7656 results about "Fluorine containing" patented technology

The invention relates to a battery monomer, a battery device and a power utilization device, the battery monomer comprises an electrode assembly and an electrolyte, and the electrode assembly comprises a positive pole piece and a negative pole piece; the positive pole piece comprises a positive pole current collecting part and a positive pole film layer; the positive pole film layer comprises lithium-containing phosphate with an olivine structure; the negative pole piece comprises a negative pole current collecting part and a negative pole film layer, and the negative pole film layer comprises a carbon-based material; the electrolyte comprises a carboxylic ester solvent, a first additive and fluorine-containing lithium sulfimide, and the mass content of the carboxylic ester solvent is 8%-60%; the total mass content of the first additive is 2.5%-10%, the first additive comprises 1, 3-propane sultone with the mass content larger than or equal to 0, an ethylene carbonate derivative with the mass content larger than or equal to 0 and vinylene carbonate with the mass content larger than 0, and the ethylene carbonate derivative comprises a compound shown in the formula A; the mass content of the fluorine-containing lithium sulfimide is 4%-8%. According to the invention, the rapid charging performance and the cycle performance of the battery monomer can be improved. # imgabs0 # formula A

The present invention discloses a water-based emulsion of PHA, PBAT and PVOH and its application in paper-based barrier coatings. This emulsion is prepared by first melt-blending PHA and PBAT at 150-170 °C and then dispersing them into an aqueous PVOH solution at 80-95 °C. Plasticizers, cross-linking agents and surfactants can be added to improve the performance. After coating on paper and drying at 80-150 °C, a barrier film with a Cobb value of 10-15 g / m² and a Kit ≥ 10 grade is formed. Compared with traditional PE film laminating or fluorine-containing coatings, this system is more environmentally friendly and recyclable; PVOH dissolves in pulping water, PHA and PBAT are easily separated, and fibers can be efficiently recovered; in composting, soil and marine environments, PHA and PBAT have extensive biodegradability and are superior to PLA which is difficult to recycle and requires industrial composting. It is applicable to food, industrial, special packaging and agricultural paper products.

The invention discloses a preparation method of a fluorine-containing carbazole phosphonic acid compound, which solves the technical problems of harsh reaction conditions, high raw material price and low yield in the existing preparation process, 4-trifluoromethoxyaniline and 4-trifluoromethoxyiodobenzene are used as initial raw materials, and Ullmann reaction is performed under a solvent-free condition to obtain 4, 4 '-difluorocarbazole phosphonic acid. The preparation method comprises the following steps: taking 3, 4 '-bis (trifluoromethoxy) diphenylamine as a raw material, carrying out palladium acetate catalytic oxidation cyclization to obtain 3, 6-bis (trifluoromethoxy) carbazole, reacting the 3, 6-bis (trifluoromethoxy) carbazole with 2-bromoethyl dimethyl phosphonate to obtain N-(2-ethyl dimethyl phosphonate) 3, 6-bis (trifluoromethoxy) carbazole, and finally hydrolyzing to obtain the N-(2-ethyl phosphonate) 3, 6-bis (trifluoromethoxy) carbazole. The reaction process is simpler to operate, the yield is guaranteed, and the method is suitable for large-scale production. In the preparation method disclosed by the invention, a solvent is not required to be used in multiple steps, the reaction is performed under a solvent-free condition, and the preparation method is high in safety and environment-friendly.

A production method for an aqueous dispersion according to the present invention comprises polymerizing a first monomer that includes tetrafluoroethylene in the presence of a compound represented by formula (X) and a polymerization initiator under conditions in which an aqueous medium is present but an emulsifier that includes fluorine atoms is substantially absent to produce an aqueous dispersion that includes particles of a first fluorine-containing polymer that has an average particle diameter of no more than 500 nm and does not have a melting point.　Formula (X): C(X1)(X2)=C(X3)-L-Z. In formula (X), X1, X2, and X3 are each independently a hydrogen atom, a fluorine atom, a perfluoromethyl group, or an alkyl group, L is a single bond or a divalent linking group, and Z is an anionic group or a salt of an anionic group.

The invention provides a positive electrode, a low-temperature electrolyte, a low-temperature sodium-ion battery and a preparation method and application of the low-temperature sodium-ion battery, and belongs to the technical field of battery materials. The low-temperature sodium ion battery comprises a positive electrode, a negative electrode and a low-temperature electrolyte, wherein the positive electrode comprises a positive electrode active material, a binder, sodium salt containing fluorine and sulfur and conductive carbon; the positive electrode is improved by adding sodium salt containing fluorine and sulfur, sulfur / fluorine rich in anion derivatives can be formed on a contact interface of the positive electrode and an electrolyte to form a firm SEI film, the internal resistance of the battery is further reduced, and the coulombic efficiency of the battery during charging and discharging at normal and low temperatures is improved. The low-temperature electrolyte comprises an ester solvent and an ether additive, by adding the ether solvent, the physicochemical property of the electrolyte and the composition of an SEI film on a contact interface of an electrode and the electrolyte are optimized, the viscosity of the electrolyte at low temperature is reduced, the ionic conductivity is improved, and formation of the SEI film rich in sodium fluoride on the surface of a negative electrode can be promoted; and thus, the problem of low coulombic efficiency of battery charge-discharge cycle at low temperature is solved.

Monoorgano tin trialkoxide compounds having chemical formula R'SnX3 and containing less than about 5 mol% R'2SnX2are described. R' is an optionally substituted organic substituent having about 1 to about 20 carbon atoms and each X is independently ORf, wherein Rf is a fluorinated organic substituent having about 1 to about 20 carbon atoms. Methods for synthesizing and purifying these compounds are also provided. The monoorgano tin compounds may be used for the formation of high-resolution EUV lithography patterning precursors and are attractive due to their high purity and minimal concentration of diorgano tin impurities.

Disclosed in the present invention is a process for deeply removing fluorine from wastewater by means of an induced crystallization method in sludge backflow. The process comprises the following steps: step 1. placing lime powder and deionized water in a seed crystal reactor to prepare lime milk and at the same time putting a calcite seed crystal into the seed crystal reactor; step 2. introducing high-concentration fluorine-containing acidic wastewater into a reactor; and step 3. introducing the lime milk obtained in step 1 into the reactor in step 2 to undergo a reaction, wherein during the reaction, the pH value of the mixed solution is controlled to remain neutral. The present invention is based on a high-density sludge method (HDS process). By utilizing the HDS process, the advantages of effectively improving the sludge density, reducing the lime consumption, facilitating the operation, and enabling the water quality of an effluent to be more stable are realized. In conjunction with induced crystallization technology, an induced crystallization process in a high-density sludge backflow is formed to promote precipitation and crystallization and allow sedimentation to proceed quickly, thereby shortening the process time and overcoming the defects of traditional lime precipitation methods.

The invention provides a double-layer polymer solid electrolyte, a preparation method thereof and a lithium ion battery, and belongs to the technical field of solid electrolyte manufacturing. The first polymer solid electrolyte layer comprises the following raw materials in parts by weight: 4-30 parts of a first reactive monomer A, 5-25 parts of a first reactive monomer B, a first cross-linking agent, a first photoinitiator, a first lithium salt, 1-20 parts of a first carbonic ester plasticizer and 20-45 parts of a nitrile plasticizer; the second polymer solid electrolyte layer comprises the following raw materials in parts by weight: 4-30 parts of a second reactive monomer A, 5-25 parts of a second reactive monomer B, a second cross-linking agent, a second photoinitiator, a second lithium salt, 1-35 parts of a second carbonic ester plasticizer and 10-35 parts of a fluorine-containing plasticizer; the double-layer polymer solid electrolyte has the advantages of relatively high ionic conductivity and compatibility of a high-voltage battery positive electrode and a low-voltage lithium metal negative electrode, so that the corresponding battery has relatively excellent cycle performance and relatively high capacity.

A fluoroelastomer production method including a step in which monomers A comprising a compound represented by CX1X2=CX3-L-Z, a cyano-group-containing monomer, and at least one compound selected from the group consisting of tetrafluoroethylene, fluorine-containing vinyl ethers, and fluorine-containing allyl ethers are polymerized in an aqueous medium under conditions that substantially no fluorine-atom-containing emulsifier is present.

The present invention relates to a lithium-ion battery diaphragm modified by high-temperature fluorine-containing liquid crystal polymer and polyvinylidene fluoride, and a preparation method and application thereof. The lithium-ion battery diaphragm of the present invention comprises a base diaphragm and a modified coating coated on the surface of the base diaphragm, wherein the modified coating comprises a fluorine-containing liquid crystal polymer and polyvinylidene fluoride. The present invention forms a modified coating by mixing and dissolving the two materials in a suitable solvent, which significantly improves the thermal stability, chemical stability, mechanical strength and ionic conductivity of the diaphragm, thereby improving the safety performance and cycle life of the battery.

The invention discloses a deep defluorination sludge backflow method and a defluorination agent preparation method, and particularly relates to the technical field of sewage treatment.The deep defluorination sludge backflow method comprises the following steps that fluorine-containing waste water is introduced into a mixing cavity through flow regulation for a continuous flow defluorination reaction, polyaluminum chloride, anhydrous calcium chloride and sodium chloride serve as the defluorination agents, the water inflow amount is added, and the defluorination reaction is completed; and reducing the pH value in the wastewater to a set threshold value. The sludge reflux rate is predicted through the effluent fluorine concentration and the sludge concentration, when the effluent fluorine concentration exceeds the set threshold value, the reflux rate is increased to ensure the fluorine ion removal efficiency, and when the sludge concentration exceeds the set threshold value, the reflux amount is reduced, and the situation that excessive sludge in the reaction tank affects the action of a medicament is avoided; the method has the advantages that the fluorine ions in the wastewater can be effectively removed and the wastewater can reach the emission standard by accurately calculating the chemical dosage, dynamically feeding back and adjusting and controlling the sludge backflow rate through real-time monitoring data and dynamically adjusting a regression model.

A method of fabricating a field effect transistor (FET) over a substrate that includes: growing a doped p-type semiconductor from a silicon nanosheet of the substrate, the substrate including a layer stack of alternating layers of the silicon nanosheet and a sacrificial layer, and a dummy gate formed over the layer stack, the layer stack including a trench exposing sidewalls of the layer stack, the doped p-type semiconductor and the sacrificial layer being separated by a dielectric inner spacer; removing the dummy gate; and etching the sacrificial layer selectively to the doped p-type semiconductor, the etching including exposing the substrate to a process gas including a fluorocarbon and a fluorine-containing etch gas in the absence of plasma.

The invention relates to the technical field of batteries, in particular to a lithium ion secondary battery. The lithium ion secondary battery comprises a negative plate and electrolyte, the negative plate comprises a negative current collector and a negative active layer located on at least one side surface of the negative current collector, the negative active layer comprises a first coating and a second coating which are arranged in the thickness direction of the negative plate, and the first coating is located between the negative current collector and the second coating; the second coating comprises first silicon carbon, and the sphericity degree of the first silicon carbon is 0.8-1; the silicon content of the first silicon carbon is 30%-60%; the average particle size of the first silicon carbon is R1, and R1 is more than 6 microns and less than or equal to 15 microns; the electrolyte comprises a fluorine-containing solvent and a nitrile compound, the fluorine-containing solvent comprises fluoroethylene carbonate and / or ethyl difluoroacetate, based on the total weight of the electrolyte, the content of the fluorine-containing solvent is w1, and w1 is larger than or equal to 30% and smaller than or equal to 70%; the content of the nitrile compound is w2, and 0.4% < = w2 < = 7%. The lithium ion secondary battery provided by the invention has good cycling stability and dynamic performance at high voltage and high temperature.

The invention relates to the field of oil well opening and killing fluid production, in particular to a solid-free well killing fluid for shale oil reservoir and a preparation method of the solid-free well killing fluid. The solid-free well killing fluid for the shale oil reservoir comprises the following raw materials in parts by mass: 50-70 parts of water, 10-30 parts of a density regulator, 3-6 parts of a copolymer tackifier, 1-3 parts of a dispersant, 3-7 parts of a filtrate reducer and 2-4 parts of a corrosion inhibitor. The copolymer tackifier is obtained by initiating copolymerization by taking acrylamide, a quaternary ammonium salt-containing monomer, an unsaturated silane coupling agent and polyethylene glycol diacrylamide as monomer free radicals, and the dispersing agent comprises gas-phase nano silicon dioxide and a fluorine-containing surfactant. Through reasonable compatibility of all the components in the formula, especially the copolymer tackifier, the effect that one agent has multiple functions is achieved, and meanwhile the high temperature resistance, the corrosion inhibition performance and the clay stability of the well killing fluid are improved.

The invention discloses a comprehensive treatment system and treatment method for industrial wastewater containing organic fluorine, electrocatalytic oxidation is carried out through an electrocatalytic oxidation reactor in a physicochemical treatment area, the toxicity of the wastewater containing fluorine is effectively reduced, chain scission is carried out on fluorine-containing organic matter macromolecules, the biodegradability of the wastewater containing fluorine is improved, and the treatment effect is good. The fluorine removal reaction sedimentation tank and the calcium removal reaction sedimentation tank are sequentially adopted to effectively remove most fluorine ions and excessive calcium ions, so that the fluorine ion concentration of the fluorine-containing wastewater reaches 10 mg / L, the biological reaction area and the rear fluorine removal guarantee area are arranged at the rear end, the fluorine ion concentration of effluent is further reduced, fluorine removal is effective, operation is easy and convenient, and the cost is low.

The embodiment of the invention provides a preparation method of a negative electrode active material, the negative electrode active material, a battery and equipment. Fluorine-containing gas is used as discharge gas, and discharge current is introduced into a plasma treatment device in the process of performing vibration dispersion treatment on a porous carbon substrate through the plasma treatment device; the fluorine-containing gas is used for carrying out plasma discharge treatment on the porous carbon matrix, so that the fluorine element provided by the fluorine-containing gas can react with carbon atoms on the surface of the porous carbon matrix to form chemical bonding, and the chemical bonding uniformity between the fluorine element and the carbon atoms on the surface of the porous carbon matrix can be improved; and the preparation cost of the negative electrode active material can be reduced, and the preparation efficiency of the negative electrode active material is improved, so that the battery capacity and the cycle performance of a secondary battery prepared from the negative electrode active material disclosed by the embodiment of the invention can be improved.

The invention relates to the technical field of heavy anti-corrosion coatings, in particular to a graphene enhanced epoxy modified organic silicon resin heavy anti-corrosion powder coating. The coating is prepared from the following components in parts by weight: 42 to 58 parts of epoxidized epoxy modified organic silicon resin, 0.8 to 2.5 parts of hydroxylated graphene, 6 to 11 parts of nano zirconium dioxide coated boron nitride, 2.5 to 5.5 parts of lanthanum iso-octoate-titanate composite coupling agent, 1.5 to 3.5 parts of bis (3-triethoxysilylpropyl) disulfide, 4 to 7 parts of polyhedral oligomeric silsesquioxane, 5 to 8 parts of curing agent, 0.8 to 1.8 parts of flatting agent and 0.4 to 0.9 part of defoaming agent. 2.5 to 4.5 parts of polyether-ether-ketone micro powder and 1.2 to 2.8 parts of fluorine-containing phosphate ester. According to the invention, the resin is modified through chemical bridging, the modified graphene and the nano-coated powder are matched to construct a synergistic enhancement system, and the interface bonding is optimized by the composite coupling agent. The coating is excellent in adhesive force, corrosion resistance and mechanical property, good in processing fluidity and high in aging resistance and thermal stability, solves the problem that a traditional product is short in performance, and meets the industrial requirement.

The invention relates to the field of lithium ion batteries, in particular to a fluorine-containing soluble polyimide adhesive special for a lithium battery and a preparation method and application of the fluorine-containing soluble polyimide adhesive. The fluorine-containing polyimide is prepared by reacting dianhydride and diamine, the dianhydride comprises 4, 4 '-hexafluoroisopropyl phthalic anhydride (6FDA), the diamine comprises 4, 4'-diaminodiphenylamine (NDA), and the structural formula of the fluorine-containing polyimide (6FDA-NDA) is # imgabs0 #. The electrode material prepared from the adhesive material obtained by the invention has the characteristics of low impedance and high adhesion, the assembled lithium battery shows higher magnification, and the adhesive material shows excellent magnification performance and adhesion performance when being applied to the lithium ion battery, especially a silicon-containing negative electrode lithium ion battery, and has a good industrial prospect.

The invention belongs to the technical field of new energy, and discloses a preparation method and application of a LiaMXb-based composite solid electrolyte membrane, and the preparation method comprises the following steps: S1, carrying out spray drying on a mixed solution in which a Li source, an M source and an ammonium salt are dissolved, placing the mixed solution in a crucible of which the bottom is paved with the ammonium salt, and annealing for 2-10 hours at 350-800 DEG C in an inert atmosphere to obtain a LiaMXb solid electrolyte; s2, mixing the LiaMXb solid electrolyte with a fluorine-containing monomer A and a dispersing agent, and performing spray drying to obtain electrolyte powder wrapped by the fluorine-containing monomer A; s3, ball-milling and uniformly mixing the electrolyte powder wrapped by the fluorine-containing monomer A, a lithium salt, a thermal curing agent and a monomer B in an inert atmosphere to obtain composite electrolyte powder; and S4, carrying out cold isostatic pressing and hot pressing curing on the composite electrolyte powder to prepare the LiaMXb-based composite solid electrolyte membrane. The prepared LiaMXb-based composite solid electrolyte membrane not only has excellent air stability, flexibility and machinability, but also has a continuous three-dimensional ion conduction path, and the assembled all-solid-state lithium battery has good electrochemical performance.

The invention provides a single-glass crystalline silicon photovoltaic module recovery method, and aims to solve the problems that fluorine film residues easily exist on a packaging adhesive film and fluorine-containing waste gas is discharged during subsequent pyrolysis of the packaging adhesive film after a back plate is removed by an existing physical disassembly, pyrolysis, separation and recovery process, and in addition, most welding strip coatings on the market contain lead, so that when the adhesive film is removed by pyrolysis, the lead-containing waste gas cannot be discharged during the subsequent pyrolysis of the packaging adhesive film. The lead element diffuses to pollute the battery piece, and the subsequent recovery difficulty is increased. Before the packaging adhesive film and the battery piece are shoveled off by a heat knife, a packaging adhesive film thinning process and a welding strip removing process are added. The residual backboard and the residual fluorine film can be removed together through the adhesive film thinning process, and the problem of fluorine-containing tail gas emission is solved; in addition, the lead-containing solder strip is removed before pyrolysis, and the solder strip is not subjected to a high-temperature process, so that pollution of lead elements to a battery piece is reduced; by optimizing the disassembling process, the breakage rate of the removed back glass is reduced, and the production yield of a production line is increased. The method is not only suitable for recycling of complete single-glass assemblies, but also suitable for recycling of broken single-glass assemblies, and the process applicability is high.

To provide a perfluoropolyether compound expressing excellent surface tension reduction performance, and expressing excellent foamability and foam stability not only during diluting fresh water but also during diluting sea water, and a fluorine-based surface active agent including the compound.SOLUTION: A perfluoropolyether dicarboxylic acid compound or a salt thereof is expressed by the following formula (1). In the formula, Rf1 represents a 1-4C perfluoroalkyl group. R1 represents a substituted or unsubstituted 1-10C hydrocarbon group. R2 represents a substituted or unsubstituted 1-6C hydrocarbon group. R3 and R4 are same or different and each represent a substituted or unsubstituted 1-4C hydrocarbon group. n is an integer of 0-5.SELECTED DRAWING: None

The invention provides an aluminum alloy brazing composite material, an Al-Zn-based pre-buried brazing flux plate blank and a preparation method of the Al-Zn-based pre-buried brazing flux plate blank and relates to the technical field of aluminum alloys, and the aluminum alloy brazing composite material sequentially comprises a non-brazing filler metal layer and a brazing filler metal layer; the non-brazing filler metal layer sequentially comprises a core layer and an Al-Zn-based pre-embedded brazing flux layer, and the Al-Zn-based pre-embedded brazing flux layer is arranged close to the brazing filler metal layer; the Al-Zn-based pre-embedded brazing flux layer comprises an Al-Zn alloy and a fluorine-containing brazing flux; the Al-Zn series alloy comprises 1-12 wt% of Zn element according to the mass fraction, the Al-Zn based pre-buried brazing flux layer has dislocation, and the dislocation density of the Al-Zn based pre-buried brazing flux layer is 2.5-4.0 * 10 < 14 > / m < 2 >; and the core layer and the Al-Zn-based pre-embedded brazing flux layer cannot be melted during brazing. The problem that the yield strength after welding is insufficient due to the fact that the proportion of the core layer in the aluminum alloy brazing composite material is reduced can be solved.

The invention relates to the technical field of intelligent materials, in particular to low-temperature-resistant magnetorheological fluid and a preparation method thereof.The low-temperature-resistant magnetorheological fluid is prepared from, by weight, 60-75 parts of magnetic particles; 3 to 15 parts of modified magnetic particles; 10-25 parts of low-temperature-based carrier liquid, which comprises 40-60% of silicone oil and / or mineral oil, 20-30% of synthetic ester and 10-20% of poly-alpha-olefin; 0.1 to 1.0 part of a dispersant; 0.5 to 2.0 parts of an anticoagulant; wherein the modified magnetic particles are prepared by coating magnetic particles with SiO2 aerogel and grafting the coated magnetic particles with fluorine-containing silane; the preparation method comprises the steps that magnetic particles are sequentially subjected to silane coupling agent treatment, aerogel deposition and fluorine-containing silane gas-phase grafting, and modified magnetic particles are prepared; carrying out ultrasonic mixing on the base carrier liquid and an anticoagulant at 40-60 DEG C for 30 minutes; adding magnetic particles, modified magnetic particles and a dispersing agent, dispersing by adopting a micro-jet homogenizer, and then carrying out gradient cooling treatment. The low-temperature-resistant magnetorheological fluid has the effect of improving the low-temperature-resistant performance of the magnetorheological fluid.

The invention discloses a battery monomer, a battery device and electric equipment, the battery monomer comprises a positive pole piece, the positive pole piece comprises a positive pole film layer, and the positive pole film layer comprises a lithium iron phosphate material and a lithium supplement agent; the negative electrode plate comprises a negative electrode film layer, the negative electrode film layer comprises a negative electrode active material, and the negative electrode active material comprises graphite; the isolating membrane is positioned between the positive pole piece and the negative pole piece; the electrolyte comprises lithium salts, the lithium salts comprise an organic lithium salt and an inorganic lithium salt, the organic lithium salt comprises at least one of fluorine-containing lithium sulfimide, fluorine-containing lithium oxalato borate and fluorine-containing lithium oxalato phosphate, the inorganic lithium salt comprises at least one of lithium hexafluorophosphate, lithium tetrafluoroborate and lithium fluorosulfonate, and the organic lithium salt comprises at least one of fluorine-containing lithium sulfimide, fluorine-containing lithium oxalato borate and fluorine-containing lithium oxalato phosphate. The mass ratio of the inorganic lithium salt to the organic lithium salt is (6-2): 1. As a result, a battery cell having both a long life and high power is obtained.

The invention relates to an in-situ polymerized flame-retardant perfluorogel electrolyte, a lithium metal battery and a preparation method, the in-situ polymerized flame-retardant perfluorogel electrolyte is prepared from a fluorinated organic solvent, a lithium salt, a fluorine-containing polymer precursor and a thermal initiator, and the fluorine-containing polymer precursor further comprises a fluorine-containing polymer and a cross-linking agent. Compared with the prior art, the composite material has a high electrochemical window and excellent flame retardant property, and can realize matching with a high-voltage high-nickel positive electrode at room temperature and stable circulation of a high-voltage lithium metal battery; the preparation method is simple, the interface performance is optimized, and large-scale preparation is easy to realize.

The invention discloses a crosslinked polyethylene reinforced high-strength insulating aerial cable, and belongs to the technical field of crosslinked polyethylene cable materials.The crosslinked polyethylene reinforced high-strength insulating aerial cable is prepared by the steps that hydroxyl is introduced to nano boron nitride powder, then amino is grafted through KH-550, nano alpha-Al2O3 powder is modified through gamma-glycidyl ether oxypropyl trimethoxy silane, and the cross-linked polyethylene reinforced high-strength insulating aerial cable is obtained; the preparation method comprises the following steps: preparing low-density polyethylene, compounding the low-density polyethylene with aminated nano boron nitride powder to form nano composite powder, improving the interface bonding force between the low-density polyethylene and the nano composite powder, carrying out melt blending on the low-density polyethylene and the nano composite powder to improve the dispersity of the nano composite powder in the low-density polyethylene, and carrying out nucleophilic acyl substitution reaction to obtain a fluorine-containing modified monomer. The nano boron nitride powder and the nano alpha-Al2O3 powder are subjected to a cross-linking reaction under the initiation action of an initiator and then coat the exterior of the thermal insulation layer, and the nano boron nitride powder and the nano alpha-Al2O3 powder are bridged through siloxane bonds to form a three-dimensional heat-conducting network, so that the heat resistance of the outer insulating layer is improved.

The present invention provides a method for manufacturing a dried ion exchange membrane that can manufacture a water electrolysis device having suppressed liquid leakage.　The method for producing a dried ion exchange membrane according to the present invention is a method in which a wet ion exchange membrane, which was obtained as a result of an ion exchange membrane that includes a fluoropolymer having ion exchange groups being wetted using a liquid medium, is dried to remove the liquid medium, thereby obtaining a dried ion exchange membrane, wherein the wet ion exchange membrane is dried from a state where the amount of the liquid medium adhering to the surface of the wet ion exchange membrane is 40 g / m2 to 600 g / m2.

An advanced defluoridation agent and a method for removing fluoride ion in fluorine-containing wastewater are provided. The advanced defluoridation agent includes 40-70wt% of polyaluminum sulfate, 0.3-30wt% of hydroxyapatite and deionized water supplemented to 100wt%. Using the advanced defluoridation agent of the present disclosure to treat fluoride-containing wastewater can achieve increased defluorination efficiency, reduced electrical conductivity, and reduced sludge content, and a better defluorination effect. The concentration of fluoride ions is lower than 15ppm after using the advanced defluoridation agent of the present disclosure.

The invention provides gel with a three-dimensional network structure, a preparation method of the gel and a lithium battery, and belongs to the technical field of lithium batteries. The gel provided by the invention comprises the following raw materials: polyethylene glycol dimethacrylate (PEGDMA) and / or a derivative thereof, a fluorine-containing carbonate compound, a cross-linking agent, a lithium salt, a flame retardant and an organic solvent. The PEGDMA and / or the derivative thereof and the fluorine-containing carbonic ester compound generate a three-dimensional network structure under the action of the cross-linking agent, the fluorine-containing carbonic ester compound can improve the interface stability between the gel and the electrode material, reduce the interface side reaction and improve the thermal stability of the gel, and the performance of the electrode material is improved. Meanwhile, the three-dimensional network structure has relatively high porosity and liquid absorption capacity, so that an ion transmission channel is improved, and the ionic conductivity of the gel is further improved. The room-temperature ionic conductivity of the gel with the three-dimensional network structure is larger than or equal to 3 mS / cm, and the thermal decomposition initial temperature is larger than or equal to 250 DEG C.

The invention provides a composite noble metal catalyst as well as a preparation method and application thereof, and relates to the technical field of proton exchange membrane electrolyzed water. The composite noble metal catalyst comprises a noble metal oxide catalyst and a modified inert oxide, wherein the specific surface area of the modified inert oxide is greater than or equal to 50m < 2 > / g; a modifier adopted for modification comprises any one or a combination of at least two of a fluorine ion-containing inorganic substance, perfluoro-substituted organosilane or organic amine silane. According to the invention, the modified inert oxide with high specific surface area is introduced into the catalyst, so that the pores of the catalyst layer are accurately regulated and controlled from the molecular level, and the uniformity and repeatability of regulation and control are improved. A pore gradient is constructed in multiple dimensions, a microporous structure is formed inside the aggregate, mesopores and macropores are formed outside the aggregate, and the material transmission process is further promoted. The electrolytic performance of the PEM electrolyzed water is enhanced, and the stability of the PEM electrolyzed water is also improved.