The invention provides a flotation collecting agent, a flotation reagent and a flotation method for improving the separation efficiency of ilmenite and gangue of ilmenite.The flotation collecting agent comprises a collecting agent A, the collecting agent A has a formula shown in the specification. In the formula, R1 is C1-C15 alkyl, C4-C15 cycloalkyl, allyl, ethynyl, phenyl, benzyl or benzyloxy; and R2 is hydrogen, C1-C15 alkyl, C4-C15 naphthenic base, propenyl, ethynyl, phenyl or benzyl. The collecting agent A serves as the flotation collecting agent of the ilmenite, benefited from the special synergistic effect of the benzene ring and the phosphate group, the collecting agent A shows good flotation selectivity and recovery rate, and the recovery rate and grade of the ilmenite can be improved.