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294 results about "Propylene carbonate" patented technology

Propylene carbonate (often abbreviated PC) is an organic compound with the formula C₄H₆O₃. It is a cyclic carbonate ester derived from propylene glycol. This colorless and odorless liquid is useful as a polar, aprotic solvent. Propylene carbonate is chiral, but is used exclusively as the racemic mixture in most contexts.

Battery

The invention relates to the technical field of batteries, in particular to a battery. Comprising a positive plate and electrolyte, the positive plate comprises a positive current collector and a coating positioned on the surface edge of at least one side of the positive current collector along the length direction; the coating comprises filling particles, and the filling particles comprise at least one of inorganic particles and nitrogen-containing particles; the electrolyte comprises non-fluorinated cyclic carbonate and fluorinated ethyl acetate; the non-fluorinated cyclic carbonate comprises propylene carbonate and optional ethylene carbonate; on the basis of the total mass of the electrolyte, the content ratio C1 of the non-fluorinated cyclic carbonate is smaller than or equal to 25%, the content ratio C11 of the propylene carbonate is 3.1%-24.9%, the content ratio C12 of the ethylene carbonate is 0%-5%, and the content ratio C2 of the fluorinated ethyl acetate is 20.2%-70%. The battery provided by the invention can improve the problem of lithium precipitation under low-temperature discharge, and has relatively good short-circuit safety performance and relatively low high-temperature gas production rate.
Owner:CHONGQING COSMX BATTERY CO LTD

Lithium ion battery

The invention relates to the technical field of lithium ion batteries, and provides a lithium ion battery. The battery comprises a battery cell and a shell, the battery cell comprises an electrode assembly and electrolyte, and the electrode assembly comprises a negative plate, a diaphragm and a positive plate which are stacked in sequence; the mass ratio of the silicon element in the negative electrode active material is a%, and a is greater than or equal to 1 and less than or equal to 50; the shell comprises an aluminum layer and a first polymer layer which is positioned on the side, facing the battery core, of the aluminum layer and comprises a polyolefin material; the thickness of the first current collector of the first pole piece on the outermost side in the cell stacking direction is greater than that of the second current collector of the second pole piece with the same polarity as the first pole piece on the inner side; the thickness of the first current collector is recorded as c [mu] m; the ratio s of c to a satisfies 0.5 < = s < = 20; the electrolyte comprises a cyclic carbonate solvent containing ethylene carbonate and propylene carbonate, and the mass ratio of the cyclic carbonate solvent is smaller than or equal to 40%. The problems of swelling and damage of the packaging material caused by volume change of the silicon negative electrode can be solved, the safety of the battery is improved, and the cycle life of the battery is prolonged.
Owner:ZHUHAI COSMX BATTERY CO LTD

Preparation method and application of silicon-based biodegradable essence microcapsule

The invention relates to a preparation method and application of a silicon-based biodegradable essence microcapsule, and the preparation method of the silicon-based biodegradable essence microcapsule comprises the following steps: S1, uniformly mixing oily essence and a silicon-based mesoporous material to obtain an oil phase; dissolving an emulsifier in water to obtain a water phase; s2, mixing the oil phase and the water phase, and homogenizing to obtain an emulsion; and S3, adding a diisocyanate compound and polypropylene carbonate into the emulsion, and carrying out a stirring reaction to obtain the silicon-based biodegradable essence microcapsule. A silicon-based mesoporous material is introduced in the process of preparing the essence microcapsule by taking polypropylene carbonate as a wall material, a synergistic wrapping system of the essence microcapsule is constructed, and the volatile essence is subjected to double-layer protection by utilizing a mode of combining physical adsorption and chemical crosslinking embedding, so that the fragrance retention time of the essence is prolonged, and the fragrance retention time of the essence is prolonged. Meanwhile, the embedding rate of the microcapsule can be effectively improved, and the application of the essence microcapsule in actual production can be promoted by combining the biodegradable characteristic of the polypropylene carbonate.
Owner:SUDA NEW MATERIAL DEV (SUZHOU) CO LTD

Environment-friendly silk-screen printing ink diluent based on propylene carbonate and dimethyl carbonate and preparation method of environment-friendly silk-screen printing ink diluent

The invention relates to the technical field of printing materials, in particular to an environment-friendly silk-screen printing ink diluent based on propylene carbonate and dimethyl carbonate, which comprises dimethyl carbonate and propylene carbonate, and the dimethyl carbonate and the propylene carbonate are compounded according to a certain proportion. The diluent further comprises a synergistic solvent and a functional additive which are added according to a certain proportion. The environment-friendly silk-screen printing ink diluent formula for silk-screen printing ink and the preparation method of the environment-friendly silk-screen printing ink diluent formula are particularly suitable for viscosity adjustment and printability optimization of solvent type oil black, have the characteristics of low volatility and high solubility, and solve the problems of high toxicity of a traditional solvent, poor stability of a compound system, insufficient printability and the like.
Owner:CHANGXING XINGYING GLASS FIBER TECH CO LTD

Composite enhanced solid electrolyte membrane and preparation method thereof

The invention relates to the technical field of lithium battery electrolyte, in particular to a composite enhanced solid electrolyte membrane and a preparation method thereof. The polymer solid electrolyte is a polycarbonate-based solid electrolyte such as a poly (ethylene carbonate)-based solid electrolyte PVC, a poly (vinylene carbonate)-based solid electrolyte PEC, a poly (propylene carbonate)-based solid electrolyte PPC, a poly (propylene carbonate)-based solid electrolyte PTMC and a polyoxyethylene-based solid electrolyte. The electrolyte is one or more of polysiloxane-based polymer electrolyte and single-lithium-ion conductive polymer electrolyte materials. The composite enhanced solid electrolyte membrane is disclosed. The preparation method comprises the following steps: preparing the three-dimensional nanofiber skeleton through electrostatic spinning, loading the two surfaces of mixed slurry of the polymer electrolyte and the lithium salt on the base membrane in an inert atmosphere, and carrying out vacuum curing molding. The composite membrane has high safety and a wide electrochemical window, the process of the composite membrane is compatible with an existing lithium battery production line, the raw material cost is controllable, and the composite membrane has large-scale commercial application potential.
Owner:BEIJING INST OF TECH

Preparation method of piezoelectric response type hybrid ceramic membrane

The invention discloses a preparation method of a piezoelectric response type hybrid ceramic membrane, which is characterized in that polyvinylidene fluoride powder is used as a base material of the membrane, propylene carbonate or ethylene carbonate is used as a diluent, negative-voltage-loaded piezoelectric ceramic modified nanoparticles are doped, and a proper amount of inorganic piezoelectric nanoparticles are doped, so that the electrical property of the pressed membrane is remarkably improved; a negative charge group introduced to the surface of the membrane through surface grafting is combined, so that the relative content of beta crystal forms of the polyvinylidene fluoride membrane is increased, and finally efficient interception and excellent anti-pollution effects on humic acid are achieved.
Owner:GUIZHOU MATERIAL IND TECH INSTITUE

Wide-voltage wide-temperature-range sodium-ion battery electrolyte as well as preparation method and application thereof

ActiveCN120895738ASecondary cellsPositive electrodesTrifluoromethanesulfonic anhydridePhosphoric Acid Esters
The invention discloses a wide-voltage wide-temperature-range sodium-ion battery electrolyte and a preparation method and application thereof, and belongs to the technical field of sodium-ion battery electrolytes.The wide-voltage wide-temperature-range sodium-ion battery electrolyte comprises sodium salt, an organic solvent and an additive, the organic solvent is selected from one or more of ethylene carbonate, propylene carbonate, ethyl methyl carbonate, dimethyl carbonate, diethyl carbonate, ethylene glycol dimethyl ether, diethylene glycol dimethyl ether and triethylene glycol dimethyl ether, and the additive is selected from one or more of fluoroethylene carbonate, allyl-1, 3-propane sultone, 1, 3-propylene sultone, 1, 3-propylene sultone and 1, 3-propylene sultone. The additive is one or more of 1, 3-propyl sultone, methylene methane disulfonate, ethylene sulfate, trifluoromethanesulfonic anhydride, pentaerythritol bicyclic sulfate, tri (trimethylsilane) phosphate, tri (trimethylsilane) phosphite, tri (trimethylsilane) borate, acesulfame sodium and aluminum trifluoromethanesulfonate, and the additive is one or more of 2, 3-propylene sultone, methylene methane disulfonate, ethylene sulfate, trifluoromethanesulfonic anhydride, pentaerythritol dicyclosulfate, tri (trimethylsilane) phosphate, tri (trimethylsilane) phosphite, tri (trimethylsilane) borate, tri (trimethylsilane) phosphate and tri (trimethylsilane) borate. The electrolyte provided by the invention not only keeps high coulombic efficiency at low temperature, but also has good cycle stability at high temperature.
Owner:ZHEJIANG NATRIUM ENERGY CO LTD

Preparation method of lithium difluorobisoxalato phosphate concentrated solution

The invention relates to a preparation method of a lithium difluoro-bis (oxalate) phosphate concentrated solution, the lithium difluoro-bis (oxalate) phosphate concentrated solution is composed of lithium difluoro-bis (oxalate) phosphate and an aprotic solvent, the aprotic solvent comprises any one or a combination of at least two of diethyl carbonate, ethyl methyl carbonate, ethylene carbonate or propylene carbonate, the concentration of the lithium difluoro-bis (oxalate) phosphate in the lithium difluoro-bis (oxalate) phosphate concentrated solution is 10-35 wt%. The lithium difluoro bis (oxalate) phosphate concentrate provided by the invention exists in a non-proton electrolyte state, so that an evaporative crystallization process is omitted, and the production cost is reduced; the product transportation cost can be reduced through pipeline transportation; and compared with a lithium phosphate solid difluoro bis (oxalate), the process of re-dissolution during use is omitted, the risk of impurity introduction is avoided, and the use cost is reduced.
Owner:HANGZHOU WANLIDA NEW ENERGY TECH CO LTD

Hydrosilylation reaction catalyst and preparation method thereof

The invention relates to the technical field of organic silicon catalysis, and discloses a hydrosilylation reaction catalyst and a preparation method thereof, the catalyst is prepared from a platinum complex catalyst solution, maleic anhydride, triphenyl borate, tetraethoxysilane, propylene carbonate and diethylene glycol dibutyl ether; the preparation method comprises the steps of solvent water removal, electronic relay adduct preassembly, active metal introduction, thermal induction aging and the like. An electron-deficient coordination center is constructed through a step-by-step process, the electron cloud density of the platinum center is reduced by utilizing the Lewis acid characteristic of triphenyl borate, and the solvent cage effect of propylene carbonate is matched, so that the high-temperature tolerance of the catalyst is improved, and the generation of platinum black is effectively inhibited; meanwhile, the solubilizing and bridging effects of diethylene glycol dibutyl ether are utilized, the compatibility problem of a high-polarity component and a non-polar silicone oil matrix is solved, and the obtained catalyst has high activity, high regioselectivity and excellent long-term storage stability.
Owner:江西宏柏新材料股份有限公司

Production of semi-solid electrodes via addition of electrolyte to mixture of active material, conductive material, and electrolyte solvent

Embodiments described herein relate generally to semi-solid electrodes, and methods of producing the same. In some embodiments, a method of forming a semi-solid electrode can include mixing an active material, a conductive material, and an electrolyte solvent to produce a semi-solid material. The electrolyte solvent is free of electrolyte salt. The method further includes dispensing the semi-solid material onto a current collector and wetting the semi-solid material with an electrolyte solution to form the semi-solid electrode. In some embodiments, the wetting can be via spraying. In some embodiments, the electrolyte salt can have a concentration in the electrolyte solution of at least about 1 M, at least about 2 M, or at least about 3 M. In some embodiments, the solvent can include ethyl methyl carbonate (EMC), ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), gamma-Butyrolactone (GBL), or any combination thereof.
Owner:24M TECHNOLOGIES INC

Metformin hydrochloride sustained release tablet and preparation method thereof

The invention belongs to the technical field of pharmaceutical preparations, relates to a metformin hydrochloride sustained-release tablet and a preparation method thereof, and aims to overcome the technical defects of insufficient release behavior regulation and control precision and poor stability of an existing metformin hydrochloride sustained-release preparation. The metformin hydrochloride sustained-release tablet disclosed by the invention takes metformin hydrochloride as an effective component, is matched with sustained-release materials including hydroxypropyl methyl cellulose, propylene carbonate, zein, a filling agent, an adhesive and a lubricating agent, and can be selectively matched with a gastric-soluble film coating material. According to the invention, the stable release of the medicine is realized, the initial burst release phenomenon is avoided, meanwhile, the stability of the preparation is remarkably improved, and the good slow release performance can still be maintained after long-term storage.
Owner:浙江省人民医院毕节医院

Polylactic acid composite material for packaging bottle and preparation method of polylactic acid composite material

PendingCN120923993AAntioxidantCaprolactone
The invention discloses a polylactic acid composite material for a packaging bottle and a preparation method of the polylactic acid composite material. The polylactic acid composite material for the packaging bottle is prepared from the following components in parts by mass: 50 to 70 parts of polylactic acid, 10 to 30 parts of poly (epsilon-caprolactone), 10 to 30 parts of poly (propylene carbonate), 30 to 50 parts of functional master batch and 0.1 to 0.5 part of antioxidant, the functional master batch is prepared from a polylactic acid-modified nano silicon dioxide-poly (propylene carbonate) graft and a polylactic acid-modified nano silicon dioxide-poly (epsilon-caprolactone) graft; the modified nano silicon dioxide is 4-phenylethynyl phthalic anhydride modified nano silicon dioxide. The modified nano silicon dioxide is obtained by adopting an ultrasonic blending method, and different macromolecular substances are bonded through the modified nano silicon dioxide by utilizing an electron irradiation method to obtain a modified graft, so that the surface energy of particles can be reduced, the agglomeration among the particles can be reduced, and the dispersing performance of the nano silicon dioxide can be improved.
Owner:CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES

Confinement type iodine-based homogeneous immobilized catalyst, preparation method and application thereof

The application relates to the technical field of catalysts, and discloses a limited type iodine-based homogeneous immobilized catalyst as well as a preparation method and application thereof. The catalyst comprises a carrier and iodine ions, magnesium ions and quaternary ammonium ions loaded on the carrier, wherein the molar ratio of the magnesium ions, the quaternary ammonium ions, the iodine ions and the carrier is 0.01-1:4-15:1-30:1. The limited type iodine-based homogeneous immobilized catalyst disclosed by the application enhances the electrostatic interaction between iodine ions and quaternary ammonium ions through the molecular sieve limiting effect to construct a limited type structure. The catalyst has significantly enhanced CO2 adsorption and activation capacity, can activate an epoxide compound, and accelerates the ring opening of the epoxide compound. In a cycloaddition reaction catalyzed by the catalyst under the conditions of no solvent and no auxiliary agent, the conversion rate of propylene oxide can reach more than 73%, and the propylene carbonate selectivity can reach more than 85%.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

A method of oligonucleotide inkjet printing

The application provides a method for inkjet printing of oligonucleotides, and belongs to the technical field of in-situ synthesis of oligonucleotides.The method comprises the following steps: modifying the surface of a solid carrier with a chemically active functional group; depositing oligonucleotide synthesis reagents onto the surface of the modified solid carrier by inkjet to perform in-situ synthesis; and the solvent in the oligonucleotide synthesis reagents comprises one or two of glutaronitrile, acetonitrile and propylene carbonate.The application uses a new type of difficult-to-vaporize solvent, greatly reduces the volatilization of reagents during inkjet synthesis and the generation of organic vapors during synthesis, and thus maintains a high in-situ synthesis reaction efficiency of oligonucleotides.
Owner:BEIJING MINGYI INTELLIGENT MFG TECH CO LTD

Electrochemical and Electronic Devices

The present invention relates to electrochemical devices and electronic devices. Specifically, the present invention provides an electrochemical device comprising a cell, the cell comprising a positive electrode, a negative electrode, an electrolyte, and a separator, the outermost electrode of the cell having a curved portion and a straight portion, the straight portion having a length L mm and a radius D mm, where L / D is 5≦L≦10, the electrolyte containing propylene carbonate, and the propylene carbonate content A % based on the mass of the electrolyte, where A % is 5≦A≦15. The electrochemical device of the present invention has significantly improved room temperature cycle performance.
Owner:NINGDE AMPEREX TECHNOLOGY LTD

Method for synthesizing propylene carbonate by tubular reactor

The invention discloses a method for synthesizing propylene carbonate by a tubular reactor. The method comprises the following steps: carrying out contact reaction on CO2, epoxypropane and a catalyst by adopting a tubular reactor to obtain propylene carbonate, the tubular reactor comprises a shell pass and a tube pass; the reaction of synthesizing the propylene carbonate is carried out in a tube pass; a heat exchange medium is introduced into the shell side; the heat exchange medium comprises propylene carbonate and CO2. According to the method, the content of propylene carbonate in the product is increased, the energy consumption in the production process is reduced, and the economic benefit is increased.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Nanometer magnesium oxide material, preparation method and application thereof

The application relates to the technical field of catalysts, and discloses a nano magnesium oxide material and a preparation method and application thereof. The nano magnesium oxide material has a porous structure, wherein the particle size of the nano magnesium oxide is 20-200 nm; and the pore size of the porous structure is 5-45 nm. The classical nucleation growth process of the magnesium oxide is directionally adjusted in a weak alkaline nucleation system, and then the nano magnesium oxide with a controllable grain size distribution is obtained. The nano magnesium oxide material has good catalytic activity in the synthesis of propylene carbonate from CO2 and an epoxide under the conditions of no solvent and no auxiliary agent, and the catalyst is not deactivated after multiple uses, and has good stability.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Electrolyte for lithium battery

The invention discloses an electrolyte for a lithium battery, which comprises an organic solvent, a lithium salt and an additive, and the mass percentage ratio of the organic solvent to the lithium salt to the additive is (70-90): (5-20): (0.2-10); the organic solvent is composed of cyclic carbonate and chain carbonate in a mass ratio of (10-30): (70-90); the lithium salt is one or more of lithium hexafluorophosphate, lithium perchlorate and lithium tetrafluoroborate; the additives comprise a high-temperature stabilizer, an antioxidant and a film-forming accelerant, the cyclic carbonate is one or two of ethylene carbonate and propylene carbonate, and the chain carbonate is one or more of dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, dipropyl carbonate and methyl propyl carbonate. By optimizing the components of the electrolyte, the stability of the electrolyte at a high temperature is improved, and decomposition and side reactions are reduced, so that the performance of the battery in a high-temperature environment is improved, and the cycle life of the battery in a high-temperature environment is prolonged.
Owner:DALIAN CBAK POWER BATTERY CO LTD

High-activity catalyst for synthesizing propylene carbonate from CO2 and epoxypropane as well as preparation method and application of high-activity catalyst

The invention relates to a high-activity catalyst for synthesizing propylene carbonate from CO2 and epoxypropane and a preparation method and application thereof.The catalyst comprises a molecular sieve and metal oxide loaded on the molecular sieve, the molecular sieve is a pure silicon molecular sieve, the metal oxide is one or a combination of more of ZnO, Fe2O3, NiO, CoO and Cr2O3, the metal content accounts for 1-7 wt% of the mass of the catalyst, and the metal content accounts for 1-5 wt% of the mass of the catalyst. The particle size of the catalyst is 0.1-4 [mu] m. The preparation method comprises the following steps: treating a molecular sieve with an organic alkali, dipping the treated molecular sieve in a metal precursor solution subjected to acid treatment, controlling the pH value of the prepared metal precursor solution to be 2-4, shaking with an orbital shaking table, standing, drying, and roasting to obtain the catalyst. According to the invention, rich silicon hydroxyl nest sites on the surface of the molecular sieve with small particle size are utilized to effectively anchor metal species, and under the appropriate metal loading capacity, the synergistic catalysis of the metal and the adjacent silicon hydroxyl sites enables the molecular sieve to have high reaction performance for synthesizing propylene carbonate from CO2 and epoxypropane.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Electrolyte, lithium iron manganese phosphate battery and electric device

The invention provides an electrolyte, a lithium iron manganese phosphate battery and an electric device. The electrolyte comprises a lithium salt and a solvent, the solvent comprises ethylene carbonate, propylene carbonate, ethyl methyl carbonate, fluorobenzene and a low-viscosity solvent in a volume ratio of (2-5): (2-5): (3-5): (3-5): (2-5). The high dielectric constants of ethylene carbonate and propylene carbonate improve the dissolving capacity of the electrolyte to lithium salt, and meanwhile, the molecular structure can form a stable interface layer on the surface of a positive electrode to inhibit migration and dissolution of manganese ions; due to the low viscosity characteristic of the low-viscosity solvent, the overall viscosity of the electrolyte is reduced, and the permeability of the porous positive electrode material is enhanced, so that the wettability is improved, and uniform de-intercalation of lithium ions is promoted; a physical adsorption protection layer can be formed on the surface of the positive electrode through the coordination effect of high-electronegativity fluorine atoms in fluorobenzene and manganese, and direct contact between manganese and electrolyte is further blocked.
Owner:EVE ENERGY CO LTD +1

Electrolyte, application thereof and lithium carbon fluoride battery

The invention relates to the technical field of batteries, and discloses an electrolyte and application thereof, and a lithium carbon fluoride battery. The electrolyte comprises a lithium salt and an organic solvent; wherein the lithium salt is lithium bis (fluorosulfonyl) imide; the organic solvent is selected from one of ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene carbonate, propylene carbonate, dimethyl carbonate, ethyl methyl carbonate, dimethylformamide, dimethylacetamide and dimethyl sulfoxide. The electrolyte can be applied to preparation of a lithium primary battery. The invention also relates to a lithium carbon fluoride battery comprising the electrolyte. The electrolyte system provides an optimized solution for the preparation of the high-energy-density lithium carbon fluoride battery, has a wide application prospect, can remarkably improve the performance of the battery, reduces the production cost, and promotes the further development of the lithium carbon fluoride battery technology.
Owner:BEIJING UNIV OF CHEM TECH

Non-aqueous electrolyte solution and lithium-ion secondary battery using same

An object of the present disclosure is to provide a nonaqueous electrolytic solution and a lithium ion secondary battery using same, the nonaqueous electrolytic solution having both excellent battery safety when used at a high temperature, an important feature for secondary batteries to be installed in modern vehicles such as electric vehicles, and having excellent battery characteristics. The nonaqueous electrolytic solution of the present disclosure is a nonaqueous electrolytic solution including an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous solvent containing from 80 to 100 vol % in total of at least one selected from ethylene carbonate, propylene carbonate, and γ-butyrolactone, and the nonaqueous electrolytic solution further including a trifluoroacetic acid ester having an alcohol group with a carbon chain length of from 6 to 8.
Owner:KYOCERA CORP

Bio-based electrophoretic paint cross-linking agent composition and electrophoretic paint composition prepared from bio-based electrophoretic paint cross-linking agent composition

The invention discloses a bio-based electrophoretic paint cross-linking agent composition S1. The bio-based electrophoretic paint cross-linking agent composition S1 comprises the following components: a bio-based polyol component; an isocyanate component; the catalyst comprises an organic bismuth or zinc catalyst; the solvent comprises propylene glycol methyl ether acetate or bio-based propylene carbonate. The electrophoretic paint cross-linking agent composition S2 comprises the following components: a cyclic carbonate monomer; a polyene polyamine; a thiol-ene click chemical reagent; an end-capping reagent and an organic tin catalyst component. An electrophoretic paint composition is prepared from the bio-based electrophoretic paint cross-linking agent composition. The invention provides a polyisocyanate cross-linking agent taking castor oil and bio-based polycarbonate diol as raw materials and a carbamate cross-linking agent prepared from cyclic carbonate and polyene polyamine, and the polyisocyanate cross-linking agent and the carbamate cross-linking agent have the following advantages that the bio-based content is greater than or equal to 60%, and the consumption of petroleum resources is reduced; the curing temperature is not more than 140 DEG C; vOC emission is reduced by more than 30%; and the adhesion, salt fog resistance and other properties of the coating reach or exceed those of a traditional system.
Owner:HAOLISEN CHEM TECH (JIANGSU) CO LTD +1

Electrolyte, electrochemical apparatus and electronic device

Disclosed in the present application are an electrolyte, an electrochemical apparatus and an electronic device. The electrolyte contains a carbonic ester compound and a substance T, wherein the substance T comprises a sulfur-containing compound; the carbonic ester compound comprises at least two of ethyl propionate, propylene carbonate, diethyl carbonate or propyl propionate, and at least contains ethyl propionate; and based on the total mass of the electrolyte, the mass percentage content of the carbonic ester compound is A, and the mass percentage content of the sulfur-containing compound is B, both of which satisfy: 6.5≤A / B≤45. The electrolyte of the present application can alleviate the expansion of a lithium-ion battery during charging and discharging, which is beneficial for improving the overcharge safety performance of the lithium-ion battery at a high temperature.
Owner:NINGDE AMPEREX TECHNOLOGY LTD

Surface protection layer of ultrathin lithium strip as well as preparation method and application of surface protection layer

The invention discloses a surface protection layer of an ultrathin lithium strip as well as a preparation method and application of the surface protection layer, and belongs to the technical field of lithium batteries. The surface protection layer is formed after lithium metal reacts with a composite additive, and the composite additive is composed of solid powder and an organic solvent; wherein the solid powder is selected from one or more of dialkyl dithiophosphate or metal fluoride; the organic solvent is selected from any one of dimethyl sulfoxide, formamide, butyrolactam, acetone, 1, 4-dioxane, tetrahydrofuran, trimethyl phosphate, triethyl phosphate and propylene carbonate. The electrochemical performance of the produced lithium strip with the surface protection layer is remarkably improved, large-scale production can be achieved on the premise that existing equipment is not transformed and technological processes are not increased by means of the preparation method, the technical advantages in cost and technology are achieved, and therefore the lithium strip with the surface protection layer has a good application prospect. The surface protection layer of the ultrathin lithium strip and the preparation method of the surface protection layer have good application prospects.
Owner:TIANQI LITHIUM NEW ENERGY TECH RES (MEISHAN) CO LTD +1

Low-temperature electrolyte, positive electrode slurry and low-temperature sodium ion battery thereof

The application provides a low-temperature electrolyte, a positive electrode slurry and a low-temperature sodium ion battery, and belongs to the technical field of battery materials.The low-temperature electrolyte comprises sodium hexafluorophosphate, propylene carbonate, ethylene carbonate, dimethyl carbonate, methyl ethyl carbonate, fluoroethylene carbonate, 2,2,3,4,4,4-hexafluorobutyl acrylate and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether.The battery comprises the low-temperature electrolyte.The low-temperature electrolyte and the low-temperature sodium ion battery can not only be compatible with blended positive electrode materials, but also take into account the low-temperature performance, ensure that the prepared low-temperature sodium ion battery has good reaction kinetics and cycle performance, and can also improve the energy density of the electrode and reduce the powder resistivity.
Owner:HENGYANG BST POWER

Lithium-ion batteries

Lithium-ion battery, characterized in that it consists of a cathode, an anode and a non-aqueous electrolyte; wherein the cathode comprises a cathode material layer containing an active cathode material, wherein the active cathode material comprises a compound represented by formula (A): Li x Ni a Co b M' 1-a-b O 2-y A y Formula (A) where in formula (A) -0.1 ≤ x ≤ 0.2, 0.8 ≤ a < 1, 0 ≤ b < 0.2, 0.8 ≤ a + b < 1, 0 ≤ y < 0.2 hold; where M' comprises one or both of the elements Mn or Al and zero, one or more of the elements Sr, Mg, Ti, Ca, Zr, Zn, Si, Fe, B, Ga, Cr, W, V, Nb and Ce; where A comprises one or more of S, N, F, B, Cl, Br and I; wherein the anode comprises an anode material layer containing an active anode material, wherein the active anode material comprises a silicon-based material; wherein the non-aqueous electrolyte comprises a lithium salt and an organic solvent, wherein the organic solvent comprises cyclic carbonate, and wherein the cyclic carbonate comprises fluorinated ethylene carbonate and propylene carbonate; where the lithium-ion battery meets the following conditions: 0.2 ≤ S / F ≤ 2 ,0 ,2 ≤ P / F ≤ 3 ,5 and 3 ≤ S ≤ 15 ,2 ≤ F ≤ 15 ,2 ≤ P ≤ 25 , 15 ≤ C ≤ 40; where S denotes the mass fraction of silicon in the anode material layer, expressed in wt.%; where F denotes the mass fraction of fluorinated ethylene carbonate in the non-aqueous electrolyte, expressed in wt.%; where P denotes the mass fraction of propylene carbonate in the non-aqueous electrolyte, expressed in wt.%; where C denotes the mass fraction of cyclic carbonate in the non-aqueous electrolyte, expressed in wt.%.
Owner:SHENZHEN CAPCHEM TECH CO LTD

Reaction system and reaction process for preparing propylene carbonate by urea method

The invention discloses a reaction system and a reaction process for preparing propylene carbonate by a urea method, and relates to the technical field of chemistry and chemical engineering. The reaction system comprises a primary reaction system, a secondary reaction system and a final reaction system which are sequentially connected, the primary reaction system comprises a first reaction kettle and a first flash tank, the secondary reaction system comprises a second reaction kettle and a second flash tank, and the final reaction system comprises a third reaction kettle and a third flash tank; a baffle plate is arranged in the first reaction kettle, a spray nozzle is arranged in the second reaction kettle, a rotating plate is arranged in the third reaction kettle, and the rotating plate is coaxially connected with a stirrer in the third reaction kettle. The reaction process comprises the steps of primary reaction, secondary reaction and final reaction. The method can effectively remove ammonia gas generated in the process reaction, realizes continuous production of propylene carbonate, and is high in process yield, simple in equipment, clear in process and beneficial to large-scale production.
Owner:CHONGQING JIANFENG CHEM

Process for production of an alkoxylated product

The invention relates to a process for preparing an alkoxylated product. The aim of the invention is to provide aromatic polyols for preparing polyurethane-based and polyisocyanurate-based polymers, which ensure good miscibility with the isocyanate component and other components, have a good storage stability and render the end product flameproof. For this purpose, the invention devises a process for preparing an alkoxylated product by reacting bisphenol F with propylene carbonate and / or propylene oxide as propoxylation agent and ethylene carbonate and / or ethylene oxide as ethoxylation agent, the propoxylation agent and the ethoxylation agent being used in a molar ration of 70:30 to 45:55.
Owner:BAKELITE GMBH

Catalytic synthesis method of propylene carbonate

The invention discloses a catalytic synthesis method of propylene carbonate, belongs to the technical field of synthesis of propylene carbonate, and aims to solve the technical problem that the conversion rate and selectivity of propylene carbonate prepared by catalyzing a reaction of 1, 2-propylene glycol and carbon dioxide and the cyclic regeneration stability of a catalyst need to be further improved in the prior art. The method specifically comprises the following steps: adding 1, 2-propylene glycol and a cyclization catalyst into a high-pressure reaction kettle, stirring, introducing inert gas into the high-pressure reaction kettle, replacing and removing air in the high-pressure reaction kettle, and heating the high-pressure reaction kettle to 115-125 DEG C; according to the present invention, the epoxy silane-ionic salt is introduced after the activated carbon carrier is pretreated, and the highly dispersed immobilized Lewis acid center is introduced by using the tetraethoxysilane sol-gel, such that the conversion rate and the selectivity of the catalytic preparation of the propylene carbonate are effectively improved, and the performance stability of the cyclization catalyst during the cycle use is improved.
Owner:SHANDONG LIXING ADVANCED MATERIAL TECH CO LTD