The application belongs to the technical field of ship exhaust purification, and particularly relates to a catalyst for decomposing N2O in the exhaust of a ship
ammonia internal combustion engine and a preparation method thereof. 3+ By replacing Co ions in the Co3O4
spinel lattice into the lattice, the
doping behavior can effectively reduce the number of hydroxyl groups on the surface of the catalyst, significantly weaken the adsorption and combination ability of water molecules, and thus improve the stability of the catalyst in a high-
humidity exhaust environment. As an additive, CeO2 uses its
oxygen storage capacity to promote the migration and
desorption of
oxygen species in the reaction, preventing the deactivation of active sites due to
oxygen poisoning. The
molecular sieve carrier not only provides a highly dispersed surface for the
active component to prevent
sintering, but also optimizes the adsorption and activation path of N2O and alleviates the poisoning effect of
nitrogen-containing intermediate species or impurities in the exhaust on the Co
active center during the reaction.