701 results about "Anhydrous ethanol" patented technology

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

The invention provides a photo-thermal evaporation material based on black titanium dioxide as well as a preparation method and application of the photo-thermal evaporation material. The preparation method comprises the following steps: mixing urea, absolute ethyl alcohol and tetrabutyl titanate into a solution A, mixing absolute ethyl alcohol, ultrapure water and hydrochloric acid into a solution B, dropwise adding the solution B into the solution A, mixing to form a white colloid, heating in a water bath, drying, and calcining in a nitrogen atmosphere to obtain black titanium dioxide powder; the preparation method comprises the following steps: fully mixing a certain amount of black titanium dioxide, sodium alginate and ultrapure water to form a uniform dispersion liquid, dipping the pretreated polyurethane sponge in the dispersion liquid, and crosslinking with a calcium chloride solution to prepare the photo-thermal evaporation material of the black titanium dioxide-calcium alginate composite hydrogel. The photo-thermal evaporation material breaks through the photo-thermal application bottleneck of traditional titanium dioxide, has excellent evaporation rate and seawater desalination performance, and can effectively remove various printing and dyeing wastewater to obtain clean water.

The invention relates to the technical field of transposed conductors, in particular to a preparation process of an ultrathin paint film transposed conductor, which comprises the following steps of: coating acetal paint on a base material, then coating intermediate modified paint, finally coating outer paint, and processing a treated copper wire into the transposed conductor. According to the ultrathin paint film transposed conductor, a copper wire is cleaned through absolute ethyl alcohol, then acetal paint, intermediate modified paint and outer paint are coated in a matched mode, finally, the transposed conductor is manufactured through the transposed conductor device and the wrapping device, the electrical performance, the heat conduction performance, the salt mist resistance and the high temperature resistance of the product are excellent, and the service life of the product is prolonged. Meanwhile, the impact resistance and the waterproof effect of the product are excellent, and the comprehensive coordination of the product is improved in a balanced manner.

The invention relates to the technical field of heat energy storage materials, and particularly provides a silicon dioxide aerogel composite phase change heat storage material and a preparation method thereof. The method comprises the following steps: mixing an organic silicon source, absolute ethyl alcohol and deionized water according to a specific ratio, fully stirring to obtain a mixed solution, and dropwise adding an acid catalyst into the mixed solution at room temperature for hydrolysis reaction to obtain a hydrolysate; sequentially adding a drying control agent and an alkali catalyst, and standing for gelation reaction to obtain gel; adding an organic solvent to carry out aging reaction, and then adopting the organic solvent to carry out replacement for multiple times to obtain alcogel; replacing the alcohol gel with an organic solvent for multiple times to obtain wet gel, soaking the wet gel in an excessive molten phase change material, and carrying out normal-pressure solvent replacement and drying at 40 DEG C to obtain the phase change material, the loading capacity of octadecane in the obtained CPCM is about 83%, the phase change enthalpy reaches up to 192J / g, the heat conductivity is as low as 0.0812 W / m.K, and no obvious leakage occurs after 200 times of circulation.

The invention provides an aluminum oxide aerogel composite material as well as a preparation method and application thereof, and belongs to the technical field of aluminum oxide aerogel preparation. The preparation method provided by the invention comprises the following steps: (1) preparing aluminum sol by taking coal gangue as an aluminum source; (2) mixing the aluminum sol obtained in the step (1) with aluminum silicate fibers, and performing gelation to obtain composite hydrogel; and (3) mixing the composite hydrogel obtained in the step (2) with ethanol, aging, mixing with a modifier, modifying, and carrying out graded normal-pressure drying to obtain the aluminum oxide aerogel composite material, the modifier in the step (3) is one or more of absolute ethyl alcohol, tetraethoxysilane and normal hexane. The alumina aerogel composite material prepared by the preparation method provided by the invention has the characteristics of low density, low heat conductivity coefficient and high strength, and is suitable for the high-temperature processing field of special materials and the aerospace field.

The invention relates to the technical field of metal materials, in particular to a ceramic reinforced aluminum alloy composite material and a preparation method thereof. The aluminum alloy composite material comprises the following raw materials in parts by weight: 75-85 parts of an aluminum alloy matrix and 10-20 parts of a ceramic reinforced phase, a preparation method of the ceramic reinforced phase comprises the following steps: step 1, adding silicon carbide and a silane coupling agent into absolute ethyl alcohol, and drying after ultrasonic dispersion; 2, dissolving tetraethoxysilane in an ethanol-water mixed solvent, adjusting the pH value to 3-4, adding the silicon carbide treated in the step 1, stirring to form sol, drying, converting into gel, and calcining to form a coating layer; step 3, dispersing the silicon carbide treated in the step 2 into water, adding nickel nitrate, uniformly stirring, adding a reducing agent, stirring for reaction, and collecting precipitate particles; and 4, adding an interface modifier, and uniformly mixing. The ceramic reinforced aluminum alloy composite material has high strength, high wear resistance and good mechanical property and thermal stability.

The invention discloses a high-performance polyether-ether-ketone modified sealing material and a preparation method thereof, and relates to the technical field of sealing materials. The high-performance polyether-ether-ketone modified sealing material is prepared from the following raw materials in percentage by mass: 5 to 10 percent of polytetrafluoroethylene micro powder, 5 to 10 percent of graphene nanosheets, 10 to 15 percent of silicon carbide whiskers, 0.5 to 2 percent of silane coupling agent and the balance of polyether-ether-ketone, the preparation method of the high-performance polyether-ether-ketone modified sealing material comprises the following steps: mixing graphene nanosheets with a silane coupling agent, deionized water and absolute ethyl alcohol, carrying out ultrasonic dispersion for 2 hours, carrying out pretreatment to obtain a graphene nanosheet suspension, mixing the graphene nanosheet suspension with silicon carbide whiskers, polytetrafluoroethylene micro powder and polyether-ether-ketone, carrying out melt blending, and carrying out compression molding to obtain the high-performance polyether-ether-ketone modified sealing material. And cooling to obtain the high-performance polyether-ether-ketone modified sealing material.

The application discloses a kind of nano magnetic flocculants and its preparation method and application, belong to drinking water processing technical field, including the following steps: step S1, modified ferroferric oxide nanosphere is ultrasonically dispersed in ammonia alcohol solution, while stirring, slowly drop adding tetraethyl orthosilicate, continue stirring after drop, after centrifugal separation, wash, obtain silica coated ferroferric oxide nanoparticles;Step S2, phenylalanine modified chitosan is added into glacial acetic acid solution, after completely swelling and dissolving, add silica coated ferroferric oxide nanoparticles and ultrasonic treatment, under low pressure ultraviolet lamp, then with anhydrous ethanol wash purification, vacuum drying to constant weight, obtain nano magnetic flocculants;The method of the application is simple and easy to operate, the nano magnetic flocculants prepared can be quickly adsorbed to the surface of sulfonamide antibiotics, produce flocculation and can be magnetically separated, very suitable for trace sulfonamide antibiotics in drinking water source efficient removal.

The invention relates to the technical field of rubber tree bark beetle prevention and control and green ecological prevention and control, in particular to a rubber tree bark beetle attractant and lure preparation and application thereof. Comprising the following components in parts by weight: 1 part of (S)-cis-verbenol, 1 part of isoamyl alcohol, 1 part of longifolene and 6500 parts of absolute ethyl alcohol. The attractant can attract bark beetles on rubber trees, has the advantages of being good in attraction effect, long in lasting period, environmentally friendly and the like and is suitable for long-term monitoring and efficient prevention and control of bark beetle populations on the rubber trees, and the attraction core is not affected by terrains and terrains when applied.

The invention discloses a rinsing process for deep cleaning of purified natural quartz, which comprises the following steps: putting acid-washed quartz sand into a cleaning medium tank containing a mixed cleaning solution of deionized water and absolute ethyl alcohol for cleaning, and applying ultrasonic waves in the cleaning process; the cleaned quartz sand is put into a cleaning medium tank containing a mixed cleaning solution composed of deionized water, hydrogen peroxide and hydrofluoric acid to be cleaned, and ultrasonic waves are applied in the cleaning process; and the cleaned quartz sand is put into a cleaning medium tank containing deionized water to be rinsed so as to remove acid pickling residues to achieve deep cleaning, and ultrasonic waves are applied in the cleaning process. According to the method, a three-step cleaning scheme is innovatively adopted, so that loose impurities on the surfaces of quartz sand particles and organic reagent residues of a flotation process are efficiently stripped; the three steps are clear in function and have a synergistic effect, and the cleaning effect is far better than that of traditional single washing.

The invention provides a preparation method of a cellulose-based water-induced deformation and color-changing film. Water-induced deformation and color-changing response are realized synergistically. The film is mainly prepared from the following components in parts by weight: 16.67 to 25 parts of hydrophilic micelle, 33.33 to 50 parts of absolute ethyl alcohol, 10 to 16 parts of modified cellulose, 12.5 to 20 parts of cross-linking agent and 2.5 to 4 parts of red dye. The cellulose-based water-induced deformation and color-changing film can realize deformation and color-changing response at the same time, the water absorption rate and the water absorption capacity of the two surfaces of the film are regulated and controlled by utilizing the content difference of hydrophilic micelles in the upper surface and the lower surface of the film, and the water-induced deformation response of the film is realized. Meanwhile, after the thin film absorbs water and swells, the microstructure arrangement in the thin film is changed due to the increase of the volume, so that incident light generates a stronger scattering effect in the material, and the hydrochromic behavior of the thin film is realized. The cellulose-based water-induced deformation and color-changing film has synergistic deformation and color-changing response to water stimulation, and has great application potential in the fields of actuators, wearable electronic equipment, intelligent robots and the like.

The invention provides a preparation method of an SA / GO / metal ion functional coating diaphragm suitable for a chloride ion battery, which comprises the following steps: mixing SA (sodium alginate) and GO (graphene oxide) aqueous solution, grinding into gel, and uniformly coating the gel on the diaphragm; then, the diaphragm is sequentially put into an ethanol solution containing metal salt and absolute ethyl alcohol to be soaked; and finally, vacuum drying is performed to prepare the SA / GO / metal ion functional coating diaphragm. By introducing the sodium alginate, on one hand, the sodium alginate is crosslinked with the graphene oxide to construct a better network structure, so that an excellent effect can still be ensured while the dosage of the sodium alginate is reduced; on the other hand, carboxyl and hydroxyl on the sodium alginate can be cross-linked with multivalent metal ions to form a film layer capable of effectively preventing ions from passing through so as to prevent loss of active substances, and meanwhile, rich oxygen-containing functional groups can capture free multivalent metal ions. The synergistic effect finally greatly improves the discharge capacity and the cycle stability of the chloride ion battery.

The invention discloses a preparation method of an aerogel laminated composite heat insulation pad, and relates to the technical field of aerogel heat insulation pads, and the preparation method comprises the following steps: mixing and dispersing a silane precursor and absolute ethyl alcohol, adding a basic catalyst, hydrolyzing to generate sol, and aging to form prefabricated sol; adding a flame retardant, a smoke retardant and reinforced fibers, dispersing and gelatinizing, and carrying out supercritical drying to obtain an aerogel block; and coating basalt fiber non-woven fabric with the aerogel slurry to form a base layer, laminating a plurality of layers, and carrying out hot-pressing curing, cooling, post-curing, cutting and edge covering to obtain the composite heat insulation pad. According to the invention, by optimizing the ratio of silane and a drying process, the pore structure and the thermal stability of the aerogel are obviously improved; the flame-retardant, mechanical and heat-insulating properties are improved through multi-component collaborative design, and the obtained heat-insulating pad has the characteristics of low heat conductivity, high strength, excellent flame retardance and light weight, and is suitable for multiple heat-insulating and flame-retardant fields.

The invention relates to the technical field of automobile essence preparation, and particularly discloses automobile essence capable of removing formaldehyde and releasing anions and a preparation method of the automobile essence. Comprising the following raw materials in parts by weight: 500-600 parts of deionized water, 18-24 parts of a negative ion release enhancing component, 12-20 parts of an aldehyde removing component, 30-40 parts of absolute ethyl alcohol, 8-14 parts of a dispersing agent, 14-18 parts of phenoxyethanol, 22-26 parts of an initiator solution and 6-10 parts of citral. A negative ion release enhancing component and a formaldehyde removal component are added, the negative ion release enhancing component is prepared by modifying core-shell particles with a silane coupling agent, the outer layer of each core-shell particle is of a porous titanium dioxide structure, the inner core of each core-shell particle is modified electrical powder, and the formaldehyde removal component is prepared by carrying out a ring-opening esterification reaction on sodium alginate and allyl glycidyl ether, so that the formaldehyde removal effect is improved. And then carrying out chemical cross-linking with hydroxypropyl acrylate and methacrylic acid, thereby coordinating and enhancing the formaldehyde removal capability, the anion release capability and the antibacterial effect.

The invention discloses an anti-reflection self-cleaning coating for silane modified photovoltaic glass as well as a preparation method and application of the anti-reflection self-cleaning coating. The preparation method comprises the following steps: mixing 40-50 parts by weight of water and 30-40 parts by weight of absolute ethyl alcohol, adding 0.05-1 part by weight of a silane coupling agent, and stirring to obtain a mixture; dividing the sample into two parts, marking the two parts as a solution A and a solution B, and adding 0.5-1 part by weight of nano titanium dioxide into the solution A; adding 10-20 parts by weight of hydrophilic silica sol into the solution B; adding the solution A into the solution B, mixing, and adding 1-10 parts by weight of hexadecyl trimethyl ammonium chloride to obtain a TiO2 / SiO2 composite super-hydrophilic self-cleaning coating; mixing 5-10 parts by weight of absolute ethyl alcohol and 1-5 parts by weight of silane, and adding the mixture into the coating to obtain an anti-reflection self-cleaning coating solution for silane modified photovoltaic glass; and coating the coating on a photovoltaic glass substrate, and drying to obtain the anti-reflection self-cleaning coating for the silane modified photovoltaic glass.

The invention discloses a high-flame-retardant plate and a production process thereof, and relates to the technical field of flame-retardant materials. The high-flame-retardant plate is prepared from the following raw materials in parts by weight: 90 to 110 parts of magnesium oxide, 15 to 20 parts of magnesium chloride, 30 to 35 parts of magnesium sulfate, 1.5 to 3 parts of modified polyvinyl alcohol, 1 to 2 parts of starch, 0.3 to 0.8 part of modified borax, 0.2 to 0.5 part of silane coupling agent KH-550, 1 to 2 parts of absolute ethyl alcohol, 2.5 to 3.5 parts of nano zinc borate, 2 to 4 parts of chlorinated paraffin-70, 0.5 to 1 part of nano titanium dioxide, 5 to 10 parts of basalt fiber and 0.2 to 0.5 part of calcium stearate. And 90 to 110 parts of deionized water. The raw materials of the high-flame-retardant plate are subjected to condensation cross-linking and nanometer enhancement of the modified polyvinyl alcohol and esterification and chelation treatment of the modified borax, so that the flame-retardant compatibility is improved. In production, pre-dispersion of the silane coupling agent and synergistic mixing of the starch paste are matched with precise viscosity regulation and control and stepped sanding, so that uniformity of the slurry is ensured. And hot pressing parameters are optimized, so that the plate is high in density and excellent in flame retardance and surface precision.

The invention belongs to the field of photovoltaic module recovery, and discloses a method for treating an EVA (Ethylene Vinyl Acetate) adhesive film of a decommissioned photovoltaic module by a low-temperature chemical method. The method comprises the following steps of: disassembling the decommissioned photovoltaic module and cutting the decommissioned photovoltaic module into small samples; pretreating the sample; and putting the pretreated sample into a mixed solution of gamma-valerolactone, D-limonene, polyethylene glycol, absolute ethyl alcohol, 2-methylimidazole and polydimethylsiloxane, and soaking at low temperature, so that the EVA adhesive film is swelled, the adhesive force between the EVA adhesive film and the battery piece is reduced, and the separation of the EVA adhesive film and the battery piece is realized. Treatment can be carried out at low temperature, energy consumption is remarkably reduced, and the environment-friendly requirement is met; the operation process is simple, and the treatment period is short.

The invention discloses a hawthorn, hippophae rhamnoides fruit and red date compound beverage with an anti-caries function and a preparation method thereof, and relates to the technical field of compound beverages. The preparation method comprises the following steps: crushing dried hawthorn for later use without specific particle size limitation so as to meet the contact requirement of subsequent extraction), sea-buckthorn primary pulp (without additional pretreatment requirement so as to ensure no spoilage) and red date primary pulp (with the quality requirement of the sea-buckthorn primary pulp); the specifications of the auxiliary materials and the solvent are as follows: stevioside (food grade, the purity meets the industrial standard), erythritol (food grade, white crystalline), distilled water (meeting the standard of pure water for food processing) and absolute ethyl alcohol (analytically pure and used for polysaccharide alcohol precipitation); according to the process, ultrasonic-assisted heat extraction, alcohol precipitation and freeze drying are taken as a core process, and the polysaccharide extraction rate of more than or equal to 15.5% is realized by optimizing extraction parameters.

The invention discloses a modified PVC (polyvinyl chloride) particle and a preparation method thereof in the field of high polymer material modification, the modified PVC particle takes PVC resin as a matrix, and two brand new modifiers, namely a silicon-boron-nitrogen hybrid epoxy nanosphere and epoxidized soybean oil-maleic anhydride-2-ethylhexyl acrylate random copolymer, and other auxiliaries are added. The silicon-boron-nitrogen hybrid epoxy nanospheres are prepared by the following steps: hydrolyzing tetraethoxysilane and triethyl borate in absolute ethyl alcohol to generate a silicon-boron alcohol intermediate, then carrying out sol-gel reaction on the silicon-boron alcohol intermediate and glycidyl methacrylate to form a hybrid network containing an epoxy group, and finally carrying out ultrasonic dispersion. The epoxidized soybean oil-maleic anhydride-2-ethylhexyl acrylate random copolymer is prepared by carrying out ring opening on epoxidized soybean oil and peracetic acid to generate epoxidized soybean oil acrylate, and then carrying out free radical copolymerization reaction on the epoxidized soybean oil acrylate, maleic anhydride and 2-ethylhexyl acrylate. The method is suitable for the fields of high-end building materials, automotive interiors and the like.

The invention discloses a preparation method of an environment-friendly photo-thermal super-hydrophobic coating and application of the environment-friendly photo-thermal super-hydrophobic coating on a road, and aims to solve the problems that the deicing and anti-icing effects of an existing photo-thermal super-hydrophobic coating are limited, and fluorine-containing low-surface-energy components are mostly adopted and are difficult to degrade. The preparation method comprises the following steps: 1, dispersing epoxy resin, polydimethylsiloxane and a PDMS curing agent into absolute ethyl alcohol to obtain dispersion liquid; 2, adding nano silicon dioxide particles and a silane coupling agent into the dispersion liquid; 3, continuously adding hydroxylated multi-walled carbon nanotubes to obtain a dispersion liquid; 4, adding an epoxy resin curing agent; and 5, coating the pavement with the photo-thermal super-hydrophobic material dispersion liquid, and curing to obtain the photo-thermal super-hydrophobic coating. According to the invention, an epoxy resin and polydimethylsiloxane composite system is adopted as a matrix, excellent adhesive force and flexibility are taken into account, a stable bonding layer can be formed on a road base material, and long-term durability of the coating under the conditions of freeze-thaw cycle, vehicle friction and wind and rain erosion is ensured.

The invention provides a silicon-carbon negative electrode material and a preparation method and application thereof, and belongs to the technical field of lithium ion battery negative electrode materials. The preparation method comprises the following steps: adding silicon tetrachloride and calcium carbide into a carbon tetrachloride solution, uniformly stirring, and transferring into a high-pressure reaction kettle for reaction to obtain a Si-C precursor; adding the obtained Si-coated C precursor into absolute ethyl alcohol and carrying out ball milling treatment; and carrying out suction filtration and drying on the material obtained by ball milling, calcining and carbonizing in inert gas, and cleaning the obtained product to obtain the silicon-carbon negative electrode material. The silicon-carbon negative electrode material prepared by the invention is used for preparing a negative electrode material of a lithium ion battery, has good cycle performance, has relatively high reversible specific capacity and first coulombic efficiency, and is excellent in overall electrochemical performance.

This invention relates to a method for preparing carbon materials based on in-situ surface fluoride modification, comprising the following steps: ① dissolving carbon material powder, aluminum nitrate, and polyvinyl alcohol in anhydrous ethanol to obtain an aluminum nitrate solution; ② dissolving ammonium fluoride in a mixed solvent to obtain an ammonium fluoride solution; slowly adding the ammonium fluoride solution dropwise to the aluminum nitrate solution to carry out an in-situ AlF3 growth reaction to obtain a composite material precursor; ③ drying the composite material precursor and then calcining it using a programmed temperature rise method to solidify the coating layer, thereby obtaining the AlF3@C composite material. This invention also discloses the application of this carbon material. The preparation method of this invention is simple and low-cost, and can efficiently prepare AlF3@C composite materials. The obtained AlF3@C composite material, as a negative electrode material for potassium-ion or lithium-ion secondary batteries, can significantly improve a series of properties such as the initial coulombic efficiency, rate performance, cycle stability, and potassium ion diffusion kinetics of the battery.

The invention discloses a synthesis method and application of nitrogen-doped carbon-coated Co porous spheres, cobalt nitrate hexahydrate and 4-picolinic acid are dissolved in a mixed solution, the mixed solution comprises dimethylformamide and absolute ethyl alcohol, then the mixed solution is transferred into a reaction kettle for heating reaction, and after the reaction is finished, centrifugal drying is performed to obtain a Co coordination compound precursor; and calcining the precursor in an argon hydrogen atmosphere, and selecting and setting a proper heating rate, a proper calcining temperature and a proper calcining time to obtain the nitrogen-doped carbon-coated Co porous ball. The obtained nitrogen-doped carbon-coated Co porous ball is used as the air cathode of the zinc-air battery, so that high power density and excellent charge-discharge cycle stability are realized.

The application relates to the technical field of solar energy, in particular to a self-cleaning solar photovoltaic panel and a preparation process thereof. The application adds anhydrous ethanol, ammonia water, deionized water, methyl triethoxysilane, tetraethyl orthosilicate and octadecyl trimethoxysilane to prepare silica sol. Then, tetra(2-hydroxyethoxy)silane, polypropylene glycol, toluene diisocyanate, betulin, 3,4-diamino furazan, silica sol and a catalyst stannous octoate are added to prepare a polymer. Glass, ethylene-vinyl acetate copolymer, a cell piece and ethylene-vinyl acetate copolymer are sequentially laid in layers; the laminated assembly is assembled with a frame to obtain a solar photovoltaic panel. Finally, a coating is prepared by taking the polymer as a raw material, and the coating is coated on the solar photovoltaic panel to obtain a finished product. The finished product has good hydrophobicity and antibacterial property, and therefore has a wide application prospect.

The invention provides a prismatic titanium diboride reinforced boron nitride-based conductive ceramic evaporation boat and a preparation method thereof, and belongs to the technical field of ceramic evaporation boats. The step of preparing the boron nitride matrix comprises the following steps: adding boron nitride powder into a nitric acid solution to obtain pretreated boron nitride powder; adding the pretreated boron nitride powder into absolute ethyl alcohol, adding tetrabutyl titanate and deionized water, adjusting the pH value to 4.0-4.3, stirring for 1.2-1.5 hours at the temperature of 30-32 DEG C, drying and calcining to obtain a boron nitride matrix; the prepared conductive ceramic evaporation boat is low in resistivity, high in strength, excellent in corrosion resistance and good in comprehensive performance.

The application discloses a copper-tin oxide composite material and a preparation method thereof. The preparation method comprises the following steps: firstly, mixing spherical gas-atomized copper-tin alloy powder, ultrapure water and hydrogen peroxide solution, and placing the mixture in a high-temperature and high-pressure reaction kettle to perform supercritical water in-situ reaction to generate copper-tin oxide powder. After the reaction, the powder is treated by ultrasonic cleaning, water and ethanol cleaning and vacuum drying. Then, the copper oxide is reduced by using hydrogen gas in a tube furnace to obtain copper-tin oxide powder. After that, the copper powder and the copper-tin oxide powder are mixed in proportion, and stearic acid or anhydrous ethanol is added as a dispersant to perform ball milling, so as to obtain copper-tin oxide composite powder. Finally, the copper-tin oxide composite material is obtained by pressing and discharge plasma sintering technology. The copper-tin oxide composite powder is prepared by supercritical water in-situ oxidation, so that the process flow is simplified, the performance and conductivity of the composite material are improved, and the environmental protection requirement is met.

The invention relates to a difunctional organic lithium salt, a preparation method thereof and application of the difunctional organic lithium salt in regeneration of waste lithium iron phosphate. Firstly, benzene-containing organic molecules, inorganic lithium salt, an organic solvent and the like are used as raw materials, difunctional organic lithium salt with a lithium carboxylate (COO-Li +) and lithium phenolate (Ph-O-Li +) composite structure is prepared, then the waste lithium iron phosphate positive electrode material and the difunctional organic lithium salt are evenly mixed according to a certain proportion, the obtained mixture is heated to 650-800 DEG C to be subjected to high-temperature calcination, and the waste lithium iron phosphate positive electrode material is obtained. And repeatedly cleaning with absolute ethyl alcohol and deionized water, and drying to finally obtain the regenerated lithium iron phosphate which has a crystal structure equivalent to that of the original lithium iron phosphate and has high specific capacity, excellent rate capability and good cycle stability. In the regeneration process of the waste lithium iron phosphate, the difunctional organic lithium salt can supplement lithium vacancies and realize carbon coating, so that the defects of the waste lithium iron phosphate are repaired, the regenerated lithium iron phosphate can be directly used for manufacturing battery positive electrodes and lithium batteries, and an important support is provided for sustainable development of the lithium battery industry.

This invention discloses a TiC-Ti3C2T x The preparation method of MXene composite material includes: acid etching of Ti3AlC2 ceramic powder, washing of etching products, centrifugation, and ultrasonic layering to obtain single-layer and few-layer Ti3C2T. x Colloidal solution, then freeze-dried to obtain monolayer and few-layer Ti3C2T x Powder; TiC powder, dried Ti3C2T x TiC-Ti3C2T was prepared by high-shear emulsification and mixing of powder and polytetrafluoroethylene dissolved in anhydrous ethanol, followed by rotary evaporation, drying, and spark plasma sintering. x MXene composite material. This invention solves the problem of reinforcement dispersion in TiC ceramic matrix and addresses the issue of Ti3C2T under high-temperature sintering conditions. x The MXene phase transformation and oxidation problems are addressed, and the TiC matrix is ​​strengthened and toughened by inducing matrix grain refinement, crack deflection, crack bridging, and lamellar pull-out, thereby improving bending strength and fracture toughness.

The invention relates to a lasting antibacterial photocatalyst particle and a preparation method thereof, and the preparation raw materials of the lasting antibacterial photocatalyst particle comprise the following components in parts by weight: 10-15 parts of butyl titanate, 5-10 parts of tetraethoxysilane, 1-2 parts of a rare earth compound, 8-15 parts of a silane coupling agent, 250-280 parts of absolute ethyl alcohol, 5-10 parts of industrial hydrochloric acid and 5-10 parts of deionized water. According to the photocatalyst particles, titanium dioxide serves as a core body, silicon dioxide serves as a shell layer, the silicon dioxide shell layer is of a mesoporous structure, and rare earth elements are distributed between the titanium dioxide core body and the silicon dioxide shell layer. Through the synergism of the titanium dioxide core, the porous silicon dioxide shell and the rare earth elements distributed between the core and the shell, the photocatalyst particles have the excellent effects of lasting and efficient antibacterial property and high stability.