5766 results about "High selectivity" patented technology

The invention belongs to the technical field of CO catalytic oxidation, and particularly discloses a method for synthesizing a CuO / CeO2 catalyst through a rapid fluid mixing method and application thereof.The method comprises the steps that a copper salt solution A and a cerium salt solution B are put into a rapid fluid turbulence mixing reactor, the flow speed is controlled, a catalyst precursor is prepared after product treatment, the catalyst precursor is put into a muffle furnace, air is introduced for calcination, and the catalyst is prepared; and high selectivity and high conversion rate in CO oxidation reaction in a hydrogen-rich environment are realized. The method provided by the invention also improves the traditional MOF synthesis method, adopts water as a solvent, and reduces the synthesis conditions. The prepared catalyst has high conversion rate and selectivity, the CO conversion rate at 90 DEG C reaches 100%, and the corresponding selectivity is 100%.

The present disclosure relates to high selectivity doped hardmask films, as well as methods of providing and using such films. In particular examples, the high selectivity doped hardmask film can be employed as a hardmask, an intermediate layer, or a coverage layer.

The invention discloses a self-powered biosensor for double-signal detection of sugarcane pokkah boeng disease, the self-powered biosensor comprises an anode, a cathode and an electrolyte, the anode is a CuCo-MOF / AuNPs / GOD biological anode, the cathode is a CuCo-MOF / AuNPs / DNA chain biosensor, and the electrolyte comprises glucose, MB and a PBS buffer solution. According to the self-powered biosensor, analysis is carried out through two non-interfering modes of electrochemical detection and colorimetric detection, and whether a detection result is a false positive signal or not can be effectively verified. An external power supply is not needed, and real-time outdoor detection can be realized. The material source is wide, the assembly process is simple, and accurate and rapid detection can be realized. The method has the advantages of high sensitivity, good selectivity and real-time detection, and can be used for accurately detecting the sugarcane pokkah boeng rot.

The invention relates to the technical field of catalysts, and discloses a preparation method and application of a copper-based metal-organic framework catalytic material.The preparation method comprises the following steps that S1, cuprous salt, N, N '-bis (5-aminonicotinyl) naphthalimide and a solvent are mixed, and a mixture is obtained; s2, heating the mixture to a reaction temperature, carrying out a constant-temperature reaction, and cooling to obtain a crystal; and S3, washing and drying the crystal to obtain the copper-based metal-organic framework catalytic material. According to the preparation method of the copper-based metal-organic framework catalytic material provided by the invention, N, N '-bis (5-aminonicotinyl) naphthalimide is used as an organic ligand to prepare the copper-based metal framework Cu-PTD with N / O co-coordination, and the copper-based metal framework Cu-PTD has relatively strong electrocatalytic carbon dioxide reduction and electron transfer capabilities; and the catalyst has relatively high selectivity on electrocatalytic carbon dioxide reduction products.

The invention discloses a copper-based nano-enzyme, a preparation method thereof and application of the copper-based nano-enzyme in organophosphorus pesticide detection, and belongs to the technical field of pesticide residue detection. The copper-based nano-enzyme has a netted-like structure, a high specific surface area and many active sites, the valence state of a copper element is zero-valence Cu, Cu < + > and Cu < 2 + >, the copper-based nano-enzyme has high peroxidase-like activity and laccase-like activity, the detection limit is low, and glyphosate can be sensitively detected; and glyphosate, glufosinate-ammonium and isazofos can be well distinguished from six organophosphorus pesticides with medium concentration, and the method has high selectivity. The nano enzyme provided by the invention is prepared from ammonium citrate and copper nitrate in an N, N-dimethylformamide (DMF) solution by using a solvothermal method; the preparation process of the nano enzyme is simple.

The invention belongs to the field of electrochemical biosensors, discloses a preparation method of an electrochemical biosensor capable of being used for multi-mode sweat detection, and particularly provides a single-electrode multifunctional arrangement method in a three-electrode system. A sensor material with high sensitivity and high selectivity is prepared, then the sensor material is printed through screen printing and assembled into a portable device to achieve simultaneous detection of multiple biomarkers in sweat, and the preparation method comprises the steps of selection and modification of an electrode material, sensor assembly and integration of a signal acquisition and analysis system. Through innovative material design and process optimization, the sensor not only can acquire information of various biomarkers in sweat in real time, but also can provide reliable data analysis, and shows excellent long-term stability and anti-interference capability in practical application. The technology provides an effective and reliable solution for real-time health monitoring.

The invention discloses a conformal antenna component manufacturing system and method based on cross-scale space-time frequency shaping femtosecond laser, and belongs to the technical field of micro-nano machining. The system comprises an ultrafast laser excitation module, a laser pulse time / frequency shaping module, a pulse detection module, an online monitoring module and a focusing high-speed scanning galvanometer module. By means of the system, high-selectivity, large-breadth and three-dimensional precision machining of conformal antenna circuit patterns is achieved, and it is ensured that a substrate is not damaged. The femtosecond laser time-frequency shaping technology is combined in the machining process, layered scanning and accurate removal of the heterogeneous multilayer structure are achieved through an adjustable pulse sequence and a high-speed galvanometer system, and the problems that in the prior art, materials are damaged, and the size precision is low are solved. The device further integrates an on-line depth monitoring function, the machining efficiency and the forming quality are remarkably improved, and the device is suitable for high-precision patterning machining of complex curved surface heterogeneous thin film materials.

The invention belongs to the technical field of ethylene oligomerization catalysis, and discloses a catalytic system for ethylene selective oligomerization and a preparation method and application thereof, and the catalytic system comprises a carbon bridge bidentate phosphine chromium catalyst, an organic boron auxiliary agent and an aluminum-containing activator in a molar ratio of 1: (1-50): (100-1500). The carbon-chromium catalyst is prepared by the following steps: reacting CrCl3 (THF) 3, a ligand and CH2Cl2 under stirring, filtering, and carrying out post-treatment to obtain the catalyst, the catalyst and the aluminum-containing activating agent are uniformly mixed, and then the organic boron auxiliary agent is added and stirred. The catalyst system constructed by the carbon bridge bidentate phosphine chromium catalyst, the organic boron auxiliary agent and the aluminum-containing activating agent realizes ethylene selective oligomerization. The catalytic system can realize high-efficiency and high-selectivity preparation of 1-hexene and 1-octene under the condition that aluminoxane co-catalysts such as MAO and MMAO are not adopted, the catalytic activity is high, the reaction initiation is rapid, the operation is stable, and the repeatability is good.

The invention discloses a method for simultaneously detecting ergothioneine, ergosterol, ergosterol peroxide and lentinine in lentinus edodes, and belongs to the technical field of measurement of active ingredients of the lentinus edodes. The method comprises the following steps: detecting a shiitake mushroom extracting solution by adopting an ultra-high performance liquid chromatography-tandem mass spectrometry mode, wherein a chromatographic column is an HILIC or C18 chromatographic column; the mobile phase A and the mobile phase B are an aqueous solution containing formic acid and a methanol or acetonitrile solution containing formic acid respectively; the mass spectrum conditions comprise an electrospray ionization source; a positive ion multiple reaction monitoring mode; the ion spraying temperature is 315-325 DEG C; the temperature of the ion transmission tube is 320-330 DEG C; and the ion spraying voltage is 3500 V to 3700 V. The method has the characteristics of high sensitivity, high selectivity and high accuracy, and is suitable for quantitative detection of ergothioneine, lentinine, ergosterol peroxide and ergosterol compounds in shiitake mushrooms.

The invention relates to the technical field of preparation of lithium adsorbents, in particular to a fluorine-containing polymer microsphere adsorbent for selectively adsorbing lithium as well as a structure regulation and control method and an application method thereof, and solves the technical problems of poor selectivity, low adsorption capacity, high preparation cost and complex preparation process of an existing lithium adsorbent. The fluorine-containing polymer microsphere adsorbent material based on the emulsion polymerization method is synthesized, operation is easy, cost is low, synthesis efficiency is high, large-scale preparation can be achieved, and high selectivity and adsorption capacity are achieved. The adsorbent material can efficiently and selectively adsorb lithium ions in lithium-containing wastewater containing a large number of coexisting monovalent and high-valent competitive ions, the adsorbability of the adsorbent material to the lithium ions is far better than that of the adsorbent material to ions such as sodium, potassium, cobalt, manganese and the like, and the adsorption capacity of the adsorbent material to the lithium ions can reach 38.5 mg / g at most.

An IPD high-selectivity band-pass filter based on a weak coupling transformer technology comprises an LC parallel resonance circuit, an LC series resonance circuit, an LC parallel resonance circuit and a fourth capacitor C4, and inductors in the LC parallel resonance circuit and inductors in the LC parallel resonance circuit have a weak transformer coupling relation; the coupling coefficient required by the weak coupling transformer provided by the invention is very small and can be realized in a mode of adjacently placing metals on the same layer, so that the structural complexity of the filter is effectively reduced; the band-pass filter is based on an IPD technology, an extra decoupling equivalent inductor is introduced through a weak transformer coupling technology, the extra decoupling equivalent inductor and a parallel capacitor which is connected between the input end and the output end of the filter in a bridging mode form a new resonance path, and a transmission zero point is introduced into an upper stop band and a lower stop band of the filter respectively to improve the selectivity of the filter. According to the invention, the selectivity of the filter can be effectively improved on the premise of not additionally introducing an inductance element and not increasing the order of the filter.

The invention provides a process for preparing cyclohexane-1, 2-dioctyl phthalate, which adopts a loop reaction process to perform hydrogenation reaction of dioctyl phthalate, and comprises the following steps: under the condition of excessive hydrogen atmosphere, firstly putting a catalyst, a solvent and a target product into a reaction tank to form a circulating material; when reaction liquid passes through the Venturi ejector, hydrogenation reaction can be carried out, the Venturi reactor can provide a high gas-liquid mixing ratio, the reaction rate is high, and the production efficiency is high. The catalyst and the reaction mixed liquid are separated by combining a membrane separation process, so that the catalyst is recycled, and the cost is reduced. The target product is added into the system to maintain material balance in the system, so that stable production is ensured. Compared with the traditional technical process, the method has the advantages that the reaction time is shortened, the energy consumption of the device and the investment cost are reduced, the high conversion rate of reactants and the high selectivity of target products can be kept, the operation period of the device is long, and continuous and stable production is realized.

The invention relates to a method for producing diacetylmonoxime with high selectivity. The method comprises the following steps: by taking a catalyst, a solvent, butanone, ammonia water and a hydrogen peroxide aqueous solution as raw materials, carrying out ammoximation reaction, tert-butyl alcohol rectification, oxime-water separation and diacetylmonoxime rectification to obtain diacetylmonoxime; the catalyst is a boron-nickel-doped titanium silicalite molecular sieve, and the titanium silicalite molecular sieve, sulfydryl siloxane and ethanol are mixed to react, filtered and dried to obtain the sulfydryl titanium silicalite molecular sieve; the preparation method comprises the following steps: heating and reacting a mercapto titanium silicalite molecular sieve, allyl (cyclopentadienyl) nickel and sodium ethoxide; and finally adding (+)-IPC2B (allyl) borane, continuously reacting, and distilling to remove ethanol, thereby obtaining the product. The diacetylmonoxime prepared by the method disclosed by the invention has relatively high conversion rate and selectivity.

The invention belongs to the technical field of membrane separation, and aims to provide a preparation method and application of a covalent organic framework bipolar membrane. The method comprises the following steps: combining at least one amine, hydrazide or aldehyde monomer containing ionic groups with a monomer without ionic groups, and respectively synthesizing covalent organic framework COF nanosheets with positive charges and negative charges through a one-pot method under the condition of coexistence of an acid catalyst and an organic solvent; sequentially depositing COF nanosheets with positive and negative charges on the surface of the porous carrier by a hot solvent evaporation method; by constructing two COF separation layers with regular pore channels and opposite electrical properties, the covalent organic framework bipolar membrane with charge asymmetry is finally obtained. The product provided by the invention has high selectivity, can realize efficient separation of protons and metal cations, and significantly improves the extraction and recovery purity of hydrochloric acid; through charge repulsion and pore size screening mechanisms, separation of different anions can be further realized, and selective recovery of acid molecules is enhanced.

The invention belongs to the technical field of energy and petrochemical engineering catalysts, and particularly discloses a preparation method and application of a copper-zinc-aluminum spinel solid solution catalyst. The Cu-Zn-Al spinel solid solution catalyst is prepared by ball-milling copper, zinc and aluminum precursors and then roasting at 800-1200 DEG C in the air atmosphere, and the preparation method is simple, does not need a large amount of solvent, is less in wastewater and avoids the influence of other impurity ions. The Cu-Zn-Al spinel solid solution catalyst prepared by the invention is used for methanol reforming hydrogen production reaction, the methanol conversion rate is as high as 95.5%, the H2 selectivity in the product is 74.8%, and the CO selectivity is 0.76%, so that the Cu-Zn-Al spinel solid solution catalyst has high activity, high selectivity and good reaction stability.

The invention discloses a method for synthesizing deuterated olefin under catalysis of a palladium membrane by taking D2O as a deuterium source, and belongs to the technical field of synthesis of deuterated olefin building blocks. According to the method, a three-chamber electrolytic tank separated by a palladium membrane and an ion exchange membrane is used as a reactor, the palladium membrane is used as a working electrode, an electrolyte deuterium aqueous solution is used as an electrolyte, deuterium water is electrolyzed through a constant-potential electrolysis method, and formed active deuterium is transmitted to one side of an organic reaction taking absolute ethyl alcohol or cyclohexane as an organic solvent; and catalyzing an alkyne compound by using a palladium membrane modified by sodium thiophenol to perform reduction deuterization so as to synthesize a deuterated olefin compound with high selectivity, and further synthesizing a corresponding deuterated drug. The invention provides a green, efficient, high-universality and low-cost amplification synthesis method for synthesizing a deuterated olefin building block containing a functional group easy to reduce and hydrolyze, and the method has a wide application prospect.

The invention relates to the technical field of analysis and detection, in particular to a molecularly imprinted sensor for in-situ detection of epicatechin in plant leaves and a preparation and application method of the molecularly imprinted sensor. The molecular imprinting sensor for detecting epicatechin is prepared by assembling a zeolite imidazate skeleton-amide functionalized single-walled carbon nanotube composite material, amino-formyl imidazole modified reduced graphene and an MIP film on the surface of an electrode layer by layer. The high-selectivity and high-sensitivity detection on the target molecule epicatechin is realized. The technology can effectively reduce the detection cost, simplify the operation process and improve the performance of the sensor. Particularly, due to the introduction of the MIP, the sensor has the capabilities of in-situ detection and high-precision molecular recognition, can realize rapid and reliable quantitative analysis in a complex sample, and has a wide application prospect.

The invention relates to the technical field of developing, in particular to a high-selectivity developing solution for alkali-soluble photoresist and a developing process. The problem that the developing effect and the dissolving effect are poor in the developing process is solved. The developing solution is prepared from the following synthetic raw materials: a modified active agent, a weakly alkaline mixture, a modified defoaming agent, a composite dispersing agent, an improved chelating agent, an organic solvent and deionized water. According to the invention, the dissolution rate of the unexposed photoresist is improved by preparing the modified active agent and the weakly alkaline mixture, and the high selectivity of the developing solution is embodied; the defoaming performance of the developing solution is improved by preparing the modified defoaming agent and adding the composite dispersing agent; the developing effect of the material can be improved through the synergistic effect of the improved chelating agent and the organic solvent in the developing solution; the developing solution is applied to the developing process, and the pH value and process parameters are adjusted, so that the developing effect and efficiency of the material are improved.

The invention discloses a preparation method of a low-salt-permeability bipolar membrane, and belongs to the field of bipolar membrane preparation, aiming at the inherent characteristic that in a tape casting process, an anion membrane layer is difficult to form a cross-linked structure, the high selectivity of the anion membrane layer and a good middle interface layer formed by an anion membrane layer and an anion membrane layer are separately designed, and after the surface of an cation membrane layer is coated with a water dissociation catalyst, the cation membrane layer is separated from the anion membrane layer. Coating a negative film polymer solution to form a relatively thin negative film layer, then attaching a high-selectivity negative film, and fixing all the film layers together by using a hot melting process to form a whole body; the first anion membrane layer is a thin anion membrane layer formed by coating, the key point of the design is that the bipolar membrane is low in water dissociation voltage, the second anion membrane layer is a high-selectivity anion membrane layer, and the membrane layer ensures low salt permeation of the bipolar membrane; the positive membrane layer, the first negative membrane layer and the second negative membrane layer are all designed to be fused together through a hot melting process, and the prepared bipolar membrane has low salt permeability and low water dissociation voltage.

A method for preparing a self-supporting composite nanofiltration membrane is provided. A porous graphene-based two-dimensional sheet material is prepared by taking amino graphene quantum dots as the main body and subjecting them to an interfacial polymerization reaction with polyacyl chloride, and then the porous graphene-based two-dimensional sheet material is encapsulated in-situ with polyamide by an in-situ encapsulating technology to prepare a self-supporting porous graphene / polyamide separation layer with excellent permeability and high selectivity.

The invention discloses a multi-component gas detection device and method based on a metasurface quasi-continuous domain bound state. The advanced nanometer manufacturing technology and the deep learning algorithm are adopted, and high-precision, high-sensitivity and high-selectivity gas detection is achieved. According to the invention, the metasurface array with specific design is utilized, and the quasi-continuous domain bound state in the middle-infrared band is realized by accurately regulating and controlling the geometric parameters and material characteristics of the microstructure, so that excellent optical response is obtained. In combination with a deep learning algorithm, complex spectral information is converted into accurate gas composition and concentration information, and a reliable solution is provided for the fields of environmental monitoring, industrial production, safety monitoring and the like.

The invention discloses an aptamer sensor based on a bimetallic organic framework nano-enzyme as well as a preparation method and application of the aptamer sensor. According to the aptamer sensor, the catalytic activity of the bimetallic organic framework nano-enzyme is simply and conveniently regulated through an aptamer, so that colorimetric and photo-thermal dual-mode detection on kanamycin is realized; the aptamer can regulate and control the activity of the bimetal organic framework nano-enzyme through co-incubation without immobilization, the aptamer falls off from the surface of the nano-enzyme to generate signal response by utilizing the high selective affinity of kanamycin to the aptamer, and a temperature signal is generated by further utilizing the photothermal effect of an oxidation product. Therefore, the comparison of color and photo-thermal double-signal detection results is realized, and the credibility of the detection results is improved.

The invention discloses a method for extracting and purifying flavone in litsea coreana through an ultrasonic-assisted eutectic solvent, and belongs to the technical field of green processing of natural products. The invention provides a method for efficiently preparing litsea coreana flavone by integrating computer prediction, green solvent extraction and resin purification technologies. The method comprises the following steps: firstly, calculating and screening a deep eutectic solvent system with the highest affinity with the litsea coreana flavone on the basis of a COSMO-RS theoretical model, then coupling the optimized DES with an ultrasonic-assisted extraction (UAE) technology, and through the synergistic effect of the DES and the UAE technology, remarkably improving the extraction rate of the litsea coreana flavone and furthest keeping the biological activity of a target component; then, a macroporous resin dynamic adsorption-desorption purification process is linked, so that high-selectivity enrichment and impurity removal of the flavonoid compounds in the crude extract are realized, a high-purity product is obtained, and a complete process route from intelligent screening, efficient extraction to precise purification is finally formed.

The invention discloses a polycrystalline silicon etching method, which comprises the following steps of: firstly, carrying out a polycrystalline silicon etching process for the first time, and carrying out a certain amount of transverse etching; an isotropic dry etching process is adopted, so that the polycrystalline silicon has transverse etching. And then a polycrystalline silicon etching process with a high selection ratio is carried out, and an anisotropic etching process is adopted to ensure that the polycrystalline silicon on the surface is etched cleanly. According to the etching process, a step-by-step etching process method is adopted, the isotropic etching process is firstly carried out to control the etching amount of transverse etching, then the anisotropic etching method and the high-selectivity etching method are adopted to carry out etching of different etching amounts on areas with inconsistent feature sizes, and accurate etching of polycrystalline silicon is guaranteed.

The invention discloses an ion exchange membrane based on an intrinsic microporous polymer, and a preparation method and application thereof, and belongs to the technical field of high polymer materials. According to the application, 1, 3, 5-tri (4-aminophenyl) benzene (TAPB) and dimethyl formal are taken as polymeric monomers, a polymer with intrinsic sub-nano micropores and a corresponding homogeneous ion exchange membrane are prepared by utilizing the structural characteristics of rigidity and distortion of the TAPB, an ion transmission channel is formed by a unique micropore structure, and the sub-nano micropores have a size screening effect, so that the ion exchange membrane can be used for preparing the ion exchange membrane. The selective separation of monovalent / multivalent anions can be realized; after quaternization treatment is carried out on the membrane and a positively charged group is introduced, the positively charged group has a strong electrostatic repulsion effect, and selective separation of monovalent / multivalent cations can be realized, so that the polymer ion exchange membrane disclosed by the invention can be simultaneously applied to an acid-base recovery process, and has the characteristics of high selectivity, high permeation flux and stable long-term operation.

The invention discloses a method for preparing 1, 5-pentanediol by catalyzing furfural conversion, and belongs to the technical field of biomass conversion. The method for preparing 1, 5-pentanediol by catalyzing furfural conversion comprises the following steps: furfural is taken as a raw material, ethanol is taken as a solvent, hydrogenation ring-opening reaction is carried out under the action of a hydrogenation catalyst, 1, 5-pentanediol is obtained, the hydrogenation catalyst comprises the following raw materials in percentage by mass: 0-1 wt% of Fe, 1-10 wt% of Cu, 20-40 wt% of Co and 50-80 wt% of La, and the content of Fe is not 0. The metals in the hydrogenation catalyst have a synergistic effect, so that furfural can be efficiently and highly selectively converted into 1, 5-pentanediol. According to the method, trace Fe is added into the hydrogenation catalyst, so that the problem that byproducts such as tetrahydrofurfuryl alcohol are generated from furfural is solved, and the selectivity of 1, 5-pentanediol is greatly improved.

The invention relates to the field of catalysts, and discloses a nitrile rubber hydrogenation catalyst and a preparation method and application thereof.The nitrile rubber hydrogenation catalyst comprises a carrier and an active metal component loaded on the carrier, and the carrier comprises a composite metal oxide and silicon dioxide; wherein the composite metal oxide is M < 1-x > Al < x > O (x + 2) / 2, x is 0.1-0.4, and M is selected from at least one of Mg, Ni and Zn; wherein the active metal component is Os; wherein in terms of metal elements, the content of the active metal component is 0.01-5wt% on the basis of the total weight of the catalyst. The catalyst provided by the invention is used for preparing hydrogenated butadiene-acrylonitrile rubber by hydrogenation of butadiene-acrylonitrile rubber, and has high selectivity and hydrogenation degree.

The invention provides a high-molecular adsorption material with high selectivity on platinum group metals as well as a preparation method and application of the high-molecular adsorption material, and belongs to the technical field of material science. Comprising the following steps: (1) preparing a methanol solution containing platinum group metal ions, and adding a functional monomer mixture and modified graphene oxide to form a pre-assembled compound; (2) adding a cross-linking agent and an initiator, removing oxygen, and polymerizing to obtain a polymer; and (3) grinding the polymer, eluting metal ions, washing to be neutral, and drying. The high-molecular adsorption material provided by the invention takes modified graphene oxide as a support body, template molecules and specific functional monomers (4-vinylpyridine and 2-mercaptobenzimidazole) are combined to form a pre-assembled compound, then a cross-linking agent and an initiator are added, recognition sites are fixed through cross-linking polymerization, and finally, the high-molecular adsorption material is obtained after the template molecules are eluted. The adsorbent is high in adsorption rate, capable of specifically adsorbing platinum group metal, good in stability and reproducibility and capable of being repeatedly used.

The invention discloses a preparation method and application of a magnetic enrichment composite SERS (Surface Enhanced Raman Scattering) detection chip, gold nanoparticles are electrostatically adsorbed on the surface of a magnetic ferroferric oxide nanoring, the prepared material is subjected to cyclodextrin modification, nanogaps among the gold nanoparticles form hot spots, a local electromagnetic field enhancement effect is generated, and the magnetic enrichment composite SERS detection chip is obtained. The cyclodextrin molecules adsorb PAHs in the environment through a hydrophobic effect and are fixed in an electromagnetic field enhancement area, amplification of Raman signals is achieved, the magnetic material serves as a carrier, aggregation of gold nanoparticles can be effectively prevented, SERS signals can be further enhanced through a magnetic enrichment effect, and therefore, the method has the advantages that the method is simple, and the application prospect is wide. The high-sensitivity and high-selectivity detection of PAHs in the tail gas of the engineering machinery vehicle is realized by constructing the magnetic composite SERS nano sensing chip.

The invention discloses an electrochemical detection method of dopamine, and belongs to the technical field of analysis. According to the method, SnS2 quantum dots are loaded on Zn-MOF and modified on an electrode, then gold nanoparticles and a sulfydryl-containing dopamine aptamer single chain are sequentially fixed on the electrode, an Apt / AuNPs / SnS2QDs (at) Zn-MOF / GCE composite electrode (in an open state) is formed, an electrochemical signal of the composite electrode is greatly improved, and based on specific recognition between dopamine and an aptamer chain, the electrochemical performance of the composite electrode is improved. A large cavity of Zn-MOF is used for packaging SnS2 quantum dots with excellent electrochemical properties, electrochemical signal amplification is achieved, when a target object dopamine exists, dopamine can quench an ECL signal, an electric signal is obviously reduced (in a closed state), and therefore a linear relation between the change of the electrochemical signal and the concentration of dopamine is constructed, and the electrochemical property of the electrochemical signal is improved. Therefore, high-sensitivity and high-selectivity detection of dopamine is realized.