8028 results about "Reducing agent" patented technology

The invention relates to the field of concrete, and provides high-strength concrete and a preparation method thereof, and the high-strength concrete comprises modified basalt chopped fiber, a self-repairing agent, cement, fly ash, slag powder, coarse aggregate, natural sand, a water reducing agent and an air entraining agent. The modified basalt chopped fiber is oxidized by hydrogen peroxide, etched by hydrochloric acid and modified by a nano silicon dioxide coating, so that the interface bonding force is enhanced. The self-repairing agent is prepared by adopting expanded perlite to load bacillus through thallus culture, purification, dipping adsorption and low-temperature vacuum drying, CaCO3 deposition can be induced at concrete cracks, and self-repairing is achieved. The invention further provides a preparation method of the concrete. The preparation method comprises the steps of aggregate screening, hydrated liquid preparation, wet mixing, fiber and self-repairing agent adding, vibration forming and curing. The crack resistance of the concrete is improved by enhancing the fiber-matrix interface bonding force, meanwhile, the service life of the concrete is prolonged by utilizing a biological self-repairing technology, and the concrete is suitable for high-durability concrete engineering.

The invention relates to the technical field of drilling fluids, and discloses a lignite-based modified filtrate reducer for a drilling fluid and a preparation method of the lignite-based modified filtrate reducer. The lignite-based modified filtrate reducer for the drilling fluid is obtained by stirring and mixing the lignite grafted copolymer, the hydroxy propyl cellulose and the graphene oxide, drying and crushing. The steric effect generated by an oxazine ring, a pyridine ring, a triazine ring, a benzene ring and a pyrrole ring grafted into the lignite improves the temperature resistance and salt resistance of the filtrate reducer; the dispersing capacity of clay particles in a drilling fluid system is improved through sulfonic acid hydrated groups, and high-temperature coalescence of drilling fluid clay due to the high-temperature effect is avoided; a sulfonic acid anion group and a quaternary ammonium salt cation group are introduced into the filtrate reducer at the same time, so that the filtrate reducer can form a salt internal bond under the action of electrostatic force, and the salt resistance of the filtrate reducer is improved; the nano silicon dioxide increases the rigidity of the filtrate reducer, so that the filtrate reducer is not easy to curl under the conditions of high temperature and high salt.

The invention relates to the field of solidified soil, and particularly discloses solid-waste-based premixed flow-state solidified soil and a preparation method thereof. The solid-waste-based premixed flow-state solidified soil comprises soil, water and a curing agent according to the weight ratio of (28-36): (50-54): (6-9), according to the total weight of the curing agent, the curing agent comprises the following components in parts by weight: 20-40 parts of fly ash, 30-47 parts of slag, 6-18 parts of silica fume, 10-15 parts of sea sludge, 1-3 parts of a water reducing agent, 1-3 parts of sodium hydroxide, 1-3 parts of calcium sulphoaluminate, 3-10 parts of a fiber reinforced material and 1-3 parts of phosphate. The problems that stress generated by the solidified soil in the hydration process is excessively concentrated and shrinkage is excessive can be solved, and therefore cracking of the solidified soil subjected to premixed flow state solidification is reduced.

The invention discloses crack-chloride ion double-triggered subsea tunnel corrosion-resistant concrete and a preparation method thereof, and relates to the field of subsea tunnel engineering materials. The concrete is prepared from the following components in parts by weight: 400 to 500 parts of Portland cement, 50 to 80 parts of fly ash, 60 to 100 parts of superfine mineral powder, 1000 to 1100 parts of coarse aggregate, 700 to 800 parts of fine aggregate, 140 to 160 parts of water, 10 to 20 parts of self-repairing microcapsules and 1 to 5 parts of a water reducing agent, the self-repairing microcapsule comprises a capsule wall material, a self-repairing material and a layered dihydroxyl composite metal oxide. A crack-chloride ion double-response system is constructed, and the limitation of traditional single trigger repair is broken through. When a crack with a certain width appears in the concrete, the capsule wall of the self-repairing microcapsule is broken to release the repairing component, so that effective filling of the crack is realized; and meanwhile, the layered double-metal hydroxide can directionally adsorb chloride ions to form a stable compound, so that the migration rate of the chloride ions is remarkably reduced.

The invention discloses a high-purity quartz sand reinforced chlorination purification method, and belongs to the technical field of inorganic non-metallic material processing. The method comprises the following steps: putting a quartz sand raw material containing crystal structure impurities into a roasting furnace, and synchronously introducing a gas chlorinating agent and a gas reducing agent into the roasting furnace for roasting to obtain purified quartz sand. According to the method, on the basis of conventional chloridizing roasting purification, a gas reducing agent is introduced to regulate and control the reaction atmosphere, efficient dissociation and chlorination of crystal structure impurities difficult to remove are promoted, and deep efficient purification of quartz sand is achieved. The method has the advantages of simple process equipment, high raw material applicability, high impurity removal efficiency and the like, and can be widely applied to production of 4N5-grade and above high-purity quartz sand.

The invention relates to the technical field of building materials, and particularly discloses a high-performance solid-waste-based grouting material and a preparation method thereof. Comprising the following raw materials in parts by weight: 32 to 54 parts of Portland cement, 12 to 16 parts of a modified admixture, 2.4 to 3.6 parts of a functional filler, 42 to 56 parts of aggregate, 45 to 55 parts of a photoinitiator solution, 0.6 to 0.8 part of a water reducing agent, 0.9 to 1.1 parts of a composite expanding agent, 0.04 to 0.06 part of a defoaming agent and 9.2 to 12.4 parts of deionized water. Siloxane groups, acylamino groups, ester groups and benzene rings are chemically bonded on the surface of the modified admixture, so that the hydrophilicity of the modified admixture is reduced, the modified admixture can form hydrogen-bond interaction with hydroxyl groups and cement hydrates on the functional filler, and meanwhile, a flexible long-chain alkane structure on the functional filler can be entangled with the modified admixture, so that the flexibility of the modified admixture is improved. The mechanical property, the durability and the fluidity of the grouting material are improved.

The invention discloses silver-coated copper powder and a preparation method thereof, and creatively provides a technology for preparing the silver-coated copper powder by combining a chemical reduction method and a replacement method through process innovation and optimization aiming at the defects in the prior art, namely, copper powder is pretreated by acid and ammonia water and then is mixed with a reducing agent; and then the reducing agent is adsorbed on the surface of the copper powder, so that the reduction reaction is limited on the surface of the copper powder, and a uniformly-coated compact silver layer is formed on the surface of the copper powder. And in the replacement and reduction process, the organic solvent is used as a medium for dispersing the copper powder, the situation that a large amount of reducing agent exists in a dispersion medium can be effectively avoided, and then the phenomenon that pure silver powder particles are formed due to independent nucleation of the silver powder is well avoided. The technological process is simple and easy to operate, and the comprehensive performance of the prepared silver-coated copper powder is basically equivalent to that of pure silver powder conductive silver paste.

The invention relates to the field of microfluid chemical synthesis, and discloses a method for preparing gold nanoparticles based on two-phase flow microfluid control. The method comprises the following steps: 1) converging a gold precursor water phase, a reducing agent water phase and an organic phase in a micro-fluidic chip at 0-25 DEG C to form water-in-oil liquid drops; (2) conveying the fluid to a mixing area channel of a micro-fluidic chip, and carrying out instantaneous nucleation reaction to form a gold nanoparticle prototype; 3) conveying the fluid into a capillary reactor, and further nucleating, growing and curing the gold nanoparticle prototype; and (4) the fluid is subjected to phase splitting, and a gold nanoparticle solution is obtained. A three-in-one micro-fluidic chip is adopted, process parameters are optimized, and a gold precursor and a reducing agent are wrapped in an organic phase before reaction to form water-in-oil liquid drops, so that on one hand, the situation of adsorption and scaling of the inner wall of a channel can be avoided, and on the other hand, the heat and mass transfer efficiency of a material can be improved through the generated liquid drops; and the uniformity of a reaction nucleation environment is ensured.

The invention provides an early-strength rapid-repair grouting material and a preparation method thereof, and the early-strength rapid-repair grouting material is mainly prepared from the following raw materials: 50 to 150 parts of sulphoaluminate cement, 10 to 150 parts of aluminate cement, 200 to 350 parts of a regenerated gelling powder material, 1200 to 1400 parts of quartz sand, 50 to 100 parts of silica fume, 10 to 150 parts of mineral powder, 10 to 100 parts of fly ash, 15 to 50 parts of a composite retarder, 0.1 to 2 parts of a water reducing agent and 1 to 10 parts of an early strength agent. 0.01 to 1 part of a water-retaining agent and 200 to 300 parts of water. The early-strength quick-repair grouting material is characterized in that activated low-cementitious active mineral solid waste is adopted as a main cementitious material, and the product has excellent construction stability, low-carbon weather resistance, corrosion resistance, micro-expansion quick-hardening early strength and economical efficiency.

The present disclosure is directed to a processing solution composition comprising a metal salt, an acid, a solvent, and a non-metal reductant. The present disclosure is also directed to a method of impregnating a porous material by covering or coating the porous material with a processing solution comprising a metal salt, an acid, a solvent, and a non-metal reductant.

The invention provides a modified coal gangue-based large-flow-state grouting and water plugging material and a preparation method thereof. Comprising 80-90 parts of a coal gangue sample, 1-5 parts of Portland cement, 1-5 parts of sulphoaluminate cement, 0.51-3 parts of a polycarboxylic acid water reducing agent, 1-4 parts of cellulose ether with the viscosity of 200w, 0.1-5 parts of a calcium oxide expanding agent, 0.5-5 parts of a plastic expanding agent, 0.5-1 part of redispersible latex powder, 0.5-5 parts of polyacrylamide with the molecular weight of 1000 and water, and the water-material ratio is 0.4. According to the modified coal gangue-based large-flow-state grouting and water plugging material and the preparation method thereof, the cement consumption can be remarkably reduced, the cost is reduced, the utilization rate of solid wastes (such as coal gangue) is increased, and the material has good flow-state performance and adjustable setting time; the method is suitable for deep and large shaft surrounding rock water seepage treatment in coal mining and other mine engineering.

The invention discloses a direct-current hollow electrode hydrogen plasma furnace mineral powder smelting system and method and application, and belongs to the technical field of hydrogen metallurgy. The system comprises a hollow electrode gas powder injection hydrogen plasma gun system, a direct current bottom electrode ore-smelting electric furnace system, a fine ore and hydrogen supply system and the like. The hollow electrode and the furnace bottom electrode form a direct-current arc, hydrogen carrying mineral powder is sprayed into an arc area to generate high-temperature hydrogen plasma, mineral powder reduction is achieved, and metal and slag are separated. According to the method, hydrogen serves as a reducing agent, carbon emission is reduced, the reaction efficiency is high, energy consumption is low, and the method can be used for steelmaking, smelting of micro-carbon ferromanganese and titanium slag and recovery of valuable metal in nonferrous smelting waste slag and has good green metallurgy application prospects.

The invention discloses a method for recovering lithium, nickel cobalt manganese composite hydroxide and aluminum copper powder from a waste ternary lithium ion battery pole piece. The method comprises the following steps: treating waste pole pieces of a ternary plant or a mixture of positive and negative pole pieces by using a Fenton technology, leaching by using a mixed ferric salt solution, and filtering to obtain lithium-containing leachate and slag; adjusting the pH value of the leachate, oxidizing and filtering to obtain a purified solution and ferric hydroxide precipitate, and adding the purified solution and a lithium hydroxide solution into a reactor for coprecipitation to obtain a deeply purified solution and the nickel-cobalt-manganese composite hydroxide. And dissolving the ferric hydroxide precipitate with dilute acid, adding a reducing agent to generate a ferrous salt solution, and returning the ferrous salt solution for Fenton reaction and leaching reaction. And adding the sodium carbonate saturated solution into the deep purification solution, and crystallizing and precipitating to obtain the battery-grade lithium carbonate. And performing hydrodynamic screening on the leaching residues to obtain an aluminum-copper mixture and graphite residues, and performing grinding and specific gravity separation on the aluminum-copper mixture to obtain high-purity aluminum powder and copper powder. According to the method, the iron salt is directly leached from the pole piece, the used iron salt can be recycled, and the method is suitable for large-scale recovery of the waste ternary lithium ion battery.

The invention provides a treatment method of copper-nickel concentrate rich in platinum group metals, which comprises the following steps: feeding the copper-nickel concentrate rich in platinum group metals and a first flux into a smelting furnace, and introducing first oxygen-enriched gas for smelting; copper matte and a second flux are continuously fed into a first converting furnace, and second oxygen-enriched gas is continuously introduced for first converting; raw copper and a third flux are fed into the oxygen inclined blowing rotary converter, and oxygen is introduced for second blowing; the crude copper is fed into an anode refining furnace, and air and a first reducing agent are introduced for fire refining; casting the copper liquid into an anode plate, and carrying out electrolytic refining on the anode plate; feeding the first converting slag, the second converting slag, a second reducing agent and a vulcanizing agent into a dilution electric furnace for slag dilution to obtain low-nickel matte and dilution slag; and the low-nickel matte is fed into a third converting furnace, air or oxygen-enriched air is introduced for third converting, and the problem that the recovery rate of nickel metal elements and platinum group metals in the copper-nickel concentrate rich in the platinum group metals is low is solved.

The invention relates to the technical field of additives for concrete, and particularly discloses a waterproof synergistic interface agent, an interface permeation type water reducing agent mother solution, an interface permeation type water reducing agent and a preparation method of the interface permeation type water reducing agent. The waterproof synergistic interface agent is prepared from the following raw materials: organic acid modified nano inorganic powder and polyhydroxy acrylate. Through the design of the raw materials of the waterproof synergistic interface agent, the surface active groups, the adsorption performance and the dispersity of the nano inorganic powder are increased, the grafting degree of polyhydroxy acrylate with other large monomers, small monomers and functional monomers is improved, the polyhydroxy acrylate is grafted or dispersed in a water reducing agent mother solution through a polymerization reaction, and the waterproof synergistic interface agent is prepared. By combining the synergistic anti-seepage filling effect of the nano inorganic powder, the internal phase interface structure of the concrete is improved, the adhesiveness of different interfaces and the binding force of new and old concrete interfaces are increased, and the hydration hardening product can improve the compactness and toughness of the concrete and improve the ion penetration resistance and mechanical property of the concrete; the problem that an existing water reducing agent is single in function is solved.

The invention discloses a high belite sulphoaluminate cement-based two-component grouting material and a preparation method thereof. The grouting material comprises a gelling component and a coagulating reinforcing component, wherein the gelling component is prepared from a high belite sulphoaluminate cement clinker and an additive A; the admixture A comprises a water reducing agent, a retarder and slow-release minerals; the coagulating and reinforcing component comprises ordinary Portland cement clinker, calcium hydroxide, gypsum and an additive B; the admixture B comprises a water reducing agent and an early strength agent. According to the high belite sulphoaluminate cement-based grouting material, the formula composition of the high belite sulphoaluminate cement-based grouting material is optimized, so that the hydration process of the high belite sulphoaluminate cement is more continuous and lasting, and the compressive strength of the obtained high belite sulphoaluminate cement-based grouting material can be continuously improved.

The invention provides a lead-free high-phosphorus chemical nickel plating solution, and relates to the technical field of chemical nickel plating, and the lead-free high-phosphorus chemical nickel plating solution comprises the following components: 4-10 g / L of nickel salt, 6-12 g / L of a complexing agent, 0.1-0.8 g / L of a brightener, 8-12 g / L of a reducing agent, 0.4-0.8 g / L of a stabilizer, 1-5 g / L of a plating starting agent, 0.1-0.6 g / L of an anti-cracking agent, 0.5-1.5 g / L of an accelerator and 0.1-0.5 g / L of a wetting agent. The excellent chemical nickel-plating process of the circuit board and the carrier plate can be realized, and the chemical nickel-plating solution has the characteristics of high deposition rate, excellent stability, brightness, smoothness, no skip plating or diffusion plating, excellent binding force and the like.

The invention provides a method for recycling lithium iron phosphate, which comprises the following steps: S1, obtaining lithium iron phosphate black powder, and washing the lithium iron phosphate black powder by using alkali liquor to obtain aluminum-removed black powder and aluminum-containing lithium filtrate; s2, the aluminum-removed black powder is subjected to acid leaching treatment with acid liquor, and acid leaching liquor is obtained; s3, carrying out reduction precipitation treatment on the acid leaching solution by using a composite reducing agent to obtain a copper-removed leaching solution and solid-phase copper-containing slag; s4, adding a phosphorus source and an oxidizing agent into the copper-removed leaching solution, adding alkali to adjust the pH value, and carrying out oxidation precipitation treatment to obtain iron phosphate precipitate and a first lithium-containing solution; and S5, adjusting the pH value of the aluminum-lithium-containing filtrate in the step S1 by using an acid solution to obtain aluminum filter residues and a second lithium-containing solution. According to the method, iron phosphate with relatively high purity can be obtained; meanwhile, the obtained first lithium-containing solution and the second lithium-containing solution are relatively low in impurity ion content and can be used for obtaining a lithium salt product with relatively high purity.

The invention belongs to the technical field of creatine kinase detection kits, and particularly relates to a creatine kinase detection reagent, a creatine kinase detection kit and application, the creatine kinase detection reagent comprises a buffer solution, creatine phosphate, glycerol, glycerol kinase, glycerophosphate oxidase, peroxidase and a color developing agent, and further comprises a CK activation reducing agent and perfluoro and polyfluoroalkyl substances, the CK activation reducing agent is a sulfur-containing reducing agent. According to the method, the detection accuracy can be improved.

The invention discloses a preparation method of a silicon-based quantum dot tracer. The silicon-based quantum dot tracer agent disclosed by the invention is prepared by taking 3-aminopropyltrimethoxysilane, sodium citrate, urea and deionized water as raw materials and adopting a hydrothermal synthesis method. The silicon-based quantum dot tracer agent is synthesized by using 3-aminopropyltrimethoxysilane as a silicon source and using the synergistic effect of double reducing agents of sodium citrate and urea, the synthesized silicon-based quantum dot tracer agent can overcome the influence of temperature and environment on the silicon-based quantum dot tracer agent, the fluorescence lifetime is prolonged, and the silicon-based quantum dot tracer agent has a relatively small particle size and can be used for preparing the quantum dot tracer agent. And inter-well tracer testing and single-well chemical testing technology research of an on-site oil field are facilitated.

The invention belongs to the field of grouting materials, and discloses a composite grouting material as well as a preparation method, a construction method and application thereof. The composite grouting material comprises the following components: sulphoaluminate cement clinker powder, Portland cement clinker powder, a reinforcing agent, a coagulant and a modifier, the reinforcing agent comprises superfine mineral powder, superfine fly ash, silica fume and calcium sulfate whiskers; the coagulant comprises alumina clinker powder, calcium hydroxide, lithium carbonate and aluminum hydroxide; the modifier comprises a shrinkage reducing agent, a thickening agent, a water reducing agent and a retarder. The composite grouting material has the advantages of being good in pumpability, short in gelation time, free of plastic shrinkage, high in early strength, good in volume stability, high in durability, appropriate in price, environmentally friendly, free of toxicity and the like, and the requirement for rapid grouting maintenance is met in the subway operation window period.

The invention relates to the technical field of cement mortar compositions, and particularly discloses a double-component anti-freezing early-strength slurry and a preparation method and application thereof. The double-component anti-freezing early-strength slurry provided by the invention is composed of a component A and a component B in a weight ratio of 25: (4-10), the component A is prepared from the following components in parts by weight: 250 to 280 parts of Portland cement, 90 to 100 parts of admixture, 145 to 165 parts of sand and 6.4 to 8.4 parts of water reducing agent; and the component B comprises the following components in parts by weight: 8-10 parts of a sodium nitrite antifreeze agent, 50-58 parts of a reinforcing aid, 32-40 parts of anhydrite, 240-270 parts of an admixture, 155-175 parts of sand and 4.1-6.1 parts of a water reducing agent. By utilizing the technical scheme, the prepared double-component anti-freezing early-strength slurry has the advantages of rapid development of early compressive strength and stable growth of later compressive strength under different ultralow temperature conditions.

The invention discloses gold-titanium alloy nanoparticles as well as a wet chemical preparation method and application thereof. The preparation method comprises the following steps: in a water-free and oxygen-free environment, uniformly dissolving a gold salt, a titanium salt and a support carrier in an ether solvent, mixing with lithium triethylborohydride, transferring into a high-pressure reaction kettle, stirring and heating to 180-220 DEG C under the inert gas pressure of 0.5-1 MPa, and keeping the temperature for 1-4 hours; and after the mixture is cooled to the room temperature, the product solution is diluted with normal hexane, cleaning and drying are conducted, and the gold-titanium alloy nanoparticles are obtained. According to the invention, gold salt and titanium salt adsorbed on a support carrier are reduced by using a strong reducing agent under the conditions of high temperature and high pressure, and highly dispersed nanoparticles with uniform particle size are prepared; by introducing the supporting carrier, the problem that the particle size is increased due to agglomeration of alloy nanoparticles at high temperature is avoided, the catalytic performance and the anti-sintering performance of the catalyst are enhanced through strong interaction with the carrier, and the catalyst has wide application prospects in the fields of CO thermal oxidation and CO electrochemical oxidation.

The invention relates to the technical field of concrete, in particular to luminous pervious concrete and a preparation method thereof. The luminous permeable concrete is prepared from the following raw materials in parts by mass: 280-300 parts of cement, 870-900 parts of interval grading coarse aggregate, 70-80 parts of modified luminous powder, 30-40 parts of fly ash, 4-6 parts of a water reducing agent, 20-30 parts of a water repellent agent, 30-40 parts of epoxy resin, 3-5 parts of a silane coupling agent and 90-100 parts of water, and the interval grading coarse aggregate is prepared by mixing coarse aggregate with a small particle size of 4.95-9mm and coarse aggregate with a large particle size of 12.5-10mm according to a mass ratio of 1: 2; the surface of the modified luminescent powder is coated with silicon dioxide sol, and sodium borate is added for heat-resistant treatment. The light-emitting water-permeable concrete has compressive strength and water permeability, the light-emitting property is stable, and the hydrophobic and oleophobic corrosion resistance in the concrete is good.

The invention discloses silver powder with a high twin crystal ratio and a preparation method and application of the silver powder with the high twin crystal ratio. The preparation method comprises the following steps that S1, a carboxylic acid coordination agent is added into a silver source solution, and a silver precursor solution is obtained; sequentially adding a dispersing agent and an initiator into the reducing agent solution to obtain a reaction base solution; s2, a silver precursor solution is added into the reaction base solution for an oxidation-reduction reaction, then curing is conducted, and mixed mother liquor is obtained; s3, the mixed mother liquor is filtered, washed, dispersed and dried, and then the silver powder with the high twin crystal proportion is obtained; the initiator comprises one or more of sulfate, carbonate and nitrate; through the synergistic effect of the initiator and the carboxylic acid coordination agent, the silver ion release rate and the crystal nucleus preferential growth direction are regulated and controlled, the rapid feeding and curing technology is combined, the low supersaturation environment is constructed, the silver powder is induced to grow in the specific direction, and the twin crystal proportion is remarkably increased.

The invention discloses a preparation method of high-purity diiodosilane, which comprises the following steps: firstly, preparing a p-phenylsilane solution from phenyl trichlorosilane and sodium hydride as raw materials, rectifying and purifying the p-phenylsilane solution, directly reacting the p-phenylsilane solution with iodine to generate diiodosilane, and reacting phenylsilane with iodine to directly generate diiodosilane; in the process of preparing diiodosilane from phenylsilane, conditions are mild, the reaction process is controllable, the reaction time is shortened by controlling the temperature in the synthesis process and increasing the pressure of a reaction system, hydrogen iodide overflow is reduced, sodium hydride is adopted as a reducing agent in the reaction process, and the yield of diiodosilane is increased. The solid waste can be recycled, the cost can be effectively reduced, and industrialization of diiodosilane is facilitated.

The invention discloses high-crystallinity superfine nickel powder and a preparation method thereof.The generation size of nickel powder in a liquid phase is adjusted through ultrasonic waves, molten salt heat treatment is combined to obtain the high-crystallinity superfine nickel powder, and the preparation method specifically comprises the following steps that an aqueous solution in which a nickel precursor is dissolved is mixed with a reducing agent; under the action of ultrasonic waves, an alkaline solution is added for a reaction, and nickel powder particles with the adjustable particle size are prepared; and then uniformly mixing the nickel powder with combined salts in different proportions, carrying out heat treatment at different temperatures, and cleaning and separating a cooled product to finally obtain the high-crystallinity superfine nickel powder with the size of 100-200nm. The nickel powder has good size uniformity, oxidation resistance and thermal shrinkage resistance, and can be applied to various fields such as conductive paste, metal electrodes and magnetic shielding materials.

The invention provides a system and a method for treating coexisting new pollutants in drinking water, and the system and the method are characterized in that firstly, ozone microbubble water with small volume and large specific surface area and magnetized superfine activated carbon are used for carrying out oxidation treatment on the coexisting new pollutants and adsorbing pollutants with small molecular weight and relatively high activity; the purpose of removing part of new pollutants is achieved; then, under the irradiation of an ultraviolet lamp tube, the reducing agent catalyzes sulfite to generate reducing free radicals such as hydration electrons [eaq-],. H and SO3., and under the substitution action of iodide ions, reductive dehalogenation and iodine substitution reaction of the halogenated organic matter difficult to degrade are achieved, and reduction removal of new pollutants difficult to degrade is achieved. The system is simple and compact in structure, is a treatment device integrating filtration, oxidation, adsorption and reduction, reduces the occupied area, can realize effective removal of coexisting new pollutants with different molecular characteristics and different reaction activities through multiple actions of physical interception, oxidation, adsorption, reduction and the like, and has a wide application prospect.

The invention provides a dump leaching method for improving the leaching rate of gold ore, and belongs to the technical field of mineral processing. The method comprises the following steps: firstly, separating minerals into oversize products and undersize products; mixing sodium carboxymethyl cellulose, bentonite and ferrous sulfate to obtain a mixture, and granulating the undersize product by using the mixture as a binder; and mixing the undersize product particles with the oversize product, and carrying out cyanide-free dump leaching. According to the method, through graded granulation and heap building, the problem that heap building permeability is poor due to the fact that the gold ore contains many clay minerals is solved. In the granulation stage, ferrous hydroxide colloid generated by hydrolysis of ferrous sulfate in the binder can assist ore particle agglomeration, and particle stability is enhanced; during subsequent cyanide-free dump leaching, ferrous sulfate can be used as an auxiliary reducing agent and a catalyst in a thiourea gold leaching system to promote oxidation and dissolution of gold; meanwhile, ferrous ions can adjust the oxidation-reduction potential of a system, so that the thiourea gold leaching reaction is in a more favorable potential interval, the oxidation efficiency of thiourea is improved, invalid decomposition of thiourea is reduced, and therefore the use amount of thiourea and the use amount of agents are reduced.

The invention discloses high-crystallinity smooth silver powder, preparation of the high-crystallinity smooth silver powder and silver paste containing the high-crystallinity smooth silver powder. A preparation method of the silver powder comprises the following steps that a silver ammonia solution is obtained; the pH value of the silver-ammonia solution is adjusted to be alkaline through a pH adjusting agent, then a stabilizer is added, ultrasonic treatment is conducted, and silver crystal nucleuses are obtained; sequentially adding a charge control agent and a silver crystal nucleus into the dispersing agent solution, and uniformly stirring to obtain a reaction base solution; and the oxidant solution and the reducing agent solution are dropwise added into the reaction base solution at the same time, stirring reaction is conducted, and the high-crystallinity smooth silver powder is obtained. The mechanism for preparing the high-crystallinity smooth silver powder is mainly reflected in precise regulation and control of silver crystal nucleation, growth and surface modification, and the comprehensive characteristics of smooth particle surface, clear edges, high crystallinity and small particle size are achieved through the multi-factor synergistic effect.