277 results about "Sulfamic acid" patented technology

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

The invention discloses a preparation method of salt-resistant sodium carboxymethyl cellulose, and relates to the technical field of petroleum fracturing materials. The preparation method comprises the following steps: reacting stearic acid with ethylenediamine to obtain a monosubstituted intermediate, reacting the monosubstituted intermediate with cocoyl chloride to obtain an intermediate 1, reacting the intermediate 1 with epoxypropane to obtain an intermediate 2, and reacting the intermediate 2 with paratoluensulfonyl chloride to obtain a hydrophobic intermediate; reacting a sodium carboxymethyl cellulose solution with the hydrophobic intermediate to obtain modified sodium carboxymethyl cellulose, and sulfonating the modified sodium carboxymethyl cellulose with sulfamic acid to obtain crude salt-tolerant sodium carboxymethyl cellulose; and reacting the crude product salt-resistant sodium carboxymethyl cellulose with borax to obtain the salt-resistant sodium carboxymethyl cellulose. The salt-resistant sodium carboxymethyl cellulose prepared by adopting a step-by-step synthesis strategy has excellent salt resistance, temperature resistance, shearing resistance and dissolution rate, and is suitable for thickening and sand carrying of high-temperature and high-salt oil and gas field fracturing fluid.

The invention discloses an electrolytic solution of a platinum-rhodium alloy, a preparation method and a preparation method of a plating layer of the platinum-rhodium alloy, and belongs to the technical field of precise electroplating. The electrolytic solution comprises a platinum salt, a rhodium salt, a first additive, a second additive, a first complexing agent, a second complexing agent, a first stabilizer and a second stabilizer, the first additive is a sulfamic acid compound containing 3-4 hydroxyalkyl groups, the second additive is sulfamic acid salt containing 3-4 hydroxyalkyl groups, and the first complexing agent and the second complexing agent are a platinum salt and a rhodium salt. The first complexing agent is a mixture of dicarboxylic acid and dicarboxylic acid containing amino or hydroxyl, the second complexing agent is a salt corresponding to the dicarboxylic acid, and the first stabilizer is a mixture of alkyl sulfonic acid and alkyl sulfonate. Through the synergistic effect of the additive, the complexing agent and the stabilizer, the additive, the complexing agent and the stabilizer form a five-membered to seven-membered heterocyclic coupling structure with platinum ions and rhodium ions, and the stability of the electrolytic solution is remarkably improved. And the obtained platinum-rhodium alloy coating is compact and uniform, and has excellent nitric acid steam and mixed gas corrosion resistance.

The invention discloses a bacteriostatic food packaging bag and a preparation method thereof, and relates to the technical field of food packaging, the bacteriostatic food packaging bag comprises the following components by weight: 12-22 parts of bamboo fiber; 55 to 80 parts of TPS (Thermoplastic Polystyrene); 15-20 parts of a modified ethylene composite copolymer; 15 to 20 parts of modified chitosan; wherein the modified ethylene composite copolymer is obtained by polymerizing active group-containing ethylene and one of vinyl acetate, butene, hexene or octylene according to a molar ratio of 10: (3-6); the active group is at least one of amino and sulfonic acid group; the modified chitosan is sulfo-grafted chitosan, and the mass grafting rate is greater than 0.1 wt%. The preparation method has the advantages that the compatibility of a composition formula is improved through the modified ethylene composite copolymer and the modified chitosan, a uniform net structure is formed in a cross-linking reaction to serve as a supporting framework, the overall mechanical structure performance is enhanced through the bamboo fibers which are synergistically and uniformly distributed in the composition formula, and the degradable and non-toxic effects are achieved through the cooperation of the bamboo fibers and the TPS.

The invention relates to a high-performance reactive asphalt cold patch mixture and a preparation process thereof. The mixture comprises a sulfonated fatty acid diluent, a graded aggregate, an atomic layer deposition (ALD) modified basalt aggregate and a solid waste-based composite curing agent. The sulfonated fatty acid diluent is prepared by sulfonating oleic acid, linoleic acid and palmitic acid through sulfamic acid, the sulfonation degree is 15-20%, and the sulfonated fatty acid diluent contains an epoxy three-membered ring structure; the 3-5mm aggregate is used as a transition layer to block the caking path of the fine aggregate; the basalt aggregate is subjected to TDMAT and TMA alternate deposition to form a Ti < x > Al < gamma > O < 2 > nano film; the curing agent comprises calcium strontium sulphoaluminate minerals, a titanium gypsum-carbide slag compound and magnesium-loaded lithium slag. During preparation, the modified aggregate, the sulfonated diluent and the curing agent are mixed at normal temperature. The problems that a traditional cold repairing material is poor in low-temperature fluidity and weak in interface bonding are solved, the viscosity at-20 DEG C is smaller than or equal to 450 mPa.s, the 7-day strength is larger than or equal to 5.2 kN, and the cold repairing material is suitable for low-temperature emergency repairing.

The invention discloses a method for extracting copper fine powder by flotation of copper-containing ore, which belongs to the technical field of mineral processing, and comprises the following steps: after copper-containing raw ore is crushed, ground and classified by a cyclone, overflow enters flotation, and settled sand is returned for regrinding; sodium carbonate is added into graded overflow to adjust the pH, a sodium hexametaphosphate-polyacrylamide composite dispersant is added, and copper sulfate is added and stirred after low-temperature microwave heating; gradient flotation is conducted, specifically, copper sulfide is roughly selected, the pH is adjusted, an amino-sulfonic acid group synergistic modified layered double metal hydroxide / cobalt ferrite composite collecting agent is added, and rough concentrate 1 is obtained through high-frequency pulse air inflation flotation; copper oxide roughing is conducted, clear water is supplemented to adjust the pH, and a collecting agent is supplemented to obtain rough concentrate 2; scavenging is performed for three times, a collecting agent is added for flotation, and concentrate returns to the previous stage; the rough concentrates are combined, and magnetic impurities are removed through high-gradient magnetic separation to obtain magnetic concentrates; and carrying out microbiological leaching on tailings to recover copper. The composite collecting agent is prepared through layered double hydroxide carrier synthesis, amino modification, sulfonic acid group grafting and cobalt ferrite anchoring.

The invention discloses a preparation method of high-purity bis (fluorosulfonyl) imide alkali metal salt. The method comprises the following steps: (1) synthesizing bis (chlorosulfonic acid) imide by taking sulfamic acid, chlorosulfonic acid, thionyl chloride and chlorosulfonic acid isocyanate as raw materials; (2) fluorinating the bis (chlorosulfonic acid) imide by ammonium fluoride to obtain bis (fluorosulfonyl) imide ammonium salt; (3) treating the imidodisulfuryl fluoride ammonium salt solution with a strong acid ion exchange column and concentrating under reduced pressure to obtain imidodisulfuryl fluoride; (4) reacting the alkali metal salt with bis (fluorosulfonyl) imide to obtain bis (fluorosulfonyl) imide alkali metal salt; and (5) carrying out a series of purification processes on the bis (fluorosulfonyl) imide alkali metal salt to obtain the high-purity bis (fluorosulfonyl) imide alkali metal salt. The preparation method has the advantages of mild reaction conditions, low danger coefficient in the technological process, easiness in control, no use and generation of corrosive acid, greenness and environmental protection, and high yield and high purity of the bis (fluorosulfonyl) imide alkali metal salt, and is suitable for large-scale industrial application.

The invention belongs to the technical field of oil exploitation, and relates to a drag reducer for fracturing and a preparation method thereof. The preparation method comprises the following steps: adding 1, 5-hexadiene-3, 4-diol and a catalyst into a high-pressure reactor, raising the temperature, introducing ethylene oxide, raising the temperature, carrying out a heat preservation reaction, stopping heating, and cooling to 50 DEG C or below; adjusting the pH value to 2-3 by using phosphoric acid, adding sulfamic acid, heating, preserving heat and reacting, and cooling to below 40 DEG C; the preparation method comprises the following steps: adding deionized water, 2-(trifluoromethyl) acrylic acid and methacryloylethyl sulphobetaine, stirring and dissolving, adjusting the pH value to 7-8, adding an initiator, heating and carrying out a heat preservation reaction to obtain a viscous liquid; and settling, centrifuging, cleaning and drying to obtain the product drag reducer. The drag reducer has the characteristics of high viscosity and high drag reduction rate.

The present invention discloses aramid insulation paper, a preparation method, and applications, relating to the technical field of aramid paper. The present invention utilizes cellulose treated with a treatment agent A and aminosulfonic acid in combination with meta-aramid chopped fibers treated with the treatment agent A to produce aramid insulation paper with excellent mechanical properties and resistance to high-frequency partial discharge and high temperatures.

The invention provides a rubidium and cesium adsorbent and a preparation method and application thereof. The preparation method comprises the following steps: providing a doped and modified Prussian blue analogue, wherein the Prussian blue analogue comprises a Prussian blue matrix material and a transition metal doping element doped in the Prussian blue matrix material; granulating a mixed material containing the doped and modified prussian blue analogue and a granulating agent to obtain a rubidium and cesium adsorbent precursor; a mixed reaction system containing the rubidium and cesium adsorbent precursor and a surface modifier are subjected to a reaction, the surface modifier contains one or more functional structures of an amino group, a sulfonic group, a carboxyl group, a sulfydryl group, an acryloyloxy group, an epoxy group, a crown ether structure and a calixarene structure, and therefore the rubidium and cesium adsorbent is obtained. Through a multi-aspect synergistic strategy of transition metal doping, granulation and surface modification, the prepared rubidium and cesium adsorbent has good stability and high adsorption capacity, and has strong selectivity to Cs < + > / Rb < + >.

The invention provides a preparation method of ethylene carbonate and ethylene sulfate, which comprises the following steps: 1) by taking vinylethylene carbonate as a raw material, carrying out oxidation reaction with an oxidant to obtain epoxy ethylene carbonate as shown in a formula I; and 2) carrying out heating reaction on the epoxy ethylene carbonate as shown in the formula I obtained in the step 1) and sulfamic acid in an acidic solvent to obtain ethylene carbonate disulfate as shown in a formula II. The method avoids the problem of poor reaction selectivity caused by using butantetraol as a raw material in the prior art; according to the method disclosed by the invention, an intermediate butantetraol carbonate is not generated, so that the problem that the intermediate further reacts to generate a byproduct 2, 4, 7-trioxa-3-oxy-bicyclo [3.3. 0] octane does not exist; in addition, when the final product sulfate is synthesized, mild and non-irritant sulfamic acid is used, and the method has the advantages of being clean, green and environmentally friendly.

The invention relates to the technical field of all-vanadium redox flow batteries, and particularly discloses a composition for promoting continuous production of a vanadium electrolyte and application of the composition. The invention discloses a composition for promoting continuous production of a vanadium electrolyte, which is characterized by specifically comprising the following components in parts by weight: 32-42 parts of concentrated sulfuric acid, 0.8-1.2 parts of a sulfonic acid compound, 0.05-0.15 part of sodium sulfate and 60-66 parts of water, the sulfonic acid compound is selected from any one or more of methanesulfonic acid, ethanesulfonic acid, benzenesulfonic acid, sulfamic acid and p-toluenesulfonic acid. When the composition provided by the invention is used in continuous production of the vanadium electrolyte, the use amount of concentrated sulfuric acid is reduced, vanadium pentoxide can be effectively activated, and the reaction rate is increased; and the produced vanadium electrolyte has excellent electrochemical performance.

Provided in the present application is a method for treating a heavy bis(fluorosulfonyl)imide residue, comprising the following step: causing a starting material system comprising the heavy bis(fluorosulfonyl)imide residue and an acidic aqueous solution to react to obtain a fluorine-containing acid solution and a crude sulfamic acid product, wherein the fluorine-containing acid solution can be used as a by-product acid, thereby saving treatment costs; and the crude sulfamic acid product can also be directly sold as a product, thereby reducing treatment costs, bringing economic benefits, and achieving resource recycling of the heavy bis(fluorosulfonyl)imide residue.

The invention discloses a rare earth element doping modification process of an optical module electroplated layer, which belongs to the technical field of optical module manufacturing, and comprises the following steps: sequentially carrying out oil removal, acid pickling and activation treatment on an optical module matrix to form a clean active surface; the preparation method comprises the following steps: taking nickel aminosulfonate or potassium gold cyanide as main salt, adding 0.5-5g / L of rare earth salt which is at least one of cerium chloride, lanthanum nitrate or yttrium sulfate, and adding 5-15g / L of sodium citrate complexing agent and lauryl sodium sulfate surfactant; under the conditions that the pH is 3.5-4.5 and the temperature is 45-55 DEG C, pulse current with the density being 2-5 A / dm < 2 > is adopted for electroplating, the pulse frequency is 100-500 Hz, and the duty ratio is 30-50%; when electroplating deposition is carried out, hydrogen bubbles on the outer side of the optical module are removed through a hydrogen removal device, the hydrogen bubbles are prevented from being attached to the surface of a cathode, and the uniformity of codeposition of rare earth and metal is ensured; and after electroplating is completed, deionized water cleaning and vacuum drying are carried out on the optical module. The high temperature resistance of the surface of the optical module obtained through the technology is improved.

The invention belongs to the technical field of fabric treatment, and particularly relates to a fabric hydrophilic finishing agent as well as a preparation method and application thereof. The fabric hydrophilic finishing agent comprises water and the following preparation raw materials in percentage by mass: 6%-7% of hexamethylene diisocyanate tripolymer, 4%-5% of polyether polyol, 6%-8% of polyethylene glycol monomethyl ether, 0.5%-1% of sulfamic acid, 1%-2% of an emulsifier, 0.5%-1% of polyether amino silicon oil and 0.1%-0.3% of acetic acid. The prepared finishing agent has good hydrophilicity, washing resistance, yellowing resistance and the like, and is suitable for after-finishing of fabrics, especially chinlon and chinlon-containing blended fabrics.

The present invention provides sulfamate derivative prodrugs of the dopamine agonist (4aR,10aR)-1-propyl-1,2,3,4,4a,5,10,10a-octahydro-benzo[g]quinoline-6,7-diol, their use in treating conditions for which treatment with a dopamine agonist has therapeutic benefit, and pharmaceutical compositions comprising a compound of the present invention. The compounds according to the present invention have the formula (Id), wherein R1and R2are each independently selected from H and the substituent (iii) below, wherein * indicates the point of attachment to oxygen, wherein R3is selected from H and COR4, and wherein R4is selected from H and C1-C6alkyl, with the proviso that R1and R2cannot both be H, 15or a pharmaceutically acceptable salt thereof.

The present application relates to the technical field of pipeline drainage, and particularly relates to a composite hydrophobic material for inhibiting crystallization of a tunnel drainage pipeline and a preparation method thereof; the composite hydrophobic material comprises a hydrophobic inner layer and a scale inhibition outer layer attached to the outer surface of the hydrophobic inner layer; the hydrophobic inner layer comprises tetrahydrofuran, a solvent volatilizing agent, a surfactant, nano-silicon dioxide, a cross-linking agent and a curing agent; the scale inhibition outer layer comprises a scale inhibitor solution and a gum material, wherein the scale inhibitor solution comprises EDTA, hydrolyzed maleic anhydride and sulfamic acid; the preparation method comprises the following steps: S1, coating the hydrophobic inner layer material; S2, air-drying to obtain the hydrophobic inner layer; S3, coating the scale inhibition outer layer material on the surface of the hydrophobic inner layer to obtain the composite material; the composite material prepared by the present application still has excellent hydrophobic performance after being left for 24 hours and can be maintained for a long time; the scale inhibition outer layer protects the hydrophobic inner layer and simultaneously plays a scale inhibition role, thereby improving the functionality of the material.

The application belongs to the technical field of tertiary oil recovery, and relates to a heavy oil viscosity reducer and a preparation method and application thereof.The preparation method is as follows: p-nonyl phenol, 1-(4-fluorophenyl)piperazine, 40wt% formaldehyde and water are added into a reactor, stirring is carried out, temperature is increased to reflux, and temperature is kept;temperature is reduced to below 40 DEG C, extraction is carried out, the obtained product is placed in a high-pressure reactor, sodium hydroxide solid is added, nitrogen is introduced, vacuum is drawn, temperature is increased, vacuum drawing is stopped, ethylene oxide is slowly introduced, temperature is increased, and temperature is kept;viscous liquid is obtained through reduced pressure distillation, the obtained product is placed in a high-pressure reactor, pH is adjusted to 3-4, aminosulfonic acid powder is added, stirring and heating are carried out, temperature is kept, and the obtained product is cooled to below 40 DEG C;ethanolamine is added, pH is adjusted to 7-8, and the heavy oil viscosity reducer is obtained.The viscosity reducer has the advantages of low surface tension, low interfacial tension, low critical micelle concentration and good viscosity reduction effect.

A sulfamic acid refined product washing system comprises a cleaning water buffer tank, the bottom of the cleaning water buffer tank is connected with a scraper lower discharging centrifugal machine through a cleaning water conveying pipe, a cleaning liquid outlet of the scraper lower discharging centrifugal machine is connected with a horizontal centrifugal machine through a cleaning liquid conveying pipe, and the horizontal centrifugal machine is connected with an electrolytic bath through a clear liquid pipe. The electrolytic cell is connected with a top liquid inlet pipe of the cleaning water buffer tank through a clean water pipe. By the adoption of the structure, the washing efficiency is improved through improved water circulation and treatment processes, and it is ensured that washed products meet strict quality standards.

The invention provides a method for treating bis (fluorosulfonyl) imide heavy slag, which comprises the following steps: reacting a raw material system comprising bis (fluorosulfonyl) imide heavy slag and an acidic aqueous solution to obtain a fluorine-containing acid solution and a sulfamic acid crude product; wherein the fluorine-containing acid liquid can be used as a byproduct acid, so that the treatment cost is saved; and the sulfamic acid crude product can also be directly sold as a product, so that the treatment cost is reduced, economic benefits are brought, and resource recycling of the bis (fluorosulfonyl) imide heavy slag is realized.

The invention discloses an electrochemical polishing solution for laser additive manufacturing of a tantalum material and a preparation method and process, and relates to the technical field of surface treatment of metal workpieces. According to the electrochemical polishing solution, an alcohol-salt system is adopted for electropolishing treatment, and compared with a traditional electropolishing solution, the electrochemical polishing solution has the advantages of electrochemical and chemical stability, relatively high conductivity, relatively high controllability, relatively low toxicity, low volatility, environment friendliness and the like; the electropolishing solution has the characteristics of no volatilization, no odor, low toxicity to a human body and the like by adding the inorganic solid acid formed by replacing sulfamic acid sulfuric acid hydroxyl with amino, and not only has the oxidation capacity of sulfuric acid, but also can promote dissolution and improve the material removal rate by the amino; the electrochemical polishing solution is mild in process parameter, insensitive to temperature, capable of implementing polishing at room temperature, small in corrosion to electrolysis equipment and capable of being used for a long time.

The invention discloses a humic acid-based soil alkalinity adjusting agent and a preparation method thereof, and belongs to the field of soil amendments, the humic acid-based soil alkalinity adjusting agent comprises the following raw materials by weight: 30-50 parts of a modified humic acid carrier; 8-15 parts of carbonate; 3-5 parts of a microbial agent; wherein the modified humic acid carrier is prepared from the following raw materials: acylating chlorinated nano humic acid, sulfamic acid and acidified chitosan in a mass ratio of 1: (0.1-0.4): (0.1-0.3). The density of acidic functional groups is improved by modifying nano humic acid through sulfamic acid, a three-dimensional network structure is constructed by the nano humic acid and acidified chitosan, and meanwhile, carbonate, a microbial agent and hydroxyapatite are compounded, so that high efficiency and durability of an alkali adjusting effect are realized. Compared with a traditional inorganic acid modifier, the modifier can prevent local pH sudden change from burning crop root systems, the three-dimensional network structure can delay carbonate release, the alkali adjusting effect is continuous, and the problems that a traditional modifier acts transiently, and soil is prone to being damaged are effectively solved.

The present disclosure provides methods, pharmaceutical compositions, and kits for treating cancer in patients in need thereof. The methods comprise administering to a patient in need a small ubiquitin-like modifier (SUMO) activating enzyme (SAE) inhibitor, such as [(1R,2S,4R)-4-{[5-({4-[(1R)-7-chloro-1,2,3,4-tetrahydroisoquinolin-1-yl]-5-methyl-2-thienyl}carbonyl)pyrimidin-4-yl]amino}-2-hydroxy-cyclopentyl]methyl sulfamate (Compound I-263a) or a pharmaceutically acceptable salt, in combination with one or more anti-CD19 antibodies. Also provided are medicaments for use in treating cancer.

The application relates to the technical field of organic dyes, in particular to a double-active-group cationic modified anthraquinone reactive dye as well as a preparation method and application thereof. The preparation method of the double-active-group cationic modified anthraquinone reactive dye comprises the following steps: S1: dissolving 1-amino-4-sulfonic acid-1'-(N,N-dimethylpropylaminomethyl) anthraquinone in ice water, then adding melamine dropwise to carry out reaction, and obtaining an intermediate solution; S2: the intermediate solution is warmed to 20-25 DEG C, and hydroxyethyl sulfone sulfonate is added to carry out reaction; after the reaction is completed, salting-out is carried out, and the double-active-group cationic modified anthraquinone reactive dye is obtained, as shown in formula (1). The reactive dye is synergized through the cooperation of "double active groups + cationic adjustment + precise water-solubility design", can guarantee water-solubility and dyeing fastness, and can completely get rid of the dependence on a large amount of salt.

The application relates to the technical field of barrel-mixed auxiliary agents, and particularly discloses a preparation method of an anionic vesicular barrel-mixed auxiliary agent. The method comprises the following operation steps: S1: adding a 40wt% alkali solution into component A, heating and reacting, aging, removing water, cooling to 20-25 DEG C, adding ethanol and uniformly mixing to obtain component B; S2: under a nitrogen atmosphere, heating monoglyceride to 80-85 DEG C, adding sulfamic acid and a catalyst, uniformly mixing, heating to 120-125 DEG C and reacting for 3-3.5 hours, adding propylene glycol and uniformly mixing to obtain component C; and S3: uniformly mixing component A, component B, component C and component D, adjusting the pH by using sodium dihydrogen phosphate and disodium hydrogen phosphate to obtain the anionic vesicular barrel-mixed auxiliary agent.

The present application relates to the oil field chemical technology field, it is a kind of preparation method and application of amino sulfonic acid betaine type surfactant containing polyoxyethylene ether chain segment, the amino sulfonic acid betaine type surfactant containing polyoxyethylene ether chain segment raw material includes by mass fraction.The amino sulfonic acid betaine type surfactant containing polyoxyethylene ether chain segment of the present application is green environmental protection, biodegradable, preparation operation is simple, and flammable, explosive, volatile organic solvent is not used in process, safe and reliable;It is beneficial to industrial production and popularization and application, and has broad market prospect.The acidizing fracturing cleanup aid with it as raw material can effectively reduce the oil and gas field fracturing fluid surface, interfacial tension, while the amount of surfactant in cleanup aid is lower, and the use cost is saved.

The invention relates to the technical field of oilfield chemistry, in particular to a sulfamic acid type surfactant as well as a preparation method and application thereof.The sulfamic acid type surfactant is prepared according to the following steps: step one, after fatty amine and a first solvent are mixed, adding a 3-chloro-2-hydroxypropyl sodium sulfonate aqueous solution, and stirring to obtain a first mixture; reacting to obtain 3-(long-chain alkylamino)-2-hydroxypropane-1-sodium sulfonate; and 2, dissolving a required amount of 3-(long-chain alkylamino)-2-hydroxypropane-1-sodium sulfonate in a second solvent, adding a required amount of methyl acrylate, and reacting to obtain the sulfamic acid type surfactant. The sulfamic acid type surfactant disclosed by the invention contains long-chain alkyl, amino, ester group, hydroxyl and sulfonic acid group, so that the sulfamic acid type surfactant has good surface activity and meets the development requirements of oil and gas fields, and the microemulsion cleanup additive prepared by utilizing the sulfamic acid type surfactant has excellent water solubility and surface activity and meets the industrial use standards of non-fluorocarbon cleanup additives.

This invention discloses a method for directly preparing bis(fluorosulfonyl)imide from aminosulfonic acid, chlorosulfonic acid, and oxaloyl fluoride in a one-step reaction. This method has the advantages of simple operation, mild reaction conditions, fast reaction speed, and easy product purification.

The utility model relates to the field of electrochemistry, in particular to a spiral-flow type cation exchange membrane electrolysis device, which is a spiral-flow type electrolysis device for realizing conversion electrolysis of different solution systems by utilizing the characteristic that a cation exchange membrane has selective permeation on cations. Comprising a cathode cylinder, a cation exchange membrane anode, an upper cover, a lower cover, a starting sheet, a cathode region rotational flow lower liquid inlet device, a cathode region rotational flow upper liquid outlet device, an upper starting sheet pressing ring, a lower supporting isolating ring, a sealing assembly and an anode positioning rod. The device is suitable for mutual migration and conversion of cations among a chlorination system, a sulfuric acid system, a nitric acid system, a sulfamic acid system, a phosphoric acid system, a thiourea system and a cyanide system, so that the problem that an original system cannot be normally electrolyzed is solved from the source, and the application range of an electrolysis process is expanded; the method is particularly suitable for efficient metal copper electrolysis when a copper chloride solution system is converted into a copper sulfate solution system.

The invention discloses an efficient recycling method for a ternary positive electrode material of a lithium ion battery based on a deep-eutectic solvent, and belongs to the technical field of recycling of waste lithium ion batteries. The method mainly comprises the following steps: mildly stripping a ternary positive plate obtained by disassembling in a first DES stripping solvent prepared from benzyl triphenyl phosphorus chloride and octanoic acid, washing, drying, crushing, screening and grinding to obtain ternary positive fine powder; and efficiently leaching the ternary positive electrode fine powder by using a second DES leaching solvent prepared from acetamide and sulfamic acid. According to the method, a novel eutectic solvent is adopted to achieve lossless stripping of the waste ternary positive electrode material and the current collector, another novel eutectic solvent is used to achieve efficient leaching of valuable metal in the ternary positive electrode material, and the purposes that the whole process is environmentally friendly, low in consumption, high in metal recovery rate and excellent in performance of a re-prepared battery are achieved.