52 results about "Propylene carbonate" patented technology

The application relates to the technical field of catalysts, and discloses a limited type iodine-based homogeneous immobilized catalyst as well as a preparation method and application thereof. The catalyst comprises a carrier and iodine ions, magnesium ions and quaternary ammonium ions loaded on the carrier, wherein the molar ratio of the magnesium ions, the quaternary ammonium ions, the iodine ions and the carrier is 0.01-1:4-15:1-30:1. The limited type iodine-based homogeneous immobilized catalyst disclosed by the application enhances the electrostatic interaction between iodine ions and quaternary ammonium ions through the molecular sieve limiting effect to construct a limited type structure. The catalyst has significantly enhanced CO2 adsorption and activation capacity, can activate an epoxide compound, and accelerates the ring opening of the epoxide compound. In a cycloaddition reaction catalyzed by the catalyst under the conditions of no solvent and no auxiliary agent, the conversion rate of propylene oxide can reach more than 73%, and the propylene carbonate selectivity can reach more than 85%.

The application provides a method for inkjet printing of oligonucleotides, and belongs to the technical field of in-situ synthesis of oligonucleotides.The method comprises the following steps: modifying the surface of a solid carrier with a chemically active functional group; depositing oligonucleotide synthesis reagents onto the surface of the modified solid carrier by inkjet to perform in-situ synthesis; and the solvent in the oligonucleotide synthesis reagents comprises one or two of glutaronitrile, acetonitrile and propylene carbonate.The application uses a new type of difficult-to-vaporize solvent, greatly reduces the volatilization of reagents during inkjet synthesis and the generation of organic vapors during synthesis, and thus maintains a high in-situ synthesis reaction efficiency of oligonucleotides.

The application relates to the technical field of catalysts, and discloses a nano magnesium oxide material and a preparation method and application thereof. The nano magnesium oxide material has a porous structure, wherein the particle size of the nano magnesium oxide is 20-200 nm; and the pore size of the porous structure is 5-45 nm. The classical nucleation growth process of the magnesium oxide is directionally adjusted in a weak alkaline nucleation system, and then the nano magnesium oxide with a controllable grain size distribution is obtained. The nano magnesium oxide material has good catalytic activity in the synthesis of propylene carbonate from CO2 and an epoxide under the conditions of no solvent and no auxiliary agent, and the catalyst is not deactivated after multiple uses, and has good stability.

An object of the present disclosure is to provide a nonaqueous electrolytic solution and a lithium ion secondary battery using same, the nonaqueous electrolytic solution having both excellent battery safety when used at a high temperature, an important feature for secondary batteries to be installed in modern vehicles such as electric vehicles, and having excellent battery characteristics. The nonaqueous electrolytic solution of the present disclosure is a nonaqueous electrolytic solution including an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous solvent containing from 80 to 100 vol % in total of at least one selected from ethylene carbonate, propylene carbonate, and γ-butyrolactone, and the nonaqueous electrolytic solution further including a trifluoroacetic acid ester having an alcohol group with a carbon chain length of from 6 to 8.

Lithium-ion battery, characterized in that it consists of a cathode, an anode and a non-aqueous electrolyte; wherein the cathode comprises a cathode material layer containing an active cathode material, wherein the active cathode material comprises a compound represented by formula (A): Li x Ni a Co b M' 1-a-b O 2-y A y Formula (A) where in formula (A) -0.1 ≤ x ≤ 0.2, 0.8 ≤ a < 1, 0 ≤ b < 0.2, 0.8 ≤ a + b < 1, 0 ≤ y < 0.2 hold; where M' comprises one or both of the elements Mn or Al and zero, one or more of the elements Sr, Mg, Ti, Ca, Zr, Zn, Si, Fe, B, Ga, Cr, W, V, Nb and Ce; where A comprises one or more of S, N, F, B, Cl, Br and I; wherein the anode comprises an anode material layer containing an active anode material, wherein the active anode material comprises a silicon-based material; wherein the non-aqueous electrolyte comprises a lithium salt and an organic solvent, wherein the organic solvent comprises cyclic carbonate, and wherein the cyclic carbonate comprises fluorinated ethylene carbonate and propylene carbonate; where the lithium-ion battery meets the following conditions: 0.2 ≤ S / F ≤ 2 ,0 ,2 ≤ P / F ≤ 3 ,5 and 3 ≤ S ≤ 15 ,2 ≤ F ≤ 15 ,2 ≤ P ≤ 25 , 15 ≤ C ≤ 40; where S denotes the mass fraction of silicon in the anode material layer, expressed in wt.%; where F denotes the mass fraction of fluorinated ethylene carbonate in the non-aqueous electrolyte, expressed in wt.%; where P denotes the mass fraction of propylene carbonate in the non-aqueous electrolyte, expressed in wt.%; where C denotes the mass fraction of cyclic carbonate in the non-aqueous electrolyte, expressed in wt.%.

This invention relates to the field of battery technology, specifically to a battery. The battery includes a positive electrode and an electrolyte. The positive electrode includes a positive current collector and a positive active layer. The positive active layer includes a ternary material, which comprises secondary particles interwoven from primary particles. The aspect ratio of the primary particles is 1.5-20. The ternary material has a hollow structure with internal cavities, and the area of ​​the cavities accounts for 5%-40% of the cross-section of the ternary material. The weight ratio of linear solvent to cyclic solvent in the electrolyte is 3-15. The cyclic solvent includes at least one of ethylene carbonate and propylene carbonate, and the weight percentage of the cyclic carbonate in the electrolyte is 8%-20%. The weight percentage of ethylene carbonate in the electrolyte is 0 < S1 ≤ 10%. The battery of this invention, through the synergistic effect of a specific ternary material structure and a specific electrolyte, enables the battery to possess both high low-temperature power performance and high cycle performance.

The application relates to the technical field of batteries, in particular to an electrolyte suitable for primary lithium-manganese batteries and a preparation method thereof. The electrolyte comprises propylene carbonate, ethylene carbonate, lithium bisfluorosulfonylimide, lithium perchlorate, lithium bisoxalate borate, terminal bisdifluorophosphorylated oligomeric trimethylene carbonate, ethylene glycol dimethyl ether, lithium difluorooxalate borate and 1,3-propane sultone. The electrolyte is prepared through a pre-coordination and segmented dilution process with specific timing. The electrolyte system can synergistically optimize the electrode interface film forming process, has high discharge capacity retention rate and low direct current resistance at low temperature (-20 DEG C), and has high capacity retention rate after high-temperature storage (60 DEG C), thereby significantly improving the comprehensive performance of the primary lithium-manganese battery in a wide temperature range.

This invention discloses a sodium-ion battery electrolyte, belonging to the field of sodium-ion battery technology, comprising an organic solvent, a sodium salt, and additives; the organic solvent includes ethylene carbonate, propylene carbonate, methyl ethyl carbonate, and ethyl acetate; the sodium salt includes sodium hexafluorophosphate and sodium difluorosulfonylimide; the additives include fluoroethylene carbonate, vinylene sulfate, sodium difluorophosphate, sodium difluorooxalate borate, and tris(trimethylsilane)phosphate. The sodium-ion battery electrolyte of this invention, through precise adjustment of the solvent and sodium salt ratio, maintains high conductivity at extremely low temperatures, significantly raising the lower limit operating temperature of the battery to -70°C. Simultaneously, through the synergistic effect of the sodium salt and additives, a high-temperature resistant SEI film rich in inorganic components is formed, reducing side reactions at high temperatures and raising the upper limit operating temperature of the battery to 85°C, achieving a wide temperature range application of the battery from -70°C to 85°C.

The application provides a method for preparing a lithium metal composite negative electrode by electroplating, a lithium metal composite negative electrode and application thereof, wherein the method for preparing the lithium metal composite negative electrode comprises the following steps: providing an electroplating electrolyte, wherein the electroplating electrolyte comprises a first solvent and a lithium salt dispersed in the first solvent, and the first solvent is selected from at least one of acetonitrile, gamma-butyrolactone or propylene carbonate; and immersing an electrolyte composite electrode into the electroplating electrolyte, so that lithium ions in the electroplating electrolyte are deposited on the surface of the electrolyte composite electrode through an electroplating operation, thereby obtaining the lithium metal composite negative electrode. Through the synergistic effect of the first solvent and the electroplating operation, the application solves the problems of poor interface contact between the lithium metal negative electrode and the solid-state electrolyte and lithium dendrite growth, improves the safety and long cycle life of the battery under high-rate charging and discharging, and significantly improves the performance of the solid-state battery.

Disclosed is a rechargeable lithium battery including a positive electrode including a positive active material; a negative electrode including a negative active material; an electrolyte solution including a lithium salt and a non-aqueous organic solvent; and a separator between the positive and the negative electrodes, the separator including a porous substrate and a coating layer positioned on at least one side of the porous substrate. The negative active material includes a Si-based material; the non-aqueous organic solvent includes cyclic carbonate including ethylene carbonate, propylene carbonate, or combinations thereof, the cyclic carbonate being included in an amount of about 20 volume % to about 60 volume % based on the total amount of the non-aqueous organic solvent; and the coating layer includes a fluorine-based polymer, an inorganic compound, or combinations thereof. The rechargeable lithium battery has improved cycle-life and high temperature storage characteristics.

The present application provides a solid electrolyte containing an electrolyte solution containing a lithium salt and a carbonate-based solvent, and metal oxide particles. In the solid electrolyte, the lithium salt is at least one selected from lithium bis(fluorosulfonyl)imide and lithium fluoroborate, the carbonate-based solvent is at least one selected from dimethyl carbonate and propylene carbonate, the molar ratio of the lithium salt to the carbonate-based solvent (lithium salt / carbonate-based solvent) is 1 / 4 or more and 1 / 1 or less, the mass ratio of the electrolyte solution to the metal oxide particles (electrolyte solution / metal oxide particles) is 72 / 28 or more and 93 / 7 or less, and the specific surface area of the metal oxide particles, measured based on the BET method, is 160 m 2 / g or more and 700 m 2 / g or less.

This invention discloses a nano-oxygen barrier functional masterbatch for the outer surface of packaging bottles and its preparation method, belonging to the field of polymer packaging material technology. The method involves first homogenizing and ultrasonically dispersing nisin, glycerol, montmorillonite K10, and silver nanoparticles in an aqueous phase, then adding nanocellulose to obtain a hybrid oxygen barrier suspension. Next, polylactic acid, polypropylene carbonate, and triglycidyl isocyanate are melted and laterally injected into the suspension. The mixture is then subjected to twin-screw extrusion, vacuum devolatilization, and granulation to obtain the masterbatch. This masterbatch can form an oriented "brick-and-mortar" barrier structure in the matrix, enhancing interfacial bonding and the stability of the nano-silver, significantly improving the oxygen barrier, moisture barrier, peel strength, and long-lasting antibacterial properties of the packaging outer surface.

The present invention relates to a lithium secondary battery comprising: a positive electrode including a positive electrode mixture layer containing a positive electrode active material, a negative electrode including a negative electrode mixture layer containing a negative electrode active material; and an electrolyte, wherein X defined by Equation (1) is 2 or more. Equation (1): X = 1000 / (A×B×C) In Equation (1), A is a value obtained by measuring, in seconds (sec), the time it takes for propylene carbonate to be completely impregnated in the positive electrode when 1 mL of propylene carbonate is dropped on the surface of the positive electrode, B is the sheet resistance of the positive electrode measured in Ω·cm, and C is the curvature of the positive electrode.

The application provides an electrolyte, an electrochemical device containing the electrolyte and an electronic device. The electrolyte comprises ethylene carbonate, propylene carbonate and fluoroethylene carbonate. The mass percentage of ethylene carbonate is a, 1.0% <= a <= 20%, the mass percentage of propylene carbonate is b, 12% <= b <= 35%, based on the mass of the electrolyte. The electrolyte further comprises an additive B. The additive B comprises at least one of butanedinitrile, hexanedinitrile, 1,4-dicyano-2-butene, ethylene glycol dicyan ether, 1,3,6-hexanetrimethylnitrile or 1,2,3-tris(2-cyanooxy)propane. The mass percentage of the additive B is 0.5% to 4%, based on the mass of the electrolyte. The electrochemical device with the electrolyte has good high-temperature storage performance and cycle performance.

This application relates to the field of battery technology, and provides a sodium-ion battery cell, a battery device, and an electrical device. The sodium-ion battery cell includes a positive electrode and an electrolyte; the single-layer thickness L of the positive electrode film on the positive electrode satisfies: 50μm≤L≤90μm; the general structural formula of the layered oxide material in the positive electrode film is Na. x Ni b Fe c Mn d Cu e N f O g N includes active and / or inert doped metal elements, including at least one of Zn, V, Cr, Al, Sc, Sn, Sb, Zr, Nb, Ti, Mg, Ru, Ir, and Ca; the electrolyte includes propylene carbonate and chain ester, the viscosity η of the chain ester at a temperature of 25℃±1℃ satisfies: 0.2mPa·s≤η≤3mPa·s, and the molecular weight M of the chain ester satisfies: 50≤M≤150, and the mass ratio E of propylene carbonate to chain ester satisfies: 0.11≤E≤1.

The application discloses a production method of high-performance recyclable BOPP film, and the high-performance recyclable BOPP film comprises an outer layer, a middle layer and an inner layer; the outer layer is composed of homopolymer polypropylene, polylactic acid, polyhydroxybutyrate, polypropylene carbonate, polystyrene-acrylonitrile copolymer, an antioxidant, an ultraviolet absorber and a slip agent; the middle layer is composed of homopolymer polypropylene, thermoplastic starch, polycaprolactone, polyethylene terephthalate, maleic anhydride grafted polypropylene, a fiber reinforcing agent and methyl methacrylate-butadiene-styrene copolymer; and the inner layer is composed of random copolymer polypropylene, polybutylene succinate, polyvinyl alcohol, PA6, an antistatic agent and an antibacterial agent. The BOPP film prepared by the method has good performance, is environment-friendly and recyclable.

The application discloses an ultralow-temperature aluminum electrolytic capacitor and a preparation method thereof. The capacitor comprises an anode foil, a cathode foil, an electrolytic paper between the anode foil and the cathode foil, and an electrolyte solution contained in the electrolytic paper. The electrolyte solution comprises, by weight percentage, propylene carbonate 15-25%, methyl ethyl carbonate 20-28%, diethylene glycol dimethyl ether 16-26%, lithium tetrafluoroborate 7-12%, lithium bisfluorosulfonylimide 2-5%, lithium difluorobisoxalate borate 2-5%, vinyl sulfate 4-8%, methanedisulfonate methylene 1.5-3.5%, mesoporous silicon dioxide 4-9%, lithium hexafluorophosphate 0.2-1.0%, lithium bis-trifluoromethanesulfonylimide 1.5-5%, a chelating agent 0.01-0.05%, and p-nitrophenol 0.3-1.2%. The preparation method comprises core wrapping, drying treatment, ring-type immersion, liquid removal treatment, assembly waist bundling, and aging treatment. The capacity retention rate of the capacitor can reach more than 90% at an ultralow temperature of -55 DEG C, and the Z ratio is only 1.29, so that the ultralow temperature and high temperature stability are synergistically improved.

The present application relates to gas phase material recycling equipment technical field, especially to a kind of gas phase material recycling equipment and method for ethylene carbonate system, a kind of gas phase material recycling equipment for ethylene carbonate system of the present application, comprising: body, gas phase pretreatment unit, condensing unit, collection pipeline, tail gas treatment unit;The present application is by setting two groups of outer tube, condensing tube and contact tube, let the temperature of contact tube be lower than the melting point of ethylene carbonate, to accelerate the crystallization recovery of ethylene carbonate, then solid ethylene carbonate is heated and melted into liquid to be recycled, and the time of the two groups of outer tube melting ethylene carbonate crystallization is always staggered, so that when recycling ethylene carbonate, recovery temperature reaches below the melting point of ethylene carbonate, so that recovery speed is increased compared to the recovery equipment above the melting point of recovery temperature.

The primer composition comprises a polyacrylate dissolved or dispersed in water. The polyacrylate comprises at least 20% by weight of methyl methacrylate units, at least 15% by weight of monomer units comprising at least one of secondary amines, tertiary amines, or tertiary amides, at least 15% by weight of acrylic monomer units comprising an alkyl group having at least four carbon atoms, and 2.5% to 10% by weight of acrylic monomer units comprising a carboxylic acid group. The primer composition comprises a polymer dispersed in water and a solvent, wherein water accounts for 50% by weight or more of the primer composition, and the solvent comprises at least one of propylene carbonate, polyol, polyol ether, polyol ether ester, or dibasic acid ester. The adhesive system comprises the primer composition and an adhesive tape. Furthermore, a method for producing the bonded article is also described.

The application discloses a kind of gel electrolyte with high ionic conductivity and high cation transference number and construction method, including selecting Lewis base to be dissolved in carbonate electrolyte, and gel electrolyte is formed by standing;Lewis base includes: aluminium chloride, aluminium isopropanol and other Lewis base that can initiate ring-opening polymerization of carbonate and participate in coordination;Carbonate includes: ethylene carbonate and propylene carbonate and other cyclic carbonates that can occur ring-opening polymerization;The mass fraction ratio range of Lewis base in carbonate electrolyte is the minimum concentration that can form gel to the saturated concentration in electrolyte.The disclosed gel electrolyte with high ionic conductivity and high cation transference number of the application eliminates the concentration difference polarization existing in alkali metal interface, fundamentally solves the cause of metal dendrite generation, thereby greatly improves the stability of alkali metal battery.

This invention provides a battery and an electrical device, including a positive electrode sheet comprising a positive electrode active material, the positive electrode active material being doped with and / or coated with aluminum; a negative electrode sheet comprising a negative electrode active material, the negative electrode active material comprising silicon particles; an electrolyte comprising a first solvent, a second solvent, a first additive, a second additive, and a third additive; the first solvent comprising ethyl 2,2-difluoroacetate, the second solvent comprising propylene carbonate, the first additive comprising 1,3-propanesulfonate lactone, the second additive comprising vinyl sulfate, and the third additive comprising succinate; this invention, through the synergistic design of a full battery system of "aluminum-modified positive electrode + silicon-based negative electrode + multifunctional composite electrolyte," achieves excellent low-temperature discharge performance, ultra-long cycle life, high interface stability, and outstanding thermal safety characteristics while maintaining high energy density.

A secondary battery, including a negative electrode plate and an electrolyte, where the negative electrode plate includes a negative electrode active material layer. The negative electrode active material layer includes graphite and a silicon-carbon material, and an average sphericity of the silicon-carbon material is 0.81 to 0.95. The electrolyte includes ethylene carbonate, propylene carbonate, ethyl propionate and propyl propionate, where based on a mass of the electrolyte, a mass percentage of the ethylene carbonate is a %, a mass percentage of the propylene carbonate is b %, a mass percentage of the ethyl propionate is c %, a mass percentage of the propyl propionate is d %, and (a+b) / (c+d) is in a range of 0.23 to 1.51.

A method for generating CO2 in situ for oilfield applications involves introducing propylene carbonate into a target zone and introducing a catalyst into the target zone, where the catalyst decomposes the propylene carbonate at the target zone to produce the CO2. The CO2 is subsequently used for a desired treatment objective or chemical reaction. The steps of introducing the propylene carbonate and the catalyst into the target zone occur in any order or simultaneously.

The application provides a full-biodegradable multilayer paper-plastic composite film for food and a preparation method and application thereof. The composite film comprises, in sequence, a corona layer, an adhesive layer, a barrier layer, a paper layer and a heat sealing layer. The blend of high-molecular-weight polypropylene carbonate (PPCH) and PBAT is used as the barrier layer, so that the water and oxygen barrier properties of the composite film can be effectively improved; the low-molecular-weight polypropylene carbonate (PPCL) hot melt adhesive is used as the adhesive layer, so that the adhesion and barrier effects can be achieved. In addition, the multilayer paper-plastic composite film provided by the application uses raw materials with the full-biodegradable characteristic, so that the environmental friendliness is greatly improved.

Alkene carbonate-based anhydrous cooling fluids have low toxicity and electrical conductivity, and high heat capacity. The fluids provide corrosion protection to cooling systems and remain liquid below -30°C. Furthermore, the fluids exhibit low viscosity at low temperatures. Some formulations contain dehydrating orthoesters.

This invention relates to the field of textile printing and dyeing technology, and discloses a method for preparing high-color-fastness, low-temperature, energy-saving dyed elastic fabric. The method includes: feeding a polyester / polyurethane interwoven elastic fabric into a dyeing machine; adding water to adjust to a first temperature; adding anhydrous sodium sulfate, sodium diisobutyl sulfosuccinate, and fatty alcohol polyoxyethylene ether in a circulating cycle; raising the temperature to a second temperature and adding propylene carbonate; subsequently adding gluconate-δ-lactone and Disperse Red 60, and circulating at a constant temperature; then raising the temperature to the highest dyeing temperature and holding; lowering the temperature to a third temperature and draining the dye liquor; refilling with water and adding fatty alcohol polyoxyethylene ether for hot water washing; and finally, rinsing with cold water and setting. This invention utilizes the low-temperature swelling effect of propylene carbonate and the slow-release acid-producing mechanism of gluconate-δ-lactone to control the highest dyeing temperature at 92–98°C, avoiding heat damage and elasticity loss of polyurethane fibers, improving dye uptake and fabric color fastness, while reducing dyeing energy consumption.

To improve charge and discharge characteristics. [Solution] The secondary battery comprises a positive electrode, a negative electrode, and an electrolyte. The positive electrode comprises a positive electrode current collector containing aluminum and a positive electrode active material layer provided on the positive electrode current collector. The positive electrode active material layer contains a lithium-containing compound. The electrolyte comprises an electrolyte, a solvent, and an additive. The electrolyte contains a bis(fluorosulfonyl)imide salt. The solvent contains at least one from the first group consisting of ethylene carbonate, propylene carbonate, fluoroethylene carbonate, dimethyl carbonate, and gamma butyrolactone. The additive contains at least one from lithium fluorophosphate, sulfinyl compounds, and dinitrile compounds. The intrinsic molar ratio of the solvent to lithium ions, calculated from the vibrational spectroscopy spectrum of the electrolyte, is greater than 0 and 1.78 or less.

The application provides a method for dissolving and recycling PET, comprising the following steps: 1) mixing the PET to be recycled with a mixed solvent system composed of a good solvent and a di-arylether under the protection of an inert atmosphere, stirring and dissolving under a first temperature condition to obtain a first material; the good solvent is propylene carbonate and / or ethylene carbonate; the di-arylether is at least one of diphenyl ether, butyl phenyl ether and dibenzyl ether; the first temperature is 160-200 DEG C; 2) cooling the first material to a second temperature, adding anti-solvent water to precipitate and separate out the PET; 3) separating, washing and drying the material obtained in the step 2) to obtain the recycled PET. The method for dissolving and recycling PET has the whole process in line with the green development route, effectively avoids the problem of degradation of the PET under high temperature dissolving, and the performance of the recycled PET is comparable to that of the raw material. Meanwhile, the PET yield can be as high as 97%, and the method has important large-scale industrial application value.