29512results about How to "Improve flame retardant performance" patented technology

Disclosed are aromatic polyester polyols, polyol based resin blends, and rigid closed-cell polyisocyanate-based foams made using the polyol based resin blends. The resin blends generally comprise:(a) an aromatic polyester polyol reaction product formed by inter-esterification of a phthalic acid based material; a hydroxylated material having a functionality of at least 2; and a hydrophobic material; and(b) a C4-C7 hydrocarbon blowing agent. Also disclosed is a method for preparing rigid closed-cell polyisocyanate-based foams comprising reacting a polyisocyanate and a polyol based resin blend.

A composite insulation that comprises an insulating material and amorphous micro oxide particles added to the insulating material by at least 1% weight of the composition insulation wherein the micro oxide particles provide at least one of an increase in the flame retardancy of the insulating material, a reduction in smoke generated, and an improvement in the electrical properties of the insulating material.

The invention relates to a PVC resin compound and a product thereof, in particular to a PVC resin compound with characteristics of high inflaming retarding and low smoke formation. The PVC resin compound is prepared by mixing PVC resin, inorganic powder, accessory ingredient, toughener, coupling agent and evocating agent according to a certain proportion, wherein the evocating agent is used together with the coupling agent so as to enhance the associative property of the inorganic powder inside the PVC resin compound. The PVC product made by the PVC resin compound has favorable tensile strength and tensile stretch, and has the characteristics of high inflaming retarding and low smoke formation.

The invention discloses a wood-plastic composite material and a preparation method thereof, and the wood-plastic composite material comprises the following raw materials according to the mixing ratio by parts by weight: 30-80 parts of modified fiber powder; 15-80 parts of plastics; 2-10 parts of phase solvent; 2-10 parts of lubricant; 0-10 parts of stabilizer; 0.2-1.0 part of antioxidant; 5-15 parts of filler; and 2-20 parts of flame retardant. Lignin is utilized for modifying fiber powder, then composition with the plastics is carried out, and a finished-product material is formed by extrusion. The preparation method can solve the problems of the compatibility of wood fibers with the thermoplastic plastics, the surface treatment technology of the raw materials by utilizing the lignin and the like, realize the comprehensive utilization of the lignin and the waste plastics, be capable of replacing wood, increase the additional value of the lignin and solve the utilization problem of the lignin wastes. The manufactured wood-plastic composite material can significantly improve the mechanical performance, the tensile strength, the flexural strength and the impact resistance, and realize the industrial production of high-performance products, such as construction materials.

The invention discloses a halogen-free flame-retardant thermoplastic elastomer cable material with polyphenylether as the base materials and a preparation method thereof. The raw material of the cable material contains the components with the following weight percentage: 10 to 35 percent of matrix resin A; 5 to 15 percent of matrix resin B; 10 to 25 percent of elastomer; 5 to 25 percent of softening plasticizer; 8 to 15 percent of flame-retardant plasticizer; 20 to 40 percent of smoke-suppression flame retardant; 3 to 10 percent of compatilizer; 1 to 5 percent of lubricant; 1 to 5 percent of powder surface conditioner; 0 to 10 percent of mineral filler; 0.1 to 1 percent of stabilizing agent. The invention adds matrix resin, polyphenylether of strong polarity and functional group of styrene-ethylene / butylene-styrene segmented copolymer, which effectively improves the compatibility of non-polar elastomer with polyphenylether; the invention also adds plasticizer, which reduces the hardness of the material and increases the flexibility; and through the optimization and interaction of the softening plasticizer and the flame-retardant plasticizer, the invention reduces the hardness and improves the tactility of the material, and the flame retardant performance is excellent.

The present invention discloses one kind of continuous long fiber reinforced fire-retardant thermoplastic resin and its preparation process. It is prepared through mixing continuous long fiber reinforced thermoplastic resin agglomerate, which has reinforcing fiber content of 30-80 wt% and agglomerate length of 3-30 mm, and fire-retardant agglomerate, which has thermoplastic resin as carrier, fire retardant in 20-60 wt%, fire-retarding synergist 5-20 wt% and other additive 0-5 wt%. The continuous long fiber reinforced fire-retardant thermoplastic resin has continuous long fiber content of 5-60 wt%. The continuous long fiber reinforced fire-retardant thermoplastic resin has excellent mechanical performance, especially impact resistance, and excellent fire-retarding performance.

A PVC resin composition having high flame retardancy and low smoke generation comprises a formula including a PVC resin, inorganic powders, a additive, a toughening agent, a coupling agent and an initiator mixed by proportion, wherein the initiator cooperates with the coupling agent to improve a binding effect of the inorganic powders inside the PVC resin composition to endow a PVC product if made of the composition to provide with excellent tensile strength and elongation and enable the product to perform high flame retardancy and low smoke generation during combustion.

The invention discloses an expanded type fireproof coating and a preparation method thereof, which are characterized by comprising the steps of grinding and dispersing 15-35 percent of microcapsule flame retardants, 5-10 percent of fillers and 10-30 percent of solvent according to the percentage of the total mass of the coating after preparation until the fineness thereof is less than 90 microns;then adding and dispersing coating matrixes and additives which respectively take up 20-40 percent and 1-5 percent of the total mass of the coating after preparation until the system is uniform; and alternatively adding flame retardant synergist agents which account for 0-10 percent of the total mass of the coating after preparation before grinding. The obtained expanded type fireproof coating hasgood stability, overcomes the defects of poor high-temperature resistance, poor anti-aging performance, poor water resistance and the like in the traditional organic expanded type fireproof coating,lowers the use amount and cost of the flame-retardant additives which all realize non-halogenation, does not cause larger impact on the environment, and has very good application prospects.

The invention relates to an environment-friendly light heat-insulating material for fireproof doors and buildings, and a manufacturing method thereof. The manufacturing method is characterized by comprising the following steps of: pretreating plant hollow core bodies and / or flexible porous fillers by using a water glass adhesive; mixing with inorganic fire-resistant hollow particles; and performing mould pressing, shaping and drying to obtain the environment-friendly light heat-insulating material. The hollow core bodies and the flexible porous fillers are arranged multidirectionally; one layer of water glass adhesive is arranged at least on the surfaces of the hollow core bodies and the flexible porous fillers; and discontinuous holes are reserved between the hollow core bodies and / or the flexible porous fillers and the inorganic fire-resistant hollow particles. Preferably, the hollow core bodies are rice husks and straw sections; and the flexible porous fillers are foam and fibers. Renewable plant resources and recovered foam and fiber waste are adopted, so the environment-friendly light heat-insulating material is energy-saving and environment-friendly; and a large number of sealed holes are formed among the material particles through the penetration and coating of the modified water glass adhesive, and a heat-insulating hydrophobic corrosion-resistant multi-effect protective layer is provided, so the environment-friendly light heat-insulating material has good fireproof, heat-insulating and heat-preserving effects, high weather resistance, combined rigidity and toughness, low density and low cost.

A battery case made of an intumescent flame retardant polymeric composition that provides fire shielding, thermal shielding and a low heat release rate. A fire resistant additive is blended with a base polymer to produce the flame retardant polymeric material that is molded into the battery case. In one embodiment, one or more vent holes are provided in the battery case, advantageously in the cover portion, to permit gases to escape. In another embodiment, the fire resistant additive used for the battery case composition comprises a polymeric binder that includes an α-olefin-containing copolymer and a high density polyethylene, a nitrogenous gas-generating agent; a water vapor-generating agent; an antioxidant; and optionally a reinforcing agent. In another embodiment, the base polymer comprises a polyphenylene oxide and polypropylene blend, unfilled or filled with up to 60 wt. % glass fiber.

It is an object of the present invention to provide a resin composition which can form cured formulations having various excellent properties such as an insulating property, thermal shock resistance, moldability / formability and strength, and exhibit an excellent appearance in which transparency is enhanced, a resin composition whose cured thin film has excellent flame retardancy, good mechanical property and heat resistance, a dispersing element containing an inorganic microfine particle which can give a flame retardancy to a resin, to which the inorganic microfine particle is added, and can reduce a hygroscopic property to the extent possible, a method for producing the same and a cured formulation obtained by using the resin composition. The present invention relates to a resin composition comprising a compound having at least one of a glycidyl group and / or an epoxy group and an inorganic microfine particle, a resin composition comprising three components of a phenolic compound, a compound having at least one of a glycidyl group and / or an epoxy group and an inorganic microfine particle, a flame retardant resin composition comprising a polyhydric phenol and an inorganic microfine particle, and a dispersing element containing an inorganic microfine particle obtained by a hydrolysis condensation reaction of alkoxide and / or metal carboxylate in a dispersion medium.

The invention relates to an irradiation crosslinking halogen-free high flame-retardant cable material and a preparation method thereof. The cable materials comprise the following compositions: 45-90 parts of basic resin, 10-55 parts of functional polyolefine resin, 45-125 parts of carbonate hydroxide flame retardant, 30-50 parts of charing agent, 30-50 parts of flame-retardant lubricant, 0.3-3 parts of methyl silicone rubber shell forming agent, 0.5-2 parts of silane surface modifier, 2-5 parts of crosslinking sensitizing agent, 0.2-2 parts of antioxidant, 1-4 parts of lubricant and 0.1-1.0 parts of initiator. The preparation method of the cable material comprises the following steps of: stirring the carbonate hydroxide flame retardant, the charing agent and the flame-retardant lubricant at a high speed for 2 min; and then adding the shell forming agent and continuously stirring at a high speed until the temperature rises to above 100 DEG C, coating the surface of the mixture with the shell forming agent; adding silane coupling agent and stirring for 5-8 min, and carrying out secondary surface treatment; adding initiator-alcohol solution, and discharging after mixing; extruding and pelletizing; finally drying and cooling to obtain the finished cable material product. The flame retardant performance of the product is obviously enhanced, and the product has good shell forming performance in conbustion without droplets.

There are provided: (I) a thermoplastic resin (X-1) obtained by a process comprising the step of reacting: (1) a polyphenylene ether resin (A) with (2) a specific polyorganosiloxane (B), (II) a thermoplastic resin (X-2) obtained by a process comprising the step of reacting: (1) a polyphenylene ether resin (A), with (2) a specific polyorganosiloxane (B) and (3) a coupling agent (C), (III) a process for producing the thermoplastic resin (X-1), which comprises the step of reacting: (1) a polyphenylene ether resin (A) with (2) a specific polyorganosiloxane (B), (IV) a process for producing the thermoplastic resin (X-2), which comprises the step of reacting: (1) a polyphenylene ether resin (A) with (2) a specific polyorganosiloxane (B) and (3) a coupling agent (C), and (V) a thermoplastic resin composition (Z-1) comprising: (i) the above-mentioned thermoplastic resin (X-1) or (X-2) and (ii) a thermoplastic resin (D).

Disclosed is a novel polymeric composite including a nanoparticle filler and method for the production thereof. More particularly, the present invention provides a novel halloysite nanoparticle filler which has the generally cylindrical or tubular (e.g. rolled scroll-like shape), in which the mean outer diameter of the filler particle is typically less than about 500 nm. The filler is effectively employed in a polymer composite in which the advantages of the tubular nanoparticle filler are provided (e.g., reinforcement, flame retardant, chemical agent elution, etc.) with improved or equivalent mechanical performance of the composite (e.g., strength and ductility).

A fiber blend, a yarn spun from the fiber blend, and a fabric made from the yarn, wherein the fiber blend comprises: (a) about 40 wt.% to about 65 wt.% modacrylic fibers containing antimony, or FR acrylic fibers; (b) about 10 wt.% to about 50 wt.% cotton fibers or FR cotton fibers; (c) up to about 25 wt.% nylon fibers; and (d) greater than about 3 wt.% and less than 10 wt.% para-aramid fibers. The fabric is over 90 percent dyeable and is capable of achieving ASTM F1506 certification with an Arc Thermal Performance Value greater than 8.0 cal / cm2. The fabric is woven or knitted, and has a weight of about 4.0 oz. / yd.2 to about 10.5 oz. / yd.2. The fabric is suitable for garments worn during activities in which there is potential for exposure to flame and / or electrical arc.

The invention discloses a special plastic / acrylonitrile butadiene styrene (PC / ABS) alloy for a notebook computer shell. The formula comprises the following materials in parts by weight: 30-80 parts of polycarbonate, 5-65 parts of acrylonitrile-butadiene-styrene copolymer, 5-15 parts of compatilizer, 1-15 parts of flame retardant agent, 3-20 parts of filler, 1-10 parts of hardness modifier, 0.5-5 parts of anti-falling agent and 0-1 part of auxiliary agent. By adopting specific high-molecular polymers of polymethyl methacrylate (PMMA), ultrahigh-molecular polysiloxane and the like, the special PC / ABS alloy selects mineral fillers of specific-size mica, glass fiber and the like to carry out rematching therewith and generates synergistic effect, thus obviously improving the surface hardness and scraping resistance of the material and simultaneously having no influence on the other performances of the material. The PC / ABS alloy material has excellent impact resistance, surface scraping resistance and flame retardance, can meet the requirements of plastic for the notebook computer shell and has considerable promotion and application values.

A flame-retardant resin composition comprises a base resin (A), an organic phosphorus compound (B) having a unit represented by the following formula (1a), and a flame-retardant auxiliary (C). Wherein Ar represents an aromatic hydrocarbon ring or a nitrogen-containing aromatic heterocycle; X1 represents an oxygen atom or a sulfur atom; Y1 and Y2 are the same or different and each represents a hydrocarbon group, an alkoxy group, an aryloxy group, or an aralkyloxy group; Z1 represents an alkylene group, or a nitrogen-containing bivalent group corresponding to an alkylamine; Y1 and Y2 may bind to each other, and Y1 and Y2 together with the adjacent phosphorus atom may form a ring; “a” denotes 0 or 1; and “b” denotes an integer of 1 to 6.

A process for laser welding together a laser beam transparent polyester article and a laser beam opaque polyester article. The method limits the use of a laser beam at an energy level not greater than 100 W at a scanning speed not greater than 1000 cm / min., thus causing the articles to be welded together and maintaining a high weld strength.

The present invention relates to a composite sheet material that is water vapor permeable and substantially liquid water impermeable. The composite sheet material includes an outer layer, a film, and a reinforcing layer and, preferably, has an ASTM D3833 water vapor transmission rate of greater than 250 g / m2 / day, and a tensile strength of at least about 100 N / 5 cm when tested in accordance with ASTM D5035. The sheet material is useful as a membrane for roofing, housewrap, insulation facing and in the fabrication of protective apparel.

The invention relates to an anti-explosion polyvinyl chloride sheath material for mining cables and a preparation method thereof. The preparation method comprises mixing evenly polyvinyl chloride resin 100 parts by weight, plasticizer 30-80 parts by weight, stuffing 0-60 parts by weight, high-conductivity carbon black 10-40 parts by weight, anti-static agent 0-10 parts by weight, and other auxiliary agent 3-20 parts by weight by a high-speed mixer, extruding at 130-170 DEG C by a single- or double-screw extruder after being melted, water-cooling drawing bar or wind-cooling die-surface hot cutting and granulating, oven-drying, and packaging to obtain the finished product. Compared with the prior art, the invention has the advantages of excellent durable anti-static property and flame retardant property.

The invention discloses a low-smoke halogen-free flame-retarding thermoplastic elastomer alloy used for soft wires and a preparation method of the alloy, which is characterized in that: the material comprises thermoplastic polyurethane elastomer, thermoplastic styrene elastomer, compatilizer, phosphorus-nitrogen compound flame retardant, flame-retarding potentiating agent, lubricant, antioxidant and colorant; the weight ratio of the thermoplastic polyurethane elastomer, the thermoplastic styrene elastomer, the compatilizer, the phosphor-nitrogen compound flame retardant, the flame-retarding potentiating agent, the lubricant, the antioxidant and the colorant is 40 to 55 : 5 to 25 : 5 to 10 : 20 to 25 : 3 to 10 : 1.5 : 0.25 : 0.25; the preparation method is that the all components are evenly mixed in a high-speed mixer, and then extruded, drew and granulated at 170 to 210 degree centigrade, and then a low-smoke halogen-free flame-retarding thermoplastic elastomer alloy used for soft wires is obtained. The low-smoke halogen-free flame-retarding thermoplastic elastomer alloy used for soft wires has the advantages of achieving distinct flame-retarding effect at a small quantity of flame retardant dosage, satisfying the flame-retarding requirement of low-voltage wires, adjusting the Shore durometer number of the material between 80 to 95, good pliability, high physical mechanical property and according with the halogen-free and environment-friendly requirement.

The present invention relates to a pressure-sensitive adhesive composition containing a non-halogen, non-intumescent flame-retardant system comprising at least one flame-retardant agent with the provisos that the flame-retardant system does not comprise Sb2O3 or does not consist only of alumina trihydrate.

The invention discloses a halogen-free flame-retardant polyolefin injection-grade wood-plastic composite and a preparation method thereof. The halogen-free flame-retardant polyolefin injection-grade wood-plastic composite comprises the following components in percentage by mass: 25 to 70 percent of polyolefin resin, 5 to 50 percent of plant fiber, 0.5 to 20 percent of compatilizer, 0 to 30 percent of flexibilizer, 0.5 to 8 percent of dispersant, 5 to 40 percent of fire retardant and synergist and 0 to 1 percent of antioxidant. Compared with the conventional wood-plastic composite, the halogen-free flame-retardant polyolefin injection-grade wood-plastic composite prepared by the invention has the characteristics of simple production flow, less fire retardant dosage, good halogen-free flame-retardant effect, wide molding mode range and the like, and is suitable for various injection-molded products such as shells of electrical appliance products, furniture, materials for automobiles, artworks, building products with complex construction and the like.

A prepreg for a printed wiring board, comprising a cyanate ester resin having a specific structure, a non-halogen epoxy resin, a silicone rubber powder as a rubber elasticity powder, an inorganic filler and a base material, which prepreg retains heat resistance owing to a stiff resin skeleton structure, has high-degree flame retardancy without the use of a halogen compound or a phosphorus compound as a flame retardant, and has a small thermal expansion coefficient in plane direction without using a large amount of inorganic filler, and a laminate comprising the above prepreg.

The invention relates to a high-performance halogen-free flame retardant ABS modified resin and a preparation method thereof. The resin comprises the following components with the content (in parts by weight): 100 ABS resin, 4-30 polyamide, 5-25 phosphate fire retardant, 0.1-0.5 anti-drippage agent, 5-10 toughening agent, 1-5 nano filler, 1-5 compatilizer, 0.2-1 antioxidant, 0.1-0.5 light stabilizer and 1-5 processing agent. Compared with the prior art, the invention has reasonable technique, and overcomes the defects of poor flame retardant property and low impact strength of the existing halogen-free flame retardant ABS; and the invention adopts a novel high-efficiency halogen-free flame retardant compounding synergism technology, a novel polyamide coal-forming agent, the high-efficiency synergism between organic and inorganic fire retardants, and the master batch method processing technique, thus endowing the resin with high fire resistance on the basis of improving the original good performances (especially the impact performance) of the ABS resin, and having wide application prospect.

The invention discloses a low-smoke halogen-free flame-retardant polyolefin cable material and a preparation method thereof. The formula of the cable material comprises the following raw materials in percentage by weight: 20-30% of ethylene-vinyl acetate copolymer, 10-20% of linear low-density polyethylene, 3-6% of compatilizer, 50-60% of inorganic flame retardant, 2-5% of synergistic flame retardant, 0.5-1% of coupling agent, 0.2-0.5% of lubricant and 0.2-0.5% of antioxidant. The preparation method of the cable material comprises surface treatment of the inorganic flame retardant, burdening,mixing, milling, extrusion and granulation and other process steps. Compared with the prior art, the cable material disclosed by the invention has the advantages of superior flame retardancy, low smoke, low toxicity, no droplets, good processing performance, good dispersion of the inorganic flame retardant, and better uniformity and surface finish degree.

The invention provides a halogen-free flame-retardant polypropylene composite material, which is characterized by consisting of the following raw materials in weight portion: 82.5 to 12 portions of polypropylene, 0.3 to 2 portions of heat stabilizer, 0.2 to 1 portion of processing aid, 1 to 10 portions of toughening agent, 10 to 40 portions of flame retardant, 1 to 5 portions of glass fiber compatibilizer and 5 to 30 portions of glass fiber. The invention also provides a method for preparing the material. The material has the flame retardancy up to 1.6mm V0, the tensile strength higher than or equal to 50 MPa, the flexural modulus higher than or equal to 3,000 MPa, the notched impact strength more than or equal to 8KJ / m<2>, the shrinkage between 4 and 6 per thousand, the heat distortion temperature higher than or equal to 140 DEG C, as well as the other technical indexes up to or exceeding the standard of flame-retardant acrylonitrile-butadiene-styrene copolymer materials. As the material uses the phosphorus-nitrogen flame retardant containing no halogen, the flame-retardant effect of the material completely reaches UL94-V0 grade.

The invention aims to provide high-temperature resistant flame-retarding textile. The high-temperature resistant flame-retarding textile is weaved by high-temperature resistant flame-retarding yarns, and the high-temperature resistant flame-retarding yarns are blended with preoxidized fibers, high tenacity flame-retarding fibers and common flame-retarding fibers; and conducting fibers can also be used to weave the high-temperature resistant flame-retarding textile when the high-temperature resistant flame-retarding textile is prepared. The high-temperature resistant flame-retarding textile overcomes the drawback that the preoxidized fiber is difficultly spun, low in tenacity and only has single color of blackness; and the high-temperature resistant flame-retarding textile also has the advantages of high high-temperature resistance, high tenacity, good wearing comfortability, rich color, proper price and safety and reliability for the human body and is reasonable high-temperature resistant flame-retarding textile.

The present invention discloses excellent flame-retardant polyester and preparation method of the flame-retardant polyester. The product comprises polyester and the organic silicone copolymer as well as organic phosphorus copolymer contained in the polyester. The preparation process comprises the synthesis of the polyester, etherifying of the synthesized polyester or the polycondensation phase during which organic silicon monomer and organic phosphor monomer are added. The present invention takes use of silicon monomer and organic phosphor monomer for copolymerization with the polyester. The polyester is endowed with excellent flame-retardant performance. The polyester can meet the no-drop requirements during the flame-retardant process. The product by the present invention is no-drop-typed flame-retardant polyester, which can be used to manufacture polyester fiber and correspondent woven fabric or weaving fabric textile or nonwoven cloth and so on.