The invention relates to an electrochemical iron enhanced
wastewater anaerobic treatment process and a device and a method for in-situ purification of
biogas. According to the method, an iron
electrode is used as an
anode, an electrochemical method is adopted for strengthening a
wastewater anaerobic treatment process and a
biogas in-situ purification process, pollutants such as organic matters in to-be-treated
wastewater are degraded by microorganisms in an
anaerobic reactor, treated wastewater is obtained,
biogas is generated, and main components of the biogas are CH4, CO2, H2S and other impurities; in the electrochemical reaction with the iron
electrode as the
anode, Fe < 2 + > is generated in situ at the
anode, H2 and OH <-> are synchronously generated in situ at the
cathode, CO2 and H2S in biogas generated by wastewater
anaerobic treatment react with electrochemical reaction products to generate precipitates or generate CH4 to be removed in situ, and meanwhile, the wastewater anaerobic
treatment effect is effectively improved. The method is simple, convenient, efficient, short in process, few in equipment, low in investment and operation cost and convenient to operate and maintain.