396 results about "Propylene carbonate" patented technology

The invention relates to the technical field of batteries, in particular to a battery. Comprising a positive plate and electrolyte, the positive plate comprises a positive current collector and a coating positioned on the surface edge of at least one side of the positive current collector along the length direction; the coating comprises filling particles, and the filling particles comprise at least one of inorganic particles and nitrogen-containing particles; the electrolyte comprises non-fluorinated cyclic carbonate and fluorinated ethyl acetate; the non-fluorinated cyclic carbonate comprises propylene carbonate and optional ethylene carbonate; on the basis of the total mass of the electrolyte, the content ratio C1 of the non-fluorinated cyclic carbonate is smaller than or equal to 25%, the content ratio C11 of the propylene carbonate is 3.1%-24.9%, the content ratio C12 of the ethylene carbonate is 0%-5%, and the content ratio C2 of the fluorinated ethyl acetate is 20.2%-70%. The battery provided by the invention can improve the problem of lithium precipitation under low-temperature discharge, and has relatively good short-circuit safety performance and relatively low high-temperature gas production rate.

The invention provides a low-temperature electrolyte, positive electrode slurry and a low-temperature sodium ion battery, and belongs to the technical field of battery materials. The low-temperature electrolyte provided by the invention comprises sodium hexafluorophosphate, propylene carbonate, ethylene carbonate, dimethyl carbonate, methyl ethyl carbonate, fluoroethylene carbonate, 2, 2, 3, 4, 4, 4-hexafluorobutyl acrylate and 1, 1, 2, 2-tetrafluoroethyl-2, 2, 3, 3-tetrafluoropropyl ether. The battery provided by the invention comprises the low-temperature electrolyte. The low-temperature electrolyte and the low-temperature sodium-ion battery provided by the invention not only can be compatible with a blended positive electrode material, but also can give consideration to low-temperature performance, ensure that the prepared low-temperature sodium-ion battery has good reaction kinetics and cycle performance, and also can improve the energy density of an electrode and reduce the resistivity of powder.

The invention relates to the technical field of lithium ion batteries, and provides a lithium ion battery. The battery comprises a battery cell and a shell, the battery cell comprises an electrode assembly and electrolyte, and the electrode assembly comprises a negative plate, a diaphragm and a positive plate which are stacked in sequence; the mass ratio of the silicon element in the negative electrode active material is a%, and a is greater than or equal to 1 and less than or equal to 50; the shell comprises an aluminum layer and a first polymer layer which is positioned on the side, facing the battery core, of the aluminum layer and comprises a polyolefin material; the thickness of the first current collector of the first pole piece on the outermost side in the cell stacking direction is greater than that of the second current collector of the second pole piece with the same polarity as the first pole piece on the inner side; the thickness of the first current collector is recorded as c [mu] m; the ratio s of c to a satisfies 0.5 < = s < = 20; the electrolyte comprises a cyclic carbonate solvent containing ethylene carbonate and propylene carbonate, and the mass ratio of the cyclic carbonate solvent is smaller than or equal to 40%. The problems of swelling and damage of the packaging material caused by volume change of the silicon negative electrode can be solved, the safety of the battery is improved, and the cycle life of the battery is prolonged.

The invention discloses a carbon dioxide injection and production well cementation cement paste and a preparation method and application thereof, the well cementation cement paste comprises the following components by weight: 95-105 parts of oil well cement, 44-48 parts of water, 4-6 parts of a polymer emulsion, 4-6 parts of a self-repairing material, 1.5-2.5 parts of a drag reducer, 0.5-1.5 parts of a fluid loss agent and 0.2-0.8 part of an antifoaming agent; wherein the polymer emulsion is an emulsion which is formed by taking methyl methacrylate, vinyl trimethoxy silane and propylene carbonate as monomers through polymerization; the self-repairing material is a microcapsule in which thiobacillus ferrooxidans thalli and bacillus amyloliquefaciens thalli are embedded. The well cementation cement paste keeps good strength and relatively low permeability in a carbon dioxide environment, is good in corrosion resistance and has self-repairing capability.

Embodiments described herein relate generally to semi-solid electrodes, and methods of producing the same. In some embodiments, a method of forming a semi-solid electrode can include mixing an active material, a conductive material, and an electrolyte solvent to produce a semi-solid material. The electrolyte solvent is free of electrolyte salt. The method further includes dispensing the semi-solid material onto a current collector and wetting the semi-solid material with an electrolyte solution to form the semi-solid electrode. In some embodiments, the wetting can be via spraying. In some embodiments, the electrolyte salt can have a concentration in the electrolyte solution of at least about 1 M, at least about 2 M, or at least about 3 M. In some embodiments, the solvent can include ethyl methyl carbonate (EMC), ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), gamma-Butyrolactone (GBL), or any combination thereof.

The invention belongs to the technical field of biodegradable high polymer materials, and particularly discloses a PLA / PPC degradable spinning material and a preparation method thereof. The PLA / PPC degradable spinning material is prepared from the following raw materials in parts by weight: 65 to 75 parts of terminated polypropylene carbonate, 15 to 20 parts of polylactic acid, 1 to 2 parts of epoxidized soybean oil, 7 to 10 parts of composite Na-montmorillonite, 3 to 5 parts of light calcium carbonate, 6 to 9 parts of rice straw fiber, 0.6 to 0.8 part of cross-linking agent, 0.2 to 0.5 part of antioxidant, 1 to 2 parts of maleic anhydride grafted PLA compatilizer, 0.07 to 0.01 part of catalyst and 0.3 to 0.5 part of silicone. Various raw materials are mixed, so that the mechanical property of the material is remarkably improved, the material has good strength and toughness, and the comprehensive performance of the material is improved.

The invention relates to the technical field of plastic surface treatment, in particular to an environment-friendly novel plastic brightening cleaning agent formula and a preparation method and application thereof. The formula consists of 25-35% of a high-polarity compound propylene carbonate, 5-15% of a moderate-polarity compound ethyl acetate and 55-65% of a low-polarity compound dimethyl carbonate according to a specific weight ratio, and during preparation, under the protection of nitrogen, the three components are stirred for 20-30 minutes at the temperature of 20-30 DEG C at the speed of 200-400 rpm, and are sealed in an HDPE (High-Density Polyethylene) barrel after being filtered by 0.5 mu m. The bright cleaning agent has low toxicity (VOCsilt; 50 g / L), rapid volatilization (the surface drying time is less than or equal to 3 minutes) and high biodegradability (gt; the sulfate crystals of the lead-acid storage battery shell can be efficiently removed (the wiping removal rate after spraying is gt; and moreover, the glossiness is obviously improved to be more than or equal to 85 GU (an incidence angle of 60 degrees). The method is simple in process, meets the international environmental protection standard (such as GB 38508-2020), is suitable for industrial production and multi-scene application, has efficient cleaning and environmental protection safety, and is suitable for industrial production and multi-scene application.

The invention provides a polyurethane composite material, a preparation method and application thereof and an intelligent fabric liner material, and belongs to the field of solid lubrication. The preparation method comprises the following steps: mixing polypropylene carbonate glycol, isophorone diisocyanate, 2, 2-dimethylolpropionic acid and a catalyst, carrying out a prepolymerization reaction, mixing the obtained prepolymer, 4, 4 '-diaminodiphenyl disulfide and 4, 6-diaminopyrimidine, carrying out a chain extension reaction, mixing the obtained chain extension product with triethylamine, and carrying out a polymerization reaction to obtain polyurethane resin; and mixing polyurethane resin, the isocyanate functionalized boron nitride nanosheets and the carbon quantum dots to obtain the polyurethane composite material. According to the invention, an advanced polyurethane composite material is constructed by innovatively combining self-repairing, wear resistance and damage monitoring functions for the first time, and the properties are realized by a design strategy of combining isocyanate functionalized boron nitride nanosheets and carbon quantum dots with multiple dynamic reversible bonds (disulfide bonds and hydrogen bonds).

The invention relates to a preparation method and application of a silicon-based biodegradable essence microcapsule, and the preparation method of the silicon-based biodegradable essence microcapsule comprises the following steps: S1, uniformly mixing oily essence and a silicon-based mesoporous material to obtain an oil phase; dissolving an emulsifier in water to obtain a water phase; s2, mixing the oil phase and the water phase, and homogenizing to obtain an emulsion; and S3, adding a diisocyanate compound and polypropylene carbonate into the emulsion, and carrying out a stirring reaction to obtain the silicon-based biodegradable essence microcapsule. A silicon-based mesoporous material is introduced in the process of preparing the essence microcapsule by taking polypropylene carbonate as a wall material, a synergistic wrapping system of the essence microcapsule is constructed, and the volatile essence is subjected to double-layer protection by utilizing a mode of combining physical adsorption and chemical crosslinking embedding, so that the fragrance retention time of the essence is prolonged, and the fragrance retention time of the essence is prolonged. Meanwhile, the embedding rate of the microcapsule can be effectively improved, and the application of the essence microcapsule in actual production can be promoted by combining the biodegradable characteristic of the polypropylene carbonate.

The invention relates to the technical field of printing materials, in particular to an environment-friendly silk-screen printing ink diluent based on propylene carbonate and dimethyl carbonate, which comprises dimethyl carbonate and propylene carbonate, and the dimethyl carbonate and the propylene carbonate are compounded according to a certain proportion. The diluent further comprises a synergistic solvent and a functional additive which are added according to a certain proportion. The environment-friendly silk-screen printing ink diluent formula for silk-screen printing ink and the preparation method of the environment-friendly silk-screen printing ink diluent formula are particularly suitable for viscosity adjustment and printability optimization of solvent type oil black, have the characteristics of low volatility and high solubility, and solve the problems of high toxicity of a traditional solvent, poor stability of a compound system, insufficient printability and the like.

The invention belongs to the technical field of optical glass. The invention relates to an electrochromic glass device, in particular to a preparation method of the electrochromic glass device. The preparation method comprises the following specific preparation steps: cleaning the surface of a glass substrate, and depositing an indium tin oxide transparent conductive layer on the surface of the glass substrate by adopting magnetron sputtering; the preparation method comprises the following steps: by taking nano spherical silicon dioxide as a template, dispersing the nano spherical silicon dioxide in an ethanol solution, then adding a sodium tungstate solution, then adjusting the pH value to 2-3, carrying out a stirring reaction, and then cleaning with a sodium hydroxide solution to remove the template so as to obtain a hollow spherical precursor dispersion liquid; coating the hollow spherical precursor dispersion liquid on the surface of the transparent conductive layer in a spin coating mode, drying and annealing; preparing a liquid electrolyte: taking propylene carbonate as a solvent, and taking lithium perchlorate as an electrolyte lithium salt; niO is deposited on the surface of the WO3 electrochromic layer to serve as a counter electrode through magnetron sputtering; epoxy resin is adopted to package the edge, after liquid electrolyte is injected, internal residual bubbles are removed through hot pressing, and the product is obtained.

The invention relates to the technical field of lithium battery electrolyte, in particular to a composite enhanced solid electrolyte membrane and a preparation method thereof. The polymer solid electrolyte is a polycarbonate-based solid electrolyte such as a poly (ethylene carbonate)-based solid electrolyte PVC, a poly (vinylene carbonate)-based solid electrolyte PEC, a poly (propylene carbonate)-based solid electrolyte PPC, a poly (propylene carbonate)-based solid electrolyte PTMC and a polyoxyethylene-based solid electrolyte. The electrolyte is one or more of polysiloxane-based polymer electrolyte and single-lithium-ion conductive polymer electrolyte materials. The composite enhanced solid electrolyte membrane is disclosed. The preparation method comprises the following steps: preparing the three-dimensional nanofiber skeleton through electrostatic spinning, loading the two surfaces of mixed slurry of the polymer electrolyte and the lithium salt on the base membrane in an inert atmosphere, and carrying out vacuum curing molding. The composite membrane has high safety and a wide electrochemical window, the process of the composite membrane is compatible with an existing lithium battery production line, the raw material cost is controllable, and the composite membrane has large-scale commercial application potential.

The invention belongs to the field of modification of degradable fat polycarbonate materials, and particularly relates to a PCHC / PPC composite material and a preparation method thereof. A PCHC matrix material is added into PPC for blending modification, a PCHC / PPC blended matrix material is obtained, hydrophobic microcrystalline cellulose is further added, and the PCHC / PPC composite material is obtained. The invention aims to break through the limitation of an existing degradable material in specific application, the performance of a polypropylene carbonate PPC material is better improved through a layer-by-layer progressive optimization strategy, and a novel polycarbonate composite material is obtained, so that the thermal stability and the mechanical property of the material are improved, and wider application requirements are met.

The invention relates to the technical field of preparation of propylene carbonate, and discloses a solid bifunctional catalyst as well as a preparation method and application thereof. The solid bifunctional catalyst comprises a titanium silicalite molecular sieve and alkaline earth metal oxide loaded on the titanium silicalite molecular sieve. By adopting the solid bifunctional catalyst, propylene carbonate can be directly and continuously synthesized from propylene, an oxidizing agent and CO2 through one-step reaction. The technical process is obviously simplified, the links of separation, purification, storage and transportation of epoxypropane are cancelled, and the production efficiency is improved through continuous production; the process energy consumption is obviously reduced, and the economical efficiency of the whole process is improved.

The invention discloses a preparation method of a piezoelectric response type hybrid ceramic membrane, which is characterized in that polyvinylidene fluoride powder is used as a base material of the membrane, propylene carbonate or ethylene carbonate is used as a diluent, negative-voltage-loaded piezoelectric ceramic modified nanoparticles are doped, and a proper amount of inorganic piezoelectric nanoparticles are doped, so that the electrical property of the pressed membrane is remarkably improved; a negative charge group introduced to the surface of the membrane through surface grafting is combined, so that the relative content of beta crystal forms of the polyvinylidene fluoride membrane is increased, and finally efficient interception and excellent anti-pollution effects on humic acid are achieved.

The invention discloses a benzene-free environment-friendly plastic printing ink diluent and a preparation method thereof, and relates to the field of chemical engineering. The environment-friendly flame retardant is prepared from the following components in parts by weight: 10 to 25 parts of ethyl acetate, 8 to 15 parts of refined methyl acetate, 5 to 10 parts of butyl acetate, 10 to 30 parts of dimethyl carbonate, 6 to 15 parts of methylal, 10 to 20 parts of propyl acetate, 2 to 7 parts of dibasic acid ester, 3 to 10 parts of propylene glycol monomethyl ether, 7 to 15 parts of isopropanol and 3 to 9 parts of propylene carbonate. According to the present invention, the ethyl acetate, the dimethyl carbonate and other benzene-free solvents are adopted to replace the traditional benzene-series solvent, such that the benzene-free environmental protection target is achieved, the environmental residue and the human health risk are substantially reduced, in addition, the propylene carbonate, the dibasic acid ester and the like in the formula further have the biodegradability, the environmental protection performance of the diluent is further improved, and the environmental protection performance of the diluent is further improved. The cost of the prepared benzene-free environment-friendly plastic printing ink diluent is remarkably reduced compared with that of an imported diluent.

The present invention discloses a recyclable bio-based thermosetting polyurethane hot melt adhesive and its preparation method, which includes vegetable oil polyol, poly(propylene carbonate) diol, polyester polyol, macromolecular thermoplastic tackifying resin, isocyanate, furan compound containing active hydrogen, and bifunctional bismaleimide. First, the present invention reacts vegetable oil polyol, poly(propylene carbonate) diol, polyester polyol, and macromolecular thermoplastic tackifying resin with diisocyanate to generate a polyurethane prepolymer. Subsequently, the furan compound containing active hydrogen is reacted with the above prepolymer. Finally, bifunctional bismaleimide is added to form a dynamic covalent polymer therewith. The prepared bio-based thermosetting polyurethane hot melt adhesive has a low melt viscosity, a high ultimate peel strength, and recyclable characteristics. Some raw materials of the present invention are derived from biomass and renewable materials, which improves the green sustainability of the product's entire life cycle.

The invention belongs to the technical field of secondary batteries, and particularly relates to an electrolyte and a preparation method thereof and a secondary battery, the electrolyte comprises an organic solvent, a lithium salt and an additive, the mass of the organic solvent accounts for 80-93% of the total mass of the electrolyte, and the mass of the lithium salt accounts for 6-15% of the total mass of the electrolyte. The mass of the additive accounts for 1-8% of the total mass of the electrolyte; wherein the organic solvent comprises a linear carbonic ester solvent and a cyclic carbonic ester solvent, the mass of the linear carbonic ester solvent accounts for 60%-85% of the total mass of the organic solvent, and the mass of the cyclic carbonic ester solvent accounts for 15%-40% of the total mass of the organic solvent. Compared with the prior art, the electrolyte provided by the invention has the advantages that the low-temperature performance of the battery can be remarkably improved under the condition that a large amount of propylene carbonate, methyl ethyl carbonate, carboxylic ester solvents and low-temperature additives are not required to be used by precisely regulating and controlling the mass ratio of the organic solvent to the lithium salt to the additives in the electrolyte.

The invention discloses a wide-voltage wide-temperature-range sodium-ion battery electrolyte and a preparation method and application thereof, and belongs to the technical field of sodium-ion battery electrolytes.The wide-voltage wide-temperature-range sodium-ion battery electrolyte comprises sodium salt, an organic solvent and an additive, the organic solvent is selected from one or more of ethylene carbonate, propylene carbonate, ethyl methyl carbonate, dimethyl carbonate, diethyl carbonate, ethylene glycol dimethyl ether, diethylene glycol dimethyl ether and triethylene glycol dimethyl ether, and the additive is selected from one or more of fluoroethylene carbonate, allyl-1, 3-propane sultone, 1, 3-propylene sultone, 1, 3-propylene sultone and 1, 3-propylene sultone. The additive is one or more of 1, 3-propyl sultone, methylene methane disulfonate, ethylene sulfate, trifluoromethanesulfonic anhydride, pentaerythritol bicyclic sulfate, tri (trimethylsilane) phosphate, tri (trimethylsilane) phosphite, tri (trimethylsilane) borate, acesulfame sodium and aluminum trifluoromethanesulfonate, and the additive is one or more of 2, 3-propylene sultone, methylene methane disulfonate, ethylene sulfate, trifluoromethanesulfonic anhydride, pentaerythritol dicyclosulfate, tri (trimethylsilane) phosphate, tri (trimethylsilane) phosphite, tri (trimethylsilane) borate, tri (trimethylsilane) phosphate and tri (trimethylsilane) borate. The electrolyte provided by the invention not only keeps high coulombic efficiency at low temperature, but also has good cycle stability at high temperature.

The invention relates to the technical field of preparation of propylene carbonate, and discloses a bromide ion intercalated magnesium-aluminum layered hydroxide as well as a preparation method and application thereof. The method comprises the following steps: (1) providing an aqueous solution containing an aluminum source and a magnesium source, mixing the aqueous solution containing the aluminum source and the magnesium source with an alkali source, aging the obtained mixed solution, and then separating out a solid phase; and (2) mixing the solid phase obtained in the step (1) with an aqueous solution containing a bromine source, aging the obtained turbid liquid, and then carrying out solid-liquid separation. The bromide ion intercalated magnesium-aluminum layered hydroxide prepared by the method provided by the invention can effectively catalyze ring opening of epoxypropane, can obtain obviously higher propylene carbonate yield under mild conditions, cannot be inactivated after being used as a catalyst for many times, and has higher stability.

The invention relates to a preparation method of a lithium difluoro-bis (oxalate) phosphate concentrated solution, the lithium difluoro-bis (oxalate) phosphate concentrated solution is composed of lithium difluoro-bis (oxalate) phosphate and an aprotic solvent, the aprotic solvent comprises any one or a combination of at least two of diethyl carbonate, ethyl methyl carbonate, ethylene carbonate or propylene carbonate, the concentration of the lithium difluoro-bis (oxalate) phosphate in the lithium difluoro-bis (oxalate) phosphate concentrated solution is 10-35 wt%. The lithium difluoro bis (oxalate) phosphate concentrate provided by the invention exists in a non-proton electrolyte state, so that an evaporative crystallization process is omitted, and the production cost is reduced; the product transportation cost can be reduced through pipeline transportation; and compared with a lithium phosphate solid difluoro bis (oxalate), the process of re-dissolution during use is omitted, the risk of impurity introduction is avoided, and the use cost is reduced.

The invention relates to a battery monomer, a battery device and a power utilization device, the battery monomer comprises an electrode assembly and an electrolyte, the electrode assembly comprises a positive pole piece, an isolating membrane and a negative pole piece, and the positive pole piece comprises lithium-containing phosphate with an olivine structure; the electrolyte comprises a linear carboxylic ester solvent, a cyclic carbonate solvent and an additive, wherein the viscosity of the linear carboxylic ester solvent at normal temperature is 0.4 mPa.s to 0.6 mPa.s; the cyclic carbonate solvent comprises at least one of ethylene carbonate and propylene carbonate; the additive comprises at least one of a borate additive, a sulfonate additive, a silane-based additive and an unsaturated ester additive, and the unsaturated ester additive comprises one or more of vinylene carbonate, vinylethylene carbonate, allyl ethyl carbonate and a fluoro-carbonate additive. And the mass content of the additive in the electrolyte is 0.5-6%. According to the invention, rapid charging and use reliability of the battery can be considered.

The invention relates to the technical field of organic silicon catalysis, and discloses a hydrosilylation reaction catalyst and a preparation method thereof, the catalyst is prepared from a platinum complex catalyst solution, maleic anhydride, triphenyl borate, tetraethoxysilane, propylene carbonate and diethylene glycol dibutyl ether; the preparation method comprises the steps of solvent water removal, electronic relay adduct preassembly, active metal introduction, thermal induction aging and the like. An electron-deficient coordination center is constructed through a step-by-step process, the electron cloud density of the platinum center is reduced by utilizing the Lewis acid characteristic of triphenyl borate, and the solvent cage effect of propylene carbonate is matched, so that the high-temperature tolerance of the catalyst is improved, and the generation of platinum black is effectively inhibited; meanwhile, the solubilizing and bridging effects of diethylene glycol dibutyl ether are utilized, the compatibility problem of a high-polarity component and a non-polar silicone oil matrix is solved, and the obtained catalyst has high activity, high regioselectivity and excellent long-term storage stability.

Embodiments described herein relate generally to semi-solid electrodes, and methods of producing the same. In some embodiments, a method of forming a semi-solid electrode can include mixing an active material, a conductive material, and an electrolyte solvent to produce a semi-solid material. The electrolyte solvent is free of electrolyte salt. The method further includes dispensing the semi-solid material onto a current collector and wetting the semi-solid material with an electrolyte solution to form the semi-solid electrode. In some embodiments, the wetting can be via spraying. In some embodiments, the electrolyte salt can have a concentration in the electrolyte solution of at least about 1 M, at least about 2 M, or at least about 3 M. In some embodiments, the solvent can include ethyl methyl carbonate (EMC), ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), gamma-Butyrolactone (GBL), or any combination thereof.

The invention discloses a porous composite polymer solid electrolyte, a preparation method thereof and a solid sodium ion battery. The porous composite polymer solid electrolyte is prepared from a deep eutectic solvent, an additive, a polymer solution and a sodium super-ion conductor, the deep eutectic solvent is composed of a sodium ion-containing hydrogen bond receptor and a hydrogen bond donor, wherein the sodium ion-containing hydrogen bond receptor is selected from any one of sodium hexafluorophosphate, sodium tetrafluoroborate, sodium bis (oxalato) borate, sodium difluoro (oxalato) borate, sodium bis (trifluoromethanesulfonyl) imide, sodium bis (fluorosulfonyl) imide, sodium perchlorate, sodium nitrate, sodium chloride and sodium difluorophosphate; the additives are ethylene carbonate and propylene carbonate; the polymer solution is composed of a polymer and an organic solvent; the mass ratio of the sodium super-ion conductor to the polymer is 1: (2-5). The porous composite polymer solid electrolyte disclosed by the invention has excellent ionic conductivity and flame retardance, relatively strong mechanical property and excellent safety.

The invention provides a wide-temperature-range sodium-ion battery electrolyte, a sodium-ion battery and a power utilization device. The wide-temperature-range sodium-ion battery electrolyte comprises a sodium salt, an organic solvent and a single-component additive, the sodium salt is sodium bis (fluorosulfonyl) imide; the organic solvent is a composite solvent composed of ethylene carbonate, propylene carbonate and diethyl carbonate; the additive is an unsaturated ester additive; based on the mass of the electrolyte, the use amount of the additive is 0.1-5wt%; based on the volume of the electrolyte, the amount-of-substance concentration of the sodium salt is 0.5-3 mol / L; the conductivity of the electrolyte at the temperature of-30 DEG C is 0.1-5 mS cm <-1 >, and the conductivity of the electrolyte at the temperature of 55 DEG C is 10-20 mS / cm. And the battery can stably work in a wide temperature range from-30 DEG C to 55 DEG C, and the use requirement of the battery under a relatively wide temperature working condition is met.

The invention belongs to the technical field of pharmaceutical preparations, relates to a metformin hydrochloride sustained-release tablet and a preparation method thereof, and aims to overcome the technical defects of insufficient release behavior regulation and control precision and poor stability of an existing metformin hydrochloride sustained-release preparation. The metformin hydrochloride sustained-release tablet disclosed by the invention takes metformin hydrochloride as an effective component, is matched with sustained-release materials including hydroxypropyl methyl cellulose, propylene carbonate, zein, a filling agent, an adhesive and a lubricating agent, and can be selectively matched with a gastric-soluble film coating material. According to the invention, the stable release of the medicine is realized, the initial burst release phenomenon is avoided, meanwhile, the stability of the preparation is remarkably improved, and the good slow release performance can still be maintained after long-term storage.

The invention provides a battery monomer, a battery device and electric equipment, the battery monomer comprises an electrode assembly and an electrolyte, the electrode assembly comprises a positive pole piece and a negative pole piece, the positive pole piece comprises a positive current collector and a positive active material layer arranged on at least one side of the positive current collector, the positive active material layer comprises a positive active material, and the negative active material layer comprises a negative active material; the positive electrode active material comprises lithium-containing phosphate; the negative electrode plate comprises a negative electrode current collector and a negative electrode active material layer arranged on at least one side of the negative electrode current collector, and the negative electrode active material layer comprises a negative electrode active material; the electrolyte comprises a first solvent and a first additive, the first solvent comprises one or two of ethylene carbonate and propylene carbonate, based on the total mass of the electrolyte, the mass ratio of the first solvent is 20%-40%, the first additive comprises a carbonic ester additive, and based on the total mass of the electrolyte, the mass ratio of the carbonic ester additive is 0.5%-8%.

The invention discloses a polylactic acid composite material for a packaging bottle and a preparation method of the polylactic acid composite material. The polylactic acid composite material for the packaging bottle is prepared from the following components in parts by mass: 50 to 70 parts of polylactic acid, 10 to 30 parts of poly (epsilon-caprolactone), 10 to 30 parts of poly (propylene carbonate), 30 to 50 parts of functional master batch and 0.1 to 0.5 part of antioxidant, the functional master batch is prepared from a polylactic acid-modified nano silicon dioxide-poly (propylene carbonate) graft and a polylactic acid-modified nano silicon dioxide-poly (epsilon-caprolactone) graft; the modified nano silicon dioxide is 4-phenylethynyl phthalic anhydride modified nano silicon dioxide. The modified nano silicon dioxide is obtained by adopting an ultrasonic blending method, and different macromolecular substances are bonded through the modified nano silicon dioxide by utilizing an electron irradiation method to obtain a modified graft, so that the surface energy of particles can be reduced, the agglomeration among the particles can be reduced, and the dispersing performance of the nano silicon dioxide can be improved.

The application relates to the technical field of catalysts, and discloses a limited type iodine-based homogeneous immobilized catalyst as well as a preparation method and application thereof. The catalyst comprises a carrier and iodine ions, magnesium ions and quaternary ammonium ions loaded on the carrier, wherein the molar ratio of the magnesium ions, the quaternary ammonium ions, the iodine ions and the carrier is 0.01-1:4-15:1-30:1. The limited type iodine-based homogeneous immobilized catalyst disclosed by the application enhances the electrostatic interaction between iodine ions and quaternary ammonium ions through the molecular sieve limiting effect to construct a limited type structure. The catalyst has significantly enhanced CO2 adsorption and activation capacity, can activate an epoxide compound, and accelerates the ring opening of the epoxide compound. In a cycloaddition reaction catalyzed by the catalyst under the conditions of no solvent and no auxiliary agent, the conversion rate of propylene oxide can reach more than 73%, and the propylene carbonate selectivity can reach more than 85%.