597 results about "Oxide composite" patented technology

The invention relates to the technical field of gas detection, in particular to a multi-gas accurate detection method and system.The method comprises the following steps that gas to be detected flows through a miniature gas enrichment device prepared through an MEMS technology under driving of a miniature gas pump, and target gas is adsorbed and enriched through graphene and metal oxide composite sensitive materials on the surface of a spiral gas inlet flow channel in the miniature gas enrichment device; the desorption concentrated gas is heated to the multi-gas composite detector, and the sensor array reacts with the gas to generate an electric signal; the data acquisition unit performs noise reduction, amplification and analog-to-digital conversion preprocessing on the electric signal; the data processing unit extracts characteristic vectors such as a response curve peak value and a rising slope; inputting the feature vector into a pre-trained machine learning classification-regression combined model, and outputting a gas type identifier and an initial concentration; error compensation is carried out in combination with environment temperature and humidity and a cross sensitivity interference mode library, and finally accurate information of at least nine gases is output. The device has the advantages of high sensitivity, strong anti-interference performance and miniaturization.

The invention provides a wastewater advanced oxidation catalyst and a preparation method and application thereof, the wastewater advanced oxidation catalyst is of a core-shell structure, the core is activated carbon containing copper oxide and optional ferrous sulfide, and the shell is a silicon oxide-aluminum oxide compound containing nano ferrous sulfide. The invention further provides a preparation method of the wastewater advanced oxidation catalyst and application of the wastewater advanced oxidation catalyst in organic wastewater treatment. The wastewater advanced oxidation catalyst has the characteristics of high catalytic degradation capability on organic pollutants and the like, solves the problem of copper dissolution, and improves the long-term effectiveness of the catalyst.

The invention relates to the technical field of soil remediation, in particular to a charcoal-fungus symbiont for a freeze-thaw environment and a preparation method and application of the charcoal-fungus symbiont. The preparation method of the charcoal-fungus symbiont comprises the following steps: crushing a biomass raw material, and carrying out pyrolysis to prepare basic charcoal; placing the basic biochar in an iron oxide solution, and carrying out an iron oxide loading reaction to obtain iron oxide biochar; the preparation method comprises the following steps: dipping iron oxide biochar in a chitosan solution for coating modification, then continuously adding a cross-linking agent for cross-linking solidification, and freeze-drying to obtain chitosan-iron oxide composite modified biochar; and immersing the chitosan-iron oxide composite modified biochar into a bacterial suspension of functional microorganisms, oscillating and adsorbing, and freeze-drying to obtain the carbon-bacteria symbiont. The invention aims to improve the heavy metal pollution phenomenon of soil and the soybean root rot disaster in the freezing and thawing cycle environment at the same time.

The invention relates to a preparation method of an etching-resistant and wear-resistant Y2O3-AlxOy composite coating. The preparation method comprises the following steps: carrying out ultrasonic cleaning on a corrosion-resistant matrix; performing plasma bombardment cleaning activation on the surface of the corrosion-resistant matrix; a Y2O3 coating and an AlxOy coating are alternately deposited on a corrosion-resistant base body in a double-target magnetron sputtering mode to form the Y2O3-AlxOy composite coating, the sputtering power of a Y target is larger than that of an Al target, and the ratio of x to y in the AlxOy coating is larger than 1. According to the method, the amorphous AlxOy coating dominated by the metal state is introduced into the Y2O3 coating, growth of Y2O3 columnar crystals is continuously broken, crystal grains are refined, formation of intergranular easy-to-etch point locations is inhibited, and an yttrium aluminum oxide composite strengthening phase is formed at an interface, so that plasma etching resistance is improved; the thickness of a single-layer coating in the composite coating is very thin; under the action of growth stress, the structure of the coating presents a wave-shaped microstructure and a soft and hard alternate mechanical structure, and the soft and hard alternate mechanical structure is beneficial to inhibiting generation of transverse cracks, guiding friction crack level expansion, prolonging the friction life of the coating and reducing the wear rate.

According to the emulsion mixing equipment applied to the mixing field and used for aluminum oxide composite fiberboard production, through a guide cylinder which forms an annular gap with the inner wall of a tank body in an enclosing mode and a stirring assembly arranged on the lower portion of the guide cylinder, raw materials circularly flow between the annular gap and an inner cavity of the guide cylinder, and the stirring assembly and a shearing assembly act synergistically; firstly, raw materials fully flow, components are promoted to be uniformly dispersed, local concentration difference is avoided, a foundation is laid for stable emulsification, agglomeration and precipitation are reduced, the emulsification efficiency and quality are improved, meanwhile, by means of a plurality of heat exchange structures such as a tank shell wall cooling clamping cavity, a spiral heat exchange pipe, an emulsification stator inner heat exchange channel and a guide cylinder shell wall spiral channel, sufficient heat exchange is achieved, and the emulsification efficiency and quality are improved. The raw material temperature is effectively controlled, heat accumulation and overheating are reduced, and the gelation probability is reduced.

The invention relates to an electrolytic copper foil anode plate electrode and a preparation process thereof, and belongs to the technical field of electrolytic copper foil production. The electrolytic copper foil anode plate electrode sequentially comprises a titanium substrate, an Ir-Ta oxide transition layer and an IrO2-RuO2-SnO2 oxide composite coating from inside to outside. The preparation process comprises the following steps: firstly, forming a micron-sized rough surface by utilizing acetone and ethanol ultrasonic cleaning and oxalic acid etching; the transition layer is subjected to sol dispersion and sintering treatment through polyethylene glycol, so that the balance of low porosity and high bonding strength is realized; the composite coating adopts an acetylacetone-ethylene glycol monomethyl ether solvent system, and a nanocrystalline structure is formed through step-by-step sintering; and an Ir-rich passivation layer is generated through electrochemical activation, and the finally obtained anode plate electrode has more excellent electrochemical activity and longer service life.

The invention discloses a high-entropy oxide composite negative electrode material as well as a preparation method and application thereof, and relates to the technical field of all-solid-state lithium battery negative electrode materials, and the high-entropy oxide composite negative electrode material comprises a metal element and an oxygen element, the high-entropy oxide composite negative electrode material comprises a metal element and an oxygen element, wherein the metal elements are at least five of a chromium element, an iron element, a nickel element, a manganese element, a molybdenum element, a copper element and a cerium element; the molar ratio of the metal element to the oxygen element is 3: 4; the high-entropy oxide composite negative electrode material is of a spinel structure. According to the prepared high-entropy oxide composite negative electrode material, the problems that a traditional negative electrode material is unstable in structure, poor in interface contact and short in cycle life are solved, the electrochemical performance is improved, and an all-solid-state lithium battery prepared from the high-entropy oxide composite negative electrode material shows high reversible specific capacity and excellent cycle stability.

The invention discloses a sulfur iron oxide composite denitrification filler, a preparation method and application, and relates to the technical field of sewage treatment, the sulfur iron oxide composite denitrification filler comprises sulfur powder, siderite, magnesite, magnesium oxide, metal manganese, metal aluminum, nano iron, boric sludge, magnetite and a binder; wherein the sum of the addition amounts of the metal manganese, the metal aluminum and the nano iron accounts for 8-16% of the mass of the sulfur-iron oxide composite denitrification filler. The technical problems that in the prior art, strength and abrasion resistance are insufficient, and denitrification efficiency is low are solved.

The invention discloses a metal element doped MnO2 and MnFe oxide composite catalyst as well as a preparation method and application thereof, and belongs to the technical field of flue gas desulfurization and denitrification. The preparation method comprises the following steps: dissolving potassium permanganate, divalent manganese salt and doped metal salt in water for reaction to prepare metal element doped MnO2; and mixing and reacting with a template agent, ferric salt and sodium salt, drying and roasting to obtain the final catalyst. The MnO2 electronic structure is modulated by doping metal elements, and the three-dimensional porous structure of the MnFe oxide is constructed by using the template agent, so that the catalyst has efficient adsorption and strong catalytic oxidation capacity, NO and SO2 can be synergistically removed at the same time, and the catalyst has desulfurization and denitrification activity in a wide temperature range of 30-300 DEG C, and is suitable for industrial production. And liquid ammonia does not need to be used in the purification process, so that the purification agent is high in safety and is particularly suitable for purification treatment under complex flue gas conditions in the non-electric industry.

The invention discloses a sulfide-oxide composite solid electrolyte based on Lewis acid-base reaction, a preparation method of the sulfide-oxide composite solid electrolyte and a battery, and relates to the technical field of solid-state batteries. Comprising a sulfide electrolyte and a composite coating coated on the surface of the sulfide electrolyte, and the composite coating comprises an oxide electrolyte and a Lewis alkaline substance. The oxide electrolyte and the Lewis alkaline substance are adopted as the composite coating material, so that the sulfide electrolyte can be isolated from air, the air stability of the sulfide electrolyte is effectively improved, and the phenomenon that the sulfide electrolyte is subjected to oxidation-reduction decomposition in the charge-discharge process is reduced; and by-products generated in the use process of the sulfide electrolyte can be neutralized in situ by the Lewis alkaline substance, so that the great increase of interface impedance is reduced, the cycle performance and high-current stability of the battery are remarkably improved, and the problem that the interface impedance is increased in the charge-discharge process of the traditional sulfide solid electrolyte is solved.

The invention relates to the technical field of manganese zinc ferrite materials, and particularly discloses a manganese zinc ferrite high-frequency high-impedance material and a preparation process thereof. The manganese zinc ferrite high-frequency high-impedance material is prepared from the following raw materials: Fe2O3, Mn3O4, ZnO, a carbon nanotube loaded rare earth oxide composite material, P2O5, Co2O3 and CaCO3. The preparation raw materials of the carbon nanotube loaded rare earth oxide composite material comprise a multi-walled carbon nanotube and a rare earth salt, and the mass ratio of the multi-walled carbon nanotube to the rare earth salt is 1: (0.12-0.14). According to the invention, the loss capability of the manganese zinc ferrite material to electromagnetic interference is enhanced, and the problem that the magnetic conductivity and impedance of the material are reduced in a high-frequency environment is solved.

The invention relates to the technical field of metal surface coating preparation, in particular to a high-temperature thermal cycle impact resistant yttrium oxide composite coating on the surface of refractory metal and a preparation method of the yttrium oxide composite coating. The refractory metal composite coating material is composed of a refractory metal matrix and a coating. The coating comprises a bonding layer, a middle layer and a surface layer which are arranged in a contact manner; the bonding layer is composed of the refractory metal and yttrium oxide, and the porosity of the bonding layer is 1%-5%; the middle layer is a pure yttrium oxide layer with the porosity of 5%-10%; the porosity of the surface layer is 1t; 2% of a pure yttrium oxide layer; the melting point of the refractory metal is 2470 DEG C or higher. According to the refractory metal composite coating material and the preparation method and application thereof, the refractory metal coating structure is optimized, the porosity of the coating is further adjusted, the high-temperature molten metal corrosion resistance and the high-temperature thermal shock resistance of the coating are improved, meanwhile, the bonding strength between the coatings is guaranteed, and the service life of the coating is prolonged. The method is expected to be applied to high-melting-point metal smelting equipment.

The invention discloses a preparation method of a manganese-doped iron-based sulfide / nitrogen-doped reduced graphene oxide composite electrode material for a sodium-ion battery, a simple solvothermal method is combined with annealing treatment, and iron atoms in a hexagonal system are replaced by part of manganese atoms in a hydrothermal process to form multivalent iron-based sulfide, so that the composite electrode material is prepared. The manganese-doped iron-based sulfide / nitrogen-doped reduced graphene oxide composite electrode material for the sodium-ion battery is successfully prepared by uniformly compounding the manganese-doped iron-based sulfide and the nitrogen-doped reduced graphene oxide, and the manganese-doped iron-based sulfide / nitrogen-doped reduced graphene oxide composite electrode material can effectively regulate and control the electronic state density, reduce the sodium ion migration energy barrier and promote the electron / ion transmission; meanwhile, continuous growth of iron-based sulfide particles is limited, so that the iron-based sulfide particles are uniformly dispersed on the surface of the graphene, more active sites are exposed, the electrochemical reaction activity is improved, and the structural stability is enhanced. The composite electrode material disclosed by the invention can be widely applied to a negative plate for a sodium-ion battery, and has excellent adaptability and application prospect in a wide temperature range and under a high-current working condition.

The invention provides a bacteriostatic proppant technology based on a palladium oxide-reduced graphene oxide composite material, aiming at the problem of hydrogen loss caused by microbial activity in a hydrogen storage bank of an exhausted gas reservoir. A PdO (at) rGO composite material functionally modified by lead ions (Pb < 2 + >) is loaded on the surface of a porous ceramsite carrier to form an adsorption-inactivation-blocking synergistic antibacterial network; precise laying of the proppant in a crack network is achieved through the end sand removal technology, hydrogen consumption is reduced, and an efficient, economical and environment-compatible innovative solution is provided for biological pollution control of the underground hydrogen storage library.

The invention provides a modified high-temperature-resistant heat-insulating anticorrosive coating and a preparation method thereof. The modified high-temperature-resistant heat-insulating anticorrosive paint comprises a component A and a component B, the component A comprises organic silicon resin, epoxy resin, a polyaniline-nano metal oxide-graphene oxide composite material, hollow glass beads and hexagonal boron nitride; the component B comprises an organic silicon modified amine curing agent, an anhydride curing agent, a titanate catalyst and an accelerant. The modified high-temperature-resistant heat-insulating anticorrosive paint has excellent corrosion resistance, high-temperature-resistant heat-insulating performance and high-temperature cracking resistance, and also has the advantages of strong adhesive force and short surface drying time. The modified high-temperature-resistant heat-insulating anticorrosive paint provided by the invention is suitable for corrosion protection of metal components exposed in high-temperature and complex corrosive environments for a long time.

The invention discloses organic silicon modified acrylic resin antifouling paint and a preparation method thereof, and particularly relates to the field of chemical paint. The antifouling paint is prepared from the following components in parts by mass: 8 to 12 parts of adamantane acrylate, 5 to 8 parts of trifluoroethyl acrylate, 2 to 3 parts of 2-hydroxyethyl acrylic phosphate, 0.8 to 1.2 parts of tert-butyl peroxypivalate, 4 to 6 parts of tridecafluorooctyltrimethoxysilane, 1 to 2 parts of isophorone diisocyanate, 3 to 6 parts of fluorosilane modified nano TiO2 and 1 to 2 parts of graphene oxide. 20-30 parts of deionized water, 0.5-1 part of a polyether modified polysiloxane defoaming agent, and 0.3-0.5 part of an ultraviolet light absorber UV-327 can be additionally added. The preparation method comprises the following steps: S1, preparing isocyanate modified fluorine-containing organic silicon; s2, preparing a ternary copolymer prepolymer; s3, preparing a modified resin matrix; s4, preparing a fluorosilane modified nano TiO2 / graphene oxide composite filler dispersion liquid; and S5, mixing the resin matrix and the dispersion liquid, and performing stirring and vacuum desolventizing to obtain a finished product. The coating has the characteristics of super-hydrophobicity, high hardness, strong adhesion, long-acting antifouling property, aging resistance and environmental protection.

The invention relates to a normal-temperature curing high-corrosion-resistance self-lubricating composite coating which is prepared from the following components in parts by weight: 25 to 35 parts of modified epoxy resin, 12 to 22 parts of waterborne polyurethane-acrylate copolymer, 6 to 14 parts of lubricating filler, 4 to 9 parts of corrosion-resistant filler, 10 to 18 parts of composite curing agent, 1 to 4 parts of dispersing agent, 0.5 to 3.5 parts of flatting agent, 0.8 to 2.5 parts of defoaming agent and 35 to 55 parts of auxiliary solvent. According to the coating disclosed by the invention, an interpenetrating network matrix is constructed through modified epoxy resin and a waterborne polyurethane-acrylate copolymer, and is matched with components such as a nano molybdenum disulfide / graphene composite lubricating filler and a nano titanium dioxide-zinc oxide composite corrosion-resistant filler, and a photoinitiator-amine composite curing agent is combined, so that dual curing is realized. The coating has excellent properties of rapid curing at normal temperature, high corrosion resistance, self-lubrication and the like, is low in VOC content and wide in application range, and provides an innovative solution for the field of surface protection.

The invention relates to the technical field of memristors, and provides a chitosan-based memristor which comprises a substrate, a buffer layer, a composite dielectric layer and a top electrode which are sequentially stacked from bottom to top, the buffer layer is formed by spin-coating a PEDOT: PSS aqueous solution on the substrate and then carrying out heat treatment; the composite dielectric layer is formed by spin-coating the buffer layer with an ultrasonic composite solution formed by a graphene oxide aqueous dispersion and a chitosan acetic acid solution and then carrying out heat treatment. By adopting a collaborative architecture of the chitosan-graphene oxide composite dielectric layer and the PEDOT: PSS buffer layer, the prepared bio-based memristor has the effects of relatively high switching ratio, relatively low operating voltage and good performance stability. Meanwhile, based on stable high and low resistance states of the device, all seven basic logic operations including a NOT gate, an AND gate, an OR gate, a NAND gate, a NOR gate, an XOR gate and an XNOR gate are completely realized on a single bio-based platform, the function accuracy can reach 100%, and an unexpected effect is achieved.

The invention discloses a manganese-doped Ir-Ta oxide composite coating titanium anode and a preparation method thereof. The titanium anode comprises an insoluble titanium base material, an oxide middle layer and an oxide catalyst layer which are sequentially arranged, wherein the oxide catalyst layer is composed of an iridium (Ir) oxide, a tantalum (Ta) oxide and a doped manganese (Mn) element. The preparation method comprises the following steps: carrying out sand blasting and surface treatment on a titanium substrate to increase the roughness and binding force of the surface, then carrying out proper intermediate layer coating on the surface of the substrate, and finally preparing the manganese-doped Ir-Ta oxide composite coating on the surface of the intermediate layer. Compared with a traditional titanium anode, the prepared manganese-doped Ir-Ta oxide composite coating titanium anode has the advantages of being higher in reaction specific surface area, lower in oxygen evolution potential, longer in catalytic life and the like, and meanwhile the transition metal element manganese is higher in reserve, lower in price and high in oxygen evolution activity.

The invention relates to a modified nano molecular sieve / graphene oxide composite membrane for lithium-magnesium separation and a preparation method thereof, and the preparation method comprises the following steps: (1) stirring a nano molecular sieve and an amino modified solution at a certain temperature to react for a certain time, and centrifugally collecting an aminated nano molecular sieve, the preparation method comprises the following steps: ultrasonically mixing an aminated nano molecular sieve and graphene oxide in an aqueous solution, and then carrying out vacuum filtration on the surface of a porous base membrane to obtain the functionalized nano molecular sieve / graphene oxide composite membrane. The preparation method has the beneficial effect that the introduction of the nano molecular sieve into the graphene oxide membrane optimizes an interlayer channel. The aminated nano molecular sieve enhances the positively charged property of the composite membrane and enhances the selectivity of lithium and magnesium ions. The prepared modified nano molecular sieve / graphene oxide composite membrane is simple in preparation method and high in controllability, the pore channel effect and the charge repulsion effect of the composite membrane are enhanced through introduction of the aminated nano molecular sieve, and the modified nano molecular sieve / graphene oxide composite membrane has wide application prospects in lithium and magnesium ion separation.

The invention discloses a preparation method of a lanthanum ferrite / zinc oxide composite material, which comprises the following steps: preparing lanthanum ferrite LFO, ultrasonically stirring ferric nitrate nonahydrate, lanthanum nitrate hexahydrate and a dispersing agent in a hydrothermal solvent to obtain a mixed solution, preparing an LFO / ZnO composite material, dispersing the LFO prepared in the step S1 and zinc acetate in ethanol, performing ultrasonic treatment, heating and stirring, and condensing and refluxing to obtain the LFO / ZnO composite material. Cooling, and continuously stirring in an ice-water bath; dropwise adding a NaOH ethanol solution at the temperature of 0 DEG C, and stirring for 2 hours; adding deionized water, stirring, centrifuging to remove the supernatant, dispersing the precipitate powder in ethanol, and carrying out hydrothermal reaction; after the hydrothermal reaction is finished, centrifuging the solution, and after centrifugation is finished, pouring out the solution to obtain a precipitate; washing with deionized water and an ethanol solution, drying the precipitate, and calcining the dried powder in a muffle furnace to obtain a p-n type LFO / ZnO composite material; according to the method, the size of lanthanum ferrite can be accurately regulated and controlled through a cooperative regulation strategy of the solvent proportion and the ligand size, and different types of gases can be accurately distinguished.

The invention discloses a high-temperature-resistant steel pipe anticorrosive coating and a preparation method thereof, and relates to the technical field of coatings. The high-temperature-resistant steel pipe anticorrosive paint is prepared from reinforcement modified silica sol, titanium dioxide, mica powder, a BYK-323 flatting agent and an FLOWLENAC-300 defoaming agent. A silicon carbide and carbon shell / reduced graphene oxide composite powder filler is used as a reinforcing body and is embedded into silica sol under the crosslinking effect, reinforcing body modified silica sol is formed, a highly-crosslinked and compact organic-inorganic hybrid composite network structure is presented, and then the reinforcing body modified silica sol is used as a continuous matrix of the coating to play a core role; the high temperature resistance and corrosion resistance of the coating are improved, the interface bonding force among the components can be enhanced, agglomeration and sedimentation of the filler in the storage and curing process are effectively prevented, the micropore defect is reduced, and the effectiveness and durability of protection of the high-temperature-resistant and corrosion-resistant coating are further enhanced.

The invention discloses a carbon-coated high-entropy oxide composite material and a preparation method and application thereof.The preparation method comprises the steps that 1, soluble salt of Al, soluble salt of Mn, soluble salt of Co, soluble salt of Ni and soluble salt of Zn are mixed and dissolved in water, and a metal salt mixed solution is prepared; 2) adding glycine into the metal salt mixed solution, and carrying out a water bath reaction; (3) drying the reaction liquid to obtain a gel-like product, continuously putting the gel-like product into the muffle furnace for combustion reaction, and cooling to obtain high-entropy oxide powder; 4) mixing glucose with the high-entropy oxide powder, grinding, and adding a grinding aid during grinding to obtain composite powder; 5, the composite powder is subjected to vacuum drying, sintered in a tubular furnace under the inert atmosphere and naturally cooled to the room temperature. Glucose is adopted as a single carbon source to replace an existing multi-carbon-source complex regulation and control system, the raw material purchasing cost is remarkably reduced, the process control difficulty of multi-carbon-source matching optimization is reduced, and the production stability is improved.

The invention provides a moisture-proof corrugated board and a production process thereof. The moisture-proof corrugated board comprises inner paper, core paper and surface paper which are sequentially arranged, and the surfaces of the inner paper and the core paper are coated with moisture-proof coatings; the invention relates to a preparation method of an anti-aging agent. The moisture-proof coating is prepared from the following raw materials: 35 to 45 parts of waterborne acrylic resin, 10 to 16 parts of fluorine modified shape memory polyurethane, 8 to 12 parts of waterborne polyurethane dispersion, 4 to 8 parts of bamboo charcoal loaded nano silver-zinc oxide composite particles, 3 to 6 parts of hydrophobic nano silicon dioxide, 5 to 9 parts of chitosan modified nano cellulose, 1.5 to 2.5 parts of silane coupling agent, 0.8 to 1.2 parts of dispersing agent, 0.2 to 0.4 part of defoaming agent and 0.5 to 0.9 part of wetting leveling agent. The corrugated board provided by the invention has excellent moisture resistance, mildew resistance and structural stability.

The invention discloses a pH / temperature dual-response type quaternary ammonium salt-nano silver-zinc oxide composite antibacterial coating material as well as a preparation method and application thereof, and belongs to the technical field of antibacterial materials. The antibacterial effective life of the coated product is at least up to 5 years. The coating product is preferably a gastrointestinal endoscope, efficient bacteriostasis is achieved under the condition that the light transmittance of the gastrointestinal endoscope is not affected, biocompatibility is good, safety is high, precise controlled release of silver ions is achieved, and biotoxicity caused by sudden release of the silver ions is avoided. The quaternary ammonium salt-nano silver-zinc oxide composite coating material with the pH / temperature dual-response antibacterial effect is finally obtained through the steps of preparing a composite carrier material, loading antibacterial metal elements, constructing a pH / temperature dual-response polymer network and the like in sequence. A high-performance, safe and environment-friendly antibacterial coating system which is rapid in sterilization, precise in controlled release and long-acting in interference resistance is constructed, and an antibacterial solution with high technical adaptability is provided for the fields of medical treatment, food, water treatment and the like.

The invention discloses a preparation method and application of a nano heat-insulating metal oxide composite coating. The preparation method comprises the following steps: preparing a nano ATO crystal of which the surface contains silicon hydroxyl; preparing polymerizable ATO (antimony tin oxide) nano particles; and uniformly mixing the polymerizable ATO nano particles, the silane modified nano silicon dioxide, the self-emulsifying polyurethane emulsion and the auxiliary agent to obtain the required coating. Nanometer ATO crystallization and surface silicon hydroxyl modification are synchronously completed in a hydrothermal environment, and the problem of uneven coating caused by traditional two-step modification is solved; after the high-temperature reaction, cold ethanol is used for realizing shock cooling to stop crystal growth, so that the problem of thermodynamic instability of the nanocrystalline is solved; the interfacial compatibility is improved by introducing a vinyl-containing siloxane monomer; by compounding the polymerizable ATO nano particles, the silane modified nano silicon dioxide, the self-emulsifying polyurethane emulsion and the auxiliaries, a stable topological structure connected by covalent bonds is constructed, and the aging resistance, the heat insulation property and the adhesive force of the coating are remarkably improved.

The invention discloses a denitration purification method for flue gas containing oxynitride, belongs to the technical field of waste gas purification, and aims to solve the technical problem that the denitration performance of the flue gas containing oxynitride and the cycle performance of an absorbing material need to be further improved in the prior art. Introducing the modified ionic liquid into a regeneration tank for regeneration, and then supplementing the modified ionic liquid to the absorption tower for continuous use; according to the invention, efficient catalytic oxidation of NO is realized by constructing a graphene oxide loaded metal oxide composite catalyst, and meanwhile, a functionalized modified ionic liquid is introduced as an absorbent to enhance selective absorption and cyclic regeneration capacity of NO2, and the catalytic oxidation and absorption processes are highly coupled in the process, so that the catalytic oxidation and absorption efficiency is improved. A'catalysis-absorption 'integrated denitration system is formed, and the flue gas denitration performance and the cycle performance of the absorption material are improved.

The invention discloses a flue gas wet desulphurization composite nano synergist and a preparation method thereof, the flue gas wet desulphurization composite nano synergist comprises the following components by mass: 60-70 parts of organic acid, 10-20 parts of a nano metal oxide compound, 5-10 parts of a surfactant, 3-8 parts of a pH value regulator, and 3-8 parts of a dispersant; the organic acid is a mixture of adipic acid and glutaric acid; the nano metal oxide compound is a mixture of nano titanium dioxide, nano zinc oxide and nano copper oxide, and the mass ratio of the nano titanium dioxide to the nano zinc oxide to the nano copper oxide is (2-5): (1-4): 1. The problems that in an existing desulfurization process, the desulfurization efficiency is low, the limestone utilization rate is not high, equipment is prone to scaling and corrosion, and desulfurization by-products are poor in quality are solved. The desulfurization synergist can significantly improve the desulfurization efficiency, reduce the operation cost, reduce the damage to equipment, and improve the overall performance and stability of a desulfurization system.

The application provides a ceria / yttria composite stabilized zirconia grinding medium and a preparation method. The method comprises the following steps: step one, mixing zirconia, ceria, yttria and kaolin, and then adding an appropriate amount of dispersant and water to obtain a slurry; step two, performing centrifugal spray drying on the slurry to obtain ceria / yttria composite stabilized zirconia powder; step three, adding the ceria / yttria composite stabilized zirconia powder into a binder, and then rolling to form a green body of spherical grinding medium; and step four, sintering and polishing the green body of spherical grinding medium to obtain the ceria / yttria composite stabilized zirconia grinding medium. The method can obtain low particle size and high specific surface area through high-temperature ball milling, and can also promote the solid solution of the stabilizer into the zirconia crystal lattice through heat treatment, so as to improve sintering activity, reduce sintering temperature and reduce production cost.

The invention belongs to the technical field of electronic information components, and discloses a ceramic composite protective layer capable of improving working temperature, and a preparation method and application thereof. Firstly, a silicon nitride film is deposited on the surface of a sensitive layer of a film temperature sensor by adopting a magnetron sputtering technology; and depositing an aluminum oxide protection layer on the surface of the silicon nitride film by adopting an ultrasonic spraying technology to form a protection layer with a silicon nitride / aluminum oxide composite structure. The internal stress of the composite structure protection layer can be reduced, the thermal stability of the composite structure protection layer is improved, meanwhile, the problem of overflow of sensitive layer material elements in the sensor is inhibited, and the high-temperature stability of the film temperature sensor is improved. According to the invention, the working temperature range of the thin film temperature sensor in an ultra-high temperature environment is obviously expanded, so that the thin film temperature sensor can better adapt to a severe environment at a hot port of an aero-engine with a large thrust-weight ratio.