The invention discloses a super-hydrophobic conformal coating, and a preparation method and an application method thereof. The super-hydrophobic conformal coating is composed of, by mass, 5 to 40% of fluorocarbon resin, 10 to 30% of fluorosilicon resin, 20 to 60% of an organic solvent, 10 to 30% of silica, 1 to 10% of titanium dioxide, 1 to 10% of polytetrafluoroethylene, 0.1 to 0.5% of a catalyst, and 1 to 5% of a curing agent. According to the preparation method, the ingredients are subjected to stirring mixing and ultrasonic uniform dispersion in sequence at a certain ratio. According to the application method, the super-hydrophobic conformal coating is subjected to direct spraying or brush coating onto the surfaces of insulators and outdoor electric power facilities; the thickness of obtained coating layers is controlled to be 0.1 to 0.5mm preferably; and 20 to 60min of normal temperature curing is needed. The preparation method is simple; the cost is low; the super-hydrophobic conformal coating is convenient to use, possesses extremely high hydrophobicity and weatherability, is capable of realizing self cleaning, is a nanometer composite hybrid normal-temperature cured fluorocarbon coating, is capable of realizing stain prevention, pollution flashover prevention, and corrosion prevention of insulators and outdoor electric power facilities effectively, and is promising in application prospect.