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Preparation method of hydro-treatment catalyst

The invention discloses a preparation method of a hydro-treatment catalyst. The preparation method comprises the following steps: preparing an alumina carrier, preparing an impregnation solution containing the VIII group metal and VIB group metal, wherein the impregnation solution comprises a proper amount of an organic auxiliary agent containing chelating ligand, then impregnating the alumina carrier into the impregnation solution under a proper ultrasonic treatment condition, and drying so as to obtain the hydro-treatment catalyst. The preparation method utilizes the ultrasonic cavitation effect to properly reduce the viscosity of the impregnation solution; at the same time the complexing capacity between the chelating ligand in the organic auxiliary agent and nickel / cobalt is improved by the catalytic function of the ultrasonic, the interaction force between the chelating ligand and nickel / cobalt is strengthened, thus the active metal component is promoted to highly disperse on the carrier surface, furthermore, the existing state of the active metal on the catalyst surface is improved at the same time, the sulfurization degree and sulfurization uniformity of the active metal are both improved, so the activity and stability of the catalyst are both improved. The catalyst is especially suitable for being used in the hydro-denitrogenation process and hydro-desulfurization process of heavy distillate oil.
Owner:CHINA PETROLEUM & CHEM CORP +1

Preparation method of star polycarboxylic acid high-performance water reducing agent

ActiveCN102887979AExtended Dionon Design-Structure-PropertyExpanding the theoretical connotation of the design-structure-performance of moleculesWater reducerPollution
The invention relates to a preparation method of a star polycarboxylic acid high-performance water reducing agent. Polybasic alcohol and (methyl) acrylic acid used as main raw materials for esterification are esterified and polymerized to prepare the star polycarboxylic acid high-performance water reducing agent material: the (methyl) acrylic acid and polybasic alcohol used as reactants are esterified under the action of a catalyst to firstly prepare a star polymerizable active terminal, and free-radical polymerization reaction is carried out with unsaturated polyethenoxy ether, molecular weight regulator and unsaturated carboxylic acid monomer under the action of an initiator to prepare the star polycarboxylic acid high-performance water reducing agent. The invention is easy to control, and has the advantages of high polymerization degree, low cost and no pollution; the esterification reaction is carried out form an active core, and the free-radical polymerization is carried out to generate the chain arm, thereby implementing the polycarboxylic acid high-performance water reducing agent in a star molecular structure; and under the condition of common doping amount and low doping amount, the star polycarboxylic acid high-performance water reducing agent has better cement paste flowability and holding capacity than the traditional linear and comb polycarboxylic acid water reducing agents, and has favorable cement adaptability and concrete application performance.
Owner:GUIZHOU DR SHI TECH

Synthesis method of polycarboxylic acid high-performance water reducing agent of star-like structure

ActiveCN102911322AExtended Dionon Design-Structure-PropertyExpanding the theoretical connotation of the design-structure-performance of moleculesSynthesis methodsPolyethylene glycol
The invention discloses a synthesis method of a polycarboxylic acid high-performance water reducing agent of a star-like structure, belonging to the field of a water reducing agent. According to the synthesis method, polybasic alcohol, (methyl) acrylic acid, a polyethylene glycol compound and the like are used as esterification raw materials, and the polycarboxylic acid high-performance water reducing agent of the star-like structure is prepared through a sequential esterification and polymerization method, i.e., the (methyl) acrylic acid and the polybasic alcohol are used as reactants, a star-like polymerizable active end is prepared through esterification reaction under the action of a catalyst, and then the polycarboxylic acid high-performance water reducing agent is prepared from the star-like polymerizable active end and esterification macromolecule, a molecular weight regulator and an unsaturated carboxylic acid monomer under the action of an initiator through free radical polymerization reaction. The synthesis method has the advantages of simplicity, easiness in control, high polymerization degree, low cost, no pollution, capability of realizing the polycarboxylic acid high-performance water reducing agent of the star-like structure connected with a plurality of polycarboxylic acid molecules, and more superior cement paste fluidity and holding capacity, good cement adaptability and concrete application performance compared with the conventional linear and comb-shaped polycarboxylic acid water reducing agent in the case of normal and low added amount.
Owner:GUIZHOU DR SHI TECH

Process for recycling waste mineral oil without hazardous material emission

The invention discloses a process for recycling waste mineral oil without hazardous material emission. The process includes steps of 1, carrying out heating pyrolysis; 2, carrying out condensation and liquefaction and simultaneously recycling combustible gas; 3, carrying out conditioning; 4, storing finished products; 5, clearing coke residues, and to be more specific, clearing solid residual substances-coke residues obtained after clearing pyrolysis is carried out in reaction kettles; 6, gasifying the coke residues, to be more specific, crushing the coke residues cleared at the step 5 to obtain granules, then feeding the granules into a coke residue gasification furnace, gasifying the granules by the aid of the gasification furnace to obtain combustible gas, leading the combustible gas into a gas furnace used at the step 1 and combusting the combustible gas in the combustible furnace. The process has the advantages that certain waste gas and waste residues which are generated during pyrolysis on the waste mineral oil can be used as fuel to be fed into heating furnaces for the reaction kettles in closed-loop procedures, and accordingly the process is basically free of emission of toxic waste gas and toxic waste residues; all combustible substances in the waste mineral oil can be comprehensively sufficiently utilized, accordingly, environments can be protected, energy can be saved, and the process is favorable for society and people.
Owner:洛阳德正废弃资源再利用有限公司

Food processor

The invention provides a food processor. The food processor comprises a machine base, a crushing barrel and an extruding barrel; a driving device is arranged in the machine base and comprises a first output shaft and a second output shaft; the crushing barrel can be detachably installed on the machine base and comprises a crushing barrel shell and a crushing device, wherein the crushing device is arranged in the crushing barrel shell and used for pushing and crushing food materials, the crushing barrel shell is arranged in an inclined mode, the gap between the crushing barrel shell and the crushing device gets smaller and smaller from top to bottom; the extruding barrel is connected to the crushing barrel and communicated with the crushing barrel and comprises an extruding barrel shell and an extruding device, wherein the extruding device is arranged in the extruding barrel shell and used for extruding the food materials and separating juice and residues of the food materials, a juice outlet and a residue outlet are formed in the extruding barrel, and an extruding rib is arranged on the side wall of the extruding barrel shell; the included angle between the first output shaft and the second output shaft is beta, and the included angle beta is larger than or equal to 75 degrees and smaller than or equal to 160 degrees. According to the scheme, crushing and extruding can be conducted on the food materials separately, and therefore the juice yield of the product can be increased, the structure of the product is simplified, and the product is easy to clean.
Owner:GUANGDONG MIDEA CONSUMER ELECTRICS MFG CO LTD +1

Metal hydride hydrogen storage tank

The invention discloses a metal hydride hydrogen storage tank, and belongs to the technical field of hydrogen storage. The metal hydride hydrogen storage tank is composed of a tank body, a hydrogen storage alloy, a supporting frame, a porous metal gas guide segregation board, a gas guide pipe, a sealing head, a filter and a valve. The supporting frame is used for supporting the porous metal gas guide segregation board, and the hydrogen storage alloy is divided into a plurality of layers through the supporting frame and the porous metal gas guide segregation board; meanwhile, the diameter of a center hole of the porous metal gas guide segregation board is the same as the outer diameter of the gas guide pipe, and it is guaranteed that hydrogen between the layers of the hydrogen storage alloy is smooth. The metal hydride hydrogen storage tank is simple in structure and easy to manufacture and machine; as the supporting frame and the porous metal gas guide segregation board are arranged, the hydrogen storage alloy can be effectively prevented from being gathered to the bottom of the hydrogen storage tank due to volume expansion / shrinkage in the repeated hydrogen sucking / releasing process, tank deformation and cracking, caused by gathering of the hydrogen storage alloy and too-large stress, of the hydrogen storage tank are avoided, the using safety of the hydrogen storage tank is improved, and the service life of the hydrogen storage tank is prolonged.
Owner:GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS BEIJNG

Ag/C (Silver/Carbon) hollow nano-sphere and preparation method thereof

The invention discloses an Ag/C (Silver/Carbon) hollow nano-sphere and a preparation method thereof, and belongs to the field of a catalysis technique. The preparation method comprises the following steps: taking an amorphous carbon ball as a carrier, uniformly mixing and stirring glucose and silver nitride, and reducing to obtain a uninuclear carbon-coated silver core-shell structure through a one step hydro thermal method; then, corroding the uninuclear carbon-coated silver core-shell structure through H2O2 (Hydrogen Peroxide), gradually changing a Ag core of which the size is about 100nm into nano-silver particles of which the sizes are smaller, diffusing the nano-silver particles to a carbon shell layer from inside to outside, and embedding the nano-silver particles into a carbon layer to leave a cavity; and obtaining the Ag/C hollow nano-sphere of the core-shell structure. The Ag/C hollow nano-sphere provided by the invention has the advantages of being capable of loading nano-scale catalyst granules in the amorphous hollow carbon ball, and preventing the aggregation and oxidation of the nano-catalyst; furthermore, a catalyst is simple in preparation process, high in activity and good in stability, thereby being extensively applied to the preparation of para-aminophenol by the catalytic hydrogenation of nitro-phenol.
Owner:EAST EIGHT ENERGY (SHANGHAI) CO LTD

Remanufacturing method for scrap titanium chips through ball milling-equal channel angularpressing

The invention provides a remanufacturing method for scrap titanium chips through ball milling-equal channel angular pressing. The remanufacturing method sequentially comprises the step of recovering and pretreating titanium chips, the step of performing ball milling treatment on the titanium chips, the step of loading the titanium chips into an equal channel angular pressing mold, the step of performing preprocessing at a room temperature through the equal channel angular pressing, the step of curing and processing at a high temperature, and the step of quenching. The ball milling-equal channel angular pressing composite technique provided by the invention is simple and practical to operate and high in controllability. Through remanufacturing, not only can nanometer block titanium materials (smaller than 200nanometers) with full densification be obtained, but also the metallurgical defect of the continuous distribution and gathering of large sliced oxides can be eliminated. In addition, the shapes of the titanium chips are refined and reformed, and anisotropy caused by deformation texture in hexagonal close packed titanium materials is restrained. The yield strength of the remanufactured nanometer titanium materials reaches to the level of 5-grade titanium, the distribution of nanometer particles of the oxides presents a dispersed uniform state, and through the isotropy of the properties of the materials, the remanufacturing of scrap titanium resources for value increase at low cost is realized.
Owner:SHANGHAI DIANJI UNIV
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