The invention discloses a novel method for crystallizing
thiamine nitrate, which comprises the following steps of: adding
ammonium nitrate prepared by mixing industrial-grade stronger
ammonia water and concentrated
nitric acid according to the volume ratio of 1: 1 into 15-20 percent by
mass of
thiamine thiooxide liquid, and regulating the temperature to 15-45 DEG C; and adjusting the pH value with
ammonia water not higher than 25%, adding a
seed crystal when the pH value is 4.0-5.0 until the final pH value is 5-8, stirring and crystallizing for 0.5-2 hours at the speed of 100-600r / min, and then filtering and
drying. Preferably, the concentration of
ammonia water is 5%, the temperature is 15-35 DEG C, and the rotating speed is 300-400 r According to the method, parameters are accurately regulated and controlled, the length-
diameter ratio of
thiamine nitrate is reduced to 1.8-2.1, the yield is increased to 93-95% from 87%, the flowability is greatly optimized, the problems that existing products are fine in grain and prone to
electrostatic adsorption are solved, the process is simple, the cost is low, and the method is suitable for industrial production.