2462results about "Catalyst carriers" patented technology

Graphitic nanotubes, which includes tubular fullerenes (commonly called "buckytubes") and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized fibrils linked to one another. The invention also relates to methods of introducing functional groups onto the surface of such fibrils.

This invention relates to processes for the assembly of three-dimensional structures having periodicities on the scale of optical wavelengths, and at both smaller and larger dimensions, as well as compositions and applications therefore. Invention embodiments involve the self assembly of three-dimensionally periodic arrays of spherical particles, the processing of these arrays so that both infiltration and extraction processes can occur, one or more infiltration steps for these periodic arrays, and, in some instances, extraction steps. The product articles are three-dimensionally periodic on a scale where conventional processing methods cannot be used. Articles and materials made by these processes are useful as thermoelectrics and thermionics, electrochromic display elements, low dielectric constant electronic substrate materials, electron emitters (particularly for displays), piezoelectric sensors and actuators, electrostrictive actuators, piezochromic rubbers, gas storage materials, chromatographic separation materials, catalyst support materials, photonic bandgap materials for optical circuitry, and opalescent colorants for the ultraviolet, visible, and infrared regions.

The invention relates to a catalyst for dehydrogenating propane to prepare propone, which uses thermal-resistant oxide as carrier, uses palladium-group metal as main catalyst, uses IV A group metal and rare-earth metal as agents, uses halogen as modifier, and uses inorganic oxide with high temperature resistance as adhesive. The inventive catalyst under high temperature and low pressure has higher propane transfer rate, propone selectivity and reaction stability. And the preparation comprises that at 60-100Deg. C, immerging thermal-resistant oxide with rare-earth metal water solution for 2-10h, at 60-180Deg. C baking for 2-10h, at 400-600Deg. C baking for 3-10h, immerging said carrier and the water solution which contains palladium metal and IVA metal at 60-100Deg. C for 2-10h, and baking for 2-10h at 60-180Deg. C, adding adhesive, protruding agent and acid gel solvent, protruding and shaping, baking for 2-10h at 60-180Deg. C, activating for 3-10h at 400-600Deg. C, and reducing for 2-10h in hydrogen flow at 400-600Deg. C.

The invention discloses a manufacturing method for aluminium dioxide, blends two kinds of different thin water aluminium wafer powder evenly, and then carries on dissolving and forming, drying, baking and gets the aluminum oxide. The first kind of thin water aluminum mine has a hole capacity of 0.50ml/g~0.80ml/g, the proportion accounts for 5w%~50w% of Al2O3 . the hole capacity of the second aluminum mine is about 0.85ml/g ~1.50ml/g. There has no contamination by using the method; the diameter of the carrier is in the range of 6nm~35nm and 100nm~2000nm; the carrier can be used as carrier of protection agent in heavy oil producing, metal eliminating catalyst and so on.

The invention relates to a nanometer hole metal-organic frame material in a single-level or multilevel pore canal structure as well as a preparation method and the application thereof. The preparation method comprises the following steps: at least one metal salt and at least one polyfunctional group organic ligand reacts with at least one template agent in at least one solvent under the condition that no hole aid agent exists or only one hole aid agent exist, and single-level or multilevel nanometer holes or channels with the size of 0.5-100 nm exist in at least one direction in the internal space of the obtained metal-organic frame solid. The nanometer hole metal-organic frame material with large hole size and the nanometer hole metal-organic frame material in the layered multilevel pore canal structure can be obtained without the synthesis of the large-size organic ligand and have wide applications.

The invention discloses a heavy oil hydrogenation catalyst and a preparation method thereof. The heavy oil hydrogenation catalyst comprises a carrier and an active ingredient; the carrier is aluminum oxide, and is prepared from pseudo-boehmite with dry basis content below 50% via moulding; the active ingredient are metals selected form family VIII, Co or Ni, and/or family VI B, Mo or W. The preparation method comprises following steps: preparation of pseudo-boehmite, preparation of the carrier, and loading of the active ingredient. The heavy oil hydrogenation catalyst is capable of maintaining high demetalization, desulphurization, and carbon residue removing activities, simplifying drying process of pseudo-boehmite preparation, avoiding dust pollution caused by moulding process, increasing production efficiency, reducing production energy consumption, and reducing catalyst cost further.

This invention relates to a stable composite material comprising a support member that has a plurality of pores extending through the support member, and a macroporous crosslinked gel that is located in, and fills, the pores of the support member, in which crosslinked gel is entrapped a stabilising polymer, which stabilising polymer is neutral, linear or branched, non-crosslinked, and substantially water-insoluble. The presence of the stabilising polymer is such that it allows the composite material to largely retain its porosity and morphology after being dried. The invention also relates to a process for preparing the stable composite material described above, and to its use. The stable composite material is suitable, for example, for separation of substances, for example by filtration or adsorption, including chromatography, for use as a support in synthesis or for use as a support for cell growth.

A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.

A shift converter (16) in a fuel processing subsystem (14, 16, 18) for a fuel cell (12) uses an improved catalyst composition (50) to reduce the amount of carbon monoxide in a process gas for the fuel cell (12). The catalyst composition (50) is a noble metal catalyst having a promoted support of mixed metal oxide, including at least both ceria and zirconia. Cerium is present in the range of 30 to 50 mole %, and zirconium is present in the range of 70 to 50 mole %. Additional metal oxides may also be present. Use of the catalyst composition (50) obviates the requirement for prior reducing of catalysts, and minimizes the need to protect the catalyst from oxygen during operation and/or shutdown.

The invention discloses a diesel oil hydrogenation pour point depressing method. A series flow of hydrofining and hydrogenation pour point depressing is adopted in the method, wherein a hydrogenation pour point depressing catalyst is modified by metal auxiliary agent and silicon, effectively regulates the acidity and orifice shape of the inner surface and the outer surface of a shape-selective cracking molecular sieve, is favorable for dispersing wax molecules in a diesel oil raw material into pore canals of the molecular sieve to perform shape-selective cracking reaction, and has high catalytic activity and selectivity of a target product; and because the acidity of the outer surface of the molecular sieve is weak, side reactions such as secondary cracking and the like are reduced, the pour point depressing effect of the diesel oil is good, and the fraction yield of the diesel oil is high.

The invention discloses an active alumina/active carbon composite material and a preparation method thereof. The composite material comprises the following ingredients: 70-90 weight portions of sludge, 10-30 weight portions of active carbon, and 15-35 weight portions of binder, and is prepared by uniformly mixing, pelleting, aging, molding, drying in the air, sintering, rinsing and drying. Using sludge as raw material has an important meaning to environmental protection and recycling of waste. The invention has the advantages of simple preparation method, easy obtainment of raw material, and low cost, and can be widely applied in the fields of industry, agriculture, environmental protection, air cleaning, water treatment and the like.

An integral de-nitrating catalyst SCR with dual oxides as carrier for removing NOx from fume is characterized by that the cellular cordierite ceramic is used as skeleton, its composite carrier is composed of Al2O3 as internal layer and TiO2 as external layer, and its active component consists of V2O5 and WO3. Its advantages are high activity, wide active temp window, and high effect and mechanical stability.

The invention discloses preparation methods for a macroporous alumina carrier and a hydrodemetallization catalyst. The preparation method for the macroporous alumina carrier includes the following steps: (1) dry pseudoboehmite gel powder is hydrothermally processed under high pressure; (2) the dry pseudoboehmite gel powder obtained in step 1 is kneaded into a plastic, and pore-expanding agent is added in step 1 or step 2; (3) the plastic obtained in step 2 is shaped, the shaped material is dried and baked, and thereby the macroporous alumina carrier is obtained. The impregnation method is adopted to prepare the hydrodemetallization catalyst. The hydrodemetallization catalyst prepared by the method has large pore volume and pore diameter, centrally distributed pores, moderate mechanical strength and high activity and activity stability.

The invention involves alumina carrier used for Ag catalyst which is used for produce epoxyethane with oxygenizing ethane and its preparation method the Ag catalyst prepared by the carrier, and relates to the usage of the catalyst in ethane oxygenizes epoxyethane. The preparation method mixes three-hydratedalpha-aluminum oxide with certain particle size, hydratedalpha-aluminum oxide, certain amount of inflammable carbonaceous material, fluxing agent, fluoride and optional heavy alkaline earth metal compounds, adds admixture and water after mixing uniformly, kneading uniformly, squeezing and shaping, then preparingalpha-alumina carrier after drying and roasting. The specific surfaceof the invention is 0.2- 2.0m2/g, the hole volume is 0.35-0.85ml/g, water absorption ratio>=30%, crushing strength is 30-120N/ particle. The carrier is dipped by the solution of silver ammine complex, alkaline metal compound and alkaline earth metal compound, and prepares the Ag catalyst for epoxyethane with oxygenizing ethane after drying and activating.

The invention provides mesoporous spherical alumina and a method for preparing the mesoporous spherical alumina by guiding of a template. By the adoption of an oil column forming method, the template with a guiding function is added into aluminum sol during the aluminum sol preparation process; and during the forming and aging processes of the aluminum sol, due to the existence of the template with the guiding function, a large number of meso-structures are prepared in alumina balls. The mesoporous spherical alumina has the following characteristics of: its specific surface is 150-300 m<2>/g; particle diameter is 0.1-5 mm; pore volume is 0.7-1.5 ml/g; holes, hole diameter of which is 2-40 nm, are greater than 97%; bulk density is 0.30-0.80g/cm<3>; and crushing strength is 70-250 N/granule. The mesoporous spherical alumina can be used as a catalyst or a catalyst carrier in the petrochemical industry and the industry of fine chemicals.

The invention relates to a novel preparing method for an in-situ nitrogen-doped porous carbon material, the application of the in-situ nitrogen-doped porous carbon material serving as a carrier of a load type catalyst, the load type catalyst comprising the in-situ nitrogen-doped porous carbon material, and the application of the load type catalyst in the water phase alcohol condensation reaction. Cheap micromolecule nitrogen substances serve as a nitrogen source of the in-situ nitrogen-doped porous carbon material, nitrogen atom in-situ doping is achieved in the carbon material preparing process, the doping content of the in-situ nitrogen-doped porous carbon material is controllable, the in-situ nitrogen-doped porous carbon material is distributed evenly, the dispersity of metal in the carrier and the combining strength with the carrier can be improved through doping of nitrogen atoms, and therefore the catalytic activity of the nitrogen-doped porous carbon material can be improved, and the service life of the nitrogen-doped porous carbon material can be prolonged.

The invention discloses a hydrocracking catalyst carrier and a preparation method thereof. The catalyst carrier comprises a modified Y-type molecular sieve, amorphous silica-alumina and alumina, wherein the modified Y-type molecular sieve is Y-type molecular sieve treated by mixed aqueous solution of an aluminum salt and an acid and by hydrothermal process. In the carrier, the modified Y-type molecular sieve has a high crystallinity, high silicon to aluminum ratio and proper total acidity and acid distribution and can form an acid component with the amorphous silica-alumina. Therefore, the carrier is particularly suitable for serving as a hydrocracking catalyst carrier to improve the activity of a hydrocracking catalyst and the selectivity of middle distillates.

A catalyst for residual oil hydrodemetalling, which is composed of a carrier containing two types of pores and metal components such as Mo and/or W and Co and/or Ni, fixes on the carrier. The distribution of the pores in the said carrier is: the volume percentage of 10-20nm diameter pores in the total pore volume is 35-80%, the volume percentage of 500-1200nm diameter pores in the total pore volume is 15-60%, and the volume percentage of the pores with diameters ú“10nm, ú¥20-ú“500nm and ú¥1200nm in the total pore volume is 5-40%. The process for preparing the carrier comprises the steps of: mixing an alumina precursor with a nonacid nitrogenous compound, molding and sintering. The catalyst in this invention can be used as the catalyst for crude oil and normal atmosphere residual oil hydrodemetalling.

A cellular metallic wire net carrier with coated aluminum oxide layer is composed of a metallic carrier and a coated layer and has an internal 3D through structure. Its preparing process includes such steps as preparing the planar metallic wire nets and corrugated metallic wire nets from stainless steel wire, pre-treating, preparing electric depositing liquid from gamma-Al2O3 powder, electric depositing to form a coated aluminum oxide layer on said metallic wire nets, stacking them in stagger mode, and binding them together by the strips of metallic wire net.

A honeycomb structural body is constituted with a ceramic block made by arranging a plurality of through-holes side by side in the longitudinal direction through partition walls and sealing either one end portions of these through-holes. The ceramic block of this honeycomb structural body is made of a composite member consisting of ceramic particles and amorphous silicon, so that the honeycomb structural body has an excellent compression strength even if its porosity is increased, and is less in the lowering of mechanical strength even if it is heated to a high temperature, and is excellent in the durability.

Belonging to the technical field of catalysts, the invention discloses a nitrogen doped carbon material loaded catalyst. The carbon material can realize nitrogen doping by means of nitrogen containing precursor chemical coupling and other surface modification methods, also a nitrogen source and a carbon source can be introduced simultaneously at high temperature for in situ synthesis of a nitrogen doped carbon material, and then a simple substance or compound of one or more of gold, copper, manganese, potassium or bismuth can be loaded on the nitrogen doped carbon material. The nitrogen doped carbon material loaded mercury-free catalyst involved in the invention has activity and stability obviously superior to those of ordinary carbon material loaded catalysts. Under certain reaction conditions, the activity of the nitrogen doped carbon material loaded catalyst is superior to that of ordinary carbon material loaded catalysts by over 10%. The carbon material and the catalyst disclosed in the invention are green and non-toxic, and have good environmental benefits. The process involved in the invention is simple, economical and feasible.

A catalyst carrier including a ceramic block having two open faces, an outer peripheral surface, and multiple cells divided by a cell wall and extending between the open faces. The ceramic block has multiple honeycomb units combined by interposing an adhesive layer, where the honeycomb units include an outer-peripheral-side honeycomb unit and a center-side honeycomb unit combined to form the outer peripheral part and the center part, respectively, of the block. The outer-peripheral-side honeycomb unit has an outer peripheral cell wall forming the outer peripheral surface of the outer-peripheral-side honeycomb unit. The outer peripheral cell wall includes an outermost peripheral cell wall forming part of the outer peripheral surface of the block. A cell of the outer-peripheral-side honeycomb unit in contact with the outermost peripheral cell wall thereof has a corner part having a curved surface, where the corner part is on the side contacting the outermost peripheral cell wall.

The invention provides a multiphase wet oxidation catalyst, in which noble metal elements, which are selected from one or more than one of the group consisting of platinum, ruthenium, rhodium, iridium and aurum, are taken as active components; and rare earth elements, which are selected from one or more than one of the group consisting of lanthanum, cerium, praseodymium and neodymium, are taken as auxiliary components; the active components and the auxiliary components are carried on a ceramic-activated carbon carrier, wherein the content of activated carbon accounts for 1 to 15% of the totalweight of the ceramic-activated carbon carrier, and the weight of elements in the active components and the auxiliary components accounts for 0.25 to 5% of the weight of the activated carbon respectively. The invention further provides a preparation method and uses thereof. The catalyst of the invention is particularly suitable for the treatment of high-concentration organic waste water which is hardly degraded.

A catalyst carrier which comprises particles of a silicon-containing ceramic material. Each of these particles is covered by a film of alumina on which a noble metal is carried.

A honeycomb structure having multiple through holes includes at least ceramic particles and an inorganic binder. A wall thickness of each wall between adjoining through holes, on which a catalyst component is carried, is designed to be not greater than about 0.25 mm. The honeycomb structure satisfies a relation of Y≧250×X+22500 (50≦X≦80), where X denotes an aperture ratio (%) of a honeycombed face of the honeycomb structure perpendicular to the multiple through holes and Y denotes a specific surface area per unit volume (m²/L) of the honeycomb structure.

The invention discloses a method for preparing 5-hydroxymethylfurfural by solid acid catalysis. The method comprises the following steps of taking lignin residue hydrolyzed by biomass as carrier raw material of solid acid; synthesizing the raw material into solid acid through a two-step way of carbonization and sulfonation, so that the waste material is recycled and the problem of disposal of pollutants is solved. In the dehydration reaction of lignin-based solid acid catalyzed fructose and glucose, the yield of 5-hydroxymethylfurfural can be respectively 84% and 68%; after the dehydration reaction, the lignin-based solid acid is easy to separate and reusable, the acid density of the solid acid can be reduced after being reused five times, and the yield of the 5-hydroxymethylfurfural is still higher than 75%. The method provided by the invention can be used for realizing emission without pollution, and is helpful for realizing environment-friendly producing process of 5-hydroxymethylfurfural.

A catalyst with high activity for cleaning the tail gas of car is prepared through preparing the coated composite alumina layer containing Ce, Zr and one or more of La, Pr, Y, Fe, Mn, Cu and Ba on the cellular cordierite ceramic carrier, and chemically plating Pd.

The invention relates to hydrocracking of lignin, and specifically relates to a method for applying a tungsten-based catalyst to catalyze lignin hydrocracking for producing an aromatic compound. The catalyst comprises a main active component of non-zero-valent tungsten, and a second metal component of a small amount of one or more transition metals selected from zero-valent nickel, cobalt, ruthenium, iridium, palladium, platinum, iron, and copper. According to the method, raw materials such as lignin, biomass hydrolysis residue, lignosulfonate, and alkaline lignin are subject to catalytic hydrogenation under a hydrothermal condition with a temperature of 120 to 450 DEG C and a hydrogen pressure of 1 to 20MPa; the raw materials are cracked into C6-C9 phenolic compounds with high selectivity. A maximal phenol yield reaches 55.6%. Compared to existing technologies, according to the invention, renewable natural biomasses are adopted as raw materials, such that the raw materials are cheap, and have wide sources; inorganic acid and alkali are not required, such the production of a large amount of alkaline solution in traditional lignin catalysis is avoided; the tungsten-based catalyst is cheap; the reaction process is green, and has atom economical characteristics.

The invention discloses an attapulgite clay porous porous ceramsite, a preparation method of the ceramsite, and a purpose of the ceramsite. The ceramsite is prepared from raw materials of attapulgite clay and biomass, and a binder of industrial soluble glass. The ceramsite is prepared through calcining and oxidizing. The attapulgite clay porous ceramsite prepared by the present invention has advantages of high porosity, large specific surface area, high strength, strong water resistance, high water absorption, high catalytic activity, and the like. The porous ceramsite prepared by the presentinvention can be applied as a carrier for a catalyst, and a filling material for an aerated biological filter.

The invention discloses a preparation method of an alumina carrier with a composite pore structure, which comprises the steps of mixing and roasting an aluminum-contained compound and a composite template, wherein the composite template comprises a mesoporous template selected from at least one of a polyethylene glycol-polypropylene glycol-polyethylene glycol triblock polymer, polyethylene glycol, dodecylamine, hexadecyl trimethyl ammonium bromide, lauric acid, stearic acid and fatty alcohol polyoxyethylene ether and a macroporous particulate template selected from polystyrene microspheres with the particle size of greater than 50nm, polymethyl methacrylate microspheres, biomaterial particles, asphalt particles or heavy oil residues; and the weight ratio of the mesoporous template to the macroporous particulate template to the aluminum-contained compound (by alumina) is 0.1-2:0.1-0.7:1. The invention also discloses the alumina carrier simultaneously having mesoporous tunnels and macroporous tunnels prepared through the method, wherein mesopores account for 40-90% of the total pore volume, and macropores account for 10-60% of the total pore volume.