155results about How to "Reduce surface tension" patented technology

A boron-containing polyethylene glycol fatty acid ester surfactant belongs to the field of organic chemistry and functional materials. The boron-containing polyethylene glycol fatty acid ester surfactant is prepared as follows: polyethylene glycol (PEG), boric acid and fatty acid are used as raw materials, first esterification reaction of the PEG and the boric acid is performed, then esterification reaction of the PEG and the fatty acid is performed to obtain boron-containing poly ethylene glycol fatty acid ester; by changing the species of fatty acids and catalysts and molecular weight of the PEG, the esterification rate can be enhanced, the boron-containing poly ethylene glycol fatty acid ester product can be used as a surfactant, and the boron-containing poly ethylene glycol fatty acid ester can reduce water surface tension and has good emulsifying properties.

The invention discloses a triazine desulfurizer and a preparation method thereof, and belongs to the technical field of gas purification. The triazine desulfurizer is mainly prepared from the following raw materials in percentage by weight: 20 to 50 weight percent of triazine derivative, 10 to 15 weight percent of sterically hindered amine, 3 to 7 weight percent of stabilizer, 1 to 3 weight percent of synergist, 0.5 to 1.5 weight percent of penetrant, 0.5 to 1.5 weight percent of inhibitor, 1 to 2 weight percent of additive and the balance of water, the preparation method of the triazine derivative comprises the following steps: adding 2-(diphenylphosphino) ethylamine into a toluene solvent, adding a paraformaldehyde aqueous solution in batches under a stirring condition, and reacting for 2-8 hours to obtain the triazine derivative. According to the triazine desulfurizer and the preparation method thereof provided by the invention, the triazine derivative and the sterically hindered amine are taken as a host, and the stabilizer, the synergist, the penetrant, the inhibitor and the assistant are compounded, so that the scaling trend of the triazine desulfurizer in an oil and gas well can be slowed down, the dissolution rate of hydrogen sulfide and the mass transfer rate in a solution are increased, and the desulfurization reaction is promoted; the desulfurization effect and the desulfurization rate are improved, and meanwhile, a very good scale inhibition effect is also achieved.

The application relates to the field of contaminated gas treatment, and particularly discloses a high-absorption VOCs absorbent and a preparation method thereof. The high-absorption VOCs absorbent comprises the following components in parts by weight: a solubilizing composition 20-30%; a cosurfactant 10-15%; solvent oil 40-50%; and water in the remainder. The solubilizing composition comprises component A, wherein the component A comprises polyoxyethylene nonionic surfactant and paeonol, and the weight ratio of the polyoxyethylene nonionic surfactant to the paeonol is 1: (0.1-0.2). The high-absorption VOCs absorbent and the preparation method thereof comprise the following steps: S1, uniformly mixing the solubilizing composition and the cosurfactant, adding water, and dropwise adding solvent oil to obtain the high-absorption VOCs absorbent. The high-absorption VOCs absorbent can be used for industrial absorption of solvents in waste gas, has the advantages of high absorption rate and an absorption amount of 141.5-145.7 mg / g after 50 hours of ventilation, and the preparation method has the advantages of few steps, simplicity and high efficiency.

This invention relates to the field of surfactant technology and discloses a biodegradable amphoteric surfactant and its preparation process. The process involves reacting a diol compound and a diacyl chloride compound, followed by a reaction with 1,3-propanesulfonate lactone to obtain the biodegradable amphoteric surfactant. Both the main chain and side chains of this surfactant contain a large number of biodegradable ester groups, exhibiting a high biodegradability rate and making it environmentally friendly. The side chains of this surfactant contain a large number of amphoteric betaine ion groups, among which a large number of sulfonic acid anions have strong coordination and complexation effects with iron ions. After complexation, the concentration of iron ions in the solution is significantly reduced, making it suitable as a complexing agent for better application in the iron complexation desulfurization process. Complexing iron ions can prevent iron ion precipitation, thus maintaining the good oxidizing properties of iron ions and reducing hydrogen sulfide to sulfur.

The invention discloses efficient closed-pore high-stability slurry and a preparation method thereof, a lithium ion battery and electric equipment, and relates to the technical field of lithium batteries, the efficient closed-pore high-stability slurry comprises water, core-shell microspheres, a heat stabilizer, a wetting auxiliary agent and a dispersing auxiliary agent, the core-shell microspheres comprise first core-shell particles and second core-shell particles, the core of the first core-shell particle is a mixture of a heat conducting agent and a flame retardant, or a composition of any one or more of the heat conducting agents, and the shell of the first core-shell particle is a mixture of a thermosensitive accelerator and a thermosensitive main agent, or a composition of any one or more of the thermosensitive accelerators; the core of the second core-shell particle is a mixture of a heat conducting agent and a flame retardant, or a composition of any one or more of the flame retardants, and the shell of the second core-shell particle is a mixture of a thermosensitive accelerator and a thermosensitive main agent, or a composition of any one or more of the thermosensitive main agents. The material has the advantages of early quick and synchronous response to temperature change, excellent thermal stability and excellent flame retardancy.

This application discloses a method for preparing ultra-high purity citric acid monohydrate based on supercritical CO2, belonging to the field of citric acid preparation technology. The method includes the following steps: dissolving citric acid monohydrate in an organic solvent to prepare a citric acid solution; spraying the citric acid solution into a supercritical CO2 environment to crystallize the citric acid using the supercritical anti-solvent effect; performing dynamic washing with pure supercritical CO2; and obtaining ultra-high purity citric acid monohydrate crystals after depressurization and drying. The citric acid monohydrate product prepared by this method has high purity, high light transmittance, low total metal ion content, controllable crystal habit, and low organic solvent residue, meeting the stringent requirements of high-end applications such as electronic and pharmaceutical grades.

The invention relates to the technical field of oil and gas well reservoir transformation, and provides a permeability-enhancing surfactant for shale gas fracturing and a preparation method thereof, and the permeability-enhancing surfactant is synthesized from 3, 4-difluoromaleic anhydride, alkyl polyoxyethylene polyoxypropylene alcohol and sodium isethionate. According to the permeability-enhancing surfactant for shale gas fracturing, fluorine atoms in aliphatic fluoride enable the permeability-enhancing surfactant to have very good low surface tension and wettability, and meanwhile, epoxy groups are introduced into gemini surfactant molecules, so that the wetting effect can be improved, and the permeability-enhancing surfactant is environmentally friendly. Therefore, aiming at the characteristics of a shale reservoir, from the aspects of excellent surface performance, cost reduction, environmental friendliness and the like, the permeability-enhancing surfactant for shale gas fracturing, provided by the invention, has a relatively good practical application value.

The invention relates to the technical field of chemical material preparation, and particularly discloses a safe preparation method of a short fluorocarbon alkyl sulphobetaine surfactant, a product and application, and the safe preparation method comprises the following steps: (1) in a solvent system I, reacting epoxy chloropropane with secondary amine to obtain an intermediate 1; (2) in a solvent system II, reacting the intermediate 1 with sodium hydrosulfide or a hydrate thereof to obtain an intermediate 2; (3) reacting the intermediate 2 with short fluorocarbon alkyl iodide to obtain perfluoroalkyl thioether propyl tertiary amine; and (4) carrying out sulfonation treatment on perfluoroalkyl thioether propyl tertiary amine to obtain the short-fluorocarbon alkyl sulphobetaine surfactant. According to the invention, by designing a synthetic route without using a high-risk reagent, the safety and operability of the process are remarkably improved, and the sulphobetaine surfactant with excellent acid, alkali and salt chemical stability and excellent surface activity is successfully prepared; and a key material and a safe and reliable preparation process are provided for development of a new-generation efficient environment-friendly fire extinguishing agent.

The invention discloses a low-temperature-resistant negative electrode zinc paste and a low-temperature alkaline zinc-manganese battery containing the zinc paste. The negative electrode zinc paste comprises the following components in parts by weight: 60-65 parts of zinc powder, 1-2 parts of a composite conductive agent, 0.1-0.3 part of a composite corrosion inhibitor and 35-38 parts of a low-temperature electrolyte; the low-temperature electrolyte comprises a multi-element nonionic surfactant system, a multi-element nano anti-freezing agent system and a mixed solution A, the 3.9 ohm discharge capacity of the battery under the condition of-40 DEG C is larger than or equal to 60% compared with the capacity retention rate at normal temperature, the interface impedance amplification is smaller than or equal to 15%, the hydrogen evolution amount is reduced by 80% on year-on-year basis, the process is compatible with an existing production line, and the battery is suitable for polar scientific investigation and electronic equipment in plateau and cold regions.

The utility model relates to the technical field of porridge cooking pots, in particular to a novel anti-overflow porridge cooking pot which comprises a pot body, an inner pot arranged in an inner cavity of the pot body and a pot cover arranged at the top end of the pot body, a supporting block is fixedly connected to the pot body, and an installation block is fixedly installed on the pot cover. An anti-overflow assembly is arranged on the pot cover, the anti-overflow assembly is used for preventing porridge liquid in the porridge cooking pot from overflowing outwards when the porridge cooking pot is used, and the anti-overflow assembly comprises a mounting plate fixedly mounted on the pot cover. By arranging the anti-overflow assembly, when the congee cooking pot is used, after internal steam drives the steam switch to be turned on, the electric push rod pushes the container to move downwards, so that edible oil flows into the oil receiving opening in the oil column on the bubble poking plate, and the bubble poking plate is driven by the rotary electromagnet to rotate to enter congee in the inner pot; and the surface tension of water can be reduced through the edible oil, so that foam is easier to break and dissipate, and the possibility of overflowing is reduced.

This invention relates to the field of ceramic composite metal casting technology, and discloses a method and apparatus for producing ceramic composite iron-based wear-resistant castings. The production method involves treating ceramic particles with decontamination, coarsening, sensitization, activation, and chemical plating to obtain modified ceramic particles; mixing and stirring the modified ceramic particles and a coating material to obtain a ceramic preform; fully heating the ceramic preform; then removing it and placing it into a mold cavity to obtain a mold; heating the mold in a tank; pouring molten iron after heating; and cooling after casting to obtain the ceramic composite iron-based wear-resistant casting. This invention also discloses a production apparatus for ceramic composite iron-based wear-resistant castings. This invention, employing the above-mentioned method and apparatus for producing ceramic composite iron-based wear-resistant castings, promotes the composite of ceramic and molten metal from a casting process perspective, ensuring that the molten metal can penetrate the fine pores of the ceramic preform, resulting in a good interface bonding between the high-chromium cast iron and ceramic particles, without unbonded or microscopic gaps.

This invention discloses a Tibetan bath composition compound and its preparation method, relating to the field of daily chemical products technology. The Tibetan bath composition compound consists of a ternary complex of scutellaria baicalensis hydroxypropyl-β-cyclodextrin nanoshell powder, Bacillus subtilis, Tibetan medicine composition, starch, anhydrous citric acid, sodium bicarbonate, calcium citrate, crospovidone, and magnesium stearate. Bacillus subtilis is used to ferment the ternary complex of scutellaria baicalensis hydroxypropyl-β-cyclodextrin nanoshell powder to obtain a fermentation-modified porous carrier, which is then loaded with the Tibetan medicine composition to form a Tibetan medicine inclusion powder. This not only achieves efficient drug delivery through a triple mechanism of biomodification, metabolite synergy, and structural optimization, but also forms a quaternary system with Terminalia chebula. The effervescent effect also enhances the penetration of Tibetan medicine components, which is beneficial for better exerting the antibacterial and anti-inflammatory effects of active substances, and significantly improving fungal infections and eczema-related skin problems.

The application discloses a kind of nano-permeable resin coating for construction in high-humidity water environment of desulfurization chimney lining anticorrosion, chimney lining includes reducing agent layer, reinforcing agent layer, primer layer, topcoat layer in turn from inside to outside, nano-permeable resin primer and topcoat can be permeated into the concrete matrix to form the anticorrosion layer of "matrix-coating", "mixing element integration", so that it not only has excellent acid corrosion resistance, but also has high and low temperature alternation and airflow scouring performance, solve the problem that chimney lining anticorrosion layer fails due to stress corrosion, also has good construction performance, solve the difficult problem that chimney lining anticorrosion layer construction period is short.

This invention relates to the field of concrete admixtures, specifically to an anti-mud polycarboxylate superplasticizer, its preparation method, and its application. The anti-mud polycarboxylate superplasticizer provided by this invention comprises, by weight, the following raw materials: 100-180 parts of unsaturated polyether monomer, 5-10 parts of unsaturated carboxylic acid monomer, 2-5 parts of air-entraining monomer, 5-10 parts of anti-mud monomer, 10-20 parts of oxidant, 0.4-0.6 parts of reducing agent, 5-7 parts of chain transfer agent, and 150-300 parts of water; the air-entraining monomer and the anti-mud monomer have specific structures. The simultaneous introduction of specific anti-mud monomers and air-entraining monomers into the anti-mud polycarboxylate superplasticizer of this invention not only reduces clay adsorption but also provides better dispersibility and anti-mud effect at lower dosages, increasing the overall workability of concrete and improving concrete performance.

The invention provides a green, environment-friendly, efficient and mild detergent and a preparation method and application thereof, and belongs to the technical field of detergents. Comprising the following raw materials in parts by weight: 10 to 20 parts of a mild surfactant, 5 to 8 parts of an auxiliary surfactant composition, 1 to 2 parts of a plant extract, 0.5 to 1 part of vitamin C, 0.1 to 0.3 part of vitamin E, 0.2 to 0.5 part of vitamin B5, 0.005 to 0.007 part of essence, 0.1 to 0.3 part of EDTA (Ethylene Diamine Tetraacetic Acid) disodium and 60 to 80 parts of deionized water. The prepared green, environment-friendly, efficient and mild detergent is good in foaming effect, stable in chemical property, mild, low in toxicity, good in washing effect and good in degradability, due to addition of the auxiliaries, the sense of the detergent is smoother, the fragrance of the detergent is more loved, and the detergent has wide application prospects.

The application discloses a kind of building waste self-reinforced recycled aggregate preparation methods, comprising the following steps: (1), the building waste containing red brick and hardened cement paste is crushed, and red brick material and the block of hardened cement paste containing are separated out;(2), red brick material is mixed with the solution containing carboxyl ether and is ground, and the modified slurry containing nanoscale red brick particle material is obtained;(3), the block of hardened cement paste containing separated out is immersed in modified slurry, after immersion is completed, the block of hardened cement paste containing is taken out and is dried, and building waste self-reinforced recycled aggregate is obtained;In the solution containing carboxyl ether, solvent is water, and the concentration of carboxyl ether is 0.1-0.8mol / L;The particle size range of nanoscale red brick particle material is 50-200nm;During the process of immersion, the mixture is heated and stirred, and the heating temperature is 40-80 DEG C.The method can prepare building waste self-reinforced recycled aggregate with high strength and low water absorption.

The invention relates to the technical field of coatings, in particular to dual-curing conformal coating as well as a preparation method and application thereof. The dual-curing three-proofing paint is composed of siloxane containing oxazolidinyl groups, a UV oligomer containing isocyanate groups, a diluting monomer, a water removal agent, a photoinitiator, a wetting agent, a catalyst and the like. Wherein the siloxane containing the oxazolidinyl group has two functional groups of long carbon chain oxazolidine and siloxane, the long carbon chain oxazolidine can realize rapid moisture curing of oligomer and does not generate volatile harmful substances, and meanwhile, hydrolysis residues of the long carbon chain oxazolidine can plasticize the conformal coating and reduce adhesion loss caused by shrinkage. On the other hand, siloxane groups can form a stronger physical or chemical action with a base material, so that the adhesive force to the base material is improved. In conclusion, the three-proofing paint has excellent low surface tension and high wettability, can effectively wet the polluted surface of the PCB and form interaction, has the characteristics of excellent adhesive force, salt mist resistance, high flexibility and the like, and has very high market application value.

The invention discloses an antibacterial fabric for underwear and a preparation method of the antibacterial fabric, and relates to the technical field of textile fabrics. According to the invention, 2-(chloromethyl) 1, 3-butadiene and dodecyl dimethyl tertiary amine are used as reaction raw materials to prepare quaternary ammonium salt, and then the quaternary ammonium salt and vinyl-terminated silicone oil are subjected to a polymerization reaction to generate an organosilicon quaternary ammonium salt antibacterial agent, so that bacterial adhesion can be effectively prevented, and the antibacterial performance of the fabric is enhanced; ethylene glycol and 2, 5-dimercapto terephthalic acid are condensed to obtain sulfydryl-containing polyester fibers, ethylene glycol disodium salt is added to obtain modified polyester fibers, the antibacterial performance of the fabric is improved, meanwhile, the moisture absorption performance of the fabric is improved, and the fabric is easy to dye; soaking the modified polyester fiber into the organosilicon quaternary ammonium salt antibacterial agent mixed solution, performing water treatment, drying, and weaving to obtain the antibacterial fabric for underwear. The prepared antibacterial fabric for underwear has excellent antibacterial, moisture-absorbing and easy-to-dye effects.

The application discloses a kind of strong penetration cooking-resistant type water-based textile paper tube two-component epoxy dip coating and preparation method thereof, belong to water-based paint technical field.The coating is composed of A component and B component, A component uses the composite wetting penetrant that self-emulsifying submicron water-based epoxy dispersion and sulfobutane acid dioctyl sodium salt, acetylene glycol surfactant are composed of;B component selects fast-drying water-soluble modified polyamine curing agent, adds reactive curing accelerator.By the synergy of small particle size epoxy dispersion and composite wetting penetrant, the technical problem that traditional water-based paint is poor in paper tube fiber permeability, weak adhesion is solved;At the same time, through the synergistic effect of fast-drying curing agent and accelerator, the drying time is shortened.The coating has the characteristics of low VOC content, environmental protection safety, strong penetration to paper tube substrate, fast drying speed, excellent adhesion, and the dense paint film formed after curing has the performance of saturated water vapor cooking resistance.

This invention discloses an oil sludge extraction system, comprising a separation tower, multiple partition units, and an inlet pipe. The separation tower includes a feed section and an extraction section from top to bottom. The feed section has an inlet and an outlet. The inlet is for the oil sludge and extraction solvent to enter. The extraction section is used to extract light tar from the oil sludge and has a light oil outlet for discharging the light tar. The multiple partition units are spaced apart from top to bottom within the extraction section. Each partition unit includes multiple partition tubes spaced apart along a first direction and extending along a second direction. The inlet pipe is located on the separation tower and extends one end into the extraction section. The pipe wall of the inlet pipe has multiple spaced-apart vents for introducing heating gas into the extraction section. The oil sludge extraction system of this invention has the advantages of high oil yield.

The invention discloses a modified organic silicon defoaming agent as well as a preparation method and application thereof, and belongs to the field of papermaking defoaming agents. The preparation method comprises the following steps: firstly, carrying out addition reaction on hydrogen-containing silicone oil, alkyne and enol to obtain an alkyne modified organic silicon defoaming agent intermediate; performing high-temperature phase inversion emulsification on the alkyne modified organic silicon defoaming agent, docosanol, octadecanol and an emulsifier to obtain the alkyne modified organic silicon defoaming agent. The modified organic silicon defoaming agent obtained by the preparation method disclosed by the invention is applied to a papermaking section, not only can quickly eliminate foams on the surface of a system, but also can remove small bubbles attached to the surfaces of fine fibers in pulp, so that the gas content of a paper machine system is reduced, the operation efficiency of a paper machine is improved, and the modified organic silicon defoaming agent has the characteristics of no toxicity, no harm, simple process and the like.

The application discloses a creep-resistant die-casting rare earth magnesium alloy with high strength and high fluidity, and a preparation method and application thereof. The application belongs to the field of die-casting magnesium alloys. The magnesium alloy comprises, in percentage by mass, Al: 4.8-7.2%, La: 3.0-4.2%, Sm: 1.2-2.0%, Y: 0.4-1.2%, Mn: 0.1-0.6%, Te: 0.01-0.1%, Bi: 0.01-0.5%, and the balance of Mg and inevitable impurity elements. The application significantly refines the structure of the magnesium alloy by optimizing the alloy composition, changes the composition, distribution and morphology of intermetallic compounds in the alloy, simultaneously generates Al-Te phases stable at high temperatures, improves the mechanical properties and creep resistance of the magnesium alloy, and further improves the die-casting fluidity of the magnesium alloy, so as to meet the requirements of large-scale integrated design automobile parts.

This invention provides a carboxylated nitrile butadiene latex, its preparation method, and its application. The carboxylated nitrile butadiene latex, by mass parts, is composed of the following raw materials: butadiene, acrylonitrile, methacrylic acid, emulsifier, dispersant, electrolyte, ferrous sulfate, reducing agent, molecular weight regulator, oxygen scavenger, initiator, and demineralized water. The emulsifier is a mixture of anionic and cationic emulsifiers; the anionic emulsifier is sodium dodecyl sulfate, and the cationic emulsifier is a glycosyl gemini cationic surfactant. The mass ratio of the anionic emulsifier to the cationic emulsifier is 1:0.05–0.1. This carboxylated nitrile butadiene latex not only has low gel content and high mechanical stability, but its preparation method is also simple and controllable, making it easy for industrial production.

The invention relates to a water-based zero-VOC (volatile organic compound) coating as well as a preparation method and application thereof. The water-based zero-VOC coating is prepared from a component A and a component B, wherein the mass ratio of the component A to the component B is (11: 1)-(12: 1); wherein the component A is prepared from the following components in parts by mass: 27 to 35 parts of low-hydroxyl acrylate dispersoid, 27 to 35 parts of polyurethane dispersoid, 1 to 2 parts of wetting dispersant, 0.1 to 0.3 part of defoaming agent, 17 to 27 parts of pigment filler, 0.05 to 0.2 part of color paste and 1 to 4 parts of delustering agent; the water-based ink comprises the following components in parts by weight: 30-50 parts of water-based ink, 0.3-1 part of a substrate wetting agent, 0.3-1 part of an ultraviolet light absorber, 0.3-1 part of a light stabilizer, 0.1-0.4 part of a thickening agent and 3-12 parts of deionized water. And the component B is a hexamethylene diisocyanate curing agent. No solvent is added into the coating, the VOC content is zero, and harmful substances such as heavy metal, benzene and formaldehyde are not contained.

The invention relates to the technical field of manufacturing of metal composite materials, and discloses a corrosion-resistant and wear-resistant bimetal composite cylinder liner which is prepared through the following steps that the inner wall of an outer-layer matrix steel pipe is pretreated and coated with an interface activation flux; raw materials containing waste steel, ferrochrome and the like are molten, ferrotitanium and ferroboron are sequentially added for alloying, then ferric oxide powder and metal yttrium are added for modification treatment, and inner-layer alloy liquid is obtained; the preheated outer-layer matrix steel pipe is placed in a rotating state, and the inner-layer alloy liquid is poured; and after the to-be-solidified pipe fitting is cooled to the room temperature, the pipe fitting is heated to the austenitizing temperature, heat preservation is conducted, and then isothermal quenching treatment is conducted. According to the method, interface oxides are effectively removed and firm metallurgical bonding is promoted by utilizing the interface activation flux; a core is formed through in-situ reaction of metal yttrium and ferric oxide so as to refine grains; and a lower bainite and retained austenite mixed structure is obtained through isothermal quenching, the comprehensive mechanical property of the cylinder sleeve is improved, and the service life of the cylinder sleeve is prolonged.

The invention belongs to the technical field of soil curing agents, and particularly relates to an anti-freeze-thaw sludge curing agent and a preparation method and application thereof. The sludge curing agent comprises the following raw materials in parts by mass: 40-60 parts of cement, 10-20 parts of an admixture, 10-20 parts of quicklime, 5-10 parts of gypsum, 5-8 parts of carboxylated porous resin, 0.5-0.8 part of a nonionic surfactant and 5-8 parts of activated carbon, and the carboxylated porous resin is of a three-dimensional network structure formed by condensation reaction of phenolated alkali lignin and dialdehyde. Meanwhile, porous resin microspheres are formed by utilizing a pore-foaming agent, and then the porous resin microspheres, chloroacetic acid and alkali are subjected to a reaction to prepare carboxylated porous resin microspheres. According to the non-ionic surface active agent disclosed by the invention, organic matters which are easy to migrate and free in the sludge are emulsified into micro-micelles, and the micro-micelles are adsorbed by the activated carbon, so that the micro-micelles are prevented from wrapping gel particles, hydration is hindered, a communicated pore network is prevented from being formed, and the freeze-thaw resistance of a sludge solidified body is improved. The inner surfaces of pores of carboxylated porous resin contain a large amount of phenolic hydroxyl groups and carboxyl groups, so that the migration activity of heavy metal ions is reduced.

The application discloses a recycling method of by-product cyclohexene distillation still residue, and belongs to the technical field of recycling of by-product cyclohexene distillation still residue. The still residue is analyzed by liquid chromatography-mass spectrometry, and the chlorocyclohexane in the still residue is reacted with sodium disulfide under the condition of a catalyst. After static separation, the oil phase is refined to obtain dicyclohexyl disulfide and cyclohexene, and the water phase can be recycled. The catalyst is composed of sulfonated castor oil and a phase transfer catalyst, can improve the conversion rate of chlorocyclohexane and the selectivity of dicyclohexyl disulfide, and greatly shortens the reaction time. The application can realize recycling and utilization of the still residue, avoids waste of resources and pollution to the environment, saves the chemical production cost, and meets the environmental protection concept of green chemical industry.

The application discloses a pesticide synergist and a preparation method thereof. The pesticide synergist comprises a silanol-initiated polyether shown in formula I, an inositol phosphate-initiated polyether shown in formula II, an alcohol auxiliary agent and water. The silanol-initiated polyether shown in formula I and the inositol phosphate-initiated polyether shown in formula II are synergized, so that the adhesion, spreading, penetration and retention capacity of pesticide droplets on a target surface are significantly enhanced, and the utilization rate of the pesticide is effectively improved. The product has the advantages of low toxicity, environmental friendliness, multi-functional synergism, wide compatibility and the like, the preparation process is simple and stable, and the product is suitable for industrial production.

This invention relates to the field of natural product separation and recombination, and particularly to a recombinant saponin from *Gleditsia sinensis* and its preparation method. The method includes: 1) crude saponin extraction: water extraction of *Gleditsia sinensis* pericarp to obtain a crude saponin solution; 2) impurity removal: loading the crude saponin aqueous solution into macroporous adsorption resin AB-8 and eluting to remove impurities; 3) saponin component separation: eluting sequentially with 25-35% ethanol solution, 40-50% ethanol solution, 55-65% ethanol solution, and 70-80% ethanol solution to obtain S30, S45, S60, and S75 saponin components, respectively; 4) saponin hydrolysis: hydrolyzing the S45 saponin component to obtain hydrolyzed saponin; 5) saponin component recombination: recombining the saponin components obtained in steps 3) and 4) with the hydrolyzed saponin to obtain recombinant saponin from *Gleditsia sinensis*. This invention enables saponin purification and improves the surface activity of *Gleditsia sinensis*.

The application discloses an inorganic copolymer anticorrosive paint and a preparation method thereof, and relates to the technical field of paints. The inorganic copolymer anticorrosive paint comprises the following raw materials in parts by weight: 20-30 parts of silica sol, 8-15 parts of sodium hydroxide, 30-45 parts of metakaolin, 8-20 parts of quartz sand, 15-25 parts of water, 0.3-2 parts of sodium polyacrylate, 0.2-3 parts of polydimethylsiloxane emulsion, 5-12 parts of modified nanometer titanium dioxide, 6-10 parts of modified epoxy resin, 10-25 parts of hydroxyethyl methacrylate, 5-10 parts of zinc phosphate, 3-8 parts of aluminum tripolyphosphate and 2-6 parts of red iron oxide. The inorganic copolymer anticorrosive paint has scientific raw material proportioning, and the anticorrosive performance is enhanced through the modified nanometer titanium dioxide and the epoxy resin. In the preparation, step-by-step feeding and ultrasonic dispersion are adopted to ensure that the materials are uniform, and vacuum degassing and nitrogen protection are adopted to improve the stability. The silica sol, the zinc phosphate and other components have a synergistic effect, a dense coating is formed, the anticorrosive performance is high, the construction performance is good, and the inorganic copolymer anticorrosive paint is suitable for various scenes.