The invention relates to an acidizing block remover suitable for a complex lithologic reservoir. The acidizing block remover suitable for the complex lithologic reservoir comprises the following components by weight: 0-12% of hydrochloric acid, 0-3% of ammonium bifluoride, 0-10% of sulfamic acid, 0-5% of fluoboric acid, 0-3% of boric acid, 0-4% of alcohol, 0-2% of triethanolamine, 3% of glacial acetic acid, 4.0-6.0% of corrosion inhibitor, 2.0-4.0% of mutual solvent, 0.5-1.0% of penetrating agent, 2.0% of clay stabilizer and 45-88.5% of water. The problems that the lithologic and physical property differences of oil fields are large, the oil fields are in staggered distribution, and the acidizing debugging construction effect of a common water injection well is not ideal are mainly solved. The acidizing block remover suitable for the complex lithologic reservoir can effectively corrode the strata minerals and obstruent, does not destroy a rock skeleton, can prevent secondary precipitation caused by sensitive mineral, improves the water absorbing capacity of the reservoir, and increases the daily increasing water injection rate of an average single-well measure.