This invention relates to a method for desiliconizing
green liquor in
papermaking, belonging to the field of
papermaking pulping chemical regeneration technology. This method aims to solve the technical problem in existing technologies where direct
carbon dioxide is introduced into
green liquor for desiliconization, resulting in the formation of colloids from the generated
silicic acid, making subsequent
solid-liquid separation difficult. The key points of the technical solution are: first,
solid-liquid separation of the
green liquor is performed to obtain a clear green liquor; then, white mud
slurry is added to the clear liquor as seed crystals, and
carbon dioxide gas is introduced to carry out a
carbonization reaction, generating an easily separable
silicon-containing suspension; next,
solid-liquid separation is performed on the
silicon-containing suspension to obtain a
silicon-containing
filter cake and a causticizing
mother liquor; finally,
calcium hydroxide is added to the causticizing
mother liquor to carry out a causticizing reaction, obtaining
white liquor and recyclable white mud
slurry. This method is mainly applied to the desiliconization and purification of green liquor during the alkali
recovery process in
papermaking, and can utilize
carbon dioxide in industrial
flue gas to achieve carbon
resource utilization; the separated silicon-containing
filter cake can be further processed into activated
calcium silicate products.