1453 results about "Hydroxyl radical" patented technology

The invention discloses a system and a method for degrading organic wastewater through cooperation of hydrodynamic cavitation and plasma. The system comprises a liquid storage tank, an aeration device and a plasma rotary cavitation reactor, the plasma rotary cavitation reactor comprises a reactor shell, and the reactor shell is provided with an organic wastewater inlet and an organic wastewater outlet; the aeration device is communicated with the organic wastewater inlet; and the liquid storage tank is communicated with the aeration device. The plasma discharge technology and the hydrodynamic cavitation technology are fused, active substances such as ozone and hydroxyl radicals are generated through dielectric barrier plasma discharge, degradation of organic wastewater is enhanced in cooperation with the hydrodynamic cavitation technology, and the degradation effect of the wastewater is improved; an upper row of teeth and a lower row of teeth with opposite tooth inclination angles are arranged on the rotor, so that fluid is triggered to circularly flow between a cavitation area and a discharge area, and the gas-liquid mass transfer efficiency is further improved; by arranging the upper jet flow cavitation channel and the lower jet flow cavitation channel which are variable in inner diameter and opposite in direction, the pressure drop value when fluid flows through the channels is changed, and the cavitation effect is enhanced.

The invention discloses a porphyrin copper ion covalent organic framework material with excellent biocompatibility, and belongs to the technical field of biological medicines. The porphyrin copper ion covalent organic framework material is obtained by carrying out solvothermal reaction copolymerization on a porphyrin compound and a novel copper Schiff base boric acid complex in a protective atmosphere; the porphyrin compound is 5, 10, 15, 20-tetra (3, 4-dihydroxyphenyl) porphyrin, and the structural formula of the porphyrin compound is shown in the specification. The structural formula of the novel copper Schiff base boric acid complex is # imgabs0 #. According to the invention, a novel copper Schiff base complex and 5, 10, 15, 20-tetra (3, 4-dihydroxyphenyl) porphyrin are copolymerized to obtain Cu-COF with negligible biotoxicity, and the material realizes the synergistic effect of three antibacterial modes of PDT, PTT and hydroxyl free radicals. The prepared Cu-COF can also be slowly degraded in an acid environment, the infected microenvironment is improved in the degradation process, and the antibacterial effect is improved.

The invention discloses a nano system for tumor radioimmunotherapy and a preparation method and application thereof, and belongs to the technical field of biological medicines.The system modifies bacteria outer membrane vesicles (OMVs) through engineering to enable the bacteria outer membrane vesicles to carry magnetite nanoparticles (Fe3O4NPs) and an ATR inhibitor VE822, the Fenton reaction activity of the Fe3O4NPs and the synergistic effect of the ATR inhibitor for inhibiting DNA damage repair are utilized, and the tumor radioimmunotherapy effect is improved. DNA damage is amplified, DNA damage reaction (DDR) is inhibited, generation of hydroxyl radicals (. OH) under radiation is enhanced, radiation resistance of tumor cells is reduced, immune reaction is reactivated, infiltration of effector T cells to tumors is improved, growth of mice tumors is remarkably inhibited, and an effective strategy is provided for tumor radioimmunotherapy.

The invention discloses equipment and method for preparing double-electrolyzed water based on O3 and H2O2 in parallel, and relates to the technical field of disinfectant fluid preparation, the equipment comprises a lower shell and an upper shell, a self-priming pump, an ozone generation device, a hydrogen peroxide generation device and an ultraviolet device are installed in the lower shell, and the ozone generation device and the hydrogen peroxide generation device are arranged in parallel; a water inlet of the self-priming pump is connected with a first quick connector extending out of the side wall of the lower shell, and an outlet end of the ultraviolet device is connected with a second quick connector extending out of the side wall of the lower shell. The ozone generation device and the hydrogen peroxide generation device are connected in parallel, an aqueous solution containing ozone and hydrogen peroxide at the same time is obtained by controlling the proportion of ozone and hydrogen peroxide, photolysis of ozone and hydrogen peroxide is promoted by utilizing the synergistic effect of ozone and hydrogen peroxide and introducing an ultraviolet light source, and therefore more hydroxyl radicals are generated; and compared with an ozone solution, the sterilization effect of the disinfectant fluid is better.

The invention provides lepidolite flotation wastewater treatment equipment and a flotation process, and relates to the technical field of wastewater treatment, the lepidolite flotation wastewater treatment equipment comprises a reaction tank, a stirring mechanism, a swing dosing mechanism and a spraying mechanism; the stirring mechanism comprises a mounting frame fixedly arranged at the top of the reaction tank, and a rotating shaft is vertically and rotatably connected to the inner side of the mounting frame. According to the scheme, a ferrous sulfate solution is finally added into the reaction tank through the spraying mechanism, then a diluted H2O2 solution is intermittently fed through the swing medicine feeding mechanism, the H2O2 solution generates strong oxidizing hydroxyl free radicals under the catalysis of the ferrous sulfate solution, and therefore hydrophobic chains and polar groups of residual medicine are destroyed, and the medicine is obtained. The lepidolite metallurgical flotation wastewater is degraded into small molecular organic matters or mineralized into CO2 and H2O, so that the phenomenon that the subsequent coagulating sedimentation or adsorption process is hindered by residual chemicals is avoided, the chemical oxygen demand and toxicity of the wastewater are reduced, the subsequent biological treatment on the wastewater is facilitated, and the treatment effect and efficiency of the lepidolite metallurgical flotation wastewater are effectively improved.

The invention discloses an aerobic granular sludge culture method based on a micro-nano aeration technology, and belongs to the technical field of water treatment. According to the invention, micro-nano aeration is used, so that the oxygen transfer rate in the aerobic granular sludge reactor is 2.1 times of that of a conventional aeration group, the generated hydroxyl radicals are 2.6 times of that of the conventional aeration group, the final removal efficiencies of ammonia nitrogen, total nitrogen and COD (Chemical Oxygen Demand) can respectively reach 98%, 85% and 97%, the denitrification performance is excellent, the treatment period is shortened by 1 hour, and the treatment cost is reduced. After the aeration time is shortened, 28% of aeration energy consumption is saved. Micro-nano aeration not only is beneficial to culture and domestication of aerobic granular sludge and promotes removal of pollutants, but also improves the energy utilization efficiency.

The invention discloses a preparation method of magnesium threonate. The preparation method comprises the following steps: S1, preparing a stable glucose-magnesium six-membered ring compound; s2, concentrating the reaction liquid, crystallizing, and drying in vacuum to obtain a glucose-magnesium six-membered ring compound; s3, dissolving the compound in water, and adding Fe < 2 + > to adjust the pH value to 2.5-3.0; s4, the solution obtained in S3 is heated, H2O2 is dropwise added, Fe < 2 + > in the solution catalyzes H2O2 to generate hydroxyl radicals, the glucose-magnesium compound is selectively cracked, and magnesium threonate is generated; s5, adding Na2S2O3 to terminate the reaction, and filtering to remove Fe (OH) 3 precipitate; concentrating the filtrate under reduced pressure until the filtrate is sticky, standing at low temperature, and separating out a magnesium threonate crude product; according to the method, the glucose-magnesium six-membered ring compound is used as a raw material and is converted into magnesium threonate through Fenton reaction oxidative cracking, and the purified magnesium threonate is high in purity, low in Fe residue, mild in process condition and suitable for large-scale production.

The invention provides an electrochemical active oxygen supply device for a washing machine and a preparation method. The device comprises a shell, a single closed reaction chamber is formed in the shell, a bifunctional anode electrode and a bifunctional cathode electrode are integrated in the reaction chamber, and a compact and uniform reaction area is formed between the anode electrode and the cathode electrode. When water flows through the reaction area, hydrogen peroxide (H2O2) and / or hydroxyl radicals (OH) are / is electrochemically generated on the surface in situ by accurately adjusting the electrode potential of the difunctional anode, so that instant generation and instant utilization of active oxygen are realized. The active oxygen directly enters a washing system of the washing machine along with water flow, bacteria, viruses and fungi can be efficiently inactivated under the normal-temperature or low-temperature washing condition without additionally adding chemical disinfectants, organic stains and peculiar smell molecules are synchronously degraded, and green, efficient and intelligent healthy washing is achieved.

The invention discloses an antistatic PPO material based on graphene and a preparation method thereof.The preparation method comprises the steps that aminated polyphenyl ether and modified filler react to prepare modified polyphenyl ether, the modified polyphenyl ether is treated with benzenesulfonyl chloride to prepare the antistatic PPO material, when the aminated polyphenyl ether and the modified filler are used, the modified filler is equivalent to a cross-linking agent, and when the modified filler is used for modifying the aminated polyphenyl ether, the modified filler is equivalent to a cross-linking agent; the modified filler is interspersed among the molecular chain segments, graphene is arranged in the modified filler and has a very good conductive effect, so that the material has an antistatic effect, and the surface of the modified filler contains an organic silicon chain segment, so that the antistatic property of the material is improved; when the material is combusted, a phosphorus-containing organic silicon chain segment on the surface of the modified filler can form a P-O-Si compact carbon layer, a nitrogen element on a side chain can generate amino free radicals, then active hydrogen atoms and hydroxyl free radicals are captured, a combustion chain reaction is interrupted, a sulfur element can release sulfur dioxide gas, the oxygen concentration is further diluted, and the oxygen concentration is reduced. Therefore, the material has a good flame-retardant effect.

The invention belongs to the technical field of free radical detection, and provides an in-situ online detection method for hydroxyl free radicals in a hydrocarbon-water system high-temperature action process. The method comprises the following steps: preparing a capillary reaction kettle, preparing a capillary injector, preparing a test solution, and injecting a sample: sequentially injecting an aqueous solution and a hydrocarbon mixed solution containing a paramagnetic trapping agent into the capillary reaction kettle, so that the hydrocarbon mixed solution is discontinuous in short-column-shaped sections in the aqueous solution, a'hydrocarbon-water-hydrocarbon-water-hydrocarbon-water... 'multi-hydrocarbon-water 'interface is completed; sample detection and image analysis. According to the invention, hydrocarbons and a water solution to be detected are sealed by using a fused quartz capillary tube and a high-pressure valve, and multiple sections of hydrocarbon-water interfaces are sealed in a quartz capillary tube system, so that the oil-water interfaces of the hydrocarbon-water system in the capillary tube are densely arranged near detection points; the distribution density of oil and water droplets near an interface under a high-temperature condition and the generation of a large amount of free radicals are increased, and the signal-to-noise ratio of effective signals is improved.

The present invention relates to magnetic, catalytically active, and radiosensitizing nanoparticles (NanoXcats) and the method for their production. A method is disclosed for the production of functionalized greigite nanoparticles with a narrowband size distribution (10-30 nm) for use in multimodal cancer therapy. NanoXcats are superparamagnetic Fe3S4 nanoparticles whose surfaces are equipped with polar functional groups. The surface structures of NanoXcats are suitable for conjugation with, or for covalent or electrostatic binding of, active substances, which may be cancer drugs, cell growth inhibitors, or NO donors. Due to the EPR effect, NanoXcats are preferentially internalized by tumor cells. The targeted accumulation of NanoXcats in tumor tissue is achieved by an external inhomogeneous magnetic field. NanoXcats exhibit enhanced catalytic activity in tumor cells.The catalytic activity of intracellular NanoXcats can be triggered, controlled, and enhanced by low-dose X-rays. Surface-bound drugs are additionally activated in tumor cells by the catalytic activity of NanoXcats. NanoXcats act as superoxide dismutase, nitric oxide synthase, and Fenton catalyst. They catalyze, for example, reactions of the superoxide anion radical to hydrogen peroxide, of L-arginine to NO, and of hydrogen peroxide to the hydroxyl radical.

The invention discloses a wastewater degradation system and a wastewater degradation method based on cooperation of radial microchannel discharge and cavitation, and belongs to the technical field of organic wastewater treatment. The device comprises a waste liquid pool, a micro-channel discharge cavitation degradation device, an ozone generator, a Venturi tube and a collection pool, the Venturi tube is respectively communicated with the ozone generator, the waste liquid pool and a to-be-degraded wastewater inlet of the micro-channel discharge cavitation degradation device. A dielectric barrier discharge technology and a hydrodynamic cavitation technology are fused, a large number of active substances are generated in the inner and outer cavitation cavities through dielectric barrier discharge, a strong cavitation effect is generated around the rotor in cooperation with rotation of the cavitation rotor, and organic wastewater is degraded; by arranging the radial micro-channel discharge device, the discharge area is increased, the number of active substances such as ozone and hydroxyl radicals in gas and liquid phases is increased, and the inactivation loss of the active substances in the transportation process is reduced; and by arranging rotor cavitation teeth with opposite rotation directions, circular flow of a gas phase and a liquid phase is triggered, and the mass transfer efficiency is improved.

The invention discloses a drug-loaded liposome nano-particle, a preparation method thereof and application of the drug-loaded liposome nano-particle in treatment of brain glioma, and belongs to the technical field of biological nano-medicines. The invention provides a novel copper phthalocyanine derivative and catalase co-loaded lipidosome nanoparticle and application of the novel copper phthalocyanine derivative and catalase co-loaded lipidosome nanoparticle to treatment of brain glioma on the cellular level. The nano-particles are obtained by wrapping copper phthalocyanine derivatives and catalase with lipidosome prepared by a microfluidic method. The co-drug-loaded liposome can catalyze excessive H2O2 in brain glioma to generate oxygen, and O2 is continuously supplied to photodynamic therapy (PDT) to generate active oxygen; meanwhile, Cu < 2 + > can deplete glutathione and improve the oxidative stress level in the glioma, the reduction product Cu < + > can convert H2O2 into hydroxyl radicals with higher toxicity through a Fenton-like reaction, oxidative stress injury is doubly amplified, cascade cooperation of PDT and chemical dynamic therapy (CDT) is achieved, and the treatment effect on the glioma is remarkably enhanced.

The utility model discloses a water treatment device adopting an ozone micro-nano bubble coupling electrochemical oxidation process. The water treatment device comprises an ozone generating device, a micro-nano bubble generating device, a BDD (Boron Drain Discharge) electrode unit and an air flotation filter tank device, the device has the following beneficial effects: (1) the Venturi jet device is adopted to release ozone micro-nano bubbles, so that wastewater and the micro-nano bubbles are fully stirred and mixed and are fully contacted with the BDD electrode for oxidative degradation, and the impact force formed by jet flow can wash the BDD electrode plate, so that the BDD electrode plate is prevented from being easily blocked; (2) an ozone micro-nano bubble technology and a BDD electrode technology are coupled to generate a synergistic effect, a large number of hydroxyl radicals are generated, the oxidation capacity is enhanced, the organic matter removal capacity is improved, and the sterilization, decoloration and deodorization capacities of the device on raw water are enhanced. And (3) the BDD is combined with an air flotation process, so that the occupied area is reduced, and the layout is optimized. And (4) fine particles in the water body are further removed by the air floatation superposition filter tank, and the concentration of suspended particulate matters is reduced.

The invention belongs to the technical field of environmental engineering, and particularly relates to a method for enhancing the reaction efficiency of a Fenton-like fluidized bed through intelligent magnetic control. Specifically, customized composite magnetic particles are placed in a columnar Fenton-like fluidized bed reactor with an electromagnetic coil array distributed on the periphery, percarbonate activated by iron and aluminum phosphate is used as an oxidizing agent, and magnetic fields with different directions and intensities are applied to the magnetic particles by utilizing the electromagnetic coil array; the magnetic particles guide the fluid to form a required flowing form, and the fluid flowing path and the mixing process are highly accurately controlled, so that the aims of fully mixing the composite magnetic particles with the percarbonate ions, efficiently generating secondary oxidants such as hydroxyl free radicals, carbonate free radicals and superoxide anion free radicals and efficiently degrading pollutants are fulfilled.

The invention discloses a nano-carbon supported ruthenium cluster nano-catalyst as well as a preparation method and application thereof. According to the present invention, the synthesis process of the catalyst is simple and easy to perform, the reaction process is controllable, the nanocarbon with characteristics of rich defects and large specific surface area is adopted as the carrier, the ruthenium cluster is loaded on the surface of the nanocarbon, and the nanometer catalyst with characteristics of high specific surface area and high atom utilization rate is synthesized. The catalyst can catalyze persulfate (PDS) to generate products with strong oxidation activity, namely sulfate free radicals (SO4.-), hydroxyl free radicals (. OH) and singlet oxygen (1O2), so that effective inactivation of bacteria is realized. In the invention, the reaction of activating the persulfate to disinfect by the catalyst is carried out at room temperature under neutral conditions, and in a mild reaction environment, the nanocarbon-loaded ruthenium cluster nanocatalyst shows good capability of catalyzing the persulfate to inactivate bacteria, and has huge potential in practical application of water disinfection.

The invention discloses an aeration type water treatment device for catalytic degradation of pollutants based on triboelectrification, and belongs to the field of sewage and wastewater treatment. The lower portion is of a hollow cone structure, and the upper portion is of a cylinder structure. Positive and negative friction particles with spherical structures are placed in the device, the built-in rotatable aeration device can rotate and uniformly distribute gas under the action of gas flow, a gas-liquid-solid three-phase vortex flow is formed in combination with the rotation action of the stirring paddle, the friction particles generate high-frequency collision to generate an electrification effect, and the gas-liquid-solid three-phase vortex flow is formed. Hydroxyl free radicals (. OH) and superoxide free radicals (. O2-) are generated, and organic pollutants are efficiently degraded. The externally added magnetic field can inhibit electron-hole recombination. The device can realize innocent treatment of toxic and harmful wastewater, and has better practical and economic values.

The invention discloses a membrane pore aeration ozone heterogeneous catalytic reactor and a water treatment system, and relates to the technical field of water treatment. The reactor comprises a reactor cavity, the top of the reactor cavity is provided with a water outlet assembly, and the bottom is provided with a water inlet assembly and a gas inlet assembly; the membrane component is arranged in the reactor cavity and comprises a bundle of hollow fiber membrane filaments which are bent in a U shape; the two ends of the hollow fiber membrane filaments are bundled and fixed in a mounting hard tube, the mounting hard tube is detachably connected with the air inlet assembly, and the air inlet assembly is used for communicating an external air supply device with the hollow fiber membrane filaments; micropores are distributed in the surfaces of the hollow fiber membrane filaments; and the reactor cavity is filled with catalyst particles. According to the membrane pore aeration ozone heterogeneous catalytic reactor provided by the invention, the ozone mass transfer efficiency and the utilization rate are improved, and the content of hydroxyl radicals used for degrading organic matters in water is increased, so that the organic matters which are difficult to degrade in water can be more effectively removed, and the ozone treatment operation cost is reduced.

The utility model discloses a double-pulse internal aeration type electro-Fenton device, which relates to the technical field of sewage treatment equipment and comprises an electrolytic bath, a plurality of cathode plates and anode plates are arranged in the electrolytic bath at intervals, a water inlet and a water outlet are respectively arranged at two diagonal positions of the electrolytic bath, the cathode plates comprise a plurality of small cathode plates, and the anode plates comprise a plurality of small cathode plates. The small cathode plates are spliced on the same plane, and each small cathode plate is of a hollow honeycomb plate structure; the positive electrode of the power supply system is connected with the positive plates, and the negative electrode of the power supply system is connected with each small negative plate through a pulse switch; the aeration system is respectively connected with each small cathode plate; the control system is in control connection with the power supply system and the aeration system; the electro-Fenton device solves the problems of low hydrogen peroxide yield, side reaction decomposition of hydrogen peroxide at a polar plate, poor hydroxyl radical mass transfer, low utilization rate, high treatment cost and the like in the traditional electro-Fenton device.

The invention provides a diaphragm-free electrochemical sewage treatment method and device, and belongs to the technical field of sewage treatment. A sewage stock solution, an oxidizing agent and a catalyst are mixed, the mixed solution flows parallel to an anode and perpendicular to a cathode at the same time, a dynamic and stable anode acid zone, a dynamic and stable cathode alkaline zone and a dynamic and stable metal ion metastable zone are presented in a reactor by regulating and controlling a flow field and an electric field, and the mixed solution flows through an anode compression acid diffusion layer in parallel to promote the anode reaction efficiency; the alkaline diffusion layer vertically penetrating through the porous cathode efficiently reduces high-valence metal ions into low-valence metal ions, metal oxides and nano metal particles; hydroxyl free radicals and high-valence metal complexes are generated through a Fenton or Fenton-like catalytic reaction to degrade and mineralize refractory organic pollutants in the sewage stock solution, a large amount of acid and alkali does not need to be added before and after the reaction to adjust the pH value of the sewage stock solution, and the yield of active species is high; and cyclic utilization of the catalyst can be realized through intermittent backwashing of the porous cathode.

The invention provides an efficient chloramphenicol degradation method based on Co-Cu-carbon composite nano-catalyst activated peroxymonosulfate, which comprises the following steps: regulating the Co / Cu molar ratio in a bimetal organic framework precursor, and performing pyrolysis to prepare the Co-Cu-carbon composite catalyst with an optimized pore structure, graphitization degree and metal dispersity; peroxymonosulfate is activated by utilizing the synergistic effect of Co / Co and Cu / Cu redox pairs to generate sulfate free radicals, hydroxyl free radicals, singlet oxygen and superoxide free radicals, and direct oxidative degradation of chloramphenicol is promoted by taking a catalyst as an electron transfer bridge; the method realizes rapid and efficient removal of chloramphenicol, high mineralization rate, excellent cycle stability and strong anti-interference capability, and solves the technical problems of low removal efficiency, high cost and easy secondary pollution in the prior art.

The invention provides a Fenton technology coupled microbial fuel cell, a preparation method and application, and relates to the field of environment, materials and energy, the specific technical scheme is as follows: the Fenton technology coupled microbial fuel cell comprises an anode, a cathode and a catholyte, and is characterized in that the anode is a biological anode, the cathode is an air cathode, and the air cathode is an air cathode; the air cathode comprises an oxygen reduction electrocatalyst and a cathode substrate I, the oxygen reduction electrocatalyst is attached to the cathode substrate I, and the catholyte is common industrial and domestic wastewater. The electro-Fenton technology is introduced into the air cathode of the microbial fuel cell, the cathode fully utilizes electrons generated by metabolism of a biological anode to carry out an oxygen reduction process in the presence of air, so that hydrogen peroxide is generated in situ and is activated into active species such as hydroxyl free radicals through a Fenton catalyst, and the hydrogen peroxide is converted into hydrogen peroxide. Therefore, the purpose of degrading complex pollutants with low energy consumption is achieved.

The invention belongs to the technical field of microorganisms, and particularly relates to a lactobacillus plantarum (Lactobacillus plantarum) and an application of the lactobacillus plantarum. The preservation number of the lactobacillus plantarum is CGMCC (China General Microbiological Culture Collection Center) NO.24756. The lactobacillus plantarum has good DPPH (1, 1-diphenyl-2-picrylhydrazyl) scavenging capacity, hydroxyl radical scavenging capacity and reducing capacity, and can remarkably reduce the level of malondialdehyde (MDA) as an oxidative stress marker in serum and liver of an oxidative stress body, the pathological damage level of liver tissue and the level of inflammatory factors in serum; the level of an antioxidant substance glutathione (GSH) in serum and liver of an oxidative stress body and the activity of antioxidant enzymes superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPx) in the serum and liver can be remarkably improved. In addition, fire extinguishing bacteria of the lactobacillus plantarum have more excellent antioxidant activity than viable bacteria.

The invention provides a fluorescent probe for detecting hydroxyl radicals as well as a preparation method and application thereof, and the preparation method comprises the following steps: (S10) synthesizing a first intermediate compound by taking 2, 3, 3-trimethyl-3H-indoline and methyl iodide as raw materials; (S20) synthesizing a second intermediate compound by taking phosphorus trichloride, cyclohexanone and anhydrous dimethylformamide as raw materials; (S30) mixing and reacting the first intermediate compound and the second intermediate compound to synthesize a compound IR780; and (S40) synthesizing OH-probe on the basis of the IR780. The prepared OH-probe has extremely high sensitivity and excellent selectivity on hydroxyl radicals, can be effectively used for monitoring and mapping the level of the hydroxyl radicals, and can be applied to detection of atherosclerosis, obesity, cancers, neurodegenerative diseases, inflammatory diseases and other free radical related diseases. Wide development prospects and practical application values are realized.

The invention belongs to the technical field of wastewater treatment, and provides a method for realizing continuous degradation of pollutants under a low dosage based on a self-assembly induced carbon confinement material, which comprises the following steps: adding peracetic acid and a carbon confinement material into wastewater containing organic pollutants, treating the wastewater under a stirring condition, and in the wastewater treatment process, adding the peracetic acid and the carbon confinement material into the wastewater, the carbon confinement material activates peracetic acid to generate hydroxyl free radicals, organic free radicals, singlet oxygen and Co (IV) to degrade organic pollutants in the wastewater; the carbon confinement material is composed of a cobalt material and a nitrogen-doped carbon material coating the cobalt material, the cobalt material is composed of Co and CoO, and the carbon confinement material is nanoparticles with a core-shell structure. According to the invention, the high-efficiency utilization of the oxidizing agent peracetic acid can be realized under the condition of low-carbon confinement material dosage, the continuous degradation of micropollutants can be mediated, and the treatment cost of wastewater containing organic pollutants can be reduced.

The invention provides an active oxygen free radical generation method and application thereof. According to the method, a PFC nanoemulsion is utilized to catalyze H2O2 to generate active oxygen free radicals (hydroxyl radical.OH). The principle of generating reactive oxygen free radicals by the method is as follows: a PFC nanoemulsion and an H2O2 aqueous solution are adopted to form a liquid-liquid interface, interface contact is promoted through vortex or ultrasound, water molecules and hydroxyl ions are induced to lose electrons and generate. OH by utilizing a contact electrification effect, and PFC captures the electrons to form PFC * with negative electricity; then, H2O2 obtains electrons from PFC *, and OH is generated again. The method can be used in the fields of environmental pollutant degradation and drug preparation. The function and mechanism of the PFC nanoemulsion for catalyzing H2O2 to generate. OH active oxygen free radicals are found for the first time, the new application of the PFC nanoemulsion is widened, an important scientific basis is provided for developing a novel catalysis strategy, and the PFC nanoemulsion has important theoretical and application values.

The invention discloses a mining gas extraction conveying device which comprises at least one protective sleeve used for conveying gas, an extraction pump used for extracting gas and a conveying pipe located in the protective sleeve, and the protective sleeves are fixedly connected through a fixing sleeve in an airtight embedded mode. A first butt joint sleeve in airtight connection with the conveying pipe is fixedly installed in the middle of the fixing sleeve. The inner wall of the protective sleeve is coated with the manganese dioxide coating, ozone is filled in cooperation with the one-way gas pipe, when gas leaks to the protective sleeve in the conveying pipe, the ozone generates hydroxyl free radicals under catalysis of manganese dioxide, the hydroxyl free radicals and methane are subjected to an oxidation reaction, and the hydroxyl free radicals are decomposed into carbon dioxide and water, so that the explosion risk is reduced while the gas concentration is reduced; leaked gas is actively treated by utilizing a chemical catalysis principle, decomposition can be carried out when the gas leaks, the safety of the device is effectively improved, meanwhile, generated water prompts the leakage position through a dyeing patch of a drainage pipe, and timely maintenance is facilitated.

The invention discloses a method for accelerating straw composting by utilizing magnetite and compound microorganisms to drive biological advanced oxidation, and belongs to the technical field of efficient composting of agricultural organic solid wastes. The method comprises the following steps: (1) uniformly mixing straws and excrement as a compost body, adjusting the C / N ratio and the water content, adding magnetite, a bacillus subtilis liquid and a crushed white rot fungus liquid, and putting the mixture into a composting device; (2) intermittent aeration is carried out, the temperature is 28-32 DEG C, and the composting period is 40-50 days. According to the composting method, through intermittent aeration, controllable aerobic conditions and anoxic conditions are formed in a compost body, under the anoxic conditions, ferric iron is subjected to dissimilatory iron reduction to generate ferrous iron, and under the aerobic conditions, compound microorganisms reduce oxygen through extracellular electron transfer to form hydrogen peroxide, so that the composting effect is improved. Divalent iron and hydrogen peroxide are subjected to a Fenton-like reaction to generate hydroxyl free radicals with high oxidizing property, so that decomposition of straw lignocellulose is accelerated, and the composting efficiency of compost is improved.

The invention belongs to the technical field of extraction and purification of plant components, and relates to a low-temperature freezing vacuum drying nano processing method for extracting anthocyanin from purple corn, in particular to a method for extracting anthocyanin from corn kernels, cores, straws, roots and stigmas of purple corn. The processing method comprises the steps of pretreatment, concentration, hydroxyl radical treatment, quick freezing, nano crushing and the like. A hydroxyl radical treatment method is adopted, so that harmful substances such as pesticide residues can be efficiently, quickly and thoroughly removed; the effect of extracting the anthocyanin from corn kernels, roots, cores, stems and stigma of purple corn by adopting a low-temperature freezing vacuum drying technology is remarkable, the purification rate is high, and the anthocyanin containing 99% of biological activity is achieved. The nanoscale anthocyanin is processed by adopting jet mill equipment and can be conveniently absorbed by a human body and widely applied to various fields.

The electro-catalytic oxidation treatment device comprises an electro-catalytic box, a plurality of water pipe connectors are arranged at one length end of the electro-catalytic box, a supporting plate is arranged at the bottom in the electro-catalytic box, a plurality of polar plate groups are arranged on the upper portion of the supporting plate in the length direction, and insulating bars penetrate through the polar plate groups; the polar plate group comprises two cathode plates and an anode plate, the anode plate is positioned in a gap between the two cathode plates and is parallel to the two cathode plates, the bottoms of the anode plate and the two cathode plates are fixedly connected, and the anode plate and the cathode plate are L-shaped and form the right-angle U-shaped polar plate group; the upper ends of the anode plates and the cathode plates are fixedly connected with metal rods, the metal rods penetrate out of the side walls of the adjacent electro-catalysis boxes, and electric connectors are arranged at the outer ends of the metal rods. According to the electrocatalytic oxidation treatment device for the landfill leachate, the generation amount of oxidants such as hydroxyl radicals is changed by adjusting the current and voltage of the catalytic polar plate, so that pollutants are oxidized and removed. The method has the characteristics of simplicity in operation, low cost, broad spectrum, full quantization and the like.