2563results about "Amino compound preparation" patented technology

The invention relates to a catalyst for selective hydrogenation reaction of an aromatic nitrocompound and a preparation method of the catalyst. The catalyst consists of a catalyst carrier and active metal coated with carbon, wherein the catalyst carrier includes a carbon-base carrier, SiO2, TiO2 or Al2O3; the active metal is selected from Co, Fe, Ni or Cu and other poor and noble metals. The catalyst is prepared by adopting a Pechini type sol-gel process which comprises the steps of dispersing an active metal precursor to water containing a coordination compound, adding a polyhydric alcohol solution and a macromolecule auxiliary, then adding the carrier, stirring for dispersion, carrying out hydrothermal reaction, separating out solid on the lower layer, and calcining in the inert atmosphere to obtain the catalyst in which carbon coats the active metal. Compared with the prior art, the catalyst can realize the hydrogenation reaction of a substituted aromatic nitrocompound in the mild condition; substrate conversion rate and production selectivity are high; the catalyst has recyclable economy and good application prospect.

The invention provides a method of producing a graphene material from a starting graphitic material. In an embodiment, the method comprises: (a) dispersing the starting graphitic material in a liquid medium to form a graphite suspension; and (b) introducing the graphite suspension into a hydrodynamic cavitation reactor that generates and collapses cavitation or bubbles in the liquid medium to exfoliate and separate graphene planes from the starting graphitic material for producing the graphene material. The process is fast (minutes as opposed to hours or days of conventional processes), environmentally benign, and highly scalable. The reactor can concurrently perform the functions of graphene production, chemical functionalization, dispersion, and mixing with a polymer to make a composite.

One aspect of the present invention relates to novel ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in transition metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming reactions. The subject methods provide improvements in many features of the transition metal-catalyzed reactions, including the range of suitable substrates, reaction conditions, and efficiency.

A catalyst comprising a plurality of support nanoparticles and a plurality of catalytic nanoparticles. At least one catalytic nanoparticle is bonded to each support nanoparticle. The catalytic particles have a size and a concentration, wherein a first configuration of the size and the concentration of the catalytic nanoparticles enables a first catalysis result and a second configuration of the size and the concentration of the catalytic nanoparticles enables a second catalysis result, with the first and second configurations having a different size or concentration, and the first and second catalysis results being different. In some embodiments, the first catalysis result is a selective reduction of a first selected functional group without reducing one or more other functional groups, and the second catalysis result is a selective reduction of a second selected functional group without reducing one or more other functional groups.

A phenylcarbazole-based compound is represented by Formula 1, and has superior electric properties and charge transport abilities, and thus is useful as a hole injection material, a hole transport material, and/or an emitting material which is suitable for fluorescent and phosphorescent devices of all colors, including red, green, blue, and white colors. The phenylcarbazole-based compound is synthesized by reacting carbazole with diamine. The organic electroluminescent device manufactured using the phenylcarbazole-based compound has high efficiency, low voltage, high luminance, and a long lifespan.

Disclosed is an edge-functionalized graphitic material manufactured by using a mechanochemical process. The edge-functionalized graphitic material is manufactured by pulverizing graphite in the presence of a variety of atmospheric agents in the form of gas phase, liquid phase, or solid phase. The edge-functionalized graphitic material, which is a precursor applicable into various fields, is expected to replace the prior art oxidized graphite.

An aromatic amine derivative with a special structure obtained by bonding a diphenylamino group having a substituent to a substituted pyrene structure; and a process for producing the aromatic amine derivative. An organic electroluminescence device which comprises at least one organic thin film layer comprising a light emitting layer sandwiched between a pair of electrodes consisting of an anode and a cathode, wherein at least one of the organic thin film layer comprises the aromatic amine derivative singly or as its mixture component. An organic electroluminescence device having a prolonged lifetime and emits blue light with an enhanced efficiency of light emission and an aromatic amine derivative realizing the device are provided.

New ligands and compositions with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

In a process for preparing amines, in which at least one compound containing at least one nitro group is reacted with hydrogen in the presence of a supported catalyst comprising, as catalytically active metal, nickel, if desired together with at least one metal of transition group I, V, VI and/or VIII, the reduced and stabilized supported catalyst comprises nickel crystallites having a bimodal nickel crystallite size distribution having maxima at 30-80 Angstr+E,uml o+EE m and 81-150 Angstr+E,uml o+EE m on a support comprising ZrO2, ZrO2-HfO2 and/or SiO2-ZrO2 and/or SiO2-ZrO2-HfO2 and in the reduced and passivated state has a nickel content of 60-80 percent by mass, an SiO2 content of 0-20 percent by mass, a ZrO2 content of 0-40 percent by mass, an HfO2 content of 0-4 percent by mass and after further reduction for one hour at 100 DEG C. has a degree of reduction of at least 70%.

The invention provides a method for preparing ethylenediamine from reactants of glycol and ammonia in the presence of a solid catalyst with a main component of copper through a hydrogenation and amination one-step method. The method comprises the following steps of: making glycol containing water or not containing water and ammonia enter a reactor filled with the catalyst with a main component of copper, performing dehydrogenation to obtain the ethylenediamine and water and an ethanolamine byproduct, and separating the mixture obtained through reaction to obtain the product of ethylenediamine.

The invention provides a solid catalyst for preparing ethylene diamine through catalytic amination of ethylene glycol. The catalyst takes copper and nickel as main components and zirconium as an auxiliary component; and other metal components can be one or more than one of zinc, aluminum, titanium, manganese and cerium. The invention further provides a preparation method of the solid catalyst. The preparation method is characterized in that the catalyst is prepared through the processes of roasting, reducing and re-roasting by utilizing a coprecipitation method.

The invention relates to a novel metal catalyst loaded by mesoporous carbon and a preparation method thereof. The metal catalyst is composed of 0.01-90 wt% of metal grains and 10-99.99 wt% of mesoporous carbon carrier, wherein the mesoporous carbon carrier is made of a heteroatom-doped mesoporous carbon material; the heteroatom-doped mesoporous carbon material is prepared by the following steps of: taking ionic liquid containing heteroatoms as a monomer and mixing the ionic liquid with a template agent at a room temperature; and then calcining the mixture at a temperature in a range of 400-1000 DEG C for 1-6 hours and cooling the mixture to the room temperature; and finally, removing the template agent to obtain the heteroatom-doped mesoporous carbon material. The average grain diameter of the metal grains is 1-100 nm and the mass percentage of the heteroatoms in the mesoporous carbon material is 0.01-80 wt%. The catalyst provided by the invention is good for enhancing the catalytic activity of the catalyst by adjusting the valence state of nano metal through doping the heteroatoms including nitrogen, sulfur, phosphorus, boron, fluorine and the like, and depositing and dispersing on the metal on the surface of the carrier. Furthermore, the catalyst is simple in preparation and is stable for water, air and heat.

Hydrocarbon or oxygenate conversion process in which a feedstock is contacted with a non zeolitic molecular sieve which has been treated to remove most, if not all, of the halogen contained in the catalyst. The halogen may be removed by one of several methods. One method includes heating the catalyst in a low moisture environment, followed by contacting the heated catalyst with air and/or steam. Another method includes steam-treating the catalyst at a temperature from 400° C. to 1000° C. The hydrocarbon or oxygenate conversion processes include the conversion of oxygenates to olefins, the conversion of oxygenates and ammonia to alkylamines, the conversion of oxygenates and aromatic compounds to alkylated aromatic compounds, cracking and dewaxing.

An activated carbon monolith catalyst comprising a finished self-supporting activated carbon monolith having at least one passage therethrough, and comprising a supporting matrix and substantially discontinuous activated carbon particles dispersed throughout the supporting matrix and at least one catalyst precursor on the finished self-supporting activated carbon monolith. A method for making, and a method for use, of such an activated carbon monolith catalyst in catalytic chemical reactions are also disclosed.

The production process is liquid phase catalytic hydrogenation reaction of nitrobenzene halide, such as o-chloronitrobenzene, p-chloronitrobenzene, 3, 4-dichloronitrobenzene and 3-chloro-4-fluoronitrobenzene, etc. with carbon nanotube carried Pd and Pt as hydrogenation catalyst to produce corresponding haloarylamine. The said production process can inhibit hydrodehalogenation, and has the advantages of high selectivity, high yield and high catalyst stability, etc. and thus high practical value.

The present invention relates to an improved epoxidation process and an improved epoxidation reactor. The present invention makes use of a reactor which comprises a plurality of microchannels. Such process microchannels may be adapted such that the epoxidation and optionally other processes can take place in the microchannels and that they are in a heat exchange relation with channels adapted to contain a heat exchange fluid. A reactor comprising such process microchannels is referred to as a “microchannel reactor”. The invention also provides a method of installing an epoxidation catalyst in a microchannel reactor. The invention also provides a method of preparing an epoxidation catalyst. The invention also provides an epoxidation catalyst. The invention also provides a certain process for the epoxidation of an olefin and a process for the preparation of a chemical derivable from an olefin oxide. The invention also provides a microchannel reactor.

Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney(R) nickel or Raney(R) cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.

An acid gas absorbent comprising an alkylamino alkyloxy (alcohol) monoalkyl ether and a process for the selective removal Of H₂S from gaseous mixtures containing H₂S and CO₂ using an absorbent solution comprising an alkylamino alkyloxy alcohol monoalkyl ether.

Methods of preparing, and compositions comprising, derivatives of venlafaxine are disclosed. Also disclosed are methods of treating and preventing diseases and disorders including, but not limited to, affective disorders such as depression, bipolar and manic disorders, attention deficit disorder, attention deficit disorder with hyperactivity, Parkinson's disease, epilepsy, cerebral function disorders, obesity and weight gain, incontinence, dementia and related disorders.

Stable carbene ligands are provided having a carbene center flanked by a quaternary carbon and an amino group, and having utility in the preparation of various transition metal complexes.

The invention discloses a method for synthesizing halogen aromatic amines by halogen aromatic nitro compounds through liquid phase hydrogenation, which is characterized in that: the reaction for synthesizing the halogen aromatic amines by the halogen aromatic nitro compounds through liquid phase hydrogenation is carried out in the presence of a Pd/C catalyst under the condition of no solvent; and the method for preparing the Pd/C catalyst comprises the following steps of: performing impregnation pretreatment on active carbon by using aqueous solution of potassium halide, and filtering and washing until the filter liquor does not contain halide ions; preparing the pretreated active carbon into slurry by using de-ionized water, adding aqueous solution of HaPdCl4 dropwise for impregnation treatment, adjusting the pH value to alkali, and filtering and washing until the filter liquor is neutral; and preparing the obtained filter cakes into slurry by using de-ionized water, reducing in aqueous solution of reducing agent by a wet method, and filtering and washing until the filter liquor is neutral to obtain the Pd/C catalyst. The catalyst is adopted to prepare the halogen aromatic amines under the condition of no solvent, the selectivity is over 99.9 percent, the product quality meets the medical requirements, the production process is simplified, the production cost and energy consumption are reduced, the production efficiency is improved, and adverse factors such as solvent and product steam severely harming human bodies and polluting environment are improved.

A method for preparing multi-arm poly(ethylene glycol) (PEG) amines from multi-arm PEG polyols is described. The method comprises a two step process, wherein the multi-arm PEG polyol is first reacted with thionyl chloride to form a multi-arm PEG chloride, which is subsequently reacted with aqueous or anhydrous ammonia to yield the multi-arm PEG amine.

The invention relates to a catalyst for synthesizing hexamethylenediamine. The catalyst is composed of three parts, namely a main active ingredient, aids and a carrier subjected to ammoniated treatment, wherein the main active ingredient is Ni or Co; the aids refer to one or more ofmetals such as Fe, Cu, Ru, Re, K, Zn and B or oxides; and the carrier subjected to ammoniated treatment is selected from SiO2 or Al2O3 subjected to ammoniated treatment. In the total weight of the catalyst, the main active ingredient accounts for 1-40%, and the aids account for 0.1-20%. The catalyst disclosed by the invention has the characteristic that the adopted carrier needs special ammoniated treatment. According to the catalyst disclosed by the invention, an ammonolysis reaction of hexanediol or amino hexanol or a hexanediol/amino hexanol mixture is implemented, the hexamethylenediamine product is synthesized under a hydrogen present condition, and the catalyst has high activity, high selectivity and stability.

The invention discloses a method for preparing tetrapropyl ammonium hydroxide by utilizing bipolar membrane electrodialysis, and the method comprises the following steps of: using a tetrapropyl ammonium bromide aqueous solution as a raw material, processing the tetrapropyl quaternary ammonium salt aqueous solution through a microporous filter, and then enabling the processed tetrapropyl quaternary ammonium salt aqueous solution to enter a material liquid room of a bipolar membrane electrodialyzing device, respectively adding water in an acid room and an alkali room, respectively adding a sodium sulfate solution in pole liquid rooms, controlling the current density, the voltage and the temperature of the bipolar membrane electrodialyzing device to be 150-600 A/M2, 20-300 V and 5-45DEG C respectively, carrying out circulating cooling through chilled saline water in a circulating coil pipe by using an electrodialyzing compartment in a running process, stopping running when the conductivity of the material liquid room is decreased to below 2000 [mu]s/cm, obtaining a tetrapropylammonium hydroxide solution in the alkali room, and recycling a hydrobromic acid solution in the acid room. By using the method, the raw material cost is low; the selectivity is multiple; the purity of the tetrapropyl ammonium hydroxide is high; hydrobromic acid further can be recovered; and the generation of a pollutant in the process is effectively avoided.

The present invention discloses the synthesis method of dapoxetine. The method of the present invention adopts 3-chlorophenyl ethanone as initial material, has shortened reaction process, lowered cost and simple operation, and is suitable for industrial production.

A process for the catalytic hydrogenation of an organic compound, in particular a labile organic compound, in the presence of a support catalyst with a coating containing ruthenium as active metal and a total of 1.01 to 30 wt. % of active metals. Higher stereoselectivity and a greater catalyst shelf life may be obtained by using a support catalyst of which the oxide, carbide, nitride or siliceous support material has a BET (N2) surface area smaller than 10 m2/g, particularly preferably 0.1 to 5 m2/g, prior to loading with at least one active metal diatomaceous earth with a BET (N2) surface area greater than 2 m2/g is excluded and the ruthenium content thereof makes up at least 50 wt. %, preferably at least 99 wt. % of the active metals. The process and the catalysts are particularly suitable for the hydrogenation of polyfunctional compounds such as hydroxycarbonyl compounds and aromatic amines.

The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

The invention relates to a catalyst for synthesizing ethylene amine and a method for preparing ethylene amine. The catalyst comprises 1-40 wt% of a main active component, 0.1-20 wt% of an auxiliary agent, and a carrier processed by ammonification, wherein the main active component is Ni or Co, the auxiliary agent comprises one ore more of Fe, Cu, Ru, Re, K, Zn, B and other metal or oxides, and the ammonified carrier is ammonified SiO2 or Al2O3. The catalyst is characterized in that the used carrier needs to be ammonified. The ethylene amine product synthesized in hydrogen environment by using the catalyst of the invention to carry out ethanolamine ammonification reaction has high activity, high selectivity and stability.

The invention relates to multiple kinds of alkaline ionic liquids as well as preparation methods and application thereof. The alkaline ionic liquid provided by the invention mainly comprises a cation X<+> and an anion Y<->, wherein the precursor of the cation X<+> is choline, phosphine, guanidine or amine; and the precursor of the anion Y<-> is imidazole, phenol or alcohol. The alkaline ionic liquid is prepared from the precursors of the cation and anion at room temperature in a certain ratio. The ionic liquid synthesized in the invention can be applied to the absorption of acidic gases such as carbon dioxide and sulfur dioxide, the absorption and desorption effects are good and the ionic liquid can be recycled.

A process is described for the synthesis of an aryl sulfur pentafluoride compound. In one embodiment of the present invention, there is provided a process for preparing an aryl sulfurpentafluoride compound comprising: combining an at least one aryl sulfur compound with a fluorinating agent to at least partially react and form an intermediate aryl sulfurtrifluoride product; and exposing the intermediate aryl sulfurtrifluoride product to the fluorinating agent and optionally a fluoride source to at least partially react and form the aryl sulfurpentafluoride compound.