adaptability and practical application prospects are achieved.

The invention belongs to the technical field of electrochemical energy storage, and particularly discloses an aqueous zinc ion battery electrolyte containing maleamic acid, a battery and a preparation method of the battery. The electrolyte takes water as a solvent and comprises zinc salt and a maleamic acid additive. Maleamic acid forms a stable interface protection layer on the surface of zinc through selective adsorption of polar carboxyl functional groups of maleamic acid, so that the free water activity of an electrode / electrolyte interface is remarkably reduced, and hydrogen evolution and byproducts are inhibited; the nucleation overpotential of zinc deposition is improved, and uniform nucleation of zinc ions is promoted; and the zinc crystal face is induced to preferentially grow, and a compact and ordered deposition layer dominated by the (101) crystal face is formed, so that dendritic crystals are inhibited. A battery assembled by adopting the electrolyte shows excellent cycling stability. The electrolyte provided by the invention is simple in formula, low in cost and environment-friendly, provides a new solution for developing a water-based zinc ion battery with high safety and long service life, and has important application value in the field of large-scale energy storage.

The invention discloses an MOF-based porous liquid modified composite membrane, a preparation method and an application in an ECMO system, the composite membrane comprises a PMP hollow fiber membrane, Pebax and an MOF-based porous liquid material are doped on the PMP hollow fiber membrane, the Pebax comprises a polyamide-polyether block, the MOF-based porous liquid material is doped on the PMP hollow fiber membrane, the Pebax is doped on the PMP hollow fiber membrane, and the MOF-based porous liquid material is doped on the Pebax. The MOF-based porous liquid material comprises UiO-66 of which the surface is grafted with organic silane. The composite membrane shows excellent CO2 / O2 selective adsorption performance in an ECMO system, and has good blood compatibility and biocompatibility at the same time.

The invention provides application of a silver modified AFX molecular sieve in xenon and krypton gas separation, and belongs to the technical field of gas separation. According to the invention, silver ions with electronegativity are introduced into AFX molecular sieve pores through ion exchange, selective adsorption of xenon is realized through the AFX topological molecular sieve subjected to Ag exchange so as to enrich xenon, and excellent separation of xenon and krypton is finally realized. The xenon and krypton adsorption isotherm of the silver modified AFX molecular sieve under the condition of 25 DEG C is tested, and the IAST (ideal adsorption solution theoretical value) of the molecular sieve is analyzed to be 36.5 through a static adsorption curve; according to the method disclosed by the invention, a dynamic penetration test is carried out under trace Xe and Kr concentrations by simulating the waste gas subjected to UNF post-treatment, and the dynamic capacity of Xe is calculated to be 104 mmol kg <-1 >, which is superior to that of other reported materials.

The invention belongs to the technical field of lead ion detection, and particularly relates to a black phosphorus field-effect tube lead ion detector and a use method thereof. The detector comprises an insulating substrate, a gate electrode layer, a gate electrode insulating layer, a sensitive layer, a source electrode and a drain electrode. The gate electrode layer is arranged on the insulating substrate, and the sensitive layer is arranged on the gate electrode insulating layer; particularly, the sensitive layer comprises a black phosphorus material, and noble metal particles are arranged on the surface of the sensitive layer. According to the invention, black phosphorus is used as a sensitive material of the field effect transistor, the black phosphorus and lead ions have good chemical matching property, and a stable coordination effect is formed through surface phosphorus atoms and lead ions, so that the conductivity of a channel is obviously changed; in addition, precious metal particles are introduced to the surface of the black phosphorus sensitive layer, so that the selective adsorption capacity of lead ions is enhanced. In a word, high-selectivity and high-sensitivity electrical detection of lead ions can be realized, and a high-performance field-effect tube sensor platform is provided for rapid monitoring of heavy metal pollutants.

The invention discloses an application of a novel miscellaneous [3] aromatic hydrocarbon crystal material in adsorptive separation of a pyrrolidine and tetrahydrofuran mixture and / or capture of iodine vapor, and relates to the technical field of adsorption.Firstly, the novel miscellaneous [3] aromatic hydrocarbon crystal material capable of adsorptive separation of pyrrolidine and tetrahydrofuran so as to realize iodine capture is synthesized; the application method comprises the following steps: selectively adsorbing pyrrolidine in a mixture of pyrrolidine and tetrahydrofuran by adopting the novel miscellaneous [3] aromatic hydrocarbon crystal material to obtain a pyrrolidine-miscellaneous [3] aromatic hydrocarbon crystal material, realizing separation of tetrahydrofuran and pyrrolidine, and capturing iodine vapor by adopting the pyrrolidine-miscellaneous [3] aromatic hydrocarbon crystal material. Compared with other macrocyclic aromatic hydrocarbons, the method provided by the invention not only can realize separation of tetrahydrofuran and pyrrolidine, but also has the advantages of high iodine adsorption capacity, good thermal stability and the like; meanwhile, the synthesis method has the advantages of simplicity in operation, high yield, simplicity in post-treatment, easiness in separation and purification of products and the like.