1541 results about "Aluminium hydroxide" patented technology

The invention discloses a process and system for recovering phosphorus and fluorine from ardealite leachate, which comprises the following steps: feeding the ardealite leachate into an induced crystallization reactor for induced crystallization, discharging generated large-particle fluorapatite crystals from a crystal discharge port at the bottom of the induced crystallization reactor, and collecting and recycling; aluminum hydroxide flocs and fine-particle fluorapatite crystals enter a cyclone separator along with the effluent, the fine-particle fluorapatite crystals are separated and then flow back to the induced crystallization reactor, the aluminum hydroxide flocs form precipitates in the flocculation sedimentation tank through flocculation to be removed, and the effluent of the flocculation sedimentation tank enters a multi-stage treatment system. According to the method disclosed by the invention, fluorine and phosphorus in the phosphogypsum leachate are recovered together, the recovered fluorapatite finished product is high in purity and can be recycled, and the amount of chemical sludge is also greatly reduced, so that the treatment cost of the sludge is reduced.

The invention relates to the technical field of cables, and provides a fireproof flame-retardant 10kV power cable and a preparation method thereof. The fire-resistant flame-retardant 10kV power cable comprises a conductor and a fire-resistant flame-retardant layer, the fireproof flame-retardant layer is prepared from the following raw materials in parts by weight: 35 to 45 parts of linear low-density polyethylene, 40 to 50 parts of ethylene-vinyl acetate copolymer, 25 to 30 parts of modified aluminum hydroxide, 5 to 8 parts of polyethylene grafted maleic anhydride, 10 to 12 parts of phosphate modified halloysite nanotube, 5 to 8 parts of ZIF-8 loaded zinc borate core-shell particles, 15 to 20 parts of magnesium hydroxide and 2 to 3 parts of silane coupling agent. 0.5 to 1 part of antioxidant, 0.5 to 1 part of calcium stearate and 1 to 1.5 parts of polyethylene wax. According to the cable prepared in the invention, the situation that a conductor is exposed and the fire resistance is lost due to cracking and falling under long-time high-temperature baking is avoided; the continuous effectiveness of the flame retardant at high temperature is improved.

The invention provides a tear-resistant, wear-resistant, low-smoke and non-dripping sheath material as well as a preparation method and application thereof. The tear-resistant wear-resistant low-smoke non-dripping sheath material is prepared from the following components in parts by weight: 25 to 35 parts of metallocene linear low-density polyethylene, 10 to 15 parts of ethylene-vinyl acetate copolymer, 6 to 8 parts of compatilizer, 50 to 60 parts of aluminum hydroxide, 10 to 15 parts of magnesium hydroxide, 3 to 4 parts of microencapsulated red phosphorus, 5 to 8 parts of lithium oxide synergist, 4 to 6 parts of silicone master batch, 0.3 to 0.7 part of carbon black master batch and 1.5 to 2.5 parts of coupling agent. The tear-resistant wear-resistant low-smoke non-dripping sheath material provided by the invention has the characteristics of being halogen-free, flame-retardant, tear-resistant and wear-resistant, and a low-smoke halogen-free flame-retardant power cable prepared from the sheath material has the characteristics of high smoke light transmittance during combustion, no dripping and cracking resistance.

The invention discloses an environment-friendly high-strength water-stop belt and a preparation method thereof, and relates to the technical field of high-molecular compound composition water-stop belts. The environment-friendly high-strength water-stop belt is prepared from the following components in parts by mass: 100 parts of ethylene propylene diene monomer, 40 to 70 parts of reinforcing filler, 10 to 25 parts of environment-friendly plasticizer, 1 to 5 parts of interface modifier, 1.5 to 3.5 parts of vulcanizing agent, 3 to 8 parts of active agent, 1 to 3 parts of anti-aging agent and 5 to 15 parts of flame retardant. White carbon black and calcium carbonate are adopted as reinforcing filler to replace traditional carbon black, and energy consumption and pollution emission in the production process are remarkably reduced. By optimizing the formula and the preparation process, the tensile strength, the elongation at break, the tearing strength and other mechanical properties of the waterstop are remarkably improved. Aluminum hydroxide is added as a flame retardant, absorbs heat during thermal decomposition and forms a barrier layer, so that oxygen is effectively diluted, and fire spreading is prevented.

The invention discloses a PA6 nylon composite material for a high-temperature-resistant filter screen and a preparation method of the PA6 nylon composite material, and relates to the technical field of composite materials. The invention discloses a PA6 nylon composite material for a high-temperature-resistant filter screen. The nylon material is prepared from the following raw materials in parts by weight: 60 to 80 parts of modified PA6 nylon, 10 to 20 parts of modified glass fiber, 2 to 5 parts of montmorillonite, 0.3 to 0.8 part of antioxidant 1010, 0.2 to 0.6 part of stearic acid, 0.5 to 1.0 part of ethoxylated fatty amine, 1 to 3 parts of nano titanium dioxide, 1 to 3 parts of polytetrafluoroethylene micro powder, 3 to 8 parts of aluminum hydroxide, 0.5 to 1.5 parts of chitosan, 1 to 3 parts of hyperbranched polyamide and 0.5 to 1.5 parts of urea-formaldehyde resin coated epoxy resin microcapsules. And 0.3 to 0.8 part of sodium polyacrylate. The PA6 nylon composite material for the high-temperature-resistant filter screen has remarkable advantages. The material disclosed by the invention is high in mechanical property, good in thermal stability and stable in size at high temperature; the self-cleaning, antibacterial and antistatic functions are realized, and the filtering efficiency is high; chemical corrosion resistance, wear resistance and low water absorption are achieved; part of the raw materials can be recycled, the environmental protection concept is met, and the use requirement of the high-temperature-resistant filter screen in a complex environment can be met.

The invention discloses an anti-aging water-stop belt and a preparation method and application thereof, and relates to the technical field of water-stop belts. The invention relates to an anti-aging water-stop belt which is prepared from the following raw materials in parts by mass: 40-60 parts of chloroprene rubber, 10-20 parts of natural rubber, 10-20 parts of ethylene propylene diene monomer, 15-30 parts of carbon black, 5-15 parts of white carbon black, 5-15 parts of a plasticizer, 0.5-2 parts of sulfur, 0.5-1.5 parts of an accelerant, 1-2 parts of an anti-aging ultraviolet light absorber, 5-15 parts of aluminum hydroxide, 1-3 parts of stearic acid and 3-8 parts of zinc oxide. The obtained water-stop belt has excellent ultraviolet aging resistance, ozone resistance and chemical corrosion resistance while keeping high elasticity, the mechanical stability of the water-stop belt is remarkably improved compared with that of a traditional product, the water-stop belt is suitable for joint sealing in harsh environments such as bridges, tunnels and water conservancy projects, and the waterproof service life of engineering structures can be effectively prolonged.

The invention discloses an environment-friendly flame-retardant medium-voltage cable, and relates to the technical field of cables, the outer side of an inner conductor is provided with a flame-retardant protection assembly, the flame-retardant protection assembly comprises flame-retardant filling bodies, the middle parts of the opposite side surfaces of the adjacent flame-retardant filling bodies are provided with supporting grooves, and arc-shaped spring plates are adhered to the interiors of the supporting grooves. The outer side of the cable is extruded and collided, the impact force is attenuated layer by layer, the situation that the cable is damaged due to collision and impact is reduced, when the outer side of the cable is frozen, the heating wire emits heat, and the cable is prevented from being damaged. When the cable is deiced, the inflatable strip outside the insulating middle layer is uniformly heated, the outer insulating layer is pushed to bulge, and the ice layer outside is jacked open, so that the ice layer is broken and falls off, and compared with the conventional deicing method which only depends on heating, the energy consumption is lower, the cable is environment-friendly and energy-saving, the deicing effect is better, and the cable is more favorably protected.

The invention relates to the technical field of insulating materials, in particular to insulating powder and a preparation method thereof. The invention discloses a flame-retardant coating which comprises the following components in parts by weight: 15-25 parts of epoxy resin, 10-20 parts of aluminum hydroxide, 5-12 parts of nano boron nitride, 1-3 parts of a silane coupling agent KH-560, 3-8 parts of polytetrafluoroethylene micro powder, 2-6 parts of fluorine-modified montmorillonite, 4-9 parts of melamine cyanurate, 2-5 parts of nano titanium dioxide, 1-4 parts of a fluorine-modified graphene oxide-polyaniline composite material and 0.5-2 parts of pentaerythritol stearate. The anti-corrosion coating is prepared from the following components in parts by weight: 1 to 3 parts of nano zinc oxide, 5 to 10 parts of glass fiber, 2 to 5 parts of polyhedral oligomeric silsesquioxane-polyimide copolymer, 1 to 4 parts of ferrocenyl epoxy resin and 0.5 to 2 parts of perfluorooctyltriethoxysilane. The insulation powder is high in corrosion resistance, excellent in insulation, heat dissipation and mechanical performance, environmentally friendly in processing, good in adaptability, capable of prolonging the service life of equipment and reducing the cost, suitable for special environments and wide in popularization prospect.

The invention discloses a preparation method of a high-adsorbability aluminum hydroxide adjuvant for livestock, which comprises the following steps: when an aluminum chloride solution reacts with alkali liquor, generating a colloidal suspension by combining pH two-step adjustment with dispersant addition; and after instant high-speed shearing and room-temperature aging, performing ultrafiltration purification to remove salts, and finally performing moist heat sterilization to obtain the suspension morphological adjuvant. The adjuvant is high in antigen adsorption rate, low in 72-hour desorption rate, large in specific surface area, uniform in particle and suitable for vaccines of pigs, cattle and poultry, and the problems that a traditional adjuvant is low in adsorption rate and poor in stability are solved.

The invention belongs to an aluminum fluoride production technology, and particularly relates to a process and a system for producing aluminum fluoride by matching with a low-grade fluorite dry method, fluorite powder and sulfuric acid are added into a pre-reactor to be uniformly mixed and then are guided into a reaction furnace to be heated, and when the reaction furnace rotates, a free spiral structure in the reaction furnace rotates to promote the reaction of the fluorite and the sulfuric acid; discharging the calcium sulfate through a discharging spoon at the discharging end of the reaction furnace, and collecting the hydrogen fluoride volatilized from the reaction furnace; volatilized hydrogen fluoride enters a pre-purification tower and is treated to obtain purified hydrogen fluoride gas, the purified hydrogen fluoride gas and dried aluminum hydroxide are added into a fluidized bed to react to obtain aluminum fluoride and tail gas, and the tail gas enters a tail gas recovery treatment system. The problems that low-grade fluorite is poor in resource utilization rate, prone to crusting in a reaction furnace, low in fluorine utilization rate and the like are solved.

The invention discloses a perfluorohexanone fire extinguishing agent and a preparation method and application thereof.The perfluorohexanone fire extinguishing agent is prepared from, by mass, 60-70 parts of perfluorohexanone microcapsules, 10-20 parts of aluminum hydroxide, 6-10 parts of graphite, 5-10 parts of titanium dioxide, 4-8 parts of ultraviolet absorbent, 2-6 parts of ammonium polyphosphate, 3-6 parts of calcium oxide, 1-3 parts of fumed silica, 1-3 parts of nano-silica and 1-3 parts of trimethyl phosphate. According to the formula and process of the fire extinguishing agent, through triple technical innovation of shell layer modification, nano compounding and supercritical deposition, the breakthrough of efficient explosion suppression, long-acting anti-after-combustion, low toxicity and environment friendliness of the fire extinguishing agent is achieved, and the industrial popularization potential is achieved.

The invention relates to the technical field of vaccine adjuvants, and particularly discloses a preparation method of a nanoscale aluminum hydroxide adjuvant based on organic metal alkoxide hydrolysis. Aluminum isopropoxide is used as a precursor, and a hydrolysis interface is directionally regulated and controlled through a compound surfactant; a staged hydrolysis process is adopted, and a kinetic equation is met; and the surface is modified by a KH-550 coupling agent. According to the preparation method disclosed by the invention, boehmite phase crystallization, nanoscale uniformity and high antigen adsorption stability are synchronously realized at low temperature through alcoholate hydrolysis bond energy reconstruction, surface activity compounding interface regulation and control and staged kinetic control, and the bottlenecks of high temperature, high energy consumption and non-uniform particle size of a traditional process are overturned; and a novel industrial scheme with low consumption and high efficiency is provided for vaccine adjuvants.

Disclosed in the present invention are a 90°C thermoplastic halogen-free low-smoke flame-retardant polyolefin sheath material and a preparation method therefor. The sheath material is prepared from raw materials comprising the following components in parts by mass: 20-40 parts of an ethylene-vinyl acetate copolymer, 20-40 parts of a linear low-density polyethylene, 2-10 parts of a high-density polyethylene, 20-40 parts of a metallocene ethylene-octylene copolymer, 10-15 parts of a maleic-anhydride-grafted metallocene linear low-density polyethylene copolymer, 58-73 parts of aluminum hydroxide, 20-25 parts of modified magnesium hydroxide, 64-84 parts of a synergistic flame retardant, 2-3 parts of a coupling agent, 1-4 parts of a lubricant, 1-3 parts of an antioxidant, and 2-7 parts of a coloring agent, wherein the synergistic flame retardant comprises lithium oxide. A matrix resin has low-temperature performance, mechanical properties and cracking resistance. With regard to flame retardance, a large amount of the synergistic flame retardant, i.e., lithium oxide, is added to a traditional magnesium-aluminum compound flame-retardant system, and therefore an off-white hard shell can be formed during a combustion process while low heat release is ensured, thereby ensuring no dripping during the combustion process.

The invention discloses a heat-proof skirt which is of a single-layer or multi-layer structure, each single-layer material is formed by compositing quartz fiber cloth and coating when multiple layers are arranged, the heat-proof skirt is made of 6-8 single-layer materials, and the skirt edge is in a wave shape. The coating is prepared from the following raw materials in parts by weight: 4 to 6 parts of vinyl polysiloxane, 15 to 20 parts of hydrogen-containing silicone oil, 15 to 20 parts of ammonium polyphosphate, 10 to 15 parts of aluminum hydroxide, 5 to 8 parts of silicon dioxide, 0.005 to 0.02 part of a platinum catalyst and 30 to 40 parts of a solvent. The heat-proof skirt has contractility, and the influence on normal swinging resistance of the engine is reduced to the maximum extent.

The preparation method comprises the following steps: S1, uniformly mixing aluminum hydroxide dry glue powder, silica sol and an extrusion aid, then adding deionized water and nitric acid for mixing and kneading, and after caragana microphylla is formed, drying and roasting to obtain an aluminum oxide-silicon oxide composite carrier; s2, putting the carrier into a modification solution, and performing modification treatment in a high-pressure reaction kettle to obtain a modified aluminum oxide-silicon oxide composite carrier; and S3, preparing a precursor containing metals Mo, Co and Re into an impregnation liquid, adding L-asparaginic acid into the impregnation liquid, impregnating the modified alumina-silicon oxide composite carrier in the impregnation liquid, drying, and roasting to obtain the catalyst. The catalyst prepared by the method has high hydrodenitrogenation performance and metal capacity and long service life.

The invention belongs to the technical field of inorganic powder material modification, and discloses an aluminum hydroxide powder modification treatment method which comprises the following steps: step 1, plasma pretreatment, step 2, in-situ coordination reaction, step 3, nano-composite coating and step 4, post-treatment. The performance of aluminum hydroxide is remarkably improved through a plasma pretreatment-in-situ coordination-nano coating synergistic process, specifically, surface hydroxyl groups are reduced by 45% through plasma treatment, and a contact angle is larger than or equal to 120 degrees, the thermal decomposition temperature is increased by 55 DEG C, and LOI is increased to 31.8% by combining Al-O-P bonding and a SiO-GQDs composite coating layer. According to the process, the energy consumption of the pulse plasma is reduced by 40%, the cost of the spray drying coating process is reduced by 60%, and the GQDs are derived from the graphite waste, so that resource circulation is realized; and the material is non-toxic, has no stripping on a cold-hot cycle interface, meets the green flame-retardant standard, and provides an efficient solution for sustainable development of inorganic fillers.

The invention discloses a process for treating nickel wastewater containing nickel acetate cleaning water and nickel acetate concentrated water, which comprises the following steps: S1, filtering nickel wastewater, S2, carrying out primary concentration treatment, S3, carrying out secondary concentration treatment, S4, treating by a sodium metaaluminate method, S5, carrying out collaborative filtration treatment, and S6, discharging RO (Reverse Osmosis) produced water up to the standard. The method comprises the following steps: primarily enriching nickel ions by adopting primary nickel concentration treatment and secondary nickel concentration treatment, adding a sodium metaaluminate solution into a mixed solution, enabling the pH value of the mixed solution to be 8-12, enabling the nickel ions to react with hydroxyl ions to generate a nickel hydroxide precipitate, adding a sulfuric acid solution to adjust the pH value of the mixed solution back to 6.5-7.5, hydrolyzing sodium metaaluminate to generate an aluminum hydroxide precipitate, and carrying out secondary nickel concentration treatment on the aluminum hydroxide precipitate; aluminum hydroxide adsorbs nickel hydroxide to form a composite precipitate, aluminum ions and nickel ions are subjected to a competitive complexation reaction, and a flocculating agent is added into a mixed solution to form a flocculent precipitate, so that the reaction time is short, the nickel content in the nickel sludge can be greatly increased, the treatment period can be shortened, and the operation cost can be reduced.

The invention relates to the technical field of refractory materials, in particular to a refractory composite material for a roller support and a preparation method of the refractory composite material. The material comprises the following components: high-crystallinity co-polypropylene, a phosphorus-nitrogen-silicon ternary synergistic flame retardant, an expanded graphite-manganese series interlayer compound, mesoporous aluminum hydroxide, a ternary magnesium-aluminum-silicon layered composite material, temperature-responsive core-shell structure cerium oxide nanoparticles and the like. Through a multi-synergistic flame-retardant mechanism and a multi-scale structural design, excellent flame-retardant performance, mechanical performance and thermal stability are achieved, the material is particularly suitable for a roller support in a high-temperature industrial environment, and the problem that a traditional material is prone to failure in the high-temperature environment is solved.

The invention discloses a fluoride-salt-free and nitrate-free cast iron enamel zirconium white glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The zirconium white glaze is prepared from quartz, borax pentahydrate, magnesium carbonate, potassium carbonate, potassium feldspar, zinc oxide, aluminum hydroxide, calcium carbonate, zirconium silicate, sodium tripolyphosphate and lithium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The zirconium white glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, and meanwhile, the zirconium white glaze has good porcelain surface, luster and firing adaptability, is suitable for cast iron matrixes, has the firing temperature of 740-760 DEG C and the firing time of 87-87 hours, and can be widely applied to cast iron substrates. The method can be used for producing green and environment-friendly enamel products.

The invention relates to the technical field of fireproof cables, and provides an aluminum alloy core fireproof cable and a preparation process thereof. An aluminum alloy core fireproof cable comprises a conductor, an insulating layer, a filling layer, a bundling heat insulation layer, an isolation layer, a fireproof layer and a sheath layer which are sequentially arranged from inside to outside, and the sheath layer comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride, 10-15 parts of a plasticizer, 10-15 parts of an ethylene-vinyl acetate copolymer, 25-30 parts of a flame retardant, 0.5-1.5 parts of an antioxidant, 10-20 parts of a filler and 0.5-1 part of a lubricant. The preparation method of the flame retardant comprises the following steps: mixing calcium oxide, magnesium oxide and zinc oxide, carrying out solid solution annealing to obtain a solid solution, and mixing the solid solution with aluminum hydroxide, ammonium polyphosphate and a metal acetylacetonate complex to obtain the flame retardant. According to the technical scheme, the problem of insufficient flame retardant property of the fireproof cable in the prior art is solved.

The invention provides a high-sealing-performance flame-retardant composite film and a preparation method thereof, and belongs to the technical field of composite film material preparation, the high-sealing-performance flame-retardant composite film comprises an outer layer, a middle layer, a transition layer and an inner sealing layer which are sequentially stacked, the material of the middle layer comprises a polypropylene matrix, modified aluminum hydroxide and zinc borate, the material of the transition layer comprises epoxy resin and nano silicon carbide, and the material of the inner sealing layer comprises ethylene-vinyl acetate copolymer and maleic anhydride grafted polyethylene; the flame-retardant PET also contains 12 to 20 weight percent of phosphorus-nitrogen synergistic flame retardant; the outer layer and the middle layer are combined in a physical entanglement mode, and the transition layer and the inner sealing layer are combined in a chemical crosslinking mode. The high-sealing-performance flame-retardant composite film provided by the invention has excellent flame-retardant performance and sealing performance, and is suitable for packaging of new energy automobile batteries and high-end electronic equipment.

The invention discloses a hydrotalcite precursor calcium-based material as well as a preparation method and application thereof. The method comprises the following steps: taking calcium hydroxide and aluminum hydroxide as a calcium source and an aluminum source, and performing constant-temperature water bath and phase transformation in an alkaline environment created by sodium carbonate to obtain a hydrotalcite precursor material with a layered double hydroxide structure; the preparation method comprises the following steps: performing high-temperature calcination on a hydrotalcite precursor, performing phase transformation on the hydrotalcite precursor to form a composite structure containing active CaO and a mayenite skeleton phase, and introducing oxygen vacancies into the material to improve the COadsorption capacity and cycling stability to obtain the calcium-based material based on hydrotalcite phase transformation modification. The problems of high-temperature sintering and agglomeration of the calcium carbonate calcium-based heat storage material in multiple heat charging and discharging processes can be solved, and the service life of the material is prolonged. Meanwhile, oxygen deficiency is introduced into the material in the phase transformation process, the reaction cycle stability and the thermochemical heat storage efficiency are improved, and the material is suitable for the field of medium-high temperature thermochemical industrial energy storage.

The invention relates to the technical field of cables, and provides a high-temperature-resistant flame-retardant cable and a preparation method thereof. The high-temperature-resistant flame-retardant cable comprises a conductor and a flame-retardant outer sheath, the flame-retardant outer sheath is prepared from the following raw materials in parts by weight: 40 to 50 parts of linear low-density polyethylene, 35 to 45 parts of ethylene-vinyl acetate copolymer, 10 to 15 parts of ethylene propylene diene monomer, 15 to 18 parts of modified aluminum hydroxide, 10 to 14 parts of modified magnesium hydroxide, 5 to 8 parts of polyethylene grafted maleic anhydride, 5 to 8 parts of microencapsulated red phosphorus, 2 to 3 parts of silane coupling agent and 0.8 to 1 part of antioxidant. The composite material is prepared from the following components in parts by weight: 0.5-1 part of a light stabilizer, 0.5-1 part of calcium stearate, 0.8-1 part of polyethylene wax and 0.5-0.9 part of carbon nanotubes. According to the cable prepared in the invention, the performance stability of an existing high-temperature-resistant material in a high-temperature environment is improved, and the problems of softening, melting and the like of the cable are avoided.

The invention relates to a composite powder explosion suppressant for suppressing aluminum hydride explosion and a preparation method of the composite powder explosion suppressant, belongs to the technical field of explosion suppressants, and solves the problems of single action mechanism, high required explosion suppression concentration, low efficiency and the like of a traditional explosion suppressant. According to the solution, the composite powder explosion suppressant for suppressing aluminum hydride explosion is prepared through raw material pretreatment, powder mixing and drying in sequence, and the composite powder explosion suppressant is prepared from the following components in parts by mass: 10.2 to 30.2 parts of melamine cyanurate, 20.4 to 40.6 parts of monopotassium phosphate, 15.2 to 25.2 parts of potassium bicarbonate, 8.4 to 13.2 parts of aluminum hydroxide, 6.8 to 11.1 parts of zinc borate, 5.0 to 9.0 parts of fumed silica and 2.0 to 5.3 parts of calcium silicate. The explosion suppressant can act on different combustion areas and combustion stages in the aluminum hydride explosion process, the physical and chemical explosion suppression effects of all the components of the explosion suppressant are fully exerted, and meanwhile, efficient explosion suppression of aluminum hydride explosion can be achieved through the synergistic effect of all the components.

The invention discloses a cold-resistant and anti-freezing cable and a preparation method thereof, and relates to the technical field of cables. The cold-resistant and anti-freezing cable sequentially comprises a sheath layer, an insulating layer and a conductive core layer from outside to inside, the sheath layer is prepared from a sheath material, and the sheath material comprises polyvinyl chloride resin, dioctyl terephthalate, modified polyurethane, epoxidized soybean oil, aluminum hydroxide, magnesium hydroxide, a calcium-zinc stabilizer and modified halloysite. The sheath material prepared by the invention has good mechanical properties, antibacterial properties and anti-aging properties, and is suitable for cold-resistant and anti-freezing cables.

The invention discloses bio-based ultralow-water-permeability two-component polyurethane which is characterized in that a component A comprises 20-40 parts of modified castor oil, 5-15 parts of diisooctyl adipate, 1-5 parts of a coupling agent, 60-70 parts of aluminum hydroxide, 5-10 parts of a water removal agent and 1-3 parts of a coloring agent; the component A is polymethylene polyphenyl isocyanate, the component B is composite isocyanate formed by combining two of polymethylene polyphenyl isocyanate, diphenylmethane diisocyanate, carbodiimide modified diphenylmethane diisocyanate and isophorone diisocyanate, and the component B is composite isocyanate formed by combining two of polymethylene polyphenyl isocyanate, diphenylmethane diisocyanate, carbodiimide modified diphenylmethane diisocyanate and isophorone diisocyanate. The invention further discloses a preparation method. The polyurethane pouring sealant with ultralow water permeability is obtained by optimizing a polyurethane formula and compounding a curing agent component.

The invention discloses a flame-retardant flat flexible high-current cable and a preparation method thereof, and relates to the technical field of cables. The cable comprises a flat conductor, an insulating layer, a shielding layer, a reinforcing layer and a sheath layer, the insulating layer contains 85-90 parts of low-density polyethylene, 1.2-1.5 parts of dicumyl peroxide, 12-15 parts of modified aluminum hydroxide and the like; and the sheath layer contains 42-50 parts of modified chlorinated polyethylene, 28-34 parts of modified aluminum hydroxide and the like. The modified chlorinated polyethylene is prepared through a three-step extrusion reaction, and the modified aluminum hydroxide is subjected to coupling agent treatment, coating modification and carbon nanotube composite modification. The flame-retardant flat flexible large-current cable has prominent advantages, an efficient flame-retardant system is constructed by modified aluminum hydroxide and antimony trioxide, and the V-0 level requirement of UL94 can be met; the flat structure is combined with the modified chlorinated polyethylene, so that the flexibility is excellent and the temperature-resistant range is wide. The design of the insulating layer and the shielding layer ensures excellent electrical performance, segmented temperature control and accurate parameter regulation and control are performed in preparation, stable product quality is ensured, and the device can adapt to a large-current application scene.

The invention relates to the technical field of cables, and provides a crosslinked polyethylene high-voltage cable which comprises a conductor, an insulating layer and a protective sleeve which are arranged from inside to outside. The protective sleeve comprises the following components in parts by weight: 50-80 parts of high-density polyethylene, 0.5-1 part of a cross-linking agent, 10-20 parts of a composite flame retardant, 0.5-1 part of an antioxidant, 0.5-1 part of a lubricant, 2-3 parts of polyethylene grafted maleic anhydride and 1-2 parts of carbon black. The flame-retardant monomer disclosed by the invention has the beneficial effects that the flame-retardant monomer has phosphorus-nitrogen synergistic flame-retardant and interface enhancing functions. The thiadiazole ring acts with the surface of aluminum hydroxide, so that the dispersity is improved, the mechanical property of the material is enhanced, and the flame-retardant efficiency is improved. The aluminum hydroxide is more efficient in thermal decomposition after being uniformly dispersed, and cooperates with the gas-phase flame-retardant and char-forming effects of the flame-retardant monomer to form a compact protective layer, so that the integration of flame retardance and enhancement is realized. And aluminum hydroxide with good dispersion can also be used as a rigid particle reinforced matrix, so that stress concentration is avoided.

The invention relates to the technical field of cables, and discloses a multilayer flame-retardant heat-conducting crosslinked polyethylene cable structure and a preparation process thereof. The product sequentially comprises a conductor layer, a heat-conducting flame-retardant buffer layer, a flame-retardant reinforced linkage layer and an outer sheath layer from inside to outside, wherein the heat-conducting flame-retardant buffer layer comprises a cross-linked polyethylene matrix, boron nitride, aluminum hydroxide and a shape memory polymer, and the outer surface of the heat-conducting flame-retardant buffer layer is provided with interlocking bulges with embedded heat-conducting microtubes; the flame-retardant reinforced linkage layer contains a cross-linked polyethylene matrix, expanded graphite and graphene, and a groove with a flame-retardant elastic piece is formed in the inner surface of the flame-retardant reinforced linkage layer. The preparation method comprises the following steps: firstly preparing the silver-plated conductor, then respectively preparing the heat-conducting flame-retardant buffer layer and the flame-retardant reinforced linkage layer, then aligning the two layers, carrying out hot-pressing compounding, carrying out irradiation crosslinking on the composite structure, and finally extruding and coating the outer sheath and carrying out cooling shaping. The product can be used in scenes of new energy power stations, data centers and the like, and has the advantages of synergism of flame retardance and heat conduction and long-term stability of an interlayer structure.

The invention provides a preparation method of 3D printing ceramic slurry and a ceramic shaping method, and the preparation method of the 3D printing ceramic slurry comprises the following steps: S1, loading nano-scale silicon dioxide on the surface of micro-nano-scale aluminum oxide to obtain nano-silicon dioxide modified aluminum oxide; s2, coating the surface of the nano silicon dioxide modified aluminum oxide with aluminum hydroxide to obtain modified aluminum oxide; and S3, ball-milling and mixing the modified aluminum oxide and a dispersing agent, and then mixing and stirring with a binder, an auxiliary agent and a solvent. The 3D printing ceramic slurry provided by the invention can realize high solid content, has good dispersibility and fluidity, is strong in stability, is not liable to cause problems of layering, precipitation and the like, the surface smoothness of extruded silk threads is high, and a prepared ceramic product is high in strength.