4414 results about "Electrolysed water" patented technology

The invention discloses an operation state monitoring method and system for AEM water electrolysis hydrogen production equipment, particularly relates to the technical field of electrolytic bath operation monitoring control, and aims to solve the problem of efficiency nonlinear fluctuation caused by polarization mode alternating dominance and microstructure degradation under a low current density working condition in the prior art. Extracting polarization fluctuation characteristics by generating a dynamic response sequence and calculating a dynamic coupling degree to identify a polarization alternating dominant mode; analyzing a local blocking probability based on frequency characteristics, positioning an active site sparse region in combination with temperature gradient spatial distribution characteristics, and generating an efficiency fluctuation evaluation coefficient; an active site sparse region and a dynamic compensation factor matrix of a cathode flow field pressure gradient are constructed to cooperatively adjust an anode current density distribution weight and a cathode pressure gradient parameter, so that an adjusting variable is accurately matched with a local blocking probability and a dynamic coupling degree; the multi-scale correlation analysis of the microcosmic degradation state and the macroscopic efficiency fluctuation of the electrolytic cell is realized, and the operation stability under the low current density is remarkably improved.

The invention discloses an alkaline electrolytic water hydrogen evolution electrode, a preparation method thereof and an electrolytic bath based on the electrode. The electrode comprises a nickel net base material, raney nickel located on the nickel net base material and a catalytic layer which is electrochemically deposited on the surface of the raney nickel to cover a zigzag edge to form a smooth surface. The catalytic layer is a platinum catalytic layer, a nickel-sulfur alloy catalytic layer, a nickel-cobalt-zinc layer or a nickel-iron-zinc layer, and an electroplate liquid for electrochemical deposition comprises sulfosalicylic acid. According to the electrolytic cell, an alkaline electrolytic water hydrogen evolution electrode is used as a cathode, and Raney nickel / nickel net is used as an anode. According to the alkaline electrolytic water hydrogen evolution electrode, the catalyst layer which is high in binding force with the base material is deposited on the Raney nickel / nickel net base material in a specific electrochemical deposition mode, and the catalyst layer can effectively cover the sawtooth-shaped edge of the surface of the electrode and keep a part of the original high-specific-surface-surface structure of Raney nickel at the same time; the catalytic performance of the electrode is improved, and the overpotential of the electrode under 100mA / cm < 2 > can be lower than 241mV.

The invention relates to an optimization method of an alkaline water electrolysis hydrogen production system based on multi-parameter cooperative control. The method comprises the following steps: acquiring real-time power and historical output data of renewable energy sources, environmental parameters and operation data of an electrolytic cell, and preprocessing the real-time power and historical output data, environmental parameters and operation data of the electrolytic cell; constructing a fusion renewable energy fluctuation prediction model, and inputting historical output data, environmental parameters and electrolytic cell operation data into the model to predict renewable energy fluctuation characteristics; establishing a wind-light output prediction model, and determining an optimal current density interval based on the real-time power of the renewable energy and the wind-light output prediction model; correcting the real-time electrolyte concentration by adopting a conductivity-pH dual channel, constructing a concentration-current two-dimensional compensation model, and inputting the corrected real-time electrolyte concentration into the model to obtain a target electrolyte concentration; and dynamically adjusting related parameters of the hydrogen production system, calculating a self-adaptive threshold value of the system, determining a grading response threshold value based on the self-adaptive threshold value, and controlling the hydrogen production system to operate. And high-efficiency hydrogen production and stable operation of the system are realized.

The invention discloses a one-key starting system and method for an alkaline water electrolysis hydrogen production device, the system comprises a control system and a one-key starting control unit, and the control system is connected with the one-key starting control unit; the one-key start control unit comprises a standby panel soft button, a start panel soft button, a make-up pump selection soft button and a drainage panel soft button; therefore, the whole starting process of the alkaline water electrolysis hydrogen production device is subjected to sequential control integration, a safe and efficient one-key starting scheme with high automation degree is formed, safety risks in the manual starting process are avoided, manpower is saved, the labor cost is reduced, meanwhile, the starting time is shortened, unnecessary energy waste in the starting process is reduced, and the starting efficiency is improved. Therefore, the problems that the starting speed of the cluster electrolytic cell is low and the starting operation difficulty of the cluster electrolytic cell is high due to human factors in a large-scale electrolytic hydrogen production project are solved.

The invention provides a water electrolysis hydrogen production monitoring and control method with dynamic fluctuation adaptability, and relates to the technical field of hydrogen production. Comprising the steps that a multi-dimensional operation parameter set of an electrolytic cell is collected in real time through a multi-source sensor array, an electrolysis process prediction model is established based on the LSTM and the CNN neural network, and therefore the prediction result of the electrolysis state is determined. And according to the prediction result, a dynamic parameter adjustment matrix is constructed, and the electrolytic current density, the electrolyte concentration and other key parameters of the electrolytic cell are adjusted for the first time through fuzzy PID control. After adjustment, the multi-dimensional operation parameter set is updated, the health degree index of the electrolytic cell is calculated, and the relation between the index and a preset health index threshold value is monitored in real time. And second-time adjustment is carried out according to the monitoring result, so that safe and efficient operation of the electrolytic cell under the dynamic fluctuation condition is ensured. The problems that in the prior art, an electrolytic cell is slow in response to load change, insufficient in monitoring capacity, dependent on manual maintenance and the like are effectively solved.

The invention discloses an intelligent hydrogen production system and method.The intelligent hydrogen production system comprises a water supply device, a hydrogen production device, a purification device, a hydrogen conveying device, a pressure relief device, a system monitoring unit and a system control unit.The liquid level of a water tank is detected through a first liquid level meter, and the temperature of pure water of the water tank is detected through a first temperature sensor; the conductivity of water treated by the water machine is detected through the first conductivity meter so as to judge the purity degree of the water, the conductivity of electrolyzed water entering the electrolytic bath is detected through the second conductivity meter, the temperature of the electrolyzed water in the electrolytic bath is detected through the second temperature sensor, and it is guaranteed that the water quality and the water temperature in the electrolytic bath meet the electrolysis requirement. The liquid level of separated water in the water-vapor separator is detected through the second liquid level meter, the dew-point temperature of hydrogen is detected through the dew-point meter, and the actual output flow of hydrogen flowing through the hydrogen outlet is detected through the flow meter. The water temperature, the water level, the hydrogen flow, the conductivity and the like can be monitored, safe and efficient operation of equipment is ensured, and potential safety hazards are prevented.

The device is mainly used in the technical field of electrolytic hydrogen production. The invention discloses a water electrolysis hydrogen production system based on a proton exchange membrane electrolytic cell. The water electrolysis hydrogen production system comprises an electrolysis unit, a water circulation unit and a gas-liquid separation unit, the electrolysis unit is used for carrying out electrolysis treatment on the liquid water to obtain hydrogen, oxygen and gas-liquid mixed water; the gas-liquid separation unit comprises a primary separation module and a secondary separation module; the primary separation module is used for carrying out separation treatment on the gas-liquid mixed state water to obtain separated liquid water; the second-stage separation module is used for performing gas release treatment on the separated liquid water to obtain the liquid water after gas release; and the water circulation unit is used for transmitting liquid water after gas release to the electrolysis unit. According to the technical scheme, the release speed of the gas dissolved in the liquid water can be increased, the content of the gas in the liquid water is reduced, and therefore the safety risk of the water electrolysis hydrogen production system in the hydrogen production process is reduced.

The invention discloses an alkaline electrolytic water hydrogen production diaphragm for strengthening hydroxyl ion transfer and a preparation method of the alkaline electrolytic water hydrogen production diaphragm. The diaphragm comprises a supporting base net and a hydrophilic gas insulation coating which is arranged on the supporting base net and contains a hydroxyl ion transfer carrier, the method comprises the steps that a supporting base net is pretreated; the preparation method comprises the following steps: dissolving a polymer binder, a pore-foaming agent, a hydroxyl ion transfer carrier and a hydrophilic metal oxide in an organic solvent according to a mass ratio to obtain hydrophilic slurry; uniformly coating two sides of a supporting base net with the hydrophilic slurry, and then carrying out non-solvent induced phase conversion to obtain the alkaline electrolytic water hydrogen production diaphragm for strengthening hydroxyl ion transfer; polar groups such as hydroxyl, amino and carboxyl are introduced into a traditional composite diaphragm to construct a hydrogen bond network, so that hydroxyl ions can be transmitted in a jumping manner along the dynamic hydrogen bond network in the diaphragm to promote transmission of the hydroxyl ions, the performance of the diaphragm can be improved, the materials are cheap and easy to obtain, the preparation process is simple and convenient, and industrial expanded production is facilitated.

The invention relates to the technical field of temperature control, in particular to a temperature control management method and system for an electrolytic water tank and a medium. The method comprises the following steps: performing micro-channel structure processing on a main body shell of the electrolytic water tank, and embedding a modular micro-channel cooling plate to obtain geometric parameters of a cooling channel; identifying a key thermosensitive area of the electrolytic water tank; deploying a flexible micro temperature sensor array in the key thermosensitive area, and constructing a multi-point temperature monitoring network; collecting data in real time based on a multi-point temperature monitoring network to obtain real-time temperature data; and designing a micro-channel cooling liquid flow path based on cooling channel geometric parameter topological optimization to obtain a cooling liquid flow field structure. By integrating the micro-channel cooling structure and the high-density temperature monitoring network, efficient heat exchange and dynamic intelligent regulation and control of the electrolytic water tank cooling system are achieved, and the heat stability, safety and energy utilization efficiency are remarkably improved.

The invention discloses a device for assembling an electrolytic bath disc spring group and an assembling method thereof, and relates to the technical field of alkaline water electrolysis hydrogen production equipment. The device for assembling the electrolytic bath disc spring set comprises a bearing mechanism and further comprises a tightening mechanism, the bearing mechanism comprises a bearing tray and a holder fixed to the bearing tray, and the holder is located above the holder; the center of the bearing tray is provided with a through hole penetrating up and down, and the tightening mechanism is located below the through hole. The problems that in the prior art, when the electrolytic bath disc spring set is assembled, operation difficulty is large, and potential safety hazards are high are solved, the assembling quality is improved, and the assembling speed is increased.

The invention discloses a preparation method and application of an amorphous nickel-cobalt-iron phosphate anode catalyst, and belongs to the technical field of alkaline water electrolysis hydrogen production, the preparation method comprises the following steps: (1) dissolving transition metal salt in a solvent, and stirring to obtain a metal salt solution; (2) dissolving phosphate in a solvent, and stirring to obtain a phosphate solution; and (3) adding the phosphate solution into the metal salt solution for reaction, washing with deionized water and ethanol, centrifugally separating, and drying to obtain the amorphous nickel-cobalt-iron phosphate anode catalyst. According to the preparation method and application of the amorphous nickel-cobalt-iron phosphate anode catalyst, process safety improvement and environmental friendliness optimization are achieved through an all-water-phase green synthesis system, the obtained catalyst shows excellent performance in an AEM electrolytic cell, the cell voltage is only 1.87 V under the current density of 2 A / cm, and the method has remarkable industrial application prospects.

The invention relates to the technical field of hydrogen production by alkaline electrolyzed water, in particular to an anti-stripping alkaline electrolyzed water diaphragm casting solution, a diaphragm, a preparation method and application. The anti-stripping alkaline electrolyzed water diaphragm casting solution is prepared from the necessary solvent, the polydimethylsiloxane material, the polysulfone material, the inorganic nano-particles, the pore-forming agent, the cross-linking agent and the catalyst, and the polydimethylsiloxane material, the cross-linking agent and the catalyst act together, so that the enveloping of the inorganic nano-particles can be improved; the mechanical property of the membrane casting liquid on the membrane supporting layer is improved, and the anti-stripping effect is achieved. The diaphragm prepared by adopting the alkaline electrolyzed water diaphragm casting solution shows relatively low sheet resistance and stripping resistance, is good in air tightness, and is suitable for preparing the diaphragm of alkaline electrolyzed water hydrogen production equipment, so that the effects of maintaining free movement of ions in an electrolytic bath and blocking mixing of hydrogen and oxygen are achieved.

The invention discloses a solid oxide electrolysis reactor and system for producing hydrogen by coupling electrolytic water with combustible gas, the solid oxide electrolysis reactor comprises an anode end plate, an intermediate plate assembly and a cathode end plate which are connected in sequence, the intermediate plate assembly comprises a plurality of repetitive units, and the repetitive units are connected through connecting plates; the repeating unit comprises an electrolytic tank, the electrolytic tank comprises an anode, an electrolyte and a cathode, water vapor or a water vapor and hydrogen mixed gas is introduced into the cathode to generate an electrolyzed water reduction reaction to obtain hydrogen, and a combustible gas, water vapor and / or carbon dioxide mixed gas is introduced into the anode to generate hydrogen; and the combustible gas and oxygen ions which are generated by electrolyzing water at the cathode and are transmitted to the anode are subjected to deep oxidation reaction to obtain carbon dioxide. The cathode product gas is high-purity hydrogen or high-purity hydrogen obtained after condensation, the anode product gas is mixed gas of water vapor and carbon dioxide or mixed gas mainly comprising water vapor and carbon dioxide, and self-enriched high-concentration carbon dioxide can be obtained after condensation.

The invention discloses equipment and method for preparing double-electrolyzed water based on O3 and H2O2 in parallel, and relates to the technical field of disinfectant fluid preparation, the equipment comprises a lower shell and an upper shell, a self-priming pump, an ozone generation device, a hydrogen peroxide generation device and an ultraviolet device are installed in the lower shell, and the ozone generation device and the hydrogen peroxide generation device are arranged in parallel; a water inlet of the self-priming pump is connected with a first quick connector extending out of the side wall of the lower shell, and an outlet end of the ultraviolet device is connected with a second quick connector extending out of the side wall of the lower shell. The ozone generation device and the hydrogen peroxide generation device are connected in parallel, an aqueous solution containing ozone and hydrogen peroxide at the same time is obtained by controlling the proportion of ozone and hydrogen peroxide, photolysis of ozone and hydrogen peroxide is promoted by utilizing the synergistic effect of ozone and hydrogen peroxide and introducing an ultraviolet light source, and therefore more hydroxyl radicals are generated; and compared with an ozone solution, the sterilization effect of the disinfectant fluid is better.

The invention discloses a gas-liquid separation and washing integrated device and method for hydrogen production through water electrolysis. The device comprises a hydrogen side gas-liquid separation unit, a hydrogen side washing unit, an oxygen side gas-liquid separation unit, an oxygen side washing unit and a pressure balance unit. The hydrogen side gas-liquid separation unit is coupled with the hydrogen side washing unit, the oxygen side gas-liquid separation unit is coupled with the oxygen side washing unit, and the hydrogen side gas-liquid separation unit is coupled with the oxygen side gas-liquid separation unit through the pressure balance unit. According to the invention, the gas-liquid separation and washing processes of the hydrogen-oxygen electrolyte are integrated in one device, so that the number of the whole equipment of the process for producing hydrogen by electrolyzing water is reduced, the complexity of the whole process is reduced, and the compactness of the process equipment is improved, thereby improving the whole operation efficiency of the process. And hydrogen and oxygen are separated at the same time and collected separately, so that the process requirements and safety specifications of gas-liquid separation of the hydrogen-oxygen electrolyte in a water electrolysis hydrogen production process are well met, and the operation efficiency of the whole hydrogen production process is improved.

The invention provides a water electrolysis hydrogen production system and a control method thereof.The water electrolysis hydrogen production system comprises a water tank, a heat exchanger, an electrolytic bath and a hydrogen-water separator which are sequentially connected through a pipeline, and further comprises a water quality optimization branch, a water inlet end and a water outlet end of the water quality optimization branch communicate with the water tank; the system further comprises a branch variable frequency pump and a resin tank; the first drainage valve is arranged on a drainage pipeline communicated with the drainage port of the water tank; an inlet conductometer and an anode thermometer to detect a first real-time conductivity and real-time temperature of liquid entering the anode input end of the electrolytic cell; the outlet conductivity meter is used for detecting the second real-time conductivity of fluid flowing out of the oxygen output end of the electrolytic bath, and controlling the operation of the branch variable frequency pump and the opening and closing of the drain valve according to the first real-time conductivity, the real-time temperature and the second real-time conductivity; the problem that the service life of an electrolytic cell is short due to the water quality problem of a water electrolysis hydrogen production system in the prior art is solved.

The invention discloses a hierarchical optimization scheduling method for an electric power system containing a large-scale water electrolysis hydrogen production device, and relates to the technical field of hierarchical optimization scheduling of the electric power system.A gradient heterogeneous compensation unit fuses covariance alignment and differential privacy encryption, and on the premise that original data does not need to be shared, the optimal scheduling of the electric power system is achieved. The federal learning convergence speed is improved to a practical level; after each hydrogen production station uploads the encryption gradient, a coordinator corrects and eliminates equipment difference interference through statistical distribution, and generates a global consistent frequency modulation strategy, so that commercial sensitive information is protected, and model oscillation failure is avoided; the knowledge distillation unit further compresses the volume of the model to guarantee the real-time response capability of edge nodes, and when the frequency of the power grid changes suddenly, a quick response protocol automatically triggers a dynamic priority distribution mechanism; the regional aggregation layer directly broadcasts a frequency modulation instruction based on a historical performance label, and skips a federated learning iteration process, so that a hydrogen production cluster forms an adjusting resultant force in a second level.

The invention provides a proton exchange membrane electrode and application of the proton exchange membrane electrode in water electrolysis hydrogen production. The invention particularly relates to application of the proton exchange membrane electrode prepared by adopting a specific preparation process in water electrolysis hydrogen production. The membrane electrode used in hydrogen production by electrolysis of water adopts long-chain and short-chain perfluorinated sulfonic acid resin, has adjustable hydrophilicity, is beneficial to the generation of catalytic reaction and rapid discharge of generated gas, and improves the gas-liquid mass transfer effect of the membrane electrode; the adopted membrane electrode reduces the occupation of bubbles on the surface and improves the performance expression of the membrane electrode.

According to the supercritical CO2 circulation and water electrolysis hydrogen production coupled alcohol-electricity co-production system and method, water in an electrolytic bath is electrolyzed through wind and light abandoned electricity, and oxygen and hydrogen are generated. Oxygen and coal are subjected to pure oxygen gasification in a gasification furnace, and generated gasified gases (mainly including methane CH4, hydrogen H2 and carbon monoxide CO) are subjected to direct-fired supercritical CO2 circulation for power generation. Waste gas exhausted by the turbine is subjected to heat recovery through the heat regenerator, water is condensed in the condenser, and remaining CO2 is fed into the gas tank to be stored. One part of CO2 is pressurized by a compressor and then is fed into the combustion chamber through a heat regenerator, and the other part of CO2 and H2 are catalyzed to synthesize methane. According to the system, wind and light abandoned electricity can be converted into hydrogen energy to be stored, efficient clean power generation of coal and synthesis of green methanol are achieved through direct-fired supercritical CO2 circulation, and the green methanol / electricity co-production system with zero carbon emission is formed.

The invention relates to the technical field of water electrolysis hydrogen production, in particular to a water electrolysis hydrogen production optimization method and system based on big data analysis, and the method comprises the following steps: S1, data collection: collecting operation data in a water electrolysis hydrogen production process in real time through a sensor; s2, data preprocessing and feature extraction: extracting features related to electrolytic efficiency and electrode life; s3, bubble management based on self-adaptive sound wave control: dynamically adjusting the frequency and intensity of sound waves by using a self-adaptive sound wave control algorithm, and optimizing the distribution and discharge path of bubbles on the surface of the electrode; and S4, fatigue prediction and optimization of the electrode material: analyzing the performance change of the electrode material in real time, predicting the fatigue life of the electrode, and automatically adjusting electrolysis operation parameters or intelligently scheduling replacement operation of the electrode according to a prediction result. According to the invention, the stability of the electrolysis process is ensured, and the problem of performance reduction caused by bubble accumulation is avoided.

The invention relates to the technical field of nano catalytic materials, in particular to a preparation method and application of a nano bowl-shaped molybdenum-doped metal cobalt phosphide catalyst. The preparation method comprises the following steps: S1, preparing CoMo-MOF; S2, preparing Mo-CoP; according to the application method, the nanometer bowl-shaped molybdenum-doped metal cobalt phosphide catalyst is applied to the process of catalyzing water electrolysis hydrogen absorption and oxygen absorption reaction. According to the preparation method, the Mo-doped metal organic framework is adopted as a precursor, the target catalyst is prepared through phosphating and calcining, due to the fact that the valence state of Co in cobalt phosphide is improved through molybdenum doping, the intrinsic catalytic activity of the catalyst is improved, and electrolysis of water can be effectively catalyzed.

The invention discloses a hydrogen purification pressure optimization system and a control strategy for hydrogen production through electrolysis of water, and relates to the technical field of hydrogen production through electrolysis of water, and the hydrogen purification system comprises a hydrogen purification unit which comprises a plurality of adsorption towers arranged in parallel and is used for adsorbing and removing impurities in hydrogen; the pressure optimization system comprises a pressure sensor, a pressure regulating valve and a controller, the pressure sensor is used for monitoring the pressure in the adsorption tower in real time, the pressure regulating valve regulates the pressure according to an instruction of the controller, and the controller is used for regulating the pressure according to the adsorption characteristics of the adsorbent and the requirements of the hydrogen purification process. Setting pressure control parameters to adjust the pressure in the adsorption tower in real time; and the control unit is used for performing coordinated management on the temperature and the flow of the pressure optimization system, and forming closed-loop feedback regulation of parameters by comparing the actual purity of the purified hydrogen with a preset purity standard. The hydrogen purity is improved, the adsorbent works under the optimal pressure by optimizing the pressure control strategy, the hydrogen purity is effectively improved, and the energy consumption is reduced.

The invention belongs to the technical field of electrocatalyst material preparation, and discloses a long-range disordered localized CoOOH ultrathin nanosheet electrocatalyst as well as a preparation method and application thereof, fluorine-doped cobalt selenide nanobelts prepared by a low-temperature annealing method are used as a base material, and the CoOOH ultrathin nanosheet electrocatalyst is prepared by in-situ reconstruction under an alkaline electrolyzed water anode oxygen evolution reaction condition. In the preparation process of the CoOOH ultrathin nanosheet provided by the invention, lattice cobalt is stabilized in the water electrolysis anode reconstruction process through fluorine ions with strong bonding action with cobalt ions, so that the long-range disordered structure of amorphous CoOOH generated after reconstruction is limited by localization, and the alkaline water electrolysis anode reaction performance is improved. The catalyst has activity and durability obviously superior to those of a commercial ruthenium oxide catalyst in industrial application of anion exchange membrane water electrolysis hydrogen production.

The invention provides a novel adjustable partition type alkaline electrolytic cell technology and a matched electrolysis cell structure, and belongs to the technical field of alkaline water electrolysis hydrogen production. According to the technology, a flow channel of an alkaline water electrolysis device is changed to be four-in and four-out and is divided into four areas, and the flow of each area is independently adjusted; a hydrogen molecule detector is arranged on the gas outlet side, the opening degree of a liquid inlet adjusting valve is controlled according to a detection result, dynamic adjustment is achieved, and flow balance is guaranteed; the small electrolysis chamber comprises a pole frame, a pole plate, a diaphragm and an electrode net, the pole frame is in four-partition design, and a vertical partition plate is added to enhance the rigidity; the pole plate is divided into three phases and the mastoid structure is optimized; the diaphragm is designed in a split manner; the electrode net is optimized according to the polar plate. The process and the structure are optimized, the electrolysis efficiency is improved, the structural safety is enhanced, the energy consumption is reduced, and good application prospects are achieved in the field of hydrogen production through alkaline electrolysis of water.

The invention provides a modified alkaline electrolytic water hydrogen production diaphragm and a preparation method thereof. The modified diaphragm comprises a base membrane loaded with a Cu < 2 + > complexed chitosan alkali-resistant ion conduction unit, and the Cu < 2 + > complexed chitosan alkali-resistant ion conduction unit is obtained by loading chitosan through the base membrane and soaking in a Cu < 2 + > complexed solution for complexing. By introducing a copper-chitosan complex structure, a stable ionic conduction channel is constructed in an alkaline environment, and the alkali resistance and ionic conductivity of the membrane are effectively improved. According to the modified alkaline diaphragm for hydrogen production by electrolysis of water, the problems of insufficient alkali resistance, limited ion transmission capability and the like of a diaphragm material in the prior art are solved, and a new solution is provided for preparing the diaphragm for hydrogen production by electrolysis of alkaline water with long service life, high efficiency and low cost.

The invention discloses an electrocatalyst for acidic oxygen evolution reaction as well as a preparation method and application of the electrocatalyst, and belongs to the technical field of electrolyzed water. The preparation method of the electrocatalyst for the acidic oxygen evolution reaction comprises the following steps: growing a transition metal oxide on a conductive substrate in situ to obtain a transition metal oxide carrier; the transition metal oxide carrier is subjected to plasma treatment and then placed in a precious metal salt solution for a cation exchange reaction, and the electrocatalyst is obtained. The electrocatalyst prepared by the invention has extremely low initial overpotential (187mV) when a water electrolysis reaction is carried out in a 0.5 M H2SO4 solution, has no obvious performance degradation in a continuous acidic water electrolysis process for 4500h, shows very high operation stability, and has great application potential in the aspects of replacing a commercial RuO2 / IrO2 catalyst and reducing electrode preparation cost and acidic water electrolysis.

The invention relates to a non-noble metal-based self-supporting electrode, a preparation method thereof and application of the non-noble metal-based self-supporting electrode in efficient electrolyzed water. The self-supporting electrode comprises a non-noble metal substrate layer, and a transition layer and a catalytic activity layer which are sequentially arranged on the surface of the non-noble metal substrate layer, the transition layer comprises NiFe unit cell nano particles; the catalytic activity layer comprises CoFeLDH, and the CoFeLDH is of a cactus spherical structure formed by a nano needle-shaped array; and a heterojunction interface is arranged between the transition layer containing the NiFe unit cell nanoparticles and the catalytic activity layer containing the CoFeLDH. The catalyst has low oxygen evolution overpotential and has high current density and excellent stability under the working condition, the transition layer is constructed between the catalytic active layer and the foamed nickel substrate, interface contact between the catalytic active layer and the substrate can be optimized, more uniform stress distribution and better interface adhesion can be achieved, charge transfer and mass transfer are enhanced, and the catalytic activity of the catalyst is improved. Therefore, the electrode interface stability is realized.

The invention provides a fault diagnosis method and system for a water electrolysis hydrogen production system based on a graph neural network, and belongs to the technical field of water electrolysis hydrogen production, and the method comprises the steps: obtaining key operation parameters of the water electrolysis hydrogen production system; constructing a time-varying dynamic adjacency matrix based on the key operation parameters, wherein the time-varying dynamic adjacency matrix is obtained by weighting and fusing physical topological structure data and multivariate time sequence data through arbitration parameters; inputting the multivariate time sequence data into a time feature extraction module, and extracting time dependent features; inputting the dynamic adjacency matrix into spatial feature extraction module spatial dependency features based on the time dependency features; fusing the time dependency feature and the spatial dependency feature by adopting a time-space gating fusion mechanism to obtain a fused spatial-temporal feature; and a fault classification module is adopted to identify whether the water electrolysis hydrogen production system has a fault and a fault type based on the fusion features. The diagnosis method is high in accuracy and fast in response.

The invention discloses a self-suction type water electrolysis hydrogen production capillary electrolytic bath and belongs to the technical field of water electrolysis hydrogen production. The capillary electrolytic bath comprises an electrolysis assembly and an electrolyte cavity which are connected through a capillary transmission layer, and the electrolysis assembly comprises a diaphragm, an anode unit arranged on one side of the diaphragm and a cathode unit arranged on one side of the diaphragm; electrolyte is stored in the electrolyte cavity, and the capillary transmission layer extends into the electrolyte in the electrolyte cavity and is connected with the electrolyte cavity and the electrolysis cavity of the electrolysis assembly. Therefore, the self-suction water electrolysis hydrogen production capillary electrolytic cell provided by the invention is applied to PEM water electrolysis hydrogen production and AEM water electrolysis hydrogen production. By means of the capillary transmission layer with the capillary phenomenon, the electrolyte is conveyed from the electrolyte cavity to the electrolysis anode cavity or the electrolysis cathode cavity, generated oxygen and hydrogen can be directly discharged without resistance, bubbles are not generated, and the problem that gas bubbles generated in the prior art block porous channels is solved.

The invention provides a hydrogen production electrode doped with platinum, ruthenium, tin and praseodymium, a preparation method of the hydrogen production electrode and a water electrolysis hydrogen production device, and relates to the field of water electrolysis hydrogen production. The preparation method of the hydrogen production electrode doped with platinum, ruthenium, tin and praseodymium comprises the following steps: coating the surface of a conductive substrate with mixed powder; the conductive base material coated with the mixed powder is subjected to thermal oxidation treatment, the mixed powder comprises first metal powder, second metal powder and a pore forming agent, the first metal powder comprises Ni powder, and the second metal powder comprises Pt powder, Ru powder, Sn powder and Pr powder; and putting the structure subjected to thermal oxidation treatment into an alkaline solution, and activating to obtain the hydrogen production electrode doped with platinum, ruthenium, tin and praseodymium. The platinum, the ruthenium, the tin and the praseodymium are introduced into the hydrogen production electrode, so that the hydrogen evolution overpotential can be reduced. The hydrogen production electrode prepared by the method disclosed by the invention has relatively high catalytic activity, relatively high stability and a uniformly distributed porous structure, the electrolytic efficiency can be remarkably improved, and the service life of equipment is prolonged.