495results about "Reinforcing agents addition" patented technology

The invention discloses a biomass-based reinforcing agent for paper and application of the biomass-based reinforcing agent. The reinforcing agent comprises a biomass-based material, the biomass-based material comprises a micron-sized structure and a nano-sized structure distributed on the micron-sized structure. The reinforcing agent prepared by the invention has abundant nanostructures, is beneficial to physical crosslinking such as entanglement and bridging of fibers in paper pulp, and improves the wet strength of paper; the preparation of the reinforcing agent is a simple physical process, and a complex synthesis chemical process for synthesizing a polymer in a traditional organic reinforcing agent is avoided; the reinforcing agent is prepared by a dissolution regeneration method, so that the energy consumption is low, the solvent can be recycled and reused, no chemicals are consumed, and the reinforcing agent is environment-friendly; the reinforcing agent prepared by the invention can achieve a satisfactory wet strength effect at a lower content.

The invention discloses a cationic core-shell PHA nano-emulsion reinforcing agent as well as preparation and application thereof, and belongs to the technical field of papermaking chemicals. The problems that a traditional wet strength agent is poor in environmental protection property and difficult to recycle, and a conventional bio-based material needs high-temperature curing and is high in energy consumption are solved. According to the reinforcing agent, low-MFFT bio-based polyhydroxyalkanoate is used as a core, and a positive ion shell layer with strong positive charges is wrapped outside the core. The method has the core advantages that extra high-temperature curing is not needed, the film can be efficiently formed under the conventional 105 DEG C drying condition, and the energy consumption is remarkably reduced; meanwhile, high dry and wet strength and water resistance are achieved, the treated paper has excellent re-pulping recycling suitability, and the industrial pain point that traditional wet strength paper is difficult to recycle is solved.

A method of making an absorbent structure including mixing ultra-high molecular weight (“UHMW”) glyoxalated polyvinylamide adducts (“GPVM”) and / or high molecular weight (“BMW”), glyoxalated polyacrylamide and / or high cationic charge glyoxalated polyacrylamide (“GPAM”) copolymers and high molecular weight (“BMW”) anionic polyacrylamide (“APAM”) with the furnish during stock preparation of a wet laid papermaking process.

The invention discloses base paper for aluminum spraying and a preparation method thereof, and relates to the technical field of base paper. The preparation method comprises the following steps: pulping softwood pulp, then adding deionized water to dilute the softwood pulp until the mass concentration is 0.8%-1%, then adding modified gel particles, modified bentonite and a PAE wet strength agent, adjusting the pH value to 6.5-7.5, stirring for 40-60 minutes, and then adding deionized water to dilute the softwood pulp until the mass concentration is 0.5%-0.7% to obtain mixed paper pulp; and then making the mixed paper pulp into paper sheets, squeezing, drying, coating the surface layer coating on the surface of base material paper, and drying with hot air to obtain the body paper for aluminum spraying. According to the invention, the modified gel particles and the modified bentonite are added, so that the mildew-proof and moisture-proof capabilities of the base paper for aluminum spraying are effectively improved; the introduction of the surface coating further improves the mildew-proof and moisture-proof capabilities. Therefore, the method has a wider application prospect.

The invention discloses a silica powder modified paperboard material of embossed frame paper for cigarettes and a preparation method of the silica powder modified paperboard material, and belongs to the field of advanced inorganic non-metallic materials. The material comprises bleached chemical wood pulp, core-shell structure in-situ modified nano silicon micropowder, an auxiliary agent and a latent temperature-sensitive cross-linking agent, a modification system contains a compound silane coupling agent and amino modified organosilane, and a dual network of static triple cross-linking and dynamic secondary cross-linking is formed; the nanometer silicon micro powder is of a core-micro-nano protrusion-shell multilevel structure, a shell layer is thermoplastic resin containing latent epoxy groups, and a double-peak particle size distribution design is adopted. The preparation process is realized through in-situ generation modification, high-speed shearing fusion and an embossing-shaping integrated closed-loop control process, and is adaptive to an existing fourdrinier papermaking production line. The product quantification is 210-220 g / m < 2 >, the transverse stiffness is larger than or equal to 210 mN.m, the embossing retention rate is larger than or equal to 99.5%, after 50 cycles at the temperature of-5 DEG C-40 DEG C and the humidity of 30%-80%, the stiffness is reduced by smaller than or equal to 3%, the barrier property is reduced by smaller than or equal to 6%, the printing adsorption uniformity error is smaller than or equal to 3%, and the barrier property and the environmental protection property are excellent. The method solves the problems of agglomeration, embossing resilience, multi-performance contradiction, poor environmental stability and other pain points of conventional modified filler, realizes the cooperation of low quantification and high performance, conforms to the high-end and green requirements of the tobacco industry, can pass the application of strategic emerging industry priority review channels, and has a wide application prospect.

The invention relates to the technical field of agricultural paper, in particular to double anti-mite fruit cultivating bag paper and a preparation method thereof. The preparation method comprises the following steps: pulping: respectively pulping natural-color bamboo pulp and natural-color softwood pulp, then mixing, adding water, and uniformly mixing to obtain pulp; papermaking: sequentially adding iron oxide yellow, aluminum sulfate, rosin size and a wet strength agent into the pulp, adding water for dilution, and drying after papermaking to obtain fruit cultivating bag body paper; sizing: taking oxidized cassava starch, adding water, preparing starch slurry, heating, continuously stirring until the starch is completely gelatinized, taking starch gelatinized liquid, adding neem oil, putting into a high-speed homogenizing emulsifying machine, emulsifying to obtain neem oil anti-mite emulsion, uniformly mixing the neem oil anti-mite emulsion with wax emulsion to obtain anti-mite glue liquid, immersing the fruit cultivating bag body paper into the anti-mite glue liquid, and drying to obtain the fruit cultivating bag. And taking out and drying to obtain the double anti-mite fruit cultivating bag paper. The composite material has physical barrier and long-acting anti-mite functions, and the risk of insect attack invasion is greatly reduced.

The invention discloses an acid-neutral nano PHA paperboard reinforcing agent as well as preparation and application thereof, and belongs to the technical field of papermaking chemicals. The reinforcing agent is a bio-based nano water-based emulsion, and the core of the reinforcing agent is that a stable high-positive-charge nanoparticle interface is constructed under an acid-neutral window through the synergistic effect of polyphenol and an amine polymer. The environment-friendly wet strength agent solves the potential safety hazard of the traditional wet strength agent, and does not contain free formaldehyde and epichlorohydrin. The method has the outstanding advantages that the method is completely compatible with a modern papermaking acid-neutral process, and the defect that the similar bio-based technology needs to react under alkalinity is overcome; the adhesive is flexible to apply, can be efficiently used for wet end addition, or can be stably compounded with oxidized starch for surface sizing; the preparation method is simple, efficient and energy-saving, can realize excellent wet strength retention rate and dry strength improvement under the conditions of low addition amount and conventional industrial drying at 105 DEG C, and does not need extra high-temperature curing.

The invention provides multifunctional composite fiber reinforced decorative base paper and a preparation method thereof. The decorative base paper is prepared from the following raw materials in parts by weight: 30-60 phr of wood pulp fibers, 15-35 phr of bamboo fibers, 1-10 phr of polyester fibers, 1-10 phr of polyamide fibers, 57-91 phr of an antibacterial reinforcing agent, 3-20 phr of a flame retardant and 1-10 phr of nano cellulose. The antibacterial reinforcing agent is prepared from the following components in parts by weight: 1 to 5 phr of silver nitrate, 3 to 10 phr of tetrabutyl titanate, 2 to 8 phr of sulfydryl modified chitosan, 50 to 70 phr of absolute ethyl alcohol and 2 to 6 phr of plant essential oil; the flame retardant is a composition of ammonium polyphosphate and aluminum hydroxide wrapped by chitosan. According to the invention, the composite fiber prepared by compounding four fibers is used, and the antibacterial agent, the flame retardant and the nano cellulose are added to supplement functionality, so that the multifunctional composite fiber reinforced decorative base paper with high strength, excellent wear resistance and excellent antibacterial performance is obtained, and the fireproof performance of the multifunctional composite fiber reinforced decorative base paper reaches the national B1-level fireproof standard.

The invention belongs to the technical field of high-molecular polymers, and particularly relates to glyoxal modified polyacrylamide and a synthesis method thereof. Comprising the following steps: adding sulphaguanidine and 4-vinyl benzaldehyde into a solvent for reflux to obtain a compound 1; the preparation method comprises the following steps: adding acrylamide and methacryloyloxyethyl trimethyl ammonium chloride into water, adding into the hydrolysate of 1, 3-dimethoxy-1, 3-dimethyl-1, 3-divinyl disiloxane, and adding an ammonium persulfate solution for reaction to obtain a mixed solution; adding an acetone solution of a compound 1 into the mixed solution, and adding an ammonium persulfate solution to react to obtain cationic polyacrylamide; the cationic polyacrylamide and glyoxal are stored separately, and are mixed and reacted during use to obtain glyoxal modified polyacrylamide. According to the invention, early crosslinking of glyoxal and a polymer is avoided, the paper strength can be obviously improved, and the product can show excellent stability in the storage process.

The invention provides a preparation method of environment-friendly straw paper with hydrophobic and lip-sticking-free properties. The preparation method comprises the following steps: respectively pulping bleached softwood pulp and bleached hardwood pulp, and mixing to obtain a fiber mixture; adding a biological wax waterproof system sizing agent into the fiber mixture, or adding the biological wax waterproof system sizing agent and an antibacterial agent, and adding a wet strength agent and an alkyl ketene dimer, and carrying out net forming treatment; the preparation method comprises the following steps: carrying out squeezing dehydration and primary drying treatment on paper pulp subjected to net forming treatment, carrying out surface coating and sizing by adopting a sizing system containing a biological wax waterproof system sizing agent, carrying out secondary drying treatment, and finally sequentially carrying out calendering and coiling to obtain the environment-friendly straw paper. Experiments show that the straw paper disclosed by the invention has the advantages of excellent hydrophobicity, no lip sticking, high strength, high antibacterial property, complete degradability, no toxicity and environment friendliness.

A method of making paper and paperboard products, including absorbent structures, where the method includes mixing ultra-high molecular weight (“UHMW”) glyoxalated polyvinylamide (“GPVM”) adducts and high molecular weight (“HMW”) anionic polyacrylamide (“APAM”) with the furnish during stock preparation of a wet laid papermaking process.

The invention relates to the technical field of papermaking and food packaging materials, in particular to a preparation method of full-degradable plastic-substituted high-strength food packaging paper. Preparing a fiber layer by taking plant fiber as a base material; the preparation method comprises the following steps: grafting a methyl methacrylate-butyl acrylate block copolymer on nano-cellulose through an atom transfer radical polymerization technology to prepare enhanced nano-cellulose; dialdehyde starch rich in aldehyde groups and chitosan are subjected to a Schiff base reaction to form a dynamic cross-linked network, polylactic acid microspheres modified by beta-cyclodextrin are introduced to serve as supramolecular enhancement units, and functional coating liquid is prepared; and finally, coating the functional coating liquid on the fiber layer, and drying, cross-linking and curing to obtain a finished product. Through cooperation of chemical grafting, dynamic covalent bonds and supramolecular action, the packaging paper is endowed with extremely high strength and toughness and excellent oil and moisture resistance and heat sealability, meanwhile, it is ensured that the packaging paper can be completely biodegraded in the natural environment, and functional replacement of traditional plastic packaging is successfully achieved.

The present invention relates to a water-resistant paper having heat-sealing properties, excellent water resistance and excellent oil resistance, and a packaging container obtained using the water-resistant paper. The water-resistant paper of the present invention comprises: a paper substrate; and an undercoat layer 1 and a water-resistant layer 1 on one surface of the paper substrate in the stated order from the paper substrate side, wherein an average Runkel ratio of pulp forming the paper substrate is 0.51 or less, wherein the undercoat layer 1 contains latex and a pigment, and wherein a coating amount of the water-resistant layer 1 is 4.5 g / m2 or more.

According to an example aspect of the present invention, there is provided a method comprising: in a mould, forming a multi-layered foamed fibrous structure from foamed fibrous compositions, wherein each of the foamed fibrous compositions comprises cellulosic fibres, water, air, and at least one foaming agent; dewatering the foamed fibrous structure; hot-pressing the dewatered structure, to obtain a moulded fibrous product, wherein said at least one foaming agent comprises at least one surface-active foaming agent and / or at least one polymeric foaming agent, and wherein at least one of the foamed fibrous compositions comprises a hydrophobic agent.

Sanitary tissue products, which may be creped, having non-wood fibers and exhibits a coverage greater than about 5.5 fiber layers and a fiber count-area (C(n)) greater than about 830 million / m2 and / or a coverage greater than about 7.5 fiber layers and / or a coverage greater than a line defined by an expression: Y=0.00767X+3.0 (wherein the fiber coverage is “Y” and wherein a fiber count-area (C(1)) is “X”) are provided.

The invention discloses a high-toughness carton and a preparation method thereof, and relates to the technical field of papermaking and environment-friendly packaging materials. The carton is made of a high-toughness composite corrugated board, and raw materials of the carton comprise main material pulp fibers, cross-linked modified nanocellulose, a modified starch adhesive, a wet strength agent and a rheology modifier. The cross-linked modified nano-crystalline cellulose is nano-crystalline cellulose of which the surface is grafted with a hyperbranched supramolecular cross-linking agent. According to the method, by preparing the nanocellulose with the surface grafted with the hyperbranched cross-linking agent, a mechanism capable of dissipating energy is constructed in a fiber network, and compared with the prior art, the defect that regenerated fibers are large in brittleness can be effectively overcome, and the dynamic impact toughness of the carton is remarkably improved. By using the modified starch adhesive disclosed by the invention, an adhesive layer has better ductility and interlayer binding force, and when a paperboard is stressed and deformed, the adhesive layer can be deformed along with the deformation and is not easy to break, so that the stability of interlayer binding is favorably kept.

The invention belongs to the technical field of novel environment-friendly printing and water-based packaging protection materials, and discloses high-wear-resistance degradable water-based plastic-replacing oil, a preparation method and application of the high-wear-resistance degradable water-based plastic-replacing oil. Water-based matte polyurethane, a water-based acrylic polymer and water-based bright polyurethane serve as core film-forming substances, and water-based matte polyurethane, water-based acrylic polymer and water-based bright polyurethane serve as core film-forming substances; degradable reinforcing agents such as nano-crystalline cellulose and functional auxiliaries are compounded, and a step-by-step dispersion technology is adopted for preparation. Through cooperation of the formula and the technology, the comprehensive performance that the A4 paper is resistant to abrasion for more than 3000 times, the natural biodegradation rate is more than 3000 times, the folding and explosion resistance is 30 times and the like can be achieved, complex chemical modification is not needed in the technology, the production period is remarkably shortened, a traditional BOPP film covering technology can be replaced, and the method is suitable for a high-speed printing and packaging production line and is suitable for protection of various paper packages such as digital electronics, cosmetics and tobacco and wine. The problems that a traditional BOPP covering film is difficult to degrade, wear resistance and degradation of existing water-based plastic replacing oil are difficult to consider, and quick drying conflicts with film forming are solved.

An absorbent retail paper product made up of cellulose fibers, and having a 1,3-dichloro-2-propanol concentration of non-detected amounts to 50 ppb as measured using the AOAC Official Method 2000.0150, a 3-monochloro-1,2 propanediol concentration of non-detected amounts to 1000 ppb as measured using the AOAC Official Method 2000.0150, a polyaminoamide-epihalohydrin concentration of non-detected amounts to 0.09% as measured by an “Adipate test”, and a cross direction wet strength of 80 to 200 n / m, wherein all of the cellulose fibers contained in the absorbent paper product are non-synthetic, cellulose fibers and the absorbent paper product is substantially free of formaldehyde.

The invention relates to a production process of dialdehyde polymer and its use in the paper industry and particularly in papermaking.

The application discloses a multi-carboxyl copolymer aqueous composition for pulp adding in packaging paperboard, synergism in short-stay pulp of packaging paper and fiber synergism in wet end of bamboo pulp paper, and a preparation and application method thereof, and belongs to the technical field of pulp and paper chemicals and wet end chemical control. The composition contains carboxyl-rich copolymer, and can be selected as high filtration rate homogeneous aqueous solution type, flexible type acid or bamboo pulp low cation density copolymer according to paper types, and is prepared through water phase free radical polymerization. In application, the composition is diluted and then added in a divided mode after a fan pump outlet to a pressure screen inlet or after a cationic polyacrylamide retention agent or in a bamboo pulp system. The method is beneficial to improving fiber combination, drainage stability, first-pass retention rate, white water stability and paper strength, and improving the adaptability of wet end dosing windows of different paper types.

The invention provides an environment-friendly low-chlorine wet strength agent and a preparation method and application thereof.The preparation method comprises the steps that adipic acid and tetraethylenepentamine are mixed and react for 2-6 h at the temperature of 170-190 DEG C, and a prepolymer is obtained; cooling the prepolymer to 120-140 DEG C, adding a modifier, carrying out a heat preservation reaction for 2-3 h, and adding deionized water to adjust the solid content to 55-65% so as to obtain a modified polyamide solution; adding a cationizing agent and epoxy chloropropane into the modified polyamide solution, heating to 65-75 DEG C, reacting, and adding acid to adjust the pH value to 2.5-4.5 when the viscosity of the system reaches 50-80 mPa.s; adding sodium hydrogen sulfite, and carrying out heat preservation reaction for 1-2 hours; and adding deionized water to adjust the solid content to 12-13%, thereby obtaining the environment-friendly low-chlorine wet strength agent. The specific modifier is adopted to modify a polyamide main chain, and the cationizing agent is introduced, so that the prepared wet strength agent not only can remarkably reduce the content of organic chlorine in a product, but also can improve the dry and wet strength, water resistance and folding resistance of paper. In addition, the product can also shorten the curing time of the paper.

The application relates to the field of decorative materials, in particular to a wear-resistant decorative paper and a preparation method thereof. The preparation method of the wear-resistant decorative paper comprises the following steps: coating wear-resistant paint on the surface of base paper to form a wear-resistant coating layer through drying treatment, so that the wear-resistant decorative paper is prepared; the wear-resistant paint is prepared by using acrylic acid hydroxy ester, ethyl acrylate and methyl methacrylate, so that the wear-resistant paint has good adhesion; the wear-resistant paint is prepared by using divinylbenzene and styrene, so that the hardness and strength of the film layer formed by the wear-resistant paint are improved; the wear-resistant paint is prepared by using vinyl silicone oil, so that the flexibility and water / oil repellency of the film layer formed by the wear-resistant paint are improved; the wear-resistant paint is prepared by using acrylic acid hydroxy ester, ethyl acrylate, methyl methacrylate, divinylbenzene, styrene and vinyl silicone oil, so that the prepared wear-resistant decorative paper has excellent wear resistance.

To provide a paperboard with an excellent strength and printing quality.SOLUTION: There is provided a paperboard, comprising a top layer, at least one or more middle layers and a bottom layer, and contains 20 mass% or more of hardwood kraft pulp relative to the total pulp mass, and the surface layer contains 50 to 100 mass% of softwood kraft pulp. The paperboard has a compression energy of 2.0 to 25.0 gf cm / cm2, and a compression recovery rate of 40 to 95%.SELECTED DRAWING: None

The invention discloses a manufacturing method of an environment-friendly paper product. The environment-friendly paper product is prepared from the following raw materials in parts by mass: 60-70 parts of a main fiber raw material, 25-35 parts of an auxiliary fiber raw material, 3-8 parts of an environment-friendly additive and 1-2 parts of a pretreating agent. By means of the components, by adding the auxiliary fiber raw materials, the environmental protection property is remarkably improved, waste cotton and linen and agricultural waste are converted into papermaking raw materials, consumption of primary fibers is reduced, meanwhile, waste recycling is achieved, and pollution caused by incineration and landfill is reduced. The auxiliary fibers and the main fibers have a synergistic effect and are matched with the environment-friendly auxiliaries to reinforce the quality of the paper, the cotton and linen fibers improve the flexibility, the agricultural waste fibers enhance the stiffness, lignin and short fibers are separated through low-temperature pyrolysis, impurities are prevented from affecting the performance of the paper, and solid powder rich in the lignin and the short fibers is recycled and reused.

A drainage-optimized additive composition for papermaking is disclosed. The composition comprises an aqueous media and a glyoxalated polyacrylamide (gPAM) resin having a weight average molecular weight (Mw) of at least about 5 MDa. The composition comprises from about 1.95 to about 2.45 wt. % of the gPAM resin. A method of preparing the composition is also disclosed, and comprises preparing a cationic acrylamide (cAM) prepolymer having at least one predetermined property, and selectively glyoxalating the cAM prepolymer by controlling the concentration of the cAM prepolymer in the aqueous media during glyoxalation in relation to the predetermined property. The method may be carried out in situ during a papermaking process (i.e., as an on-site method). A process of forming paper with the composition also disclosed, and comprises combining the composition with the aqueous suspension of cellulosic fibers, forming the cellulosic fibers into a sheet, and drying the sheet to produce a paper.

The invention discloses a preparation method of a high-strength water-resistant special functional paperboard, and belongs to the technical field of papermaking, the high-strength water-resistant special functional paperboard sequentially comprises a surface sizing layer, a surface paper layer, a core paper layer, a bottom paper layer and a bottom sizing layer from top to bottom, and the surface paper layer, the core paper layer and the bottom paper layer are made of waste paper pulp. The surface sizing layer and the bottom sizing layer are made of environment-friendly glue, through the surface paper layer, the core paper layer and the bottom paper layer, the functional paper has higher paperboard physical strength and better water resistance, and the functional paper is environmentally friendly, efficient and remarkable in superiority.

The invention relates to the technical field of paper wet strength agents, in particular to an environment-friendly wet strength agent and a preparation method thereof. The preparation method of the wet strength agent comprises the following steps: under the action of a catalyst, succinic acid, maleic acid and triethylene tetramine react to obtain an unsaturated polyamide polyamine prepolymer; adding water into the unsaturated polyamide polyamine prepolymer to adjust the solid content, heating, adding double-bond-containing nanocellulose, tea saponin, glycidyl acrylate and an initiator, and reacting to obtain an intermediate emulsion; cooling the intermediate emulsion to room temperature, adding epichlorohydrin to react for 0.5-3 hours, heating to 50-75 DEG C, continuing to react for 1-5 hours, cooling reaction liquid to 25-30 DEG C, adding glyoxal to react for 0.5-1 hour, adjusting the pH value of the reaction liquid after the reaction is completed, and adding water to adjust the solid content, thereby obtaining the product. The preparation method is simple in process, and the prepared wet strength agent can reduce organic chlorine residues.

The invention relates to absorbent paper as well as a preparation method and application thereof. The method comprises the following steps: pulping plant fiber pulp, adding sodium bicarbonate for pretreatment, and washing to obtain pretreated paper pulp; adding a dispersing agent, a wet strength agent and a composite antibacterial component into the pretreated paper pulp, and uniformly mixing to obtain mixed paper pulp; the composite antibacterial component is prepared from chitosan, polylysine and a modified copper oxide dispersion liquid; feeding the mixed paper pulp into a rotary screen paper machine to produce upper-layer single-layer wrinkling base paper, then compounding the upper-layer single-layer wrinkling base paper with lower-layer single-layer semi-forming base paper on which the macromolecular water-absorbent resin particles are scattered, and then drying to obtain the water-absorbent paper. The antibacterial rate of the absorbent paper on various pathogenic bacteria is larger than or equal to 99.5%, the antibacterial rate is still larger than or equal to 97% after 20 times of water washing, and the absorbent paper is high in water absorption speed, stable in physical performance, safe, environmentally friendly, controllable in cost, capable of being widely applied to the fields of hygienic products, medical dressings, food packaging and the like, simple in preparation process and suitable for industrial production.

The embodiment of the invention provides a preparation method of cotton-feeling household paper, which comprises the following steps: providing long fibers and short fibers in a specific ratio, and controlling the dry weight ratio of bamboo pulp in mixed pulp to be 20-40%; the pulp is subjected to tandem type two-stage pulp grinding treatment, the specific energy consumption of the first stage is 30-50 kWh / adt, and the specific energy consumption of the second stage is 150-170 kWh / adt; sequentially adding a wet strength agent and a softening agent; and finally, forming, squeezing, drying and carrying out wrinkling treatment with the wrinkling rate of 22-26% to obtain the raw paper, through cooperation of the processes, the problem that high wet strength and high softness of the bamboo-based household paper are difficult to consider at the same time is solved, the wet-to-dry ratio of the prepared product is larger than or equal to 32%, the softness is smaller than or equal to 110 mN, and the product has the wet durability of cotton-like soft towels and the softness of high-end household paper.