1496 results about "Supercritical carbon dioxide" patented technology

The invention relates to the technical field of aircrafts, in particular to a built-in compressed air and carbon dioxide linkage drainage system and an aircraft. The drainage system comprises a drainage device, a water ballast tank, a first connecting pipeline and a control unit, a first storage cavity for storing liquid carbon dioxide is formed in the first power unit, a second storage cavity for storing high-pressure air is formed in the second power unit, and a pressure reduction cavity is formed in the pressure reduction unit; the first storage chamber and the second storage chamber are both selectively communicated with the pressure reduction chamber; the water ballast tank is provided with a third storage chamber selectively communicated with the pressure reduction chamber; the first connecting pipeline is connected with the second power unit and the pressure reduction unit, and a first on-off valve is arranged on the first connecting pipeline; the first power unit is suitable for converting liquid carbon dioxide into high-pressure supercritical carbon dioxide under the control of the control unit, and the high-pressure supercritical carbon dioxide enters the third storage chamber after being decompressed by the decompression chamber, so that the first connecting pipeline selectively communicates with the second storage chamber and the decompression chamber.

The invention relates to the technical field of underwater vehicles, in particular to a modular supercritical carbon dioxide phase change drainage device and an underwater vehicle. The modular supercritical carbon dioxide phase change drainage device comprises a plurality of power unit sets, a plurality of pressure reduction units and a flow guide assembly, each power unit set comprises a plurality of power units, each power unit is provided with a first storage cavity, and the first storage cavity is used for storing liquid carbon dioxide; the plurality of pressure reduction units are in one-to-one correspondence with the plurality of power unit groups, each pressure reduction unit is provided with a pressure reduction chamber, the pressure reduction chambers selectively communicate with the corresponding first storage chambers, and the pressure reduction chambers of the plurality of pressure reduction units communicate with one another; the flow guide assembly is provided with a first air inlet and a first air outlet, the first air inlet communicates with at least one of the multiple pressure reduction cavities, and the first air outlet communicates with the water ballast space. The modular supercritical carbon dioxide phase change drainage device is small in occupied space, safe, efficient and high in drainage capacity.

The invention discloses a control method and device for a supercritical carbon dioxide recompression cycle power generation system, and the method comprises the steps: predicting the load change of the supercritical carbon dioxide Brayton cycle power generation system according to the historical operation data and current operation state of the supercritical carbon dioxide Brayton cycle power generation system; predicting the surge risk of the compressor according to the load change of the supercritical carbon dioxide Brayton cycle power generation system; according to the load change of the supercritical carbon dioxide Brayton cycle power generation system, the split ratio is adjusted, so that the recompression Brayton cycle power generation system operates at the optimal efficiency; and the flow, pressure and temperature of a compressor working medium in the supercritical carbon dioxide Brayton cycle power generation system are adjusted according to the surge risk, so that the compressor works in a non-surge area. When the supercritical carbon dioxide Brayton cycle power generation system approaches the surge boundary, the system adjusts the opening degree of the bypass valve in advance for flow release, so that active closed-loop control of surge prediction-response-relief is achieved, a compressor is effectively prevented from entering an unstable area under sudden load change, start and stop or extreme disturbance, and the service life of the compressor is prolonged. And the safety stability and the operation continuity of the system are obviously improved.

The invention discloses a green processing technology of sea cucumber powder capable of realizing directional enrichment and improving polysaccharide release rate, and belongs to the field of food processing. The sea cucumber powder is prepared by the following steps: S1, pretreating sea cucumbers; s2, enrichment of nutrient substances of the sea cucumbers; s3, regulating and controlling the particle size of the sea cucumber powder; s4, performing'single 'supercritical treatment; s5, carrying out in-situ ultramicro physical crushing; and S6, performing'dual 'supercritical treatment. Through the design of the gas disperser and the additional arrangement of the second hole disc, the supercritical extraction instrument can perform effective supercritical carbon dioxide extraction on the ultramicro sea cucumber powder, the deodorization of the ultramicro sea cucumber powder is realized, and the eating quality of the ultramicro sea cucumber powder is improved. Moreover, by detecting and regulating the stacking density and the tap density, optimal processing parameters for the ultramicro sea cucumber powder are found, so that the prepared ultramicro sea cucumber powder is high in polysaccharide release rate, good in eating quality and easy for subsequent processing.

The invention relates to a preparation method of silica gel microspheres used as a catalyst carrier, which comprises the following steps of: adjusting the speed of converting acidified water glass into gel by means of controlling material temperature and material concentration, multiple times of acidification and the like, so that the acidified water glass is atomized to form liquid drops, and then the liquid drops are quickly converted into the gel; and carrying out aging, acid washing, water washing, supercritical carbon dioxide drying, roasting in an atmosphere furnace and the like to prepare the silica gel microspheres with high specific surface area and large pore volume. Compared with the prior art, the specific surface area of the obtained silica gel can reach 250-450 m < 2 > / g, the pore volume can reach 1.5-3.0 cm < 3 > / g, and the silica gel has good strength and fluidity.

The invention relates to the technical field of thermal hydraulic power, in particular to a rapid prediction method for flow heat transfer characteristics of supercritical carbon dioxide of a micro-channel heat exchanger, and the method comprises the steps: dividing a training set and a test set according to a preset working condition parameter space, and generating a full-order flow field database under multiple working conditions through numerical simulation; performing eigenorthogonal decomposition on the full-order flow field database, and extracting a key mode of a dominant flow heat transfer feature to construct a reduced-order solution space; training an optimized neural network model by using the training set, and establishing a mapping relationship between the working condition parameters and the reduced-order solution space; and reconstructing flow field and temperature field information based on the mapping relation, and calculating and outputting a flow heat transfer characteristic prediction result. The method aims at solving the technical problem that the heat transfer characteristic prediction calculation efficiency of the supercritical carbon dioxide heat transfer flow of the micro-channel heat exchanger is low.

The invention belongs to the technical field of monitoring equipment, and discloses a supercritical carbon dioxide contact angle direct monitoring system and method.A first needle valve is connected with the bottom of a high-temperature and high-pressure reaction kettle, the other side of the first needle valve is connected with a supercritical carbon dioxide storage device, and a heater is arranged on the periphery of the columnar high-temperature and high-pressure reaction kettle; a sight glass is arranged on the side face of the high-temperature and high-pressure reaction kettle, a light source is arranged on the left side of the high-temperature and high-pressure reaction kettle, the top of the high-temperature and high-pressure reaction kettle is connected with a second needle valve, the other side of the second needle valve is connected with a water injection pump, and a CCD camera is arranged on the right side of the high-temperature and high-pressure reaction kettle and connected with a computer. The computer is connected with the high-temperature and high-pressure reaction kettle through the temperature sensor and the pressure sensor. According to the invention, the change of the contact angle of the supercritical carbon dioxide can be accurately monitored and analyzed in real time, and an effective tool is provided for researching the wettability of the supercritical carbon dioxide and the effects of anisotropy, cohesiveness, adsorptivity and the like of the surface of a material.

The invention discloses a purification method for removing quartz inclusion, which comprises the following steps: calcining a quartz sand raw material at high temperature for a certain time, then taking out and quickly putting into cold water for cold quenching; dehydrating quartz sand, feeding into a microwave reactor, heating to a set temperature, and keeping for a period of time; after the reaction is finished, cleaning the quartz sand with ultrapure water; filling the quartz sand into a high-temperature and high-pressure reactor, introducing supercritical carbon dioxide and hydrogen fluoride mixed gas, and keeping the temperature and the pressure for a period of time; and after the reaction is finished, discharging gas to obtain the high-purity quartz. Through two-stage heat treatment, a channel between gas-liquid inclusions in quartz particles and the outside can be efficiently opened, and meanwhile, the supercritical method ensures that impurities in the inclusions can be effectively dissolved out; the treatment time is short, the required temperature is low, the acid consumption is less than 10%, and the method has the advantages of high efficiency and low cost.

The invention discloses supercritical fluid foaming polyimide wave-absorbing foam and a preparation method thereof.The thermoplastic polyimide is prepared by the steps that aromatic dianhydride, aromatic diamine and aliphatic diamine serve as comonomers, polyimide acid is generated through solution polymerization, and then high-temperature cyclization is conducted; wherein the mole number of the aliphatic diamine accounts for 10-50% of the total mole number of the diamine, and the free volume and glass transition temperature of a molecular chain are effectively regulated and controlled by introduction of the aliphatic diamine; the wave-absorbing foam is prepared by taking polyimide as a matrix, doping 1-20wt% of wave-absorbing filler, and foaming for 1-3 hours in a supercritical carbon dioxide or nitrogen environment at the temperature of 180-220 DEG C and the pressure of 9-25MPa, through molecular structure design, the adsorption capacity and impact resistance of polyimide to carbon dioxide are remarkably improved, and the prepared foam has the advantages of light weight, high porosity, uniform foam structure and excellent heat resistance, can realize effective electromagnetic wave absorption in an X wave band, and is suitable for the fields of aerospace stealth and electromagnetic compatibility protection.

The invention discloses a technology for manufacturing a thin film by recycling and calendering a polytetrafluoroethylene material, and belongs to the technical field of high polymer material recycling and processing, the technology for manufacturing the thin film by recycling and calendering the polytetrafluoroethylene material comprises the following steps: crushing waste products, and carrying out three-stage screening impurity removal and melt index detection; after being cleaned by supercritical carbon dioxide, the qualified material is mixed with industrial by-product filler, waste tire rubber powder and the like, low-temperature mixing is conducted through a double-screw extruder, and mixing parameters are automatically regulated and controlled through a tension sensor; performing calendaring forming by a five-roller calendaring unit, preheating the first two rollers, performing differential stretching by the middle three rollers, engraving a micro groove by the third roller, and controlling the thickness precision to be + / -3% by an online thickness gauge; the film is slit after being compounded according to requirements, and scrap edges are crushed and recycled. The method realizes efficient recovery of waste polytetrafluoroethylene, and has the advantages of thorough impurity removal, stable performance, environmental protection and energy saving.

The invention provides a supercritical carbon dioxide core displacement experiment device and method, and the device comprises a supercritical carbon dioxide preparation system, a displacement reaction system, a temperature and pressure control system, a recovery metering system, and a data acquisition monitoring system. Flexible preparation of supercritical carbon dioxide can be achieved, the oil displacement process in the oil reservoir stratum environment can be accurately reduced, the experimental device is high in modification flexibility, and data collection, transmission and monitoring are efficient and high in precision. A series of experiment requirements of supercritical carbon dioxide preparation, injection oil displacement, data processing and the like can be conveniently met, the device can be conveniently subjected to experiment modification through the arrangement of the pipeline, the valve and the sensor, various experiment purposes are achieved, the utilization efficiency of the experiment device is improved, experiment operation is efficient, the carbon dioxide oil displacement and sealing experiment effects can be explored, and the experimental device is suitable for popularization and application. The method provides an experimental research thought for oil reservoir recovery efficiency, and has important guiding significance on improvement of oil and gas field recovery efficiency and development of a negative carbon technology.

The invention provides a biological magnesium alloy micro-arc oxidation coating supercritical hole sealing method based on a thermodynamic sedimentary phase diagram, which comprises the following steps: establishing deposition-dissolution balance of metal ion phosphide and hydroxide of a phosphate conversion film in a supercritical carbon dioxide environment at different pH values to obtain the thermodynamic sedimentary phase diagram; selecting a NaH2PO4 solution according to a thermodynamic sedimentary phase diagram, and adding NaHCO3 to obtain a hole sealing solution; the hole sealing solution is injected into a reaction kettle to be heated, and then a refrigerator is started to convert generated carbon dioxide gas into supercritical carbon dioxide; and the biological magnesium alloy subjected to micro-arc oxidation is placed in the hole sealing solution in the reaction kettle to be pressurized, and holes of the micro-arc oxidation coating on the surface of the biological magnesium alloy are sealed. The invention provides a supercritical hole sealing method for a biological magnesium alloy micro-arc oxidation coating based on a thermodynamic sedimentary phase diagram. And the hole sealing effect is good.

Methods and apparatus to provide vortex cooled secondary flow for a supercritical carbon dioxide pump are disclosed herein. An example thermal management system includes a hot secondary flow extract section fluidly coupled to an outlet of a pump system, a cooled secondary flow section fluidly coupled to the hot secondary flow extract section, the hot secondary flow extract section including a vortex tube to generate cooled secondary air flow from hot secondary flow extract air of the hot secondary flow extract section, and a bearing inlet fluidly coupled to the cooled secondary flow section, the bearing inlet positioned to route the cooled secondary flow to bearings of the pump system.

This invention discloses a supercritical carbon dioxide cycle generator set water spray desuperheating system, comprising a supercritical carbon dioxide cycle power generation system and a water spray desuperheating system; the supercritical carbon dioxide cycle power generation system includes a heater, a screen-type superheater, a final-stage superheater, and a turbine; the water spray desuperheating system includes a first desuperheating water injection point, a second desuperheating water injection point, and a liquid-water separation system; the heater outlet is sequentially connected to the turbine inlet via the first desuperheating water injection point, the screen-type superheater, the second desuperheating water injection point, and the final-stage superheater; the turbine outlet is connected to the inlet of the liquid-water separation system; the liquid outlet of the liquid-water separation system is connected to the first and second desuperheating water injection points; and the gas outlet of the liquid-water separation system is connected to the heater inlet. This system can solve various problems caused by carbon dioxide desuperheating.

A refrigeration cycle is connected to a supercritical carbon dioxide (sCO2) power cycle by incorporating a CO2 condenser which is also the refrigeration cycle evaporator. The heat rejected by the carbon dioxide is absorbed by the refrigerant in the CO2 condenser. Work is done on the refrigerant to raise its temperature above the local ambient temperature. The heat absorbed from the power cycle and the work required to raise the refrigerant temperature is rejected to the ambient environment, which may be either air, earth, or water. This results in improved efficiencies in carbon dioxide power cycles without regard to the ambient temperature by forcing a transcritical phase change even when ambient temperatures are above the carbon dioxide critical point. A two-phase heat transfer on both sides of the CO2 condenser further improves efficiency of the sCO2 power cycle.

The invention discloses an in-situ carbon-coated positive electrode lithium supplement agent, a preparation method and application, and belongs to the field of lithium ion batteries. The preparation method of the positive electrode lithium supplement agent comprises the following steps: S1, mixing lithium oxalate with a carbon source, and grinding to prepare mixed powder; s2, the mixed powder is placed in a reaction kettle, sealing and vacuumizing are conducted, carbon dioxide gas is introduced, and the pressure is controlled to be 10-20 Mpa; keeping the temperature at 30-60 DEG C and reacting for 10-24 hours; and S3, exhausting, washing with alcohol, centrifuging and drying to obtain the in-situ carbon-coated positive electrode lithium supplement agent. The invention provides a preparation method of an in-situ carbon-coated positive electrode lithium supplement agent, which comprises the following steps: placing lithium oxalate and a carbon source in a supercritical carbon dioxide fluid, stirring and dissolving, controlling the reaction temperature and pressure to promote the polymerization reaction of carbon source micromolecules, and depositing a layer of compact and uniform carbon material on the surface of lithium oxalate particles in situ, thereby obtaining the in-situ carbon-coated positive electrode lithium supplement agent. The conductivity and the ion mobility of the material are improved, so that the electrochemical activity of lithium oxalate is improved.

The invention discloses a supercritical carbon dioxide pipeline transportation simulation method and device. The method comprises the following steps: acquiring physical property data of the supercritical carbon dioxide pipeline; correcting the unit of the physical property data; obtaining a preset steady-state calculation formula; correcting a partial derivative formula in the preset steady-state calculation formula to obtain a corrected steady-state calculation formula; and inputting the physical property data after unit correction into the corrected steady-state calculation formula, and carrying out steady-state calculation so as to realize static simulation of supercritical carbon dioxide pipeline transportation. According to the scheme provided by the invention, by correcting the physical property unit in the steady-state calculation formula and correcting the partial derivative formula of the unit mass flow rate of the energy equation part in the steady-state calculation formula on the fixed distance, the correctness of steady-state data of supercritical carbon dioxide during pipeline transportation is ensured.

The invention relates to the technical field of underwater vehicles, and discloses a built-in phase change drainage system and an underwater vehicle, the built-in phase change drainage system comprises a drainage device, a water ballast tank and a control unit, the drainage device comprises a first power unit and a pressure reduction unit, a first storage chamber for storing liquid carbon dioxide is arranged in the first power unit, and a pressure reduction chamber is arranged in the pressure reduction unit; the water ballast tank is provided with a containing cabin used for containing water, and the containing cabin is selectively communicated with the pressure reduction cavity. The control unit is in communication connection with the first power unit, the first power unit is suitable for converting liquid carbon dioxide into high-pressure supercritical carbon dioxide under the control of the control unit, and the carbon dioxide enters the containing cabin after being subjected to pressure reduction of the pressure reduction cavity so as to discharge water in the containing cabin. The drainage system is safe, efficient and high in drainage capacity.

The invention discloses a high-temperature supercritical carbon dioxide steady-state jet flow experiment device and method, and the device comprises a liquid storage tank, a liquid booster pump, a plunger pump, a first mass flow meter, a second mass flow meter, a heating section, a first electric control valve, a first-stage cooler, a second-stage condenser, a back pressure valve, and a main loop system composed of related pipe fittings and equipment. The gas supply system consists of a carbon dioxide gas cylinder group, a gas storage tank, a gas booster pump and related pipe fittings and equipment; and the jet experiment section consists of a spray pipe, a second electric control valve, an electric stop valve and related pipe fittings and equipment. The invention further provides an experimental method of the device. According to the invention, the steady-state jet flow experiment research of supercritical carbon dioxide under the high-temperature condition can be realized.

The invention provides a method and a device for measuring the flowing heat exchange characteristic of supercritical carbon dioxide in a tiny circular channel, and belongs to the field of research on the flowing heat exchange characteristic of supercritical fluid. The problem that parameters such as temperature, pressure and flow velocity in a tiny circular channel are difficult to measure by traditional measuring means is solved. The invention discloses a method for measuring the flowing heat exchange characteristic of supercritical carbon dioxide in a tiny circular channel. The method comprises the following steps: enabling the supercritical carbon dioxide to flow into a testing section of the tiny circular channel at preset pressure and flow; measuring temperature, pressure and flow velocity data of different positions of the micro circular channel test section in real time; according to the data, supercritical carbon dioxide flow heat exchange characteristic parameters are calculated through a pre-established model; and changing the working condition of the supercritical carbon dioxide supply system to obtain the flow heat exchange characteristic parameters of the supercritical carbon dioxide under different working conditions. The device is mainly used for measuring the flow heat exchange characteristic.

The invention discloses a supercritical entrainment extraction device for total flavonoids in folium cortex eucommiae, and relates to the technical field of pharmaceutical production. Comprising a fluid supply mechanism and an extraction mechanism, the fluid supply mechanism comprises a material mixing tank, a stirring pipe is rotatably arranged in the material mixing tank, a plurality of strip-shaped shells are fixedly arranged on the surface of the stirring pipe, and a plurality of nozzles are fixedly embedded in the surfaces of the strip-shaped shells. A dispersing disc and a grinding roller are arranged in the extraction tank, eucommia ulmoides leaves on the surface of the dispersing disc can be ground and smashed, and meanwhile, supercritical carbon dioxide mixed fluid is sprayed to the surfaces of the eucommia ulmoides leaves on the surface of the dispersing disc through a spray head on the surface of a rotating arm, so that the mixed fluid and the eucommia ulmoides leaves fully react; by utilizing the dissolving capacity of the supercritical carbon dioxide mixed fluid, a worker can conveniently extract the total flavonoids from the folium cortex eucommiae dissolved solution, so that the residual of solvent toxicity under the traditional solvent extraction condition can be effectively avoided, and meanwhile, the poison to a human body and the pollution to the environment in the extraction process are also prevented.

The invention discloses antioxidant salmon collagen peptide and a preparation method thereof, and belongs to the technical field of processing of salmon collagen peptide. The preparation method comprises the following steps: firstly, carrying out enzymolysis on the salmon material by using phospholipase A2, hydrolyzing abundant membrane phospholipids in the salmon material, destroying fat cell structures and releasing wrapped triglyceride, then carrying out secondary enzymolysis by using aspergillus oryzae lipase, hydrolyzing macromolecular lipids into free fatty acids which are easily dissolved in supercritical carbon dioxide, and carrying out secondary enzymolysis by using aspergillus oryzae lipase. The degreased salmon material is obtained by means of supercritical carbon dioxide extraction, the lipid removal rate is greatly increased, and the antioxidant salmon collagen peptide which is small in molecular weight and high in oxidation resistance is obtained through subsequent collagen extraction and enzymolysis.

The invention relates to the technical field of oilfield development, in particular to a reservoir supercritical carbon dioxide fracturing soaking production simulation method and device. Well cementation is simulated; fracturing simulation: placing the core sample subjected to well cementation in a core holder, applying axial pressure and confining pressure to the core sample, simulating stratum triaxial stress at a required temperature, obtaining initial experimental data of the core sample at the moment, injecting supercritical carbon dioxide into the core sample through a shaft, and obtaining experimental data during core fracturing; soaking is simulated, and the core sample enters a soaking stage after being fractured; carrying out production simulation, enabling the core sample to enter a flowback stage under a specific return pressure condition, and recording experimental data of the core sample in the flowback stage; and performing three-dimensional imaging analysis. According to the method, the spatial distribution of the crude oil after the supercritical carbon dioxide fracturing of the unconventional reservoir can be monitored in real time, and the characteristics of the cracks formed after the fracturing and the crude oil recovery capacity are quantitatively evaluated.

The invention belongs to the technical field of carbon dioxide energy storage, and particularly relates to a supercritical carbon dioxide energy storage system with combined cooling, heating and power, which realizes combined cooling, heating and power by recycling waste heat of a combined cooling, heating and power system and improves the energy utilization rate of the system. Carbon dioxide generated by the combined cooling heating and power system is captured and stored in the exhausted oil and gas reservoir high-pressure gas chamber and the exhausted oil and gas reservoir low-pressure gas chamber through the carbon dioxide capturing system, energy is stored through the stored carbon dioxide gas, and the stability maintaining effect on electric energy is achieved while carbon emission is reduced. The energy release unit is in heat exchange connection with the carbon dioxide capture system, the temperature of high-pressure carbon dioxide in the energy release stage is increased, and the comprehensive energy utilization rate and efficiency of the system are further improved.

The invention discloses a methanol fuel ship hybrid power system coupled with carbon dioxide in-situ capture and utilization. The methanol fuel ship hybrid power system comprises an SOFC / GT system, a supercritical carbon dioxide cycle power generation system, an organic Rankine cycle power generation system and a carbon dioxide in-situ utilization system. Exhaust gas of a gas turbine in the SOFC / GT system serves as a heat source to be sequentially used for heating cycle working media of the supercritical carbon dioxide cycle power generation system and the organic Rankine cycle power generation system and then enters the carbon dioxide in-situ utilization system. Exhaust gas received by the carbon dioxide in-situ utilization system is condensed through a condenser to separate H2O and then enters a cathode of the porous solid electrolytic cell, the cathode comprises a KOH solution and an anion exchange membrane, an anode comprises water and a cation exchange membrane, an electrode catalyst is bismuth oxide, anode exhaust gas enters the SOFC / GT system, and formic acid discharged by a middle interlayer enters a formic acid storage tank. According to the invention, the carbon dioxide in the waste gas is captured in situ on the methanol fuel ship to generate a high-added-value product, and the energy of a power system is comprehensively utilized.

The invention discloses a risk assessment method for a supercritical carbon dioxide conveying pipeline and related equipment, and the method comprises the steps: constructing a fault tree model for a failure event of the pipeline; obtaining a consequence event corresponding to the failure event, and constructing a consequence model according to the consequence event; based on the fault tree model and the consequence model, obtaining a bow-tie model of the supercritical carbon dioxide conveying pipeline; obtaining a plurality of groups of evaluation data of the plurality of evaluation policies for the basic event in the bow-tie model, and obtaining a failure probability corresponding to the basic event based on the plurality of groups of evaluation data; and obtaining an occurrence probability of a leakage consequence corresponding to the basic event based on the failure probability, and performing hazard assessment on the leakage consequence based on the occurrence probability to obtain an assessment result. According to the method, the occurrence frequency of consequences in various risk scenes is accurately calculated, the problem that the risk in the actual conveying process cannot be accurately reflected is avoided, and the design and implementation of subsequent risk management decisions and optimization measures can be effectively supported.

The invention discloses a valve monitoring method and device, a storage medium and an electronic device. The method comprises the steps that a distribution diagram of pipelines for transmitting supercritical carbon dioxide between trapping equipment and a sealing shaft is determined; identifying a plurality of valves to be monitored in the pipeline distribution diagram; real-time data collected by the detection sensing assemblies at the multiple valves are obtained, and the target probability that each valve leaks is evaluated based on the real-time data; and comparing the target probability with a preset leakage probability, and determining a monitoring result according to a comparison result. By the adoption of the technical scheme, the problem that in the related technology, the efficiency of finding the leakage state of the valve of the connecting pipeline in the transmission state is low is solved.

Extraction media for removal, concentration, and recovery of PEAS from contaminated materials in fluorous biphasic and / or multiphasic systems and related methods. The systems may include a fluorous functionalized solid support and a fluorous fractionation reactor permitting PFAS separation for targeted recovery. Extraction mediums comprise a polyelectrolyte with carbon dioxide / supercritical carbon dioxide (CO2 / SCCO2) with additional possible reagent modifiers that permit miscibility switches and compatibility with NSF / ANSI certifications. The extraction medium may include modifiers to enhance targeted recovery, such as F -solvents and / or organic carrier solvents. The disclosed systems and methods permit advantages such as 1 ) reduced sensitivity to PFAS-impacted phase co-contam inants such as competing anionic species and / or organic contaminants, 2) simple contact reactor retrofits, 3) enhanced removal of ultra- and / or short chain PFAS, 4) enhanced uniformity of matrix chemistry for downstream waste / wastewater management processes, and 5) the ability to recover valuable PFAS from waste / wastewater for processes that are dependent on their chemistry.

The invention provides a method for separating EPA (eicosapentaenoic acid) and DHA (docosahexaenoic acid) through supercritical fluid chromatography, and relates to the technical field of separation and purification. The invention provides a method for separating EPA (eicosapentaenoic acid) and DHA (docosahexaenoic acid) by supercritical fluid chromatography, which comprises the following steps: by taking supercritical carbon dioxide and an organic reagent as mobile phases, and by utilizing the specific mobile phase property of supercritical CO2 after being mixed with the organic reagent (saturated aliphatic hydrocarbon) and matching with a normal-phase chromatographic column, separating the EPA from the DHA by supercritical fluid chromatography. A specific stationary phase (one or more of a silica gel surface bonded propylurea stationary phase, a silica gel surface bonded phenyl stationary phase and a silica gel surface bonded imidazolyl stationary phase) is adopted, effective separation and preparation of the EPA and the DHA in the fish oil can be achieved, the EPA and the DHA in the fish oil can be effectively separated within 50 min, the separation speed is high, the separation effect is good, and the method is suitable for industrial production. The purity of the obtained EPA and DHA is 98% or above, the purity of the EPA and the DHA is high, and the EPA and the DHA have good application prospects in the fields of medicine production and food and health care products.

The invention relates to the technical field of supercritical carbon dioxide extraction devices, in particular to a supercritical carbon dioxide extraction device and a method thereof.The supercritical carbon dioxide extraction device comprises a cover plate, an outer shell, a carbon dioxide tank, a pump, a recycling box, a collecting box and a pressurizing device; through dynamic stirring, modular design, partition separation, carbon dioxide recycling and a rapid operation structure, the defects that an existing supercritical carbon dioxide extraction device is low in extraction efficiency, high in maintenance cost and high in energy consumption are overcome, and the device is more competitive in industrial production; the method is suitable for large-scale extraction of the biological source inhibitor eugenol.