This invention discloses a weather-resistant, high-
hardness composite anti-
corrosion coating and its preparation method, belonging to the field of anti-
corrosion coating technology. The preparation method includes: firstly, synthesizing an
epoxy resin containing dynamic disulfide bonds by reacting dithiodibenzoic acid and
epichlorohydrin in an alkaline aqueous phase; secondly, constructing a low
surface energy siloxane network using hydroxyl-terminated
polydimethylsiloxane and methyltriethoxysilane; subsequently, introducing chlorzoxazone and N-acetyl-p-aminophenol as composite organic
corrosion inhibitors, blending them with the resin to obtain a composite base material; finally, adding
graphene, carbon nanotubes, and inorganic anti-corrosion fillers, and cross-linking and curing to form a film using a
polyamine curing agent. This invention suppresses microcracks through the
dynamic stress relief of disulfide bonds, combined with the weather-resistant barrier of the
siloxane network, the active interface
passivation of the
heteroatom corrosion inhibitor, and the three-dimensional synergistic mechanical bonding of carbon-based
nanomaterials, achieving a perfect unity of ultra-strong corrosion resistance, excellent
weather resistance, and high mechanical
hardness in the
coating.