350 results about "Graft reaction" patented technology

The present application provides a preparation method for a filtrate reducer and the use thereof. The preparation method comprises: dropwise adding a silane coupling agent containing double bonds into a graphite dispersion under an acidic condition for grafting reaction to obtain silane-coupling-agent-modified graphite, then adding a cross-linking agent into the silane-coupling-agent-modified graphite, adjusting the pH to neutrality to obtain a first intermediate solution, mixing acrylamide, a sulfonic monomer, a cationic monomer and a monomer containing a cyclic group, then adjusting the pH to neutrality to form a second intermediate solution, finally adding an initiator into the first intermediate solution, then dropwise adding the second intermediate solution for polymerization reaction to obtain the filtrate reducer. The filtrate reducer prepared by such a method has a better high-temperature-resistant filtrate loss reduction property, and better pressure bearing capacity and plugging capacity.

The invention provides a water-based floating aluminum pigment and a preparation method thereof.The preparation method of the water-based floating aluminum pigment comprises the steps that an aluminum pigment and a silane coupling agent are subjected to a grafting reaction in the presence of an alkaline regulator, the silane coupling agent is grafted to the surfaces of aluminum particles, and a pretreated aluminum pigment is obtained; and carrying out polymerization reaction on the pretreated aluminum pigment, a hydrophilic monomer and a hydrophobic monomer under the condition of an initiator, and coating the surfaces of aluminum particles with an amphiphilic polymer to obtain the water-based floating aluminum pigment. According to the water-based floating aluminum pigment and the preparation method thereof provided by the invention, after the aluminum pigment is modified by using a silane coupling agent, the surfaces of aluminum particles are coated with a layer of amphiphilic polymer, so that the floating performance of the obtained aluminum pigment is improved, and meanwhile, the corrosion-resistant effect of the aluminum pigment is improved.

The invention provides a functional nanofiber material as well as a preparation method and application thereof, and the preparation method comprises the following steps: (1) adding raw materials into water to form an electrostatic spinning solution; performing electrostatic spinning to obtain a nanofiber membrane; (2) cross-linking the nanofiber membrane in an organic solvent under the catalysis of acid to obtain a cross-linked nanofiber membrane; and (3) carrying out grafting reaction on the cross-linked nanofiber membrane in a polyamine cross-linking agent, and then reacting with a sulfur-containing reagent to obtain the functional nanofiber material, the functionalized nanofiber material prepared by the preparation method disclosed by the invention combines good biocompatibility of polyvinyl alcohol, high specific surface area and high porosity of nanofiber and a synergistic adsorption effect of the polyamine cross-linking agent and cysteine, and has the advantages of large adsorption capacity, high adsorption rate, strong selectivity, good biocompatibility, stable structure and the like; the heavy metal ions in the plasma can be efficiently and safely removed, and a plurality of defects of the existing adsorption material are overcome.

The invention discloses a preparation method of a high-performance boehmite coating diaphragm based on photocuring interface grafting, and belongs to the technical field of lithium ion battery materials. The method comprises the following steps: carrying out surface vinyl activation on boehmite particles, and carrying out plasma activation on a polyethylene diaphragm base material; mixing the activated boehmite particles with a thiolated polyurethane acrylate solution containing a photoinitiator to prepare slurry; and after coating, carrying out ultraviolet irradiation in a wet coating state, synchronously initiating acrylate polymerization, sulfydryl-alkene click reaction and free radical grafting reaction, and finally drying and curing to obtain the product. By constructing a covalent bonding interface, the interface bonding strength, the thermal stability and the electrochemical performance of the diaphragm are remarkably improved, the problem that a traditional coated diaphragm is easy to peel off is solved, and the preparation method is suitable for manufacturing a high-performance lithium ion battery.

The invention discloses a high-temperature-resistant flame-retardant wire harness and a preparation method thereof, and relates to the technical field of electric harnesses. The method comprises the following steps: firstly, introducing phosphorus and silicon flame-retardant elements on a polyethylene molecular chain through plasma activation and free radical grafting reaction to prepare phosphorus-silicon grafted modified polyethylene, then compounding aminated silicon dioxide and organic intercalated montmorillonite by using isophorone diisocyanate as a bridging agent to prepare the phosphorus-silicon grafted modified polyethylene composite material. The preparation method comprises the following steps: preparing an isocyanate-bridged silicon dioxide-montmorillonite composite filler to improve the dispersity and compatibility of the filler in a matrix, carrying out extrusion granulation on modified polyethylene, an ethylene-butyl acrylate copolymer, maleic anhydride grafted polyethylene, the composite filler, nano magnesium hydroxide and other additives to prepare polyethylene wire harness particles, and finally, carrying out extrusion granulation on the polyethylene wire harness particles to prepare the cable harness. And coating the surface of a copper core wire with the particles through a single-screw extrusion coating machine, and carrying out subsequent water cooling, steam treatment, drying and rolling to obtain a finished wire harness. The wire harness prepared by the invention has excellent high temperature resistance and flame retardance.

The invention discloses delayed coagulation type super-early-strength quick-hardening mortar and a preparation method thereof, and relates to the technical field of building materials, a shell-core structure targeted modified early strength agent is designed, a staged dry-wet mixing technology is adopted, seabed in-situ curing is combined, cooperation of mortar delayed coagulation construction and super-early-strength development is achieved, and the construction efficiency is improved. According to the present invention, with the design of the targeted modified early strength agent, the surface delayed coagulation shell and the core early strength core structure are formed through the grafting reaction of the sodium nitrite and the hydroxyl carboxylic acid monomer, and the 15-25% accurate grafting rate control is matched, such that the antagonism problem of the traditional early strength agent and the delayed coagulation agent can be solved, and the deep sea open caisson grouting temporary support requirement can be met; in the deep sea environment, the delayed coagulation shell can guarantee a construction window of 75-105 min, the requirement for long-distance grouting of the seabed is met, deep sea high pressure can trigger the delayed coagulation shell to be broken, the core early strength core rapidly activates cement to be hydrated, and the mortar can rapidly form the requirement for rapid bearing of the open caisson temporary support with enough strength.

The invention provides a polyglutamic acid granular fertilizer and a preparation method thereof, and the preparation method comprises the following steps: S1, dissolving lignin in an alkaline solution, and heating until the lignin is dissolved; adding epsilon-polylysine fermentation liquor, mixing, heating, adding a formaldehyde solution, and carrying out grafting reaction to obtain epsilon-polylysine grafted lignin; s2, mixing the epsilon-polylysine grafted lignin solution and the gamma-polyglutamic acid solution, adding N-hydroxysuccinimide, standing at a low temperature, adding 1-ethyl-(3-dimethylaminopropyl) carbodiimide hydrochloride, and mixing; carrying out gradient temperature reaction to obtain lignin grafted epsilon-polylysine / gamma-polyglutamic acid hydrogel; and S3, homogenizing the lignin-grafted epsilon-polylysine / gamma-polyglutamic acid hydrogel, carrying out normal-temperature high-pressure airflow crushing, and spraying the crushed hydrogel to the surfaces of particles obtained by granulating a basic material through high-pressure electrostatic spraying, so as to obtain the polyglutamic acid granular fertilizer. The obtained polyglutamic acid granular fertilizer has relatively strong water-retaining and slow-release (releasing water, urea and the like) effects.

The invention discloses a power battery insulation pressure-sensitive adhesive and a preparation method thereof, and belongs to the technical field of high-molecular polymer materials, the power battery insulation pressure-sensitive adhesive comprises an insulation base material, a fluorine grafting agent, a phosphorus grafting agent, silicon-based resin, a cross-linking agent and a platinum catalyst, the preparation method comprises the following steps: S1, fluorine side chain grafting; s2, phosphorus side chain grafting; s3, dispersing the silicon-based resin; s4, carrying out a cross-linking reaction; and S5, impurity removal and purification. Through a fluorine-phosphorus side chain grafting reaction, the balance of initial viscosity and persistent viscosity of a system is optimized, a synergistic protection system is constructed, a fluorine element forms a compact permeation barrier, a phosphorus element provides an efficient char forming flame retardant site, and an insulating framework of PHMS and a cross-linked network of PHS are matched, so that the flame retardant performance of the composite material is improved. The problems of insufficient insulation stability, unbalanced initial viscosity and persistent viscosity and poor flame retardance caused by lack of targeted function modification in the prior art are solved, and the pressure-sensitive adhesive has the potential of being applied to preparation of a power battery pressure-sensitive adhesive.

The invention discloses an anti-ultraviolet functional plastic particle and a preparation method thereof, and belongs to the technical field of polymer modified materials. The plastic particles are prepared from polyolefin resin subjected to organic silicon-phenolic hydroxyl synergistic grafting modification, 2, 4-dihydroxyacetophenone, an antioxidant, a hindered amine light stabilizer, a lubrication dispersant and an anti-yellowing agent. A siloxane-phenolic hydroxyl bifunctional chain segment is introduced into the surface of a molecular chain of the polyolefin resin subjected to organic silicon-phenolic hydroxyl synergistic grafting modification, so that a flexible-rigid synergistic interface layer is formed; the 2, 4-dihydroxyacetophenone has a hydroxyl and carbonyl conjugated structure and can form hydrogen bond complexation with a matrix, so that free radical degradation is effectively inhibited. The preparation method disclosed by the invention comprises the following three steps: grafting reaction of polyolefin resin subjected to organic silicon-phenolic hydroxyl synergistic grafting modification, high-speed mixing and melt blending granulation. Tests show that after the plastic particles are subjected to 365nm ultraviolet radiation for 500h, the tensile strength retention rate exceeds 94%, the chromatic aberration delta E is less than or equal to 1.5, the oxidation induction time is prolonged to 55min, and the plastic particles have excellent ultraviolet aging resistance, yellowing resistance and thermal oxidation stability.

The invention discloses a supercapacitor with a high specific surface area and a preparation method thereof, and relates to the technical field of supercapacitors. Comprising the following steps: performing layer-by-layer cladding forming on TC4 alloy powder to obtain a three-dimensional bionic curved surface structure with Gyandroid topology in a three-period minimal curved surface, and forming a randomly distributed microcosmic columnar bulge structure on the surface of the three-dimensional bionic curved surface structure as a metal current collector; polyaniline is continuously deposited to form a film along the three-dimensional bionic curved surface structure and the surface microcosmic columnar protrusion structure of the three-dimensional bionic curved surface structure in a pulse electrodeposition mode, and a TC4-coated PANI electrode is obtained; the preparation method comprises the following steps: preparing a three-dimensional bionic curved surface structure, performing grafting reaction on polyvinyl alcohol and an epoxy compound containing a quaternary ammonium group under an alkaline condition to prepare a PVA-g-TMAC polymer, preparing a PVA-g-TMAC hydrogel electrolyte, injecting the PVA-g-TMAC hydrogel electrolyte into a mold, arranging two TC4-coated PANI electrodes in the mold according to a preset interval, clamping the three-dimensional bionic curved surface structure, and performing freeze thawing and consolidation to obtain the supercapacitor with a sandwich structure.

The invention discloses a high-temperature-resistant low-friction-coefficient low-abrasion sealing material and a preparation method thereof, and belongs to the technical field of sealing materials. The sealing material is prepared from the following raw materials in parts by mass: 60 to 80 parts of hydrogenated butadiene-acrylonitrile rubber, 20 to 40 parts of hydrogenated carboxyl butadiene-acrylonitrile rubber, 40 to 50 parts of carbon black N234, 4 to 6 parts of modified carbon fiber, 2 to 4 parts of modified hexagonal boron nitride, 3 to 5 parts of liquid polybutadiene, 3 to 4 parts of composite vulcanizing agent, 2 to 3 parts of zinc oxide, 1 to 2 parts of rubber anti-aging agent 445, 1 to 2 parts of anti-aging agent MB, 0.2 to 0.5 part of accelerant BZ and 0.5 to 2 parts of stearic acid. The modified carbon fiber is obtained by growing molybdenum disulfide on the surface of carbon fiber in situ and performing amination modification, the modified hexagonal boron nitride is obtained by performing grafting reaction on hydroxylated hexagonal boron nitride and an epoxy silane coupling agent, and the sealing material provided by the invention has high wear resistance and high temperature resistance.

The invention discloses a preparation method and application of a hydrophobic air filtering material based on lignin modification, and belongs to the technical field of personal protective articles. According to the method, environment-friendly lignin and a silane coupling agent are subjected to a pre-grafting reaction to prepare a functionalized impregnation liquid, a mask melt-blown cloth filter material is modified, and the modified mask melt-blown cloth filter material serves as a long-acting hydrophobic mask filter material to prepare a mask. According to the invention, a firm hydrophobic network is constructed on the surface of the fiber by utilizing the'molecular bridge 'effect of silane. The modified filter material prevents the filter efficiency from being reduced due to moisture, and meanwhile, the coating is resistant to airflow scouring through chemical bonding, so that the protective life of the mask is prolonged. Compared with a reported modification method, the preparation method disclosed by the invention has the comprehensive advantages of environmental friendliness, low cost and lasting performance.

The invention discloses a wear-resistant anti-icing easy-to-deice coating for power equipment and a preparation method thereof, and relates to the technical field of coatings. The wear-resistant anti-icing easy-to-deice coating for the electrical equipment is prepared from the following raw material components in parts by weight: 40 to 60 parts of water-based fluorocarbon resin dispersion, 5 to 15 parts of perfluorosilane surface modified filler, 3 to 10 parts of light-absorbing heating material, 0.5 to 2 parts of wetting dispersant, 0.2 to 0.6 part of defoaming agent, 0.2 to 1 part of flatting agent, 0.5 to 1 part of anti-aging agent, 15 to 25 parts of deionized water and 12 to 20 parts of water-based isocyanate curing agent. The perfluorosilane surface modified filler is obtained by modifying a filler with a perfluorosilane coupling agent; the light-absorbing heating material is a Fe3O4 / C composite material or a product obtained by further modifying the Fe3O4 / C composite material through a vinyl silane coupling agent and then reacting and grafting with amino-terminated hyperbranched polyamide.

The application belongs to the technical field of flexible piezoelectric materials, and discloses a grafted ferroelectric polymer thin film with a high piezoelectric coefficient and a preparation method thereof, wherein the preparation method comprises the following steps: obtaining a polymer solution by selecting a polyvinylidene fluoride-based ferroelectric polymer; adding a grafting agent reagent to the polymer solution and uniformly mixing to obtain a mixed solution; uniformly casting the mixed solution on the surface of a glass substrate, heating in an oven to volatilize the solvent, then increasing the temperature of the oven to perform a grafting reaction to obtain a grafted thin film; after the oven is naturally cooled to room temperature, the grafted thin film is peeled off from the glass substrate, and a polarization process is adopted to obtain the grafted ferroelectric polymer thin film with a high piezoelectric coefficient. The polyvinylidene fluoride-based ferroelectric polymer is modified by grafting side chains, the relative stability of different molecular conformation energies in the ferroelectric polymer is regulated by grafting side chains in the polymer, the ferroelectric phase and the relaxor phase in the ferroelectric polymer are induced to compete with each other, and the piezoelectric coefficient of the material is significantly improved.

The invention belongs to the technical field of functional coatings, and particularly relates to a static conductive coating for nonmetal and a preparation method of the static conductive coating. The coating is composed of modified Si-C fluorosilicone resin, conductive nickel powder, ethandiamide and multiple auxiliaries, the modified Si-C fluorosilicone resin is prepared through a double-grafting reaction of mercaptoethanol and vinyl trifluoroacrylate,-S-and-CF groups are introduced into molecules at the same time, and the polarity of the resin and the dispersity of the conductive nickel powder are remarkably improved. The oxadiamide as a polar small molecule synergist can promote the formation of a conductive network and enhance the interface bonding force. The surface resistivity of the obtained coating is about 2.8 * 10 omega / square, the static decay time is 0.38 s, the adhesive force reaches 5B, and the conductivity retention rate after wear resistance exceeds 97%. The coating has excellent static conductivity, adhesive force and environmental stability, is suitable for the surfaces of non-metal base materials such as ABS, PVC and polycarbonate, and can be widely applied to the fields of electronic equipment shells, rail transit interior trim parts, anti-explosion and anti-static terraces and the like.

This invention relates to the field of functional fiber technology, specifically to a method for preparing polyester staple fibers with deodorizing and antibacterial functions. The method includes preparing hydroxyl-loaded polyester masterbatch, preparing polyester fibers and grafting them, and post-treatment. This invention prepares hydroxyl-rich polyester masterbatch by adding high-temperature resistant hydroxyl-rich nanoparticles to polyester powder, and then adds the hydroxyl-rich polyester masterbatch to the spinning of polyester staple fibers. This increases the number of active hydroxyl groups on the surface of the polyester fibers, solving the problem that polyester itself does not have active groups and cannot be directly grafted onto the surface of pure polyester fibers. The active hydroxyl groups of modified cyclodextrin undergo nucleation and addition reactions with isocyanate groups, replacing high-temperature esterification and radiation crosslinking reactions, resulting in low energy consumption and environmental friendliness. The desealing temperature of the water-based end-capped polyisocyanate is consistent with the drying and relaxation setting temperatures in polyester staple fiber production, triggering the nucleation and addition reaction and solving the problem of side reactions caused by excessively active isocyanate groups.

The invention belongs to the technical field of medical polymer materials, and particularly relates to a preparation method of a surgical anti-adhesion hydrogel material. The material is prepared from 2, 3-diformylbenzoic acid modified gelatin, 3, 4-dihydroxyphenylethylamine, sodium hyaluronate, sodium tripolyphosphate, hydrogen peroxide, ascorbic acid and a phosphate buffer solution. Modified gelatin powder is obtained through a grafting reaction of 2, 3-diformylbenzoic acid and gelatin, then the modified gelatin powder, 3, 4-dihydroxyphenylethylamine and an auxiliary agent are prepared into a main gel solution, hydrogen peroxide and ascorbic acid are added before use, and the main gel solution is quickly crosslinked into gel under the body temperature condition. The obtained hydrogel can be stably combined with the tissue surface, the degradation process is matched with tissue repair, and the hydrogel has a free radical scavenging effect. Animal experiments show that the material can effectively reduce abnormal adhesion between postoperative tissues and has a good clinical application prospect.

The invention relates to the technical field of organic pollution treatment, in particular to a lignin grafted graphene oxide quantum dot material, a preparation method thereof and a polycyclic aromatic hydrocarbon degradation method, and the material is prepared by grafting reaction of alkaline lignin and graphene oxide quantum dots under alkaline conditions. When the strain is applied to degradation of polycyclic aromatic hydrocarbon, the strain and a Microbacterium sp.W1-2 strain with the preservation number of CGMCC (China General Microbiological Culture Collection Center) NO.35223 form a synergistic degradation system. The material can significantly promote thallus growth, enhance pollutant interface mass transfer and bioavailability, and realize efficient degradation in a dark environment without photocatalysis. Experiments show that under the condition that the initial concentration of benzo [a] pyrene is 5000g / L, by adding the material, the degradation rate within 6 hours can be increased to 651.4 g / h, which is increased by 2.9 times compared with that of a single strain; and the removal rate within 72 hours reaches 86.4%. The method has the advantages of being high in degradation efficiency, short in period, high in environmental adaptability, independent of illumination and the like, and is suitable for rapidly repairing the polycyclic aromatic hydrocarbon in the industrial wastewater.

This invention discloses an enzyme-responsive silk fibroin nanovesicle, its preparation method, and its application, comprising the following steps: silk fibroin is mixed with a hydrophobic acylation reagent containing enzymatically cleavable chemical bonds and a catalyst for a grafting reaction to obtain amphiphilic modified silk fibroin; the amphiphilic modified silk fibroin is mixed with hair care active ingredients in an aqueous phase, and self-assembly is induced to form nanovesicles encapsulating the active ingredients through ultrasonic treatment or high-pressure homogenization. This invention uses silk fibroin as the main body to provide a biocompatible framework and self-assembly basis. Hydrophobic groups are introduced through chemical modification, and these hydrophobic groups are connected to the silk fibroin backbone through enzymatically cleavable chemical bonds. These chemical sites can be recognized and cleaved by sebaceous lipase secreted by the scalp sebaceous glands or other specific lipases highly expressed in the hair follicle microenvironment, achieving specific enzymatic release of the nanovesicles in the hair follicle microenvironment.

The invention discloses a preparation method of a catalytic ceramic hydrophobic modified membrane, which comprises the following steps: step 1, pretreating a membrane base material to obtain a clean membrane base material; step 2, immersing a clean membrane substrate into the catalyst precursor solution, repeatedly performing ultrasonic-assisted impregnation, taking out, drying and roasting treatment, so that catalytic nanoparticles grow in situ on the surface and in pore channels of the membrane substrate and are firmly loaded to obtain a ceramic membrane substrate; and step 3, immersing the ceramic membrane substrate into the silane ethanol hydrolysate, carrying out a grafting reaction, and after the reaction is completed, cleaning and drying to prepare the catalytic ceramic hydrophobic modified membrane. The invention also discloses a catalytic ceramic hydrophobic modified membrane. The invention also discloses an application method of the catalytic ceramic hydrophobic modified membrane. The problems that a membrane base material of a traditional membrane only has a separation function and lacks catalytic activity, efficient degradation of pollutants is difficult to achieve, and consequently the wastewater treatment efficiency is low are solved.

The application discloses a polymer crosslinking system with a siloxane structure for deep profile control. A preparation method of the polymer crosslinking system for deep profile control comprises the following steps: S1, in an inert atmosphere, under the condition that an initiator exists, performing a polymerization reaction on nonionic monomers, anionic monomers and an epoxy monomer in water to obtain an epoxy polymer; S2, in an inert atmosphere, performing a grafting reaction on polyethyleneimine, an epoxy compound-1 and an epoxy compound-2 in an organic solvent to obtain a silicon-containing polymer; and S3, performing a crosslinking reaction on the epoxy polymer and the silicon-containing polymer in water to obtain the polymer crosslinking system. The polymer crosslinking system has certain delayed crosslinking characteristics and excellent temperature resistance and salt resistance.

This invention relates to the field of fire-retardant coating production technology, specifically to a water-based intumescent fire-retardant coating, its preparation method, and its application. The coating comprises, by weight, 25-35 parts of a water-based acrylic emulsion, 40-60 parts of a flame retardant, 15-25 parts of water, 5-10 parts of titanium dioxide, and 1-5 parts of a film-forming aid. Its core lies in the use of N-methylpiperazine-modified ammonium polyphosphate as a single-component flame retardant. This modified flame retardant integrates an acid source, a carbon source, and a gas source at the molecular scale. Compared to traditional physical compounding systems and sterically hindered substituent modification schemes, this invention utilizes the low steric hindrance and excellent hydrophilic-philic balance of N-methylpiperazine to significantly improve the uniformity and controllability of the grafting reaction, and improve the dispersion stability and compatibility of the flame retardant in the water-based emulsion.

The application relates to the field of sewage treatment, and discloses a sulfur autotrophic denitrification biofilter composite filler and a preparation method thereof. The method comprises the following steps: carrying out a silane hydrolysis reaction on a silane coupling agent containing a mercaptan group to prepare a hydrolysis solution, and then adding hydroxylated polystyrene microspheres into the hydrolysis solution to carry out a grafting reaction and prepare the sulfur autotrophic denitrification biofilter composite filler. The method grafts mercaptan groups to the surface of the polystyrene microspheres by using the silane coupling agent containing the mercaptan group. The mercaptan groups can specifically combine with sulfur transport proteins on the cell membrane of sulfur autotrophic denitrification microorganisms, so that the sulfur autotrophic denitrification microorganisms can selectively colonize on the surface of the polystyrene microspheres, competition between other microorganisms and the sulfur autotrophic microorganisms can be avoided, the colonization stability of the sulfur autotrophic microorganisms is improved, and the biofilm formation efficiency is improved.

The application discloses an anti-ultraviolet heat-insulating polypropylene material and a preparation method thereof, and relates to the technical field of high-performance polypropylene, which comprises the following components: 65-85 parts of polypropylene resin, 5-20 parts of a compatilizer, 3-30 parts of a filler, and 0-5.0 parts of an auxiliary agent; the filler is composed of hollow glass beads with low thermal conductivity and mica powder with sheet layer barrier capacity, and the filler is surface-modified; the anti-ultraviolet compound is chemically bonded to the surface of the filler through Zn-Ti co-deposition and PDA-mediated grafting reaction, the polarity of the filler is improved, the dispersibility of the filler in the polypropylene resin is improved, the interfacial bonding force between the polypropylene is improved, the stress concentration is reduced, the tensile strength and impact toughness of the material are improved, and the overall mechanical property is enhanced; the modified filler can effectively absorb UVB / UVA, the hydroxyl phenyl structure of the modified filler can effectively quench free radicals, and the ultraviolet shielding property of the modified filler and the polypropylene material is improved.

The invention belongs to the technical field of coatings, and particularly relates to a coating for a galvanized plate and a preparation method thereof. According to the invention, molybdenum disulfide is modified by using graphene oxide and carbon nanotubes. Compared with an inert structure of a molybdenum disulfide nanosheet, a graphene oxide sheet layer contains a large number of oxygen-containing functional groups, and dispersion of the molybdenum disulfide nanosheet in the waterborne polyurethane coating can be effectively improved by modifying the molybdenum disulfide nanosheet through graphene oxide. The one-dimensional-structure carbon nanotubes added in the grafting reaction process of the graphene oxide and the modified molybdenum disulfide nanosheets can effectively prevent agglomeration of the nanosheet layers in the reaction process, so that uniform modification of the molybdenum disulfide nanosheets is ensured; and moreover, the carbon nanotubes have relatively high specific strength and specific modulus, and the added carbon nanotubes can form an interactive network with the graphene oxide and the molybdenum disulfide nanosheets, so that the mechanical property and the corrosion resistance of the waterborne polyurethane coating are greatly improved.

The invention relates to a preparation method and application of modified resin for adsorbing gallium in an acid system, belongs to the technical field of separation and extraction of rare metals, and solves one of the problems of small resin adsorption capacity, poor selectivity and the like in the existing gallium extraction process of a resin adsorption method. Comprising the following steps: cleaning substrate resin which is macroporous resin with weakly alkaline active sites; mixing the cleaned substrate resin and the modifier aqueous solution to obtain a mixed solution, introducing inert gas into a reaction container, adding an initiator into the mixed solution, stirring to carry out a grafting reaction, continuously introducing the inert gas during the reaction, and carrying out solid-liquid separation after the reaction is ended to obtain wet modified resin; and carrying out washing, suction filtration and vacuum drying on the wet modified resin to obtain the finished product modified resin. The total exchange capacity of the resin and the selective adsorption capacity of gallium ions are improved. The modified resin prepared by the method has large adsorption capacity on gallium in an acid system.

The invention relates to a PET (Polyethylene Terephthalate) base film for a composite current collector and a preparation method of the PET base film. The PET base film comprises PET slices, modified PET, modified silicon dioxide, a lubricant and an antioxidant, wherein the modified PET is obtained by esterification and polycondensation of terephthalic acid, ethylene glycol and an imidazole-containing diol monomer; the imidazole-containing diol monomer is composed of a compound A shown in the formula and a compound B shown in the formula, the modified silicon dioxide is obtained by treating nano silicon dioxide particles by using a silane coupling agent KH560 and then carrying out ring-opening grafting reaction on the treated nano silicon dioxide particles and a compound A. According to the invention, a bi-component diol monomer containing an imidazolyl group is introduced into a PET main chain, and a compound A is grafted on the surface of nano silicon dioxide, so that dual enrichment of the imidazolyl group on a base film body and the surface is realized, the mechanical modulus and the heat resistance of the base film are enhanced, the base film is not easy to deform in a high-temperature coating environment, and the service life of the base film is prolonged. And meanwhile, the problem that the metal layer is easy to fall off is effectively solved.

The application discloses a preparation method of a reversible crosslinking POE ionomer, and comprises the following process: POE, a multi-vinyl ionic compound, a grafting aid and an initiator are blended to obtain a mixture; the mixture is subjected to a melt grafting reaction through a double-screw extruder, and POE ionomer is obtained after extrusion and granulation. The POE ionomer provided by the application has improved mechanical strength and elongation at break, and still has a very high performance retention rate and excellent reprocessing characteristics after secondary processing.

The invention discloses a self-lubricating PEEK-based composite material and a preparation method thereof, and belongs to the technical field of PEEK composite materials. The self-lubricating PEEK-based composite material is prepared from the following raw materials in parts by mass: 100 parts of polyether-ether-ketone resin, 10 to 15 parts of polyarylene sulfide ketone, 5 to 10 parts of polyarylene sulfide amide, 15 to 25 parts of epoxy group modified MoS2atCO-SiO2 nano material, 4 to 12 parts of modified carbon fiber and 1 to 2 parts of antioxidant. Wherein the modified carbon fiber is obtained by carrying out acylation reaction on carboxylated carbon fiber and then carrying out grafting reaction on the carboxylated carbon fiber and 2-aminodiphenyl sulfide. According to the invention, polyether-ether-ketone, polyarylene sulfide ketone and polyarylene sulfide amide are blended to form a polymer matrix of the PEEK-based composite material, and the epoxy group modified MoS2atCO-SiO2 nano material and the modified carbon fiber are used as lubricating components, so that the composite material has an excellent self-lubricating effect under the combined action.

The invention discloses a functional fabric preparation method and finishing equipment for realizing fabric functionalization, and relates to the technical field of textile fabric functionalization and finishing equipment. According to the preparation method of the functional fabric, the functional finishing agent and fabric fibers can be triggered to be subjected to chemical grafting reaction through ultraviolet irradiation and / or heating, and the textile fabric is subjected to one-time continuous multifunctional finishing; the finishing equipment comprises two functional modules, an ultraviolet light initiation module and a thermal initiation module, can support different finishing processes of fabrics, realizes chemical covalent bond grafting reactions of different principles, has strong production operability and high flexibility, and has ideal popularization and application values in the fields of textile fabric finishing and engineering.