195 results about "Sulfamic acid" patented technology

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

The invention discloses an electrolytic solution of a platinum-rhodium alloy, a preparation method and a preparation method of a plating layer of the platinum-rhodium alloy, and belongs to the technical field of precise electroplating. The electrolytic solution comprises a platinum salt, a rhodium salt, a first additive, a second additive, a first complexing agent, a second complexing agent, a first stabilizer and a second stabilizer, the first additive is a sulfamic acid compound containing 3-4 hydroxyalkyl groups, the second additive is sulfamic acid salt containing 3-4 hydroxyalkyl groups, and the first complexing agent and the second complexing agent are a platinum salt and a rhodium salt. The first complexing agent is a mixture of dicarboxylic acid and dicarboxylic acid containing amino or hydroxyl, the second complexing agent is a salt corresponding to the dicarboxylic acid, and the first stabilizer is a mixture of alkyl sulfonic acid and alkyl sulfonate. Through the synergistic effect of the additive, the complexing agent and the stabilizer, the additive, the complexing agent and the stabilizer form a five-membered to seven-membered heterocyclic coupling structure with platinum ions and rhodium ions, and the stability of the electrolytic solution is remarkably improved. And the obtained platinum-rhodium alloy coating is compact and uniform, and has excellent nitric acid steam and mixed gas corrosion resistance.

The invention discloses a bacteriostatic food packaging bag and a preparation method thereof, and relates to the technical field of food packaging, the bacteriostatic food packaging bag comprises the following components by weight: 12-22 parts of bamboo fiber; 55 to 80 parts of TPS (Thermoplastic Polystyrene); 15-20 parts of a modified ethylene composite copolymer; 15 to 20 parts of modified chitosan; wherein the modified ethylene composite copolymer is obtained by polymerizing active group-containing ethylene and one of vinyl acetate, butene, hexene or octylene according to a molar ratio of 10: (3-6); the active group is at least one of amino and sulfonic acid group; the modified chitosan is sulfo-grafted chitosan, and the mass grafting rate is greater than 0.1 wt%. The preparation method has the advantages that the compatibility of a composition formula is improved through the modified ethylene composite copolymer and the modified chitosan, a uniform net structure is formed in a cross-linking reaction to serve as a supporting framework, the overall mechanical structure performance is enhanced through the bamboo fibers which are synergistically and uniformly distributed in the composition formula, and the degradable and non-toxic effects are achieved through the cooperation of the bamboo fibers and the TPS.

The invention discloses a method for extracting copper fine powder by flotation of copper-containing ore, which belongs to the technical field of mineral processing, and comprises the following steps: after copper-containing raw ore is crushed, ground and classified by a cyclone, overflow enters flotation, and settled sand is returned for regrinding; sodium carbonate is added into graded overflow to adjust the pH, a sodium hexametaphosphate-polyacrylamide composite dispersant is added, and copper sulfate is added and stirred after low-temperature microwave heating; gradient flotation is conducted, specifically, copper sulfide is roughly selected, the pH is adjusted, an amino-sulfonic acid group synergistic modified layered double metal hydroxide / cobalt ferrite composite collecting agent is added, and rough concentrate 1 is obtained through high-frequency pulse air inflation flotation; copper oxide roughing is conducted, clear water is supplemented to adjust the pH, and a collecting agent is supplemented to obtain rough concentrate 2; scavenging is performed for three times, a collecting agent is added for flotation, and concentrate returns to the previous stage; the rough concentrates are combined, and magnetic impurities are removed through high-gradient magnetic separation to obtain magnetic concentrates; and carrying out microbiological leaching on tailings to recover copper. The composite collecting agent is prepared through layered double hydroxide carrier synthesis, amino modification, sulfonic acid group grafting and cobalt ferrite anchoring.

The invention belongs to the technical field of oil exploitation, and relates to a drag reducer for fracturing and a preparation method thereof. The preparation method comprises the following steps: adding 1, 5-hexadiene-3, 4-diol and a catalyst into a high-pressure reactor, raising the temperature, introducing ethylene oxide, raising the temperature, carrying out a heat preservation reaction, stopping heating, and cooling to 50 DEG C or below; adjusting the pH value to 2-3 by using phosphoric acid, adding sulfamic acid, heating, preserving heat and reacting, and cooling to below 40 DEG C; the preparation method comprises the following steps: adding deionized water, 2-(trifluoromethyl) acrylic acid and methacryloylethyl sulphobetaine, stirring and dissolving, adjusting the pH value to 7-8, adding an initiator, heating and carrying out a heat preservation reaction to obtain a viscous liquid; and settling, centrifuging, cleaning and drying to obtain the product drag reducer. The drag reducer has the characteristics of high viscosity and high drag reduction rate.

The invention provides a rubidium and cesium adsorbent and a preparation method and application thereof. The preparation method comprises the following steps: providing a doped and modified Prussian blue analogue, wherein the Prussian blue analogue comprises a Prussian blue matrix material and a transition metal doping element doped in the Prussian blue matrix material; granulating a mixed material containing the doped and modified prussian blue analogue and a granulating agent to obtain a rubidium and cesium adsorbent precursor; a mixed reaction system containing the rubidium and cesium adsorbent precursor and a surface modifier are subjected to a reaction, the surface modifier contains one or more functional structures of an amino group, a sulfonic group, a carboxyl group, a sulfydryl group, an acryloyloxy group, an epoxy group, a crown ether structure and a calixarene structure, and therefore the rubidium and cesium adsorbent is obtained. Through a multi-aspect synergistic strategy of transition metal doping, granulation and surface modification, the prepared rubidium and cesium adsorbent has good stability and high adsorption capacity, and has strong selectivity to Cs < + > / Rb < + >.

The invention provides a preparation method of ethylene carbonate and ethylene sulfate, which comprises the following steps: 1) by taking vinylethylene carbonate as a raw material, carrying out oxidation reaction with an oxidant to obtain epoxy ethylene carbonate as shown in a formula I; and 2) carrying out heating reaction on the epoxy ethylene carbonate as shown in the formula I obtained in the step 1) and sulfamic acid in an acidic solvent to obtain ethylene carbonate disulfate as shown in a formula II. The method avoids the problem of poor reaction selectivity caused by using butantetraol as a raw material in the prior art; according to the method disclosed by the invention, an intermediate butantetraol carbonate is not generated, so that the problem that the intermediate further reacts to generate a byproduct 2, 4, 7-trioxa-3-oxy-bicyclo [3.3. 0] octane does not exist; in addition, when the final product sulfate is synthesized, mild and non-irritant sulfamic acid is used, and the method has the advantages of being clean, green and environmentally friendly.

Provided in the present application is a method for treating a heavy bis(fluorosulfonyl)imide residue, comprising the following step: causing a starting material system comprising the heavy bis(fluorosulfonyl)imide residue and an acidic aqueous solution to react to obtain a fluorine-containing acid solution and a crude sulfamic acid product, wherein the fluorine-containing acid solution can be used as a by-product acid, thereby saving treatment costs; and the crude sulfamic acid product can also be directly sold as a product, thereby reducing treatment costs, bringing economic benefits, and achieving resource recycling of the heavy bis(fluorosulfonyl)imide residue.

The present invention provides sulfamate derivative prodrugs of the dopamine agonist (4aR,10aR)-1-propyl-1,2,3,4,4a,5,10,10a-octahydro-benzo[g]quinoline-6,7-diol, their use in treating conditions for which treatment with a dopamine agonist has therapeutic benefit, and pharmaceutical compositions comprising a compound of the present invention. The compounds according to the present invention have the formula (Id), wherein R1and R2are each independently selected from H and the substituent (iii) below, wherein * indicates the point of attachment to oxygen, wherein R3is selected from H and COR4, and wherein R4is selected from H and C1-C6alkyl, with the proviso that R1and R2cannot both be H, 15or a pharmaceutically acceptable salt thereof.

The present application relates to the technical field of pipeline drainage, and particularly relates to a composite hydrophobic material for inhibiting crystallization of a tunnel drainage pipeline and a preparation method thereof; the composite hydrophobic material comprises a hydrophobic inner layer and a scale inhibition outer layer attached to the outer surface of the hydrophobic inner layer; the hydrophobic inner layer comprises tetrahydrofuran, a solvent volatilizing agent, a surfactant, nano-silicon dioxide, a cross-linking agent and a curing agent; the scale inhibition outer layer comprises a scale inhibitor solution and a gum material, wherein the scale inhibitor solution comprises EDTA, hydrolyzed maleic anhydride and sulfamic acid; the preparation method comprises the following steps: S1, coating the hydrophobic inner layer material; S2, air-drying to obtain the hydrophobic inner layer; S3, coating the scale inhibition outer layer material on the surface of the hydrophobic inner layer to obtain the composite material; the composite material prepared by the present application still has excellent hydrophobic performance after being left for 24 hours and can be maintained for a long time; the scale inhibition outer layer protects the hydrophobic inner layer and simultaneously plays a scale inhibition role, thereby improving the functionality of the material.

A sulfamic acid refined product washing system comprises a cleaning water buffer tank, the bottom of the cleaning water buffer tank is connected with a scraper lower discharging centrifugal machine through a cleaning water conveying pipe, a cleaning liquid outlet of the scraper lower discharging centrifugal machine is connected with a horizontal centrifugal machine through a cleaning liquid conveying pipe, and the horizontal centrifugal machine is connected with an electrolytic bath through a clear liquid pipe. The electrolytic cell is connected with a top liquid inlet pipe of the cleaning water buffer tank through a clean water pipe. By the adoption of the structure, the washing efficiency is improved through improved water circulation and treatment processes, and it is ensured that washed products meet strict quality standards.

The invention provides a method for treating bis (fluorosulfonyl) imide heavy slag, which comprises the following steps: reacting a raw material system comprising bis (fluorosulfonyl) imide heavy slag and an acidic aqueous solution to obtain a fluorine-containing acid solution and a sulfamic acid crude product; wherein the fluorine-containing acid liquid can be used as a byproduct acid, so that the treatment cost is saved; and the sulfamic acid crude product can also be directly sold as a product, so that the treatment cost is reduced, economic benefits are brought, and resource recycling of the bis (fluorosulfonyl) imide heavy slag is realized.

The invention discloses an electrochemical polishing solution for laser additive manufacturing of a tantalum material and a preparation method and process, and relates to the technical field of surface treatment of metal workpieces. According to the electrochemical polishing solution, an alcohol-salt system is adopted for electropolishing treatment, and compared with a traditional electropolishing solution, the electrochemical polishing solution has the advantages of electrochemical and chemical stability, relatively high conductivity, relatively high controllability, relatively low toxicity, low volatility, environment friendliness and the like; the electropolishing solution has the characteristics of no volatilization, no odor, low toxicity to a human body and the like by adding the inorganic solid acid formed by replacing sulfamic acid sulfuric acid hydroxyl with amino, and not only has the oxidation capacity of sulfuric acid, but also can promote dissolution and improve the material removal rate by the amino; the electrochemical polishing solution is mild in process parameter, insensitive to temperature, capable of implementing polishing at room temperature, small in corrosion to electrolysis equipment and capable of being used for a long time.

The invention discloses a humic acid-based soil alkalinity adjusting agent and a preparation method thereof, and belongs to the field of soil amendments, the humic acid-based soil alkalinity adjusting agent comprises the following raw materials by weight: 30-50 parts of a modified humic acid carrier; 8-15 parts of carbonate; 3-5 parts of a microbial agent; wherein the modified humic acid carrier is prepared from the following raw materials: acylating chlorinated nano humic acid, sulfamic acid and acidified chitosan in a mass ratio of 1: (0.1-0.4): (0.1-0.3). The density of acidic functional groups is improved by modifying nano humic acid through sulfamic acid, a three-dimensional network structure is constructed by the nano humic acid and acidified chitosan, and meanwhile, carbonate, a microbial agent and hydroxyapatite are compounded, so that high efficiency and durability of an alkali adjusting effect are realized. Compared with a traditional inorganic acid modifier, the modifier can prevent local pH sudden change from burning crop root systems, the three-dimensional network structure can delay carbonate release, the alkali adjusting effect is continuous, and the problems that a traditional modifier acts transiently, and soil is prone to being damaged are effectively solved.

The present disclosure provides methods, pharmaceutical compositions, and kits for treating cancer in patients in need thereof. The methods comprise administering to a patient in need a small ubiquitin-like modifier (SUMO) activating enzyme (SAE) inhibitor, such as [(1R,2S,4R)-4-{[5-({4-[(1R)-7-chloro-1,2,3,4-tetrahydroisoquinolin-1-yl]-5-methyl-2-thienyl}carbonyl)pyrimidin-4-yl]amino}-2-hydroxy-cyclopentyl]methyl sulfamate (Compound I-263a) or a pharmaceutically acceptable salt, in combination with one or more anti-CD19 antibodies. Also provided are medicaments for use in treating cancer.

The application relates to the technical field of organic dyes, in particular to a double-active-group cationic modified anthraquinone reactive dye as well as a preparation method and application thereof. The preparation method of the double-active-group cationic modified anthraquinone reactive dye comprises the following steps: S1: dissolving 1-amino-4-sulfonic acid-1'-(N,N-dimethylpropylaminomethyl) anthraquinone in ice water, then adding melamine dropwise to carry out reaction, and obtaining an intermediate solution; S2: the intermediate solution is warmed to 20-25 DEG C, and hydroxyethyl sulfone sulfonate is added to carry out reaction; after the reaction is completed, salting-out is carried out, and the double-active-group cationic modified anthraquinone reactive dye is obtained, as shown in formula (1). The reactive dye is synergized through the cooperation of "double active groups + cationic adjustment + precise water-solubility design", can guarantee water-solubility and dyeing fastness, and can completely get rid of the dependence on a large amount of salt.

The application relates to the technical field of barrel-mixed auxiliary agents, and particularly discloses a preparation method of an anionic vesicular barrel-mixed auxiliary agent. The method comprises the following operation steps: S1: adding a 40wt% alkali solution into component A, heating and reacting, aging, removing water, cooling to 20-25 DEG C, adding ethanol and uniformly mixing to obtain component B; S2: under a nitrogen atmosphere, heating monoglyceride to 80-85 DEG C, adding sulfamic acid and a catalyst, uniformly mixing, heating to 120-125 DEG C and reacting for 3-3.5 hours, adding propylene glycol and uniformly mixing to obtain component C; and S3: uniformly mixing component A, component B, component C and component D, adjusting the pH by using sodium dihydrogen phosphate and disodium hydrogen phosphate to obtain the anionic vesicular barrel-mixed auxiliary agent.

The present application relates to the oil field chemical technology field, it is a kind of preparation method and application of amino sulfonic acid betaine type surfactant containing polyoxyethylene ether chain segment, the amino sulfonic acid betaine type surfactant containing polyoxyethylene ether chain segment raw material includes by mass fraction.The amino sulfonic acid betaine type surfactant containing polyoxyethylene ether chain segment of the present application is green environmental protection, biodegradable, preparation operation is simple, and flammable, explosive, volatile organic solvent is not used in process, safe and reliable;It is beneficial to industrial production and popularization and application, and has broad market prospect.The acidizing fracturing cleanup aid with it as raw material can effectively reduce the oil and gas field fracturing fluid surface, interfacial tension, while the amount of surfactant in cleanup aid is lower, and the use cost is saved.

The invention relates to the technical field of oilfield chemistry, in particular to a sulfamic acid type surfactant as well as a preparation method and application thereof.The sulfamic acid type surfactant is prepared according to the following steps: step one, after fatty amine and a first solvent are mixed, adding a 3-chloro-2-hydroxypropyl sodium sulfonate aqueous solution, and stirring to obtain a first mixture; reacting to obtain 3-(long-chain alkylamino)-2-hydroxypropane-1-sodium sulfonate; and 2, dissolving a required amount of 3-(long-chain alkylamino)-2-hydroxypropane-1-sodium sulfonate in a second solvent, adding a required amount of methyl acrylate, and reacting to obtain the sulfamic acid type surfactant. The sulfamic acid type surfactant disclosed by the invention contains long-chain alkyl, amino, ester group, hydroxyl and sulfonic acid group, so that the sulfamic acid type surfactant has good surface activity and meets the development requirements of oil and gas fields, and the microemulsion cleanup additive prepared by utilizing the sulfamic acid type surfactant has excellent water solubility and surface activity and meets the industrial use standards of non-fluorocarbon cleanup additives.

This invention discloses a method for directly preparing bis(fluorosulfonyl)imide from aminosulfonic acid, chlorosulfonic acid, and oxaloyl fluoride in a one-step reaction. This method has the advantages of simple operation, mild reaction conditions, fast reaction speed, and easy product purification.

The utility model relates to the field of electrochemistry, in particular to a spiral-flow type cation exchange membrane electrolysis device, which is a spiral-flow type electrolysis device for realizing conversion electrolysis of different solution systems by utilizing the characteristic that a cation exchange membrane has selective permeation on cations. Comprising a cathode cylinder, a cation exchange membrane anode, an upper cover, a lower cover, a starting sheet, a cathode region rotational flow lower liquid inlet device, a cathode region rotational flow upper liquid outlet device, an upper starting sheet pressing ring, a lower supporting isolating ring, a sealing assembly and an anode positioning rod. The device is suitable for mutual migration and conversion of cations among a chlorination system, a sulfuric acid system, a nitric acid system, a sulfamic acid system, a phosphoric acid system, a thiourea system and a cyanide system, so that the problem that an original system cannot be normally electrolyzed is solved from the source, and the application range of an electrolysis process is expanded; the method is particularly suitable for efficient metal copper electrolysis when a copper chloride solution system is converted into a copper sulfate solution system.

The invention discloses an efficient recycling method for a ternary positive electrode material of a lithium ion battery based on a deep-eutectic solvent, and belongs to the technical field of recycling of waste lithium ion batteries. The method mainly comprises the following steps: mildly stripping a ternary positive plate obtained by disassembling in a first DES stripping solvent prepared from benzyl triphenyl phosphorus chloride and octanoic acid, washing, drying, crushing, screening and grinding to obtain ternary positive fine powder; and efficiently leaching the ternary positive electrode fine powder by using a second DES leaching solvent prepared from acetamide and sulfamic acid. According to the method, a novel eutectic solvent is adopted to achieve lossless stripping of the waste ternary positive electrode material and the current collector, another novel eutectic solvent is used to achieve efficient leaching of valuable metal in the ternary positive electrode material, and the purposes that the whole process is environmentally friendly, low in consumption, high in metal recovery rate and excellent in performance of a re-prepared battery are achieved.

Provided is an etchant composition including, about 3.0 wt % to about 15.0 wt % of ammonium persulfate, about 0.1 wt % to about 5.0 wt % of an inorganic acid, about 0.1 wt % to about 2.0 wt % of a fluorine-containing ammonium salt, about 0.01 wt % to about 1.5 wt % of a chlorine-containing ammonium salt, about 0.1 wt % to about 2.0 wt % of a 2-nitrogen cyclic compound, about 0.1 wt % to about 2.0 wt % of a 4-nitrogen cyclic compound, about 0.1 wt % to about 3.0 wt % of an aminosulfonic acid, and a remainder of water such that the total weight of the entire etchant composition becomes 100 wt %, wherein the weight ratio of the 4-nitrogen cyclic compound to the 2-nitrogen cyclic compound is in a range of about 1.6 to about 5.0.

Composition comprising a thiopyridinone compound and an aminosulfonic compound. The present invention relates to a composition, in particular a cosmetic composition, comprising at least one compound of formula (I), at least one aminosulfonic compound of formula (II), and strictly less than 0.2% by weight of an alkali salt of thiosulfuric acid and / or its solvates such as hydrates, or totally free of an alkali salt of thiosulfuric acid and / or its solvates such as hydrates. Figure for the abstract: none

The application belongs to the technical field of disinfection, and discloses a composite disinfectant and a preparation method thereof. The disinfectant is composed of potassium hydrogen persulfate, urea peroxide, sodium percarbonate, sodium hexametaphosphate, sodium citrate, ethylenediaminetetraacetic acid disodium, sulfamic acid, sodium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether, cocamidopropyl betaine, nano manganese dioxide, nano silicon dioxide, nano zinc oxide, sodium carboxymethyl cellulose, polyethylene glycol 6000, amaranth red, sodium chloride and a residual amount of anhydrous sodium sulfate, and is prepared through a feeding, mixing and granulating process. The application is suitable for disinfection in multiple scenes, has high safety and a simple preparation process, and is suitable for large-scale industrial production.

The application discloses a bacteriostatic and deodorizing zeolite cat litter and a preparation method thereof, and belongs to the technical field of zeolite cat litter preparation. The bacteriostatic and deodorizing zeolite cat litter is composed of the following components in parts by weight: 55-75 parts of modified zeolite, 3-6 parts of bacteriostatic gel, 2-5 parts of adhesive, and 1-3 parts of filler. The modified zeolite is prepared from sulfamic acid, N,N-dimethylformamide, lignocellulose and zeolite, and the bacteriostatic agent is prepared from four-arm polyethylene glycol, succinic anhydride, triethylamine, N-hydroxyl glutarimide, 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and polylysine. The zeolite cat litter prepared by the method has excellent water absorption, antibacterial property and deodorizing property.

This invention discloses a solid sodium aminosulfonate β-H elimination promoter, its preparation method, and its application, relating to the technical field of β-H elimination promoters. The technical solution is as follows: S1, diethylenetriamine is dissolved in an organic solvent; S2, chlorosulfonic acid organic solution is added dropwise to the diethylenetriamine organic solution at 0-10℃ to carry out the reaction; after the addition is complete, the temperature is raised to continue the reaction; S3, the white solid generated by the reaction is filtered and washed with chloroform and ethanol respectively. The washed white solid is poured into anhydrous methanol and dispersed evenly. The reaction temperature is lowered to 0℃, sodium hydroxide is added for neutralization, and the solvent is removed by vacuum distillation. The resulting pale yellow solid is washed with ethanol and finally dried under vacuum to obtain the solid sodium aminosulfonate β-H elimination promoter. The solid sodium aminosulfonate β-H elimination promoter prepared by this invention has advantages such as high metal salt content, strong alkalinity, and easy separation, making it a promising additive for industrial application.

The invention discloses a copper-nickel-gold multi-layer electroplating process in semiconductor packaging. The process mainly comprises the steps of substrate pretreatment (degreasing, micro-etching and activation), copper layer electroplating, low-stress nickel aminosulfonate barrier layer electroplating, nickel layer weak acid activation, thin gold layer electroplating and post-treatment. The core of the method is that the internal stress of the nickel layer and the thickness and compactness of the gold layer are accurately controlled, and interlayer activation treatment is optimized, so that high binding force, excellent weldability, excellent diffusion resistance and long-term reliability of the plating layer are realized, and meanwhile, the gold consumption and the production cost are remarkably reduced. The process is particularly suitable for semiconductor packaging components such as lead frames and packaging substrates.

A highly efficient and environmentally friendly liquid metal degreasing agent and its preparation method are disclosed, belonging to the field of metal surface treatment technology. This degreasing agent is composed of a pH adjuster (a mixture of aminosulfonic acid and citric acid), a composite surfactant (a mixture of nonionic and anionic surfactants), a phosphorus-free chelating agent, a composite corrosion inhibitor, a defoamer, a detergent builder, and deionized water in specific weight proportions. The preparation method involves sequentially dissolving and mixing each component. This invention achieves highly efficient synergistic degreasing and rust removal under weakly acidic conditions. At room temperature, it provides excellent cleaning and corrosion protection for various metal substrates such as steel, aluminum alloys, and galvanized sheets. It is free of strong acids, phosphates, and heavy metals, making it environmentally friendly, safe, low-foaming, and stable. It is particularly suitable for automated spray production lines, comprehensively solving the problem of simultaneously achieving effective cleaning, substrate protection, and environmental protection requirements in existing technologies.