584results about How to "Improve interface compatibility" patented technology

The invention discloses a core-shell structure flame retardant with a thermo-oxidative aging resistance function and application of the core-shell structure flame retardant in preparation of a flame-retardant material, and belongs to the technical field of flame retardance. The core-shell structure flame retardant with the thermo-oxidative aging resistant function is composed of the core and the shell structure, the core is the flame retardant, the shell structure is a polymer containing hindered phenol and low-valence phosphorus, on one hand, hydrophobicity of the flame retardant can be improved, on the other hand, compatibility and dispersity of the flame retardant in a polymeric material can be improved, and the flame retardant performance is improved. Further, the flame retardant property and the mechanical property of the polymer material are improved. Besides, hindered phenol and low-valence phosphorus in the shell polymer not only can capture RO.and ROO.free radicals and inhibit the thermo-oxidative aging process of the polymer, but also can play a role in capturing the free radicals in the combustion process, so that the flame retardant property of the polymer material is further improved. The flame retardant disclosed by the invention has excellent flame retardance and thermal aging resistance, and can be applied to the fields of buildings, traffic, chemical engineering, machinery, communication, energy sources and the like.

The invention relates to the technical field of solid-state batteries, in particular to a solid-state electrolyte composite membrane, a preparation method thereof and a solid-state battery. The preparation method comprises the following steps: performing ultrasonic-initiated cross-linking polymerization on a polymer solid electrolyte monomer, a cross-linking agent and a surface hydroxylated oxide solid electrolyte to obtain a polymer-oxide solid electrolyte matrix, washing the polymer-oxide solid electrolyte matrix, and soaking the polymer-oxide solid electrolyte matrix in an electrolyte to obtain the solid electrolyte composite membrane. According to the invention, crosslinking of the polymer electrolyte monomer is initiated by ultrasound, and chemical bonds are formed between part of the polymer electrolyte monomer and the surface-hydroxylated oxide solid electrolyte, so that the interfacial compatibility of the polymer electrolyte monomer and the surface-hydroxylated oxide solid electrolyte is effectively improved, and the ionic conductivity, chemical stability and mechanical strength of the polymer electrolyte are improved; due to the properties of easy processing, good flexibility and the like of the polymer electrolyte, the interface compatibility between the oxide solid electrolyte and the positive and negative pole pieces can be fully improved, the flexibility and the processability are improved, and a win-win effect is achieved.

The invention belongs to the technical field of polymer heat conduction, and particularly relates to a preparation method of a high-heat-conductivity polymer with modified boron nitride as filler, which comprises the following steps: (1) dissolving boron nitride nanosheets into tetrahydrofuran, ultrasonically dispersing uniformly, adding a modifier for reaction, then removing tetrahydrofuran by using a rotary evaporator, transferring into deionized water, and drying to obtain a boron nitride nano-sheet; drying to obtain a modified boron nitride nanosheet; (2) dispersing carbon nanotubes in deionized water, stirring and carrying out ultrasonic treatment, adding the modified boron nitride nanosheets, and then carrying out freeze orientation treatment and freeze drying treatment to obtain a porous foamed composite heat-conducting filler; and (3) carrying out melt blending on the composite heat-conducting filler and polyethylene glycol terephthalate, and carrying out hot press molding to finally prepare the modified high-heat-conductivity polymer. According to the invention, the composite heat-conducting filler improves the interfacial compatibility and dispersity with a polymer matrix, and reduces the interfacial thermal resistance of the composite material, so that the modified polymer has good application in the aspect of heat dissipation of electronic equipment.

The invention relates to the technical field of TPU (thermoplastic polyurethane) protective films, in particular to a fluoride-free antibacterial TPU protective film and a preparation method thereof. The fluoride-free antibacterial TPU protective film comprises the following raw materials in parts by weight: 35-40 parts of TPU particles, 10-15 parts of a balance regulator, 8-12 parts of an antibacterial agent, 3-6 parts of an antioxidant, 3-5 parts of a heat stabilizer and 2-3 parts of a lubricant. According to the TPU protective film disclosed by the invention, TPU particles are matched with the antibacterial agent, the antioxidant, the heat stabilizer and the lubricant to serve as functional aids, and the balance regulator and the filling agent doped with flaky boron nitride are added to coordinate, cooperate and jointly achieve synergistic effects, so that the product is excellent in raw material interfacial compatibility, and the antibacterial property, barrier property and mechanical property of the product are improved in a coordinated and balanced manner; and the product has remarkable weather-resistant and acid-corrosion-resistant stability effects.

The invention relates to the technical field of solid electrolyte, in particular to normal-temperature surface modified flexible oxide solid electrolyte and a preparation method and application thereof. The normal-temperature surface-modified flexible oxide solid electrolyte is prepared from the following raw materials: a monomer, polyethylene oxide, a solvent, an initiator, a modified oxide ceramic electrolyte and electrolyte salt, wherein the mass of the monomer is 1-10% of the total mass of the components; the molar ratio of the initiator to the monomer is 0.01%-0.1%; the molar ratio of the electrolyte salt to the monomer is 1: (6-12); the mass ratio of the electrolyte salt to the modified oxide ceramic electrolyte is 1: (2.5-5). The flexible oxide solid electrolyte has high conductivity, wide temperature tolerance range and high structural stability, and when the flexible oxide solid electrolyte is applied to an all-solid-state lithium metal battery, the ionic conductivity, safety and cycle performance of the battery are improved.

The invention relates to the technical field of biodegradable materials, and particularly discloses a BBM-added bamboo powder biodegradable material and application thereof in beer bottles. The BBM-added bamboo powder biodegradable material is prepared from the following raw materials in parts by mass: 10 to 20 parts of poly (butylene succinate), 10 to 30 parts of poly (butylene adipate-co-terephthalate), 10 to 20 parts of bamboo powder, 1 to 3 parts of dopamine hydrochloride, 0.1 to 0.5 part of n-butylamine, 1 to 2 parts of hexadecyl trimethyl ammonium bromide, 1 to 5 parts of tetraethyl orthosilicate and 1 to 2 parts of tetrabutyl titanate. 1-2 parts of 3-aminopropyltriethoxysilane, 1-2 parts of an antioxidant and 1-2 parts of a plasticizer. The BBM obtained by the invention has excellent mechanical properties, improves the anti-ultraviolet intensity of a degradable material to a certain extent, and has very good biodegradability.

The invention discloses a multilayer polyimide film as well as a preparation method and application thereof, belongs to the technical field of high-performance polyimide, and solves the problem that the thermal stability is not ideal when a PI film is applied to a flexible PI plate in the prior art. The method comprises the following steps: mixing ODA, GAPD and DMAc in an ice bath, mixing BPDA and TAHQ, and adding the mixture in batches to obtain a solution B; adding SiO2 aerogel into absolute ethyl alcohol, and carrying out ultrasonic treatment at room temperature to obtain a solution C; coating the solution B into a film shape, drying, coating the solution C on the film, drying, coating the solution B on the film again, and drying to obtain the polyimide film. The multilayer low-dielectric polyimide film prepared by the invention has the advantages of low dielectric, high temperature resistance, high interface compatibility and low water absorption.

The invention discloses a preparation method of a bio-based epoxy resin anticorrosive coating, and relates to a preparation method of a bio-based epoxy resin coating. The bio-based epoxy resin anticorrosive paint mainly comprises an anticorrosive filler COFs-AA, bio-based epoxy resin and a curing agent. Wherein the anticorrosive filler COFs-AA is prepared from a two-dimensional covalent organic framework COFs and a bio-based material arachidonic acid (AA) through a covalent condensation reaction; the bio-based epoxy resin is prepared by epoxidizing a bio-based material galangin serving as a raw material through epichlorohydrin, and the curing agent is a common curing agent for epoxy resin. The bio-based epoxy resin anticorrosive paint is compounded by taking biomass as a basic component, and has the characteristics of greenness, environmental protection, no toxicity, good hydrophobicity and good corrosion resistance; the bio-based epoxy resin anticorrosive paint can be applied to the field of corrosion protection of materials such as various metals and woodware.

The invention discloses a titanium lithium aluminum phosphate solid electrolyte polymer interface modification method and a preparation method thereof. The method comprises the following steps: firstly, selecting LITFSI (lithium ion conductor), PVDF-HFP (polyvinylidene fluoride-hexafluoropropylene) and DMSO (dimethyl sulfoxide) liquid, and mixing to form PVDF-HFP-based polymer mixed liquid; then, the PAN film doped with titanium lithium aluminum phosphate powder is uniformly coated with the mixed solution through a press coating method, and the PVDF-HFPPAN film is obtained through drying treatment. And cutting the membrane, placing the cut membrane on two sides of a ceramic chip solid electrolyte, assembling an all-solid-state battery, activating at 40-80 DEG C until the polymer is attached to a metal lithium negative electrode and the surface of the solid electrolyte in a gel state, and cooling to finally obtain the solid electrolyte with a PVDF-HFPPAN coated LATP coated PVDF-HFPPAN sandwich structure. The modified solid-state electrolyte membrane can effectively inhibit the interface reaction of LATP on the lithium negative electrode side and enhance the wettability of the positive and negative electrode interface, thereby meeting the cycle performance requirement of the solid-state battery under the normal temperature condition.

The invention belongs to the technical field of insulating flame-retardant adhesive tapes, and particularly relates to an insulating flame-retardant adhesive tape and a preparation method thereof. According to the invention, phytic acid reacts with 3-amino-5-methylpyrazole, triaminopyrimidine and polyether amine-2000 to prepare a flame-retardant auxiliary agent, and the flame-retardant auxiliary agent is compounded with magnesium hydroxide, zinc borate and melamine to prepare a modified flame retardant which can generate an expansive carbon layer during combustion to block heat and isolate oxygen so as to achieve a flame-retardant effect; an aluminum oxide layer generated on the artificial diamond micro-powder is used as an insulating heat-conducting aid, so that the insulativity, wear resistance and corrosion resistance of the insulating flame-retardant adhesive tape are improved, the adhesive tape can be assisted in uniform heat conduction, and combustion caused by over-high local temperature is prevented; epoxy resin is used for wrapping the uniformly dispersed insulating heat-conducting auxiliary agent, and anisyl and boron nitride ceramic powder are cured to prepare an insulating material, so that the dielectric breakdown performance of the adhesive tape is enhanced. The insulating flame-retardant adhesive tape prepared by the invention is excellent in insulativity and flame retardance and free of halogen flame retardants, and the production process is environment-friendly.

The invention belongs to the technical field of high polymer materials, and particularly discloses a cross-linked antistatic supercritical microcellular foaming material. Comprising the following raw materials in parts by weight: 80-100 parts of HIPS, 10-15 parts of thermoplastic elastomer, 5-10 parts of low-density polyethylene, 10-15 parts of organic multifunctional master batch, 5-10 parts of high-dispersion conductive functional filler, 5-10 parts of modified calcium sulfate whisker, 5-10 parts of grafted modified talcum powder master batch, 1-5 parts of cross-linking agent, 1-5 parts of lubricant and 1-5 parts of antioxidant. The invention provides a cross-linked antistatic supercritical microcellular foaming material as well as a preparation method and application thereof. The cross-linked antistatic HIPS supercritical microcellular foaming material which is excellent in comprehensive performance and can be applied to multiple fields is prepared.

The invention belongs to the technical field of multifunctional fibers, and particularly relates to a preparation method of multifunctional jasmine, camellia and chamomile fibers, and the preparation method comprises the steps of preparation of beta-cyclodextrin microspheres, modification of carboxyl, adsorption, preparation of bis-aminated polyethylene glycol polycaprolactone and spinning. The prepared multifunctional jasmine, camellia and chamomile fiber has an excellent antibacterial effect and a natural antibacterial effect, the bacteriostasis rate to staphylococcus aureus is 98.5-99.2%, the bacteriostasis rate to candida albicans is 98.2-99%, the bacteriostasis rate to escherichia coli is 97.5-98.7% after the multifunctional jasmine, camellia and chamomile fiber is washed with water for 50 times, and the antibacterial standard of textiles is met; the antibacterial durability is good, and the average antibacterial loss rate after 50 times of washing is lower than 2%; the antioxidant and anti-mite effects are good, and the free radical scavenging rate is more than 96%; and the mite repelling rate is greater than 70%.

The invention belongs to the field of sodium ion solid electrolyte manufacturing, and particularly relates to a terbium-doped NASICON type sodium ion conductor material and a preparation method thereof. The stoichiometric formula of the terbium-doped NASICON-type sodium ion conductor material is Na < 3 + x > Zr < 2-x > Tb < x > Si < 2 > PO < 12 >, x is more than 0 and less than or equal to 0.3, and the total ionic conductivity of the terbium-doped NASICON-type sodium ion conductor material is 3.07 * 10 <-4 > S / cm to 1.02 * 10 <-3 > S / cm. Compared with the prior art, a proper amount of terbium ions are used for replacing skeleton ions (such as Zr < 4 + >) in an NASICON structure, so that the concentration of transferable sodium ions is increased, and the ionic conductivity is improved. By doping terbium ions, the size of a sodium ion transmission channel is effectively increased, the transmission energy barrier is reduced, and the ionic conductivity is further improved. The ionic conductivity of the Na < 3.2 > 2Zr < 1.8 > Tb < 0.2 > Si2PO12 electrolyte doped with terbium ions at the room temperature reaches 1.02 * 10 <-3 > S / cm. According to the invention, the selected raw materials are economical and practical oxides, and the raw materials are easy to purchase and low in price, so that the production cost can be reduced.

The invention belongs to the technical field of lithium ion batteries, and discloses a carbon compatible binder for a silicon-carbon negative electrode of a lithium ion battery and a preparation method and application of the carbon compatible binder for the silicon-carbon negative electrode of the lithium ion battery. Then N-hydroxysuccinimide and 1-ethyl-(3-dimethylaminopropyl) carbodiimide are added to activate carboxyl of sodium carboxymethyl cellulose, finally 1-pyrene methylamine hydrochloride is added, N2 is introduced at the room temperature, and a reaction is performed under stirring. According to the binding agent, sodium carboxymethyl cellulose is used as a main chain to be subjected to amidation reaction with 1-pyrene methylamine hydrochloride, pi-pi conjugation can be formed by introduced pyrene groups and graphite in a silicon-carbon material, the interface compatibility of the binding agent and the silicon-carbon material can be effectively improved, the dispersity and the binding property of the silicon-carbon material are enhanced, and the binding agent can be used for preparing the silicon-carbon material. And the electrochemical performance of the silicon-carbon negative electrode of the lithium ion battery is obviously improved.

The invention relates to the technical field of building materials, and discloses fire-resistant decoration waste exterior wall external thermal insulation mortar and a preparation method thereof. The fire-resistant decoration waste exterior wall external thermal insulation mortar comprises the following raw material components in parts by weight: 60-410 parts of cement; 120 to 550 parts of decoration waste recycled aggregate; 36 to 75 parts of SiO2 aerogel; 8 to 17 parts of a silane coupling agent; 1.3 to 2.1 parts of dispersible latex powder; 0.5 to 1.0 part of methyl cellulose; 7-15 parts of a water reducing agent; 0.2 to 0.4 part of an air entraining agent; and 120 to 180 parts of water. According to the invention, the low-cost and high-strength decoration waste recycled aggregate is used for partially replacing expensive and low-strength aerogel, so that the thermal insulation performance of the mortar is ensured, and the material cost is greatly reduced; the decoration garbage exterior wall external thermal insulation mortar can resist high-intensity fire disasters with the highest temperature of 1000 DEG C and the fire receiving time of 2.5 h, and can be applied to exterior wall external thermal insulation systems of high-rise and super high-rise buildings with high fire extinguishing difficulty.

The invention relates to the technical field of composite materials, in particular to a PTFE composite material for a shaft sleeve and a preparation method of the PTFE composite material. The PTFE composite material for the shaft sleeve consists of the following raw materials in parts by weight: 80-140 parts of polytetrafluoroethylene powder, 3-8 parts of polyphenylene sulfide, 8-12 parts of modified glass fibers and 10-15 parts of a reinforcing agent. The lubricating property of a base material is effectively improved by adding the modified glass fiber, and meanwhile, the wear resistance and the mechanical property of the polytetrafluoroethylene composite material are favorably improved by improving the tribological property, enhancing the mechanical strength and improving the interface bonding and load dispersion through the reinforcing agent.

The invention belongs to the technical field of MOFs-biomass composite carbon matrix preparation, and particularly relates to a preparation method and application of a high-performance solid hydrogen storage material, and the high-performance solid hydrogen storage material is a ZIF-8-pine sawdust composite carbon matrix; the preparation method of the high-performance solid hydrogen storage material comprises the following steps: S1, carrying out acid pickling treatment on biomass, washing the biomass with deionized water until the biomass is neutral, and drying the biomass for later use; s2, performing carbonization treatment on the biomass obtained in the step S1 in an inert protective atmosphere to obtain a carbon precursor; and S3, grinding and mixing the carbon precursor obtained in the step S2 and a chemical activator, putting the mixture into a self-made reactor, sealing after all air in the reactor is exhausted, and carrying out an activation reaction. The MOFs and pine sawdust composite carbon substrate with a high specific surface area is prepared by adopting a method which is simple in process, green, environment-friendly, economical and efficient, and the MOFs and pine sawdust composite carbon substrate has a three-dimensional interconnected pore structure, is adjustable in specific surface area and has relatively high hydrogen storage capacity.

The invention discloses a fly ash-based adsorbent as well as a preparation method and application thereof, and belongs to the technical field of adsorbent materials. The fly ash-based adsorbent is prepared from the following raw materials: modified fly ash, modified lignin, activated carbon, polyethylene glycol polyvinyl alcohol grafted copolymer, titanate and metal oxide. The coal ash is subjected to ball milling and acid modification treatment, and a surfactant is introduced, so that the adsorption sites and the adsorption efficiency of the coal ash are increased. Through the synergistic effect of the raw materials, the prepared fly ash-based adsorbent can efficiently adsorb fluorine ions in wastewater, and the fluorine ion removal rate can reach 99% after adsorption is performed for 30 min.

The invention discloses a high-efficiency low-resistance electrostatic spinning multi-layer filtering material for a mask filter element and a preparation method of the high-efficiency low-resistance electrostatic spinning multi-layer filtering material. The method comprises the following steps: firstly, dissolving ODA and PMDA raw materials in a solvent to prepare a first PAA solution; then, preparing the solution into a first bead-like PAA nanofiber membrane by utilizing an electrostatic spinning technology; the preparation method comprises the following steps: preparing a first PAA / ZIF-8 nanofiber layer, dissolving a ZIF-8 raw material in the first PAA / ZIF-8 nanofiber layer, mixing the ZIF-8 raw material with ODA and PMDA to form a second PAA / ZIF-8 solution, superposing second PAA / ZIF-8 nanofiber layers on the first PAA / ZIF-8 nanofiber layer above and below the first PAA / ZIF-8 nanofiber layer through an electrostatic spinning technology, and carrying out thermal imidization treatment to successfully prepare the multi-layer filter material with a ZIF-8 modified PI / bead-like PI / ZIF-8 modified PI structure. The preparation process provided by the invention is simplified and efficient, and the prepared bead-like multilayer filtering material not only has the characteristics of excellent filtering efficiency and low resistance, but also shows huge application potential in the field of air purification.

The invention relates to a flame-retardant cellulose composite film and a preparation method thereof, belongs to the field of flame-retardant materials, and aims to solve the problems that a cellulose film is inflammable, poor in compatibility with an inorganic flame retardant, relatively low in mechanical property and the like. The main components of the composite membrane comprise nanocellulose, titanate nanofibers, carbon dots and a cross-linking agent. The preparation method comprises the following steps: firstly, enabling the carbon dots to react with the nanocellulose under the action of an initiator; secondly, adding titanate nanofibers into the carbon dot modified nanocellulose suspension, and uniformly mixing; then, adding a cross-linking agent and uniformly dispersing to obtain a mixed solution; and finally, casting the solution into a culture dish, and curing in a vacuum drying oven to prepare the flame-retardant cellulose composite film. According to the preparation method, the compatibility of the flame retardant and the nano cellulose is remarkably improved, the mechanical property is enhanced, and the composite film has excellent flame retardance, smoke suppression and heat insulation characteristics and is suitable for preparing the flame-retardant cellulose composite film.

The invention discloses a toughened epoxy microsphere and a preparation method thereof, and the toughened epoxy microsphere is prepared from the following raw materials in parts by mass: 100 parts of epoxy resin, 31-37.2 parts of a curing agent and 65.5-524 parts of a polyether solvent. The preparation method comprises the following steps: reacting epoxy resin with a curing agent to form a low-molecular-weight prepolymer, and dispersing the low-molecular-weight prepolymer in a polyethylene glycol (PPG) solvent with a certain molecular weight to form an epoxy / PPG binary blending system. Along with the proceeding of the curing reaction, the epoxy molecule amount is continuously increased, and finally, the epoxy molecules are precipitated from the polyethylene glycol solvent in a sphere shape. According to the preparation method disclosed by the invention, the epoxy microspheres with regular shapes can be prepared only by a simple process, and the glass transition temperature (Tg) of the epoxy microspheres is relatively high and is about 170 DEG C; the excessive curing agent endows the epoxy microspheres with certain reactivity, the epoxy microspheres can react with an epoxy matrix, the toughening and reinforcing effects are achieved, the interfacial compatibility of the microspheres and the matrix is enhanced, and therefore the mechanical property of epoxy is improved.

The invention provides a preparation method and application of a mixed matrix membrane based on in-situ MOF gel, and relates to the field of gas separation membrane materials. The preparation method comprises the following steps: weighing a certain amount of dry Pebax particles, and dissolving the Pebax particles in an ethanol-water mixed solvent at 90 DEG C to obtain a solution A; dissolving zinc nitrate hexahydrate in an ethanol-water mixed solvent to obtain a solution B; dimethylimidazole is dissolved in an ethanol-water mixed solvent, and a solution C is obtained; adding a certain amount of triethylamine into the solution C, and uniformly mixing; sequentially adding the solution B and the solution C into the solution A, and stirring for reaction to obtain a mixed solution; transferring the mixed solution to a dialysis bag for dialysis; and transferring the dialyzed mixed solution to a polytetrafluoroethylene culture dish, and drying to obtain the mixed matrix membrane. The preparation method provided by the invention is simple and easy to operate, the prepared mixed matrix membrane has good interfacial compatibility with MOF gel, and the MOF loading capacity can be improved, so that the gas separation performance is improved.

The invention provides a calcium carbonate modified polypropylene composite material and a preparation method thereof.The preparation method comprises the steps that calcium carbonate powder and a surfactant containing double bonds are mixed and stirred at the high temperature for preset time, and surface modified calcium carbonate is obtained; and mixing the surface modified calcium carbonate with polypropylene and an initiator, stirring for a preset time, and carrying out melt extrusion at 170-210 DEG C to obtain the calcium carbonate modified polypropylene composite material. The preparation method provided by the invention has the advantages of rapid activation and simple process, and the prepared surface modified calcium carbonate powder has the advantages of concentrated size distribution, uniform particle size and high activation degree, has good compatibility with polyolefin materials, can enhance the tensile strength and other mechanical properties of a composite material when being filled into a polymer, and has good application prospects. And good economic benefits are achieved.

The invention discloses a flame-retardant eutectic polymer electrolyte based on in-situ polymerization, a preparation method and a solid-state lithium battery, and belongs to the technical field of lithium battery polymer electrolytes.The preparation method comprises the following steps that in the inert gas atmosphere, an amide hydrogen bond donor and alkali metal salt are evenly mixed, and a mixture is obtained; the eutectic electrolyte is obtained by utilizing the interaction of Li-N and Li-O; adding a functional additive, an ester polymer monomer and an initiator into the eutectic electrolyte, and uniformly mixing to obtain a precursor solution; and injecting the precursor solution into a diaphragm in a lithium ion battery to be assembled, sealing, and performing in-situ free radical polymerization reaction to form the flame-retardant eutectic polymer electrolyte, thereby obtaining the solid-state lithium battery of the flame-retardant eutectic polymer electrolyte based on in-situ polymerization. The eutectic polymer electrolyte disclosed by the invention has a flame-retardant property, the safety of the lithium battery is greatly improved, meanwhile, the eutectic polymer electrolyte has high ionic conductivity, the rate capability of the battery is improved, and stable long circulation of the assembled solid-state lithium battery is realized.

The invention relates to the technical field of card protection films, and discloses an anti-ultraviolet card protection film and a preparation process. Nano titanium dioxide is used as an ultraviolet shielding agent to effectively reflect and absorb ultraviolet rays. The isocyanate group on the surface of TDI-modified silicon dioxide can produce a chemical bonding effect with a hydroxyl group of a hydroxyl-containing copolyester, and the bonding force is relatively strong, thereby improving the interface compatibility between the nano titanium dioxide and a substrate, and the ultraviolet transmittance is relatively low, so that ultraviolet light in the medium-wave region and the long-wave region can be better absorbed. The modified polyethylene terephthalate contains units similar to the structure of the card protection film substrate, thereby improving the dispersibility of the nano titanium dioxide in the substrate and weakening the damage of ultraviolet light to polyethylene terephthalate molecules. At the same time, the molecular chain contains a biphenyl aromatic structure, which increases the rigidity of the molecular chain, helps to improve the heat resistance of the polyester, and further prolongs the service life of the card protection film.

The invention provides a radiation cooling and heat conducting polyether-ether-ketone composite material and a preparation method and application thereof.The preparation method of the composite material comprises the specific steps that S1, boron nitride is subjected to high-temperature calcination and furnace cooling, and hydroxyl modified boron nitride is obtained; s2, dispersing aramid staple fibers in a poor solvent, and performing high-speed shearing to form microspheres, namely aramid fiber balls; s3, uniformly mixing the aramid fiber balls obtained in S2 with polyether-ether-ketone powder, then adding the hydroxyl modified boron nitride obtained in S1, and continuously and uniformly mixing to obtain a composite material dispersion; and S4, carrying out melting and hot pressing on the composite material dispersion obtained in S3 to obtain the target polyether-ether-ketone composite material. The preparation method of the material disclosed by the invention is simple, and the prepared polyether-ether-ketone composite material shows excellent radiation cooling performance, heat-conducting property and heat stability and has a wide application prospect.

The invention discloses a high-toughness biodegradable material for film blowing forming and a preparation method of the high-toughness biodegradable material, and belongs to the technical field of biodegradable materials. Comprising 50-60 parts of polyethylene, 8-16 parts of poly (butylene adipate / terephthalate), 6-12 parts of polylactic acid, 4-9 parts of self-made nano silicon dioxide modified lignin, 3-8 parts of modified nano calcium carbonate, 1-2 parts of a plasticizer, 3-5 parts of a compatilizer, 0.2-1 part of a lubricant, 0.3-1.5 parts of carbon black and 0.2-0.8 part of an antioxidant. According to the material for film blowing forming, the self-made nano silicon dioxide modified lignin and the modified nano calcium carbonate are compounded for use, so that the material has ultrahigh toughness, and by adding the poly (butylene adipate-co-terephthalate), the polylactic acid and the lignin, the positive effect on the biodegradability of the material is achieved; therefore, a relatively good biodegradation effect is achieved.

The invention discloses a preparation method of a high-barrier fresh-keeping film for food fresh-keeping packaging, belongs to the technical field of fresh-keeping film processing, and aims to solve the technical problem that the barrier property of a high-barrier fresh-keeping film to water vapor and oxygen and the tensile property of the high-barrier fresh-keeping film in the prior art need to be further improved. The preparation method comprises the following steps: adding barrier layer mixed particles, bonding layer mixed particles and a supporting layer material into a multi-layer co-extrusion extruder, carrying out melt extrusion, injecting into a multi-layer co-extrusion film machine, and carrying out blow molding to obtain the high-barrier-property preservative film which is compounded by five layers, namely a supporting layer, a bonding layer, a barrier layer, a bonding layer and a supporting layer from top to bottom, according to the invention, modified graphene is added into composite polyester of the barrier layer for modification, and waterborne polyurethane added with modified polysiloxane is prepared to obtain the bonding layer, so that the tensile property and the barrier property to water vapor and oxygen of the preservative film are further improved.

The invention relates to the technical field of layered product materials, and discloses a polymer-ceramic composite dielectric material, a preparation method and application of the polymer-ceramic composite dielectric material to a capacitor. The preparation method of the polymer-ceramic composite dielectric material comprises the following steps: adding composite modified pullulan and modified composite nanosheets into N, N-dimethylformamide to obtain a mixed solution A, and casting to form a film to obtain an outer film; adding the composite modified pullulan and the modified ceramic-based composite filler into N, N-dimethylformamide to obtain a mixed solution B, and pouring to form a film to obtain an inner-layer film; and clamping the inner-layer film between the outer-layer films, carrying out hot press molding, and cooling to obtain the polymer-ceramic composite dielectric material with a three-layer structure. The polymer-ceramic composite dielectric material provided by the invention has good dielectric property, energy storage property and heat resistance, and can be applied to capacitors.

The invention relates to a ceramic and metal heterogeneous connection method, which is characterized by comprising the following steps of: 1, covering a metal surface with a metal plating layer; secondly, tungsten slurry or pure molybdenum powder or molybdenum-manganese composite powder is adopted, and a primary metallization layer is formed on the to-be-brazed surface of the ceramic in a high-temperature sintering mode; 3, forming a nickel layer, a nickel-phosphorus layer or a nickel-boron layer, which is called as a secondary metallization layer, with the thickness of less than 20 microns on the surface of the primary metallization layer in a manner of electroplating, evaporation, chemical plating or sintering; 4, attaching a tertiary metallization layer to the surface of the secondary metallization layer in an electroplating manner; fifthly, a ceramic side brazing filler metal layer is formed, and a metal side brazing filler metal layer is formed; and 6, placing a metal middle buffer layer structure in a gap between the ceramic side brazing filler metal layer and the metal side brazing filler metal layer, wherein the main body of the metal middle buffer layer structure is pure nickel, pure copper, pure silver or pure aluminum. According to the method, cracks can be prevented from being generated on the brazing interface, and the sealing performance and the mechanical connection strength of the brazing interface are improved.