1746 results about "Membrane surface" patented technology

The invention relates to the field of wastewater treatment, and provides an industrial wastewater membrane process intelligent optimization method and system based on multi-dimensional data modeling. The method comprises the following steps: acquiring wastewater quality parameters of a target scene and a production line equipment state in real time through a multi-dimensional sensor network, and constructing a digital twinborn model of a wastewater treatment system in the target scene; the membrane surface pollution type of each node in the wastewater treatment system is identified through a digital twin model, and the inner membrane pollution evolution condition in the future preset duration is predicted; a multi-strategy evolutionary reinforcement learning algorithm is adopted, the wastewater quality parameters, the production line equipment state and the membrane pollution prediction result are combined, multi-target dynamic optimization is conducted on a wastewater treatment system through a multi-agent collaborative decision-making algorithm, an optimization strategy is generated based on the multi-target dynamic optimization result, and membrane process operation parameters and production control parameters are dynamically adjusted. According to the method, real-time intelligent adjustment of membrane process operation can be realized, the stability of membrane process operation is guaranteed, and the treatment efficiency of membrane process operation is improved.

The invention discloses a defoaming agent foam distribution analysis method based on image feature recognition, and particularly relates to the field of industrial foam behavior perception and analysis for recognizing an image object with a random mode as a feature, and the method comprises the following steps: obtaining a foam image sequence in a target area, and collecting the foam image sequence through imaging equipment, the image frames of the foam image sequence have time continuity; and performing disturbance feature extraction operation on the foam image sequence to obtain local disturbance speed information, membrane surface tension change trend information and form boundary fluctuation information of the foam edge within a preset time. According to the method, foam structure disturbance characteristics are extracted from an image time sequence, a structure evolution graph memory bank is constructed, and irregular sudden change image behaviors are identified in combination with a trend matching mechanism, so that dynamic perception and abnormal response of a sudden foam state without prior support are realized, and the problem that a random mode foam state cannot be identified is solved.

The invention relates to the technical field of skin-touch coatings, in particular to a preparation method of a paint film of an excimer UV skin-touch coating which comprises the following components in percentage by mass: 30%-90% of resin, 5%-40% of monomers, 0.01%-10% of a photoinitiator and 0.01%-10% of an auxiliary agent, the prepared paint film is soft and smooth in surface, low in glossiness, good in wear-resistant effect and good in chemical resistance, the uneven structure formed by the difference of curing of the surface layer and the inner layer of the paint and the effect of microcosmic wrinkles caused by shrinkage of the surface layer achieves the effects that the surface glossiness is low, and the glossiness is lower than 10 degrees when the incident angle is tested to be 60 degrees; and the generated wrinkles are very fine and are naturally generated radians, so that the hand feeling is very smooth, the dynamic friction coefficient of the surface is very low, and the wrinkles on the surface of the coating are caused because the surface curing speed and the bottom curing speed are different, the surface shrinkage is large and the inside shrinkage is small.

The invention relates to the technical field of water resource purification, in particular to a control method and equipment of a reverse osmosis water purification system.The control method comprises the steps that firstly, on the fluctuation dimension of the pre-membrane pressure, the adjusting requirement of the frequency of a high-pressure pump is preliminarily determined on the dimension of the pre-membrane pressure according to an obtained pressure fluctuation index; determining a membrane resistance increase factor representing the pollution state of the reverse osmosis membrane on the basis of the transmembrane pressure difference on the dimension of separation function failure of the reverse osmosis membrane; finally, a membrane separation abnormal value is comprehensively represented by combining a pressure fluctuation index and a membrane resistance increase factor, and a purified water recovery rate is introduced to a membrane separation result end, so that the finally obtained frequency reduction demand degree is more accurate, and the control effect of the reverse osmosis water purification system is improved; therefore, the stable, efficient and sustainable operation of the reverse osmosis water purification system can be ensured while the membrane surface pollutant deposition driving force can be effectively reduced and the membrane pollution speed can be slowed down.

The invention discloses a preparation method of a photocatalytic nanofiltration membrane based on IL-GQDs. The method comprises the following steps: pretreating bagasse, and applying the pretreated bagasse and imidazole ionic liquid (IL) to preparation of ionic liquid functionalized graphene quantum dots (IL-GQDs); the IL-GQDs are uniformly distributed on the surface of the base membrane by utilizing a vacuum-assisted low-temperature interfacial polymerization technology to form an ultrathin photocatalytic active layer; and finally, curing and cleaning to obtain the photocatalytic nanofiltration membrane based on the IL-GQDs. According to the prepared IL-GQDs, the membrane surface is endowed with high specific surface area and excellent photocatalytic activity, and meanwhile, an additional water transmission channel can be established under the condition that the pore diameter of the membrane is not changed, so that the problem of trade-off of a traditional membrane is solved. In addition, through combination of low-temperature and vacuum-assisted interfacial polymerization technologies, the membrane structure is more uniform and compact, defects on the surface of the membrane are reduced, and the stability and the anti-pollution capacity of the membrane are improved. The membrane disclosed by the invention shows relatively high water flux, salt recovery rate and long-term stability in water treatment application.

The invention discloses a preparation method of a crown ether functionalized anti-pollution nanofiltration membrane, which comprises the following steps: soaking a membrane of a commercial nanofiltration membrane in pure water, and coating the surface with a double-end epoxy compound ethanol solution; uniformly coating the surface of the membrane with an aza 12-crown-4 methanol solution; and drying the membrane in an atmosphere of 40-90 DEG C to obtain the crown ether functionalized anti-pollution nanofiltration membrane. The nano-filtration membrane is realized by chemically grafting aza 12-crown-4 on the membrane surface of a commercial nano-filtration membrane by utilizing a double-end epoxy compound; compared with a traditional nanofiltration membrane, the crown ether functionalized nanofiltration membrane provided by the invention has the advantages that the electronegativity of the surface is reduced, and the surface is similar to an aquatic plant molecular brush structure, so that the deposition of pollutants on the surface of the membrane can be effectively improved, and the anti-pollution performance of the membrane is enhanced; meanwhile, due to the complexing effect of 12-crown-4 molecules on lithium ions, the lithium ions can be effectively captured, concentration polarization of the lithium ions on the surface of the diaphragm is improved, and then the magnesium-lithium separation efficiency of the diaphragm is improved.

The invention relates to the technical field of water treatment, in particular to a high-recovery-rate short-process salt-tolerant reverse osmosis system and treatment method.The system comprises a pretreatment unit, a sensor monitoring unit, a self-adaptive pressure-flow coupling control unit, an intelligent operation and maintenance unit and a gradient boosting reverse osmosis membrane set. According to the invention, ultrahigh recovery rate and desalination performance are realized, gradient boost membrane module design is combined with concentration polarization inhibition technology, membrane surface flow state distribution is optimized, osmotic pressure influence is significantly reduced, pressure-flow coupling control and concentrated water excess pressure energy recovery technology are integrated, energy dynamic cyclic utilization is realized, energy consumption is reduced, and the method is suitable for industrial production. By monitoring the membrane flux attenuation rate and the transmembrane pressure difference in real time and dynamically optimizing a pulse cleaning strategy, dynamic optimization of high-salinity wastewater treatment is realized, and the problems of low recovery rate, high energy consumption and quick membrane pollution in high-salinity wastewater treatment are solved.

The invention discloses a silicon dioxide reinforced high-hydrophobicity polyvinylidene fluoride membrane as well as a preparation method and application thereof, SiO2 nanoparticles are taken as a mechanical reinforcing agent and a structure regulator and are directly added into a membrane casting solution system, and solid-liquid phase separation is preliminarily induced on the surface of a primary membrane in combination with non-solvent spraying ethanol, so that the high-hydrophobicity PVDF membrane is successfully prepared. A unique multi-stage micro-nano structure consisting of mutually connected spherocrystals is constructed on the surface of the membrane, the hydrophobicity, aperture, porosity and mechanical property of the membrane are effectively improved, and the membrane shows excellent and stable separation performance in performance tests of seawater desalination and erythritol concentration, and has good application prospects in seawater desalination and erythritol concentration. The method shows huge application potential in the fields of wastewater treatment, food production and the like.

The invention discloses a composite isolating membrane based on synergistic modification of a porous material and an ionic conductor material and a preparation method of the composite isolating membrane. The composite isolating membrane comprises a base membrane and a coating which is coated on the surface of the base membrane and comprises a porous material and an ion conductor material. The composite isolating membrane has multiple ion transmission paths including ion diffusion or migration transmission, lattice diffusion transmission and ion seepage transmission, the ion transmission efficiency is synergistically enhanced, and the problem that the ion transmission mechanism is single is solved. In addition, the composite separation membrane has accessory functionality, and migration of transition metal can be inhibited. The composite isolating membrane disclosed by the invention is suitable for a high-capacity-density and high-rate battery system, and meets the requirements of battery development.

The invention discloses a flexible pressure sensor with a multistage hemispherical structure and a preparation method thereof, the sensor comprises an electrode layer, and an upper friction layer, a separation layer and a lower friction layer which are sequentially arranged below the electrode layer from top to bottom, the separation layer is used for providing a space for full contact and separation of the upper friction layer and the lower friction layer, and the separation layer is used for providing a space for full contact and separation of the upper friction layer and the lower friction layer. And the lower friction layer is formed by a multi-stage hemispherical structure constructed on the surface of a flexible film. The sensor has the remarkable effects that benefited from the characteristics of a triboelectric sensing mechanism, the sensor has the advantages of self power supply, stable output and simple structure, and meanwhile, the upper friction layer and the lower friction layer of the sensor are in step-by-step contact under the action of pressure through the surface microstructure of the lower friction layer of the multi-stage hemispherical structure; the compressibility is enhanced, and the contact and separation process of the sensor is optimized, so that the sensitivity of the sensor is improved.

The invention discloses an advanced treatment and recycling method for cold-rolled silicon steel magnesium oxide wastewater, and particularly relates to the technical field of wastewater treatment. Through pH adjustment, coagulation pretreatment, pre-membrane fine filtration and medicament stabilization of wastewater, stable control of inlet water quality is realized; a two-stage reverse osmosis system is combined with a dynamic flow and cross flow structure, so that the risks of concentration polarization and local stress corrosion are remarkably inhibited; by combining real-time monitoring of membrane surface pressure difference and recovery rate and an intelligent algorithm, self-adaptive optimization regulation and control of operation parameters of the system are realized; according to the method, the problems of serious membrane pollution, poor system stability, low recycling efficiency and the like in the prior art are effectively solved, and the wastewater resource utilization level and the system operation safety are remarkably improved.

The invention relates to a base membrane for a composite current collector based on SiO2 nano composite modification and a preparation method of the base membrane. Synergistic modified nano SiO2 is compounded with aluminum hypophosphite, montmorillonite and the like to form modified auxiliary particles, the modified auxiliary particles and PET master batches are subjected to blending extrusion, and meanwhile, the surface of the base membrane is coated with a modified coating containing nano SiO2, so that the composite current collector is obtained. The mechanical property, the thermal stability and the flame retardance of the base film are obviously improved.

The invention relates to the field of decorative films, in particular to an indented pattern color scraping decorative film and a preparation method thereof.The indented pattern color scraping decorative film comprises a skin feeling functional layer, a pattern developing layer, a supporting strengthening layer and a coloring strengthening layer, the skin feeling functional layer, the pattern developing layer and the supporting strengthening layer are composited into an integrated structure through hot pressing, and micron-sized air guide grooves are formed in the bonding faces of all the layers; the air guide grooves are arranged in parallel along the extending direction of the dimpled grains, the 60-degree glossiness of the surface of the decorative film is less than 3GU, the pencil hardness is greater than 1H, and the texture spacing difference between the outline edge of the dimpled grains and the printed pattern layer is 0.1-0.5 mm, so that the decorative film is endowed with excellent stereoscopic visual effect and physical property. The dimpled grain structure in the skin-touch functional layer is directly formed on the surface of the skin-touch coating, the problem of interlayer dislocation caused by traditional composite embossing is avoided, it is ensured that the dimpled grain outline is clear, the peeling strength between layers is high, bonding is tighter, and no bubble is left on the bonding face between the layers.

The invention relates to the technical field of preparation of medical supplies, in particular to a surgical membrane and a preparation process. During specific use, firstly, a polyurethane base membrane is selected and subjected to plasma treatment; spraying a nano SiO2 dispersion liquid containing a photoinitiator on the surface of the treated polyurethane base film, and then performing ultraviolet patterning irradiation to form a micro-bulge structure to obtain a base material layer; projecting the colloidal fluid to a temperature gradient mask through a digital micromirror device, so that the colloidal fluid is subjected to regional thermal polymerization on the substrate layer to form an intelligent adhesive layer with viscosity gradient; by adopting an aerosol jet printing technology, super absorbent fibers and polyvinyl alcohol-borax dynamic crosslinking hydrogel are co-deposited to form a drainage layer, so that the technical problems that a surgical membrane prepared by a surgical membrane preparation mode in the prior art is inflexible in adhesion and poor in surface structure performance, and a preparation process is difficult to accurately control are solved.

The invention relates to the technical field of water treatment, and provides a reverse osmosis membrane cleaning method, a cleaning agent composition and application. According to the method, whether cleaning is needed or not is determined by comparing initial operation parameters and current operation parameters of a system; the pollutant type is accurately judged by observing the appearance characteristics of the membrane surface and detecting related index parameters; and selecting a corresponding cleaning agent formula according to the pollutant type, and sequentially performing physical washing and chemical cleaning. The cleaning agent composition comprises a biological pollution cleaning agent, an organic pollution cleaning agent and / or an inorganic scaling cleaning agent. By establishing a scientific pollution diagnosis system and a targeted cleaning strategy, the problems of fixed cleaning scheme and low pertinence in the prior art are solved, the pressure difference recovery rate after cleaning can reach 90% or above, the desalination rate recovery rate can reach 99% or above, the cleaning efficiency is remarkably improved, the operation cost is reduced, and the service life of the membrane is prolonged.

The invention discloses a preparation method and device of a composite current collector, and the preparation method of the composite current collector comprises the following steps: carrying out baking treatment on a polymer film raw material to obtain a base film; the preparation method comprises the following steps: adding a pre-plating layer on the surface of a base film through pre-plating treatment, carrying out film plating treatment on one side, far away from the base film, of the pre-plating layer, and plating a metal thickening layer to obtain a base material; winding the base material to obtain a roll material, and after winding of the roll material is completed, slitting the whole roll material through a slitting machine to obtain a sub-roll material; and carrying out surface modification treatment on the split coil material to obtain the composite current collector. According to the preparation method of the composite current collector, a single evaporation process is adopted for film coating, the process is simple, the film coating efficiency is high, the film forming quality is high, the film coating efficiency is improved through one-time film coating on the front face and the back face, meanwhile, the interface bonding force can be improved through pre-coating in an induction type heating mode, and the film forming quality is improved. And the coating efficiency is ensured, and the coating quality is improved.

The invention provides a reverse osmosis membrane cleaning system which is characterized in that a variable-frequency water pump control system is adopted to adjust water flow momentum according to cleaning parameters output by a matching algorithm, differential impact strength control of different areas on the surface of a membrane is realized through a flow adjusting valve group, and a stress distribution mode adaptive to pollution distribution is obtained; mechanical stress data of the membrane surface in the cleaning process are collected in real time through a membrane material stress monitoring sensor, if the stress value exceeds a membrane material safety threshold value, a stress protection mechanism is triggered, and the impact strength of a corresponding area is automatically reduced; establishing an adaptive parameter optimization algorithm according to pressure feedback data and a pollutant stripping effect evaluation result in the cleaning process, and calculating a parameter adjustment scheme of the next cleaning period through a tradeoff function of the cleaning effect and mechanical damage; a membrane performance degradation prediction model is established through accumulation of historical cleaning data, the remaining service life of a membrane material is predicted according to accumulated mechanical stress and cleaning frequency data, and a quantitative judgment basis of the membrane replacement opportunity is obtained.

The invention provides a composite nanofiltration membrane as well as a preparation method and application thereof, and the preparation method comprises the following steps: reacting a water phase solution and an oil phase solution on the surface of a base membrane to obtain a primary composite nanofiltration membrane; wherein the water phase solution contains piperazine and polyacrylamide, and the oil phase solution contains trimesoyl chloride. The nanofiltration membrane provided by the invention is high in pure water flux, good in membrane surface hydrophilicity, strong in pollution resistance, high in mechanical strength and durability, low in cost and capable of stably running for a long time.

The invention relates to the technical field of tempered film production, in particular to an oil coating all-in-one machine for a flat tempered film, which comprises a shell, a transmission mesh belt, a cleaning assembly, a telescopic driving part, a sealing cover and a plugging film, a transmission mesh belt is arranged on the machine shell; a cleaning assembly is arranged on the machine shell. A plurality of telescopic driving pieces are arranged on the machine shell; the telescopic ends of all the telescopic driving pieces are jointly and fixedly connected with a sealing cover. The inner wall of the sealing cover is an inclined surface; a blocking film is arranged at the bottom of the sealing cover. The closed chamber is formed by combining the closed cover, the blocking film and the tempered film, oil mist sprayed out at a high speed is prevented from diffusing all around after making contact with the tempered film and adhering to the surface of other sprayed or unsprayed tempered film, uneven adhesion of the oil mist on the surface of the tempered film is avoided, meanwhile, oil liquid is prevented from adhering to the back face of the tempered film, and the service life of the tempered film is prolonged. The viscosity reduction of the adhesive layer on the back of the tempered film is avoided and the quality of the tempered film is guaranteed.

The invention discloses a self-cleaning composite piezoelectric ceramic membrane as well as a preparation method and application thereof, and belongs to the field of composite ceramic membranes. The technical problem that an existing ceramic membrane separation technology is poor in biomembrane pollution resisting effect is solved. According to the preparation method, the barium titanate ceramic membrane is firstly prepared to serve as the base membrane, then the copper oxide one-dimensional nanostructure is loaded on the piezoelectric ceramic substrate, and the base membrane has a large membrane surface area and can be combined with more catalysts, so that more active sites are provided for catalytic reaction; according to the composite membrane, the hydrophilicity, the anti-pollution performance and the piezoelectric catalysis self-cleaning performance of the membrane are remarkably improved, and pollutants in water can be quickly and effectively separated, so that the flux and the anti-pollution performance of the membrane are improved.

The invention discloses a reverse osmosis membrane concentration polarization layer thickness prediction method and device based on electrical impedance tomography, and relates to the technical field of membrane process nondestructive monitoring, and the method comprises the following steps: constructing a simulation model based on an electrode array membrane filtration sensor; virtual media with different conductivities are arranged on the surface of the membrane, a simulation conductivity image is reconstructed through a conjugate gradient least square algorithm and a sensitivity matrix, and a neural network is improved through known conductivity training; and reconstructing an actually measured conductivity image by an actually measured boundary voltage data set, predicting a membrane surface conductivity estimated value by using the trained improved neural network, and performing concentration polarization layer thickness mapping. A conductivity image with a conductivity label is generated through numerical simulation, so that the problem that the thickness of the concentration polarization layer is difficult to calibrate is solved, then a neural network is improved through training so that the truth value of the conductivity can be predicted according to the conductivity image, and interpretable mapping of the thickness of the concentration polarization layer is carried out in combination with a membrane mass transfer theory. The thickness of the concentration polarization layer can be subjected to online lossless quantitative detection.

The invention relates to the technical field of mine water treatment, in particular to a mine water filtering device.According to the mine water filtering device, an ultrafiltration membrane assembly is arranged in a membrane pool to filter mine water, a pressure detector is arranged at a liquid outlet to monitor the water pressure in real time, and the pressure detector transmits real-time data to a controller; the controller is used for judging whether the water pressure entering the clean water tank meets the water production requirement or not, and automatically controlling the starting and stopping of each electrical device according to the judgment result, so that the spraying pump and the moving assembly are started in time when the membrane pollution problem occurs, and the clean water in the clean water tank is pumped to the spray head through the water production pipeline to clean the ultrafiltration membrane assembly; and different positions of the ultrafiltration membrane assembly are cleaned by moving the spray head through the moving assembly, so that pollutants on the surface of the ultrafiltration membrane can be quickly and thoroughly removed, and the water production efficiency is ensured. And moreover, the device does not need to add a coagulant to carry out flocculation and sedimentation treatment on the mine water, so that potential risks of drug residues on subsequent recycled water quality are avoided.

The invention belongs to the technical field of water electrolysis hydrogen production, and relates to a modification method of an alkali-resistant super-hydrophobic PTFE hollow fiber membrane and a membrane component, the method adopts the main process of alkali treatment hydroxylation, fluorosilane coating growth and heating curing, and a hydrophobic layer is grown on the surfaces of the PTFE hollow fiber membrane and the component thereof, so that super-hydrophobic modification is realized. A perfluorosilane hydrophobic layer and a rich long-chain CF2 structure are uniformly and densely distributed on the surface of the modified membrane, so that the surface energy of the PTFE membrane is remarkably reduced, and meanwhile, the surface roughness is improved, so that the hydrophobicity is improved; due to the anti-infiltration performance of the coating, seawater and a concentrated alkali solution are not easy to attach to the surface of the membrane, so that the service life of the membrane component in the application of supplying water to the concentrated alkali solution from the seawater is remarkably prolonged; the coating uniformly grows on a separation layer of the PTFE hollow fiber membrane, and meanwhile, membrane holes are fully reserved, so that the flux of water vapor is maintained.

The invention discloses a preparation method and application of a photo-thermal biosensor for tumor cell quantification and vitality dual-index liquid biopsy. Phosphatidylserine (PS) is exposed by enriching and cracking tumor cells, is identified and combined by an aptamer Apt2, and is driven to be separated from Apt2-Cu2-xTe NSs; after magnetic separation, separated supernatant is subjected to photo-thermal detection; the photo-thermal signal intensity is positively correlated with the number of cells, so that quantitative detection is realized; during cell apoptosis, PS is turned out of the membrane, Apt2-Cu2-xTe NSs is combined with the surface of the membrane, separated supernatant is subjected to photo-thermal detection after magnetic separation, and the photo-thermal signal enhancement amplitude is in negative correlation with cell activity. The platform has the advantages of POCT characteristics, low cost and portability, and a new tool is provided for precise tumor diagnosis and treatment.

The invention discloses a full-automatic vehicle film laminating machine and a hot-pressing compounding process thereof, and aims to improve the production efficiency of a vehicle film and the adhesive force of a film layer. The laminating machine comprises an electrostatic spraying chamber and a hot pressing chamber, and efficient compounding of membrane materials is achieved through the synergistic effect of the electrostatic spraying chamber and the hot pressing chamber; a film material is automatically fed into a laminating machine through an upper-layer film leading-in roller and a base material film leading-in roller, after the film material enters an electrostatic spraying chamber, the surface of the film material is subjected to corona treatment, and a nano coating solution is uniformly sprayed on the surface of an upper-layer film through an atomizer; meanwhile, redundant charged particles on the surface of the substrate film are collected through an electrostatic collection plate; the sprayed membrane material enters a hot-pressing chamber, and is heated and pressurized under the action of a hot-pressing roller, so that the two layers of membranes are tightly combined, and the high bonding strength between the membrane layers is ensured; and finally, the finished product film material is wound through a finished product storage roller, and a high-quality vehicle film product is formed.

The invention provides a metal ion cross-linked nano cellulose composite film as well as a preparation method and application thereof, and belongs to the technical field of cellulose film preparation. The preparation method of the metal ion cross-linked nanocellulose composite film comprises the following steps: mixing nanocellulose dispersion liquid and nanosheet dispersion liquid to obtain mixed dispersion liquid; applying a metal ion aqueous solution to the filter membrane with the lyophilic surface to form a liquid membrane on the lyophilic surface; pouring the mixed dispersion liquid on the surface of the liquid film and standing for a period of time, super-spreading the nanosheets on the surface of the liquid film and performing oriented arrangement, and then performing cross-linking curing on the metal ions, the nanocellulose and the nanosheets to obtain a composite film; and drying the composite film to obtain the metal ion cross-linked nano cellulose composite film.

The invention discloses a high-flux anti-pollution nanofiber membrane modified by a nanoparticle reinforced coating and a preparation method of the high-flux anti-pollution nanofiber membrane. The nanofiber membrane is prepared by doping hydrophilic nanoparticles into a spinning solution and coupling an electrostatic spinning process with a functional coating for modification. The hydrophilic nano-particles are selected from hydrophilic modified inorganic nano-particles, organic nano-particles, carbon-based nano-materials or metal organic framework materials. Nanoparticles, a membrane base material and a solvent are blended to form a uniform spinning solution, and functional coating deposition is performed after electrostatic spinning forming. The method is simple and efficient in preparation process, and the obtained nanofiber membrane has excellent hydrophilicity and anti-pollution performance. The introduction of the nanoparticles not only realizes hydrophilic modification of the membrane surface, but also significantly enhances the bonding strength of the coating and the matrix, so that the membrane material has excellent selective separation performance on oil substances (the rejection rate is greater than or equal to 99%) and macromolecular impurities while maintaining high flux (pure water flux is 3000-4000 L.m <-2 >. H <-1 >), and the transmittance on protein can reach 99%. The membrane material also has outstanding flux recovery rate (greater than or equal to 90%) and long-term operation stability, and has wide application prospects in the fields of sewage treatment, food processing and the like.

The invention relates to the field of sewage treatment, in particular to an urban sewage treatment system based on the Internet of Things. Comprising a grating tank, a desilting tank, an anoxic tank, an anaerobic tank, an aerobic tank, a sludge concentration tank and a disinfection tank which are sequentially connected, a membrane filtration unit and an aeration unit are arranged in the aerobic tank, the membrane filtration unit comprises a plurality of membrane assemblies which are distributed at equal intervals in the length direction of the aerobic tank, and each membrane assembly is provided with a flow sensor. A membrane treatment mechanism corresponding to each membrane component is arranged in the aerobic tank, each membrane treatment mechanism comprises a rotating frame and a sliding frame, and when the sliding frames slide along the sliding chutes from top to bottom, membrane surfaces with different heights are sequentially close to the aeration units to form a gradient flushing mode. The membrane flux condition of the membrane module is known through monitoring of the Internet of Things, the membrane treatment mechanism can be started in time, the membrane module slides down obliquely along with the sliding frame, the membrane surface is scoured section by section in combination with aeration, flux stability is effectively maintained, and stable operation of the sewage treatment system is ensured.

The invention discloses a preparation and application method of a modified ion exchange membrane for electrodialysis, aiming at the problems of poor selectivity, low mechanical strength, high energy consumption and the like of the existing ion exchange membrane, the high-performance modified membrane is prepared by a base membrane pretreatment-functional grafting-gradient curing synergistic process. The preparation method specifically comprises the following steps: performing ultrasonic cleaning and acid-base activation on a polyethersulfone or sulfonated polystyrene-based membrane, soaking the polyethersulfone or sulfonated polystyrene-based membrane in a modification solution containing an amino / carboxyl / sulfo functional monomer, a cross-linking agent and an initiator, and performing gradient heating curing to form a stable cross-linked network; the grafting rate of the modified membrane is 15-35%, the ion exchange capacity is 1.8-2.5 mmol / g, the water content is 25-40%, and the membrane surface resistance is less than 3 omega.cm < 2 >. When the membrane is applied to an electrodialysis device, the membrane runs under the conditions of 10-30V direct-current voltage, 5-15cm / s flow velocity and 25-45 DEG C, the high-salinity wastewater desalination rate is greater than or equal to 95%, and the monovalent ion selectivity coefficient reaches 5.8-7.2; when the catalyst is used for acid-base recovery, the H < + > migration number is 0.92-0.96, and the energy consumption is reduced by 18-25%.

The invention discloses a modified microfiltration membrane for enriching biological particles and a preparation method and application thereof, and belongs to the technical field of biological separation.The preparation method of the modified microfiltration membrane comprises the following steps that a mixed cellulose ester microfiltration membrane is provided and subjected to alkali liquor activating treatment; placing the activated membrane in a weakly alkaline buffer solution for balancing; the preparation method comprises the following steps: in a weakly alkaline buffer solution, firstly contacting the surface of the membrane with a tannic acid solution to carry out a first reaction, and then directly adding a polyethyleneimine solution to carry out a second reaction under the condition of not replacing a system, so as to form a phenol-amine cross-linked network on the surface of the membrane in situ; sodium cyanoborohydride is continuously added for reduction stabilization treatment, and the modified microporous filter membrane is obtained. The modified microporous filter membrane prepared by modifying the microporous filter membrane with tannic acid and polyethyleneimine can realize one-step synchronous enrichment of all negatively charged targets, and the problems of target loss, efficiency loss and the like caused by a multi-step process are avoided from the source.