4623 results about "High concentration" patented technology

The invention relates to the technical field of soil pollution detection, in particular to a soil heavy metal pollution intelligent detection method and system.The method comprises the steps that soil multi-source information and regional environment parameters of to-be-detected soil are collected, and soil pollution characteristics are recognized according to the soil multi-source information; establishing a pollution identification analysis model according to the soil pollution characteristics and the regional environment parameters, and analyzing whether the to-be-detected soil contains heavy metal pollutants or not; if the heavy metal pollutants are contained, pollution diffusion paths of the heavy metal pollutants in time and space are predicted according to a pollution identification analysis model; and if the soil does not contain the heavy metal pollutants, performing time sequence analysis on soil pollution characteristics, monitoring and analyzing future concentration distribution of the heavy metal pollutants, and establishing pollution risk early warning. According to the invention, the problems of long sampling analysis time consumption, incapability of dynamically monitoring pollutant concentration change in real time, insufficient diffusion prediction accuracy and difficulty in comprehensively evaluating high-concentration and potential risk areas in a traditional soil heavy metal detection method are effectively solved.

The invention provides a solar interface evaporator based on amphoteric polyelectrolyte photo-thermal hydrogel, a preparation method and application, and belongs to the field of solar interface evaporation. The solar interface evaporator with a three-dimensional multi-surface evaporation structure is prepared by combining the polyelectrolyte resisting effect of the amphoteric polyelectrolyte photo-thermal hydrogel and the porous capillary effect of the sponge, and has the characteristics of high light absorptivity, good water absorption effect, excellent antibacterial property, mechanical property, salt resistance, evaporation property and the like; particularly, compared with a traditional hydrogel-based solar interface evaporator, the water delivery capacity and the salt resistance in high-concentration saline water are greatly improved through the application of the autonomously designed zwitterionic hydrogel, water molecules in the saline water are activated through the cooperation of salt-resistant ionized water, the evaporation enthalpy is reduced, and the evaporation efficiency is improved. And a great positive effect is achieved on improvement of the evaporation rate. The evaporator is easy to prepare and excellent in multi-dimensional performance, and a new way and thought are provided for application to seawater desalination and wastewater treatment.

The invention discloses a carbonyl reductase mutant and a method for catalytically synthesizing high-concentration glassine by using the carbonyl reductase mutant, and belongs to the field of biological catalysis. According to the invention, a one-pot method is adopted to catalyze beta-acetone xyloside to synthesize high-concentration boine, carbonyl reductase CnMDR coded enzyme and rational design of a substrate pocket key are combined with multiple sites, beneficial mutations are combined, dominant mutant enzyme recombinant bacteria are used as a catalyst, beta-acetone xyloside is used as a substrate, and formate dehydrogenase variants and NAD + kinase are introduced at the same time, so that the high-concentration boine is synthesized. The NADP < + >-NADPH coenzyme is driven to circulate, the yield of the synthesized boine is 200g / L, and the conversion rate is gt; the ee value of the product is gt; the invention provides a one-pot efficient low-cost method for synthesizing the boine, only a trace amount (0.3 mM) of coenzyme needs to be added, byproducts in a reaction system are easy to separate, and great convenience is provided for industrial large-scale production.

The invention provides particles, compositions including the particles, and methods of making the particles using electrospray. In certain embodiments, the particles allow for high concentrations of a therapeutic or diagnostic agent to be delivered at low viscosity. Particles may also exhibit beneficial properties with respect to stability.

The invention provides particles, compositions including the particles, and methods of making the particles using electrospray. In certain embodiments, the particles allow for high concentrations of a therapeutic or diagnostic agent to be delivered at low viscosity. Particles may also exhibit beneficial properties with respect to stability.

The invention provides an SF6 digital density meter based on multi-parameter acquisition and automatic temperature compensation and a control method thereof, the SF6 digital density meter is provided with a density meter display, a detection docking port is arranged below the SF6 digital density meter, the digital density meter is internally provided with a multi-parameter acquisition module and a temperature and pressure arrangement module, and the multi-parameter acquisition module and the temperature and pressure arrangement module are connected with the SF6 digital density meter display. The multi-parameter acquisition module and the temperature and pressure arrangement module are electrically connected with the single-chip microcomputer. And a detection docking port of the SF6 digital density meter is directly and completely contacted with SF6 gas. High concentration of physical quantity acquisition components is realized, and the physical quantity acquisition components are directly and fully contacted with the SF6 gas in the gas chamber, so that accurate acquisition of physical quantities such as actual temperature, pressure and micro water of the SF6 gas for temperature compensation is ensured. Meanwhile, practical improvement is carried out on an existing disclosed SF6 density algorithm model, and an algorithm model with better convergence is obtained.

Disclosed in the present invention is a process for deeply removing fluorine from wastewater by means of an induced crystallization method in sludge backflow. The process comprises the following steps: step 1. placing lime powder and deionized water in a seed crystal reactor to prepare lime milk and at the same time putting a calcite seed crystal into the seed crystal reactor; step 2. introducing high-concentration fluorine-containing acidic wastewater into a reactor; and step 3. introducing the lime milk obtained in step 1 into the reactor in step 2 to undergo a reaction, wherein during the reaction, the pH value of the mixed solution is controlled to remain neutral. The present invention is based on a high-density sludge method (HDS process). By utilizing the HDS process, the advantages of effectively improving the sludge density, reducing the lime consumption, facilitating the operation, and enabling the water quality of an effluent to be more stable are realized. In conjunction with induced crystallization technology, an induced crystallization process in a high-density sludge backflow is formed to promote precipitation and crystallization and allow sedimentation to proceed quickly, thereby shortening the process time and overcoming the defects of traditional lime precipitation methods.

The invention provides glabridin nano-vesicles based on glycyrrhizic acid wrapping, a preparation method of the glabridin nano-vesicles and application of the glabridin nano-vesicles in preparation of whitening and skin care cosmetics, and relates to the technical field of cosmetics. According to the glabridin nano-vesicle based on glycyrrhizic acid wrapping, glabridin is carried by glycyrrhizic acid, glycyrrhizic acid serves as a carrier, the solubility of glabridin can be improved, the skin transmittance of glabridin can be increased, the anti-inflammatory effect of glabridin can be achieved, then the effect of one stone for three birds is achieved, the characteristic and advantage of integration of medicine and auxiliary materials are achieved, and the glabridin nano-vesicle based on glycyrrhizic acid wrapping has good application prospects. The tyrosinase inhibition activity of the glabridin is greatly improved. Meanwhile, the glabridin nano-vesicles wrapped based on glycyrrhizic acid have the advantages of high encapsulation efficiency, large drug loading capacity, good stability and high safety, can effectively promote the whitening factor glabridin to penetrate through the skin cuticle to enter the skin deep tissue, can stay in the skin at a high concentration for a long time, and can continuously play a whitening role.

The invention discloses a cyanamide axial coordination cobalt monatomic catalyst for persulfate activation and a preparation method and application thereof, and belongs to the technical field of persulfate advanced oxidation. The catalyst is prepared by the following method: simultaneously adding NH2CN and NaOH into a CoCl2 solution, stirring for reaction, and after the reaction is finished, washing, filtering and drying to obtain the catalyst CoN4 (NCN). The catalyst CoN4 (NCN) with an isolated Co site and cyanamide ([NCN] 2-) coordination structure is synthesized by adopting a one-step precipitation method. The catalyst can be used for an advanced oxidation system based on persulfate activation, and can be used for deeply treating a water body polluted by high-concentration organic matters, so that the biodegradability of the water body is improved. In addition, CoN4 (NCN) also has obvious stability and environmental adaptability, and has important application prospect and value in the field of organic pollutant degradation.

The invention relates to the technical field of data processing, in particular to an abnormal data processing system for atmospheric pollution monitoring, which comprises the following steps: acquiring a concentration sequential sequence and a standard sequential sequence of gas; performing preliminary evaluation on the concentration time sequence to obtain a preliminary abnormal degree; sequentially carrying out segmentation and fitting on the concentration time sequence to determine subsequences and a target curve; dividing a segmentation sequence based on the target curve, and segmenting a matching sequence; based on the change of the correlation between the segmentation sequence and the standard time sequence along with time, analyzing the offset characteristic of the gas concentration change trend to determine the trend time sequence offset degree, and combining the normal distribution fitting result of the concentration time sequence to determine the detection influence weight; and acquiring abnormal data in the concentration data of each gas at the monitoring point according to the detection influence weight and the initial abnormal degree. According to the method, the decision weight of the isolated tree is adaptively determined, so that the detection accuracy of the abnormal data in the concentration data is improved.

The invention relates to an EVA high-concentration color master batch detection method based on multispectral imaging, which comprises the following steps: S1, arranging an adjustable multicolor LED light source on a production line, and acquiring a multispectral image of a color master batch by using a multispectral imager to obtain a spectral data set; s2, extracting spectrums from the spectral data set based on a color master batch component identification model, and identifying spectral characteristics of different components or impurities; s3, constructing a color master batch color difference detection model and a defect identification model, and respectively carrying out color difference detection and defect identification based on the spectral characteristics; s4, based on real-time image color difference detection and defect recognition results, feeding back and controlling a control system of a production line based on an intelligent agent, and realizing automatic adjustment; and S5, visualization is carried out based on color difference detection and defect identification results, so that an operator can obtain a real-time color master batch detection result, and alarm processing is carried out on unqualified products. According to the scheme, high-efficiency and accurate monitoring on the EVA high-concentration color master batch is realized, and production intelligence and high product quality are ensured.

The invention discloses a method for preparing a high-stability W / O / W type multiple Pickering emulsion based on Janus particles, and belongs to the technical field of colloid and interface chemistry. According to the preparation method, the Janus particles with different hydrophilic and hydrophobic properties are prepared by using alkylsilane modified SiO2 with different chain lengths, the multiple emulsion is stabilized together, different types of Janus particles are adsorbed on different oil-water interfaces, and the interface activity and amphipathicity of the Janus particles are fully exerted to prepare the high-stability multiple emulsion. The multi-emulsion provided by the invention has excellent stability, keeps stable under the conditions of long-term storage, strong acid, strong alkali, high-concentration electrolyte and the like, and can effectively expand the practical application of the multi-emulsion.

The invention provides a high-concentration ytterbium-doped double-clad silicate optical fiber single-frequency amplifier which comprises a single-frequency laser seed source, a double-clad optical fiber pre-amplifier and a high-concentration ytterbium-doped double-clad silicate optical fiber main amplifier which are connected in sequence. The single-mode optical fiber pre-amplifier is used for primarily amplifying the single-frequency laser; the double-clad optical fiber pre-amplifier is used for further amplifying the optical signal output from the single-mode pre-amplifier; and the high-concentration ytterbium-doped double-clad silicate optical fiber main amplifier is used for performing high-power amplification on the signal light amplified by the double-clad optical fiber pre-amplifier and outputting specific high-power narrow-linewidth single-frequency laser. Single-frequency laser seed source low-noise coefficient pre-amplification is achieved through a front multi-stage pre-amplification system, a high-concentration ytterbium-doped double-clad silicate optical fiber is adopted in a final main amplifier, the length of a needed active optical fiber is shortened through provided high gain, the stimulated Brillouin scattering effect is restrained, and the optical fiber is high in gain and high in power consumption. And the output power of the single-frequency narrow-linewidth optical fiber amplifier is improved.

The invention provides a method for selecting a high-concentration VOCs adsorbent at different temperatures and application, and belongs to the technical field of waste gas governing. According to the method, through testing pore structure parameters of a model adsorption material with concentrated pore size distribution, a static adsorption isotherm and a dynamic penetration curve for VOCs at different temperatures, a high-concentration VOCs adsorbent is obtained; a linear relation equation of the critical aperture and the critical pressure is established through linear fitting, then a correlation equation of the critical aperture, the temperature and the partial pressure is established, and the appropriate aperture distribution range and the model selection standard of the high-concentration VOCs adsorbent at different temperatures are determined by combining dynamic adsorption results. According to the method, the ternary matching relation equation of the VOCs partial pressure, the temperature and the critical aperture is constructed, accurate type selection of the high-concentration VOCs adsorbent at different temperatures is achieved, the pore volume utilization rate and the adsorption capacity can be improved, meanwhile, desorption energy consumption and the VOCs pyrolysis risk are reduced, and a theoretical basis is provided for adsorbent type selection and technical optimization.

The invention relates to the field of water quality detection, in particular to a method, system and equipment for detecting solution impurities through a water quality detector and a medium. The method comprises the following steps: acquiring spectral data of a to-be-detected ion solution; a correction observation window is constructed on the spectral data according to the local concentration gradient and used for extracting local nonlinear features, and the local nonlinear features comprise absorbance gradient change features and fitting residual error anomaly features; establishing a mapping relation between the spectral data and a water quality detection result according to the local nonlinear characteristics in the correction observation window, and generating a correction coefficient through a scatter correction algorithm; correcting the spectral data according to the mapping relation and the correction coefficient; and identifying impurity components in the ion solution based on the corrected spectral data. The stable mapping relation between the absorbance and the impurity concentration can still be maintained in a strong ion interference environment, so that the measurement result can keep reliable precision even in a high-concentration ion intensity environment.

The invention provides particles, compositions including the particles, and methods of making the particles using electrospray. In certain embodiments, the particles allow for high concentrations of a therapeutic or diagnostic agent to be delivered at low viscosity. Particles may also exhibit beneficial properties with respect to stability.

The invention discloses a back surface structure of a TBC battery, a preparation method of the back surface structure, the TBC battery and a preparation method of the TBC battery, and belongs to the technical field of solar batteries. According to the back surface structure of the TBC battery, the first doped polycrystalline silicon layer is provided with the high-concentration doped region and the low-concentration doped region, so that on one hand, good contact between a metal electrode and polycrystalline silicon is ensured, and meanwhile, the battery has relatively low contact resistance and high conversion efficiency. According to the back surface structure of the TBC battery or the preparation method of the TBC battery provided by the invention, on the basis of ensuring that the thickness of the first doped polycrystalline silicon layer is not reduced, by arranging the low-concentration doped region, the adverse effect of laser patterning processing on subsequent wet etching of polycrystalline silicon is reduced, the wet etching effect of the polycrystalline silicon is ensured, and the production efficiency of the TBC battery is improved. Therefore, on the basis of ensuring the battery performance, the difficulty of the preparation process is reduced, and the battery manufacturing yield is improved.

The invention provides a method for detecting multi-gas concentration in exhaust gas and a gas filtering system, and relates to the technical field of gas detection. The method comprises the following steps: setting components and concentration of mixed gas according to characteristics of target detection gas, and injecting the mixed gas into a light filtering channel to eliminate illumination interference of a red light wave band so as to obtain first illumination; after a user detection instruction is obtained, the gas inlet valve is opened, the exhaust gas enters the detection chamber, the exhaust gas entering the detection chamber is detected through the gas automatic identification module, and the concentration of multiple target detection gases is estimated. Determining the target detection gas with the highest concentration, adjusting an optical filter to filter the first illumination to obtain second illumination, enabling the second illumination to penetrate through the exhaust gas to obtain third illumination, determining the concentration of the target detection gas according to the third illumination and the second illumination, and displaying the concentration on a screen in real time. In a complex gas emission environment, the influence of interference gas is eliminated, and the concentration of target detection gas is accurately detected.

The invention discloses a sewage sludge advanced treatment device, which belongs to the technical field of sludge treatment, and comprises a flocculation basin and a dehydration device, a concentration adjusting tank is arranged between the flocculation basin and the dehydration device, the inside of the tank is divided into a high-concentration area and a low-concentration area through a filter plate, the high-concentration area is provided with a first liquid inlet pipe, and the low-concentration area is provided with a second liquid inlet pipe; flowing into a dehydration device through a mixing pump; the filter plate is controlled by a driving mechanism to move so as to change the volume of the high-concentration area, and a first concentration detector is mounted on the first liquid inlet pipe and is used for moving the filter plate to reduce the volume of the high-concentration area when the first concentration detector detects that the concentration is lower than a threshold value; a control valve is installed on the second liquid inlet pipe and used for opening the control valve when the first concentration detector detects that the concentration is larger than the threshold value. The concentration regulating tank is arranged between the flocculation tank and the dehydration device to regulate the concentration of the sludge, so that the concentration of the sludge input into the dehydration device is stable, and the qualified rate of sludge caking is ensured.

The invention relates to the technical field of exosome loaded drugs, and provides a preparation method and application of exosome vesicles capable of efficiently loading drugs, and the preparation method comprises the following steps: exosome preparation: preparing an exosome sample with enough granularity and purity; pretreatment of exosomes: performing precipitation treatment and collecting the exosomes to prepare exosome precipitates; carrying out loaded medicine pretreatment: treating loaded medicine or a medicine preparation by using a lipid reagent; target drug loading: rapidly treating the exosome precipitate by using a drug lipid component, and then treating by using a buffer system to obtain the exosome load of the drug; and free lipid and drug removal: reducing free lipid and drug residues by re-enriching the exosomes. The problems of high concentration, high purity and low cost in industrial production of the exosome are solved, meanwhile, an efficient and convenient technical method is provided for taking the exosome loaded medicine as a delivery system, and the method can be suitable for the fields of health medical treatment, medical beauty cosmetics and biological medicine products.

The invention discloses a production method for reducing slag runners in a spring steel square billet casting process, which specifically comprises the following steps: the superheat degree of continuous casting molten steel is 20-40 DEG C, slag is automatically added into a continuous casting square billet, and casting powder is conveyed into a crystallizer by taking compressed air as a carrier, so that a high-concentration compressed air atmosphere at an upper opening of the crystallizer is ensured, and the casting quality is improved. And a combustion-supporting effect is achieved on the casting powder, so that the melting effect of the casting powder is improved. And the insertion depth of the submersed nozzle is 70-80mm, so that the higher temperature of molten steel on the meniscus of the crystallizer is ensured, and the slag surface melting effect is improved. The slag line is not changed in the casting process; the crystallizer uses vibration parameters with high vibration frequency and high amplitude, so that the negative slippage time and the vibration advance amount of the crystallizer are improved, the inflow of liquid casting powder in an air gap between a steel billet and a copper pipe is facilitated, and the slag runner phenomenon in the casting process of the casting blank is avoided.

The invention provides application of poly-2-acrylamide-2-methylpropanesulfonic acid in removal of residual lithium on the surface of a high-nickel NCM ternary material, and relates to the technical field of surface treatment of the high-nickel NCM ternary material. The method aims at solving the problem that an existing method for removing lithium carbonate on the surface of an NCM material through high-temperature calcination or high-concentration ethyl alcohol soaking and cleaning has adverse effects on the structure and performance of the high-nickel NCM ternary material. According to the invention, the cleaning agent using poly-2-acrylamide-2-methylpropanesulfonic acid as a main component is provided for cleaning the residual lithium of the high-nickel NCM ternary material, and verification proves that the high-nickel NCM ternary material can be effectively prevented from being damaged by existing high-temperature calcination and high-concentration ethanol soaking and cleaning treatment, and meanwhile, the electrochemical performance of the high-nickel NCM ternary material is remarkably improved.

The invention belongs to the technical field of back contact photovoltaic cells, and particularly relates to a back contact photovoltaic cell with high-concentration co-doped regions and a manufacturing method and application thereof.The back contact photovoltaic cell with the high-concentration co-doped regions is characterized in that N-type doped regions and P-type doped regions which are alternately distributed are arranged on the backlight face of an intrinsic amorphous silicon layer, and the high-concentration co-doped regions are arranged between the N-type doped regions and the P-type doped regions; a doping source of the co-doped region comprises doping source phosphorus of the N-type doped region and doping source boron of the P-type doped region, the co-doped region, the doping source of the N-type doped region and the doping source of the P-type doped region form a specific concentration gradient structure, and the specific concentration gradient structure meets the condition that the doping concentration of phosphorus contained in the co-doped region is greater than that of phosphorus contained in the N-type doped region; the doping concentration of boron contained in the co-doped region is greater than the doping concentration of boron in the P-type doped region. The carrier transport and collection efficiency is optimized, the fill factor and open-circuit voltage are improved, the cell conversion efficiency and stability are improved, the preparation process is simple, and multiple times of opening etching are not needed.

The invention discloses a method, a device, equipment and a medium for simulating migration of a proppant, and relates to the technical field of analogue simulation. Simulation is carried out through fluid dynamics and a discrete element analysis model, specifically, fluid parameters are obtained, a calculation model is constructed, and constraints are set; parameters are input for fluid and particle stress analysis, and particle displacement and grid updating are calculated; contact is judged through the particle collision sequence, boundary force is calculated, and the particle motion state is updated; and cyclically feeding back the flow field parameters to particle stress analysis until the number of iterations is met so as to obtain the void ratio, the flow velocity, the position and the momentum of the particles. According to the invention, the motion among particles can be captured and accurately calculated in a high-concentration particle flow or particle dominated collision system.

The invention relates to the technical field of laser particle size analyzers, in particular to a laser particle size analyzer with a double-ultrasonic structure, which comprises a particle size analyzer body, a sample pool is arranged on the particle size analyzer body, a sample dispersion mechanism for crushing particle blocks is arranged in the sample pool, and a stirring auxiliary mechanism for preventing suspended particles from settling is arranged above the sample pool. The stirring auxiliary mechanism can push the particles to a sound field strong area of the sample dispersion mechanism so as to improve the dispersion efficiency, and a splash-proof covering mechanism is arranged at the upper end of the sample pool. By arranging the sample dispersion mechanism and adopting a mode of combining phase orthogonality and material orthogonality layout, a stable three-dimensional acoustic vortex can be formed in the sample pool, and the coverage range of the ultrasonic cavitation effect can be obviously improved, so that the particle dispersion uniformity is improved, and the particle dispersion efficiency is improved. A detachable low-frequency ultrasonic vibrator is adopted at the bottom, so that the penetrating power of a high-concentration and high-viscosity sample is further enhanced, and dispersion dead angles can be effectively eliminated.

The invention belongs to the technical field of friction catalysis, and particularly relates to application of an aluminum oxide substrate in friction catalytic degradation of high-concentration organic dye wastewater, an aluminum oxide ceramic chip is used as a substrate, titanium dioxide nano powder is used as a catalyst, and the aluminum oxide ceramic chip is fixed at the bottom of a flat-bottom glass beaker; the method comprises the following steps: adding organic dye wastewater, a magnetic turntable and titanium dioxide nano powder into a flat-bottomed glass beaker, then putting the flat-bottomed glass beaker in a dark environment at room temperature, stirring and reacting on a magnetic stirrer for 90-150 minutes, and after the reaction is completed, completely degrading organic dye in the wastewater. According to the method, the aluminum oxide ceramic chip is added into a system for performing friction catalytic degradation on the organic dye wastewater by using the titanium dioxide nano powder as the substrate, so that the degradation rate of the organic dye is greatly improved, the complete degradation time of the organic dye is shortened, and a new thought is provided for performing friction catalytic degradation on the organic dye wastewater by using the titanium dioxide nano powder.

The present invention discloses a method for improving the extraction efficiency of single-chirality carbon nanotubes, a reagent composition and an application. The method comprises: mixing a reinforcing polymer, a chiral extracting polymer, a carbon nanotube raw material and a solvent, and then separating the obtained mixture to obtain a high-concentration single-chirality carbon nanotube solution. The method provided by the present invention greatly improves the concentration and separation efficiency of single-chirality carbon nanotubes while ensuring the purity of carbon nanotubes, and the improvement is about 10 times; at the same time, the method has universal applicability and is applicable to the extraction and separation of various carbon nanotubes such as (6, 5), (7, 5), (10, 5) and the like.

The invention relates to the technical field of dispersing agents, and particularly discloses a high-concentration water-based graphene dispersing agent. The high-concentration water-based graphene dispersing agent is prepared from the following raw materials in parts by weight: 25 to 30 parts of a modified nonionic surfactant, 8 to 12 parts of sodium lignin sulfonate, 0.4 to 0.8 part of a de-foaming agent and 90 to 100 parts of de-ionized water, the modified nonionic surfactant is prepared by the following steps: carrying out dehydration esterification reaction on 1-pyrene butyric acid and N-hydroxysuccinimide, carrying out nucleophilic substitution reaction on the obtained product and polyethylene glycol monododecyl ether to obtain modified 1-pyrene butyric acid, and finally polymerizing the modified 1-pyrene butyric acid and n-butyl acrylate. The method is easy to operate, graphene does not need to be subjected to oxidation reduction, the integrity of a graphene sheet layer can be completely kept, and the performance of the graphene can be fully exerted; the prepared graphene dispersing agent realizes efficient dispersing effect, excellent stability and environment-friendly safety characteristics, and provides solid technical support for wide application of graphene in multiple fields.

The invention is suitable for the technical field of inorganic luminescent materials, and provides a fluorescent powder material based on a double-perovskite structure and a preparation method and application thereof. The general chemical formula of the fluorescent powder is Ca2AlNbO6: xEu < 3 + >, wherein x is a molar fraction of 0.06 to 0.30; the excitation spectrum coverage range of the fluorescent powder under the condition of monitoring the emission wavelength of 615 nm is 260-500 nm, and the emission main peak is located at 615 nm; when x is equal to 0.18, the quantum efficiency under the excitation of 396nm ultraviolet light is greater than or equal to 91%, and the red light emission ratio is greater than or equal to 85%. According to the invention, Ca2AlNbO6 double perovskite is taken as a substrate, and a red fluorescent powder material with wide-spectrum excitation and high quantum efficiency is designed through Eu < 3 + > high-concentration doping and local symmetry regulation and control design engineering, so that the characteristics of high quantum efficiency, efficient red light emission, wide-spectrum excitation and excellent concentration quenching resistance are realized.

The present invention relates to a kind of silk fibroin hydrogel and preparation method thereof, silkworm raw silk is degummed, sol, dialyzed, filtered, freeze-dried to obtain silk fibroin freeze-dried powder, then redissolved into high concentration silk fibroin solution, filtered and spray-dried into silk fibroin microspheres; silk fibroin microspheres are slowly added to a phosphate buffered saline solution containing γ-polyglutamic acid and glutaraldehyde, stirred and ultrasonically carried out the first cross-linking, then a cross-linking agent solution is added, stirred evenly and ultrasonically, and the second cross-linking is carried out, and the silk fibroin hydrogel is obtained after being rinsed with pure water after being placed for a period of time. In the preparation method of the present invention, a phosphate buffered saline solution containing γ-polyglutamic acid and glutaraldehyde is used as a cross-linking agent and secondary cross-linking is carried out, and the prepared silk fibroin hydrogel silk fibroin has a long retention time, good stability and mechanical strength, and the cross-linking method is simple, and it is suitable for large-scale industrial production.