1091 results about "Cationic exchange" patented technology

The invention provides a self-humidifying CO2 membrane electrode structure and a preparation method thereof. The self-humidifying CO2 membrane electrode structure comprises an electrolyte isolation plate, the electrolyte isolation plate is provided with an anode side and a cathode side, the anode side is sequentially provided with a cation exchange membrane, an anode catalyst layer, a current collector and an anode electrode plate, and the cathode side is sequentially provided with an anion exchange membrane, a cathode catalyst layer and a cathode electrode plate; the anode electrode plate is provided with a first inlet, hydrogen enters the anode electrode plate from the first inlet and is subjected to a hydrogen oxidation reaction under the action of an anode catalyst to generate protons and electrons, and the protons are migrated to the electrolyte isolation plate through the cation exchange membrane; the cathode electrode plate is provided with a second inlet, CO2 gas enters the cathode electrode plate from the second inlet and is subjected to a reduction reaction under the action of a cathode catalyst to generate a reduction product and OH <->, and OH <-> is migrated to the electrolyte isolation plate through the anion exchange membrane to react with protons. The long-term operation stability of the membrane electrode structure is remarkably improved.

The invention relates to a novel composite bipolar membrane for preparing low-carbon alcohol alkali metal salt and an electrodialysis process of the novel composite bipolar membrane, and belongs to the technical field of membrane separation and electrochemical synthesis. The composite bipolar membrane comprises a cation exchange layer, a middle catalyst layer and an anion exchange layer which are sequentially laminated and compounded, the process comprises the following steps: introducing a salt solution containing alkali metal ions into an anode chamber of a bipolar membrane electrodialysis system, and introducing a low-carbon alcohol solution into a cathode chamber; applying a direct-current electric field to the two sides of the composite bipolar membrane, so that the low-carbon alcohol is dissociated at the membrane interface to generate alkoxy ions and hydrogen ions; the alkoxy ions migrate to an anode chamber to be combined with the alkali metal ions to generate low-carbon alcohol alkali metal salt; the membrane material is high in adaptability, the membrane structure is good in stability, technological parameters are mature, and the system integration degree is high.

The invention relates to polystyrene cation exchange resin as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a dispersing agent in a solvent to obtain a dispersed phase for suspension polymerization reaction, uniformly mixing a reaction monomer, a cross-linking agent, a pore-foaming agent and an initiator, and carrying out suspension polymerization reaction under segmented stirring and segmented temperature change to prepare copolymer microspheres; and putting the dried microspheres into a reaction kettle, swelling, carrying out sulfonation reaction through a variable temperature program on the basis to obtain sulfonated microspheres, and carrying out alkali exchange reaction on the sulfonated microspheres to obtain the final product cation exchange resin. Compared with the prior art, the cation exchange resin preparation method provided by the invention has the characteristics of simple and feasible process, easiness in large-scale production, low cost, high specific surface area, high adsorption capacity and high separation efficiency, and is especially suitable for separating and purifying substances containing amino groups or aminoglycosidic bonds.

The invention relates to a method for simultaneously preparing lithium hydroxide and sulfuric acid. The invention provides a method for simultaneously preparing lithium hydroxide and sulfuric acid, which comprises the following steps: preparing a bipolar membrane electrodialysis device which comprises a first bipolar membrane, an anion exchange membrane, a cation exchange membrane and a second bipolar membrane, and forming an acid chamber between the first bipolar membrane and the anion exchange membrane, a salt chamber is formed between the anion exchange membrane and the cation exchange membrane, and an alkali chamber is formed between the cation exchange membrane and the second bipolar membrane; a lithium sulfate aqueous solution is added into a salt chamber of the bipolar membrane electrodialysis device, a sulfuric acid aqueous solution is added into an acid chamber, and a lithium hydroxide aqueous solution is added into an alkali chamber; and discharging the desalted solution formed in the salt chamber of the bipolar membrane electrodialysis device, discharging the sulfuric acid aqueous solution formed in the acid chamber, and discharging the lithium hydroxide aqueous solution formed in the alkali chamber.

The utility model provides a purification treatment device, and relates to the technical field of process water treatment. The purification treatment device comprises: a first cation exchange resin tank for adsorbing and extracting at least a part of oligomers and cations in water; a water inlet of a heating medium channel of the first heat exchanger is connected with a water outlet of the first cation exchange resin tank, and the first heat exchanger is used for cooling the entered extraction water; a water inlet of a heating medium channel of the second heat exchanger is connected with a water outlet of a heating medium channel of the first heat exchanger so as to cool the extraction water, so that the temperature of the extraction water flowing out of the heating medium channel of the second heat exchanger is lower than or equal to a first threshold value; the anion exchange resin tank is connected with a water outlet of the heating medium channel of the second heat exchanger; the second cation exchange resin tank is connected with the water outlet of the anion exchange resin tank; and the water outlet of the second cation exchange resin tank is connected with the water inlet of the refrigerant channel of the first heat exchanger. According to the invention, impurities in the extracted water can be removed.

The invention belongs to the technical field of heavy metal treatment, and particularly relates to a synthesis method and application of a sludge biochar Schwertmannite composite material capable of synchronously mineralizing cadmium and arsenic. Municipal or industrial sludge is used as a raw material, sludge biochar rich in Ca, Fe and alkaline functional groups is prepared through pyrolysis, then the sludge biochar is deeply compounded with Schwertmannite through a high-energy ball milling technology, a core-shell-like nested structure is formed through induction, and a large number of reaction sites are exposed. Under the condition that As / Cd coexists, the surface of the composite material can be induced to generate stable minerals, a synchronous precipitation mechanism is formed, and As and Cd have an adsorption synergistic enhancement effect. The process is wide in raw material source, clean and efficient in preparation process and free of high-temperature hydrothermal or organic reagents, has cation exchangeability, alkali energy storage and carbon immobilization value, provides a new theory and material support for long-term environment immobilization of multi-metal pollutants, and has large-scale application potential.

The invention belongs to the technical field of biological bacterial fertilizers, and discloses a Chinese herbal medicine carrier-based multifunctional microbial bacterial fertilizer, which comprises a microbial strain group, a Chinese herbal medicine active component group, an organic matter and nutrition carrier, mineral elements and auxiliary components, and a functional synergist. Through the synergistic interaction of Chinese herbal medicine active ingredients and functional microbial flora, breeding of harmful bacteria in soil is inhibited, synthesis of acetylcholin esterase of nematodes is interfered, a continuous cropping disease occurrence chain is blocked from the source, and meanwhile, organic acid and flavonoid substances slowly released by a Chinese herbal medicine carrier are utilized to activate resistance gene expression of a plant system, so that the disease resistance of the nematodes is improved. The tolerance threshold of crops to high temperature, cold damage and diseases is enhanced; in the composite carrier, humic acid and diatomite are crosslinked through hydrogen bonds to form a stable granular structure, the cation exchange capacity and porosity of soil are effectively improved, the strong hydration capacity of polyglutamic acid is combined to lock nutrients and moisture, and development of meristem of a root system and proliferation of capillary roots are promoted.

Provided is a cation exchange membrane in which when a hydroxide aqueous solution showing strong alkalinity is produced by using an electrodialyzer, significant swelling in the cation exchange membrane in contact with the hydroxide aqueous solution is suppressed, destruction of a cation exchange resin due to polyvalent cations contained as impurities in a raw material inorganic salt is suppressed, and the capacity of the cation exchange membrane is hardly lowered.　This cation exchange membrane is characterized by having an electric resistance of 2.0-5.0 (Ω∙cm2), as measured at 25ºC in 0.5 mol / L of a NaCl aqueous solution, and a dimensional change rate of at most 1.2%.

An oral amphetamine extended release solid dose is described. The compositions contain a combination of an uncoated amphetamine-cation exchange resin complex, a barrier coated amphetamine-cation exchange resin complex-matrix, and an uncomplexed amphetamine, wherein one or more of these components contains blends of different forms of amphetamines. Either the modified release coated and / or the uncoated amphetamine-cation exchange resin complex may have two forms of amphetamine in a complex with a single cation exchange resin. Following administration of a single dose of the composition, a therapeutically effective amount of amphetamine is reached by about one hour and the composition provides at least a thirteen hour effect post-dose.

This invention provides a heterogeneous tubular cation exchange membrane, its preparation method, and its application. The preparation method of the heterogeneous tubular cation exchange membrane includes: (1) mixing cation resin powder, binder, softener, stabilizer, and antioxidant to obtain agglomerated ion exchange material; (2) extruding the obtained agglomerated ion exchange material to obtain the heterogeneous tubular cation exchange membrane. The preparation method has simple overall operation steps and can prepare a heterogeneous tubular cation exchange membrane with a smaller inner diameter of the mold tube while ensuring that the tube wall remains unchanged. This is beneficial to improving the packing density of the membrane module and has important research significance.

The invention provides a cation exchange membrane chromatography medium and a preparation method and application thereof, the cation exchange membrane chromatography medium comprises a homo-porous membrane, polydopamine is loaded on two side surfaces and in a pore structure of the homo-porous membrane, and a cation exchange functional ligand is grafted on the polydopamine; a homogeneous pore membrane is selected as a matrix membrane, polydopamine is loaded on the surface and in an internal pore structure of the homogeneous pore membrane, and then a cation exchange functional ligand is further grafted, so that the surface of a chromatography medium of the obtained cation exchange membrane has relatively strong negative charges, and biomolecules with positive charges can be effectively adsorbed, thereby being separated from biomolecules with negative charges; meanwhile, the membrane is relatively low in transmembrane pressure and relatively high in separation degree, also has the characteristics of high permeability and high selectivity, and is suitable for being applied to separation and purification of biological drug macromolecules.

The present invention relates to a monovalent selective cation exchange membrane and a preparation method thereof, belonging to the technical field of cation exchange membranes. The specific steps are: weighing DA and ammonium persulfate and adding them to a buffer solution to obtain a PDA coating solution, pouring the PDA coating solution on the surface of a base membrane for soaking, depositing a PDA coating on the surface of the activated base membrane to obtain membrane I; dissolving zirconium tetrachloride and 2-aminoterephthalic acid in DMF, then solvent-thermally synthesizing an amino-functionalized MOF (UIO-66-NH2) under acidic conditions, weighing PEI and MOF (UIO-66-NH2) powders and adding them to a buffer solution, then pouring them on the surface of membrane I, depositing a PEI-MOF composite coating to obtain membrane II, and air-drying membrane II to obtain a monovalent selective cation exchange membrane. It can be seen that the present invention can prepare a low-cost, highly selective, and stable-performance monovalent selective cation exchange membrane by modifying the cation exchange membrane through a simple and easy-to-operate method.

A bipolar membrane in which a cation-exchange membrane and an anion-exchange membrane are joined to each other, wherein a leakage ratio of gluconic acid at 60° C. is not more than 1.0%, and the cation-exchange membrane is supported by a polyolefin reinforcing member and, further, contains a polyvinyl chloride.

A method comprising obtaining a bodily fluid from a subject; contacting the bodily fluid with an adsorbent material comprising a synthetic carbon particle (SCP) to produce a first filtrate having a level of disease mediators (y); contacting the first filtrate with an adsorbent material comprising the SCP and an anion exchange resin where the ratio of SCP to anion exchange resin is in a range from about 0.1:100 to 100:0.1 to produce a second filtrate; contacting the second filtrate with an adsorbent material comprising the SCP and a cation exchange resin where the ratio of SCP to cation exchange resin is in a range from about 0.1:100 to 100:0.1 to produce a third filtrate.

An electrochemical apparatus comprising: an anode; a bipolar membrane; an anion exchange membrane; a cation exchange membrane; and a cathode; wherein: the anode at least partially defines a first fluid flow path; the anode and / or the first fluid flow path is in contact with the anion exchange membrane of the bipolar membrane; a second fluid flow path is defined between the cation exchange membrane of the bipolar membrane and the anion exchange membrane; a third fluid flow path is defined between the anion exchange membrane and the cation exchange membrane; the cathode at least partially defines a fourth fluid flow path; and the cation exchange membrane is in contact with the cathode and / or the fourth fluid flow path.

The invention discloses a method for preparing battery-grade nickel sulfate through collaborative purification of crude nickel sulfate and crude nickel carbonate. According to the method, crude nickel sulfate is dissolved firstly, then crude nickel carbonate is utilized for batch synergistic neutralization, and the alkalinity of the nickel carbonate is effectively utilized to reduce extra acid and alkali consumption. And then through multi-stage fine purification, including Fe oxidation and preliminary precipitation, Cr (VI) reduction and high-pH precipitation, main impurities such as iron, chromium, aluminum and the like are efficiently removed. And after the mother liquor is adsorbed by activated carbon and trace impurities are removed by strong-acid cation exchange resin, vacuum evaporation and concentration are carried out, and seed crystals are introduced for cooling crystallization, so that pure NiSO4. 6H2O crystals are obtained. The whole technological process pays attention to resource recycling, washing water recycling and nickel recycling of nickel-containing filter residues, waste gas and waste liquid are treated, and clean production is achieved. The nickel sulfate product prepared by the method is high in purity, meets the battery grade standard, and has good economic benefits and environmental benefits.

The invention provides a resin evaluation device for fine treatment of condensed water in a nuclear power plant, which is applied to the technical field of detection, and is characterized in that a front cation bed is provided with a mixed water input end, a first pretreated water output end and a first resin conveying port, and the mixed water input end is connected with the mixed water output end of a water distribution system through a first pipeline; cation exchange resin is filled in the front cation bed; the high-speed mixed bed is provided with a pretreated water input end, a second pretreated water output end and a second resin conveying port, and is filled with anion and cation mixed ion exchange resin; the regeneration system comprises a first regeneration unit and a second regeneration unit; a first monitoring unit and a second monitoring unit are respectively arranged at the first pipeline and the second pretreated water output end; switch valves are respectively arranged at the first pipeline, the second pipeline, the second pretreated water output end, the first resin conveying pipeline and the second resin conveying pipeline; the control unit is electrically connected with the first monitoring unit, the second monitoring unit and the switch valve.

The invention provides a treatment process of a byproduct sodium hypophosphite in a phosphorane preparation process, and aims to efficiently remove impurities and prepare a high-purity hypophosphorous acid product. The process comprises the following steps: carrying out small-volume sampling on reaction mother liquor, introducing carbon dioxide gas, and drawing an acidification curve of pH and conductivity; according to the plateau phase of an acidification curve, the CO2 flow rate and the pH value are controlled, step-by-step selective precipitation of impurities such as PO4 < 3->, HPO4 < 2->, Fe < 3 + >, AsO4 < 3-> and S < 2-> is achieved, and loss of a target component H2PO4 < 2-> is avoided; calcium hydroxide turbid liquid is introduced at a proper time to supplement Ca < 2 + > and promote efficient removal of phosphorus, arsenic and sulfur impurities; and subsequently removing excessive Na < + > and Ca < 2 + > through cation exchange, and concentrating to obtain a hypophosphorous acid product with the purity of more than or equal to 99.5%. The method is accurate in process control, thorough in impurity removal and good in repeatability and industrial adaptability, and the resource utilization efficiency of by-products and the added value of products are remarkably improved.

The invention provides a temperature control enhanced biological electrodialysis ammonia recovery system and a recovery method. The recovery system comprises a microbial electrodialysis cell and an ammonia recovery unit, the microbial electrodialysis pool comprises a pool body, a cation exchange membrane, an anode chamber, a cathode chamber, an anode, a cathode, a power supply and a temperature control piece; the anode chamber is provided with an anolyte inlet and an anolyte outlet, and the cathode chamber is provided with a catholyte inlet and a catholyte outlet; the anode chamber is filled with ammonia-nitrogen wastewater to be treated, and the cathode chamber is filled with catholyte; the temperature control piece can control the temperature in the anode chamber and the cathode chamber for heating; the ammonia recovery unit comprises an absorption tank and a membrane assembly; the absorption tank is filled with acidic absorption liquid; membrane filaments of the membrane assembly are soaked in the acid absorption liquid, the membrane assembly is provided with an inlet end and an outlet end which are communicated with the membrane filaments, the inlet end is connected with the catholyte outlet, and the outlet end is connected with the catholyte inlet. According to the ammonia recovery system disclosed by the invention, the removal and recovery efficiency of ammonia nitrogen can be remarkably improved through a reasonable regulation and control mode, and the ammonia nitrogen recovery efficiency is optimized.

The invention belongs to the technical field of ion exchange membranes, and relates to a bipolar membrane and a preparation method thereof.The bipolar membrane comprises a cation exchange membrane, an anion exchange membrane and a middle layer; the cation exchange membrane is sulfonated polysulfone; the anion exchange membrane is aminated chloromethyl polysulfone; and the middle layer is prepared by reacting an organic amine compound with vinyl and chloromethyl polysulfone. The substrates of the three layers of polymers of the bipolar membrane are all made of polysulfone materials, the swelling characteristics of the materials are consistent, the affinity among the three layers is appropriate due to the fact that the three layers are made of the same material, the affinity among the layers of the bipolar membrane is easy to be tight, meanwhile, the stability of the middle catalyst layer is enhanced through a cross-linking method, and the stability of the middle catalyst layer is improved. The loss of the catalytic effect is prevented; the technical problem that the middle layer is prone to loss or blistering is solved.

A direct electrolysis technology for a natural mineral wet mineralization CO2 capture stock solution belongs to the field of carbon capture and resource utilization, and is characterized in that CO2 is captured through natural mineral wet mineralization to generate a bicarbonate solution, an electrolytic bath is constructed by using a bismuth-based catalyst and a cation exchange membrane to directly electrolyze to generate formate, and the formate is directly electrolyzed to generate the CO2 capture stock solution. Formate and regenerated trapping liquid are separated through a bipolar membrane electrodialysis technology, slag can be converted into a silicon-based building material, and integration of emission reduction, value addition and circulation is achieved. Compared with a traditional amine trapping technology, the method has the advantages that the energy consumption is reduced by 40%-50%, the trapping liquid raw material cost is reduced by 60%-70%, the problems of solvent volatilization and equipment corrosion are avoided, and the method is suitable for distributed carbon trapping and resource conversion in high-emission industries such as steel and chemical engineering.

The invention belongs to the technical field of membrane separation, and particularly relates to a monovalent selective cation exchange membrane and a preparation method thereof, the preparation method comprises the following steps: (1) mixing a first exchange monomer, a first cross-linking agent, a first solvent and a first initiator to obtain a first prepolymer solution; (2) mixing a second exchange monomer, a second cross-linking agent, a second solvent and a second initiator to obtain a second prepolymer solution; (3) coating the first prepolymer solution on a first substrate film to obtain a first composition; (4) coating a second substrate film with the second prepolymer solution to obtain a second composition; and (5) oppositely laminating the coating surfaces of the first composition and the second composition, and stripping the first substrate membrane and the second substrate membrane after initiation polymerization is completed, so as to obtain the monovalent selective cation exchange membrane.

A preparation method of an ionic rare earth leaching agent includes the following steps: (1) domestication microorganisms with rare earth activated mineral powder culture medium to obtain a microbial suspension; (2) amplifying and culturing the microbial suspension and additives to obtain the amplified culture medium; and (3) mixing the modified sesbania gum with the amplified culture medium to obtain the ionic rare earth leaching agent. The activated mineral powder is the active metal-containing mineral powder in nature, which has excellent cation exchange function after activation, and the activated mineral powder and ionic rare earth mineral powder are used as the medium components to domesticate microorganisms, so that microorganisms can survive in the above-mentioned ionic solution and improve the leaching rate of synergistic leaching ionic rare earth.

The invention provides a method for recovering nitrogen and phosphorus in wastewater through self-driven bipolar membrane electrodialysis. A system used in the method takes a magnesium negative electrode as a positive electrode and an air electrode as a positive electrode, and a self-driven primary battery is formed through wire connection; and ion exchange membranes with specific sequences are sequentially arranged between the two electrodes to form eight chambers, namely an anode chamber, a nitrogen and phosphorus recovery chamber, a wastewater chamber, a metal ion chamber, an ammonia water chamber, a hydrochloric acid chamber, a buffer chamber and a cathode chamber. During operation, an external power supply is not needed, and ion migration is driven by a self-generated electric field: after Mg < 2 + > and PO4 < 3-> are enriched in the nitrogen and phosphorus recovery chamber and NH4 < + > and Ca < 2 + > migrate to the metal ion chamber, NH4 < + > enters the ammonia water chamber through the monovalent cation exchange membrane, and Ca < 2 + > is separated out and reacts with OH <-> generated by the bipolar membrane to generate Ca (OH) 2 precipitate, so that membrane blockage is effectively prevented, and finally, NH4 < + >, Mg < 2 + > and PO4 < 3-> react to generate high-purity struvite. Zero energy consumption of nitrogen and phosphorus recovery of the wastewater is achieved, no additional chemicals exist, anti-blocking operation is achieved, and both environmental benefits and resource benefits are achieved.

The present application relates to a kind of methods for separating actinium from irradiated thorium target, belong to medical radioisotope manufacturing technical field, solve the problem that thorium element and lanthanide element impurity content in final actinium product in prior art is higher.The present application discloses a kind of methods for separating actinium from irradiated thorium target, first, irradiated thorium target is dissolved, then using cation exchange resin column, UTEVA or TK200 resin extraction column, DGA resin extraction column, LN resin extraction column four-stage series separation purification process, obtain final actinium product.Actinium is efficiently and selectively recovered, and the thorium element and lanthanide element impurity content in final actinium product is significantly reduced.

The invention discloses a soft clay electrochemical reinforcing device and method. The device comprises a power source, an anode, a cathode and a middle grouting pipe. A cation exchange membrane is arranged in the area, close to the cathode, of the to-be-reinforced soil body, only allows cations to migrate from the interior of the soil body to the cathode, and physically prevents anions generated by the cathode electrolytic reaction from reversely diffusing to the soil body; and the cation exchange membrane wraps the outer surface of the cathode or is arranged in the soil body around the cathode as an independent interlayer to form an ion filtering interface completely surrounding the cathode. According to the method, a selectively permeable cation exchange membrane is arranged at the interface of a cathode and a soil body, and a step-by-step grouting process of first anode grouting and then middle grouting pipe grouting is combined, so that the displacement of unit energy consumption is remarkably improved under the same voltage, the settlement amount of the soil body in a cathode area is increased by nearly 4 times, and the construction efficiency is improved. The engineering problem that an anode is hard and a cathode is soft in traditional electroosmosis is solved.

The invention relates to the technical field of water treatment equipment, and discloses a low-salt-consumption intelligent-regeneration water softener and a regenerant dosage accurate control method, the low-salt-consumption intelligent-regeneration water softener comprises: a softening unit, which comprises a tank body (made of food-grade glass fiber reinforced plastic or stainless steel and having a volume of 5-200L), and ion exchange resin (with a type of strongly acidic cation exchange resin, a type of cation exchange resin, a type of cation exchange resin, and a type of cation exchange resin) filled in the tank body; the filling volume accounts for 60%-80% of the effective volume of the tank body), and the multi-way intelligent control valve is installed at the water inlet and outlet end of the tank body. By calculating the residual exchange capacity of the resin in real time (the error is less than or equal to 5%) and dynamically adjusting the feeding amount of the regenerant (accurately matching the actual demand), the fixed excessive feeding (for example, 30-50% of more salt is added) of traditional equipment is avoided, the salt consumption is reduced by 40-70% compared with that of a traditional water softener (for example, 1.5 kg of salt is used for regeneration each time in the prior art, and only 0.45-0.9 kg of salt is needed in the invention); regeneration is triggered on the basis of the actual residual capacity of resin, and the problem of too early regeneration or too late regeneration caused by fluctuation of water consumption of traditional equipment is solved.

The utility model discloses an anion and cation double-membrane type electrodeionization device. The device internally comprises a cathode chamber, a resin chamber and an anode chamber; the cathode chamber and the resin chamber are isolated by a cation exchange membrane, the anode chamber and the resin chamber are isolated by an anion exchange membrane, and the distance between the two membranes is 10-100cm. According to the utility model, the electric regeneration efficiency of the invalid resin and the quality of subsequent produced water can be obviously improved, electrolyte solution is not consumed, the environmental protection problem is avoided, an electrode water circulating pump can be omitted, and the system and operation management are simplified.

The application discloses a microbial electrochemical system device and method for realizing wastewater treatment, CO2 fixation and in-situ synthesis of microbial protein synchronously, which comprises an anode chamber, a cathode chamber, a protein production chamber, a power supply, a mixed gas tank and a peristaltic pump; the anode chamber, the cathode chamber and the protein production chamber are sequentially arranged from left to right; a cation exchange membrane is arranged between the anode chamber and the cathode chamber; a cation exchange membrane is also arranged between the cathode chamber and the protein production chamber; an anode is arranged in the anode chamber and connected with the positive pole of the power supply through a wire, and a resistor is arranged on the wire connecting the anode and the positive pole of the power supply. The microbial electrochemical system and the protein production system are coupled to form an ammonia-nitrogen recovery-in-situ protein synthesis microbial electrochemical system, the system can convert active nitrogen into high-value protein products in-situ, the system can synchronously treat wastewater, recover ammonia-nitrogen and fix carbon dioxide, and has excellent environmental benefits.

The invention belongs to the technical field of earth and rockfill dam deep burying disease identification and positioning, and discloses an earth and rockfill dam leakage channel comprehensive detection method and system, and the method comprises the steps: determining the distribution of detection points detected by an electrical method, and collecting the apparent resistivity data and the apparent polarizability data of the detection points; inverting apparent resistivity and apparent polarizability data to obtain a resistivity profile and a polarizability profile, and obtaining a normalized polarizability profile based on the resistivity profile and the polarizability profile; performing stratum zoning on the to-be-detected area based on the section, determining the soil cation exchange capacity and the cementation index of the zoned stratum, and calculating the soil water content and the permeability of the measured section according to the normalized polarizability, the soil cation exchange capacity and the cementation index; and determining an earth and rockfill dam leakage channel according to a water content and permeability judgment mechanism. According to the method, the uncertainty of a single physical property threshold value method is overcome, and the accuracy and precision of the leakage hidden danger of the earth and rockfill dam are improved.