281results about "Retention agents addition" patented technology

The present invention discloses a water-based emulsion of PHA, PBAT and PVOH and its application in paper-based barrier coatings. This emulsion is prepared by first melt-blending PHA and PBAT at 150-170 °C and then dispersing them into an aqueous PVOH solution at 80-95 °C. Plasticizers, cross-linking agents and surfactants can be added to improve the performance. After coating on paper and drying at 80-150 °C, a barrier film with a Cobb value of 10-15 g / m² and a Kit ≥ 10 grade is formed. Compared with traditional PE film laminating or fluorine-containing coatings, this system is more environmentally friendly and recyclable; PVOH dissolves in pulping water, PHA and PBAT are easily separated, and fibers can be efficiently recovered; in composting, soil and marine environments, PHA and PBAT have extensive biodegradability and are superior to PLA which is difficult to recycle and requires industrial composting. It is applicable to food, industrial, special packaging and agricultural paper products.

The invention discloses a PHA (polyhydroxyalkanoate), PBAT (poly (butyleneadipate-co-terephthalate)) and PVOH (polyvinyl alcohol) blended water-based emulsion and application thereof in a paper-based barrier coating. The emulsion is prepared by performing melt blending on PHA and PBAT at 150-170 DEG C and then dispersing the mixture into a PVOH aqueous solution at 80-95 DEG C, and a plasticizer, a cross-linking agent and a surfactant can be added to improve the performance. And after coating paper, drying at the temperature of 80-150 DEG C to form the barrier film with the Cobb value of 10-15g / m and the Kit greater than or equal to grade 10. Compared with a traditional PE film or fluorine-containing coating, the system is more environmentally friendly and recyclable; pVOH is dissolved in pulping water, PHA and PBAT are easy to separate, and fibers are efficiently recycled; in compost, soil and marine environments, PHA and PBAT have wide biodegradability and are superior to PLA which is difficult to recycle and re-slurry and needs industrial compost. The method is suitable for food, industrial, special packaging and agricultural paper products.

The invention relates to the technical field of papermaking, and particularly provides high-strength tipping base paper for cigarettes and a preparation process of the high-strength tipping base paper. The tipping paper base paper for the cigarettes comprises a fiber raw material; functionalizing the nano cellulose; a cellulase; a dry strength agent; a wet strength agent; and a sizing agent. Nano cellulose is functionalized and a synergistic stepped enhancement mechanism is constructed, so that the synergistic breakthrough of the high-strength raw tipping paper for cigarettes in the aspects of strength, wet strength and air permeability is realized; after the functionalized nanocellulose is subjected to carboxylation treatment, the hydrogen bond and electrostatic adsorption between the functionalized nanocellulose and the fiber are enhanced, and the bonding strength in a dry state and a wet state is remarkably improved; meanwhile, the wet strength agent is added in stages, and the adsorption sequence of the dry strength agent is optimized, so that the reinforcing agent constructs a stable three-dimensional network framework in the paper sheet, and the end breaking risk under high-speed winding is effectively reduced.

The invention discloses a cationic core-shell PHA nano-emulsion reinforcing agent as well as preparation and application thereof, and belongs to the technical field of papermaking chemicals. The problems that a traditional wet strength agent is poor in environmental protection property and difficult to recycle, and a conventional bio-based material needs high-temperature curing and is high in energy consumption are solved. According to the reinforcing agent, low-MFFT bio-based polyhydroxyalkanoate is used as a core, and a positive ion shell layer with strong positive charges is wrapped outside the core. The method has the core advantages that extra high-temperature curing is not needed, the film can be efficiently formed under the conventional 105 DEG C drying condition, and the energy consumption is remarkably reduced; meanwhile, high dry and wet strength and water resistance are achieved, the treated paper has excellent re-pulping recycling suitability, and the industrial pain point that traditional wet strength paper is difficult to recycle is solved.

The present invention belongs to the technical field of special paper preparation, and particularly relates to a production method of high-strength aluminized base paper, comprising the steps of: S1, beating: respectively beating long-fiber primary pulp and short-fiber primary pulp, wherein the beating degree of the long fiber is 40-50°SR, and the beating degree of the short fiber is 20-30°SR; S2, adding additives: adding modified inorganic filler, cationic starch and retention aid to the short-fiber pulp; S3, pulp mixing: mixing the long-fiber pulp and the short-fiber pulp according to a weight ratio, and then adding modified bamboo fiber, and uniformly stirring to form a mixed pulp; S4, wire drawing and papermaking; S5, spraying a surface treatment agent; S6, paper drying, calendering and winding. The aluminized base paper obtained by the production method of the high-strength aluminized base paper of the present invention has the advantages of high strength and good smoothness.

The invention provides a paperboard and a preparation method thereof. The preparation method comprises the steps that paper pulp is prepared, the paper pulp comprises core layer paper pulp, face lining layer paper pulp, face layer paper pulp and bottom layer paper pulp, and microfibrillated cellulose and chemical pulp are added to at least one of the face lining layer paper pulp and the bottom layer paper pulp to be ground together before grinding; making raw paper from the paper pulp; and coating surface glue on the surface of the surface layer of the body paper. According to the preparation method of the paperboard provided by the embodiment of the invention, the adding point of the MFC applied to the high-speed paper machine system is determined, the influence on the paper machine system is reduced, and dehydration of the pulp and operation of the paper machine are ensured. By combining the papermaking characteristics of a multi-layer paper machine, the surface lining layer and the bottom layer applied to the paper sheets can effectively improve the interlayer bonding strength between the paper sheets, improve TV-16, reduce the use amount of spraying starch in the conventional process or cancel the spraying starch, and improve the operation of the paper machine.

The present invention relates to a multi-ply liner for use as a packaging material for food or beverages, the multi-ply liner comprising a first ply and a second ply, wherein the first ply comprises at least 70 wt% unbleached kraft pulp and less than 30 wt% neutral sulfite semi-chemical (NSSC) pulp based on dry weight, and the second ply comprises at least 50 wt% NSSC pulp and less than 50 wt% unbleached kraft pulp based on dry weight, and the NSSC pulp in the second ply is a washed NSSC pulp having an ash content of less than 1.8 wt% determined in accordance with ISO standard 1762:2019. The present invention further relates to a method for manufacturing the multi-ply liner.

The invention relates to a composition for use in a manufacture of paper, board or the like. The composition comprises a mixture of cationic starch having amylopectin content of at least 85%, and an amphoteric polymeric structure comprising structural units originating from non-ionic monomers, preferably (meth)acrylamide, anionic groups and cationic groups, the polymeric structure comprising cationic groups at least 0.2 mol-%.

The invention provides a low-interception hollow paper tube, and belongs to the technical field of tobacco heating. The low-interception hollow paper tube has a multi-layer structure and comprises at least one low-interception layer and at least one heat-resistant layer, wherein the innermost layer of the multi-layer structure is a low-interception layer, and the low-interception layer comprises paper and a smoothing agent coating formed on the inner surface of the paper. The invention further provides a preparation method of the low-interception hollow paper tube and a heated cigarette. According to the low-interception hollow paper tube, interception of aerosol on the inner wall of the paper tube can be reduced, meanwhile, heat can be prevented from being transmitted to the acetate fiber filter tip section, and the lip scalding problem is avoided.

The invention discloses a silica powder modified paperboard material of embossed frame paper for cigarettes and a preparation method of the silica powder modified paperboard material, and belongs to the field of advanced inorganic non-metallic materials. The material comprises bleached chemical wood pulp, core-shell structure in-situ modified nano silicon micropowder, an auxiliary agent and a latent temperature-sensitive cross-linking agent, a modification system contains a compound silane coupling agent and amino modified organosilane, and a dual network of static triple cross-linking and dynamic secondary cross-linking is formed; the nanometer silicon micro powder is of a core-micro-nano protrusion-shell multilevel structure, a shell layer is thermoplastic resin containing latent epoxy groups, and a double-peak particle size distribution design is adopted. The preparation process is realized through in-situ generation modification, high-speed shearing fusion and an embossing-shaping integrated closed-loop control process, and is adaptive to an existing fourdrinier papermaking production line. The product quantification is 210-220 g / m < 2 >, the transverse stiffness is larger than or equal to 210 mN.m, the embossing retention rate is larger than or equal to 99.5%, after 50 cycles at the temperature of-5 DEG C-40 DEG C and the humidity of 30%-80%, the stiffness is reduced by smaller than or equal to 3%, the barrier property is reduced by smaller than or equal to 6%, the printing adsorption uniformity error is smaller than or equal to 3%, and the barrier property and the environmental protection property are excellent. The method solves the problems of agglomeration, embossing resilience, multi-performance contradiction, poor environmental stability and other pain points of conventional modified filler, realizes the cooperation of low quantification and high performance, conforms to the high-end and green requirements of the tobacco industry, can pass the application of strategic emerging industry priority review channels, and has a wide application prospect.

The invention belongs to the field of new materials, and relates to an ultrathin thermal insulation material and a preparation method thereof. Aiming at main problems of existing aerogel heat insulation products and actual requirements of related fields on efficient heat insulation products, in combination with functional characteristics of nano-porous silicon, natural plant fibers are taken as carriers, SiO2 aerogel, nano-porous silicon and other functional materials are uniformly mixed with the plant fibers, and the composite material is prepared. And an environment-friendly and degradable new product with heat preservation and heat insulation functions is obtained through a papermaking process. The heat conductivity coefficient of the obtained ultrathin heat preservation and insulation material is smaller than or equal to 0.025 W / (m.K), and a convenient method is provided for large-scale and continuous production of the low-cost ultrathin heat preservation and insulation material. The method is easy and flexible to operate, high in operability and easy to industrially popularize and apply.

The invention relates to a preparation method of high-substitution-degree cationic micro-nano cellulose and application of the high-substitution-degree cationic micro-nano cellulose to improvement of water filtering performance of paper. In the enzymolysis pretreatment process, beta-1, 4 glucosidic bonds among glucose molecules are cut off, and more reaction binding sites are created for cationization after cellulose in an amorphous region and a part of crystalline region is hydrolyzed, so that the use amount of chemical reagents can be effectively reduced, and the environmental pollution is reduced. The prepared high-substitution-degree cationic micro-nano cellulose (CMFC) has abundant positive charges, weakens the hydrogen-bond interaction of cellulose molecules, improves the content of nano-fibrillation, and effectively reduces the mechanical preparation energy consumption of the CMFC. CMFC pulp is added into paper pulp fibers, so that pores of the paper fibers are blocked, more filler is intercepted, and the filler is difficult to be completely brought into white water by water flow in the water filtering process, so that the retention rate is increased, and the water filtering performance is effectively improved.

The invention discloses a preparation technology of collection paper literature deacidification test paper, and belongs to the technical field of papermaking engineering. The method comprises the following steps: firstly, determining physicochemical indexes of the deacidification test paper according to ontology characteristics of precious ancient books and recent modern paper literatures, then taking saponified rosin size as an internal sizing agent, taking talcum powder as a filler, taking cationic polyacrylamide (CPAM) as a retention aid, and finally, carrying out papermaking and drying to obtain the deacidification test paper. The performance of the product prepared by the process is basically consistent with that of recent modern literature paper, the product has the capability of replacing a paper literature body to carry out lossy testing, and a more reliable, more comprehensive and more economical basis can be provided for constructing a deacidification effect evaluation system.

The invention discloses an acid-neutral nano PHA paperboard reinforcing agent as well as preparation and application thereof, and belongs to the technical field of papermaking chemicals. The reinforcing agent is a bio-based nano water-based emulsion, and the core of the reinforcing agent is that a stable high-positive-charge nanoparticle interface is constructed under an acid-neutral window through the synergistic effect of polyphenol and an amine polymer. The environment-friendly wet strength agent solves the potential safety hazard of the traditional wet strength agent, and does not contain free formaldehyde and epichlorohydrin. The method has the outstanding advantages that the method is completely compatible with a modern papermaking acid-neutral process, and the defect that the similar bio-based technology needs to react under alkalinity is overcome; the adhesive is flexible to apply, can be efficiently used for wet end addition, or can be stably compounded with oxidized starch for surface sizing; the preparation method is simple, efficient and energy-saving, can realize excellent wet strength retention rate and dry strength improvement under the conditions of low addition amount and conventional industrial drying at 105 DEG C, and does not need extra high-temperature curing.

Provided is a method for the production of vinylcarboxamide-containing polymers in a granular, beaded, powdered, or particulate form and subsequent hydrolysis thereof. The vinylcarboxamide-containing polymers and co-polymers, are precipitated in a granular, beaded, powdered, or particulate form employing an inverse suspension polymerization technique.

There is provided a method of forming a multilayer paperboard comprising a top layer, a back layer and a middle layer, wherein the method comprises the following steps: - providing a top layer furnish comprising at least 50% by dry weight kraft pulp; - providing a middle layer furnish comprising 25-75% by dry weight of maple chemithermomechanical pulp (CTMP) and 15-65% by dry weight of broke pulp; - adding a cationic retention aid to the middle layer furnish in an amount of 250-700 g / tonne based on dry weight of the middle layer furnish; - adding an anionic retention aid to the middle layer furnish in an amount of 420-700 g / tonne based on dry weight of the middle layer furnish; - providing a back layer furnish comprising at least 80% by dry weight kraft pulp; - form a top layer from the top layer furnish, a middle layer from the middle layer furnish, and a back layer from the back layer furnish; and - form a multilayer paperboard from the top layer, middle layer and back layer so that the middle layer is arranged between the top layer and back layer.

The invention discloses a fiber synergistic copolymer as well as a preparation method and application thereof, and belongs to the technical field of papermaking chemicals and high polymer materials. Aiming at anion garbage interference caused by deepening of closed circulation of white water in the papermaking industry and green compliance challenges caused by replacing plastic with paper, the copolymer adopts a specific polycarboxylic acid and trace cationic monomer structure-effect design, and has excellent anti-interference capability and permeability. In the wet-end in-pulp enhancement, the enhancement effect of the additive can be superior to that of a traditional high-molecular-weight additive only by a relatively low addition amount, and water filtration and retention are remarkably improved; in a surface sizing and pulp molding hot pressing process, the rigidity and the water-resistant size stability of a product can be greatly improved through a unique cross-linking mechanism. According to the scheme, the industrial pain point of low enhancement efficiency in a complex environment is effectively solved, and the product does not contain organic fluorine and completely meets the requirements of environmental protection and sustainable development of a high-performance fiber-based material.

Sanitary tissue products, which may be creped, having non-wood fibers and exhibits a coverage greater than about 5.5 fiber layers and a fiber count-area (C(n)) greater than about 830 million / m2 and / or a coverage greater than about 7.5 fiber layers and / or a coverage greater than a line defined by an expression: Y=0.00767X+3.0 (wherein the fiber coverage is “Y” and wherein a fiber count-area (C(1)) is “X”) are provided.

The invention relates to the technical field of water-soluble polymer chemical polymerization reaction, in particular to a preparation method of a star-shaped polyacrylamide papermaking retention and drainage aid, which adopts a'core-first arm-second arm 'polymerization mode and a redox initiation system, and realizes a star-shaped structure of a product through multi-step process control. The preparation method comprises the following steps: carrying out solution polymerization and redox initiation on a star-shaped skeleton, acrylamide and a cationic monomer to obtain a colloid, and finally drying, crushing and sieving to obtain the star-shaped polyacrylamide polymer. Compared with a similar polyacrylamide retention and drainage aid, the polyacrylamide retention and drainage aid can be well used for increasing the retention rate of pulp and filler and improving the water filtering performance in the field with more complex papermaking wet end chemical environment as a retention and drainage aid, has better paper pulp water filtering and retention performance, and has a wide application prospect.

The present invention discloses a preparation method of titanium dioxide for high-covering and high-lightfast laminated paper, comprising the following steps: S1. Take the initial product of titanium dioxide to prepare a titanium dioxide-based material slurry; S2. Adjust the pH of the slurry to 8-12, and at the same time add a magnesium source, a silicic acid source and a pH regulator, and maintain the countercurrent pH at 8-12 to homogenize and form a magnesium silicate film layer; S3. Adjust the pH of the slurry to 5-6, and at the same time add an aluminum source and a phosphoric acid source, and maintain the countercurrent pH at 5-6 to homogenize and form an aluminum phosphate film layer after homogenization; S4. Add a first aluminum source to adjust the pH to 11-13 and homogenize; then add a second aluminum source to adjust the pH to 3-5 and homogenize; finally add a third aluminum source to adjust the pH to 6.5-7.5 and homogenize to form a polycrystalline composite alumina film layer. The product obtained in this application has a uniform and dense film layer and high retention rate, lightfastness and covering power, making it can be well applied to laminated paper.

A drainage-optimized additive composition for papermaking is disclosed. The composition comprises an aqueous media and a glyoxalated polyacrylamide (gPAM) resin having a weight average molecular weight (Mw) of at least about 5 MDa. The composition comprises from about 1.95 to about 2.45 wt. % of the gPAM resin. A method of preparing the composition is also disclosed, and comprises preparing a cationic acrylamide (cAM) prepolymer having at least one predetermined property, and selectively glyoxalating the cAM prepolymer by controlling the concentration of the cAM prepolymer in the aqueous media during glyoxalation in relation to the predetermined property. The method may be carried out in situ during a papermaking process (i.e., as an on-site method). A process of forming paper with the composition also disclosed, and comprises combining the composition with the aqueous suspension of cellulosic fibers, forming the cellulosic fibers into a sheet, and drying the sheet to produce a paper.

The present invention generally relates to methods and compositions for manufacture of tissue, paper, or board and for enhancing retention and drainage thereof. In particular, the disclosure provides methods for enhancing retention and drainage by addition of a retention and drainage aid comprising quick inversion cationic emulsion polyacrylamides (QIC-EPAMS) and polyvinylamine (PVAm) polymers Preparation of paper sheets under these conditions provides improved retention, gravimetric drainage rates, and DDA drainage time, without over-flocculation and allowed for significant decrease in PVAm dosage.

The invention discloses a preparation method of a high-strength water-resistant special functional paperboard, and belongs to the technical field of papermaking, the high-strength water-resistant special functional paperboard sequentially comprises a surface sizing layer, a surface paper layer, a core paper layer, a bottom paper layer and a bottom sizing layer from top to bottom, and the surface paper layer, the core paper layer and the bottom paper layer are made of waste paper pulp. The surface sizing layer and the bottom sizing layer are made of environment-friendly glue, through the surface paper layer, the core paper layer and the bottom paper layer, the functional paper has higher paperboard physical strength and better water resistance, and the functional paper is environmentally friendly, efficient and remarkable in superiority.

The present invention generally relates to methods and compositions for making tissue, paper or paperboard and for enhancing their retention and drainage. In particular, the present disclosure provides a method for enhancing retention and draining by adding a retention and drainage aid comprising a fast reversed phase cationic emulsion polyacrylamide (QIC-EPAM) and a polyvinylamine (PVAm) polymer. Manufacture of paper under these conditions provides improved retention, gravity drain rate, and DDA drain time without excessive flocculation, and allows for a significant reduction in PVAm dosage.

The present invention relates to a papermaking additive, a method for producing a papermaking additive, and paper. The present invention provides a papermaking additive which has less viscosity increase after long-term storage and exhibits excellent drainage and paper strength effects. A papermaking additive comprising a (meth)acrylamide-based polymer, the (meth)acrylamide-based polymer having starch (a1), (meth)acrylamide (a2), a polymerizable monomer having an amino group (a3), a polymerizable monomer having a carboxyl group (a4), and a polymerizable monomer having a sulfonic acid group (a5) as essential constituent components, the starch (a1) being two or more selected from the group consisting of unmodified starch, oxidized starch, esterified starch, etherified starch, amidated starch, cationized starch, amphoteric starch, and crosslinked starch.

This invention relates to a method for manufacturing paper or paperboard from a fiber suspension, the method comprising the following steps: a) injecting a P3 polymer into a cellulose fiber suspension; b) forming paper or paperboard; c) drying the paper or paperboard. Prior to step a), a P3 polymer is prepared from a water-soluble P1 polymer of at least one nonionic monomer selected from acrylamide, methacrylamide, N,N-dimethylacrylamide, and acrylonitrile. The P1 polymer is subjected to a Re1 reaction to obtain a P2 polymer, which is then subjected to a Re2 reaction to obtain the P3 polymer. The P3 polymer is then subjected to a Re2 reaction. The e1 reaction is injected into the fiber suspension within 24 hours of the start of the reaction; the -Re1 reaction comprises the preparation of a P2 polymer containing an isocyanate functional group by reacting (i) an alkali metal hydroxide and / or an alkaline earth metal hydroxide, (ii) an alkali metal hypohalide and / or an alkaline earth metal hypohalide and (iii) a P1 polymer for 10 seconds to 60 minutes; the -Re2 reaction comprises the preparation of a P3 polymer by reacting (iv) a compound containing at least one aldehyde functional group or a compound capable of generating at least one aldehyde functional group with (v) a P2 polymer containing an isocyanate functional group.

The present invention discloses a modified silica sol, a preparation method thereof and an application. Among them, the modified silica sol comprises the following components by weight ratio: 100 parts of water glass, 5 - 40 parts of sodium 3-chloro-2-hydroxypropanesulfonate, 30 - 300 parts of H-type cation exchange resin, and 100 - 2000 parts of deionized water; the preparation method includes preparing raw materials, preparing a silicic acid-containing solution, preparing a reaction solution, and preparing a sulfonated modified silica sol. The preparation route of the modified silica sol of the present invention is simple, with low energy consumption cost and no solvent pollution. While ensuring the water filtration and retention performance, the modified silica sol has good self-stability, can extend the storage period, and can also be applied to various papermaking environments.

The invention belongs to the technical field of papermaking, and particularly relates to high-strength corrugated base paper and a production method thereof. The method comprises the following steps: respectively preparing waste paper pulp and natural color chemithermomechanical pulp with 20-35-degree SR beating degree through independent preparation lines; then, mixing the two kinds of pulp in a drifting system according to the proportion of 20-50% of natural color chemimechanical pulp, and adding a ternary retention aid composed of cationic retention aids polyacrylamide with the molecular weight of 8-10 million and cationic retention aids polyacrylamide with the molecular weight of 3-6 million and bentonite; and finally, the mixed pulp is put on a net to be formed, surface sizing is conducted on paper sheets, and sizing paint comprises corn starch, starch converting enzyme, styrene acrylate emulsion, AKD emulsion and aluminum sulfate. Through the synergistic effect of branching pulping, proportion optimization, a special chemical system and surface treatment, high-proportion waste paper replacement is achieved, meanwhile, the paper forming strength is guaranteed and improved, the production cost is effectively reduced, and remarkable economic benefits are achieved.