650 results about "Selective adsorption" patented technology

The invention belongs to the technical field of power equipment state monitoring, and discloses a transformer oil dissolved gas surface enhanced Raman spectrum in-situ monitoring method and a transformer oil dissolved gas surface enhanced Raman spectrum in-situ monitoring system. The system comprises a membrane degassing unit, a Raman sensing unit, a light path unit, a data processing unit and a calibration early warning unit, the method comprises the following steps: firstly preparing a gold nanostar array sensing substrate with bifunctional groups to realize selective adsorption and signal enhancement of characteristic gas, then completing in-situ oil-gas separation through the membrane degassing unit, collecting a Raman spectrum through the light path unit, and calculating the Raman spectrum of the gold nanostar array sensing substrate according to the Raman spectrum. Spectral analysis and quantification are completed based on multiple algorithms, and fault early warning is achieved in combination with temperature and pressure compensation and an industrial standard threshold value. According to the scheme, the problems of lagging, weak interference resistance and the like of traditional monitoring are solved, high sensitivity and high specificity are achieved, full-process automatic closed-loop monitoring can be achieved, and accurate data support is provided for operation and maintenance of the transformer.

The invention discloses an intelligent modified atmosphere packaging film with gas selectivity and pH / humidity double response as well as a preparation method and application of the intelligent modified atmosphere packaging film. The preparation method comprises the following steps: mixing thymol emulsion and graphene oxide dispersion liquid, and stirring and reacting at room temperature in a dark place to prepare graphene oxide-thymol; the preparation method comprises the following steps: dissolving chitosan in an acetic acid aqueous solution, then adding graphene oxide-thymol and a plasticizer, and carrying out ultrasonic dispersion treatment to form a film-forming solution; and carrying out film forming treatment on the film forming solution by adopting a casting method to prepare the intelligent modified atmosphere packaging film with gas selectivity and pH / humidity double response. The prepared intelligent modified atmosphere packaging film can be modified automatically, is uniform and stable in structure, high in encapsulation efficiency, close in coordination, good in antibacterial and antioxidant activity and excellent in mechanical property and gas barrier property, can realize selective adsorption of gas, controls release of thymol by responding to changes of the pH value and humidity in the environment, and has a good application prospect. The method has a good application prospect in the field of fruit and vegetable preservation.

The invention belongs to the technical field of organic matter extraction, and particularly relates to a green directional extraction and purification method for haematococcus astaxanthin, which comprises the following steps: (1) mixing dried haematococcus powder and a composite pretreatment agent according to a mass ratio of 1: (8-15), and stirring to obtain a pretreated algae solution; (2) treating the pretreated algae liquid through ultrahigh-pressure microjet equipment to obtain wall-broken slurry; (3) mixing the wall-broken slurry and a composite extraction agent according to a volume ratio of 1: 3-1: 5, and performing extraction separation to obtain an astaxanthin extraction phase; (4) carrying out selective adsorption on the astaxanthin extraction phase through an adsorption column filled with a molecular imprinting adsorbent; (5) collecting eluent by adopting a gradient elution method; and (6) performing vacuum concentration on the eluent, and performing spray drying to obtain an astaxanthin product. According to the method, the astaxanthin extraction efficiency and the product purity are remarkably improved, meanwhile, the energy consumption is reduced to the maximum extent, toxic solvent residues are avoided, and the stability of the astaxanthin is effectively protected.

The invention relates to the field of industrial silicon melt purification, and discloses an industrial silicon melt purification method based on directional solidification and composite adsorption, which comprises the following steps: S1, multi-stage directional solidification pre-enrichment: carrying out primary directional solidification treatment on an industrial silicon melt, and controlling the solidification rate to be 0.5-5mm / min and the temperature gradient parameter, most of metal impurities in the melt are pre-enriched in a specific area; s2, dynamic targeted adsorption: in or after the primary directional solidification process, an efficient composite adsorbent is dynamically and continuously added into an impurity-rich area of the melt or the whole melt in batches, and the composite adsorbent has selective adsorption capacity for different impurities; and S3, intelligent regulation and control: constructing a full-flow adaptive intelligent dynamic regulation and control system based on digital twinning and AI algorithms. Compared with the prior art, the method has the advantages that the impurities are efficiently and stably removed, the grain structure is accurately modified, and meanwhile, the green and low-carbon production target is achieved.

The invention discloses a rapid enrichment-atomic absorption spectrum analysis method for low-content gold in gold ore, and relates to the technical field of gold ore analysis and detection.The rapid enrichment-atomic absorption spectrum analysis method comprises the following steps that an ore sample and a solid composite additive are mixed and roasted at the low temperature of 500-650 DEG C, and the additive contains alkali metal carbonate and zinc oxide; sulfur fixation, catalytic oxidation of organic carbon and stabilization of volatile elements can be synchronously realized; the method comprises the following steps: roasting gold-loaded activated carbon, dissolving the gold-loaded activated carbon in aqua regia to obtain a to-be-enriched solution, enabling the solution to pass through an adsorption column filled with modified activated carbon, pretreating the activated carbon with a 1-10% ammonium citrate solution to improve the selective adsorption capacity of the activated carbon on gold chloride complex ions, ashing the gold-loaded activated carbon, dissolving residues, fixing the volume, and measuring by using an atomic absorption spectrometry. According to the rapid enrichment-atomic absorption spectrum analysis method for the low-content gold in the gold ore, through cooperation of low-temperature roasting of the composite additive and selective adsorption of the modified activated carbon, the decomposition efficiency and enrichment selectivity of the ore difficult to treat are improved.

The invention belongs to the technical field of ceramic slurry, and particularly relates to ceramic slurry and a preparation method and application thereof.The ceramic slurry comprises inorganic components and organic components, the inorganic components comprise inorganic additives and glass powder, the inorganic additives comprise Al2O3, ZrO2 and Y2O3, and the organic components comprise modified acrylic resin, organic solvent and auxiliaries. By controlling the relative content of carboxyl and ester groups in the modified acrylic resin and utilizing the polarity difference of functional groups, selective adsorption of inorganic powder is realized, so that the dispersion uniformity of the powder in the ceramic slurry is remarkably improved, segregation of yttrium oxide is effectively inhibited, and the service life of the ceramic slurry is prolonged. Therefore, monoclinic-phase zirconium oxide, tetragonal-phase zirconium oxide and cubic-phase zirconium oxide with a proper proportion can be formed in the sintered ceramic substrate, further the bending strength of the ceramic substrate is remarkably improved, and the ceramic substrate is particularly suitable for manufacturing miniaturized and thin electronic components.

The invention belongs to the field of phosphorus chemical industry, and particularly relates to a method for synchronously preparing type II anhydrite in a semi-hydrated-dihydrated wet-process phosphoric acid process and the type II anhydrite. The method comprises the following steps: carrying out slurry premixing, semi-hydrated crystallization, dihydrate conversion and dihydrate filtration to obtain dihydrate gypsum, after the semi-hydrated crystallization step, leading out a part of slurry, adding a lattice orientation agent and a crystal face selective adsorbent into an intermediate pretreatment tank for pretreatment, and adding concentrated sulfuric acid into an anhydrous crystallization reactor for anhydrous crystallization, and finally, carrying out solid-liquid separation, washing and drying to obtain the type II anhydrite. The method is simple in process, energy-saving and environment-friendly, co-production of the phosphoric acid product and the high-added-value II type anhydrous gypsum is realized, and the product yield is gt; therefore, the method has remarkable economic benefits and environmental benefits.

The invention provides application of a silver modified AFX molecular sieve in xenon and krypton gas separation, and belongs to the technical field of gas separation. According to the invention, silver ions with electronegativity are introduced into AFX molecular sieve pores through ion exchange, selective adsorption of xenon is realized through the AFX topological molecular sieve subjected to Ag exchange so as to enrich xenon, and excellent separation of xenon and krypton is finally realized. The xenon and krypton adsorption isotherm of the silver modified AFX molecular sieve under the condition of 25 DEG C is tested, and the IAST (ideal adsorption solution theoretical value) of the molecular sieve is analyzed to be 36.5 through a static adsorption curve; according to the method disclosed by the invention, a dynamic penetration test is carried out under trace Xe and Kr concentrations by simulating the waste gas subjected to UNF post-treatment, and the dynamic capacity of Xe is calculated to be 104 mmol kg <-1 >, which is superior to that of other reported materials.

The invention discloses an application of a novel miscellaneous [3] aromatic hydrocarbon crystal material in adsorptive separation of a pyrrolidine and tetrahydrofuran mixture and / or capture of iodine vapor, and relates to the technical field of adsorption.Firstly, the novel miscellaneous [3] aromatic hydrocarbon crystal material capable of adsorptive separation of pyrrolidine and tetrahydrofuran so as to realize iodine capture is synthesized; the application method comprises the following steps: selectively adsorbing pyrrolidine in a mixture of pyrrolidine and tetrahydrofuran by adopting the novel miscellaneous [3] aromatic hydrocarbon crystal material to obtain a pyrrolidine-miscellaneous [3] aromatic hydrocarbon crystal material, realizing separation of tetrahydrofuran and pyrrolidine, and capturing iodine vapor by adopting the pyrrolidine-miscellaneous [3] aromatic hydrocarbon crystal material. Compared with other macrocyclic aromatic hydrocarbons, the method provided by the invention not only can realize separation of tetrahydrofuran and pyrrolidine, but also has the advantages of high iodine adsorption capacity, good thermal stability and the like; meanwhile, the synthesis method has the advantages of simplicity in operation, high yield, simplicity in post-treatment, easiness in separation and purification of products and the like.

The invention belongs to the technical field of flexible electronic materials, and particularly relates to an adsorption layer for promoting patterning and separation of liquid metal, a preparation method of the adsorption layer and a recoverable flexible liquid metal sensing device. The metal organic framework material-polymer is used as an adsorption layer for promoting patterning and separation of the liquid metal, and the characteristics that the liquid metal is adsorbed on the surface of the polymer and repelled on the surface of the metal organic framework material are achieved by adjusting surface functional groups and roughness. And meanwhile, high-precision patterning is carried out on the polymer through a 3D printing or photoetching technology, and a high-precision liquid metal pattern is obtained under selective adsorption of the liquid metal. Besides, according to the dissolution characteristics of the metal-organic framework material and the polymer, a two-step recovery method for dissolving the polymer, separating the liquid metal from the polymer and then dissolving and separating the metal-organic framework material is designed, and the scheme of the invention is beneficial to the integration and sustainable development of the liquid metal-based electronic device.

The invention discloses a method for synergistically extracting vanadium oxytrichloride, gallium trichloride and iron-titanium alloy from vanadium slag, and belongs to the field of recycling of complex multi-metal resources. The method comprises the following steps: uniformly mixing the gallium-containing vanadium slag, carbon and chlorinated waste salt according to a certain proportion, and carrying out vacuum melting treatment to obtain a Fe-Ti alloy; then chlorine is introduced for chlorination treatment, and a gaseous product is obtained; the gaseous product is adsorbed by a molecular sieve with a function of selectively adsorbing VOCl3 to obtain VOCl3, and then GaCl3 is obtained through a cold trap. According to the method, efficient collaborative conversion and recovery of multi-metal resources of vanadium, gallium, iron and titanium in the vanadium slag are achieved, and the problems that multi-metal collaborative extraction in existing vanadium slag is difficult, and the separation efficiency is low can be effectively solved.

The invention relates to the field of electroplating sludge, and particularly discloses a selective separation and resource recycling method for copper in electroplating sludge. The method comprises the following steps: mixing and roasting electroplating sludge and sodium salt, and washing with water to obtain filter residues; then carrying out acid leaching on the filter residues to obtain an acid leaching solution containing iron, copper, nickel and zinc; then enabling the pickle liquor to sequentially pass through a first ion exchange column filled with monophosphate group chelating resin and a second ion exchange column filled with copper selective functionalized resin to selectively adsorb iron ions and copper ions respectively; then desorbing the resin adsorbing the copper by using an acid solution to obtain a copper-containing eluent; and finally, carrying out evaporation concentration and recrystallization treatment to obtain a high-purity copper salt product. According to the method, the separation selectivity and the recovery efficiency of copper in the electroplating sludge are fundamentally improved by adopting a chelating resin combination with specific functional groups and an optimized acid leaching-adsorption series process.

The invention belongs to the field of medical isotope separation and preparation, and particularly relates to a method for separating and purifying < 212 > Pb from a thorium solution, which comprises the following steps: 1) leacheate is introduced into a Pb selective adsorption column to pretreat the Pb selective adsorption column, and then < 232 > Th salt solution and leacheate are introduced in sequence; 2) continuously introducing a desorption solution into the Pb selective adsorption column, enabling the desorption solution passing through the Pb selective adsorption column to flow into the Th selective adsorption column, and collecting the outflowing desorption solution; a desorption solution only containing 212Pb is obtained; according to the method, the 212Pb in the high-concentration thorium solution can be separated and purified at the same time. While < 232 > Th impurity entrainment and pollution in a < 212 > Pb product are remarkably reduced, compared with a single-column process, the separation time is basically not increased. The separated 212Pb product has high radionuclide purity and chemical purity at the same time, and can meet related pharmaceutical requirements.

The invention relates to the technical field of food safety detection, in particular to solid-phase extraction filler for detecting pesticide residues in food and a preparation method and application thereof.The solid-phase extraction filler comprises a magnetic filler core and a selective adsorption layer wrapping the magnetic filler core; wherein the interior of the magnetic filler core at least comprises magnetic particles and a coating layer for improving the stability of the magnetic particles; the selective adsorption layer is composed of a porous organic framework material which is chemically grafted outside the coating layer; and a temperature-sensitive polymer gel layer also covers the outer part of the selective adsorption layer. According to the solid-phase extraction filler disclosed by the invention, through an innovative hierarchical structure design, the extraction of trace pesticide residues in food can be effectively improved, the extraction difficulty is reduced, and the extraction efficiency and the extraction selectivity are improved.

The invention relates to a beta-cyclodextrin-based composite adsorption material with high selectivity as well as a preparation method and application of the beta-cyclodextrin-based composite adsorption material. The preparation method comprises the following steps: dissolving beta-cyclodextrin, an acrylamide monomer and a sodium p-styrenesulfonate monomer in water, and adjusting the pH value of the mixed solution to 6-8; adding an initiator into the obtained mixed solution, carrying out ultrasonic initiation polymerization reaction in an oxygen-free environment, and standing and curing overnight to obtain functional modified beta-cyclodextrin; dissolving the obtained functional modified beta-cyclodextrin, citric acid serving as a cross-linking agent and monopotassium phosphate serving as a catalyst in water, and heating for cross-linking reaction to obtain the beta-cyclodextrin-based composite adsorption material with high selectivity. Acrylamide and sodium p-styrenesulfonate monomers are grafted on beta-cyclodextrin through ultrasonic polymerization for chemical modification, then the characteristic that beta-cyclodextrin is easy to dissolve in water is changed through citric acid crosslinking, and the selective adsorption capacity of the obtained composite adsorption material to fluoroquinolone antibiotics is greatly enhanced.

A multilayer composite sorbent stack is used for gas separation. A gas feed stream is fed into a vessel that includes the multilayer composite sorbent stack. The multilayer composite sorbent stack includes several sorbent layers alternated with insulation layers, such that the insulation layer is placed between two sorbent layers. The active sorbent layer selectively adsorbs a specific gas molecule from the gas feed stream. Upon determining that the active sorbent layer is saturated with the adsorbed gas molecule, the active sorbent layer is regenerated to release the adsorbed gas molecule. If the active sorbent layer degrades or underperforms due to gas saturation, the insulation layer beneath the active sorbent layer is partially or completely exfoliated, thereby exposing the next sorbent layer to the incoming gas feed stream to continue the selective adsorption or desorption process.

The invention provides a low-VOC epoxy structural adhesive as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The low-VOC epoxy structural adhesive is mainly prepared from the following raw materials in parts by mass: 10 to 30 parts of filler, 0.1 to 0.5 part of curing accelerator, 1 to 5 parts of curing agent, 3 to 5 parts of moisture absorption agent, 0.01 to 0.05 part of pigment, 2 to 5 parts of thixotropic agent, 10 to 20 parts of core-shell modified epoxy resin, 10 to 15 parts of bisphenol F type epoxy resin, 10 to 20 parts of bisphenol A type epoxy resin, 15 to 25 parts of polyurethane modified epoxy resin and 10 to 15 parts of flexibilizer. 0.1 to 0.5 part of a silane coupling agent; and 0.1 to 0.5 part of a VOC adsorbent. By optimizing and upgrading the proportion of the low-VOC epoxy structural adhesive, high-efficiency selective adsorption of micromolecular volatile matters such as aldehydes and the like can be effectively realized, and the environmental protection property and the use safety of the product are remarkably improved.

The application provides a solid waste synthesis SSZ-16 zeolite molecular sieve and adsorption separation application thereof, and relates to the technical field of zeolite molecular sieves. Water, an alkali source, an organic template agent, a silicon source and FCC solid waste are mixed to obtain an initial reaction gel; the initial reaction gel is subjected to hydrothermal crystallization to obtain an initial SSZ-16 zeolite molecular sieve; and the initial SSZ-16 zeolite molecular sieve is calcined to obtain an SSZ-16 zeolite molecular sieve. The application uses the FCC solid waste without any treatment as an aluminum source, additionally supplements a silicon source, an organic template agent and an alkali source, and for the first time utilizes the FCC solid waste to synthesize the SSZ-16 zeolite molecular sieve with an AFX topological structure through a hydrothermal method. Moreover, the synthesized SSZ-16 zeolite molecular sieve has excellent selective adsorption and separation performance of carbon dioxide, and has a broad prospect in application fields such as flue gas carbon dioxide capture and natural gas carbon dioxide removal.

Processes and systems for providing a CO2 enriched stream from an air stream, by: selectively adsorbing, in a first separation zone, CO2 and H2O in an air stream and providing a CO2 and H2O depleted gas stream; separating, in a second separation zone, the CO2 and H2O depleted gas stream and providing an N2 enriched stream, an O2 enriched stream, and an N2 enriched regeneration stream; heating the N2 enriched regeneration stream to provide a heated N2 enriched regeneration stream; selectively desorbing, in the first separation zone, the CO2 and H2O using the heated N2 enriched regeneration stream and providing a spent regeneration gas stream; drying the spent regeneration gas stream to remove H2O and providing a dried spent regeneration gas stream; and separating, in a third separation zone, the CO2 from the dried spent regeneration gas stream to provide a CO2 enriched stream.

The invention relates to the technical field of copper smelting, in particular to an MOF composite membrane capable of selectively adsorbing rhenium and a preparation method and application of the MOF composite membrane. The preparation method of the MOF composite membrane capable of selectively adsorbing rhenium, provided by the invention, comprises the following steps: dispersing a sulfonic acid functionalized UiO-66 type metal organic framework material in a polyvinylidene fluoride solution to obtain a metal organic framework material dispersion liquid; mixing the metal organic framework material dispersion liquid with a cross-linking agent, carrying out a cross-linking reaction, and then mixing the obtained reaction liquid with an acid-resistant ionic liquid to obtain a spinning solution; performing electrostatic spinning on the spinning solution to obtain a silk membrane; and dipping the silk membrane in an amino silane coupling agent solution, and curing to obtain the MOF composite membrane capable of selectively adsorbing rhenium. The MOF composite membrane capable of selectively adsorbing rhenium provided by the invention can selectively adsorb rhenium in waste acid treatment, so that selective separation of rhenium is realized, and meanwhile, the membrane has excellent acid tolerance.

The invention discloses an indium-based metal-organic framework material based on a pyridine hexacarboxylic acid ligand as well as a preparation method and application of the indium-based metal-organic framework material, the chemical formula is {[NH2Me2] 2 [In4 (mu2-O) (H6L) 2 (H2O) 2]. 3DMF. 10H2O} n, and H6L is an organic ligand 4, 4 ', 4' '-(pyridine-2, 4, 6-triyl) triisophthalic acid. The material has excellent thermal stability and chemical stability, and due to the frame charge characteristic and the excellent pore structure of the material, the metal organic frame material shows efficient dye selective adsorption and separation performance, can selectively adsorb cationic dye methylene blue MB and repel anionic dye methyl orange MO at the same time. In conclusion, a new design thought is developed for the novel indium-based metal organic framework material based on the pyridine hexacarboxylic acid ligand, and meanwhile, a new candidate is provided for developing a high-efficiency dye wastewater purification material.

The invention discloses an electroplating sludge iron resource recovery method based on acid leaching-resin selective adsorption, and relates to the field of dangerous solid waste resource treatment.The electroplating sludge iron resource recovery method comprises the following steps that S1, collected electroplating sludge and sodium salt are evenly mixed, roasted, cooled, washed and filtered, and washing liquid and filter residues are obtained; s2, adding water into the filter residues obtained in the S1, uniformly mixing, then mixing with an acid solution, carrying out an acid leaching reaction, and carrying out solid-liquid separation to obtain an acid leaching solution; according to the electroplating sludge iron resource recycling method based on acid leaching-resin selective adsorption, selected specific chelating resin is large in iron ion adsorption capacity and excellent in selectivity under the low pH, competitive interference of coexisting ions such as Cu < 2 + > can be effectively overcome, and the iron recycling rate can reach 99% or above; the adsorption step is carried out under the strong acidic condition and is matched with the characteristics of the electroplating sludge pickle liquor, the pH does not need to be greatly adjusted, the process is simplified, and the cost is reduced.

The invention discloses high-dispersion polyhedral nano silver powder as well as a preparation method and application thereof, and belongs to the technical field of preparation of electronic materials and nano powder. The problems that an existing polyhedral nano silver powder preparation method is difficult in morphology control and poor in dispersity, uses toxic reagents and the like are solved. According to the method, the growth process of the nano-silver crystal faces in a triethylene glycol system is regulated and controlled by means of high adsorption capacity and coordination of high-valence metal ions, the high-valence metal ions are selectively adsorbed on different crystal faces of silver, the surface energy and the growth rate of each crystal face are changed, and therefore control over the polyhedral morphology of the nano-silver powder is achieved. Besides, due to the fact that different high-valence metal ions are different in radius, charge number and adsorption capacity, the different high-valence metal ions have different regulation and control effects on the silver crystal face, and then controllable preparation of the polyhedral nano silver powder is achieved by selecting the different high-valence metal ions.

The invention discloses a preparation method and application of a betaine-induced branch structure CoFe-based catalyst, and relates to a preparation method and application of a CoFe-based catalyst. The technical problem that an existing CoFe-based catalyst is poor in activity and stability is solved. The preparation method of the betaine-induced branched structure CoFe-based catalyst comprises the following steps: immersing clean foamed nickel into an isopropanol-water heterogeneous solution containing Co < 2 + > and Fe < 2 + > for in-situ growth, then introducing betaine to induce to form a branched structure, and anchoring an acidic group on the surface of a CoFe matrix to enhance the structural stability; the alkaline group faces an electrolyte interface under the action of an electric field, regulates interface charge distribution, selectively adsorbs part of Cl <-> and repels the other part of Cl <-> at the interface, so that chlorine evolution side reaction is inhibited. When the industrial-grade current density is 500 mA cm <-2 > during seawater hydrogen production, only 280 mV overpotential is needed, and stable operation can be carried out for more than 1000 h. The method can be used in the seawater hydrogen production field.

The invention discloses microcapsule self-regeneration-based long-acting formaldehyde-removing cement and a preparation method thereof, and belongs to the field of building materials and environmental functional materials. The material is composed of Portland cement clinker and a functional composite additive, wherein the additive comprises Zn < 2 + > modified zeolite, a manganese-based catalyst, a pH-responsive sustained-release microcapsule and alpha-semi-hydrated gypsum. According to the invention, through the cooperation of zeolite selective adsorption, non-photocatalytic oxidation of the manganese-based catalyst in an alkaline environment and pH-triggered microcapsule self-regeneration, an adsorption-catalysis-regeneration function closed loop is formed, efficient and lasting removal of formaldehyde under a dark condition is realized, and the mechanical properties of a cement matrix are not damaged. According to the preparation method, the functional components are pre-compounded and then co-ground with the cement clinker, the process is simple, and the preparation method is suitable for industrial production.

The present application belongs to the technical field of silica sol preparation, and particularly relates to a silica sol preparation method using ion exchange method. In the prior art, the silica sol growth time is shortened by optimizing the preparation and impurity removal process, and the silica sol seed mother liquor is prepared under ultrasonic assistance. The organic alkali catalyst maintains the silica sol growth pH and the metal ions in the complex solution, so that the impurities are reduced during the silica sol growth. After the introduction of dodecyltrimethoxysilane, hexadecyltrimethoxysilane and methyltrimethoxysilane as the hydrophobic group surface modification, the impurity metal ions are filtered through the complexing agent and the ammonium type resin. The three ethylene tetramine ethanol solution modifies the ammonium type resin, enhances the selective adsorption of the resin to the metal ions, and the maleic anhydride crosslinking agent and nano silicon dioxide modify the ammonium type resin, increase the service life of the ammonium type resin. The prepared silica sol has high purity, good mechanical properties and dispersibility, and excellent hydrophobic performance.

The invention relates to the technical field of air purification materials, and particularly discloses an amino acid grafted modified covalent organic framework composite material as well as a preparation method and application thereof. The composite material comprises a covalent organic framework matrix and amino acid grafted through covalent bonds, the covalent organic framework matrix has a porous crystal structure, and the amino acid is connected with the matrix through an amido bond or a carbon-nitrogen bond. The preparation method comprises the four main steps of covalent organic framework matrix synthesis, matrix activation, amino acid grafting and product purification. The composite material provided by the invention can be used for indoor air purification, formaldehyde removal of automotive trim and formaldehyde adsorption process in industrial waste gas treatment. The material has a high specific surface area and a rich porous structure, combines specific interaction of amino acid functional groups and formaldehyde molecules, and shows excellent formaldehyde adsorption capacity and selective adsorption performance. The preparation method disclosed by the invention is mild in process condition, and controllable adjustment of material performance is realized by accurately controlling grafting parameters.

The invention discloses a chloroethylene carbonate purification process in the technical field of synthesis of lithium battery additives. The process adopts a novel hierarchical pore asymmetric zirconium organic phosphonate frame material as an adsorbent. The method comprises the following steps: firstly, mixing, heating and stirring crude chloroethylene carbonate and absolute methanol, and standing at room temperature for pretreatment; performing selective adsorption on the pretreatment solution through an adsorption column filled with the adsorption material; carrying out toluene washing, citric acid ethanol solution treatment and supercritical carbon dioxide extraction on the saturated material to realize regeneration; and finally, rectifying the solution subjected to adsorption treatment under a reduced pressure condition to obtain a high-purity product. The adsorption material is prepared through multiple steps of reactions including synthesis and modification of an organic ligand, framework construction of a zirconium source and a phosphonic acid ligand, asymmetric functional modification of the surface of the material, and final thermal activation and hydrophobic stabilization treatment. The process is simple and efficient, the material can be reused, and the method is especially suitable for the field of lithium battery additive synthesis.

The application discloses a preparation method of a high-activity multi-level-pore boronic acid imprinting hydrogel microsphere adsorbent and application of the adsorbent to selective adsorption of a flavonoid compound naringin (NRG). The application enhances surface functionalization of COFs by dopamine modification, prepares thiol functionalized covalent organic framework microspheres, synthesizes thiol microspheres by using an emulsion interfacial polymerization method, prepares COFs boron affinity imprinting microsphere adsorbents based on boron affinity, and applies the adsorbents to selective adsorption of NRG in agricultural wastewater. The prepared adsorbent has a significant multi-layer adsorption effect, and the adsorption capacity is significantly improved by using boron affinity. The multi-level-pore structure of the COFs microspheres provides abundant sites for adsorption, and significantly improves the mass transfer rate. In addition, the prepared adsorbent has significant specificity in adsorption and separation of NRG, and provides a promising adsorption material for industrialized separation of NRG.

The invention relates to the technical field of gas separation, and discloses an impurity-interference-resistant low-concentration CO2 pressure swing adsorption purification process which comprises the following steps: S1, adsorption step: introducing raw material gas containing impurities and CO2 into a main adsorption tower filled with a composite adsorbent under adsorption pressure, so that CO2 is selectively adsorbed, and purified tail gas is obtained; s2, regenerating: regenerating the main adsorption tower, namely S2.1, equalizing and reducing pressure: discharging gas in the main adsorption tower, and recovering pressure energy; s2.2, vacuumizing: carrying out vacuum desorption on the main adsorption tower to obtain a CO2 product gas; the composite adsorbent with a gradient structure is adopted, a hydrophobic shell of the composite adsorbent effectively blocks water erosion, and acidic impurities such as SOx and NOx are preferentially and chemically fixed on an inner layer, so that high-selectivity adsorption of a core amino site to CO2 is protected, and the poisoning resistance and long-term stability under complex flue gas conditions are remarkably improved.