1247 results about "Anhydrous ethanol" patented technology

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention discloses a supported double perovskite photocatalytic material which is prepared by the following steps: putting copper nanoparticles and double perovskite Cs2NaBiCl6 into a water-absolute ethyl alcohol mixed solution, carrying out ultrasonic dispersion, heating the dispersion solution to 55-65 DEG C, carrying out cooling crystallization at a rate of 1-2 DEG C / min, completing the reaction when the temperature is reduced to 25 DEG C, carrying out solid-liquid separation on the reaction product, and washing and drying the solid, the Cu nanoparticle-loaded double-perovskite photocatalytic material is applied to photocatalytic reduction of CO2, the catalyst has the characteristics of high reduction catalysis efficiency and good selectivity, the performance is stable after repeated cyclic utilization, and the material disclosed by the invention is simple in preparation process, high in efficiency and suitable for large-scale production and market popularization and application.

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

The invention relates to the technical field of automobile tires, and discloses a new energy automobile tire self-repairing sealing material adhered with mute cotton. The preparation method comprises the following steps: adding a modified polyurethane adhesive, C5 petroleum resin and a modified carbon nanotube filler into absolute ethyl alcohol, mixing to obtain a self-repairing liquid, adhering polyurethane cotton to the upper part of the self-repairing liquid, and drying to obtain the new energy automobile tire self-repairing sealing material adhered with the mute cotton. Disulfide bonds, boric acid ester bonds and imine bonds introduced into polyurethane through a chain extension reaction and diselenide bonds introduced into carbon nanotubes all belong to dynamic covalent bonds, so that the self-repairing performance of the material is improved; by introducing a rigid benzene ring and naphthyl aromatic structure, the mechanical property of the self-repairing sealing material is improved; the carbon nano tube can play a role in skeleton supporting in a polyurethane matrix, and the mechanical property of the material is further improved by introducing an adamantane rigid structure into the carbon nano tube.

The present invention provides a method for preparing a carbon-containing lithium sulfide composite material, the method comprising: in a water-free and oxygen-free environment of a vacuum glove box, weighing a certain amount of lithium source and sulfur source, putting them into a ball mill, and then adding sodium borohydride according to a set ratio to mix evenly; sealing the ball mill, and passing an inert gas after evacuation, and then ball milling for a certain time at a set speed and after the ball milling is completed, taking out the lithium sulfide solid under the protection of the inert gas; dissolving and filtering the obtained lithium sulfide solid in anhydrous ethanol, and adding a certain amount of carbon source to the filtrate, stirring, and ultrasonic treatment; heating and evaporating to remove the solvent, and obtaining a solid Li2S / C precursor; placing the Li2S / C precursor in a vacuum freeze dryer, and freeze-drying to remove residual moisture to obtain a Li2S / C composite material. The present invention solves the problems of high cost and low purity when preparing lithium sulfide in the prior art.

The invention relates to the technical field of molecular sieves, in particular to a molecular sieve and a preparation method and application thereof in nitrogen separation.The preparation method comprises the steps that a carbonized material and 3-chloropropyltrimethoxysilane are added into methylbenzene, heating is conducted under nitrogen protection till a reflux reaction is conducted for 12-48 h, after the reaction is finished, the room temperature is recovered, filtering is conducted, a product is collected, washing and drying are conducted, and a modified carbonized material is obtained; and adding the modified carbonized material and an ionic liquid into absolute ethyl alcohol, heating to reflux reaction for 12-48 hours, after the reaction is finished, recovering to room temperature, filtering, collecting a product, performing Soxhlet extraction with dichloromethane for 12-48 hours, drying to obtain an immobilized ionic liquid carbonized material, and performing CO2 activation and vapor deposition on the immobilized ionic liquid carbonized material to obtain the molecular sieve. The molecular sieve prepared by the invention has a relatively high specific surface area, and shows excellent performance of selectively adsorbing nitrogen in a methane and nitrogen mixed system.

The invention discloses a high-strength hoop and a processing method thereof in the technical field of mechanical connection fasteners. The high-strength hoop comprises the following raw materials: modified carbon fibers, a modified epoxy resin matrix, chopped glass fibers, an antioxidant and an aluminate coupling agent. Cleaning the modified carbon fibers with acetone to remove oil stains, oxidizing the modified carbon fibers with concentrated nitric acid at 80-85 DEG C to generate polar functional groups containing hydroxyl and carboxyl, washing the modified carbon fibers with water until the modified carbon fibers are neutral, drying the modified carbon fibers, immersing the modified carbon fibers into an absolute ethyl alcohol solution of an aluminate coupling agent for ultrasonic dispersion, and curing the modified carbon fibers at 100-105 DEG C; the modified epoxy resin matrix is prepared by heating and melting epoxy resin, adding nano montmorillonite, stirring and dispersing, adding polyamide, an accelerant and a flexibilizer, and carrying out vacuum defoaming at 100-105 DEG C. The hoop has the advantages of high strength, weather resistance and the like by modifying and enhancing interface bonding and matrix toughness, and is suitable for connection under complex working conditions.

The invention provides a photo-thermal evaporation material based on black titanium dioxide as well as a preparation method and application of the photo-thermal evaporation material. The preparation method comprises the following steps: mixing urea, absolute ethyl alcohol and tetrabutyl titanate into a solution A, mixing absolute ethyl alcohol, ultrapure water and hydrochloric acid into a solution B, dropwise adding the solution B into the solution A, mixing to form a white colloid, heating in a water bath, drying, and calcining in a nitrogen atmosphere to obtain black titanium dioxide powder; the preparation method comprises the following steps: fully mixing a certain amount of black titanium dioxide, sodium alginate and ultrapure water to form a uniform dispersion liquid, dipping the pretreated polyurethane sponge in the dispersion liquid, and crosslinking with a calcium chloride solution to prepare the photo-thermal evaporation material of the black titanium dioxide-calcium alginate composite hydrogel. The photo-thermal evaporation material breaks through the photo-thermal application bottleneck of traditional titanium dioxide, has excellent evaporation rate and seawater desalination performance, and can effectively remove various printing and dyeing wastewater to obtain clean water.

The invention discloses a preparation method of a nano HZSM-5 molecular sieve, and belongs to the technical field of nano molecular sieve preparation, the preparation method comprises the following steps: 1, adding a silicon source, an aluminum source and a template agent into a supercritical crystallization reaction kettle, heating, stirring, and carrying out a melting reaction on the raw materials to obtain a seed crystal mixed material; introducing absolute ethyl alcohol into the seed crystal mixed material obtained by the melting reaction, heating, stirring, and carrying out crystallization reaction to obtain a reaction product; and cooling, washing, drying and roasting the obtained reaction product to obtain the nano HZSM-5 molecular sieve. According to the present invention, the melting reaction and the supercritical ethanol crystallization reaction technology are introduced into the preparation of the nanometer HZSM-5 molecular sieve for the first time, and the prepared nanometer HZSM-5 molecular sieve has advantages of small grain size, uniform distribution, large specific surface area and high yield.

The invention discloses a preparation method of minoxidil liniment. The preparation method comprises the following steps: uniformly mixing propylene glycol, absolute ethyl alcohol and about 40% purified water until no obvious layering exists, and finally adding minoxidil to stir and dissolve to obtain the minoxidil liniment. According to the preparation process provided by the invention, purified water and absolute ethyl alcohol can form a latent solvent, so that the solubility of minoxidil in a single auxiliary material is greatly improved, and subsequent preparation of the digoxin injection is facilitated.

The invention provides a method for recovering a graphite negative electrode from lithium extraction leaching residue of a waste lithium iron phosphate battery and application, the lithium extraction leaching residue of the waste lithium iron phosphate battery is mixed with concentrated sulfuric acid, and a constant temperature reaction is carried out in a high temperature reaction kettle, so that metal ions in the lithium extraction leaching residue are leached and dissolved in the concentrated sulfuric acid; performing solid-liquid separation to obtain metal ion-containing filtrate and graphite slag; ultrasonically washing the graphite slag with deionized water for multiple times until the graphite slag is neutral, and then drying and crushing to obtain graphite powder; the preparation method comprises the following steps: adding a nitrogen-doped carbon source and absolute ethyl alcohol into graphite powder, uniformly mixing through a ball mill, and drying to obtain a graphite precursor; calcining and regenerating the graphite precursor through a microwave high-temperature furnace to obtain regenerated graphite. Metal ions in the lithium extraction leaching residues are heated and leached through concentrated sulfuric acid, and the graphite residues are subjected to microwave calcination regeneration to obtain regenerated graphite. Graphite is recycled by using the lithium extraction leaching residues of the waste lithium iron phosphate batteries, so that the recycling efficiency of the waste lithium iron phosphate batteries is improved.

The invention discloses a corrosion-resistant stainless steel pipe and a preparation method thereof, and application of the pipe in marine engineering, and belongs to the technical field of stainless steel materials, and is used to solve the technical problem that the corrosion resistance and antifouling performance of stainless steel in the prior art need to be improved; wherein the preparation method of the corrosion-resistant stainless steel pipe comprises: adding epoxy-modified titanium dioxide and 2-aminoethyl methacrylate to anhydrous ethanol, stirring, adding hydrochloric acid aqueous solution, heating, reacting, and obtaining modified titanium dioxide; adding epoxy-modified carbon quantum dots and modified titanium dioxide to the hydrochloric acid aqueous solution, heating, reacting, and ending the reaction, filtering, washing, and drying to obtain epoxy-modified carbon quantum dot grafted modified titanium dioxide; the corrosion-resistant stainless steel pipe prepared by the invention not only has good corrosion resistance and antifouling performance, meets the application of the pipe in marine engineering, but also has good weather resistance and durability, is conducive to prolonging the service life, and reduces the cost of later maintenance.

The invention discloses a method for constructing a foamed nickel hydrogen evolution electrode with a multi-layer gradient structure based on two-step electrodeposition. According to the method, the in-situ growth of a multilayer gradient structure catalyst layer is realized by regulating and controlling the current density, and the core process comprises the following steps: 1, pretreatment of an electrode substrate: carrying out ultrasonic cleaning on foamed nickel through hydrochloric acid, absolute ethyl alcohol and deionized water in sequence, and removing surface impurities; 2, step-by-step electro-deposition of the gradient catalyst layer: firstly, electro-deposition is carried out under low current density to form a uniform and compact transition catalyst layer, the contact area between the catalyst layer and the base material is increased, and the durability and stability of the catalyst layer are improved; and then switching to high current density for bubble template method electrodeposition, spontaneously forming a catalyst layer with an inverted cone-shaped hole array structure by utilizing the dynamic template effect of violent hydrogen evolution bubbles, and promoting rapid removal of the bubbles by utilizing the hole array. The electrode prepared by the method has excellent stability, bubble removal capability and catalytic activity in hydrogen evolution reaction.

The invention discloses an acidic organic fertilizer and a preparation method thereof, relates to the technical field of organic fertilizers, and solves the problems of high alkalinity, fast decomposition and poor long-term carbon sequestration stability of existing organic fertilizers. The preparation method comprises the following steps: adding charcoal powder and FeCl3. 6H2O into absolute ethyl alcohol, uniformly stirring, performing ultrasonic treatment, drying, uniformly grinding, calcining in a muffle furnace, and grinding again to obtain charcoal-loaded nano iron particles; uniformly mixing fresh pig manure and / or chicken manure with crushed rice and / or corn straw, and adjusting the water content with water; adding charcoal-loaded nano-iron particles, uniformly mixing, and piling into a strip pile body; the temperature of the pile body is tested in real time, the pile is turned for multiple times in the heating process when spontaneous heating begins, the pile is not turned in the cooling process when spontaneous heating ends, when the temperature of the pile body is reduced to 40 DEG C or below, composting is finished, and the decomposed pile body sample is smashed to obtain the acidic organic fertilizer. The method has wide popularization and application prospects in agricultural waste resource utilization and organic fertilizer production.

The invention provides aeolian sand mortar internally doped with aluminate coupling agent modified fly ash and a preparation method of the aeolian sand mortar. The aeolian sand mortar comprises the following raw materials by mass: 10-40g of modified fly ash; 60 to 90 g of cement; 300 to 350 g of aeolian sand; 45 to 55g of water; wherein the modified fly ash is prepared through wet modification of an aluminate coupling agent, and the preparation method of the modified fly ash comprises the following steps: mixing the aluminate coupling agent and absolute ethyl alcohol according to a mass ratio of 1: (3-5), heating, and stirring for the first time until a transparent solvent is formed; and adding the transparent solvent and fly ash into water together, stirring for the second time to form slurry, and drying to obtain the super-hydrophobic modified fly ash. Through innovative selection of internal doping materials and optimization of a preparation process, the mortar has excellent, lasting and stable hydrophobic performance, the anti-permeability, compressive strength, bonding strength and other performance of the mortar are remarkably improved, and the strict requirements of modern constructional engineering for high performance and long service life of the mortar are met.

The invention belongs to the technical field of building materials, and particularly relates to a building thermal insulation aerogel material and a preparation method, the aerogel material comprises the following components by mass: 25-35 parts of a silicon source, 40-80 parts of a solvent, 0.3-0.6 part of a catalyst, 4-13 parts of an aluminum source, 9-20 parts of reinforcing fibers, 4-10 parts of a modifier, and 20-40 parts of carrier fibers; the silicon source is ethyl orthosilicate or methyl trimethoxy silane; the solvent is absolute ethyl alcohol; the catalyst is hydrochloric acid or ammonia water; the aluminum source is aluminum nitrate nonahydrate or aluminum isopropoxide; the reinforced fibers are nano titanium dioxide fibers; the modifying agent is gamma-aminopropyl triethoxy silane or gamma-methacryloyloxy propyl trimethoxy silane, and the modifying agent is gamma-aminopropyl triethoxy silane or gamma-methacryloyloxy propyl trimethoxy silane; the carrier fiber is rock wool or mineral wool. According to the invention, the thermal insulation aerogel material for buildings, which is high in mechanical strength, good in weather resistance and excellent in thermal insulation performance, can be prepared, so that the requirements of the building industry on high-performance thermal insulation materials can be met.

The invention belongs to the technical field of redox flow batteries, and particularly discloses a high-performance hierarchical pore carbon felt electrode for a flow battery and a preparation method of the high-performance hierarchical pore carbon felt electrode for the flow battery. Zinc salt or bismuth salt is dissolved in a solvent, and a precursor solution is obtained through stirring and ultrasonic treatment; dipping the pre-oxidized felt into the precursor solution, performing ultrasonic treatment, taking out and drying; and carbonizing the dried carbon felt at a high temperature in a protective atmosphere, treating with nitric acid, cleaning with deionized water, and drying to obtain the hierarchical porous carbon felt electrode with high activity and high specific surface area. The prepared high-performance hierarchical pore carbon felt electrode has a multi-scale pore structure and rich active sites, the specific surface area, the conductivity and the catalytic activity are remarkably improved, meanwhile, the hydrophilicity is optimized, and the electrolyte wettability is enhanced. The method is short in technological process, high in efficiency, low in cost and suitable for large-scale production and industrial application of the high-performance carbon felt electrode.

The invention provides an antistatic agent for fuel oil and a preparation method thereof, and belongs to the technical field of petrochemical engineering, and the preparation method comprises the following steps: S1, adding soybean lecithin and chlorosulfonic acid into dichloroethane, uniformly mixing, under the protection of nitrogen, heating and stirring for reaction, neutralizing reaction liquid, and performing rotary evaporation to obtain sulfonated soybean lecithin; the preparation method comprises the following steps: adding sulfonated soybean lecithin and ethidene diamine into absolute ethyl alcohol, then adding p-toluenesulfonic acid, heating and stirring for reaction, and carrying out reduced pressure distillation to obtain modified soybean lecithin; s2, dispersing the SiO2 particles in absolute ethyl alcohol, adding KH-550, and performing ultrasonic treatment, centrifugation and drying to obtain pretreated SiO2 particles; and uniformly mixing the modified soybean lecithin and the pretreated SiO2 particles, adding the mixture into a supercritical fluid reactor, heating and pressurizing, ultrasonically dispersing, and drying to obtain the antistatic agent. The antistatic agent has the advantages of good dispersibility, strong stability and strong antistatic capability.

The invention discloses a high-activity graphene quantum dot and a preparation method thereof, and relates to the technical field of oilfield chemistry, and the preparation method comprises the following steps: uniformly ground carbon source and nitrogen source are mixed, heated, fully reacted and cooled, uniformly dispersed in deionized water by ultrasonic waves, and then subjected to suction filtration, dialysis and freeze drying to obtain the nitrogen-containing graphene quantum dot. The preparation method comprises the following steps: dispersing nitrogen-containing graphene quantum dots, fatty alcohol-polyoxyethylene ether carboxylic acid and a catalyst in absolute ethyl alcohol, carrying out ultrasonic oscillation for 30 minutes, carrying out reflux reaction, and carrying out reduced-pressure rotary evaporation, thereby obtaining the nitrogen-containing graphene quantum dots. The prepared high-activity graphene quantum dots are small in particle size, high in activity and capable of entering small pores to peel crude oil, so that the recovery efficiency can be remarkably improved, the point injection allocation process is simple, the high-activity graphene quantum dots can be rapidly dispersed into injected water, an additional injection allocation device is not needed, and the construction cost is low.

The invention relates to the technical field of transposed conductors, in particular to a preparation process of an ultrathin paint film transposed conductor, which comprises the following steps of: coating acetal paint on a base material, then coating intermediate modified paint, finally coating outer paint, and processing a treated copper wire into the transposed conductor. According to the ultrathin paint film transposed conductor, a copper wire is cleaned through absolute ethyl alcohol, then acetal paint, intermediate modified paint and outer paint are coated in a matched mode, finally, the transposed conductor is manufactured through the transposed conductor device and the wrapping device, the electrical performance, the heat conduction performance, the salt mist resistance and the high temperature resistance of the product are excellent, and the service life of the product is prolonged. Meanwhile, the impact resistance and the waterproof effect of the product are excellent, and the comprehensive coordination of the product is improved in a balanced manner.

A magnetic nanoparticle composite microcapsule, and a preparation method therefor and the use thereof. The preparation method comprises: diluting concentrated ammonia water with absolute ethanol in which nano-Fe3O4 is dispersed, stirring same and adding ethyl orthosilicate, centrifuging same, and then performing washing to obtain Fe3O4 / SiO2 particles; dispersing same in anhydrous ethanol, then adding isopropanol containing tetrabutyl titanate, and performing a treatment to obtain Fe3O4 / SiO2 / TiO2 nanoparticles; adding polyurethane TDI prepolymer to the Fe3O4 / SiO2 / TiO2 nanoparticles, adding same to a core material, then dripping an emulsifier, and stirring same to obtain a core material emulsion; and heating same in a water bath, dropwise adding butanediol, and performing heating, stirring and vacuum filtration to obtain a magnetic nanoparticle composite microcapsule. By means of the loading with a core material having a repair function, the prepared magnetic microcapsule can actively repair damage to an insulating material caused by electrical and mechanical stress, thereby improving the reliability of a device.

The invention discloses a preparation method of a V-MOF nano material, which comprises the following steps: dissolving vanadium salt in absolute ethyl alcohol to form a solution A, and dissolving organic ligands 2-bromoterephthalic acid and diluted hydrochloric acid in absolute ethyl alcohol to form an organic ligand solution B; mixing the solution A and the organic ligand solution B, and performing stirring reaction to obtain a mixed solution C; reacting the mixed solution C under an ultrasonic condition to obtain a mixed solution D; the mixed solution D is subjected to a constant-temperature hydrothermal reaction, and after the hydrothermal reaction is finished, a product is cleaned to obtain the V-MOF nano material. According to the application of the V-MOF nano material in the aqueous zinc battery, the V-MOF nano material is prepared into electrode slurry, the surface of a titanium foil is coated with the electrode slurry, and the electrode slurry is dried to serve as an electrode plate of the aqueous zinc battery. The prepared vanadium-based nano material has high conductivity and cycling stability, the electrochemical performance of the aqueous zinc battery can be improved, the preparation process is simple and easy to operate, and the sea urchin-shaped V-MOF nano material can be obtained.

The invention discloses a preparation method for laser cladding of an iron-based alloy wear-resistant coating on the surface of an automobile brake disc, which comprises the following steps: (1) before cladding, putting iron-based alloy powder into a drying oven at 60 DEG C and drying for 120 minutes; (2) pretreating a matrix sample, removing rust and an oxide layer on the surface, cleaning the surface with absolute ethyl alcohol, and wiping to keep the surface dry; and (3) setting cladding process parameters, wherein the cladding process parameters comprise laser power, powder feeding amount, scanning speed, lap joint rate and scanning linear speed. And (4) a cladding experiment is started, and a cladding scanning path and mode are set, wherein the cladding scanning path and mode comprise a single-channel coating, a multi-channel lap joint coating and a whole-surface brake disc. And (5) after cladding is finished, waiting for natural cooling of the brake disc. The iron-based powder is used for preparing the coating on the surface of the automobile brake disc, technological parameters are optimized, the cladding procedure is simplified, the powder cost is low, the prepared coating is good in performance, and a single-layer coating scheme is provided for strengthening and repairing the brake disc.

The invention discloses a closed-cell heat-conducting flame-retardant foamed silica gel material and a preparation method thereof in the field of organic silicon functional materials. The closed-cell heat-conducting flame-retardant foamed silica gel material is prepared from the following raw materials: basic silica gel, silane modified boron nitride, titanate modified aluminum hydroxide, a foaming agent, a cross-linking agent, a catalyst, an inhibitor and absolute ethyl alcohol. The raw materials are mixed according to a certain mass ratio. Wherein the silane modified boron nitride is prepared by heating, refluxing and reacting boron nitride powder and a silane coupling agent in an ethanol solvent and then drying; the titanate modified aluminum hydroxide is prepared by ultrasonically dispersing aluminum hydroxide powder and a titanate coupling agent in deionized water, adjusting the pH value, reacting and drying. The preparation method comprises the following steps: mixing the basic silica gel with the two modified fillers at a high speed, sequentially adding other raw materials, continuously mixing, transferring into a mold, pressurizing at a certain temperature to complete vulcanization foaming, taking out, washing with water, and drying in vacuum. According to the material, the interface bonding force is improved through the modified filler, and the material has the characteristics of high heat conductivity, high flame retardance and stable closed-cell structure.

The invention relates to the technical field of heat energy storage materials, and particularly provides a silicon dioxide aerogel composite phase change heat storage material and a preparation method thereof. The method comprises the following steps: mixing an organic silicon source, absolute ethyl alcohol and deionized water according to a specific ratio, fully stirring to obtain a mixed solution, and dropwise adding an acid catalyst into the mixed solution at room temperature for hydrolysis reaction to obtain a hydrolysate; sequentially adding a drying control agent and an alkali catalyst, and standing for gelation reaction to obtain gel; adding an organic solvent to carry out aging reaction, and then adopting the organic solvent to carry out replacement for multiple times to obtain alcogel; replacing the alcohol gel with an organic solvent for multiple times to obtain wet gel, soaking the wet gel in an excessive molten phase change material, and carrying out normal-pressure solvent replacement and drying at 40 DEG C to obtain the phase change material, the loading capacity of octadecane in the obtained CPCM is about 83%, the phase change enthalpy reaches up to 192J / g, the heat conductivity is as low as 0.0812 W / m.K, and no obvious leakage occurs after 200 times of circulation.

The invention discloses a preparation method of an electrode composite material, the electrode composite material and application of the electrode composite material, and the preparation method comprises the following steps: sequentially crushing and pickling a soft carbon raw material to obtain a soft carbon precursor; placing the soft carbon precursor, a hard carbon material and absolute ethyl alcohol in a sand mill for sanding treatment, and uniformly mixing to obtain a mixed dispersion liquid; carrying out drying treatment on the mixed dispersion liquid to obtain a composite carbon matrix precursor; placing the composite carbon matrix precursor in a rotary furnace, performing carbonization treatment in an inert gas environment, and performing grinding, crushing and sieving to obtain a carbonized compound; placing the carbonized compound in a rotary furnace, and activating under the condition of carbon dioxide gas and / or water vapor to obtain a composite carbon matrix containing a pore structure; and introducing gas containing a silicon source into the rotary furnace, depositing nano silicon in pores of the composite carbon matrix through chemical vapor deposition, and crushing to obtain the electrode composite material.

The invention provides an aluminum oxide aerogel composite material as well as a preparation method and application thereof, and belongs to the technical field of aluminum oxide aerogel preparation. The preparation method provided by the invention comprises the following steps: (1) preparing aluminum sol by taking coal gangue as an aluminum source; (2) mixing the aluminum sol obtained in the step (1) with aluminum silicate fibers, and performing gelation to obtain composite hydrogel; and (3) mixing the composite hydrogel obtained in the step (2) with ethanol, aging, mixing with a modifier, modifying, and carrying out graded normal-pressure drying to obtain the aluminum oxide aerogel composite material, the modifier in the step (3) is one or more of absolute ethyl alcohol, tetraethoxysilane and normal hexane. The alumina aerogel composite material prepared by the preparation method provided by the invention has the characteristics of low density, low heat conductivity coefficient and high strength, and is suitable for the high-temperature processing field of special materials and the aerospace field.

The invention relates to the field of battery materials, and discloses a preparation method of a porous hard carbon material and application of the porous hard carbon material in a sodium-ion battery, the preparation method of the material comprises the following steps: S1, preparing a sucrose solution by taking sucrose as a carbon source, carrying out hydrothermal reaction treatment on the sucrose solution, and then filtering and separating to obtain a hard carbon precursor; s2, dissolving zinc salt with distilled water to prepare a solution, adding the hard carbon precursor obtained in S1 into the solution, then adding absolute ethyl alcohol into the solution, mixing and stirring at normal temperature, finally heating to evaporate the solvent to dryness, and fully grinding to obtain a uniformly mixed material containing the zinc salt; and S3, putting the material obtained in the S2 into a furnace body, heating to 600 DEG C under a protective atmosphere, carrying out primary carbonization, then heating to 1300 DEG C, carrying out high-temperature carbonization, cooling, taking out, and uniformly grinding, so as to obtain the porous hard carbon material. The material provided by the invention has the characteristics of convenient preparation method, high first-week coulombic efficiency and high specific capacity.

The invention relates to the technical field of metal materials, in particular to a ceramic reinforced aluminum alloy composite material and a preparation method thereof. The aluminum alloy composite material comprises the following raw materials in parts by weight: 75-85 parts of an aluminum alloy matrix and 10-20 parts of a ceramic reinforced phase, a preparation method of the ceramic reinforced phase comprises the following steps: step 1, adding silicon carbide and a silane coupling agent into absolute ethyl alcohol, and drying after ultrasonic dispersion; 2, dissolving tetraethoxysilane in an ethanol-water mixed solvent, adjusting the pH value to 3-4, adding the silicon carbide treated in the step 1, stirring to form sol, drying, converting into gel, and calcining to form a coating layer; step 3, dispersing the silicon carbide treated in the step 2 into water, adding nickel nitrate, uniformly stirring, adding a reducing agent, stirring for reaction, and collecting precipitate particles; and 4, adding an interface modifier, and uniformly mixing. The ceramic reinforced aluminum alloy composite material has high strength, high wear resistance and good mechanical property and thermal stability.

The invention discloses a high-performance polyether-ether-ketone modified sealing material and a preparation method thereof, and relates to the technical field of sealing materials. The high-performance polyether-ether-ketone modified sealing material is prepared from the following raw materials in percentage by mass: 5 to 10 percent of polytetrafluoroethylene micro powder, 5 to 10 percent of graphene nanosheets, 10 to 15 percent of silicon carbide whiskers, 0.5 to 2 percent of silane coupling agent and the balance of polyether-ether-ketone, the preparation method of the high-performance polyether-ether-ketone modified sealing material comprises the following steps: mixing graphene nanosheets with a silane coupling agent, deionized water and absolute ethyl alcohol, carrying out ultrasonic dispersion for 2 hours, carrying out pretreatment to obtain a graphene nanosheet suspension, mixing the graphene nanosheet suspension with silicon carbide whiskers, polytetrafluoroethylene micro powder and polyether-ether-ketone, carrying out melt blending, and carrying out compression molding to obtain the high-performance polyether-ether-ketone modified sealing material. And cooling to obtain the high-performance polyether-ether-ketone modified sealing material.