3377results about How to "Less corrosive" patented technology

The invention discloses a built-up synergetic class-A / B water extinguishing agent series. Class-A fires caused by solid substances (such as woods, cottons, wools, linens, paper) and products thereof and class-B fires caused by liquid or melted solids such as gasoline, kerosene, diesel oil, crude oil, methanol, ethanol, asphalt, paraffin waxes and the like can be put out rapidly through the functions such as heat absorption and cooling, diluting and smothering, insulating and covering, suppressing and blocking combustion chains, and the like which are synergetically performed by various extinguishing functional components, and a high-temperature-resistant thermal-insulation and fire-retarding covering layer is formed on the surface of an inflammable matter by various after-combustion functional components so as to achieve the effect of after-combustion resistance. Because the class A / B fires relate to multiple occasions of daily life and production activities, the extinguishing agent disclosed by the invention can be used in the fields of home fire prevention and extinguishing, urban architecture fire prevention and extinguishing, oil depot and gasoline station fire prevention and extinguishing, vehicle and ship fire prevention and extinguishing, forest and grassland fire prevention and extinguishing, mine fire prevention and extinguishing, confined spaces (such as civil air-defense architectures) fire prevention and extinguishing.

A method for producing butanol through microbial fermentation, in which the butanol product is removed by extraction into a water-immiscible extractant composition comprising a first solvent and a second solvent, is provided. The first solvent is selected from the group consisting of C12 to C22 fatty alcohols, C12 to C22 fatty acids, esters of C12 to C22 fatty acids, C12 to C22 fatty aldehydes, C12 to C22 fatty amides and mixtures thereof. The second solvent is selected from the group consisting of C7 to C11 alcohols, C7 to C11carboxylic acids, esters of C7 to C11 carboxylic acids, C7 to C11 aldehydes, and mixtures thereof. Also provided is a method for recovering butanol from a fermentation medium.

The present invention provides gels, solutions, films, membranes, compositions, and other materials containing polymerized and / or non-polymerized room-temperature ionic liquids (RTILs). These materials are useful in catalysis, gas separation and as antistatic agents. The RTILs are preferably imidazolium-based RTILs which are optionally substituted, such as with one or more hydroxyl groups. Optionally, the materials of the present invention are composite materials comprising both polymerized and non-polymerized RTILs. The RTIL polymer is formed from polymerized RTIL cations typically synthesized as monomers and polymerized in the presence of the non-polymerized RTIL cations to provide a solid composite material. The non-polymerized RTIL cations are not covalently bound to the cationic polymer but remain as free cations within the composite material able to associate with charged subunits of the polymer. These composite materials are useful in catalysis, gas separation, and antistatic applications.

The invention provides a lithium ion flow redox battery, belonging to the technical field of lithium ion batteries. The lithium ion flow redox battery comprises a positive electrode suspension tank, a negative electrode suspension tank and a battery reactor, wherein the positive electrode suspension tank contains the mixture of positive electrode composite material particles and an electrolyte; the negative electrode suspension tank contains negative electrode composite material particles and an electrolyte; the battery reactor comprises a positive electrode current collector, a negative electrode current collector and one layer or a plurality of layers of microporous separators; the microporous separators separate the positive electrode current collector from the negative electrode current collector in an insulation mode so as to respectively form a positive electrode chamber and a negative electrode chamber; the positive electrode chamber is communicated with the positive electrode suspension tank through a seal pipeline; and the negative electrode chamber is communicated with the negative electrode suspension tank through a seal pipeline. Compared with a full vanadium flow redox battery, the lithium ion flow redox battery has the advantage of high energy density, the adoption of the environmentally-friendly and non-toxic electrolyte and low cost, and is applicable to large-scale energy storage of power grids.

The invention discloses a high electrical property and low corrosion flame retardant reinforcing nylon material and a preparation method thereof, aiming at solving the defects of low electrical property and high corrosion caused by red phosphorus based flame retardant added into flame retardant reinforcing nylon in the prior art. The invention adopts the technical scheme that the high electrical property and low corrosion flame retardant reinforcing nylon material disclosed by the invention has the formulation (by weight percent): (1) 40-65% of nylon 66 resin, (2) 10-20% of red phosphorus based flame retardant masterbatch, (3) 1-5% of compatilizer, (4) 3-10% of synergistic compound flame retardant system, (5) 0.5-5% of acid absorbent, (6) 0.1-0.5% of antioxidant, (7) 0.2-0.8% of lubricating agent and (8) 10-30% of glass fiber; and the reinforcing nylon material can be prepared by mixing all the components in a high-speed mixing machine for 1-2min and then putting into a twin-screw extruder for extrusion and pelleting. The flame retardant reinforcing nylon material is excellent in the electrical property, low in corrosion (extremely low in corrosion for equipment and a mould) as well as high in fluidity, heat resistance and cost performance, and is capable of meeting the requirements of electrical and electronic appliances such as a temperature controller, a contactor, a circuit breaker and the like as well as domestic appliance products.

The invention discloses a one-variable solid effervescent tablet and a preparation method for the tablet. The material system of the effervescent tablet comprises chlorite, solid acid source, free halogen source, activated Promoter, desiccant, bond, release agent, effervescent and surfactant. The preparation technique includes: after the coating processing with chlorite grains, drying and mixing well with other raw materials according to a specific proportion and technique requirements to prepare compound raw materials, and then pressing into tablets with different specification and shaping on the tablet machine to fit for application in various occasions. The effervescent tablet can quickly release chlorine dioxide and acquire pellucid water solution of chlorine dioxide while dissolving in the water, which is high in stability, rapid in dissolving rapid and strong in bactericidal ability.

Alcohols, ethers, aldehydes, and olefins are manufactured from alkanes by mixing an alkane and a halogen selected from the group including chlorine, bromine, and iodine in a reactor to form alkyl halide and hydrogen halide. The alkyl halide only or the alkyl halide and the hydrogen halide are directed into contact with metal oxide to form an alcohol and / or an ether, or an olefin and metal halide. The metal halide is oxidized to form original metal oxide and halogen, both of which are recycled.

The invention relates to the technical field of materials for synthetic leather, in particular to weak solvent aliphatic polyurethane resin for synthetic leather and a preparation method thereof. The weak solvent aliphatic polyurethane resin for synthetic leather is prepared from the following components by weight percent: 2-30 percent of aliphatic diisocyanate compound, 5-40 percent of polyester or polyether polyalcohol compound, 0-10 percent of micromolecule polyol chain extender, 0.1-13 percent of micromolecule polyamine chain extender, 0.01-1.0 percent of catalyst, 0.05-5.0 percent of assistant and 45-85 percent of organic mild solvent. The invention also discloses the preparation method of the weak solvent aliphatic polyurethane resin for synthetic leather. By adopting the technical scheme, the polyurethane resin with different solid contents, different viscosities and different modulus can by synthesized, the requirement of the synthetic leather is satisfied, and the synthetic leather product with high temperature resistance, cold resistance, anti-sticking performance and better external tensility of pigment can be prepared.

The invention relates to the technical field of soldering pastes, in particular to a halogen-free tin-bismuth-copper soldering paste and a preparation method thereof. A soldering flux of the halogen-free tin-bismuth-copper soldering paste consists of the following components in percentage by weight: 20 to 40 percent of polymerized rosin, 1 to 6 percent of rosin amine, 4 to 8 percent of thixotropic agent, 5 to 10 percent of organic acid, 5 to 10 percent of organic amine, 1 to 5 percent of antioxidant, 0.5 to 3 percent of surfactant and an organic solvent. The halogen-free tin-bismuth-copper soldering paste is mainly characterized by adopting the organic acid and the organic amine serving as activating agents and comprising no halogens at all, so not only the solderability is not reduced, but also the expansion rate and the insulation resistance value of the soldering paste are improved, and simultaneously the corrosivity of residues after soldering to a base material is reduced and the service life of the soldering paste is prolonged; and particularly, the peak temperature of the soldering paste during soldering is lower in favor of reducing the thermal damages to electronic components.

The invention relates to denitrition catalyst with a mercury removal effect. The catalyst has a chemical general formula of: MXn-V2O5-Y / TiO2, wherein, M is a metallic element selected from Fe, Cu, Mn or Co, X is halogen Cl or Br, Y is WO3 or MoO3, and n=2-4, and the elements are in a weight ratio of: 1-10 of M, 1-1.5 of V, 7.5-8.5 of W or Mo, and 75-100 of TiO2. The catalyst is prepared by the steps of: dipping V2O5-WO3 / TiO2 or V2O5-MoO3 / TiO2 with MCln or MBrn, then conducting frying and calcination. With the catalyst of the invention, catalytic reduction of NOx and catalytic oxidation of Hg<0> can be simultaneously completed in an original flue gas denitrition catalytic reactor, and the generated divalent mercury ions are washed and cured in desulfurized gypsum in a subsequent flue gas wet desulphurization process. Thus, cooperative control of the discharge of NOx and Hg<0> can be realized without increasing flue gas purification facilities of coal-fired power plants.

The invention discloses a cleaning agent for optical glass, which comprises the following components in weight percentage: 2-4% of long carbon chain dibasic acid; 6-10% of an anionic surfactant; 2-4% of an inorganic base; 2-6% of a nonionic surfactant; 2-4% of a special surfactant; 6-12% of a chelator; 10-20% of an organic base; and 40-70% of deionized water, wherein the long carbon chain dibasic acid is dicarboxylic acid with 21 carbon atoms, the anionic surfactant is dodecylbenzene sulfonic acid, the inorganic base is industrial NaOH, the nonionic surfactant is primary alcobol ethoxylate AEO9, the special surfactant is sodium POE nonylphenol ether sodiosulfosuccinate, the chelator is a mixture of Tetrasodium Ethylenediamine Tetraacetate and sodium gluconate, and the organic base is diethanol amine. The cleaning agent for optical glass provided by the invention has low corrosivity and good cleaning effect.

The invention provides a glass cleaner. The cleaner comprises a nonionic surfactant, an anionic surfactant, a corrosion inhibitor, an antifreezing film-forming agent, a lubricant and a solvent. The invention also provides application of the glass cleaner to the cleaning of front windshields of trains, in particular application of the glass cleaner to the cleaning of front windshields of motor trains. The cleaner has extremely strong decontamination capacity, and can quickly and effectively remove pollutants which appear on windshields of trains running at a high speed; the cleaner has higher ambient temperature adaptability, and can be used at the temperature of between minus 40 and 60 DEG C; the pH value is 6.8 to 7.2, and the cleaner has lower corrosivity; the cleaner has high lubricity and can prevent the windshields from being bruised; an antifreezing film-forming component is added and can achieve the effects of anti-icing and demisting; and the cleaner does not contain components which are toxic or irritant to human bodies such as methanol, ammonia water and the like.

The invention discloses a method for synthesizing fatty acid ester through ester exchange reaction. The method comprises: adding grease, methanol and ionic liquid catalyst to a reactor, and controlling the reaction temperature to be between 45 and 85 DEG C for the ester exchange reaction for 1 to 10 hours. The method has the advantages of mild reaction condition, wide material applicability, high fatty acid yield, good quality, long service life of the catalyst and the like. Compared with the prior acid-alkali catalyst for industrial use, the catalyst of the method has the advantages of low corrosivity, high catalytic activity, no pollution and repeated use, and has the potential for industrial application.

The invention provides a method to extract aluminum oxide from a fly ash, and relates to a technological method which is to extract aluminum oxide from the fly ash and comprehensively utilize the residue after extracting aluminum oxide. The invention is characterized in the method which is as follows: ammonium sulfate is mixed into the fly ash to sintering, and the solid is dissolved to obtain the solution containing aluminum-ammonium sulfate; the solution is crystallized to form solid aluminium-ammonium sulfate; solid aluminium-ammonium sulfate reacts with ammonia gas to obtain aluminium hydroxide and ammonium sulfate, and aluminium hydroxide and ammonium sulfate are washed and filtrated to obtain solid aluminium hydroxide; solid aluminium hydroxide is calcined to obtain aluminum oxide; ammonium sulfate can be circularly used after being evaporated in the liquid phase. The ammonium sulfate which is used by the method of the invention is weak acidic, the corrosiveness on the equipment is small, and the ammonium sulfate can be used circularly. The whole process is easy to industrial application. The requirement of the corrosion resistance on the equipment is low. The amount of the residue is small which is beneficial to the comprehensive utilization of the residue after extracting the aluminum oxide.

The invention discloses a halogen-free cleaning-free rosin flux, and preparation and application thereof, and particularly relates to a flux suitable for surface mount lead-free welding paste, preparation of the flux and application of the flux. The flux comprises 20-50% (mass fraction, the same below) of rosin, 5-25% of film-forming agent, 30-50% of high boiling solvent, 3-8% of activator and 2-5% of thixotropic agent, and the flux does not contain any halogen. In order to control growth of interface IMC (intermediate compound) during welding, 0.3-1% of combined inhibitor is added. The welding paste prepared with the flux and lead-free tin-silver-copper powder has the advantages of excellent printing performance, fine weldability, less post-weld residue, thin and even welding spot interface IMC and excellent mechanical property, and is capable of meeting the requirement of high-end electronic products on packaging.

The invention relates to a composite decarbonization solution for reclaiming the carbon dioxide in the exhaust gas, wherein the component and the mass percent of the composite are that: 20-60 percent of composite amines solution, wherein one or more fast reaction rate amines with a low concentration and one or more slow reaction rate amines with a high concentration are comprised; 5-10 percent of Polyxinolum; 1-5 percent of antioxidant; 1-5 percent of inhibitor; and the rest is water. The invention has the advantage of a large absorbing capability to CO2, a high degree of purification, a light causticity, a little consume of the solution and a lower recycling energy consumption. High concentration CO2 for gas injection oil-recovery can be obtained.

The invention discloses a method for synthesizing polymethoxy dimethyl ether under the atalysis of geminal dicationic ionic liquid. In the method, methanol and trioxymethylene are taken as reaction raw materials and the geminal dicationic ionic liquid is adopted as a catalyst to catalytically synthesize the polymethoxy dimethyl ether under the reaction temperature of 333 to 423K and the reaction pressure of 0.5 to 4MPa. The method has the highest reaction conversion rate of 91.5 percent, high product selectivity, and the active diesel added-component DMM308 content of 49.6 percent.

The invention relates to an anticorrosive wearable electrodeposit clad layer of Ni-W-P ternary alloy and manufacturing technique and electroplates liquid thereof, which takes the nickel sulfate, sodium tungstate, phosphate as the main material, electrically depositing the Ni-WP amorphous mixture of amorphous or nanocrystalline alloy coating. The characteristics of the electroplate technique are following: corrosive solution is very small, the entire production of the use of cleaner production, less emissions, in line with the requirements of sustainable production. W of the coating for the content of 1-45wt%, P content of 0.1-5wt%, nickel is the residue. The plating layer is bright and dense; the hardness is 400-1100Hv, which is resistant to acid, alkali, salt and hydrogen sulfide corrosion, wear resistance is better than or equivalent to chrome plating, can not only replace decorative chromium or hard chromium is widely used, and can be used for oil field exploration equipment to deal with wear-resistant anti-corrosion.

The invention relates to a process for indirectly producing alcohol with synthetic gas. The process comprises the steps that the synthetic gas formed by mixing industrial carbon monoxide with hydrogen is taken as a raw material to synthesize methanol; methanol is dehydrated to prepare dimethyl ether; dimethyl ether, carbon monoxide and hydrogen are mixed for carbonylation reaction to prepare methyl acetate; methyl acetate is purified and hydrogenated; a hydrogenated product is purified; and an alcohol product is obtained. An adopted catalyst, the process and a device have the characteristics of high conversion per pass and high effective utilization rate of reaction heat; the load of separating a crude product is reduced greatly; the production flow is shortened; and the production energy consumption is reduced greatly.

The invention discloses a power plant wastewater zero-discharge treatment technique which comprises a pretreatment process, an evaporative concentration process and an evaporative crystallization process, wherein the pretreatment process equipment comprises a precipitation and concentration tank, a sludge dewatering machine, and a raw water precipitation tank, a primary softening reactor, a secondary softening reactor and a softening precipitation tank which are sequentially connected; the evaporative concentration process equipment comprises an automatic back flush filter, a plate-type preheater, a degasser and a falling film evaporator which are sequentially communicated; and the evaporative crystallization process equipment comprises a concentrated solution tank, a crystallizing heater and a crystallizer which are sequentially communicated. The desulfurization water treatment technique is reasonable in step design and performs the pretreatment, evaporative concentration and evaporative crystallization on the desulfurization wastewater, and the end products are only distilled water and crystalline salt, thereby reducing the discharge of the harmful substances, lowering the energy consumption and implementing the goal of zero discharge of desulfurization wastewater.

The invention discloses an efficient low-toxicity formaldehyde scavenger containing the following raw material components by weight: 0.5%-5% of hydrazide, 0.1%-5% of a water-soluble ester, 0.5%-10% of a moisture absorbent, 0.1%-0.5% and of a buffer, 0.05%-1% of a surface active agent, 0.02%-0.5% of a preservative and 80%-98% of water. The free hydrazine content in the efficient low-toxicity formaldehyde scavenger product is controlled in the range as low as possible by the manner of fine selection of the hydrazide raw material, control of free hydrazine content, adding of the water-soluble ester, adding of the buffer, and the like, and the efficient low-toxicity formaldehyde scavenger product has better security. The efficient low-toxicity formaldehyde scavenger product is good in formaldehyde removal effect, safe to people and objects, and simple in production process, and can be used for governance of the problem of formaldehyde exceeding the standard in new decorated residence or furniture.

A system for generating electrical energy using a naturally occurring temperature difference is disclosed. The system provides electrical energy by thermally coupling a conduit that conveys hot material from a petroleum reserve and cold deep-level water to opposing sides of a thermoelectric element. The thermoelectric element generates electrical energy based on the temperature difference between these two surfaces.

The invention provides a method for preparing grain active carbon with high specific surface area by a physical activation method, comprising the steps as follows: firstly, coconut shell is carbonized under high temperature; subsequently, the crushed and screened carbonization material is arranged in a microwave radiation device; by controlling activation temperature and adjusting activation time and activation gas flux, the raw material is activated so as to gain the grain active carbon product with the specific surface area more than 2200m<2> / g. The method utilizes high-temperature carbonization to improve the micro-pore structure of the carbonization material of the coconut shell, is beneficial for improving the orderly structure of the carbonization material of the coconut shell, reduces the burning of the carbon during the carbonization process and improves the yield of the active carbon product; the prepared active carbon is the grain active carbon, and the applicable range is improved.

This invention relates to acidity zeolite catalyst used for glycerol dehydration to perpare acrolein and the reaction craft. Glycerine directly dehydrate to generate acrolein under the condition of acidity zeolite catalyst, 200 to 500deg temperature, 0.001 to 3.0MPa pressure and 0.1 to 100.0h - 1 liquid airspeed, at the same time produce byproduct pyruvic alcohol. The raw material raw glycerine could be mixed liquor of water solution, alcosol, fatty acid ester solution at any ratio.

The invention discloses a silicone fireproof sealant for construction and a preparation method thereof. The preparation comprises the steps of adding alpha, omega-dihydroxy polysiloxane, a filler, an inorganic flame retardant and a nitrogen system flame retardant into a kneading machine, carrying out dehydration at the temperature of 100-180 DEG C and the vacuum degree of 0.06-0.1MPa for 0.5-4 hours, cooling, and then preparing a base material. The base material, polydimethylsiloxane, an inorganic pigment, a crosslinking agent, a silane coupling agent and a catalyst are added into a planetary mixer at the room temperature, keeping the vacuum degree at 0.06-0.1MPa, stirring at the speed of 20-80 r / min, carrying out reaction under stirring for 0.5-6 hours, and preparing the silicone fireproof sealant for construction with no pollution to the base material, flame retardance and excellent adhesion and storage stability. The inorganic flame retardant and the nitrogen system flame retardant are in synergistic flame retardance, and the silicone fireproof sealant can effectively reduce the adding amount of the inorganic flame retardant and greatly improve the mechanical processing performance of a product under the situation of achieving the equivalent flame retardant grade FV-0.

The invention provides an acidic chemical and mechanical polishing composition. The pH value of the acidic chemical and mechanical polishing composition is 2-7, and the acidic chemical and mechanical polishing composition comprises 1-20% by weight of abrasive material, 0.5-10% by weight of oxidant, 0.1-10% by weight of complexing agent, 0.001-1% by weight of corrosion inhibitor, 0.001-5% by weight of organic film-forming auxiliaries and the balance of pH regulator and deionized or distilled water, wherein the abrasive material is of colloidal silica sol after modification in the special step, and the average particle size is of 10-200nm. According to the chemical and mechanical polishing composition provided by the invention, the abrasive material is refined and modified; by using the method, the stability of the abrasive material in polishing slurry can be effectively upgraded, and polishing removal rate and surface roughness degree are respectively optimized to a certain extent; and the unique adding effect of the organic film-forming auxiliaries can well balance the strength of chemical corrosion action and the strength of mechanical grinding action, and achieve the effects of improving polishing removal efficiency and performing global planarization.

The invention relates to a green, economical and sustainable method for preparing nanocellulose fibrils. The preparation method comprises the following steps that 1, a cellulose raw material is added to a citric acid solution to be heated, stirred and hydrolyzed; 2, treated cellulose and hydrolysate are separated through methods of centrifugal sedimentation and the like, and precipitated cellulose is centrifugally washed with water multiple times and diluted into a cellulose suspension; 3, the separated hydrolysate can be directly recycled at least once, citric acid is recovered from the recycled hydrolysate, and the citric acid obtained through recovery can be recycled continuously; 4, the natural structure of the cellulose suspension obtained in the second step is further destroyed through a high pressure homogenizer or ultrasonication or physical mechanical treatment of a disc mill, and the colloidal nanocellulose fibrils are obtained. According to the method for preparing the nanocellulose fibrils, a catalyst is not adopted, the reaction condition is relatively mild, the reaction is easy to control, operation is easy, and the method is friendly to environment.

Process for the production of a hydrogen rich gas without formation of hydrocarbons comprising water gas shift conversion of a gas containing carbon monoxide and steam at a temperature of between 400° C. and 850° C. in the presence of a catalyst, which catalyst comprises one or more of the elements Mg, Mn, Al, Zr, La, Ce, Pr, and Nd, being able to form basic oxides, and mixtures thereof.

The invention discloses copper welding paste for braze welding, a preparation method of the copper welding paste for braze welding and the application of the copper welding paste for braze welding. The copper welding paste for braze welding comprises 67wt%-92wt% of brazing filler metal, 8wt%-33wt% of pasty fluid and brazing flux of which the mass is 0-5% that of the brazing filler metal, wherein the brazing filler metal comprises Cu and / or one or more types of Cu alloy, the brazing flux comprises any one or more than two components of CaF2, KF, NaF, BaF2, sebacic acid, succinic acid, lauric acid and boric acid, and the pasty fluid comprises a solvent, a thickening agent, a rheological agent, an antifoaming agent and an activating agent. When the copper welding paste prepared through the method is applied before braze welding, the copper welding paste has good thixotropy, collapse resistance and fluidity; after braze welding, a part has high joint strength, a weld joint is plump and free of residues, and the part does not need cleaning; the copper welding paste can be widely applied to welding automobile pipe fittings, copper-based heat dissipation assemblies and stainless steel parts.