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1391 results about "Cationic exchange" patented technology

Cation exchange. n. A chemical process in which cations are exchanged equally between a solid, such as zeolite, and a solution, such as water. The process is often used to soften water.

A system and treatment method for treating high-phosphorus wastewater and resourcefully utilizing phosphorus elements

The present invention relates to a system and a treatment method for treating high-phosphorus wastewater and resourcefully utilizing phosphorus elements. The system includes a bipolar membrane electrodialysis device, a phosphorus precipitator, and a membrane treatment device. Inside the bipolar membrane electrodialysis device, there are successively arranged a cathode, a first bipolar membrane, a main cation exchange membrane, a main anion exchange membrane, a second bipolar membrane, and an anode. Between the first bipolar membrane and the main cation exchange membrane is an alkali chamber, between the main cation exchange membrane and the main anion exchange membrane is a wastewater chamber, between the main anion exchange membrane and the second bipolar membrane is an acid chamber, the outside of the first bipolar membrane is a cathode chamber, and the outside of the second bipolar membrane is an anode chamber; the high-phosphorus wastewater is input into the wastewater chamber, the acid chamber is provided with a phosphoric acid recovery pipe, and the alkali chamber and the wastewater chamber are respectively connected to the phosphorus precipitator through an alkali liquid pipe and a first water production pipe; the phosphorus precipitator is provided with a precipitant inlet for inputting a calcium precipitant or a magnesium precipitant, the concentrated water outlet of the membrane treatment device is connected to the wastewater chamber, and the produced water of the membrane treatment device is reused as reclaimed water.
Owner:INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI

Self-humidifying CO2 membrane electrode structure and preparation method thereof

The invention provides a self-humidifying CO2 membrane electrode structure and a preparation method thereof. The self-humidifying CO2 membrane electrode structure comprises an electrolyte isolation plate, the electrolyte isolation plate is provided with an anode side and a cathode side, the anode side is sequentially provided with a cation exchange membrane, an anode catalyst layer, a current collector and an anode electrode plate, and the cathode side is sequentially provided with an anion exchange membrane, a cathode catalyst layer and a cathode electrode plate; the anode electrode plate is provided with a first inlet, hydrogen enters the anode electrode plate from the first inlet and is subjected to a hydrogen oxidation reaction under the action of an anode catalyst to generate protons and electrons, and the protons are migrated to the electrolyte isolation plate through the cation exchange membrane; the cathode electrode plate is provided with a second inlet, CO2 gas enters the cathode electrode plate from the second inlet and is subjected to a reduction reaction under the action of a cathode catalyst to generate a reduction product and OH <->, and OH <-> is migrated to the electrolyte isolation plate through the anion exchange membrane to react with protons. The long-term operation stability of the membrane electrode structure is remarkably improved.
Owner:SUZHOU UNIV

Novel composite bipolar membrane for preparing low-carbon alcohol alkali metal salt and electrodialysis process thereof

The invention relates to a novel composite bipolar membrane for preparing low-carbon alcohol alkali metal salt and an electrodialysis process of the novel composite bipolar membrane, and belongs to the technical field of membrane separation and electrochemical synthesis. The composite bipolar membrane comprises a cation exchange layer, a middle catalyst layer and an anion exchange layer which are sequentially laminated and compounded, the process comprises the following steps: introducing a salt solution containing alkali metal ions into an anode chamber of a bipolar membrane electrodialysis system, and introducing a low-carbon alcohol solution into a cathode chamber; applying a direct-current electric field to the two sides of the composite bipolar membrane, so that the low-carbon alcohol is dissociated at the membrane interface to generate alkoxy ions and hydrogen ions; the alkoxy ions migrate to an anode chamber to be combined with the alkali metal ions to generate low-carbon alcohol alkali metal salt; the membrane material is high in adaptability, the membrane structure is good in stability, technological parameters are mature, and the system integration degree is high.
Owner:INNER MONGOLIA XISHANGXI NEW MATERIAL TECH CO LTD +1

Calcium humic acid modified charcoal composite material as well as preparation method and application thereof

The invention provides a calcium humic acid modified biochar composite material as well as a preparation method and application thereof. The preparation method specifically comprises the following steps: preparing calcium modified biochar powder from biochar powder and a calcium source; mixing humic acid with the calcium modified charcoal powder, filtering and drying to obtain a calcium humic acid modified charcoal composite material; wherein the mass ratio of the humic acid to the calcium modified charcoal powder is 1: (2-20). When the calcium humic acid modified biochar composite material is used as a soil remediation agent for soil remediation, the pH value, the organic matter content and the cation exchange capacity of soil can be improved, the soil hardening degree is relieved, heavy metal lead and cadmium and ions thereof can be immobilized in the modes of ion exchange, electrostatic adsorption, surface complexing, deposition and the like, and the soil remediation efficiency is improved. The soil heavy metal content is further reduced.
Owner:HUANGHUAI UNIV +2

Methanol fuel ship hybrid power system coupled with carbon dioxide in-situ capture and utilization

The invention discloses a methanol fuel ship hybrid power system coupled with carbon dioxide in-situ capture and utilization. The methanol fuel ship hybrid power system comprises an SOFC / GT system, a supercritical carbon dioxide cycle power generation system, an organic Rankine cycle power generation system and a carbon dioxide in-situ utilization system. Exhaust gas of a gas turbine in the SOFC / GT system serves as a heat source to be sequentially used for heating cycle working media of the supercritical carbon dioxide cycle power generation system and the organic Rankine cycle power generation system and then enters the carbon dioxide in-situ utilization system. Exhaust gas received by the carbon dioxide in-situ utilization system is condensed through a condenser to separate H2O and then enters a cathode of the porous solid electrolytic cell, the cathode comprises a KOH solution and an anion exchange membrane, an anode comprises water and a cation exchange membrane, an electrode catalyst is bismuth oxide, anode exhaust gas enters the SOFC / GT system, and formic acid discharged by a middle interlayer enters a formic acid storage tank. According to the invention, the carbon dioxide in the waste gas is captured in situ on the methanol fuel ship to generate a high-added-value product, and the energy of a power system is comprehensively utilized.
Owner:JIANGSU UNIV OF SCI & TECH

Method and system for treating biogas slurry through electrochemical membrane ammonia stripping

The invention relates to the technical field of agricultural waste treatment and utilization, and discloses a method and system for treating biogas slurry through electrochemical membrane ammonia stripping. The method comprises the following steps: (1) adding a flocculating agent into the biogas slurry for flocculation treatment; (2) inputting the flocculated biogas liquid supernatant into a cathode chamber of an electrolytic bath, separating the cathode chamber from an anode chamber of the electrolytic bath by a cation exchange membrane, carrying out water electrolysis reaction in the electrolytic bath, and carrying out aeration stripping on the biogas liquid supernatant in the cathode chamber while carrying out water electrolysis reaction, the obtained ammonia gas is blown off from the biogas slurry supernatant under the disturbance of aeration. According to the method disclosed by the invention, the electrolytic bath is modified, and a specific electrochemical method is combined, so that relatively high ammonia nitrogen removal and recovery efficiency can be achieved under the conditions of no addition of an alkaline agent and no heating, and the problems of high cost and low ammonia removal efficiency of a biogas liquid ammonia recovery process are solved.
Owner:HUAZHONG AGRI UNIV

Polystyrene cation exchange resin as well as preparation method and application thereof

The invention relates to polystyrene cation exchange resin as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a dispersing agent in a solvent to obtain a dispersed phase for suspension polymerization reaction, uniformly mixing a reaction monomer, a cross-linking agent, a pore-foaming agent and an initiator, and carrying out suspension polymerization reaction under segmented stirring and segmented temperature change to prepare copolymer microspheres; and putting the dried microspheres into a reaction kettle, swelling, carrying out sulfonation reaction through a variable temperature program on the basis to obtain sulfonated microspheres, and carrying out alkali exchange reaction on the sulfonated microspheres to obtain the final product cation exchange resin. Compared with the prior art, the cation exchange resin preparation method provided by the invention has the characteristics of simple and feasible process, easiness in large-scale production, low cost, high specific surface area, high adsorption capacity and high separation efficiency, and is especially suitable for separating and purifying substances containing amino groups or aminoglycosidic bonds.
Owner:EAST CHINA UNIV OF SCI & TECH +1

Preparation method and application of multi-site silver-nickel hydroxide / copper nanowire catalyst

The invention relates to a preparation method of a multi-site silver (Ag) and nickel hydroxide (Ni (OH) 2) modified copper (Cu) nanowire catalyst (Ag-Ni (OH) 2) / Cu NW) and application of the multi-site silver (Ag) and nickel hydroxide (Ni (OH) 2) modified copper (Cu) nanowire catalyst. A cation exchange and electrodeposition method is adopted to prepare an electrocatalytic nitrate reduction reaction NO3-RR series catalyst with three sites of Ag, Ni (OH) 2 and Cu. Based on the synergistic effect of three sites, Ag in the catalyst promotes conversion from nitrate NO3 <-> to nitrite NO2 <->, Ni (OH) 2 promotes dissociation of water H2O to generate free hydrogen * H, Cu atoms near Ni (OH) 2 accelerate conversion from NO2 <-> to ammonia NH3, and the efficient series catalytic process is achieved. Under the condition of-0.1 V vs. Reversible hydrogen electrode RHE in a 1M potassium hydroxide solution containing 50 mM of potassium nitrate, the NH3 yield of 4.01 mgh <-1 > cm <-2 > and the NH3 Faraday efficiency of 97.3% are obtained, under the condition of 0V vs. RHE, the excellent energy efficiency of 46.5% is achieved, the excellent catalytic activity is kept in a NO3 <-> solution with the wide concentration, and the good sewage treatment capacity is achieved. The invention provides a new design thought for tandem catalysis, and has a wide application prospect in the field of NO3-RR.
Owner:JILIN UNIVERSITY

Method for simultaneously preparing lithium hydroxide and sulfuric acid

The invention relates to a method for simultaneously preparing lithium hydroxide and sulfuric acid. The invention provides a method for simultaneously preparing lithium hydroxide and sulfuric acid, which comprises the following steps: preparing a bipolar membrane electrodialysis device which comprises a first bipolar membrane, an anion exchange membrane, a cation exchange membrane and a second bipolar membrane, and forming an acid chamber between the first bipolar membrane and the anion exchange membrane, a salt chamber is formed between the anion exchange membrane and the cation exchange membrane, and an alkali chamber is formed between the cation exchange membrane and the second bipolar membrane; a lithium sulfate aqueous solution is added into a salt chamber of the bipolar membrane electrodialysis device, a sulfuric acid aqueous solution is added into an acid chamber, and a lithium hydroxide aqueous solution is added into an alkali chamber; and discharging the desalted solution formed in the salt chamber of the bipolar membrane electrodialysis device, discharging the sulfuric acid aqueous solution formed in the acid chamber, and discharging the lithium hydroxide aqueous solution formed in the alkali chamber.
Owner:POSCO HLDG INC +1

Purification treatment device

The utility model provides a purification treatment device, and relates to the technical field of process water treatment. The purification treatment device comprises: a first cation exchange resin tank for adsorbing and extracting at least a part of oligomers and cations in water; a water inlet of a heating medium channel of the first heat exchanger is connected with a water outlet of the first cation exchange resin tank, and the first heat exchanger is used for cooling the entered extraction water; a water inlet of a heating medium channel of the second heat exchanger is connected with a water outlet of a heating medium channel of the first heat exchanger so as to cool the extraction water, so that the temperature of the extraction water flowing out of the heating medium channel of the second heat exchanger is lower than or equal to a first threshold value; the anion exchange resin tank is connected with a water outlet of the heating medium channel of the second heat exchanger; the second cation exchange resin tank is connected with the water outlet of the anion exchange resin tank; and the water outlet of the second cation exchange resin tank is connected with the water inlet of the refrigerant channel of the first heat exchanger. According to the invention, impurities in the extracted water can be removed.
Owner:HANGZHOU YICHEN CHEM FIBER CO LTD

Synthesis method and application of sludge biochar Schwertmannite composite material capable of synchronously mineralizing cadmium and arsenic

The invention belongs to the technical field of heavy metal treatment, and particularly relates to a synthesis method and application of a sludge biochar Schwertmannite composite material capable of synchronously mineralizing cadmium and arsenic. Municipal or industrial sludge is used as a raw material, sludge biochar rich in Ca, Fe and alkaline functional groups is prepared through pyrolysis, then the sludge biochar is deeply compounded with Schwertmannite through a high-energy ball milling technology, a core-shell-like nested structure is formed through induction, and a large number of reaction sites are exposed. Under the condition that As / Cd coexists, the surface of the composite material can be induced to generate stable minerals, a synchronous precipitation mechanism is formed, and As and Cd have an adsorption synergistic enhancement effect. The process is wide in raw material source, clean and efficient in preparation process and free of high-temperature hydrothermal or organic reagents, has cation exchangeability, alkali energy storage and carbon immobilization value, provides a new theory and material support for long-term environment immobilization of multi-metal pollutants, and has large-scale application potential.
Owner:SUN YAT SEN UNIV

Electrochemical carbon dioxide capture and recovery in a solid electrolyte reactor system

A device for carbon capture from a CO2 containing source includes a cathode compartment including a cathode electrode, an anode compartment including an anode electrode, a middle compartment which includes an ion conducting layer, a cation exchange membrane, and an anion exchange membrane. The middle compartment is separated from the cathode and anode by the anion and cation exchange membranes. A method for carbon capture from a CO2 containing source includes providing the device, supplying the CO2 containing source to the cathode, reacting the CO2 from the source with an electrochemically generated species from the cathode to form a carbon species or directly reducing the CO2 at the cathode to form the carbon species, driving the carbon species to the middle compartment, and reacting, in the middle compartment, the carbon species with an oxidation product from the anode to form an exit product comprising CO2.
Owner:WILLIAM MARCH RICE UNIVERSITY

Multifunctional microbial fertilizer based on Chinese herbal medicine carrier and application thereof

The invention belongs to the technical field of biological bacterial fertilizers, and discloses a Chinese herbal medicine carrier-based multifunctional microbial bacterial fertilizer, which comprises a microbial strain group, a Chinese herbal medicine active component group, an organic matter and nutrition carrier, mineral elements and auxiliary components, and a functional synergist. Through the synergistic interaction of Chinese herbal medicine active ingredients and functional microbial flora, breeding of harmful bacteria in soil is inhibited, synthesis of acetylcholin esterase of nematodes is interfered, a continuous cropping disease occurrence chain is blocked from the source, and meanwhile, organic acid and flavonoid substances slowly released by a Chinese herbal medicine carrier are utilized to activate resistance gene expression of a plant system, so that the disease resistance of the nematodes is improved. The tolerance threshold of crops to high temperature, cold damage and diseases is enhanced; in the composite carrier, humic acid and diatomite are crosslinked through hydrogen bonds to form a stable granular structure, the cation exchange capacity and porosity of soil are effectively improved, the strong hydration capacity of polyglutamic acid is combined to lock nutrients and moisture, and development of meristem of a root system and proliferation of capillary roots are promoted.
Owner:临沂科技职业学院

Cation exchange membrane and manufacturing method therefor

Provided is a cation exchange membrane in which when a hydroxide aqueous solution showing strong alkalinity is produced by using an electrodialyzer, significant swelling in the cation exchange membrane in contact with the hydroxide aqueous solution is suppressed, destruction of a cation exchange resin due to polyvalent cations contained as impurities in a raw material inorganic salt is suppressed, and the capacity of the cation exchange membrane is hardly lowered. This cation exchange membrane is characterized by having an electric resistance of 2.0-5.0 (Ω∙cm2), as measured at 25ºC in 0.5 mol / L of a NaCl aqueous solution, and a dimensional change rate of at most 1.2%.
Owner:ASTOM CORPORATION

Extended release amphetamine tablets

An oral amphetamine extended release solid dose is described. The compositions contain a combination of an uncoated amphetamine-cation exchange resin complex, a barrier coated amphetamine-cation exchange resin complex-matrix, and an uncomplexed amphetamine, wherein one or more of these components contains blends of different forms of amphetamines. Either the modified release coated and / or the uncoated amphetamine-cation exchange resin complex may have two forms of amphetamine in a complex with a single cation exchange resin. Following administration of a single dose of the composition, a therapeutically effective amount of amphetamine is reached by about one hour and the composition provides at least a thirteen hour effect post-dose.
Owner:TRIS PHARMA INC

High-current-density zinc-bromine flow battery, negative electrode electrolyte and preparation method of high-current-density zinc-bromine flow battery

The invention belongs to the field of batteries, and provides a high-current-density long-circulation zinc-bromine flow battery negative electrode electrolyte and battery preparation. The battery comprises a positive electrode, a negative electrode, a diaphragm, positive and negative electrolyte, a current collector and an end plate, the diaphragm is a cation exchange membrane; and the negative electrode electrolyte comprises a metal salt, a supporting electrolyte, an organic carboxylate complexing agent and deionized water. The organic carboxylate complexing agent disclosed by the invention can be adsorbed on a porous electrode, and by increasing zinc deposition sites, inhibiting two-dimensional interface diffusion and promoting zinc mass transfer, zinc dendrites are relieved, and the zinc-bromine flow battery with high current density and long circulation stability is realized.
Owner:SOUTH CHINA UNIV OF TECH

A heterogeneous tubular cation exchange membrane, its preparation method and application

This invention provides a heterogeneous tubular cation exchange membrane, its preparation method, and its application. The preparation method of the heterogeneous tubular cation exchange membrane includes: (1) mixing cation resin powder, binder, softener, stabilizer, and antioxidant to obtain agglomerated ion exchange material; (2) extruding the obtained agglomerated ion exchange material to obtain the heterogeneous tubular cation exchange membrane. The preparation method has simple overall operation steps and can prepare a heterogeneous tubular cation exchange membrane with a smaller inner diameter of the mold tube while ensuring that the tube wall remains unchanged. This is beneficial to improving the packing density of the membrane module and has important research significance.
Owner:NANJING GREEN MFG IND INNOVATION RES INST +1

Modified ion exchange resin, preparation method and application of modified ion exchange resin in treatment of shale gas wastewater

The invention relates to the technical field of wastewater treatment, in particular to modified cation exchange resin, a preparation method and application of the modified cation exchange resin in shale gas wastewater treatment. The modified cation exchange resin is characterized in that the modified cation exchange resin is obtained by compounding cation exchange resin and sodium alginate and then grafting N, N-dimethylacrylamide, and the surface of the modified cation exchange resin has an amido group; wherein the cation exchange resin is weakly acidic cation exchange resin taking carboxylic acid groups as exchange groups. The modified cation exchange resin provided by the invention simultaneously contains carboxyl, hydroxyl and amido, can simultaneously adsorb organic pollutants and metal ions through various mechanisms (such as ion exchange, hydrogen-bond interaction, chelation, hydrophobic interaction and the like), and remarkably improves the treatment capacity and efficiency of the resin on complex wastewater. In addition, the dispersibility of the modified resin in water is improved due to the hydrophilicity of the modified resin, so that the modified resin shows higher stability and efficiency in the treatment process.
Owner:SICHUAN KUNZHI HAOYU TECH CO LTD +1

Cation exchange membrane chromatography medium as well as preparation method and application thereof

The invention provides a cation exchange membrane chromatography medium and a preparation method and application thereof, the cation exchange membrane chromatography medium comprises a homo-porous membrane, polydopamine is loaded on two side surfaces and in a pore structure of the homo-porous membrane, and a cation exchange functional ligand is grafted on the polydopamine; a homogeneous pore membrane is selected as a matrix membrane, polydopamine is loaded on the surface and in an internal pore structure of the homogeneous pore membrane, and then a cation exchange functional ligand is further grafted, so that the surface of a chromatography medium of the obtained cation exchange membrane has relatively strong negative charges, and biomolecules with positive charges can be effectively adsorbed, thereby being separated from biomolecules with negative charges; meanwhile, the membrane is relatively low in transmembrane pressure and relatively high in separation degree, also has the characteristics of high permeability and high selectivity, and is suitable for being applied to separation and purification of biological drug macromolecules.
Owner:INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES

A monovalent selective cation exchange membrane and its preparation method

The present invention relates to a monovalent selective cation exchange membrane and a preparation method thereof, belonging to the technical field of cation exchange membranes. The specific steps are: weighing DA and ammonium persulfate and adding them to a buffer solution to obtain a PDA coating solution, pouring the PDA coating solution on the surface of a base membrane for soaking, depositing a PDA coating on the surface of the activated base membrane to obtain membrane I; dissolving zirconium tetrachloride and 2-aminoterephthalic acid in DMF, then solvent-thermally synthesizing an amino-functionalized MOF (UIO-66-NH2) under acidic conditions, weighing PEI and MOF (UIO-66-NH2) powders and adding them to a buffer solution, then pouring them on the surface of membrane I, depositing a PEI-MOF composite coating to obtain membrane II, and air-drying membrane II to obtain a monovalent selective cation exchange membrane. It can be seen that the present invention can prepare a low-cost, highly selective, and stable-performance monovalent selective cation exchange membrane by modifying the cation exchange membrane through a simple and easy-to-operate method.
Owner:TIANJIN CHENGJIAN UNIV

Therapeutic compositions for viral-associated disease states and methods of making and using same

A method comprising obtaining a bodily fluid from a subject; contacting the bodily fluid with an adsorbent material comprising a synthetic carbon particle (SCP) to produce a first filtrate having a level of disease mediators (y); contacting the first filtrate with an adsorbent material comprising the SCP and an anion exchange resin where the ratio of SCP to anion exchange resin is in a range from about 0.1:100 to 100:0.1 to produce a second filtrate; contacting the second filtrate with an adsorbent material comprising the SCP and a cation exchange resin where the ratio of SCP to cation exchange resin is in a range from about 0.1:100 to 100:0.1 to produce a third filtrate.
Owner:IMMUTRIX THERAPEUTICS INC

Preparation method of monovalent / divalent selective cation exchange membrane based on crown ether

The invention relates to the field of ion separation, and particularly discloses a crown ether-based monovalent / divalent selective cation exchange membrane preparation method, which comprises: carrying out super acid catalysis copolymerization on dibenzo crown ether and a pre-sulfonated monomer to obtain a precursor, and carrying out graft modification on a main chain by using a side chain on the basis to obtain the crown ether-based monovalent / divalent selective cation exchange membrane. The separation performance of monovalent / divalent cations is optimized, and the side chain type cation exchange membrane is prepared. The ion exchange membrane provided by the invention can be used for screening various monovalent / divalent ion systems, the number of # imgabs 0 can reach 370, the number of # imgabs 1 can reach 207, and the number of # imgabs 2 can reach 11125.
Owner:UNIV OF SCI & TECH OF CHINA

Bipolar membrane electrodialysis apparatus and method

An electrochemical apparatus comprising: an anode; a bipolar membrane; an anion exchange membrane; a cation exchange membrane; and a cathode; wherein: the anode at least partially defines a first fluid flow path; the anode and / or the first fluid flow path is in contact with the anion exchange membrane of the bipolar membrane; a second fluid flow path is defined between the cation exchange membrane of the bipolar membrane and the anion exchange membrane; a third fluid flow path is defined between the anion exchange membrane and the cation exchange membrane; the cathode at least partially defines a fourth fluid flow path; and the cation exchange membrane is in contact with the cathode and / or the fourth fluid flow path.
Owner:BRINEWORKS BV

Method for preparing battery-grade nickel sulfate through collaborative purification of crude nickel sulfate and crude nickel carbonate

The invention discloses a method for preparing battery-grade nickel sulfate through collaborative purification of crude nickel sulfate and crude nickel carbonate. According to the method, crude nickel sulfate is dissolved firstly, then crude nickel carbonate is utilized for batch synergistic neutralization, and the alkalinity of the nickel carbonate is effectively utilized to reduce extra acid and alkali consumption. And then through multi-stage fine purification, including Fe oxidation and preliminary precipitation, Cr (VI) reduction and high-pH precipitation, main impurities such as iron, chromium, aluminum and the like are efficiently removed. And after the mother liquor is adsorbed by activated carbon and trace impurities are removed by strong-acid cation exchange resin, vacuum evaporation and concentration are carried out, and seed crystals are introduced for cooling crystallization, so that pure NiSO4. 6H2O crystals are obtained. The whole technological process pays attention to resource recycling, washing water recycling and nickel recycling of nickel-containing filter residues, waste gas and waste liquid are treated, and clean production is achieved. The nickel sulfate product prepared by the method is high in purity, meets the battery grade standard, and has good economic benefits and environmental benefits.
Owner:JIANGXI GUANGDE ENVIRONMENTAL PROTECTION TECH CO LTD

Resin evaluation device for precision treatment of condensed water in nuclear power plant

The invention provides a resin evaluation device for fine treatment of condensed water in a nuclear power plant, which is applied to the technical field of detection, and is characterized in that a front cation bed is provided with a mixed water input end, a first pretreated water output end and a first resin conveying port, and the mixed water input end is connected with the mixed water output end of a water distribution system through a first pipeline; cation exchange resin is filled in the front cation bed; the high-speed mixed bed is provided with a pretreated water input end, a second pretreated water output end and a second resin conveying port, and is filled with anion and cation mixed ion exchange resin; the regeneration system comprises a first regeneration unit and a second regeneration unit; a first monitoring unit and a second monitoring unit are respectively arranged at the first pipeline and the second pretreated water output end; switch valves are respectively arranged at the first pipeline, the second pipeline, the second pretreated water output end, the first resin conveying pipeline and the second resin conveying pipeline; the control unit is electrically connected with the first monitoring unit, the second monitoring unit and the switch valve.
Owner:GUODIAN NUCLEAR SAFETY TECH (CHONGQING) CO LTD

Treatment process of by-product sodium hypophosphite in phosphorane preparation process

PendingCN120757084AHypophosphorous acidCalcium hydroxidePhospholan
The invention provides a treatment process of a byproduct sodium hypophosphite in a phosphorane preparation process, and aims to efficiently remove impurities and prepare a high-purity hypophosphorous acid product. The process comprises the following steps: carrying out small-volume sampling on reaction mother liquor, introducing carbon dioxide gas, and drawing an acidification curve of pH and conductivity; according to the plateau phase of an acidification curve, the CO2 flow rate and the pH value are controlled, step-by-step selective precipitation of impurities such as PO4 < 3->, HPO4 < 2->, Fe < 3 + >, AsO4 < 3-> and S < 2-> is achieved, and loss of a target component H2PO4 < 2-> is avoided; calcium hydroxide turbid liquid is introduced at a proper time to supplement Ca < 2 + > and promote efficient removal of phosphorus, arsenic and sulfur impurities; and subsequently removing excessive Na < + > and Ca < 2 + > through cation exchange, and concentrating to obtain a hypophosphorous acid product with the purity of more than or equal to 99.5%. The method is accurate in process control, thorough in impurity removal and good in repeatability and industrial adaptability, and the resource utilization efficiency of by-products and the added value of products are remarkably improved.
Owner:CANGZHOU BOHAI NEW DISTRICT SHENGTAI CHEM CO LTD

Temperature control enhanced biological electrodialysis ammonia recovery system and recovery method

The invention provides a temperature control enhanced biological electrodialysis ammonia recovery system and a recovery method. The recovery system comprises a microbial electrodialysis cell and an ammonia recovery unit, the microbial electrodialysis pool comprises a pool body, a cation exchange membrane, an anode chamber, a cathode chamber, an anode, a cathode, a power supply and a temperature control piece; the anode chamber is provided with an anolyte inlet and an anolyte outlet, and the cathode chamber is provided with a catholyte inlet and a catholyte outlet; the anode chamber is filled with ammonia-nitrogen wastewater to be treated, and the cathode chamber is filled with catholyte; the temperature control piece can control the temperature in the anode chamber and the cathode chamber for heating; the ammonia recovery unit comprises an absorption tank and a membrane assembly; the absorption tank is filled with acidic absorption liquid; membrane filaments of the membrane assembly are soaked in the acid absorption liquid, the membrane assembly is provided with an inlet end and an outlet end which are communicated with the membrane filaments, the inlet end is connected with the catholyte outlet, and the outlet end is connected with the catholyte inlet. According to the ammonia recovery system disclosed by the invention, the removal and recovery efficiency of ammonia nitrogen can be remarkably improved through a reasonable regulation and control mode, and the ammonia nitrogen recovery efficiency is optimized.
Owner:TIANJIN UNIV

Chlorella pyrenoidosa peptide with effect of preventing alcoholic liver injury

The invention aims to provide a chlorella pyrenoidosa peptide with an effect of preventing alcoholic liver injury, which is prepared by the following steps: crushing chlorella pyrenoidosa, mixing with water, freezing and thawing, and performing ultrasonic treatment to prepare homogenate; alkaline protease is added for enzymolysis, and then flavourzyme is added for enzymolysis; and after the enzymolysis product is adsorbed by activated carbon, the supernate is adsorbed by using an SP Sephadex C25 cation exchange medium. The amino acid sequence of the chlorella pyrenoidosa peptide is PSEQ ID NO: 1-5. The chlorella pyrenoidosa peptide provided by the invention is obtained by enzymolysis, adsorption and cation exchange chromatography technologies, and is verified by a HepG2 cell model to obviously relieve alcoholic liver injury. The raw materials are natural and safe, the process is accurate and efficient, and industrialization potential is achieved. Meanwhile, the peptide is suitable for development of functional food, health care products and medicines, and a low-toxicity and sustainable liver protection solution is provided.
Owner:OCEAN UNIV OF CHINA