11271 results about "Reducing agent" patented technology

The invention relates to the field of concrete, and provides high-strength concrete and a preparation method thereof, and the high-strength concrete comprises modified basalt chopped fiber, a self-repairing agent, cement, fly ash, slag powder, coarse aggregate, natural sand, a water reducing agent and an air entraining agent. The modified basalt chopped fiber is oxidized by hydrogen peroxide, etched by hydrochloric acid and modified by a nano silicon dioxide coating, so that the interface bonding force is enhanced. The self-repairing agent is prepared by adopting expanded perlite to load bacillus through thallus culture, purification, dipping adsorption and low-temperature vacuum drying, CaCO3 deposition can be induced at concrete cracks, and self-repairing is achieved. The invention further provides a preparation method of the concrete. The preparation method comprises the steps of aggregate screening, hydrated liquid preparation, wet mixing, fiber and self-repairing agent adding, vibration forming and curing. The crack resistance of the concrete is improved by enhancing the fiber-matrix interface bonding force, meanwhile, the service life of the concrete is prolonged by utilizing a biological self-repairing technology, and the concrete is suitable for high-durability concrete engineering.

Provided herein are methods and apparatus for deposition of pure metal films. The methods involve the use of oxygen-containing precursors. The metals include molybdenum (Mo) and tungsten (W). To deposit pure films with no more than one atomic percentage oxygen, the reducing agent to metal precursor ratio is significantly greater than 1. Molar ratios of 100:1 to 10000:1 may be used in some embodiments.

The invention discloses a waste lithium iron phosphate positive electrode material recycling method and a lithium iron phosphate material, and the method comprises the following steps: calcining a waste lithium iron phosphate positive electrode material to obtain a lithium iron phosphate / carbon powder material; the element content of the lithium iron phosphate / carbon powder is obtained, and the amount of lithium, iron and phosphorus needing to be supplemented is determined; lithium, iron and phosphorus are supplemented to the lithium iron phosphate / carbon powder, then a reducing agent is added and mixed, a mixture is obtained, and the reducing agent comprises at least one of a non-amino acid reducing agent and an amino acid reducing agent; and calcining the mixture to obtain the recycled and regenerated lithium iron phosphate material. According to the method, elements missing in the waste lithium iron phosphate material are analyzed and supplemented, and the type of the reducing agent is adjusted, so that efficient repair of the waste lithium iron phosphate material is realized. The repairing efficiency of the waste lithium iron phosphate material is high, and the battery assembled by the repaired lithium iron phosphate material has excellent rate capability and cycle performance.

The invention relates to the technical field of drilling fluids, and discloses a lignite-based modified filtrate reducer for a drilling fluid and a preparation method of the lignite-based modified filtrate reducer. The lignite-based modified filtrate reducer for the drilling fluid is obtained by stirring and mixing the lignite grafted copolymer, the hydroxy propyl cellulose and the graphene oxide, drying and crushing. The steric effect generated by an oxazine ring, a pyridine ring, a triazine ring, a benzene ring and a pyrrole ring grafted into the lignite improves the temperature resistance and salt resistance of the filtrate reducer; the dispersing capacity of clay particles in a drilling fluid system is improved through sulfonic acid hydrated groups, and high-temperature coalescence of drilling fluid clay due to the high-temperature effect is avoided; a sulfonic acid anion group and a quaternary ammonium salt cation group are introduced into the filtrate reducer at the same time, so that the filtrate reducer can form a salt internal bond under the action of electrostatic force, and the salt resistance of the filtrate reducer is improved; the nano silicon dioxide increases the rigidity of the filtrate reducer, so that the filtrate reducer is not easy to curl under the conditions of high temperature and high salt.

The invention relates to the field of solidified soil, and particularly discloses solid-waste-based premixed flow-state solidified soil and a preparation method thereof. The solid-waste-based premixed flow-state solidified soil comprises soil, water and a curing agent according to the weight ratio of (28-36): (50-54): (6-9), according to the total weight of the curing agent, the curing agent comprises the following components in parts by weight: 20-40 parts of fly ash, 30-47 parts of slag, 6-18 parts of silica fume, 10-15 parts of sea sludge, 1-3 parts of a water reducing agent, 1-3 parts of sodium hydroxide, 1-3 parts of calcium sulphoaluminate, 3-10 parts of a fiber reinforced material and 1-3 parts of phosphate. The problems that stress generated by the solidified soil in the hydration process is excessively concentrated and shrinkage is excessive can be solved, and therefore cracking of the solidified soil subjected to premixed flow state solidification is reduced.

Metal films, such as molybdenum films are deposited on a semiconductor substrate having one or more recessed features in a deposition process modulated by addition of a halogen-containing compound (e.g., an alkyl halide). In some implementations, a pre-treatment of a substrate with a halogen-containing compound is performed prior to contacting the substrate with a metal-containing precursor and a reducing agent. In some embodiments, the pre-treatment is performed such that the halogen-containing compound modifies the surface of the substrate to a greater degree in a field region of the substrate and near the opening of the recessed feature, as compared to the bottom portion of the recessed feature, where the modification of the substrate inhibits deposition of the metal. As a result, deposition of metals with improved step coverage can be achieved. In some implementations, modulation of deposition by halogen-containing compounds is used to achieve bottom-up metal growth in recessed features.

The invention discloses crack-chloride ion double-triggered subsea tunnel corrosion-resistant concrete and a preparation method thereof, and relates to the field of subsea tunnel engineering materials. The concrete is prepared from the following components in parts by weight: 400 to 500 parts of Portland cement, 50 to 80 parts of fly ash, 60 to 100 parts of superfine mineral powder, 1000 to 1100 parts of coarse aggregate, 700 to 800 parts of fine aggregate, 140 to 160 parts of water, 10 to 20 parts of self-repairing microcapsules and 1 to 5 parts of a water reducing agent, the self-repairing microcapsule comprises a capsule wall material, a self-repairing material and a layered dihydroxyl composite metal oxide. A crack-chloride ion double-response system is constructed, and the limitation of traditional single trigger repair is broken through. When a crack with a certain width appears in the concrete, the capsule wall of the self-repairing microcapsule is broken to release the repairing component, so that effective filling of the crack is realized; and meanwhile, the layered double-metal hydroxide can directionally adsorb chloride ions to form a stable compound, so that the migration rate of the chloride ions is remarkably reduced.

The invention discloses a jet type high-toughness fiber reinforced cement-based composite material and a preparation method thereof, and belongs to the technical field of material preparation. The invention provides a jet type high-toughness fiber reinforced cement-based composite material, which is prepared from the following raw materials in parts by mass: 320 to 400 parts of coarse aggregate, 220 to 260 parts of fine aggregate, 90 to 110 parts of cement, 40 to 50 parts of water, 10 to 15 parts of modified fiber, 5 to 10 parts of zeolite powder, 5 to 10 parts of polymerizing agent, 4 to 7 parts of accelerator and 2 to 5 parts of water reducing agent. The chemical bonding force of the fiber and the concrete interface is improved, meanwhile, the mechanical property of a hydration product at the interface is improved, the dispersity of the fiber in the concrete is improved, and the stress transmission and dispersion capacity of the fiber is effectively enhanced, so that the mechanical property and durability of the fiber concrete are enhanced.

The invention discloses a high-purity quartz sand reinforced chlorination purification method, and belongs to the technical field of inorganic non-metallic material processing. The method comprises the following steps: putting a quartz sand raw material containing crystal structure impurities into a roasting furnace, and synchronously introducing a gas chlorinating agent and a gas reducing agent into the roasting furnace for roasting to obtain purified quartz sand. According to the method, on the basis of conventional chloridizing roasting purification, a gas reducing agent is introduced to regulate and control the reaction atmosphere, efficient dissociation and chlorination of crystal structure impurities difficult to remove are promoted, and deep efficient purification of quartz sand is achieved. The method has the advantages of simple process equipment, high raw material applicability, high impurity removal efficiency and the like, and can be widely applied to production of 4N5-grade and above high-purity quartz sand.

The invention provides a preparation method for regenerating waste lithium iron phosphate into sodium ferric pyrophosphate, and belongs to the technical field of battery material production.The recovery process comprises the steps that a high-grade oxide serves as an oxidizing agent, a waste lithium iron phosphate positive electrode material and a current collector are stripped under the acid or strong alkaline condition, and lithium iron phosphate is oxidized; recovering to obtain iron phosphate containing impurities and a solution containing lithium ions; in the regeneration process, recycling slag obtained in the recycling process is uniformly mixed with a sodium source and a phosphorus source, sintering regeneration is performed to prepare ferric sodium pyrophosphate, conductive carbon in waste lithium iron phosphate is used as a reducing agent, and a high-performance ferric sodium pyrophosphate positive electrode material is obtained without an additional reducing agent; recycled slag obtained in the recycling process mainly comprises high-purity iron phosphate, and the content of impurities can be controlled to be 0.1% or below by controlling the solid-to-liquid ratio, the temperature and the reaction time in the recycling process.

The invention belongs to the technical field of solar cell materials, and particularly relates to silver-coated copper powder and a preparation method thereof. A preparation method of silver-coated copper powder comprises the following steps that copper powder subjected to surface activation through an acid-base solution and a complexing agent are dissolved in water, and copper powder turbid liquid is obtained; dropwise adding a silver source solution into the copper powder turbid liquid to carry out a replacement reaction, and adjusting the pH value of the solution after the reaction to obtain a silver-coated copper powder precursor turbid liquid; and dropwise adding a reducing agent solution into the silver-coated copper powder precursor turbid liquid, then dropwise adding a silver source solution, carrying out oxidation-reduction reaction, carrying out solid-liquid separation, washing, and drying to obtain the silver-coated copper powder. According to the preparation method provided by the invention, in the chemical oxidation reduction process, the silver-coated copper powder with different silver layer distribution structures, compact silver coating structure and better performance is obtained by regulating and controlling the dropping sequence and dropping rate of the reducing agent solution and the silver source solution.

The invention discloses preparation of an ionic porous nitrogen-rich molecular cage and application of the ionic porous nitrogen-rich molecular cage in purification of iodine-containing nuclear medical waste, and the preparation method comprises the following steps: taking an ammonia or amine reagent as a bridge, taking an aldehyde or ketone reagent as a reaction monomer, adopting a Schiff base reaction principle, and utilizing a polydentate coordination mode to carry out imine condensation reaction on substances through a one-pot method to obtain the ionic porous nitrogen-rich molecular cage. Generating a porous nitrogen-rich molecular cage; then adding a reducing agent to further reduce the porous nitrogen-rich molecular cage, then combining with alkyl halide and an organic solvent, stirring, and carrying out rotary evaporation to obtain the ionic porous nitrogen-rich molecular cage. The method has the beneficial effects that a porous organic cage material with an ionic nitrogen-rich ligand is selected as an adsorbent, so that the physical and chemical properties are stable; the preparation method is simple in synthesis and high in yield, and the nitrogen-rich ligand is stable in structure, can adsorb iodine in a gas phase and iodine in a water phase, and can be recycled; the ion interference resistance is high, and the method adapts to iodine adsorption under the water phase condition that the pH is 3-11; the method can be applied to treatment of iodine in nuclear medical wastewater.

The invention relates to the technical field of building materials, and particularly discloses a high-performance solid-waste-based grouting material and a preparation method thereof. Comprising the following raw materials in parts by weight: 32 to 54 parts of Portland cement, 12 to 16 parts of a modified admixture, 2.4 to 3.6 parts of a functional filler, 42 to 56 parts of aggregate, 45 to 55 parts of a photoinitiator solution, 0.6 to 0.8 part of a water reducing agent, 0.9 to 1.1 parts of a composite expanding agent, 0.04 to 0.06 part of a defoaming agent and 9.2 to 12.4 parts of deionized water. Siloxane groups, acylamino groups, ester groups and benzene rings are chemically bonded on the surface of the modified admixture, so that the hydrophilicity of the modified admixture is reduced, the modified admixture can form hydrogen-bond interaction with hydroxyl groups and cement hydrates on the functional filler, and meanwhile, a flexible long-chain alkane structure on the functional filler can be entangled with the modified admixture, so that the flexibility of the modified admixture is improved. The mechanical property, the durability and the fluidity of the grouting material are improved.

The present disclosure belongs to the technical field of silver powder preparation, and particularly relates to a method for preparing a silver powder having adjustable sintering activity, and a conductive silver powder and the use thereof. The preparation method comprises the following steps: S1, subjecting a reducing agent, a sintering regulator, a dispersing agent and water to primary mixing, then adding an oxidizing agent solution under stirring conditions, and reacting same after the addition is finished, wherein a surfactant is introduced during the primary mixing and / or the surfactant is introduced into the oxidizing agent solution; and S2, filtering the material obtained in S1, then subjecting the material and a coating liquid containing a coating agent to secondary mixing, and then drying the mixture, so as to obtain a silver powder. The present disclosure can result in a silver powder having different sintering activities, and can satisfy usage scenarios of carrying out sintering in different temperature sections, such as the use in different temperature scenarios including low-temperature sintering and high-temperature sintering; and during the silver powder preparation process of the present disclosure, no slurry is formulated, and the sintering activity of the silver powder is directly tested by means of a thermal mechanical analyzer, such that the development process is more convenient, and characterization is more accurate.

The invention relates to a method for extracting vanadium from a vanadium slag roasting product and preparing vanadium oxide or vanadyl sulfate, which comprises the following steps of: crushing the vanadium slag roasting product, grinding, carrying out synchronous reduction leaching in a leaching medium, regulating the pH value of a leaching solution to 0-5 by using a pH regulator, and carrying out solid-liquid separation on the leaching medium and the roasting product according to the liquid-solid ratio of (3-20): 1, so as to obtain the vanadium oxide or vanadyl sulfate. And leaching liquid containing positive divalent vanadium oxygen ions is obtained. According to the method, when the vanadium slag roasting product is leached, the reducing agent is added to directly control the valence state of vanadium in the leaching solution, tetravalent vanadium with the stable valence state is obtained, the problem that the vanadium leaching efficiency is low due to the fact that pentavalent vanadium ions are prone to hydrolysis is solved, vanadium oxyhydroxide is prepared in combination with a selective precipitation method, VO2 or V2O5 is prepared through calcination under different atmospheres, and the method is suitable for industrial production. Or in-situ extraction-reverse extraction is carried out in the reduction leachate to prepare vanadyl sulfate. The method is short in process, high in vanadium yield, compact in process linkage, less in three wastes and easy to industrialize.

The invention discloses silver-coated copper powder and a preparation method thereof, and creatively provides a technology for preparing the silver-coated copper powder by combining a chemical reduction method and a replacement method through process innovation and optimization aiming at the defects in the prior art, namely, copper powder is pretreated by acid and ammonia water and then is mixed with a reducing agent; and then the reducing agent is adsorbed on the surface of the copper powder, so that the reduction reaction is limited on the surface of the copper powder, and a uniformly-coated compact silver layer is formed on the surface of the copper powder. And in the replacement and reduction process, the organic solvent is used as a medium for dispersing the copper powder, the situation that a large amount of reducing agent exists in a dispersion medium can be effectively avoided, and then the phenomenon that pure silver powder particles are formed due to independent nucleation of the silver powder is well avoided. The technological process is simple and easy to operate, and the comprehensive performance of the prepared silver-coated copper powder is basically equivalent to that of pure silver powder conductive silver paste.

The present invention is directed to a fission product extraction system operable to capture and extract fission products from a flow of irradiated fueled molten salt of a molten salt reactor. The example extraction systems described herein utilize electroless deposition to chemically plate fission products onto a metallic structure. The metallic structure may be partially coated with a reducing agent, such as beryllium to provide an electron source for the fission products. The metallic structure may be a component of an extraction system designed to facilitate submersion of the metallic structure into the flow of molten salt. The extraction system may also be designed to facilitate removal of the metallic structure without requiring a shut down or slowdown of the reactor system.

The invention provides a supported catalyst as well as a preparation method and application thereof. The preparation method of the supported catalyst comprises the following steps: S1, carrying out precipitation reaction on vanadate and first ammonium salt in a first solvent to obtain a first product system containing a carrier precursor; s2, enabling the carrier precursor, a second ammonium salt, a noble metal-containing compound, a chelating agent and a first reducing agent to react in a second solvent to obtain a second product system containing a catalyst precursor; and S3, carrying out annealing treatment on the catalyst precursor and a second reducing agent in protective gas to obtain the supported catalyst. The noble metal in the supported catalyst prepared by the method is not easy to migrate and aggregate, and the stability is better. In addition, the dosage of precious metal needed by the preparation method is smaller, and the atom utilization rate is higher.

The invention provides a mining inorganic environment-friendly reinforcing material and application thereof, and belongs to the technical field of mining reinforcing materials. A component A comprises the following components in parts by mass: 60-80 parts of anhydrite, 5-20 parts of lime, 5-10 parts of silica fume, 2-8 parts of sodium silicate, 1-0.5 part of a naphthalene water reducer, 3-7 parts of an early strength agent and 0.2-0.8 part of lithium salt; the component B comprises the following components in parts by mass: 50-70 parts of cement clinker, 10-30 parts of slag cement, 5-10 parts of iron powder, 1-8 parts of aluminum sulfate, 5-10 parts of calcium carbonate and 0.5-1 part of sodium tripolyphosphate; the component C is prepared from the following components in parts by mass: 10 to 25 parts of water glass, 10 to 20 parts of emulsion, 40 to 60 parts of water, 5 to 10 parts of high-efficiency water reducing agent and 1 to 5 parts of triethanolamine. The mining inorganic environment-friendly reinforcing material provided by the invention is low in reaction heat and is not easy to cause coal combustion.

The invention relates to the field of microfluid chemical synthesis, and discloses a method for preparing gold nanoparticles based on two-phase flow microfluid control. The method comprises the following steps: 1) converging a gold precursor water phase, a reducing agent water phase and an organic phase in a micro-fluidic chip at 0-25 DEG C to form water-in-oil liquid drops; (2) conveying the fluid to a mixing area channel of a micro-fluidic chip, and carrying out instantaneous nucleation reaction to form a gold nanoparticle prototype; 3) conveying the fluid into a capillary reactor, and further nucleating, growing and curing the gold nanoparticle prototype; and (4) the fluid is subjected to phase splitting, and a gold nanoparticle solution is obtained. A three-in-one micro-fluidic chip is adopted, process parameters are optimized, and a gold precursor and a reducing agent are wrapped in an organic phase before reaction to form water-in-oil liquid drops, so that on one hand, the situation of adsorption and scaling of the inner wall of a channel can be avoided, and on the other hand, the heat and mass transfer efficiency of a material can be improved through the generated liquid drops; and the uniformity of a reaction nucleation environment is ensured.

The invention provides an early-strength rapid-repair grouting material and a preparation method thereof, and the early-strength rapid-repair grouting material is mainly prepared from the following raw materials: 50 to 150 parts of sulphoaluminate cement, 10 to 150 parts of aluminate cement, 200 to 350 parts of a regenerated gelling powder material, 1200 to 1400 parts of quartz sand, 50 to 100 parts of silica fume, 10 to 150 parts of mineral powder, 10 to 100 parts of fly ash, 15 to 50 parts of a composite retarder, 0.1 to 2 parts of a water reducing agent and 1 to 10 parts of an early strength agent. 0.01 to 1 part of a water-retaining agent and 200 to 300 parts of water. The early-strength quick-repair grouting material is characterized in that activated low-cementitious active mineral solid waste is adopted as a main cementitious material, and the product has excellent construction stability, low-carbon weather resistance, corrosion resistance, micro-expansion quick-hardening early strength and economical efficiency.

The invention discloses a seed layer induced FeCoNiCuMo high-entropy alloy nanocage electrocatalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing and reacting iron, cobalt and nickel precursors to prepare a FeCoNi nanocage catalyst as a seed layer; adding copper salt and molybdate into the seed layer solution, carrying out ultrasonic mixing, adding a pH regulator and a reducing agent, carrying out ultrasonic treatment, putting the mixed solution into liquid nitrogen, cooling, carrying out primary nucleation, naturally unfreezing, standing for nucleation, cleaning, and freeze-drying to obtain the high-entropy alloy nanocage electrocatalyst. The catalyst is used for preparing urea through CO2 and NO3 <-> electro-catalysis, can effectively adjust the matching of CO2 and NO3 <-> reaction kinetics, and has extremely high Faraday efficiency and yield for synthesizing urea through C-N coupling.

The present disclosure is directed to a processing solution composition comprising a metal salt, an acid, a solvent, and a non-metal reductant. The present disclosure is also directed to a method of impregnating a porous material by covering or coating the porous material with a processing solution comprising a metal salt, an acid, a solvent, and a non-metal reductant.

The invention discloses a preparation method of an ester polycarboxylic acid water reducer, and belongs to the technical field of concrete admixtures. The preparation method of the ester polycarboxylic acid water reducing agent comprises the following steps: under an alkaline condition, carrying out free radical polymerization reaction on a polyether macromonomer and an unsaturated carboxylic acid monomer under the action of a chain transfer agent A, a chain transfer agent B and an initiator, continuously adding a catalyst, and carrying out dehydration esterification reaction under the action of the catalyst, so as to prepare the ester polycarboxylic acid water reducing agent, the polyether macromonomer is monohydroxy polyether of which the molecular weight is between 500 and 5000; the chain transfer agent A is one of acetone, isopropanol, sodium hydrogen sulfite, sodium hypophosphite, sodium formate and the like; the chain transfer agent B is one of mercaptoethanol, mercaptopropanol, mercaptoacetic acid, mercaptopropionic acid and the like; the catalyst is a phosphonic acid compound with hydroxyl or amino. The preparation method is simple in process and low in energy consumption, and the prepared ester polycarboxylic acid water reducer product is excellent in performance.

The invention provides a modified coal gangue-based large-flow-state grouting and water plugging material and a preparation method thereof. Comprising 80-90 parts of a coal gangue sample, 1-5 parts of Portland cement, 1-5 parts of sulphoaluminate cement, 0.51-3 parts of a polycarboxylic acid water reducing agent, 1-4 parts of cellulose ether with the viscosity of 200w, 0.1-5 parts of a calcium oxide expanding agent, 0.5-5 parts of a plastic expanding agent, 0.5-1 part of redispersible latex powder, 0.5-5 parts of polyacrylamide with the molecular weight of 1000 and water, and the water-material ratio is 0.4. According to the modified coal gangue-based large-flow-state grouting and water plugging material and the preparation method thereof, the cement consumption can be remarkably reduced, the cost is reduced, the utilization rate of solid wastes (such as coal gangue) is increased, and the material has good flow-state performance and adjustable setting time; the method is suitable for deep and large shaft surrounding rock water seepage treatment in coal mining and other mine engineering.

The invention discloses a direct-current hollow electrode hydrogen plasma furnace mineral powder smelting system and method and application, and belongs to the technical field of hydrogen metallurgy. The system comprises a hollow electrode gas powder injection hydrogen plasma gun system, a direct current bottom electrode ore-smelting electric furnace system, a fine ore and hydrogen supply system and the like. The hollow electrode and the furnace bottom electrode form a direct-current arc, hydrogen carrying mineral powder is sprayed into an arc area to generate high-temperature hydrogen plasma, mineral powder reduction is achieved, and metal and slag are separated. According to the method, hydrogen serves as a reducing agent, carbon emission is reduced, the reaction efficiency is high, energy consumption is low, and the method can be used for steelmaking, smelting of micro-carbon ferromanganese and titanium slag and recovery of valuable metal in nonferrous smelting waste slag and has good green metallurgy application prospects.

The invention provides a leaching agent for removing thallium and beryllium in lithium slag and application. The leaching agent comprises a first leaching agent and a second leaching agent. The first leaching agent is an organic acid solution, and organic acid comprises carboxyl and at least one group of hydroxyl, sulfydryl, carbonyl and sulfonic acid group; the organic acid is single organic acid or mixed organic acid; the second leaching agent comprises a cationic agent and a reducing agent, the cationic agent can form at least one of K < + >, NH4 < + >, Mg < 2 + >, Na < + > and Fe < 3 + > in an aqueous solution, and the reducing agent comprises an inorganic reducing agent and / or an organic reducing agent. Organic acid in the first leaching agent can destroy the crystal structure of the lithium slag, and meanwhile groups such as carboxyl and hydroxyl can be complexed with thallium and beryllium ions so that the thallium and beryllium ions can be dissolved out more easily. On the basis, cations in the second leaching agent and the reducing solution accelerate the release of thallium and beryllium through ion exchange and reduction effects. The leaching agent can remove thallium and beryllium in the lithium slag at the same time, and the removal rate of thallium and beryllium is high.

The invention discloses a method for recovering lithium, nickel cobalt manganese composite hydroxide and aluminum copper powder from a waste ternary lithium ion battery pole piece. The method comprises the following steps: treating waste pole pieces of a ternary plant or a mixture of positive and negative pole pieces by using a Fenton technology, leaching by using a mixed ferric salt solution, and filtering to obtain lithium-containing leachate and slag; adjusting the pH value of the leachate, oxidizing and filtering to obtain a purified solution and ferric hydroxide precipitate, and adding the purified solution and a lithium hydroxide solution into a reactor for coprecipitation to obtain a deeply purified solution and the nickel-cobalt-manganese composite hydroxide. And dissolving the ferric hydroxide precipitate with dilute acid, adding a reducing agent to generate a ferrous salt solution, and returning the ferrous salt solution for Fenton reaction and leaching reaction. And adding the sodium carbonate saturated solution into the deep purification solution, and crystallizing and precipitating to obtain the battery-grade lithium carbonate. And performing hydrodynamic screening on the leaching residues to obtain an aluminum-copper mixture and graphite residues, and performing grinding and specific gravity separation on the aluminum-copper mixture to obtain high-purity aluminum powder and copper powder. According to the method, the iron salt is directly leached from the pole piece, the used iron salt can be recycled, and the method is suitable for large-scale recovery of the waste ternary lithium ion battery.

The invention provides a waterborne polyurethane enhancer, a cold-resistant and salt-resistant concrete composition as well as a preparation method and application of the cold-resistant and salt-resistant concrete composition, and belongs to the technical field of buildings and civil engineering. The waterborne polyurethane enhancer comprises diisocyanate, oligomer polyol, a small molecule chain extender, oxalic acid dihydrazide, oxaloacetic acid and a catalyst, and the cold-resistant and salt-resistant concrete composition comprises cement, aggregate, a water reducing agent, an anti-freezing agent, an air entraining agent, modified straw fibers, the waterborne polyurethane enhancer, calcium silicate and water. Through mutual cooperation of all the components, the obtained concrete has excellent cold resistance, salt resistance, impermeability and compressive strength, and can meet the engineering requirements for concrete durability and use safety under low-temperature and high-salt conditions.

The invention provides a treatment method of copper-nickel concentrate rich in platinum group metals, which comprises the following steps: feeding the copper-nickel concentrate rich in platinum group metals and a first flux into a smelting furnace, and introducing first oxygen-enriched gas for smelting; copper matte and a second flux are continuously fed into a first converting furnace, and second oxygen-enriched gas is continuously introduced for first converting; raw copper and a third flux are fed into the oxygen inclined blowing rotary converter, and oxygen is introduced for second blowing; the crude copper is fed into an anode refining furnace, and air and a first reducing agent are introduced for fire refining; casting the copper liquid into an anode plate, and carrying out electrolytic refining on the anode plate; feeding the first converting slag, the second converting slag, a second reducing agent and a vulcanizing agent into a dilution electric furnace for slag dilution to obtain low-nickel matte and dilution slag; and the low-nickel matte is fed into a third converting furnace, air or oxygen-enriched air is introduced for third converting, and the problem that the recovery rate of nickel metal elements and platinum group metals in the copper-nickel concentrate rich in the platinum group metals is low is solved.