3825results about How to "Improve flame retardant performance" patented technology

A composite insulation that comprises an insulating material and amorphous micro oxide particles added to the insulating material by at least 1% weight of the composition insulation wherein the micro oxide particles provide at least one of an increase in the flame retardancy of the insulating material, a reduction in smoke generated, and an improvement in the electrical properties of the insulating material.

The invention relates to an irradiation crosslinking halogen-free high flame-retardant cable material and a preparation method thereof. The cable materials comprise the following compositions: 45-90 parts of basic resin, 10-55 parts of functional polyolefine resin, 45-125 parts of carbonate hydroxide flame retardant, 30-50 parts of charing agent, 30-50 parts of flame-retardant lubricant, 0.3-3 parts of methyl silicone rubber shell forming agent, 0.5-2 parts of silane surface modifier, 2-5 parts of crosslinking sensitizing agent, 0.2-2 parts of antioxidant, 1-4 parts of lubricant and 0.1-1.0 parts of initiator. The preparation method of the cable material comprises the following steps of: stirring the carbonate hydroxide flame retardant, the charing agent and the flame-retardant lubricant at a high speed for 2 min; and then adding the shell forming agent and continuously stirring at a high speed until the temperature rises to above 100 DEG C, coating the surface of the mixture with the shell forming agent; adding silane coupling agent and stirring for 5-8 min, and carrying out secondary surface treatment; adding initiator-alcohol solution, and discharging after mixing; extruding and pelletizing; finally drying and cooling to obtain the finished cable material product. The flame retardant performance of the product is obviously enhanced, and the product has good shell forming performance in conbustion without droplets.

Disclosed is a novel polymeric composite including a nanoparticle filler and method for the production thereof. More particularly, the present invention provides a novel halloysite nanoparticle filler which has the generally cylindrical or tubular (e.g. rolled scroll-like shape), in which the mean outer diameter of the filler particle is typically less than about 500 nm. The filler is effectively employed in a polymer composite in which the advantages of the tubular nanoparticle filler are provided (e.g., reinforcement, flame retardant, chemical agent elution, etc.) with improved or equivalent mechanical performance of the composite (e.g., strength and ductility).

A flame-retardant resin composition comprises a base resin (A), an organic phosphorus compound (B) having a unit represented by the following formula (1a), and a flame-retardant auxiliary (C).

Wherein Ar represents an aromatic hydrocarbon ring or a nitrogen-containing aromatic heterocycle; X¹ represents an oxygen atom or a sulfur atom; Y¹ and Y² are the same or different and each represents a hydrocarbon group, an alkoxy group, an aryloxy group, or an aralkyloxy group; Z¹ represents an alkylene group, or a nitrogen-containing bivalent group corresponding to an alkylamine; Y¹ and Y² may bind to each other, and Y¹ and Y² together with the adjacent phosphorus atom may form a ring; “a” denotes 0 or 1; and “b” denotes an integer of 1 to 6.

A prepreg for a printed wiring board, comprising a cyanate ester resin having a specific structure, a non-halogen epoxy resin, a silicone rubber powder as a rubber elasticity powder, an inorganic filler and a base material, which prepreg retains heat resistance owing to a stiff resin skeleton structure, has high-degree flame retardancy without the use of a halogen compound or a phosphorus compound as a flame retardant, and has a small thermal expansion coefficient in plane direction without using a large amount of inorganic filler, and a laminate comprising the above prepreg.

The invention relates to a high-performance halogen-free flame retardant ABS modified resin and a preparation method thereof. The resin comprises the following components with the content (in parts by weight): 100 ABS resin, 4-30 polyamide, 5-25 phosphate fire retardant, 0.1-0.5 anti-drippage agent, 5-10 toughening agent, 1-5 nano filler, 1-5 compatilizer, 0.2-1 antioxidant, 0.1-0.5 light stabilizer and 1-5 processing agent. Compared with the prior art, the invention has reasonable technique, and overcomes the defects of poor flame retardant property and low impact strength of the existing halogen-free flame retardant ABS; and the invention adopts a novel high-efficiency halogen-free flame retardant compounding synergism technology, a novel polyamide coal-forming agent, the high-efficiency synergism between organic and inorganic fire retardants, and the master batch method processing technique, thus endowing the resin with high fire resistance on the basis of improving the original good performances (especially the impact performance) of the ABS resin, and having wide application prospect.

The invention belongs to the field of flame retardant materials, and particularly relates to a composite flame retardant containing a microcapsule-coated intumescent flame retardant and a preparation method. The composite flame retardant containing the microcapsule-coated intumescent flame retardant consists of the following components in percentage by mass: 60-94 percent of microcapsule intumescent flame retardant, 5-25 percent of flame-retardant synergist, 0.9-10 percent of smoke suppressant and 0.1-5 percent of hindered amine light stabilizer. The preparation method comprises the following steps: preparing the microcapsule-coated intumescent flame retardant; placing the microcapsule-coated intumescent flame retardant, the flame-retardant synergist, the smoke suppressant and the hindered amine light stabilizer into a high-speed mixer for mixing uniformly, and discharging to obtain the composite flame retardant containing the microcapsule-coated intumescent flame retardant. Multiple components in the composite flame retardant can play roles in retarding flame in a synergetic way, so that the flame retardance of a high polymer material is improved remarkably, the production of toxic and harmful smog in a burning process can be suppressed, and the flame retarding efficiency is increased greatly.

A flame retardant high-wood content wood-plastic composite material and a preparation method thereof relate to a wood-plastic composite material and a preparation method thereof, wherein the problem of easy burning of the wood-plastic composite material with high wood content and the problems of high fire retardant addition amount, low anti-flaming efficiency and high cost of the existing flame retardant treatment technology are solved. The material is prepared from a fire retardant for wood fibers, a wood fiber material, thermoplastic plastics, a fire retardant for plastics, a coupling agent, a lubricant, an antioxidant, a smoke eliminating agent and auxiliaries. The method comprises the following steps of: weighing raw materials; preparing a flame retardant processing fluid; preparing aflame retardant wood fiber material; performing melting granulation on the thermoplastic plastics and the fire retardant for plastics to obtain flame retardant thermoplastic plastic base particles; mixing the flame wood fiber material with the flame retardant thermoplastic plastic base particles, the coupling agent, the lubricant, the antioxidant, the smoke eliminating agent and the auxiliaries, thereby obtaining a premix; performing melting compounding on the premix to obtain a melt material; and molding the melt material to obtain the flame retardant high-wood content wood-plastic compositematerial. The dosage of the fire retardant in the flame retardant high-wood content wood-plastic composite material is low; and the flame retardant high-wood content wood-plastic composite material is high in flame retardant efficiency and low in cost.

The invention discloses a composite phase-change energy storage material for microcapsules and a preparation method thereof. The coating of the microcapsule is made of silicon dioxide, and the core of the microcapsule is made of a phase-change energy storage material, wherein the phase-change energy storage material is a paraffin organic solid-liquid phase-change energy storage material. 0.2 to 0.5 wt.% of dispersed emulsifier, 52.5 to 62.5 wt.% of solvent water, 18.75 to 31.5 wt.% of phase-change energy storage material and 15.5 to 18.75 wt.% of inorganic silica source are matched and put into a reactor for stirring for 5 to 8 hours; the mixture is uniformly dispersed and emulsified at the temperature 3 to 8 DEG C higher than that for solid-liquid phase change; hydrochloric acid aqueous solution catalyst with the pH value of 0.93 to 4.07 or sodium hydroxide aqueous solution catalyst with the pH value of 8.0 to 12.0 is added into the emulsion; the reacting solution is naturally cooled to room temperature and precipitation solution is obtained; the precipitate is washed with the combination of water and petroleum ether, wherein the mass percent of the petroleum ether is 30 wt.%; then the precipitate is washed with deionized water and is filtered, and the product is naturally aired. The invention improves the technology of phase-change energy storage and conservation, and has the function of automatic temperature regulation, favorable physical and chemical stability, crack resistance, flame retardancy, wear resistance and high thermal conductivity.

The present invention relates to a water thin expanding steel structure fire-resisting coating material and its preparation method. Said ivnention adopts a self-synthesized high melting temp. acrylate emulsion as main film-forming substance, adding proper quantity of chlorometaemulsion to raise fibre resistance of film-forming substance self-body, and on the basis of convertional ammonium polyphosphate fire-resistant adjuvant an expandable graphite as foaming material is added so as to form the invented fire-resisting coating material. Said invention can greatly raise forming rate to coating layer, the thickness of foamed layer can be up to 30-50 times that of original coating layer, and its fire-resisting limit can be up to 75 min (thickness of coating layer is 3 mm).

A cyanate ester compound represented by the formula (1),

• • wherein Ar₂ represents a phenylene group, a naphthylene group or a biphenylene group, Ar₁ represents a naphthylene group or a biphenylene group when Ar₂ is a phenylene group, or Ar₁ represents a phenylene group, a naphthylene group or a biphenylene group when Ar₂ is a naphthylene group or a biphenylene group, R_x represents all substituents of Ar₁ each R_x is the same or different and represents hydrogen, an alkyl group or an aryl group, R_y represents all substituents of Ar₂, each R_y is the same or different and represents hydrogen, an alkyl group or an aryl group, and n is an integer of 1 to 50.

The invention relates to a monocomponent flame-retardant silane modified polyether sealant and a preparation method thereof. The sealant of the invention comprises an MS-polymer resin, a plasticizer, a reinforcement filler, a thixotropic agent, an ultraviolet ray absorbing agent, an ultraviolet ray stabilizing agent, a flame retardant, a crosslinking agent, a hydroxy group scavenger, a coupling agent, an organic tin catalyst and the like. The obtained monocomponent flame-retardant silane modified polyether sealant has the advantages of flame retardation, fast solidification, strong strength, and high weather resistance.

The invention discloses a method and device to make expandable graphite filling high density hard polyurethane foam plastic. It mixes polyether polyhydric alcohol, triethanolmine, organo-tin, silicone oil, water and expandable graphite at a certain proportion. After whisking by mechanism whisking device to equal, a certain quantity of iso-cyanic ester is added and mixed fully, then pouring into mould, covering the mould cover and taking curing process to gain the production. The invention has good fire resistance property, and the oxygen index would reach 40, the material of vertical burning testing reaches FV-0 grade. The invention conquers the disadvantage of halogenated fire resistance agent, and has crucial meaning for circumstance.

A high-wearing and fire-retardancy sofa leather is made by 1) wet condensing coating, molding in condensing groove, washing in water groove, drying and shaping and finally cooling and winding to become semi product wet process Bayes; 2) back spread coating with the semi product going through drawoff roller extraction shaping, dressing and spread coating, drying and baking and becoming fire-retardancy Bayes after cooling and winding; 3)nonaqueous shifting surface making, namely, separate paper shifting overlay; 4) kneading after treatment with pre-soaking of semi product sofa, squeezing out partial liquid, kneading and drying and finally batching on checking and final product packing. Apart from the major features of anti-friction and anti-retardancy, it can keep fine physical and mechanical performance and cosmetic styles with good quality and durable service.

The invention discloses a preparation method and application of a nano composite flame retardant containing DOPO and delamination grapheme. From the angle of improving the dispersity of the graphene, the graphene is modified by silane containing isocyanato, a DOPO structure with efficient fire resistance is introduced through a sol-gel method, and the nano composite flame retardant containing DOPO and delamination graphene is prepared, so that the graphene can form nano-scale delamination dispersion in a polymer, the phosphorus DOPO structure, delamination nanometer dispersion and silicon can achieve synergy, and the flame resistance of the polymer material can be improved remarkably when the retardant is applied in polymer matrixes of epoxy resins, polycarbonate and the like.

The invention relates to a non-woven wall paper, in particular to a long fiber non-woven wall paper raw paper and the preparation method and the non-woven wall paper prepared in the method. The long fiber non-woven wall paper raw paper comprises fiber pulp material and adhesive agent, wherein the fiber pulp material comprise wood pulp fiber and functional fiber, the weight proportion between the wood pulp fiber and the functional fiber adopts 0 to 95 percent to 5 to 100 percent, and the adhesive agent occupies 1 to 10 percent of the total weight of the raw paper; the functional fiber at least contains a functional fiber which fineness is 0.8 to 25 D, and which length is 15 to 60 mm. The surface of the wall paper in the invention presents natural stripes, the outer appearance is artistic, and further treatment is not required. Simultaneously, during the wall paper product processing, no shrinkage and moist feeling occur, the paper uncover is complete, and the paper flexibility is good. The wall paper product adopting flame-resistant fiber can be burnt on the fire source, the fire is extinguished after leaving the fire source, and the non-woven wall paper has a good flame-resistant performance.

The invention relates to a halogen-free flame-retardant long glass fiber reinforced polypropylene material, which comprises the following raw materials in percentage by weight: 49 to 88.8 percent of polypropylene, 0.1 to 0.5 percent of thermal stabilizer, 0.1 to 0.5 percent of lubricating agent, 5 to 20 percent of halogen-free flame retardant, 1 to 5 percent of glass fiber compatilizer and 5 to 25 percent of long glass fiber, wherein the polypropylene is high fluidity polypropylene. The invention also relates to a preparation method for the polypropylene material. The preparation method comprises the following steps of: preparing a long glass fiber master batch and a halogen-free flame-retardant master batch, mixing the two master batches uniformly, and thus obtaining the polypropylene material, wherein when the polypropylene material is used, the polypropylene material is directly used for injection molding of parts. The polypropylene material has excellent flame-retardant property and dimensional stability, high mechanical strength, low shrinkage rate and good creep resistance and thermal oxidation resistance, is suitable for injection molding of thin-wall large pieces and automotive part products with complex structures such as automotive engine bottom guard plates, front-end modules, instrument panel frameworks and the like, saves the automobile manufacturing cost, and is environment-friendly.

The invention provides an ultraviolet light crosslinking low-smoke zero-halogen flame-retardant cable material. The cable material comprises polyolefin, a compatilizer, an inorganic flame retardant, an organic phosphorus-nitrogen-containing flame retardant, a flame-retardant synergist, a photoinitiator, an assistant crosslinker, a surfactant, an antioxidant and a lubricant, wherein polyolefin contains low-density polyethylene, an ethylene-octylene copolymer and an ethylene-vinyl acetate copolymer in the weight proportion being (10-25):(20-35):(55-65); the compatilizer is polyethylene for grafting of maleic anhydride; the inorganic flame retardant is selected from magnesium hydroxide and aluminum hydroxide; the organic phosphorus-nitrogen-containing flame retardant contains polyphosphoric acid, pentaerythritol and melamine in the weight proportion being (10-20): (4-8): (15-30); the flame-retardant synergist contains zinc borate and/or polydimethylsiloxane. The cable material has good thermal resistance and anti-aging performance, can be used at the temperature of 125 DEG C for a long time and is excellent in comprehensive mechanical performance and better in flame retardance.

This invention discloses a composite material which is non-halogen, environment-friendly, inflatable flame-resistant, glass fiber polypropylene reinforced and method for making same. This invention compounds the inflatableaa (IFR) composed by polyammonium phosphate(APP), melamine(MEL) and pentaerythrite(PER) with polypropylene, so as to entitle polypropylene material good flame-resistant, The mechanics behaviour of the material could be reinforced largely through composition with long glass fiber, glass fiber felt and after interface modifying. This material contains no halogen constituent; it generates little smoke and smoketoxicity is small. Through controlling the content of flame-resistant in composite material, we can get polypropylene composite material whose limited oxygen index over 45 and has good mechanics behaviour. This material has good application foreground in the fields of electric, ship making, orbit and building materials, which is very sensible to expand the application range of PP.

Disclosed herein is a flame retardant thermoplastic resin composition including a polycarbonate resin, a branched acrylic copolymer, and a flame retardant. The flame retardant thermoplastic resin composition can have good compatibility as well as good flame retardancy, scratch resistance, colorability and appearance without requiring the addition of a compatibilizer.

The invention discloses a halogen-free flame retardant antistatic polycarbonate composition and a preparation method thereof. The composition comprises the components based on parts by weight: 50-70 parts of polycarbonate, 5-20 parts of polymer which can form a third phase, 8-15 parts of impact modifier, 3-15 parts of phosphonium flame retardant, 0.2 part of fluoro-polyolefine additive, 1-10 parts of conducting material and 0.1-1 part of other accessory ingredient. When in operation, the polymer which can form the third phase, the phosphonium flame retardant, the conducting material and other accessory ingredient are firstly melted and extruded by a double screw extruder to prepare intermediate composition; after being melted and extruded by the double screw extruder, the intermediate composition, the polycarbonate, the impact modifier and the fluoro-polyolefine additive are pelleted and then dried. The composition prepared by the invention does not contain chlorine and bromine, has excellent antistatic property, flame retardance, impact resistance and formability and needs a little conductive filler.

An efficient hyperbranched polyphosphazene flame retardant charring agent is prepared by reacting hexachlorocyclotriphosphazene with a binary compound containing two active groups. The charring agent has characteristics of good foaming charring performance, excellent flame retardant effects and good processing performance, and can be widely used in plastics, rubber, coating, adhesives, and other polymer materials. A preparing method adopts a one-pot method, and has characteristics of continuous reaction process, short reaction time and high production efficiency. By controlling the mole ratio of the hexachlorocyclotriphosphazene to the binary compound, no end-capping agent is added in the reaction process. When compared with the addition of end-capping agents in synthesis processes in triazine type charring agent patents, the synthetic process of the charring agent is simplified.

The invention relates to a phosphoric polyester fire-retardant epoxy resin composition. The compositions by mass portion of the phosphoric polyester fire-retardant epoxy resin composition are: 20 to 40 portions of epoxy resin, 5 to 20 portions of phosphoric polyester, 0 to 10 portions of other curing agent, 0.1 to 0.3 portion of curing accelerator and 30 to 70 portions of inorganic filler. The phosphoric polyester fire-retardant epoxy resin composition does not contain harmful substances such as halogen, antimony trioxide and so on; the fire resistance can reach the fire-retardant standard of UL94 V-0; and the phosphoric polyester fire-retardant epoxy resin composition has good fire resistance and electric property.

The invention discloses an environment-friendly flame-retardant polyurethane emulsion and a preparation method thereof, wherein the environment-friendly flame-retardant polyurethane emulsion is composed of the following raw materials in parts by weight: 26-38 parts of diisocyanate, 40-50 parts of macromolecular polyatomic alcohol, 2.5-10 parts of a flame retardant, 4-8 parts of an hydrophilic chain extender, 3-10 parts of a micromolecular chain extender, 1.5-9 parts of a neutralizer, and 0.5-1.5 parts of a catalyst. According to the invention, a chemical structure with a flame-retardant function is introduced onto a main chain of polyurethane, so aqueous polyurethane has the flame-retardant performance and the application range of the aqueous polyurethane is enlarged; and in addition, gradually increased requirements on the flame-retardant performance in the furniture industry and the construction industry are satisfied.

The invention discloses a composite intumescent flame retardant which is composed of the following components in percentage by weight: 50-65% of acid source, 10-20% of gas source, 15-20% of carbon source and 10-20% of smoke inhibitor. The acid source is composed of at least one of ammonium polyphosphate, melamine phosphate and melamine polyphosphate, wherein the ammonium polyphosphate is crystal II ammonium polyphosphate with the average degree of polymerization of greater than 1000; the gas source is composed of at least one of melamine and dicyandiamide; the carbon source is composed of at least one of pentaerythritol and bis pentaerythritol; and the smoke inhibitor is composed of at least one of magnesium hydroxide, aluminum hydroxide and zinc borate. The invention also discloses a preparation method of the composite intumescent flame retardant.

The present invention discloses the preparation process of irradiation resistant low smoke no-halogen fire retarding ethylene-propylene rubber as cable material. The preparation process includes heating and mixing ethylene-propylene rubber, aluminum hydroxide, silicone as fire retarding synergist, lead compound, antiager, copper resisting agent, gamma ray absorbent, liquid peroxide vulcalizer and phenolic heat stabilizer in a banbury mixer; and air cooled pelletizing in a double screw extruder. Thus prepared cable material has volume resistivity higher than 2x1015 Ohm.cm, heat life over 90 deg.c x 50 year, accumulated gamma ray resistance of 220 Mrad and radiation dosage rate resistance lower than 1Mrad/h, and is suitable for producing cable insulation layer for use in high nuclear radiation environment.

The invention relates to a bicomponent addition high-flame-retardant silicone rubber and a preparation method thereof. The bicomponent addition high-flame-retardant silicone rubber consists of a component A and a component B at a mass ratio of 1:10-10:1, wherein the component A consists of 100 parts of base, 0.1-0.8 parts of platinum catalyst and 20-60 parts of fire retardant; and the component B consists of 100 parts of base, 0.8-2.4 parts of hydrogenous crosslinking agent, 0.1-1 part of inhibitor and 20-60 parts of fire retardant. The base consists of 100 parts of vinyl silicone oil and 25-50 parts of reinforcement filling, and the fire retardant consists of an inorganic flame retardant and an organic fire retardant at a mass ratio of 1:(0.3-0.5). According to the rubber and the method, the inorganic flame retardant and the organic fire retardant are mixed and cooperate with the platinum catalyst for flame retardance, and the flame-retardant silicone rubber with good flame retardance, mechanical properties and processability and low raw material cost is prepared.

The invention discloses a flame retarding polypropylene composition and a preparation method thereof. The flame retarding polypropylene composition consists of the following compositions in percentage by weight: 80 to 90 percent of polypropylene, 5 to 10 percent of an organic bromine flame retardant, 3 to 5 percent of a flame retarding synergist, 0.1 to 0.5 percent of an antioxidant, 0.15 to 0.35 percent of a light stabilizer, 0.3 to 1 percent of an acid absorption addition agent, and 0.3 to 0.5 percent of a lubricant; and the compositions are put into a double screw extruder to extrude granulations, after the compositions are mixed in a high-speed mixer for 1 to 2 minutes. The flame retarding polypropylene composition has the advantages of excellent thermo oxidative resistance and aging resistance, high melt strength, easy extrusion molding, small corrosiveness to a mould and high cost performance, and can meet the requirement of thermo oxidative stability and processability of a corrugated pipe for an automobile on the flame retarding polypropylene material during processes of extrusion processing and using.

The invention provides a compound gas phase antirust masterbatch which is prepared from a gas phase antirust additive, a polyolefin carrier, a friction additive, an auxiliary function additive, a coupling agent, a dispersing agent, an auxiliary dispersing additive and other processing additives through mixing, stirring, milling and sieving. A gas phase antirust plastic film prepared from the compound gas phase antirust masterbatch of the invention is characterized by high barrier performance, electric conductivity, flame resistance and UV ray screening property. Gas phase antirust gas generated from the film can volatilize and penetrate into corners and spaces of packages where antirust oil can not reach and the gas also has long time antirust effect, thus overcoming the defects of rust prevention with antirust oil or a drying agent and being a quite good antirust material.

The invention provides a process for preparing a new plastic, which comprises the following steps: (1) preparing raw materials; (2) weighing and proportioning the raw materials; (3) mixing PVC powder, stabilizers, packing, plasticizers and other additives, then carrying out high-speed kneading on the obtained mixture, and preplasticizing the mixture so as to obtain a pre-plasticized mixture; (4) mixing the pre-plasticized mixture with TPU particles, carrying out banbury mixing on the obtained mixture under the condition of gradient temperature control so as to obtain colloidal products; (5) carrying out double-screw granulation on the obtained colloidal products; and (6) carrying out sorting, dehydration and packing on the granular products obtained in step 5 so as to obtain the new plastic. The process is simple, the conditions of the process are easy to control, and the process is suitable for large-scale production. The invention also provides a new plastic, which has the characteristics of high resistance to wear and scrape, high elasticity, easy recovery, high flame retardance, ultraviolet resistance, freezing damage (caused by low temperature in the north) resistance, environmental protection, soft handfeel and stick resistance, and the like; and the new plastic can be applicable to wire and cable compound.