The invention relates to positive electrode material of a lithium secondary battery, which can combine with electrolyte solution or solid electrolyte, and negative electrode active material to form lithium secondary battery. Its characteristics are: the positive electrode material of lithium secondary battery is LiMn2-zMzO4 (0<=z<=0.5.), M is chosen from Li, Mg, Co, Ni, Fe, Al, Sr, Cr, Ga, Cu and Zn. The manufacturing method for positive electrode material of the lithium 1 secondary battery, includes preparation of usher containing Mn; decorate to the covering of usher particle containing Mn; mix with lithium salt and prepare particle; sintering and other steps. By decoration of the surface of particle to usher of positive electrode containing Mn or active material itself, state of material or apparent condition of material can be changed and its capacity of powerful charge and discharge, cycle performance and thermal stability can be raised. The invention has notable advantages including low cost, capacity of powerful charge and discharge, super-long cycle performance, excellent safety, super-long circulation property and resistance to overcharge.