826 results about "Fluorine free" patented technology

The invention relates to a fluoride-free polyimide-based film and a preparation method thereof. The method comprises the following steps: S1, preparing a polyamide acid solution; s2, fluorine-free organic silicon serving as a modifier is added into the polyamide acid solution and dispersed, a blended spinning solution is formed, and the solubility parameter difference value of the fluorine-free organic silicon and polyamide acid is 2.0 (MPa) 1 / 2 or below; s3, carrying out electrostatic spinning on the blended spinning solution to form a polyamide acid-based nanofiber layer; and S4, carrying out thermal imidization on the polyamide acid-based nanofiber layer to obtain the fluoride-free polyimide-based film. The film has a structure formed by three-dimensional cross-linking and winding of polyimide-based nanofibers, and the polyimide-based nanofibers are composed of a polyimide base material and fluorine-free organic silicon dispersed in the polyimide base material. The method does not involve fluorine-containing raw materials, and is environment-friendly and high in process compatibility. The film provided by the invention has excellent waterproofness, air permeability and mechanical properties at the same time.

The invention discloses an environment-friendly electrolyte for anodic oxidation of titanium and titanium alloy workpieces and an electrolytic coloring method. The electrolyte comprises 8-12 parts of lactic acid, 5-10 parts of sodium tartrate, 2-5 parts of sodium bicarbonate and the balance of deionized water. The electrolytic coloring method comprises the steps of pretreatment, anodic oxidation coloring and aftertreatment. The pretreatment comprises alkali washing oil removal, water washing and laser treatment; and an electrolyte mixed by 8-12 parts of lactic acid, 5-10 parts of sodium tartrate, 2-5 parts of sodium bicarbonate and the balance of deionized water is used for anodic oxidation coloring. The post-treatment comprises sealing treatment and drying. According to the technical scheme, the technical problems that the anodic oxidation coloring technology is completely free of fluorine, low in toxicity and safe to operate, and the oxidation waste liquid is free of pollution and easy to treat can be solved, existing pretreatment steps can be simplified, and meanwhile uniform coloring is achieved.

The invention provides a titanium nitride doped fluoride-free photo-thermal super-hydrophobic coating and a preparation method and application thereof.The titanium nitride doped fluoride-free photo-thermal super-hydrophobic coating is prepared from polydimethylsiloxane modified titanium nitride, hydrophobic nanoparticles and an adhesive and has the excellent local surface plasma resonance effect and photo-thermal effect; meanwhile, the coating is of a rough and uniform micro-nano hierarchical structure, dynamic water can be efficiently removed, icing can be delayed, the surface temperature can reach 12 DEG C only through irradiation of one sunlight intensity in the environment of-30 DEG C, and rapid deicing can be achieved. The coating has good functions of self-cleaning, anti-icing, deicing, defrosting and the like, renewable solar energy is utilized, and the coating is green, environment-friendly, energy-saving and emission-reducing. Meanwhile, the super-hydrophobic surface of the coating can effectively delay icing and inhibit ice adhesion. According to the coating, organic combination of an active deicing strategy and a passive deicing strategy is achieved based on the synergistic effect of the super-hydrophobicity and the photothermal effect.

The invention relates to a preparation method of a core-shell fluorine-free super-hydrophobic emulsion based on acrylate pressure-sensitive adhesive viscosity. According to the method, a polyacrylate pressure-sensitive adhesive is adopted, an acrylate soft monomer and a functional monomer are copolymerized on the surface layer of the polyacrylate pressure-sensitive adhesive, and a polyacrylate copolymer with pressure-sensitive adhesiveness and reaction activity is coated to obtain a pressure-sensitive adhesive'rigid core at flexible shell 'core-shell polymer microsphere emulsion with a core-shell structure; the production process is simplified (two steps are combined into one step), and chromatic aberration is eliminated; the silane coupling agent can be used for replacing a silane coupling agent, and the problem of insufficient durability is further solved. According to the invention, the simplification and batch production of the production process can be effectively realized, and meanwhile, the requirements of modern industry on economic and green production can be met.

The invention relates to the technical field of layered composite fabrics, and discloses a light-absorbing and heat-emitting chinlon fabric, a preparation method and application of the light-absorbing and heat-emitting chinlon fabric to thermal fabrics. According to the invention, the fluorine-free and waterproof light-absorbing and heating finishing agent with excellent light-absorbing and heating performance is prepared, then the sulfydryl silane modified chinlon single-layer fabric is subjected to surface finishing by adopting the light-absorbing and heating finishing agent through sulfydryl-alkene click reaction, and the prepared light-absorbing and heating chinlon single-layer fabric is used as the surface layer fabric; the light-absorbing and heating chinlon fabric obtained by compounding the light-absorbing and heating chinlon fabric with the inner layer made of the acrylic fiber / special-shaped section chinlon blended yarn not only has excellent light-absorbing and heating performance, but also has good waterproof performance of the surface layer, good warm-keeping performance of the inner layer and good wearing comfort, and can be applied to warm-keeping fabrics.

The invention discloses a fluoride-free reinforced wear-resistant polyketone composite material as well as a preparation method and application thereof, and relates to the technical field of polymer composite materials. The fluoride-free reinforced wear-resistant polyketone composite material comprises polyketone resin, glass fibers, modified ultra-high molecular weight polyethylene, an antioxidant and a lubricant, wherein the modified ultra-high molecular weight polyethylene is obtained by modifying branched-chain-free linear polyethylene with the molecular weight of 2 million or more, and the dosage of the modifier is 1%-5% of that of the ultra-high molecular weight polyethylene. The modified ultra-high molecular weight polyethylene, the glass fiber and the polyketone resin are subjected to blending modification, and the characteristics of good wear resistance of the polyketone resin and high strength of the glass fiber are combined; meanwhile, the friction coefficient is low after the ultra-high molecular weight polyethylene is modified, the compatibility with the polyketone resin is enhanced, the dispersion is more uniform, and the heat resistance and friction performance of the polyketone resin are comprehensively improved. In addition, due to the use of fluorine-free, the safety of the polyketone composite material is improved, and meanwhile, the application market of the polyketone composite material is expanded.

The invention discloses a preparation method of a metal organic framework modified fluorine-free super-amphiphobic coating, and belongs to the technical field of super-amphiphobic coatings. According to the technical scheme, the method comprises the steps of preparation and modification of a metal organic framework and formation of a fluoride-free super-amphiphobic coating. Adding a metal oxide and nano silicon dioxide particles into a polyacrylic acid solution to form spherical particles; enabling the spherical particles to react with imidazole ligands to obtain metal organic framework particles with porous spherical structures, and wrapping nano silicon dioxide particles in the metal organic framework particles; modifying the metal organic framework particles by using a silane coupling agent; the preparation method comprises the following steps: firstly, attaching modified metal organic framework particles to the surface of a metal matrix, then attaching fluorine-free alkyl silane to the surface of the metal matrix, and heating and curing to obtain the fluorine-free super-amphiphobic coating. The fluorine-free super-amphiphobic coating is applied to the aspect of a metal surface super-amphiphobic coating, and the problems that an existing fluorine-free super-amphiphobic coating is poor in oleophobic and hydrophobic performance and poor in durability are solved.

The invention discloses a fluoride-free flotation-microbiological leaching-multistage magnetic separation synergistic tailing purification process, which takes mine tailings as raw materials and is realized by the following steps: 1, fluoride-free flotation desliming and impurity removal: replacing hydrofluoric acid with a novel anion collector (fatty acid derivative), and preferentially removing mica and feldspar under the condition that the pH is 2.5-3.5; 2, removing iron and aluminum by microbiological leaching: leaching for 48 hours at the temperature of 35 DEG C by utilizing an acidophilus bacillus ferroxidans bacterial solution, and dissolving Fe2O3 and Al2O3 in a wrapped state; 3, high-gradient magnetic separation refining: removing magnetic minerals through 1.2 T strong magnetic separation, and then separating weak magnetic impurities through 0.8 T weak magnetic separation; the indexes of the final product are as follows: the purity of SiO2 is greater than or equal to 99.9%, the whiteness is greater than or equal to 94% (ISO standard), the content of Fe2O3 is less than or equal to 80ppm, Al2O3 is less than or equal to 1200ppm, and the requirements of electronic grade (IOTA-4 standard) quartz powder are met.

The invention belongs to the technical field of coatings, and particularly relates to a fluoride-free anti-icing coating and a preparation method and application thereof.The coating comprises a component A and a component B, and the mass ratio of the component A to the component B is 100: 16.3-19.5; wherein the component A comprises the following components in parts by weight: 60-65 parts of modified acrylic resin; 1-1.5 parts of a low surface energy additive; 8 to 10 parts of nano silicon dioxide; 3-5 parts of a lubricating filler; 0.3 to 0.5 part of a dispersant; 0.5 to 1.5 parts of an adhesion promoter; 16.5 to 27.2 parts of a compound solvent; and the component B is aliphatic polyisocyanate resin. The anti-icing coating has a low surface energy hydrophobic effect and a dynamic lubricating effect, and has excellent anti-icing performance under the synergistic effect of the low surface energy hydrophobic effect and the dynamic lubricating effect.

The present disclosure relates to a fluoride-free binder material for a positive electrode, and a preparation method therefor and the use thereof. Provided are a fluoride-free binder material for a positive electrode and a preparation method therefor. A copolymer of acrylonitrile and an acrylate is used as a main body structure, an ionic monomer is introduced, and a polyfunctional olefin monomer is introduced during polymerization to increase the branching degree of a polymer, thereby preparing a highly-branched acrylonitrile polymer modified via copolymerization, which polymer is used as a fluorine-free binder material for a positive electrode. The modified binder can provide more sites for contact between active materials and between a current collector and the active materials so as to further enhance the bonding ability, thereby increasing the overall cohesive force and improving the adhesion to the current collector; and the binder can effectively inhibit the fracture and delamination of an electrode sheet during processing, ensures the compactness of a positive electrode material even in the case of a low use amount, and retains structural integrity and cycling stability during cycling.

The invention belongs to the technical field of polyurethane waterproof coatings, and particularly relates to a single-component fluorine-free high-hydrophobicity polyurethane waterproof coating and a preparation method thereof, and the single-component fluorine-free high-hydrophobicity polyurethane waterproof coating comprises the following raw materials by weight: 60-80 parts of composite polyether polyol; 20 to 40 parts of silane modified polyether polyol; 11 to 17 parts of diisocyanate; 2-5 parts of a chain extender; 50 to 70 parts of a plasticizer; 50 to 70 parts of filler; 0.15 to 0.2 part of a catalyst; and 3-5 parts of an auxiliary agent. A polyoxypentene ether chain segment, a castor oil-based structure and a silane group are introduced into the molecular structure of the waterproof coating through chemical modification, the intrinsic hydrophobic and mechanical properties of the material are improved, the migration defect caused by addition of a hydrophobic agent and silicone oil in a traditional preparation method is overcome, and the invention further provides a preparation method of the waterproof coating.

The invention discloses a polyetherketoneketone high-temperature-resistant wear-resistant non-stick coating and a preparation method thereof. The coating is prepared from the following components in parts by mass: 13 to 30 parts of a resin matrix group (containing 12 to 25 parts of titanium modified polyether ketone ketone resin, 1 to 5 parts of fluorine-free viscous resin and 0.65 to 6 parts of aluminum oxide), 0.5 to 3 parts of a nano reinforced group (containing 0.5 to 3 parts of KH-550 modified nano titanium dioxide, 0.025 to 0.6 part of cerium dioxide and 0.5 to 3 parts of boron nitride) and 62 to 71 parts of an auxiliary agent group. The preparation method comprises the following steps: 1) taking diphenyl ether, paraphthaloyl chloride and isophthaloyl chloride as monomers, and synthesizing titanium modified polyether ketone ketone resins with different viscosities through segmented polymerization (1.5-2.0 hours or 3.0-4.0 hours); 2) respectively preparing a smooth bottom layer water dispersion slurry and a wrinkled surface layer water dispersion slurry; and (3) forming a compact bottom layer and a micro-wrinkle surface layer on the base material by adopting a layered spraying and stepped sintering process (280-320 DEG C, 10-20 minutes). The whole system of the coating is fluorine-free and has temperature resistance gt; the coating has the characteristics of high temperature resistance (350DEG C), wear resistance (Taber wear rate of 3-5mg / 1000r), non-sticking (contact angle gt, 100 DEG C) and heavy corrosion resistance, and is suitable for cooking utensils and chemical equipment.

The invention discloses a long-chain alkyl acrylate polymer dispersion liquid which is composed of a long-chain alkyl acrylate polymer, alcoholic hydroxyl-terminated long-chain alkyl silicone oil, a surfactant, a cosolvent and water. The long-chain alkyl acrylate polymer at least comprises a long-chain alkyl acrylate monomer unit and a monomer unit containing an active hydroxyl group; and the alcoholic hydroxyl-terminated long-chain alkyl silicone oil accounts for 15-40% of the total mass of the long-chain alkyl acrylate polymer and the alcoholic hydroxyl-terminated long-chain alkyl silicone oil. The fluorine-free fabric finishing agent dispersion liquid is good in stability and excellent in continuous processing performance when waterproof processing is carried out on fabrics, and the fabrics treated by the fluorine-free fabric finishing agent dispersion liquid are excellent in waterproof performance and good in washability.

The invention relates to a method for preparing a KFI molecular sieve membrane by utilizing a secondary growth method, in particular to a method for preparing the KFI molecular sieve membrane through rapid induction under the conditions of no template agent, no fluorine medium and no heavy metal. According to the method for preparing the KFI molecular sieve membrane by adopting the seed crystal method under the condition of not using a template agent, fluoride and noble metal ions, the membrane synthesis time and the membrane application cost can be remarkably reduced, and the industrial application of the KFI molecular sieve membrane is promoted.

The invention discloses a preparation method of fluorine-free hydrolysis-resistant knurling polyurethane synthetic leather, which comprises the following steps: preparing wet-process polyurethane resin for leather by adopting PTMG (polytetramethylene glycol) with proper polymerization degree as a chain extender through a pre-polymerization process, preparing soft hydrolysis-resistant wet-process polyurethane resin by adopting bio-based poly-farnesyl alcohol as a main raw material through an insufficient method, and preparing the fluorine-free hydrolysis-resistant knurling polyurethane synthetic leather by adopting a high-temperature-resistant wet-process polyurethane resin. The two components are matched to optimize and balance the embossing performance and the thickness retention rate, the finally obtained soft hydrolysis-resistant polyurethane synthetic leather product is soft and glutinous in hand feeling and good in hydrolysis resistance, the thickness reaches the standard, and embossing is clear and does not rebound; a fluorine-containing water repellent does not need to be added, and the method is simple in process, low in cost and energy consumption and excellent in product performance.

The invention relates to the field of food packaging and coatings, and provides a bio-based fluoride-free environment-friendly oil-proof agent for food packaging paper and paperboards, which is simple in preparation process, green and environment-friendly and has the bio-based raw material proportion of 70% or above. The bio-based fluoride-free environment-friendly oil-proof agent is characterized in that the bio-based fluoride-free environment-friendly oil-proof agent is prepared by synergistic micro-nanocrystallization of paper pulp fibers, starch and inorganic particles under the action of high-speed shearing and grinding; the prepared oil-proof agent can be coated on the surfaces of sized or unsized paper, paperboards and paper pulp molded products by a conventional coating method, the coated finished product has good oil-proof performance, the coating weight is 1.5-15g / m < 2 >, and the oil-proof grade tested by a Kit method after drying can reach 12 grade to the maximum. Compared with a fluoride-free oil-proof agent on the market at present, the bio-based fluoride-free environment-friendly oil-proof agent disclosed by the invention can obtain good oil-proof performance under a relatively low coating weight, is biodegradable and is easy to recycle and reuse.

The invention relates to the technical field of finishing agents, and discloses a fluoride-free leather water-repellent finishing agent and a preparation process thereof. The preparation method comprises the following steps: reacting hydrogen-containing silicone oil, N-methylallylamino hydroxypropyl alkane and a bromoalkane monomer to obtain hydroxyl quaternary ammonium salt silicone oil; the fluorine-free leather water-repellent finishing agent contains hydrophobic silicone oil and a plurality of alkyl long carbon chains, and the hydrophobic silicone oil and the alkyl long carbon chains are introduced into a polyurethane molecular chain through a polymerization chain extension reaction, so that the hydrophobic and water-repellent properties of the polyurethane finishing agent and the leather are remarkably improved, and the water-repellent property of the leather is improved. And the hydroxyl quaternary ammonium salt silicone oil contains an organosilane quaternary ammonium salt antibacterial group which is introduced into a polyurethane molecular chain, so that the finishing agent and the leather are endowed with excellent antibacterial performance.

The invention discloses a method for recovering high-purity fluorine and silicon from fluorine-silicon slag and co-producing a low-alkali fluorine-free accelerator, which comprises the following steps: S1, dissolving the fluorine-silicon slag in a sodium hydroxide solution to obtain a solution A; s2, adding dilute sulphuric acid into the solution A, reacting until gel is obtained, and filtering to obtain filtrate A and high-purity silicon dioxide gel; s3, adding calcium sulfate and EDTA (Ethylene Diamine Tetraacetic Acid) into the filtrate A, stirring and reacting, and filtering after the reaction is finished to obtain calcium fluoride and filtrate B; and S4, taking clear water, heating, carrying out heat preservation, then adding aluminum sulfate, lithium sulfate, diethanol amine and the filtrate B obtained in S3, continuously stirring until the aluminum sulfate is completely dissolved, then adding hydrated magnesium silicate, continuously carrying out heat preservation stirring, and obtaining the low-alkali fluorine-free accelerator after stirring is finished. The method is simple in process and easy to implement industrially, and fluoride and silicon oxide obtained through separation are high in purity and beneficial to follow-up extension application; more importantly, high-value recycling of the fluorosilicon slag is achieved, and the problems of stockpiling waste and environmental pollution of the fluorosilicon slag are solved.

The invention discloses a fluoride-free gel foam extinguishing agent and a preparation method thereof. The fluoride-free gel foam extinguishing agent is composed of a composite foaming agent, a composite gelling agent, a cross-linking agent, a flame retardant and water. The weight percentage of each component is as follows: 0.1-3% of the composite foaming agent, 0.1-5% of the composite gelling agent, 0.1-1% of the cross-linking agent, 3-5% of the flame retardant and the balance of water. The preparation method of the fluoride-free gel foam extinguishing agent comprises the following steps: S1, preparing the foam component; s2, preparing a gel component; and S3, the foam component and the gel component are mixed and stirred to be uniform, the mixture is poured into a foaming device to be subjected to foaming operation, and then the fluoride-free gel foam extinguishing agent is obtained. The konjaku flour and the xanthan gum in the fire extinguishing agent have a cross-linking effect with aluminum citrate to form a stable three-dimensional cross-linked network structure, so that the stability and the water retention capacity of foam are improved, a good synergistic effect is achieved, and the fire extinguishing effect is enhanced.

The invention discloses a self-repairing chromium-free passivator, a preparation method thereof and application of the passivator in the field of corrosion prevention of alloy workpieces. The passivating agent is composed of a bifunctional silane coupling agent, a fluoride-free inorganic film-forming agent, an organic film-forming agent, a corrosion inhibition synergistic system, a nano-composite reinforcing system, self-repairing microcapsules, an anti-biological adhesion component and a functional auxiliary agent. The problems that an existing passivating agent contains chromium or fluorine, environmental protection risks exist, the self-repairing function is lost, a base material is corroded, and the process efficiency is low are solved. The passivating agent is free of chromium and fluorine, the adhesive force of the passivating agent and a zincizing / multi-component alloy co-permeation layer is larger than or equal to 7 MPa, the neutral salt mist resistance is larger than or equal to 1700 h, the self-repairing efficiency after a film layer is damaged is larger than or equal to 85%, the single-batch period of the preparation technology is smaller than 1 h, and the passivating agent is suitable for large-scale application in severe scenes such as railways and oceans.

The invention belongs to the technical field of new energy batteries, and particularly relates to a fluorine-doped graphdiyne material and a preparation method and application thereof. The preparation method of the fluorine-doped graphdiyne material comprises the following steps: in a solvent system, mixing graphdiyne and a solid fluorine source, and drying to obtain a composite precursor; under the protective atmosphere, the composite precursor is annealed, so that the fluorine source is decomposed to release hydrogen fluoride and fluorine free radicals, the hydrogen fluoride or the fluorine free radicals are combined with carbon sites on graphdiyne through nucleophilic substitution, C-F bonds are formed, and the fluorine-doped graphdiyne material is obtained; the mass ratio of graphdiyne to the solid fluorine source is 30: (1-4). The fluorine-doped graphdiyne has the advantages that the defects are increased, the disorder is reduced, and the lithium storage capacity of the graphdiyne is improved, so that the long-term cycle performance and the high-rate performance are improved.

The invention discloses a high-temperature-resistant anti-adhesion superhard transparent fluorine-free green organic silicon coating and a preparation method thereof, and belongs to the technical field of organic silicon coatings. According to the invention, methyltrimethoxysilane, silica sol, hydroxyl silicone oil, isopropanol and water are used as raw materials to prepare a high-temperature-resistant anti-adhesion superhard transparent fluorine-free green organic silicon coating, and a design strategy of manufacturing a nanoscale polysiloxane coating through an organic silicon precursor controllable sol-gel hydrolysis process is adopted. According to the present invention, the coating with the matrix completely composed of the in-situ generated nano SiO2 particles is prepared, the defect minimization and the highly-crosslinked Si-O-Si network structure are achieved, the nano-scale inorganic structure has long-term thermal stability, and the visible light transmittance of the coating can achieve 98% due to the inhibition of the light scattering by the sub-wavelength particle size; and tiny nano particles are uniformly and tightly arranged on the surface of the coating, so that the coating is endowed with ultrahigh hardness. In addition, the coating still maintains the inherent antifouling property of the organic silicon coating.

The application provides a wear-resistant transparent flexible fluorine-free super-hydrophobic composite coating and a preparation method thereof. The preparation method comprises the following steps: mixing and reacting hydroxyl-terminated polydimethylsiloxane, gamma-aminopropyl triethoxysilane and dibutyl tin dilaurate to obtain a modified precursor solution, adding swelled epoxy resin into the modified precursor solution, and obtaining a siloxane modified epoxy resin after heating reaction; dispersing nano-silicon dioxide in an ethyl acetate solution to form a SiO2 suspension; uniformly mixing the modified epoxy resin and the SiO2 suspension, adding polyether amine as a curing agent, and stirring and mixing, and then adopting an air spraying mode to build an epoxy resin / hydroxyl-terminated polydimethylsiloxane / nano-silicon dioxide super-hydrophobic coating on a substrate. The preparation method can prepare a super-hydrophobic coating with excellent transparency and flexibility, good adhesion and wear resistance, and has a wide application prospect in the fields of wearable electronic devices and optoelectronic devices.

The invention relates to the technical field of textile functional finishing agents, and discloses a low-temperature forming soft-handfeel polyurethane fluoride-free fabric waterproof agent as well as a preparation method and application thereof. The polyurethane fluoride-free fabric waterproof agent is prepared from the following components in percentage by mass: 10 to 20 percent of polyurethane polymer, 2 to 10 percent of polyurethane modified organic silicon, 10 to 20 percent of solvent, 2 to 5 percent of organic cosolvent, 1 to 5 percent of emulsifier, 50 to 70 percent of deionized water and 0.2 to 1 percent of pH regulator. The polyurethane fluoride-free waterproof agent is mainly applied to fabric treatment, can be formed at a low temperature, and has the advantages of good water repellency, low hand scratch, soft hand feeling, high coating stripping performance and the like.

The invention discloses silicon-free fluorine-free hydrophobic bactericidal water-based polyacrylic resin as well as a preparation method and application thereof, and belongs to the technical field of water-based functional polymer coating materials. The resin is prepared from the following raw materials: deionized water, a non-special acrylic functional monomer component, a special acrylic functional monomer component, a polyvinyl alcohol modified nano zinc oxide component, an emulsifier component and an initiator component. On the basis of a'molecular bridge crosslinking-nanostructure coupling 'strategy, 1, 6-hexanediol diacrylate of a hydrophobic long alkyl chain is introduced into polyacrylic resin containing a tert-butyl chain to construct a crosslinking molecular bridge, so that synergistic hydrophobicity of tert-butyl and long-chain alkyl is promoted, and meanwhile, a polyvinyl alcohol modified nano zinc oxide component is designed and introduced; the efficient integration of hydrophobic barrier and antibacterial site functions is synergistically realized, a more environment-friendly multifunctional solution is provided for the field of functional finishing and protection of textiles such as medical protection, outdoor sports and household textiles, and the application prospect is wide.

An over-current protection device comprises first and second electrode layers and a PTC material layer laminated therebetween. The PTC material layer includes a polymer matrix, a conductive filler and a titanium-containing inner filler. The polymer matrix has a fluorine-free polyolefin-based polymer. The titanium-containing inner filler has a compound represented by a general formula of MTiO3, wherein the M represents transition metal or alkaline earth metal. The total volume of the PTC material layer is calculated as 100%, and the titanium-containing inner filler accounts for 1-9% by volume of the PTC material layer.

The invention discloses a preparation method and application of lithium ion battery positive electrode slurry based on a fluoride-free binder. The positive electrode material comprises the following components in parts by mass: 100 parts of a positive electrode active material, 0.5-5 parts of a fluoride-free binder, 2-5 parts of a conductive agent and the balance of a solvent N-methyl pyrrolidone NMP. The fluorine-free binder is composed of HNBR (hydrogenated nitrile butadiene rubber) and PAA (polyacrylic acid), and the molecular structure does not contain fluorine, so that on one hand, environmental pollution can be reduced; on the other hand, through composite use of PAA and HNBR, the problem of breakage of a pole piece when PAA is singly used as a positive electrode binder and the problem of poor stability of positive electrode paste when HNBR is singly used as the positive electrode binder can be solved; in addition, carboxyl in PAA can form a CEI film on the surface of the positive electrode to protect the electrode, cyano in HNBR can endow the binder with high chemical stability, and the cyclic stability of the battery can be improved by using PAA and HNBR at the same time.

The invention relates to a method for operating an electrolysis plant (1, 20) comprising an electrolyzer (11) for generating hydrogen (H2) and oxygen (O2) as product gases. Water is supplied as a reactant and is split into hydrogen (H2) and oxygen (O2) on a proton-conducting membrane (21) made of a fluorine-free polymer (24), said polymer (24) comprising a non-functional polymer material having a functional hydrophilic group, wherein a product gas flow (5) is formed in a phase mixture comprising water (H2O) and a respective product gas, and a product gas flow is fed to a gas separator (3, 13) connected downstream of the electrolyzer (11). The release of an ionic decomposition product of the functional hydrophilic group of the membrane (21) is determined over the operating time, the time curve of the concentration of said decomposition product is determined, and a measurement of the operational degradation of the proton-conducting membrane (21) as a result of a release of the ionic decomposition product of the hydrophilic group is determined. The invention additionally relates to a corresponding electrolysis plant (1, 20) and to a measuring system for carrying out the method.

The invention relates to the field of shirt fabrics, and discloses a novel antistatic and breathable wool worsted shirt fabric and a production method of the novel antistatic and breathable wool worsted shirt fabric. Comprising the following raw materials in parts by weight: 45-55 parts of wool fibers, 5-8 parts of graphene modified polyester fibers, 1-2 parts of carbon nanotube modified wool, 8-12 parts of hemp fibers, 3-5 parts of aerogel polyamide fibers, 1-2 parts of silver zeolite composite particles, 10-15 parts of chitosan quaternary ammonium salt viscose fibers, 2-3 parts of a fluoride-free super-hydrophobic nano coating (o.w.f) and 5-10 parts of sulfobetaine modified polyamide. The graphene modified polyester fiber and the carbon nanotube modified wool are mixed, a continuous and stable conductive network is formed in the fabric by utilizing high conductivity of graphene and excellent electron transmission capability of carbon nanotubes, charge accumulation is reduced essentially, and uniform distribution of the conductive fiber is ensured by adopting a siro spinning technology.

A polymer processing aid (PPA) reduces melt defects in extruded polyolefins in the absence of fluoropolymers. A polymer processing aid comprising a block copolymer having polyamide blocks and polyether blocks reduces melt defects well in a thermoplastic polyolefin such as a linear low density polyethylene (LLDPE). Inclusion of an adjuvant PPA comprised of polycaprolactone, or polycaprolactone diol polymer further improves the melt fracture behavior in a thermoplastic and in the absence of fluoropolymers.