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1729 results about "Cationic exchange" patented technology

Cation exchange. n. A chemical process in which cations are exchanged equally between a solid, such as zeolite, and a solution, such as water. The process is often used to soften water.

A system and treatment method for treating high-phosphorus wastewater and resourcefully utilizing phosphorus elements

The present invention relates to a system and a treatment method for treating high-phosphorus wastewater and resourcefully utilizing phosphorus elements. The system includes a bipolar membrane electrodialysis device, a phosphorus precipitator, and a membrane treatment device. Inside the bipolar membrane electrodialysis device, there are successively arranged a cathode, a first bipolar membrane, a main cation exchange membrane, a main anion exchange membrane, a second bipolar membrane, and an anode. Between the first bipolar membrane and the main cation exchange membrane is an alkali chamber, between the main cation exchange membrane and the main anion exchange membrane is a wastewater chamber, between the main anion exchange membrane and the second bipolar membrane is an acid chamber, the outside of the first bipolar membrane is a cathode chamber, and the outside of the second bipolar membrane is an anode chamber; the high-phosphorus wastewater is input into the wastewater chamber, the acid chamber is provided with a phosphoric acid recovery pipe, and the alkali chamber and the wastewater chamber are respectively connected to the phosphorus precipitator through an alkali liquid pipe and a first water production pipe; the phosphorus precipitator is provided with a precipitant inlet for inputting a calcium precipitant or a magnesium precipitant, the concentrated water outlet of the membrane treatment device is connected to the wastewater chamber, and the produced water of the membrane treatment device is reused as reclaimed water.
Owner:INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI

Bipolar membrane based on charged nanosheet catalyst layer, preparation method of bipolar membrane and application of bipolar membrane in seawater dissociation

The invention provides a preparation method of a bipolar membrane based on a charged nanosheet catalyst layer and application of the bipolar membrane in seawater dissociation, and the preparation method comprises the following steps: A) coating a smooth substrate with a positive (negative) ion exchange membrane liquid, and drying to obtain a positive (negative) ion exchange membrane layer; dissolving the modified charged nanosheet to obtain a modified charged nanosheet solution; b) ultrasonically spraying the modified charged nanosheet solution on a positive (negative) ion exchange membrane layer, and drying to obtain a bipolar membrane middle layer; and C) ultrasonically spraying anion (cation) exchange membrane liquid to the bipolar membrane middle layer, and drying to obtain the bipolar membrane. According to the invention, the idea of introducing confinement mass transfer into the bipolar membrane intermediate layer is adopted, the charged nanosheets are stacked in an ultrasonic spraying manner, the distance is regulated and controlled through the modified charged nanosheets to construct the bipolar membrane intermediate layer, and the bipolar membrane has sub-nano or nano-scale charged channels, low common ion leakage and excellent water dissociation performance.
Owner:UNIV OF SCI & TECH OF CHINA

Monovalent selective cation exchange membrane with crown ether encapsulated therein and preparation method of monovalent selective cation exchange membrane

The invention belongs to the field of cation exchange membranes, and discloses a monovalent selective cation exchange membrane with crown ether encapsulated in the membrane and a preparation method of the monovalent selective cation exchange membrane. Firstly, a sulfonated chloromethylated polymer is synthesized, a solvent is evaporated to form a membrane, and a chemical reaction of chloromethyl and amido contained in the membrane endows a growth site of a covalent organic framework. And then constructing a covalent organic framework in a membrane channel by an in-situ growth method, and packaging the crown ether nano material in the membrane. A regular porous channel of the covalent organic framework and a sulfonic acid group in the base membrane have a synergistic effect, so that good ion flux of monovalent ions is ensured. Meanwhile, the crown ether structure has a special recognition complexing effect on alkali metal ions and has different affinity to different metal ions, so that the monovalent cation selective separation is achieved, and the prepared monovalent selective cation exchange membrane is suitable for an electrodialysis process.
Owner:ZHEJIANG UNIV OF TECH

Electrochemical carbon dioxide reduction device without prefabricated anion exchange membrane and application of electrochemical carbon dioxide reduction device

The invention relates to an electrochemical carbon dioxide reduction device without a prefabricated anion exchange membrane and application of the electrochemical carbon dioxide reduction device, and belongs to the fields of electrochemistry, carbon dioxide utilization and renewable energy sources. The device comprises an anode for catalyzing an oxygen evolution reaction, a cathode formed by a gas diffusion electrode, an extraction chamber arranged between the anode and the cathode, a cation exchange membrane covering the surface of the anode, a diaphragm covering the surface of the cathode, and ion exchange resin filled in the extraction chamber and used as a solid electrolyte. The device is used for a carbon dioxide reduction reaction, and an extracting solution can be used in an extracting chamber to extract a liquid product solution of carbon dioxide reduction; the components of the liquid product solution only contain the components of the extracting solution and the components of the liquid product. Based on the invention, the use of expensive prefabricated anion exchange membranes with unstable acidic conditions can be avoided, a product with higher purity of a liquid product can be directly obtained, and an additional operation unit for separating the liquid product from metal cations can be omitted.
Owner:FUJIAN AGRI & FORESTRY UNIV

Ammonia-nitrogen wastewater treatment device capable of generating target ammonium salt and method thereof

The invention discloses an ammonia-nitrogen wastewater treatment device and method capable of generating target ammonium salt, the ammonia-nitrogen wastewater treatment device comprises a bipolar membrane electrodialysis device and a membrane contactor, the bipolar membrane electrodialysis device comprises at least one treatment unit and an anode chamber and a cathode chamber which are separated by the treatment unit; the treatment unit comprises a front bipolar membrane, a front cation exchange membrane, a middle bipolar membrane, an anion exchange membrane, a rear cation exchange membrane and a rear bipolar membrane which are sequentially arranged in the direction from the anode chamber to the cathode chamber, and a feeding chamber, an ammonia production chamber, an acid production chamber, a desalting chamber and an alkali production chamber are respectively formed in spaces generated between the corresponding membranes; the membrane contactor comprises a breathable hydrophobic membrane dividing an inner cavity of the membrane contactor into a first chamber and a second chamber, and the first chamber and the second chamber communicate with the ammonia production chamber and the acid production chamber through pipelines correspondingly. And the method has relatively high application and popularization values.
Owner:CHONGQING UNIV

Method and device for purifying actinide

The invention discloses an actinide purification method and device, and belongs to the technical field of medical radioactive isotope separation and purification. The method comprises the following steps: passing a thorium target solution containing actinide through a cation exchange column, and leaching with inorganic acid to obtain a first effluent containing Ac < 3 + >; enabling the first effluent containing the Ac < 3 + > to pass through a TK221 resin extraction column to obtain a second effluent containing the Ac < 3 + >; the second effluent containing Ac3 + passes through a TRU resin extraction column, and actinide is obtained. The TK221 resin also contains phosphine oxide and a small amount of long alkyl chain alcohol on the basis of diglycolamide, and shows better performance on purification of Ac < 3 + >. Meanwhile, the elution acidity in the TRU resin separation process is properly improved, and the outflow speed of Ac, La and Ce can be delayed, so that the effect of separating Ac from La and Ce is achieved, and the yield of 225Ac is improved while the concentration of metal impurities is reduced.
Owner:STATE POWER INVESTMENT NUCLIDES TONGCHUANG (CHONGQING) TECH CO LTD

A attapulgite / molecular sieve composite adsorbent and its preparation method and application

The present invention relates to a method for preparing a attapulgite / molecular sieve composite adsorbent, comprising the following steps: (1) using NaX molecular sieve powder as a raw material, adding purified attapulgite, grinding, adding an aluminum source for crystallization, filtering, washing to a pH of 7 to 8, and drying to obtain a attapulgite / molecular sieve composite adsorbent precursor; (2) exchanging the composite adsorbent precursor obtained in step (1) with metal cations, and then filtering, washing, drying, molding, and activating to obtain the composite adsorbent. The composite adsorbent has a simple preparation method, a large adsorption capacity, and good selectivity. It can effectively adsorb and separate liquid mixtures, and has broad application prospects in selectively adsorbing and separating p-xylene from C8 aromatic isomers. The present invention also relates to a attapulgite / molecular sieve composite adsorbent and its application in adsorbing and separating p-xylene in mixed xylene.
Owner:CHINA NAT PETROLEUM CORP +1

Self-humidifying CO2 membrane electrode structure and preparation method thereof

The invention provides a self-humidifying CO2 membrane electrode structure and a preparation method thereof. The self-humidifying CO2 membrane electrode structure comprises an electrolyte isolation plate, the electrolyte isolation plate is provided with an anode side and a cathode side, the anode side is sequentially provided with a cation exchange membrane, an anode catalyst layer, a current collector and an anode electrode plate, and the cathode side is sequentially provided with an anion exchange membrane, a cathode catalyst layer and a cathode electrode plate; the anode electrode plate is provided with a first inlet, hydrogen enters the anode electrode plate from the first inlet and is subjected to a hydrogen oxidation reaction under the action of an anode catalyst to generate protons and electrons, and the protons are migrated to the electrolyte isolation plate through the cation exchange membrane; the cathode electrode plate is provided with a second inlet, CO2 gas enters the cathode electrode plate from the second inlet and is subjected to a reduction reaction under the action of a cathode catalyst to generate a reduction product and OH <->, and OH <-> is migrated to the electrolyte isolation plate through the anion exchange membrane to react with protons. The long-term operation stability of the membrane electrode structure is remarkably improved.
Owner:SUZHOU UNIV

Bipolar membrane and preparation and use method thereof

The invention discloses a bipolar membrane and a preparation and use method thereof, the bipolar membrane comprises a cation exchange membrane, the cation exchange membrane comprises a base material and a cation exchange layer arranged on at least one surface of the base material, and sulfonic acid type ionic liquid is added in the cation exchange layer; the metal catalyst layer is arranged on one surface of the base material, so that the cation exchange layer and the metal catalyst layer are respectively arranged on two opposite surfaces of the base material; the anion exchange layer is arranged on the surface of the metal catalyst layer and comprises quaternized imidazole derivatives and quaternary ammonium type ionic liquid, and the quaternary ammonium type ionic liquid accounts for 25% or above of the weight of the imidazole derivatives. The method has the advantages of high acid and alkali production concentration, stable membrane structure, stable performance and the like, and is suitable for long-term and stable preparation of high-concentration acid and alkali.
Owner:WANHUA CHEM GRP CO LTD

Novel composite bipolar membrane for preparing low-carbon alcohol alkali metal salt and electrodialysis process thereof

The invention relates to a novel composite bipolar membrane for preparing low-carbon alcohol alkali metal salt and an electrodialysis process of the novel composite bipolar membrane, and belongs to the technical field of membrane separation and electrochemical synthesis. The composite bipolar membrane comprises a cation exchange layer, a middle catalyst layer and an anion exchange layer which are sequentially laminated and compounded, the process comprises the following steps: introducing a salt solution containing alkali metal ions into an anode chamber of a bipolar membrane electrodialysis system, and introducing a low-carbon alcohol solution into a cathode chamber; applying a direct-current electric field to the two sides of the composite bipolar membrane, so that the low-carbon alcohol is dissociated at the membrane interface to generate alkoxy ions and hydrogen ions; the alkoxy ions migrate to an anode chamber to be combined with the alkali metal ions to generate low-carbon alcohol alkali metal salt; the membrane material is high in adaptability, the membrane structure is good in stability, technological parameters are mature, and the system integration degree is high.
Owner:INNER MONGOLIA XISHANGXI NEW MATERIAL TECH CO LTD +1

Preparation method of ion exchange nanofiber membrane with high ion exchange capacity

The invention discloses a preparation method of an ion exchange nanofiber membrane with high ion exchange capacity, which comprises the following steps: grinding and sieving a certain amount of strongly acidic cation exchange resin, adding the cation exchange resin into a PVDF (Polyvinylidene Fluoride) solution with DMAc as a solvent, uniformly mixing and stirring, and obtaining a nanoscale out-phase PVDF cation exchange membrane by adopting an electrostatic spinning processing method. A large number of ion exchange resin particles are dispersed in the heterogeneous PVDF cation exchange membrane and on the surface of the heterogeneous PVDF cation exchange membrane, and when the resin particles are in an aqueous solution, sulfonic acid groups (HSO3 < 2->) in the resin can exchange with ions in water, namely, a replacement reaction is carried out, so that metal ions dissolved in the water are removed. The prepared ion exchange membrane can remove alkali metal and alkaline earth metal ions in an aqueous solution, so that the total content of the alkali metal and alkaline earth metal ions in the solution is lower than 300mg / L.
Owner:ZHEJIANG SCI-TECH UNIV +1

Calcium humic acid modified charcoal composite material as well as preparation method and application thereof

The invention provides a calcium humic acid modified biochar composite material as well as a preparation method and application thereof. The preparation method specifically comprises the following steps: preparing calcium modified biochar powder from biochar powder and a calcium source; mixing humic acid with the calcium modified charcoal powder, filtering and drying to obtain a calcium humic acid modified charcoal composite material; wherein the mass ratio of the humic acid to the calcium modified charcoal powder is 1: (2-20). When the calcium humic acid modified biochar composite material is used as a soil remediation agent for soil remediation, the pH value, the organic matter content and the cation exchange capacity of soil can be improved, the soil hardening degree is relieved, heavy metal lead and cadmium and ions thereof can be immobilized in the modes of ion exchange, electrostatic adsorption, surface complexing, deposition and the like, and the soil remediation efficiency is improved. The soil heavy metal content is further reduced.
Owner:HUANGHUAI UNIV +2

Methanol fuel ship hybrid power system coupled with carbon dioxide in-situ capture and utilization

The invention discloses a methanol fuel ship hybrid power system coupled with carbon dioxide in-situ capture and utilization. The methanol fuel ship hybrid power system comprises an SOFC / GT system, a supercritical carbon dioxide cycle power generation system, an organic Rankine cycle power generation system and a carbon dioxide in-situ utilization system. Exhaust gas of a gas turbine in the SOFC / GT system serves as a heat source to be sequentially used for heating cycle working media of the supercritical carbon dioxide cycle power generation system and the organic Rankine cycle power generation system and then enters the carbon dioxide in-situ utilization system. Exhaust gas received by the carbon dioxide in-situ utilization system is condensed through a condenser to separate H2O and then enters a cathode of the porous solid electrolytic cell, the cathode comprises a KOH solution and an anion exchange membrane, an anode comprises water and a cation exchange membrane, an electrode catalyst is bismuth oxide, anode exhaust gas enters the SOFC / GT system, and formic acid discharged by a middle interlayer enters a formic acid storage tank. According to the invention, the carbon dioxide in the waste gas is captured in situ on the methanol fuel ship to generate a high-added-value product, and the energy of a power system is comprehensively utilized.
Owner:JIANGSU UNIV OF SCI & TECH

Method and system for treating biogas slurry through electrochemical membrane ammonia stripping

The invention relates to the technical field of agricultural waste treatment and utilization, and discloses a method and system for treating biogas slurry through electrochemical membrane ammonia stripping. The method comprises the following steps: (1) adding a flocculating agent into the biogas slurry for flocculation treatment; (2) inputting the flocculated biogas liquid supernatant into a cathode chamber of an electrolytic bath, separating the cathode chamber from an anode chamber of the electrolytic bath by a cation exchange membrane, carrying out water electrolysis reaction in the electrolytic bath, and carrying out aeration stripping on the biogas liquid supernatant in the cathode chamber while carrying out water electrolysis reaction, the obtained ammonia gas is blown off from the biogas slurry supernatant under the disturbance of aeration. According to the method disclosed by the invention, the electrolytic bath is modified, and a specific electrochemical method is combined, so that relatively high ammonia nitrogen removal and recovery efficiency can be achieved under the conditions of no addition of an alkaline agent and no heating, and the problems of high cost and low ammonia removal efficiency of a biogas liquid ammonia recovery process are solved.
Owner:HUAZHONG AGRI UNIV

Polystyrene cation exchange resin as well as preparation method and application thereof

The invention relates to polystyrene cation exchange resin as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a dispersing agent in a solvent to obtain a dispersed phase for suspension polymerization reaction, uniformly mixing a reaction monomer, a cross-linking agent, a pore-foaming agent and an initiator, and carrying out suspension polymerization reaction under segmented stirring and segmented temperature change to prepare copolymer microspheres; and putting the dried microspheres into a reaction kettle, swelling, carrying out sulfonation reaction through a variable temperature program on the basis to obtain sulfonated microspheres, and carrying out alkali exchange reaction on the sulfonated microspheres to obtain the final product cation exchange resin. Compared with the prior art, the cation exchange resin preparation method provided by the invention has the characteristics of simple and feasible process, easiness in large-scale production, low cost, high specific surface area, high adsorption capacity and high separation efficiency, and is especially suitable for separating and purifying substances containing amino groups or aminoglycosidic bonds.
Owner:EAST CHINA UNIV OF SCI & TECH +1

Preparation method and application of multi-site silver-nickel hydroxide / copper nanowire catalyst

The invention relates to a preparation method of a multi-site silver (Ag) and nickel hydroxide (Ni (OH) 2) modified copper (Cu) nanowire catalyst (Ag-Ni (OH) 2) / Cu NW) and application of the multi-site silver (Ag) and nickel hydroxide (Ni (OH) 2) modified copper (Cu) nanowire catalyst. A cation exchange and electrodeposition method is adopted to prepare an electrocatalytic nitrate reduction reaction NO3-RR series catalyst with three sites of Ag, Ni (OH) 2 and Cu. Based on the synergistic effect of three sites, Ag in the catalyst promotes conversion from nitrate NO3 <-> to nitrite NO2 <->, Ni (OH) 2 promotes dissociation of water H2O to generate free hydrogen * H, Cu atoms near Ni (OH) 2 accelerate conversion from NO2 <-> to ammonia NH3, and the efficient series catalytic process is achieved. Under the condition of-0.1 V vs. Reversible hydrogen electrode RHE in a 1M potassium hydroxide solution containing 50 mM of potassium nitrate, the NH3 yield of 4.01 mgh <-1 > cm <-2 > and the NH3 Faraday efficiency of 97.3% are obtained, under the condition of 0V vs. RHE, the excellent energy efficiency of 46.5% is achieved, the excellent catalytic activity is kept in a NO3 <-> solution with the wide concentration, and the good sewage treatment capacity is achieved. The invention provides a new design thought for tandem catalysis, and has a wide application prospect in the field of NO3-RR.
Owner:JILIN UNIVERSITY

Strong cation exchange chromatographic filler as well as preparation method and application thereof

The invention relates to a strong cation exchange chromatographic filler as well as a preparation method and application thereof. The strong cation exchange chromatographic filler comprises sulfonated poly (glycidyl methacrylate)-divinyl benzene microspheres. The strong cation exchange chromatographic filler provided by the invention can simultaneously show excellent separation selectivity on rare earth elements, and also has long-term stability and excellent cycle performance, so that the economic cost is reduced, and the strong cation exchange chromatographic filler has relatively high economic benefits and is green and environment-friendly.
Owner:GANJIANG INNOVATION ACAD CHINESE ACAD OF SCI

Method for simultaneously preparing lithium hydroxide and sulfuric acid

The invention relates to a method for simultaneously preparing lithium hydroxide and sulfuric acid. The invention provides a method for simultaneously preparing lithium hydroxide and sulfuric acid, which comprises the following steps: preparing a bipolar membrane electrodialysis device which comprises a first bipolar membrane, an anion exchange membrane, a cation exchange membrane and a second bipolar membrane, and forming an acid chamber between the first bipolar membrane and the anion exchange membrane, a salt chamber is formed between the anion exchange membrane and the cation exchange membrane, and an alkali chamber is formed between the cation exchange membrane and the second bipolar membrane; a lithium sulfate aqueous solution is added into a salt chamber of the bipolar membrane electrodialysis device, a sulfuric acid aqueous solution is added into an acid chamber, and a lithium hydroxide aqueous solution is added into an alkali chamber; and discharging the desalted solution formed in the salt chamber of the bipolar membrane electrodialysis device, discharging the sulfuric acid aqueous solution formed in the acid chamber, and discharging the lithium hydroxide aqueous solution formed in the alkali chamber.
Owner:POSCO HLDG INC +1

Method and device for removing thermally stable salt through electrodialysis

The invention relates to a method for removing thermally stable salt by electrodialysis, which comprises the following steps: i) providing an electrochemical reaction membrane stack which comprises a cathode plate, an anode plate and at least one repeatable unit arranged between the two polar plates, an electric field exists between the cathode plate and the anode plate, each repeatable unit comprises a pure water channel, a desalination channel and an alkali liquor channel in the direction from the cathode plate to the anode plate, the pure water channel is limited by an anion exchange membrane and a cation exchange membrane, the desalination channel is limited by the cation exchange membrane and the anion exchange membrane, and the alkali liquor channel is limited by the anion exchange membrane and the anion exchange membrane; ii) introducing pure water into the pure water channel, introducing raw water into the desalination channel, introducing alkali liquor into the alkali liquor channel, and iii) withdrawing a product stream from the desalination channel; wherein the raw water contains an organic amine compound and a heat-stable salt. The method provided by the invention realizes removal of thermally stable salts by using an electrochemical reaction membrane stack.
Owner:HANGZHOU CRAFTSMAN RONGDAO ENVIRONMENTAL TECH CO LTD

Preparation method of high-purity molybdenum trioxide

The invention provides a preparation method of high-purity molybdenum trioxide, which belongs to the technical field of molybdenum trioxide production and comprises the following steps: S1, crushing, grinding and roasting molybdenum ore sand to obtain crude molybdenum oxide, adding the crude molybdenum oxide into a sodium hydroxide solution, heating, stirring and filtering to obtain a crude sodium molybdate solution; s2, adjusting the pH value of the crude sodium molybdate solution to 5.5-7.0, introducing the crude sodium molybdate solution into an exchange column of macroporous cation exchange resin, then adjusting the pH value of the solution to 7.0-8.5, and introducing the crude sodium molybdate solution into an exchange column filled with anion exchange resin to obtain a high-purity sodium molybdate solution; s3, excessive ammonia water is added into the high-purity sodium molybdate solution, ammonium molybdate is separated out, washing and drying are conducted, and high-purity ammonium molybdate is obtained; and S4, the high-purity ammonium molybdate is put into a rotary calcining furnace, rare earth oxide is sprayed on the inner wall of a furnace tube, and the high-purity molybdenum trioxide is prepared by adopting a calcining mode of firstly heating, then cooling and then heating. According to the invention, the purpose of producing high-purity molybdenum trioxide is realized.
Owner:SHAANXI HENGCHANG MOLYBDENUM CO LTD

Recombinant collagen with enhanced skin regeneration ability, preparation method and application thereof

The present invention discloses a recombinant collagen with enhanced skin regeneration ability, a preparation method thereof and an application thereof. The present invention provides a recombinant type III collagen based on the gene sequence of human type III collagen α1 chain, and the encoding nucleic acid molecule sequence thereof is shown in SEQ NO.1. The recombinant type III collagen is expressed by high-density fermentation of Pichia pastoris GS115 strain, combined with optimized cation exchange chromatography and anion exchange chromatography purification processes, to achieve efficient preparation with a protein purity of 99.2% and a yield of 13.8 g / L; the recombinant type III collagen is highly consistent with natural collagen, and can significantly promote skin regeneration, collagen fiber deposition and wound repair.
Owner:杭州美琉生物科技有限公司

Purification treatment device

The utility model provides a purification treatment device, and relates to the technical field of process water treatment. The purification treatment device comprises: a first cation exchange resin tank for adsorbing and extracting at least a part of oligomers and cations in water; a water inlet of a heating medium channel of the first heat exchanger is connected with a water outlet of the first cation exchange resin tank, and the first heat exchanger is used for cooling the entered extraction water; a water inlet of a heating medium channel of the second heat exchanger is connected with a water outlet of a heating medium channel of the first heat exchanger so as to cool the extraction water, so that the temperature of the extraction water flowing out of the heating medium channel of the second heat exchanger is lower than or equal to a first threshold value; the anion exchange resin tank is connected with a water outlet of the heating medium channel of the second heat exchanger; the second cation exchange resin tank is connected with the water outlet of the anion exchange resin tank; and the water outlet of the second cation exchange resin tank is connected with the water inlet of the refrigerant channel of the first heat exchanger. According to the invention, impurities in the extracted water can be removed.
Owner:HANGZHOU YICHEN CHEM FIBER CO LTD

Synthesis method and application of sludge biochar Schwertmannite composite material capable of synchronously mineralizing cadmium and arsenic

The invention belongs to the technical field of heavy metal treatment, and particularly relates to a synthesis method and application of a sludge biochar Schwertmannite composite material capable of synchronously mineralizing cadmium and arsenic. Municipal or industrial sludge is used as a raw material, sludge biochar rich in Ca, Fe and alkaline functional groups is prepared through pyrolysis, then the sludge biochar is deeply compounded with Schwertmannite through a high-energy ball milling technology, a core-shell-like nested structure is formed through induction, and a large number of reaction sites are exposed. Under the condition that As / Cd coexists, the surface of the composite material can be induced to generate stable minerals, a synchronous precipitation mechanism is formed, and As and Cd have an adsorption synergistic enhancement effect. The process is wide in raw material source, clean and efficient in preparation process and free of high-temperature hydrothermal or organic reagents, has cation exchangeability, alkali energy storage and carbon immobilization value, provides a new theory and material support for long-term environment immobilization of multi-metal pollutants, and has large-scale application potential.
Owner:SUN YAT SEN UNIV

Electrochemical carbon dioxide capture and recovery in a solid electrolyte reactor system

A device for carbon capture from a CO2 containing source includes a cathode compartment including a cathode electrode, an anode compartment including an anode electrode, a middle compartment which includes an ion conducting layer, a cation exchange membrane, and an anion exchange membrane. The middle compartment is separated from the cathode and anode by the anion and cation exchange membranes. A method for carbon capture from a CO2 containing source includes providing the device, supplying the CO2 containing source to the cathode, reacting the CO2 from the source with an electrochemically generated species from the cathode to form a carbon species or directly reducing the CO2 at the cathode to form the carbon species, driving the carbon species to the middle compartment, and reacting, in the middle compartment, the carbon species with an oxidation product from the anode to form an exit product comprising CO2.
Owner:WILLIAM MARCH RICE UNIVERSITY

Sunflower seed oil matrix standard sample containing 3-chloropropanol ester and preparation method thereof

The invention relates to the technical field of food detection, in particular to a sunflower seed oil matrix standard sample containing 3-chloropropanol ester and a preparation method of the sunflower seed oil matrix standard sample. Sodium chloride, water, zinc chloride and other substances are added into sunflower seed oil, sufficient heating and stirring are performed, water is removed through refrigeration and centrifugation, chloride ions are removed through anion exchange resin, zinc ions and the like are removed through cation exchange resin, and the stability of 3-MCPD is guaranteed by adding an antioxidant. The matrix standard sample prepared by the method disclosed by the invention has the advantages of good uniformity and high stability after being subjected to strict uniformity and stability test.
Owner:CHINESE ACAD OF INSPECTION & QUARANTINE

Multifunctional microbial fertilizer based on Chinese herbal medicine carrier and application thereof

The invention belongs to the technical field of biological bacterial fertilizers, and discloses a Chinese herbal medicine carrier-based multifunctional microbial bacterial fertilizer, which comprises a microbial strain group, a Chinese herbal medicine active component group, an organic matter and nutrition carrier, mineral elements and auxiliary components, and a functional synergist. Through the synergistic interaction of Chinese herbal medicine active ingredients and functional microbial flora, breeding of harmful bacteria in soil is inhibited, synthesis of acetylcholin esterase of nematodes is interfered, a continuous cropping disease occurrence chain is blocked from the source, and meanwhile, organic acid and flavonoid substances slowly released by a Chinese herbal medicine carrier are utilized to activate resistance gene expression of a plant system, so that the disease resistance of the nematodes is improved. The tolerance threshold of crops to high temperature, cold damage and diseases is enhanced; in the composite carrier, humic acid and diatomite are crosslinked through hydrogen bonds to form a stable granular structure, the cation exchange capacity and porosity of soil are effectively improved, the strong hydration capacity of polyglutamic acid is combined to lock nutrients and moisture, and development of meristem of a root system and proliferation of capillary roots are promoted.
Owner:临沂科技职业学院

Cation exchange membrane and manufacturing method therefor

Provided is a cation exchange membrane in which when a hydroxide aqueous solution showing strong alkalinity is produced by using an electrodialyzer, significant swelling in the cation exchange membrane in contact with the hydroxide aqueous solution is suppressed, destruction of a cation exchange resin due to polyvalent cations contained as impurities in a raw material inorganic salt is suppressed, and the capacity of the cation exchange membrane is hardly lowered. This cation exchange membrane is characterized by having an electric resistance of 2.0-5.0 (Ω∙cm2), as measured at 25ºC in 0.5 mol / L of a NaCl aqueous solution, and a dimensional change rate of at most 1.2%.
Owner:ASTOM CORPORATION

Extended release amphetamine tablets

An oral amphetamine extended release solid dose is described. The compositions contain a combination of an uncoated amphetamine-cation exchange resin complex, a barrier coated amphetamine-cation exchange resin complex-matrix, and an uncomplexed amphetamine, wherein one or more of these components contains blends of different forms of amphetamines. Either the modified release coated and / or the uncoated amphetamine-cation exchange resin complex may have two forms of amphetamine in a complex with a single cation exchange resin. Following administration of a single dose of the composition, a therapeutically effective amount of amphetamine is reached by about one hour and the composition provides at least a thirteen hour effect post-dose.
Owner:TRIS PHARMA INC

High-current-density zinc-bromine flow battery, negative electrode electrolyte and preparation method of high-current-density zinc-bromine flow battery

The invention belongs to the field of batteries, and provides a high-current-density long-circulation zinc-bromine flow battery negative electrode electrolyte and battery preparation. The battery comprises a positive electrode, a negative electrode, a diaphragm, positive and negative electrolyte, a current collector and an end plate, the diaphragm is a cation exchange membrane; and the negative electrode electrolyte comprises a metal salt, a supporting electrolyte, an organic carboxylate complexing agent and deionized water. The organic carboxylate complexing agent disclosed by the invention can be adsorbed on a porous electrode, and by increasing zinc deposition sites, inhibiting two-dimensional interface diffusion and promoting zinc mass transfer, zinc dendrites are relieved, and the zinc-bromine flow battery with high current density and long circulation stability is realized.
Owner:SOUTH CHINA UNIV OF TECH