5916 results about "Reducing agent" patented technology

The invention discloses crack-chloride ion double-triggered subsea tunnel corrosion-resistant concrete and a preparation method thereof, and relates to the field of subsea tunnel engineering materials. The concrete is prepared from the following components in parts by weight: 400 to 500 parts of Portland cement, 50 to 80 parts of fly ash, 60 to 100 parts of superfine mineral powder, 1000 to 1100 parts of coarse aggregate, 700 to 800 parts of fine aggregate, 140 to 160 parts of water, 10 to 20 parts of self-repairing microcapsules and 1 to 5 parts of a water reducing agent, the self-repairing microcapsule comprises a capsule wall material, a self-repairing material and a layered dihydroxyl composite metal oxide. A crack-chloride ion double-response system is constructed, and the limitation of traditional single trigger repair is broken through. When a crack with a certain width appears in the concrete, the capsule wall of the self-repairing microcapsule is broken to release the repairing component, so that effective filling of the crack is realized; and meanwhile, the layered double-metal hydroxide can directionally adsorb chloride ions to form a stable compound, so that the migration rate of the chloride ions is remarkably reduced.

The invention provides an early-strength rapid-repair grouting material and a preparation method thereof, and the early-strength rapid-repair grouting material is mainly prepared from the following raw materials: 50 to 150 parts of sulphoaluminate cement, 10 to 150 parts of aluminate cement, 200 to 350 parts of a regenerated gelling powder material, 1200 to 1400 parts of quartz sand, 50 to 100 parts of silica fume, 10 to 150 parts of mineral powder, 10 to 100 parts of fly ash, 15 to 50 parts of a composite retarder, 0.1 to 2 parts of a water reducing agent and 1 to 10 parts of an early strength agent. 0.01 to 1 part of a water-retaining agent and 200 to 300 parts of water. The early-strength quick-repair grouting material is characterized in that activated low-cementitious active mineral solid waste is adopted as a main cementitious material, and the product has excellent construction stability, low-carbon weather resistance, corrosion resistance, micro-expansion quick-hardening early strength and economical efficiency.

The invention provides a modified coal gangue-based large-flow-state grouting and water plugging material and a preparation method thereof. Comprising 80-90 parts of a coal gangue sample, 1-5 parts of Portland cement, 1-5 parts of sulphoaluminate cement, 0.51-3 parts of a polycarboxylic acid water reducing agent, 1-4 parts of cellulose ether with the viscosity of 200w, 0.1-5 parts of a calcium oxide expanding agent, 0.5-5 parts of a plastic expanding agent, 0.5-1 part of redispersible latex powder, 0.5-5 parts of polyacrylamide with the molecular weight of 1000 and water, and the water-material ratio is 0.4. According to the modified coal gangue-based large-flow-state grouting and water plugging material and the preparation method thereof, the cement consumption can be remarkably reduced, the cost is reduced, the utilization rate of solid wastes (such as coal gangue) is increased, and the material has good flow-state performance and adjustable setting time; the method is suitable for deep and large shaft surrounding rock water seepage treatment in coal mining and other mine engineering.

The invention discloses a direct-current hollow electrode hydrogen plasma furnace mineral powder smelting system and method and application, and belongs to the technical field of hydrogen metallurgy. The system comprises a hollow electrode gas powder injection hydrogen plasma gun system, a direct current bottom electrode ore-smelting electric furnace system, a fine ore and hydrogen supply system and the like. The hollow electrode and the furnace bottom electrode form a direct-current arc, hydrogen carrying mineral powder is sprayed into an arc area to generate high-temperature hydrogen plasma, mineral powder reduction is achieved, and metal and slag are separated. According to the method, hydrogen serves as a reducing agent, carbon emission is reduced, the reaction efficiency is high, energy consumption is low, and the method can be used for steelmaking, smelting of micro-carbon ferromanganese and titanium slag and recovery of valuable metal in nonferrous smelting waste slag and has good green metallurgy application prospects.

The invention discloses a high belite sulphoaluminate cement-based two-component grouting material and a preparation method thereof. The grouting material comprises a gelling component and a coagulating reinforcing component, wherein the gelling component is prepared from a high belite sulphoaluminate cement clinker and an additive A; the admixture A comprises a water reducing agent, a retarder and slow-release minerals; the coagulating and reinforcing component comprises ordinary Portland cement clinker, calcium hydroxide, gypsum and an additive B; the admixture B comprises a water reducing agent and an early strength agent. According to the high belite sulphoaluminate cement-based grouting material, the formula composition of the high belite sulphoaluminate cement-based grouting material is optimized, so that the hydration process of the high belite sulphoaluminate cement is more continuous and lasting, and the compressive strength of the obtained high belite sulphoaluminate cement-based grouting material can be continuously improved.

The invention provides a method for recycling lithium iron phosphate, which comprises the following steps: S1, obtaining lithium iron phosphate black powder, and washing the lithium iron phosphate black powder by using alkali liquor to obtain aluminum-removed black powder and aluminum-containing lithium filtrate; s2, the aluminum-removed black powder is subjected to acid leaching treatment with acid liquor, and acid leaching liquor is obtained; s3, carrying out reduction precipitation treatment on the acid leaching solution by using a composite reducing agent to obtain a copper-removed leaching solution and solid-phase copper-containing slag; s4, adding a phosphorus source and an oxidizing agent into the copper-removed leaching solution, adding alkali to adjust the pH value, and carrying out oxidation precipitation treatment to obtain iron phosphate precipitate and a first lithium-containing solution; and S5, adjusting the pH value of the aluminum-lithium-containing filtrate in the step S1 by using an acid solution to obtain aluminum filter residues and a second lithium-containing solution. According to the method, iron phosphate with relatively high purity can be obtained; meanwhile, the obtained first lithium-containing solution and the second lithium-containing solution are relatively low in impurity ion content and can be used for obtaining a lithium salt product with relatively high purity.

The invention discloses silver powder with a high twin crystal ratio and a preparation method and application of the silver powder with the high twin crystal ratio. The preparation method comprises the following steps that S1, a carboxylic acid coordination agent is added into a silver source solution, and a silver precursor solution is obtained; sequentially adding a dispersing agent and an initiator into the reducing agent solution to obtain a reaction base solution; s2, a silver precursor solution is added into the reaction base solution for an oxidation-reduction reaction, then curing is conducted, and mixed mother liquor is obtained; s3, the mixed mother liquor is filtered, washed, dispersed and dried, and then the silver powder with the high twin crystal proportion is obtained; the initiator comprises one or more of sulfate, carbonate and nitrate; through the synergistic effect of the initiator and the carboxylic acid coordination agent, the silver ion release rate and the crystal nucleus preferential growth direction are regulated and controlled, the rapid feeding and curing technology is combined, the low supersaturation environment is constructed, the silver powder is induced to grow in the specific direction, and the twin crystal proportion is remarkably increased.

The invention provides a dump leaching method for improving the leaching rate of gold ore, and belongs to the technical field of mineral processing. The method comprises the following steps: firstly, separating minerals into oversize products and undersize products; mixing sodium carboxymethyl cellulose, bentonite and ferrous sulfate to obtain a mixture, and granulating the undersize product by using the mixture as a binder; and mixing the undersize product particles with the oversize product, and carrying out cyanide-free dump leaching. According to the method, through graded granulation and heap building, the problem that heap building permeability is poor due to the fact that the gold ore contains many clay minerals is solved. In the granulation stage, ferrous hydroxide colloid generated by hydrolysis of ferrous sulfate in the binder can assist ore particle agglomeration, and particle stability is enhanced; during subsequent cyanide-free dump leaching, ferrous sulfate can be used as an auxiliary reducing agent and a catalyst in a thiourea gold leaching system to promote oxidation and dissolution of gold; meanwhile, ferrous ions can adjust the oxidation-reduction potential of a system, so that the thiourea gold leaching reaction is in a more favorable potential interval, the oxidation efficiency of thiourea is improved, invalid decomposition of thiourea is reduced, and therefore the use amount of thiourea and the use amount of agents are reduced.

The invention discloses high-crystallinity smooth silver powder, preparation of the high-crystallinity smooth silver powder and silver paste containing the high-crystallinity smooth silver powder. A preparation method of the silver powder comprises the following steps that a silver ammonia solution is obtained; the pH value of the silver-ammonia solution is adjusted to be alkaline through a pH adjusting agent, then a stabilizer is added, ultrasonic treatment is conducted, and silver crystal nucleuses are obtained; sequentially adding a charge control agent and a silver crystal nucleus into the dispersing agent solution, and uniformly stirring to obtain a reaction base solution; and the oxidant solution and the reducing agent solution are dropwise added into the reaction base solution at the same time, stirring reaction is conducted, and the high-crystallinity smooth silver powder is obtained. The mechanism for preparing the high-crystallinity smooth silver powder is mainly reflected in precise regulation and control of silver crystal nucleation, growth and surface modification, and the comprehensive characteristics of smooth particle surface, clear edges, high crystallinity and small particle size are achieved through the multi-factor synergistic effect.

The invention belongs to the technical field of steel smelting, and particularly discloses a comprehensive utilization method of vanadium titano-magnetite, which comprises the following steps: S1, preparing the vanadium titano-magnetite into pellets, and carrying out reduction reaction to obtain direct reduced iron; s2, a carbonaceous reducing agent and the direct reduced iron obtained in the step S1 are mixed and smelted in a melt separation electric furnace, and slag and molten iron are obtained; a slag former is not added in the smelting process, the purity of the titanium slag is improved through optimal design of the furnace profile of the melting electric furnace and combination of various smelting process control means, the problems that refractory materials of the melting electric furnace are excessively eroded, the service life is short, slag-metal separation is difficult, smelting is difficult to control and the like are solved, and the purposes of high-grade titanium slag and long service life of the melting electric furnace are achieved.

The invention relates to the technical field of preparation of lithium sulfide, in particular to a method for preparing lithium sulfide through hydrogen reduction of lithium sulfate. According to the specific technical scheme, the method for preparing the lithium sulfide by reducing the lithium sulfate through the hydrogen comprises the steps that the lithium sulfate is smashed to be micron-sized and then fed into a fluidized bed reactor, then high-purity hydrogen preheated to 850 DEG C is introduced into the fluidized bed reactor from the bottom of the fluidized bed reactor, the reaction temperature is controlled to be 850 + / -20 DEG C, and the reaction time is controlled to be 5-10 min. The hydrogen reduction method is relatively low in reaction temperature (700-900 DEG C), hydrogen is used as a clean reducing agent, a reaction byproduct is only water, and the problems of insufficient purity, high energy consumption, serious environmental pollution and the like in a traditional lithium sulfide preparation method can be avoided. The introduction of the fluidized bed technology can greatly enhance the gas-solid phase heat and mass transfer efficiency, realizes the continuity and automation of the process, and is an important path for realizing the industrialization of the reaction.

The invention relates to the technical field of hydrometallurgy, in particular to a method for selectively leaching and separating cobalt and manganese from crude cobalt hydroxide leaching residues. The separation method provided by the invention comprises the following steps: S1, pre-reduction treatment; and S3, cobalt is leached through selective oxidation, and manganese is precipitated. According to the separation method, the synergistic effect of ORP and pH is regulated and controlled, proper reducing agents and oxidizing agents are selected, cobalt is selectively leached through step-by-step oxidation, dissolution of manganese is inhibited, manganese circularly entering a leaching and extraction system is reduced, the leaching and extraction operation cost is reduced, meanwhile, a selective complexing agent is introduced, impurity co-dissolution is reduced, the subsequent purification process is simplified, and the method is suitable for industrial production. The preparation method is simple to operate and easy for industrial production, and has a good application prospect.

The invention relates to the technical field of concrete, and particularly discloses super-retarded concrete for an ultra-large pile and a preparation method of the super-retarded concrete. The super-retarding concrete for the ultra-large pile is prepared from the following raw materials in parts by mass: 320 to 400 parts of a cementing material, 1820 to 1960 parts of aggregate, 20 to 28 parts of an inorganic-organic hybrid retarding reinforcing agent, 7.2 to 11.6 parts of a polycarboxylate superplasticizer and 85 to 98 parts of water, the inorganic-organic hybrid delayed coagulation enhancer is prepared by carrying out in-situ free radical polymerization reaction on a hydroxyl acrylate monomer, acrylamide and nano silicon dioxide. According to the inorganic-organic hybrid retarding reinforcing agent, a hybrid substance is formed through a chemical bond, an organic phase is chelated with calcium ions to realize retarding and does not excessively inhibit cement particles, inorganic phase nano silicon dioxide has no agglomeration risk, gaps are filled, a stable product is generated to resist alkali erosion, and the super retarding performance and the long-term strength of concrete are both considered; and the service life of the ultra-large pile is prolonged.

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: dissolving aniline and a dithio compound in an acidic ice bath, dropwise adding a peroxy strong oxidant to generate a polyaniline-disulfide bond copolymer, dialyzing, and freeze-drying to obtain powder; then heating soluble silver salt, a reducing agent, a hydrophilic dispersing agent and an organic sulfydryl silane coupling agent to prepare functionalized nano-silver particles; the powder and nano-silver particles are dispersed in N-methyl pyrrolidone for ultrasonic treatment, and dynamic self-repairing coating slurry is prepared; and performing acid pretreatment on the carbon fiber paper, and performing electrochemical deposition on the slurry to prepare the zinc-bromine battery positive electrode material. According to the zinc-bromine battery positive electrode material, the coulombic efficiency and the voltage efficiency of a zinc-bromine flow battery are remarkably improved and the cycle life of the zinc-bromine flow battery is remarkably prolonged through methods of dynamic covalent bonds, nano-silver catalysis, a hierarchical pore structure, carbon fiber pretreatment and the like, and the zinc-bromine flow battery positive electrode material has chemical stability, efficient bromine adsorption capacity and excellent catalytic activity.

The invention relates to the technical field of concrete structure repair, and particularly discloses a high-freezing-resistance and high-permeability concrete crack repair material and a preparation process thereof. The repairing material comprises the following components in parts by weight: 10-50 parts of acrylic acid, 12-50 parts of methyl methacrylate, 0.2-3.0 parts of a cross-linking agent, 0.05-2 parts of an oxidizing agent, 0.01-1 part of a reducing agent and 2-10 parts of watermelon leaf powder-saturated lime water suspension. The repairing material disclosed by the invention not only has good permeability, can penetrate into microcracks, but also has good frost resistance, so that the repairing material can be well applied to repairing of weight cracks of a concrete structure in a low-temperature environment.

The present invention provides a method for synthesizing alacastran, comprising reacting an amino compound of formula V with a chiral intermediate of formula VI, reducing the resulting product with a reducing agent capable of providing an ethyl group to produce a compound of formula VII, and then deprotecting the compound to obtain alacastran, as shown in the following reaction formula. The method for synthesizing alacastran of the present invention avoids the low yield caused by amide reduction and the risk of substrate racemization, has a high yield, low material cost, safe operation, and is suitable for industrial production.

The invention relates to the field of organic chemical synthesis, in particular to a synthetic method and application of pyrimidone compounds. The invention provides a synthesis method, reactants are o-amino heterocyclic formamide and triethyl orthoformate respectively, a solvent system is a hexafluoroisopropanol solvent, and a product is a heterocyclic pyrimidone compound. The reaction does not need strong acid or strong alkali conditions, does not need additional reducing agents or oxidizing agents, does not need transition metal catalysis, is economical and practical, the reaction conditions are relatively mild, and the synthesized pyrimidone compound has a good antibacterial effect.

The invention discloses a preparation process of a waste concrete recycled aggregate gypsum-based wall material, which comprises the following steps: (1) mixing a water repellent agent with an anhydrous solvent to obtain a pretreating agent, and then adding concrete recycled aggregate for standing; and separating out the recycled aggregate and drying the recycled aggregate to obtain the pretreated recycled aggregate. (2) calcining the magnesium oxide whisker, and then adding the obtained calcined whisker into an ethanol solution of polyethylene glycol to form a suspension; and spraying the suspension on the continuously stirred pretreated recycled aggregate, and then carrying out heating and stirring treatment to obtain the modified recycled aggregate. And (3) uniformly stirring ardealite powder, silica fume, potassium hydroxide powder and fine aggregate, then adding water, a retarder and a water reducing agent, uniformly stirring, then adding the modified recycled aggregate, and uniformly stirring, thereby obtaining the product. The process provided by the invention not only reduces the adverse effect of the recycled aggregate on the gypsum-based material, but also improves the water resistance of the gypsum-based material and enhances the mechanical strength.

The invention discloses a liquid cement grinding aid and a preparation method thereof, and belongs to the technical field of cement grinding aid preparation, the liquid cement grinding aid comprises the following raw materials by weight: 76-80% of water, 18-20% of hydrochloric acid and 2-4% of sodium hexametaphosphate. The preparation method of the liquid cement grinding aid comprises the following steps: uniformly mixing the raw materials according to the weight percentage, and carrying out activation reaction to prepare the liquid cement grinding aid. The cement grinding aid disclosed by the invention is prepared by mixing hydrochloric acid, water and sodium hexametaphosphate according to a specific proportion, and through scientific regulation and control of the synergistic effect of all the components, the cement grinding aid has good grinding aiding performance and remarkably improves the specific surface area and grinding aiding efficiency of cement; the component design fully considers the cement hydration process and the compatibility with the water reducing agent.

The invention relates to the technical field of solid waste treatment and recycling, and discloses a waste incineration fly ash geopolymer composite material and a preparation method thereof, and the composite material is prepared from waste incineration fly ash, apatite minerals, zero-valent iron powder, persulfate and an alkali activator. The preparation method comprises the following steps: mixing the waste incineration fly ash, apatite minerals, zero-valent iron powder and persulfate to obtain composite powder; performing frequency conversion mechanochemical synergistic activation on the composite powder, wherein the activation process comprises a low-temperature activation stage and a high-energy pulse activation stage; and finally, mixing the activated powder with an alkali activator, pouring, molding and curing. According to the method, the reduction reaction and the oxidation reaction are driven step by step in the same system by regulating and controlling the mechanical energy input time sequence, the compatibility problem of a reducing agent and an oxidizing agent is solved, different types of persistent organic pollutants are synergistically degraded, meanwhile, heavy metal is stabilized, and the treatment effect is good. And the fly ash is recycled to prepare a geopolymer material with mechanical properties.

The invention relates to a waste ternary lithium ion battery black powder treatment method which comprises the following steps: in the presence of a reducing agent, carrying out acid leaching on waste ternary lithium ion battery black powder to be treated to obtain a leaching system; mixing the leaching system with iron powder, and reacting to obtain copper-removed ore pulp; and waste ternary lithium ion battery black powder is added into the copper removal ore pulp, the pH value of a reaction system is made to be 4-6, solid-liquid separation is carried out after reaction, and liquid with iron and aluminum removed and black powder filter residues are obtained. According to the treatment method, the technological process is short, production equipment can be simplified, the treatment cost is reduced, meanwhile, the recovery efficiency of valuable metal such as nickel, cobalt, manganese and lithium is effectively improved, the recycling value of black powder treatment is improved, and remarkable technical and economic advantages are achieved.

The invention relates to the technical field of concrete materials, and discloses rapidly-reinforced high-performance sprayed concrete for an existing tunnel lining and a preparation method of the rapidly-reinforced high-performance sprayed concrete. The sprayed concrete is prepared from the following raw materials in parts by weight: 300 to 350 parts of low-calcium high belite sulphoaluminate cement, 80 to 100 parts of superfine slag powder, 3 to 8 parts of a trigger type activating agent, 5 to 15 parts of slow-release particles, 2 to 5 parts of nanogel, 800 to 900 parts of fine aggregate, 800 to 900 parts of coarse aggregate, 30 to 50 parts of copper-plated steel fiber, 0.8 to 1.2 parts of polypropylene fiber, 30 to 40 parts of a viscosity-adjusting accelerator, 10 to 20 parts of a water reducing agent and 160 to 180 parts of water. The sprayed concrete is high in compressive strength and good in durability, the double threats of chemical corrosion and chloride ion permeation / steel bar corrosion are cooperatively solved, and the requirement for rapid reinforcement of tunnels and underground engineering is met.

The invention belongs to the technical field of concrete, and particularly relates to dynamic carbon injection recycled coarse aggregate concrete as well as a preparation method and application thereof. The preparation method of the concrete comprises the following steps: (1) adding the cement, the mineral powder, the recycled coarse aggregate, the fine aggregate, the fly ash, the carbon sequestration agent, the retarder and the water reducing agent into water, and uniformly stirring to obtain a mixed material; (2) injecting carbon dioxide into the mixed material to obtain carbon-mixed concrete; and (3) curing the carbon-mixed concrete to obtain the carbon-mixed concrete. The invention provides a method for preparing dynamic carbon injection recycled coarse aggregate concrete by taking a carbon sequestration agent, a retarder, cement, mineral powder, recycled coarse aggregate, fine aggregate, fly ash and a water reducing agent as raw materials. The method is simple in process and easy for large-scale production. The concrete prepared by adopting the method is relatively high in carbon sequestration rate, excellent in mechanical property and capable of effectively avoiding rapid hydration.

The invention relates to the technical field of building materials, and provides washing gangue concrete with high slump loss resistance and a mixing process thereof. The high-slump-retaining washed gangue concrete is prepared from the following raw materials in parts by weight: 200 to 220 parts of cement, 140 to 150 parts of mineral powder, 60 to 65 parts of fly ash, 680 to 720 parts of machine-made sand, 950 to 970 parts of washed gangue, 150 to 160 parts of water, 16 to 17.5 parts of a water reducing agent, 0.15 to 0.3 part of a slump retaining agent and 4 to 4.3 parts of polyethylene glycol. The slump retaining agent is hydroxypropyl methyl cellulose ether; and the viscosity of the hydroxypropyl methyl cellulose ether is 100 thousand mPa.s to 300 thousand mPa.s. According to the technical scheme, the problems of poor slump retaining performance and low compressive strength of washed gangue concrete in the prior art are solved.

The invention provides high-filling silver powder and a preparation method thereof, and belongs to the field of metal powder.The preparation method comprises the steps that a nano-silver solution is prepared, a dispersing agent and a first reducing agent are mixed to obtain a mixed solution, the nano-silver solution and the mixed solution are mixed in a constant-temperature stirring state to obtain a base solution, a second reducing agent solution and a silver nitrate solution are prepared respectively, and the high-filling silver powder is prepared. And under the constant-temperature stirring state, the second reducing agent solution and the silver nitrate solution are synchronously added into the base solution, a silver powder solution is obtained through reaction, the silver powder solution is subjected to washing, solid-liquid separation, drying and depolymerization shaping treatment, and the high-filling silver powder is obtained. Controllable preparation of the large-size sphericity silver powder is achieved by controlling the particle size and the adding amount of the nano-silver, regulating and controlling heterogeneous nucleation and growth sites of silver ions and inhibiting formation of multistage dendritic crystals, surface charges and steric hindrance effects of silver particles are optimized through the surface adsorption effect of the dispersing agent, the agglomeration phenomenon of the silver powder in the growth process is reduced, and the silver powder is prepared. And meanwhile, the silver powder is endowed with excellent flowability.

The invention relates to the field of concrete, and particularly discloses anti-crack concrete and a preparation method thereof. The anti-crack concrete is prepared from the following raw material components in parts by weight: 400 parts of cement; 1000 to 1100 parts of coarse aggregate; 730 to 800 parts of fine aggregate; 40 to 50 parts of modified rubber particles; 20 to 25 parts of basalt fiber; 5-6 parts of a water reducing agent; 1.3 to 1.5 parts of SAP resin; 0.015 to 0.02 part of an air entraining agent; 130 to 140 parts of water; a modifier used for preparing the modified rubber particles is sodium hydroxide and a silane coupling agent. The anti-crack concrete disclosed by the invention has good anti-crack capability, the total cracking area does not exceed 35mm < 2 > / m < 2 >, and the 28d compressive strength is not lower than 40MPa.

The invention belongs to the technical field of hazardous waste treatment, and particularly relates to a treatment method of organic hazardous waste. An inner core is prepared from the organic hazardous waste and an additive, outer shell powder is obtained from an oxidizing agent and a reducing agent, then the core-shell structure energetic material is prepared in a coating mode, and finally the prepared core-shell structure energetic material is ignited for organic hazardous waste treatment. Compared with an existing incineration treatment technology, organic hazardous waste treatment can be conducted without traditional incineration equipment; as the oxidizing agent is in uniform and tight contact with the organic matter, large heat is released in the combustion process, the local temperature is high, oxygenolysis is rapid and thorough, and a good treatment effect is achieved; the method is short in technological process, low in energy consumption and cost and remarkable in economic and environmental benefits. According to the treatment method provided by the invention, inorganic gas and inorganic compounds are presented after combustion, so that group components forming the dioxin are fully dispersed, and generation of the dioxin is favorably inhibited.

The invention provides a preparation method of a multi-source coal-based solid waste filling material, and belongs to the technical field of solid waste reutilization, and the preparation method comprises the following steps: uniformly mixing cement, fly ash, furnace bottom slag, desulfurized gypsum, coal gangue, gasified slag and a water reducing agent to obtain a mixed material; and adding fluorine-containing mine water into the mixed material, stirring and mixing to obtain the cemented multi-source coal-based solid waste filling material with predetermined fluidity and bleeding rate. The invention further provides application of the multi-source coal-based solid waste filling material. According to the preparation method and application of the multi-source coal-based solid waste filling material, the coal-based solid waste can be comprehensively recycled and is environmentally friendly, and the prepared multi-source coal-based solid waste filling material can effectively control and treat fluorine ions in mine water.

The invention provides a method for improving the manganese recovery rate of a silicon-manganese alloy, which comprises the following steps: sequentially filling smelting raw materials into a closed electric furnace for smelting to obtain an alloy melt; transferring the alloy melt into a steel ladle, and blowing magnesium powder for desulfurization; the desulfurized alloy melt is subjected to slagging-off, and manganese-silicon alloy molten iron is obtained; the manganese-silicon alloy molten iron is poured into a mold for ingot casting, and a manganese-silicon alloy finished product is obtained after cooling; the smelting raw materials are sequentially filled with a backing material, a mixture and a surface material from bottom to top in the closed electric furnace; the surface material comprises aluminum powder and calcium carbide which are mixed according to a certain proportion, in the method, the surface material comprises the aluminum powder and the calcium carbide which are mixed according to a certain proportion, the effect of a reducing agent can be achieved while the ignition effect is achieved, manganese can be directly reduced in the reaction through addition of the aluminum powder, and therefore the effect of improving the manganese recovery rate is achieved.

The invention relates to a polycarboxylate superplasticizer compounding production line. The production line comprises an intelligent raw material pretreatment unit, a multi-component precise proportioning unit, a gradient temperature control compounding reaction unit, an online quality monitoring feedback unit and a finished product self-adaptive filling unit which are connected in sequence. The multi-component precise proportioning unit is internally provided with a dynamic proportioning adjusting system, and the feeding amount can be corrected according to the solid content deviation of raw materials and the target fluidity; the gradient temperature control compound reaction unit realizes temperature and speed coordinated regulation and control through a sectional temperature control module and a stirring speed linkage device; and the online quality monitoring feedback unit forms closed-loop control with the above two units by means of a near infrared spectrum detection module. The invention aims to solve the problem that the existing production line lacks the dynamic ratio adjustment of the actual solid content deviation of the raw material and the target fluidity, the reaction stage temperature control and stirring rate cooperative regulation and control and the online detection closed-loop control; therefore, the problems of low proportioning precision, poor reaction process controllability and large performance fluctuation of the water reducing agent are solved.