1534 results about "Ruthenium" patented technology

The invention discloses a polyrotaxane covalent organic framework material capable of regulating interlayer spacing through cyclodextrin and application of the polyrotaxane covalent organic framework material, and belongs to the technical field of biological medicine. The polyrotaalkylated covalent organic framework material is obtained by taking a cyclodextrin aromatic multi-amino inclusion compound and a (multi-aldehyde bipyridine) ruthenium (II) complex as structural units and carrying out copolymerization; the cyclodextrin aromatic polyamine inclusion compound is a beta-cyclodextrin p-phenylenediamine inclusion compound with a hydroxyl group or without a hydroxyl group; the (multi-aldehyde dipyridyl) ruthenium (II) complex is tris (4, 4 '-diformaldehyde-2, 2'-dipyridyl) ruthenium (II). The interlayer spacing of the polyrotaxane covalent organic framework material is greatly increased by utilizing a cavity of gamma-cyclodextrin, and meanwhile, the material has excellent photo-thermal and photodynamic activity, is positively charged, and can better adsorb negatively charged bacteria; and the hydrogel is good in biocompatibility and free of toxic and side effects, and has an excellent treatment effect on wounds infected with staphylococcus aureus.

A lithium supplement additive, a positive electrode sheet, a battery, and an electric device. The lithium supplement additive comprises: a first lithium supplement agent, wherein the first lithium supplement agent comprises a first core, and the first core satisfies a chemical formula LiaMbOc, wherein a is 1.5-6, b is 0-2, c is 1-6, and the element M comprises at least one of a magnesium element, a calcium element, a vanadium element, a chromium element, a manganese element, an iron element, a cobalt element, a nickel element, a copper element, a zinc element, a niobium element, a molybdenum element, a ruthenium element, a tin element, a silicon element, a carbon element and a boron element; and a second lithium supplement agent, wherein the second lithium supplement agent comprises a second core, and the second core satisfies a chemical formula LidCeOf, wherein d is 1.5-6, e is 3-5, and f is 1.5-6. The mass fraction of the first lithium supplement agent in the lithium supplement additive is m1, the mass fraction of the second lithium supplement agent in the lithium supplement additive is m2, and m1:m2 is smaller than or equal to (10:1).

The invention relates to a Bayesian optimization-based ruthenium, tin and indium doped lithium-rich manganese-based electrocatalyst screening method, electronic equipment and a storage medium, and the method comprises the following steps: generating a uniform ruthenium, tin and indium doped lithium-rich manganese-based material data set based on Dirac distribution, and generating a doped structure through element replacement; calculating hydroxyl adsorption energy and extracting descriptors to construct a data set to train a machine learning model; performing cell expansion operation on the initial electrocatalyst structure, predicting hydroxyl adsorption energy of each adsorption site, and mapping adsorption energy deviation into current density characterization component activity in combination with Boltzmann distribution; selecting an initial component based on the obtained component activity information, and constructing an agent model by utilizing Bayesian optimization; and determining a to-be-sampled component through an expectation improvement strategy, sampling and updating the agent model, and outputting an optimal doping proportion. Compared with the prior art, the method has the advantages that the ruthenium, tin and indium doped lithium-rich manganese-based electrocatalyst with excellent catalytic performance can be efficiently screened out, and the experiment cost is reduced.

The invention relates to the technical field of high-entropy oxide and electrocatalyst synthesis, in particular to a double-phase hollow high-entropy oxide catalyst and a preparation method and application thereof, the double-phase hollow high-entropy oxide catalyst comprises metal elements and non-metal elements, the metal elements comprise ruthenium, nickel, cobalt, iron, manganese and chromium; the non-metallic element is oxygen; the chemical formula of the double-phase hollow high-entropy oxide catalyst is NiCoFeMnCrRuO. The invention further discloses a preparation method of the catalyst. The double-phase hollow high-entropy oxide catalyst has a multi-shell hollow structure, provides a larger specific surface area and exposes a large number of reaction active sites, so that the double-phase hollow high-entropy oxide catalyst has lower overpotential, higher reaction efficiency and good electrochemical stability; meanwhile, the preparation method of the double-phase hollow high-entropy oxide catalyst is simple in process, low in cost, high in repeatability and suitable for industrial mass production, and has a wide application prospect.

Provided herein are methods and apparatuses for reducing line bending when depositing a metal such as tungsten, molybdenum, ruthenium, or cobalt into features on substrates by periodically exposing the feature to nitrogen, oxygen, or ammonia during atomic layer deposition, chemical vapor deposition, or sequential chemical vapor deposition to reduce interactions between metal deposited onto sidewalls of a feature. Methods are suitable for deposition into V-shaped features.

Provided herein are methods and apparatuses for reducing line bending when depositing a metal such as tungsten, molybdenum, ruthenium, or cobalt into features on substrates by periodically exposing the feature to nitrogen, oxygen, or ammonia during atomic layer deposition, chemical vapor deposition, or sequential chemical vapor deposition to reduce interactions between metal deposited onto sidewalls of a feature. Methods are suitable for deposition into V-shaped features.

The invention relates to the technical field of proton exchange membrane fuel cell cathode catalysts, and discloses a nanoscale high-entropy intermetallic compound catalyst and a preparation method and application thereof. According to the nanoscale high-entropy intermetallic compound catalyst, a nitrogen-doped porous carbon material derived from zeolite imidazole skeleton-8 is taken as a carrier, and the metal elements of a high-entropy intermetallic compound comprise platinum, copper, cobalt, nickel and iron or platinum, ruthenium, copper, cobalt, nickel and iron. The preparation method of the catalyst comprises the following steps: step 1, preparing a zeolite imidazole framework 8; 2, preparing and purifying a nitrogen-doped porous carbon material carrier; step 3, loading a metal precursor; and 4, preparing the nano-scale high-entropy intermetallic compound catalyst. Nanoscale, high dispersity and structure ordering of the high-entropy intermetallic compound are achieved, the high-entropy intermetallic compound serves as a PEMFC cathode catalyst, the ORR quality activity and durability can be remarkably improved, and Pt loading capacity and cost are effectively reduced.

The invention relates to an MOF confinement ruthenium cluster catalyst for methanation of carbon dioxide as well as a preparation method and application of the MOF confinement ruthenium cluster catalyst. The catalyst comprises a carrier and an active component loaded on the carrier, the carrier comprises a metal organic framework containing hydroxyl; the metal organic framework comprises UiO-66 (UiO-66); the active component comprises metal ruthenium; the active component grows in a pore channel of the carrier and forms a metal cluster. The catalyst provided by the invention realizes 100% methane selectivity and 98.4% carbon dioxide (CO2) conversion rate under the conditions of 1 MPa and 220 DEG C, is almost close to thermodynamic limit equilibrium conversion rate (99.4%) and is superior to the currently reported Ru-based CO2 methanation catalyst, and the catalyst shows good catalytic activity and structural stability in the process of continuous reaction for 650 hours. The catalyst provided by the invention has the characteristics of simple preparation method, high metal dispersibility, mild reaction conditions, high conversion rate, good selectivity, excellent stability and the like.

The invention discloses a rare earth oxide post-supported ruthenium-based ammonia decomposition catalyst, a preparation method and application thereof in hydrogen preparation through ammonia decomposition, and belongs to the technical field of hydrogen production. The ammonia decomposition catalyst takes an oxide or a carbon material as a carrier, firstly, ruthenium metal is loaded to form an active center, then, rare earth oxide is introduced in a post-loading mode, the structure and electronic characteristics of a metal-carrier interface are regulated and controlled, and finally, the ammonia decomposition catalyst with high dispersity and stability is obtained through reduction treatment. The low-temperature ammonia decomposition performance and the operation stability are obviously improved. Under the conditions that the temperature is 400 DEG C and the air speed of ammonia gas is 18000 mL.gcat <-1 >. H <-1 >, the ammonia conversion rate of the catalyst is close to the thermodynamic limit, and the catalyst has good anti-sintering and anti-poisoning capabilities. The catalyst is simple and convenient in preparation process, can be produced on a large scale, is suitable for various scenes of hydrogen production through ammonia decomposition, is particularly suitable for distributed and on-demand hydrogen production systems, and provides powerful technical support for efficient utilization and green conversion of hydrogen energy.

The invention discloses a hydroxyl-rich ruthenium / titanium dioxide catalyst as well as a preparation method and application thereof, and the preparation method comprises the following steps: step 1, loading a ruthenium precursor on a titanium dioxide carrier by adopting an impregnation method or a deposition-precipitation method, and drying and calcining to obtain a Ru / TiO2 catalyst; and step 2, placing the Ru / TiO2 catalyst in an atmosphere environment containing water vapor or forming a physical adsorption water film on the surface of the Ru / TiO2 catalyst, and performing ultraviolet irradiation treatment to obtain the Ru / TiO2 catalyst. According to the method, water is physically adsorbed through ultraviolet light dissociation, hydroxyl is directly generated on the surface of Ru / TiO2 in an in-situ mode, the method is easy to operate, complex liquid phase treatment is not needed, and the stability of the generated hydroxyl under the subsequent high-temperature gas-solid phase hydrogen-rich reaction condition is obviously superior to that of hydroxyl introduced through a traditional method. The stable hydroxyl enriched on the surface serves as an effective Lewis base site and cooperates with a Ru active site, adsorption and activation of CO2 molecules are remarkably promoted, and therefore the catalytic activity of the CO2 methanation reaction is greatly improved.

The invention discloses a catalyst for hydrogen production through tar steam reforming and a preparation method and application thereof. The catalyst comprises a cobalt-magnesium-aluminum composite spinel carrier and an active component loaded on the cobalt-magnesium-aluminum composite spinel carrier, the active component comprises nickel and at least one metal additive selected from iron, zirconium and ruthenium. The preparation method mainly comprises the following steps: preparing the carrier by adopting a coprecipitation method, loading the active component by adopting an impregnation method, and drying and reducing to obtain the final catalyst. The catalyst is used for tar component steam reforming hydrogen production reaction, especially for treating raw materials containing phenol and water vapor at 600-700 DEG C, tar conversion can be efficiently catalyzed, product gas rich in hydrogen can be generated, hydrogen selectivity is high, and almost no methane is generated. The catalyst has the advantages of high activity, good stability, strong carbon deposition resistance and the like, and is suitable for purification and high-value utilization of biomass pyrolysis tar.

The invention relates to a self-heating catalysis propane partial oxidation reforming coupling tube type solid oxide fuel cell system and a preparation method of a catalyst and a carrier thereof. The system comprises a fuel cell tube and a honeycomb type catalyst carrier with the catalyst, the fuel cell tube comprises a cathode layer, an electrolyte tube and an anode layer; the anode layer is located on the inner wall of the electrolyte tube, and the cathode layer is located on the outer wall of the electrolyte tube; the honeycomb type catalyst carrier is mounted at a gas inlet end of a fuel cell tube and is communicated with an inner cavity of the fuel cell tube, the catalyst is a ruthenium-based active component, comprises RuO or metal Ru and is doped with CeO as a dispersing aid, the loading capacity of Ru is 0.5-5wt%, and the proportion of CeO is 0.5-3wt%. The method has the advantages that the mechanical stability is good, the influence of the anode reduction process on the starting time is eliminated, the influence of anode carbon deposition on the performance of the SOFC is reduced, and rapid heating and rapid power generation are realized.

The invention provides a long-acting and low-cost Ru-based catalyst for hydrogen production through ammonia decomposition and a preparation method thereof.The preparation method comprises the steps that calcium salt or strontium salt and cerium nitrate hexahydrate are added into deionized water to be prepared into a mixed solution, the pH value of the mixed solution is adjusted, then a precipitate is obtained through closed heating treatment, carrier powder is prepared through roasting and grinding in sequence, and the Ru-based catalyst for hydrogen production through ammonia decomposition is obtained; and adding a proper amount of ruthenium salt, uniformly stirring to form a Ru-carrier dispersion liquid, and finally, sequentially roasting and grinding to obtain the Ru-based catalyst for hydrogen production by ammonia decomposition. The loading capacity of the catalyst is lower than that of conventional Ru, the catalyst can show good ammonia decomposition hydrogen production performance under the conditions that the 10% NH3 / Ar mass space velocity (GHSV) is 30000 ml / (gcat.h) and the low temperature is 450 DEG C, it is accidentally found that the catalyst can keep long-term stability for at least 100 hours or above, and meanwhile the simple synthesis method is suitable for industrial large-scale production.

The invention relates to the technical field of chemical catalysts, in particular to a cerium-based solid solution loaded iron-based oxygen vacancy enhanced low-temperature ammonia synthesis catalyst. The heterovalent ions are doped in CeO2 crystal lattices to introduce strain and defects, so that the oxygen vacancy formation energy and concentration are greatly improved. Experiments show that the oxygen vacancy concentration (delta) of the Ce0. 8Zr0. 2O2-delta carrier disclosed by the invention can reach 0.12, which is 3-5 times that of pure CeO2. Under the conditions of 250 DEG C and 5 MPa, the ammonia synthesis rate reaches 120 [mu] mol / g / h, which is more than 20 times that of a traditional molten iron catalyst; under the conditions of 350 DEG C and 10 MPa, the ammonia synthesis rate exceeds 1000 [mu] mol / g / h and is close to the level of a noble metal ruthenium-based catalyst. As the working temperature is reduced by 100-150 DEG C, the reaction heat consumption is reduced by more than 30%, and the overall energy consumption is reduced by 25-40%.

The present invention relates to the field of water electrolysis and hydrogen production. Disclosed is a carbon nanotube-supported nitrogen-doped catalyst. The catalyst has a carbon nanotube structure as a support, and cobalt and ruthenium as active components, wherein the content of the cobalt element is 30-45w%, the content of the ruthenium element is 1-7wt%, and the proportion of the ruthenium element present in the form of RuN is 60-90wt% relative to the total ruthenium element. A graphitized structure of the catalyst is conducive to charge conduction, Ru is uniformly loaded on the surface of the support by means of a low-temperature reduction process and interaction with defect sites on the surface of the support, and then after high-temperature roasting, Ru interacts with the N element and the metal Co, thereby improving the hydrogen evolution catalytic activity of the catalyst.

The invention provides a preparation method and application of nitrogen-doped activated carbon for a ruthenium catalyst carrier, and the preparation method comprises the following steps: carrying out in-situ polymerization on aniline on the surface of nanocellulose by adopting an oxidative polymerization method to generate polyaniline, so as to obtain polyaniline-coated nanocellulose; the preparation method comprises the following steps: reacting phenol, an aminophenol derivative and a formaldehyde solution serving as raw materials under the action of a base catalyst to obtain modified A-stage phenolic resin; and uniformly mixing the polyaniline-coated nano cellulose with the modified resol, curing, crushing, carbonizing, activating, graphitizing, grinding and sieving to obtain the nitrogen-doped carrier activated carbon. The nanocellulose contains carbon, hydrogen and oxygen elements, gas can be generated in the preparation process of the activated carbon, and the pore structure of the activated carbon is expanded along with gas escape; a nitrogen-doped activated carbon pore wall is generated in situ by polyaniline around the occupation space of the nanocellulose, and the nitrogen element is beneficial to adjusting the size of active metal ruthenium particles and improving the activity and stability of the ammonia synthesis supported ruthenium catalyst prepared from the nitrogen-doped activated carbon pore wall.

The present disclosure relates to ruthenium-based catalysts for ammonia (NH3) synthesis at mild conditions and methods of preparing the ruthenium-based catalysts. The ruthenium-based catalyst includes a MgFeOx support and ruthenium metal loaded onto the support, wherein the catalyst has the chemical formula of MgFeOx—Ru, wherein x is the number of oxygen atoms present. In an example, x is equal to four. The MgFeOx support is prepared from MgFe layered double hydroxide (LDH). An amount of ruthenium present in the ruthenium-based catalyst ranges from about 0.1 to about 1.0 wt %.

The invention discloses a forming method of a ruthenium-based ammonia synthesis catalyst, and belongs to the technical field of catalysts. Comprising the following steps: mixing ruthenium-based catalyst powder, bentonite and an extrusion aid to obtain powder, and adding deionized water into hydroxymethyl cellulose to form gel; and adding the powder into the gel, fully stirring, putting into an extruder, carrying out molding treatment, and then carrying out vacuum calcination. The prepared ammonia synthesis catalyst with the special-shaped structure has relatively high mechanical strength and relatively low abrasion rate, and the reduction of activity is avoided. The catalyst is used in an ammonia synthesis process, and can maximize the effect of a ruthenium-based catalyst according to the characteristics and requirements of high pressure and high temperature.

The invention discloses a nano-alloy catalyst for anion exchange membrane electrolyzed water and a preparation method of a membrane electrode of the nano-alloy catalyst, when any one of manganese salt, cerium salt, chromium salt, cobalt salt, lanthanum salt, ruthenium salt and iridium salt is not added, NiFe binary alloy powder is obtained, the content of Ni is 90%-100%, and the content of Fe is 0%-10%; when any one of manganese salt, cerium salt, chromium salt, cobalt salt, lanthanum salt, ruthenium salt and iridium salt is added, NiFe ternary alloy powder is obtained, the content of Ni is 76%-96%, the content of Fe is 4%, and the content of the third element is 0%-20%. The nano-alloy catalyst material for anion exchange membrane water electrolysis prepared according to the invention is good in corrosion resistance and high in stability, the total water splitting efficiency is further improved, the synthesis method is simple, the used metal salt is low in cost, the metal salt can be uniformly loaded on a substrate carrier through spraying, and industrial application of total water splitting under high current density is easy to realize.

The invention discloses a ruthenium and samarium double monatomic doped three-dimensional titanium-based tin antimony nickel electrode and a preparation method and application thereof. The preparation method of the electrode comprises the following steps: (1) pretreating the titanium felt; (2) preparing a sol impregnation liquid; (3) sol coating and drying: dipping the pretreated titanium felt in the prepared sol dipping liquid, fully adsorbing and then drying to form a uniform precursor layer; and (4) roasting treatment is conducted, specifically, the dried titanium felt is placed in a muffle furnace to be roasted, and then the steps of dipping, drying and roasting are repeated till the final ruthenium and samarium double monatomic doped three-dimensional titanium-based tin-antimony-nickel electrode is obtained. In the prepared electrocatalyst, ruthenium and samarium are doped into a tin-antimony-nickel electrode in a monatomic form, the utilization efficiency of ruthenium and samarium atoms is improved, and the electrode is endowed with excellent electrocatalytic activity. The unique three-dimensional structure and double-monatomic doping significantly enhance the electron transfer rate and the reaction kinetic characteristics, so that the electrode shows excellent stability and efficient hypochlorous acid generation ability.

The invention discloses a ruthenium-based solid solution oxide catalyst as well as a preparation method and application thereof, and the ruthenium-based solid solution oxide catalyst is prepared by adopting an acid-resistant metal (Ti, Nb, Mo, W and Ta) substrate material and ruthenium salt to synthesize a ruthenium-based precursor in situ, and then performing high-temperature calcination in an air atmosphere to prepare the ruthenium-based solid solution oxide catalyst. The prepared ruthenium-based solid solution catalyst has the characteristics of excellent conductivity, small crystal particle size, high crystallinity and the like. Elements of the solid solution catalyst synthesized by the method are good in dispersity, excessive oxidation of ruthenium sites can be effectively inhibited, long-time stability of active sites under strong acid and strong oxidation conditions can be guaranteed, and the solid solution catalyst is expected to be applied to PEM industrial electrolytic water.

The invention belongs to the technical field of catalyst preparation, and particularly relates to a preparation method of a monatomic ruthenium-based catalyst and application of the monatomic ruthenium-based catalyst in hydrogen production through ammonia decomposition. According to the method, an atom capture method is adopted, ruthenium precursor powder and the oxide carrier are subjected to high-temperature treatment in the oxygen-containing atmosphere, Ru species volatilized in the high-temperature oxidizing atmosphere are captured through the oxide carrier, anchoring of Ru atoms is achieved, the stability of Ru on the surface of the carrier is effectively improved, and the atom utilization rate of precious metal is increased. The monatomic Ru-based catalyst prepared by the invention has high reaction activity in the reaction of catalyzing ammonia decomposition to produce hydrogen, the preparation method is simple, the stability is high, and the monatomic Ru-based catalyst has a wide application prospect in the field of ammonia decomposition to produce hydrogen.

The invention relates to a Fe3C-Ru / NFs catalyst as well as a preparation method and application thereof. Wherein the Fe3C-Ru / NFs catalyst comprises carbon nanofibers NFs, and Fe3C and sub-nanoscale Ru particles which are loaded on the carbon nanofibers NFs, and the average particle size of the Ru particles is less than 3nm. The preparation method of the catalyst comprises the following steps: dissolving PVP (Polyvinyl Pyrrolidone), an iron source and a ruthenium source in a mixed solvent of DMF (Dimethyl Formamide) and ethanol to obtain a precursor solution; and preparing FeRu / PVP nanofibers from the precursor solution through an electrostatic spinning method, and then carrying out pre-oxidation and high-temperature carbonization to obtain the Fe3C-Ru / NFs catalyst. According to the invention, Fe3C and sub-nanoscale Ru particles are highly dispersed on the carbon nanofibers, and the Fe3C particles enable the electronic environment of Ru sites to be changed and to be in an electron-deficient state, so that the generation of a catalytic reaction is facilitated, and the catalyst has extremely high electro-catalysis full-water-splitting performance and stability.

This invention relates to a method for using a low-content ruthenium-based catalyst modified with nitrogen and oxygen ligands in the hydrochlorination of acetylene. The invention utilizes 2-pyridine carboxylate as a ligand, commercial activated carbon as a support, trace amounts of ruthenium as the main active component, and water as a solvent. An improved synthesis procedure yields a low-content ruthenium-based catalyst with ruthenium ions coordinated by a modifier and commercial activated carbon as a support, significantly improving catalyst performance while reducing ruthenium content. This catalyst exhibits high activity and vinyl chloride selectivity in the fixed-bed hydrochlorination of acetylene to vinyl chloride, and its low cost makes it highly valuable for industrial applications. The ruthenium loading is 0.1%, and the reaction gas space velocity is 170 h⁻¹. ‑1 V (C2H2) / V (HCl) With a ratio of 1:1.05 and a reaction temperature of 180℃, the acetylene conversion rate can reach 84.3%, the vinyl chloride selectivity is greater than 99%, and the activity remains basically unchanged within 10 hours.

The present invention relates to an ammonia decomposition catalyst and a manufacturing method thereof, and more particularly to an ammonia decomposition catalyst containing alumina (Al2O3), cerium (Ce), lanthanum (La), ruthenium (Ru) and potassium (K).

The invention discloses a method for controlling CMP (chemical mechanical polishing) dish-shaped pits, corrosion pits and interface corrosion of ruthenium barrier layer copper wiring, which is suitable for a manufacturing process of integrated circuits of 14 nanometers and below. According to the method, a specifically synthesized TTAK corrosion inhibitor is introduced into a polishing solution system, the oriented adsorption characteristic of the molecular structure of the TTAK corrosion inhibitor is utilized, the corrosion reaction of copper is selectively inhibited, meanwhile, the normal material removal efficiency of a ruthenium barrier layer and a TEOS dielectric layer is maintained, and cooperative regulation and control of the removal rate of the Cu / Ru / TEOS material are achieved. By means of the method, dished pits, corrosion pits and Fang type interface defects generated in the fine polishing and barrier layer polishing process can be effectively eliminated, and copper / ruthenium interface corrosion is improved. According to the method, the global planarization quality of the copper interconnection ruthenium barrier layer is remarkably improved, the interface bonding strength and the electrical reliability of an interconnection circuit are enhanced, and an effective solution is provided for performance optimization of an advanced process integrated circuit device.

The invention discloses a ruthenium-substituted doped manganese dioxide positive electrode material for a zinc ion battery as well as a preparation method and application of the ruthenium-substituted doped manganese dioxide positive electrode material. The cathode material has the following chemical composition: KxMn1-yRuyO2. ZH2O (0.2 < = x < = 0.5, 0.01 < = y < = 0.2, and 0 < = z < = 0.5). The transition metal ruthenium is adopted to carry out atomic-scale substitution doping on the manganese dioxide positive electrode material, Mn < 4 + > in the [MnO6] octahedron is substituted by the transition metal ruthenium, a Ru-O chemical bond is formed, the electronic structure and the crystal structure of manganese dioxide are regulated and controlled, and the electronic conductivity and the structural stability of manganese dioxide are enhanced. The ruthenium-substituted doped manganese dioxide positive electrode material shows improved rate capability and excellent cycling stability in an electrochemical performance test, and is a relatively ideal zinc ion battery positive electrode material. In addition, the material is simple in preparation process method, good in repeatability, high in yield and suitable for large-scale production and practical application.

The invention relates to a membrane electrode and application thereof in deuterium-enriched water, and belongs to the field of clean energy development and utilization. The membrane electrode comprises a proton exchange membrane, an anode catalyst and a cathode catalyst, the anode catalyst is an iridium / iridium oxide catalyst with a three-dimensional porous network structure, and the cathode catalyst is a platinum-ruthenium alloy catalyst. The preparation method comprises the following steps: coating one side of the N117 proton exchange membrane with the anode catalyst, coating the other side of the N117 proton exchange membrane with the cathode catalyst, and then performing hot pressing to prepare the membrane electrode. The method comprises the following steps: assembling a membrane electrode into an electrolytic cell, and electrolyzing water by using the electrolytic cell to realize deuterium enrichment. The membrane electrode and the electrolytic cell are reasonable in design, the preparation process is simple and controllable, and the obtained product is high in efficiency and long in service life when used for enriching deuterium and facilitates industrial application.

The invention discloses a surface oxidation monatomic nano-alloy catalyst as well as a preparation method and application thereof, and belongs to the technical field of advanced nano-energy materials and electro-catalysis. A surface-oxidized monatomic nano-alloy catalyst comprises a hydroxylated carbon nanotube carrier and bimetallic nano-alloy particles loaded on the hydroxylated carbon nanotube carrier, in the bimetallic nano-alloy particles, non-noble metal elements are dispersed in noble metal nano-particles in a monatomic form, the size of the bimetallic nano-alloy particles is 3-4 nm, and the surface-oxidized monatomic nano-alloy catalyst is prepared from a surface-oxidized monatomic nano-alloy catalyst. An oxide layer with the thickness of 0.3-0.6 nm is arranged on the surface of the bimetallic nano-alloy particle; the loading amount of the noble metal is 5-15wt%. Ruthenium and other non-noble metal elements are alloyed and anchored on the carbon material substrate, the conductivity of the catalyst can be greatly improved, the size of alloy particles is accurately controlled within the range of 3-4 nm, active sites can be exposed to the maximum extent, and structural stability is considered.

The invention belongs to the technical field of catalysts, and particularly relates to a ruthenium-based supported catalyst as well as a preparation method and application thereof. The ruthenium-based supported catalyst provided by the invention comprises a composite carrier and ruthenium supported on the composite carrier, the composite carrier is one or more of a perovskite type metal oxide and an alkali metal oxide, an alkali metal hydroxide, an alkaline earth metal oxide and an alkaline earth metal hydroxide which are dispersed on the surface of the perovskite type metal oxide; the preparation method of the composite carrier comprises the following steps: mixing a perovskite type oxide with an alkali metal hydride and / or an alkaline earth metal hydride, and carrying out first calcination; soaking the first calcined product in a solvent to obtain a composite carrier; the perovskite type oxide comprises one or two of MgTiO3 (magnesium titanate), SrTiO5 (strontium titanate), BaTiO3 (barium titanate) and CaTiO3 (calcium titanate); the solvent comprises an alcohol solvent and / or water. The catalyst provided by the invention can catalyze an ammonia synthesis reaction under a relatively low pressure.