10982 results about "Electrode material" patented technology

The invention discloses a refined disassembly system and method for a battery monomer, and belongs to the technical field of battery disassembly. The production line comprises a perforating device, a cutting device, a cutting device, a scattering device, a sorting device, a color sorting device, a defluorination device and a powder removal device. The method comprises the following steps: perforating a battery to discharge electrolyte, separating a shell from an inner core by a cutting device, cutting the inner core by a cutting device, scattering by a scattering device, sorting a diaphragm by a sorting device, sorting positive and negative electrode materials by a color sorting device, and respectively removing fluorine by a defluorination device. And finally, the metal foil and the powder are separated through the powder removing device, the damage degree of the crystal structure of the black powder can be reduced, the black powder and the metal fragments are efficiently separated according to the density difference, the metal foil and the black powder are not likely to be excessively mixed, the separation purity is high, the secondary treatment situation is reduced, efficient separation and recycling of the electrode material are achieved, and the production cost is reduced. And the comprehensive function and the resource utilization rate of the system are obviously improved.

The invention provides a biomass-derived spherical porous carbon material and a preparation method thereof, and a silicon-carbon negative electrode material and a preparation method thereof, and relates to the field of lithium ion batteries. The preparation method of the biomass-derived spherical porous carbon material comprises the following steps: carrying out pre-carbonization treatment on vinasse to obtain pre-carbonized vinasse, mixing the pre-carbonized vinasse with an acidic solution, and washing with water until the mixture is neutral to obtain pre-treated vinasse; mixing the pretreated vinasse with a pore-forming agent, a binder and water to prepare slurry, and performing spray drying on the slurry to obtain a spheroidized precursor; carrying out carbonization treatment on the spheroidized precursor; washing the carbonized spheroidized precursor with water until the spheroidized precursor is neutral, and drying the spheroidized precursor to obtain an intermediate; and activating the intermediate with water vapor to obtain the biomass-derived spherical porous carbon material. The material with a regular spherical and porous structure can be prepared, the material can be used for preparing a silicon-carbon negative electrode material with a stable structure, and the electrochemical performance of the silicon-carbon negative electrode material is improved.

A positive electrode material of the present disclosure includes: a positive electrode active material; and a first solid electrolyte material coating at least partially a surface of the positive electrode active material, wherein the first solid electrolyte material includes Li, Ti, M1, and F, and the M1 is at least one element selected from the group consisting of Ca, Mg, Al, Y, and Zr.

The invention relates to the field of batteries, in particular to a preparation method and system of a silicon-carbon material, and the preparation method comprises the following steps: pretreating porous carbon, conveying the pretreated porous carbon to a fluidized bed reactor, sequentially introducing a silicon source gas and a carrier gas for silicon deposition treatment, heating, introducing a carbon source gas, adjusting the flow of the carrier gas for carbon coating treatment, and discharging and cooling to obtain a finished product, meanwhile, reaction tail gas is recycled. The preparation system comprises a gas inlet unit, a fluidized bed reactor unit, a tail gas circulation unit, a feeding preheating unit and a discharging unit. The fluidized bed reactor comprises an outer shell, an up-down stirring device, a heat exchange assembly and an air distribution assembly, and efficient reaction and temperature control can be achieved. The silicon-carbon material prepared by the method has excellent electrochemical performance and is suitable for a lithium ion battery negative electrode material. The unique porous structure and the uniform carbon coating layer effectively improve the conductivity and the structural stability of the material, and meanwhile, the volume expansion effect of silicon in the charging and discharging process is reduced.

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a self-repairing type lithium ion battery positive electrode adhesive, a preparation method, positive electrode slurry and a positive electrode plate. The adhesive comprises a mixed solvent, and a first copolymer serving as a main component and a second copolymer serving as a cross-linking agent are dissolved in the mixed solvent; the first copolymer is an acrylate-based multipolymer containing carboxyl or hydroxyl; the second copolymer is isocyanate terminated UPy functional polyurethane; the adhesive is in a liquid state at room temperature, when the adhesive is subjected to vacuum heat treatment at 60-180 DEG C, carboxyl or hydroxyl in main components of the adhesive reacts with isocyanate groups of a cross-linking agent to form amido bonds along with volatilization of a mixed solvent, and UPy groups are associated through quadruple hydrogen bonds to form dual dynamic cross-linking points. The method can effectively adapt to the volume change of the positive electrode material in the lithium removal / insertion process, and maintains the integrity of the electrode structure, thereby improving the cycling stability and rate capability of the lithium ion battery.

The invention provides an intrinsic solid-state ion diffusion coefficient test method and device based on optical imaging, and relates to the technical field of solid-state ion test.The method comprises the steps that a test sample is pretreated; carrying out a photoelectric test on the test sample; placing the electrochemical cell in an optical imaging system, connecting the electrochemical cell with an electrical testing system, applying a constant voltage deviating from a steady state to the monodisperse electrode plate, collecting the real-time change condition of the material under the modulation of the constant voltage in real time through an industrial camera, and outputting relational data of optical intensity and time; analyzing the diffusion path through in-situ characterization equipment, and obtaining an ion diffusion path corresponding to the to-be-detected ion battery electrode material particles in combination with dynamic information provided by an optical imaging system; and determining the characteristic time according to the relational data of the optical intensity and the time, and determining the intrinsic solid ion diffusion coefficient corresponding to the test sample by combining the characteristic time and the ion diffusion path corresponding to the to-be-tested ion battery electrode material particles.

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

The application relates to the technical field of material preparation, and discloses multi-element carbon-coated lithium manganate, a preparation method thereof and a secondary battery. The multi-element carbon-coated lithium manganate comprises a lithium manganate core and a carbon nanotube layer and a hard carbon layer which are sequentially coated on the lithium manganate core. The chemical formula of the lithium manganate core is LiAl a X b Mn 2‑a‑b O4, wherein 0.01<=a<=0.10, 0.01<=b<=0.05, and X comprises at least one of Co, Cr, Ti, V and B. The preparation method of the multi-element carbon-coated lithium manganate comprises the following steps: (I) preparing doped lithium manganate, (II) preparing carbon nanotubes and (III) multi-element carbon coating. The multi-element carbon-coated lithium manganate has high conductivity, rate performance, cycle performance and safety performance, and can be used as an alternative positive electrode material with high cycle and excellent fast-charging performance.

The invention relates to the technical field of lithium ion batteries, in particular to a composite layered oxide positive electrode material, a preparation method and a lithium ion battery. The composite layered oxide positive electrode material provided by the invention comprises a ternary material core, wherein the ternary material core is a high-nickel ternary oxide doped with Zr and Mg in a gradient manner; the coating layer shell comprises a first coating layer and a second coating layer, the outer side of the first coating layer is coated with the second coating layer, the first coating layer is a composite layer of fluorine-terminated MXene and sulfide solid electrolyte, and the second coating layer is a porous high-entropy oxide. The composite layered oxide positive electrode material provided by the invention has high specific capacity, excellent cycling stability, first coulombic efficiency and high rate performance, is compatible with existing industrial production, and remarkably improves the comprehensive performance and practical value of the lithium ion battery.

The invention provides a sphere-like silicon-carbon negative electrode material and a preparation method and application thereof, and particularly relates to the technical field of negative electrode materials, the negative electrode material comprises a sphere-like porous carbon skeleton, silicon nanoparticles distributed in the sphere-like porous carbon skeleton, and an amorphous carbon layer coating the surface of the sphere-like porous carbon skeleton, the particle appearance of the sphere-like porous carbon skeleton is of a round irregular or asymmetric polyhedral structure and comprises one or more of a potato shape, an ellipse shape, an olive shape, a long strip shape and a pomegranate shape, the particle of the sphere-like porous carbon skeleton is provided with a plurality of asymmetric faces, fillets are formed between the faces, and the radius of the fillets does not exceed 20 microns. The problem of structural damage of the material under the action of external force such as rolling can be effectively relieved, good mechanical stability is kept, excellent bonding performance can be achieved in the electrode coating process, the ion transmission path of the material is improved, and the electronic conductivity and the lithium ion diffusion performance are improved.

The invention discloses a preparation method and application of three-dimensional intercalation multidirectional conductive MXene-based aerogel, and relates to the technical field of advanced electrochemical energy storage materials and devices. According to the MXene / conductive polymer and nanofiber composite aerogel developed by the invention, the two-dimensional conductive material, the pseudocapacitance polymer and the high-performance nanofiber are integrated in a three-in-one manner, so that collaborative optimization of conductivity, the number of active sites and structural stability is realized, and inherent defects of a single-component material are fundamentally avoided; and a universal solution is provided for solving the industrial problem of unbalanced performance of the electrode material.

The invention relates to the technical field of retired ternary power battery recovery, and particularly discloses a method for preferentially extracting lithium and recovering valuable metals from a retired ternary lithium battery and application of the method. According to the method, the traditional process is broken through the preferential lithium extraction, and efficient recovery of lithium, Ni, Co and Mn is realized by utilizing'fast-medium-slow 'multi-stage cooperation of a composite reducing agent and accurate adaptation of roasting and leaching parameters, so that the method has the advantages of low cost, high efficiency, low energy consumption and the like, and is suitable for large-scale industrial production. The method is low in energy consumption and environment-friendly, and is applied to resource recycling of the retired ternary lithium battery, and the precursor can be used for reproducing a positive electrode material or used for a catalytic material.

The invention discloses a silicon-carbon negative electrode material, a preparation method thereof and a lithium ion battery, and relates to the technical field of lithium ion battery negative electrode materials. The material sequentially comprises a porous silicon core, a transition layer and a shell from inside to outside, the transition layer is a nitrogen-doped SiC / C composite layer, the shell comprises a graphene / carbon nanotube skeleton and MXene quantum dots, the MXene quantum dots are embedded in the graphene / carbon nanotube skeleton, boric acid ester bonds exist between carbon nanotubes and graphene, and the MXene quantum dots are embedded in the graphene / carbon nanotube skeleton. The silicon-carbon negative electrode material is based on dual-network dynamic bonding and stress gradient regulation and control, the cycle performance of the material can be remarkably improved, and the service life of the material can be remarkably prolonged.

The invention provides a preparation method of a cobalt-based bimetallic alloy positive electrode lithium supplement composite material and an application technology of the cobalt-based bimetallic alloy positive electrode lithium supplement composite material in a battery. The lithium-supplementing composite material is a lithium salt, a cobalt-based bimetallic alloy catalyst for promoting low-pressure decomposition of the lithium salt, and a positive electrode material. The lithium salt is lithium oxalate, the cobalt-based bimetallic alloy catalyst is prepared from nitrogen and sulfur co-doped carbon impregnated in a transition metal salt solution through freeze drying and high-temperature calcination, and the positive electrode material comprises one of lithium iron phosphate, lithium cobalt oxide and ternary high nickel (LiMO2, M = Ni, Co and Mn). When the lithium supplement agent is applied to a secondary lithium ion battery, the decomposition voltage of the lithium supplement agent can be reduced, the irreversible loss of capacity is reduced, and the initial coulombic efficiency is improved.

The invention provides a lithium iron phosphate-based positive electrode material and a preparation method thereof, a positive plate and a battery, the lithium iron phosphate-based positive electrode material comprises a lithium iron phosphate matrix and a carbon material existing on the surface of the lithium iron phosphate matrix, and the lithium iron phosphate-based positive electrode material comprises mesopores and macropores. The conductivity and the ion transmission performance of the lithium iron phosphate-based positive electrode material can be both improved, and the energy density and the rate capability of the battery are improved.

The invention relates to the technical field of electrode preparation, and discloses a dry-method electrode preparation process control method and system and a storage medium. The method comprises the steps that in the rolling forming process of a dry-method electrode material, pressure roller gap data and rotation angle data of a driving motor are monitored and collected in real time, and a support vector machine algorithm is used for recognizing the transmission ratio change trend of a pressure roller system; calculating a pitch precision offset caused by wear through Kalman filtering in combination with historical wear data; when the offset exceeds the limit, an adjustment coefficient is generated based on a simulation model, and the control precision is improved through feed-forward compensation and feedback optimization; when the adjustment precision meets the process requirement, a self-adaptive parameter set is determined through dynamic deviation residual analysis, and an actuator is driven to adjust the gap between the compression rollers; and monitoring the thickness uniformity index of the electrode plate produced after adjustment in real time, and finally forming quality closed-loop control by taking the thickness uniformity of the electrode plate as a verification standard. According to the invention, the quality precision of dry-method electrode production is improved.

The invention discloses an intelligent sorting method and device for a positive electrode material of a retired lithium ion battery based on a spectrum method, and the device is connected in series with a pretreatment module, a cleaning module, an identification module and a sorting module through a conveying belt in a supporting module to form an automatic sorting assembly line. Pre-treating the retired battery to obtain a clean positive plate; an X-ray fluorescence spectrophotometer in the recognition module collects the spectrum of the positive plate and transmits the spectrum to an industrial personal computer, and the spectrum is preprocessed and then input into a classifier library; the classifier library comprises a main classifier and an increment classifier based on element and spectral shape dual channels, if the output confidence reaches a preset threshold value, the material category is judged, otherwise, the spectrum is temporarily stored as an unknown spectrum; after unknown spectrums are accumulated to a set number, new categories are identified through a clustering algorithm, and a lightweight dichotomy increment classifier is trained and added into a classifier library; and the sorting module drives the hydraulic pushing hand to sort the positive plates according to the identification result. Through cooperative evolution of the main classifier and the increment classifier, the sorting precision is effectively improved.

The invention relates to the technical field of lithium ion batteries, in particular to a composite lithium-rich manganese-based positive electrode material and a preparation method and application thereof. The composite lithium-rich manganese-based positive electrode material is of a three-layer structure and sequentially comprises a lithium-rich manganese-based oxide positive electrode material matrix, a first coating layer and a second coating layer from inside to outside, the first coating layer is a mixture of halide solid electrolyte and lithium-containing oxide; and the second coating layer is an oxide solid electrolyte. The conductivity of a contact interface with a positive electrode material can be improved, the resistance is reduced, the moisture absorption degradation of halide is inhibited, the packaging difficulty is reduced, and the cycle performance of the halide-added solid electrolyte after moisture absorption is improved.

The invention belongs to the technical field of lithium batteries, and particularly relates to a lithium-rich manganese-based positive electrode material and a preparation method and application thereof. The preparation method comprises the following steps: mixing a metal salt solution, a precipitator and a complexing agent, and carrying out coprecipitation reaction on an obtained coprecipitation reaction precursor solution to obtain a lithium-rich manganese-based precursor; the metal salt solution comprises a manganese element, a cobalt element and a nickel element; and mixing the lithium-rich manganese-based precursor, a lithium source, an auxiliary agent and a dispersing agent, and calcining to obtain the lithium-rich manganese-based positive electrode material, the auxiliary agent comprises a nitrogen source or a nitrogen source and a carbon source. The first discharge specific capacity, the rate capability and the cycling stability of the lithium-rich manganese-based positive electrode material can be improved, and the problems of capacity fading, discharge voltage drop and dynamic delay in an electrochemical reaction process are solved.

The invention discloses a Prussian blue type composite positive electrode material and a preparation method and application thereof, and the Prussian blue type composite positive electrode material provided by the invention is composite powder containing a Prussian blue type positive electrode material, a conductive agent, a binder and a functional additive, the mass ratio of the Prussian blue positive electrode material to the conductive agent to the binder to the functional additive is (90-99): (1-5): (0-5): (0-0.5). According to the Prussian blue composite positive electrode material provided by the invention, the components are uniformly distributed, the Prussian blue composite positive electrode material has the characteristics of high compaction, easy dispersion, relapse resistance, high conductivity and the like, and the Prussian blue composite positive electrode material can be directly used for wet homogenization and can also be directly used for dry electrode manufacturing.

The application discloses a high-energy-density lithium ion battery, which comprises a positive electrode sheet and a negative electrode sheet, the positive electrode sheet comprises a positive electrode active material, the positive electrode active material comprises a lithium iron phosphate material and a lithium-rich material, the mass ratio of the lithium-rich material in the positive electrode active material is 0.2%-8%, and the chemical formula of the lithium iron phosphate material is Li 1+x Fe 1‑ y M y (PO4) 1+z , 0<=x<0.1, 0<=y<0.01, 0<=z<0.04, M comprises at least one of Ti, V, Zr, Nb, Mg, Mo, W and Al, the lithium-rich material comprises at least one of LFO and LNO, the chemical formula of the LFO is Li 5+a Fe 1‑b Z b O 4+c , 0<=a<0.5, 0<=b<0.01, 0<=c<0.03, Z comprises at least one of Ti, V, Zr, Nb, Mg, Mo, W and Al, and the chemical formula of the LNO is Li 2+d Ni 1‑ e Y e O 2+f , -0.5<=d<=0.5, e>=0, -0.5<=f<=0.5, Y comprises at least one of Ti, V, Al, Mg, Mn and Fe, and the negative electrode active material comprises a silicon negative electrode material, the mass ratio of the silicon negative electrode material in the negative electrode active material is 1%-50%. The application has the advantages of improving the energy density, rate performance and cycle performance of the lithium battery.

The invention provides a fast-charging type solid-state lithium battery alloy negative electrode material, a preparation method and a solid-state lithium battery, and relates to the technical field of lithium batteries. The alloy negative electrode material comprises the following element components in percentage by mass: 30-38% of indium In, 30-35% of tin Sn, 28-35% of bismuth Bi and 0-1.5% of doping elements, crystal phases formed by the alloy negative electrode material of the fast-charging type solid-state lithium battery at least comprise two crystal phases, namely InSn4 and InBi. The alloy negative electrode material has relatively high surface capacity, lithium ion conductivity and lithium ion diffusion coefficient, lithium dendrites do not grow on a negative electrode when a solid-state lithium battery assembled by the alloy negative electrode material is charged and discharged under high current density, and the battery is high in energy density and long in cycle life.

The invention relates to the technical field of electrochemical energy storage devices, in particular to a silicon-carbon negative electrode material, a negative electrode plate, an electrochemical device and an electronic device, and mainly comprises a core material and a coating material, the core material comprises silicon particles, the coating material comprises a porous carbon material doped with indium particles, and the coating material comprises a porous carbon material doped with indium particles. The average pore size of the coating material ranges from 10 nm to 20 nm, and the porosity of the coating material ranges from 35% to 45%. According to the silicon-carbon negative electrode material provided by the invention, the coating material has the effects of buffering and inhibiting silicon volume expansion, so that pulverization of the silicon-carbon negative electrode material is inhibited, and the problem of volume expansion of a battery is solved.

The invention belongs to the technical field of lithium ion battery negative electrode materials, and particularly relates to a spinel type metal oxide coated hard carbon composite material based on a lattice matching mechanism, and a gradient doping preparation method of the spinel type metal oxide coated hard carbon composite material can overcome the defects that a hard carbon material is low in initial coulombic efficiency (about 50%), low in lithium ion transmission rate and poor in rate capability. According to the invention, magnesium salt, aluminum salt, copper salt and other metal salts are mixed with hard carbon, a precipitant is added, and a hydrothermal method is combined with a calcination process to obtain the core-shell structure composite material with hard carbon coated with a spinel structure. The technology has the following three obvious advantages: (1) lattice adaptive design of the spar type metal oxide and the hard carbon, (2) molybdenum-copper gradient doping repair of the SEI film, and (3) stable circulation of more than 5000 times at the capacity of 350mAh / g.

The invention belongs to the technical field of batteries, and particularly relates to a negative electrode material, a secondary battery and electric equipment. The second coating layer with the porous carbon material in the negative electrode material provides a sufficient buffer space for volume expansion of silicon, so that cracks and pulverization of the negative electrode material are effectively reduced, and the structural integrity of the negative electrode material is further ensured. And meanwhile, the solid electrolyte arranged in the second coating layer can maintain the smoothness of an ion transmission path in the silicon expansion process, so that the rate capability and the quick charge performance of the battery are ensured. Besides, a third coating layer (SEI film) formed by the ionic liquid has good ionic conductivity, and dynamic covalent bonds existing in some ionic liquids can be fractured and recombined under the action of external stress, so that a self-repairing function is realized. Therefore, when cracks are generated on the surface of the negative electrode material due to volume expansion, the third coating layer can quickly repair the cracks, prevent electrolyte permeation and lithium dendrite growth and inhibit side reactions.

The invention relates to the technical field of batteries, in particular to a negative electrode material, a preparation method thereof and a battery. The negative electrode material comprises a silicon nano material; the metal silicide layer at least partially coats the surface of the silicon nano material; the nitrogen and sulfur doped carbon layer at least partially coats the surface of the metal silicide; and the thickness of the metal silicide layer is greater than that of the nitrogen and sulfur doped carbon layer. According to the negative electrode material, the preparation method thereof and the battery provided by the invention, the coating structure of the negative electrode material is optimized, and the metal silicide / heteroatom doped carbon double-layer coated silicon nano material can be prepared by adopting a synthesis method which is low in energy consumption and capable of constructing a functional multi-layer coating structure, so that the long cycle life and the high-rate fast charging performance can be considered at the same time.

The invention discloses a dynamic borate bond-based self-healing polyacrylic acid binder and a preparation method thereof. The dynamic borate bond-based self-healing polyacrylic acid binder comprises a polymer main chain and a dynamic cross-linking agent, the dynamic cross-linking agent is a polyol compound containing at least two pairs of ortho-hydroxyl groups; the polymer main chain is formed by copolymerizing the following monomers: an acrylic structural monomer, the molar fraction of which accounts for 85-94% of the total monomer; a functional monomer containing a boric acid group, wherein the molar fraction of the functional monomer accounts for 3-8% of the total monomer; the mole fraction of the flexible monomer containing the acrylate group accounts for 3-8% of the total monomer. Various stresses generated by different negative electrode materials in circulation can be effectively adapted and buffered through a network formed by dynamic boric acid ester bonds and reversible fracture and combination of the boric acid ester bonds, so that the service life of the battery is generally prolonged, the working temperature range of the battery can be remarkably widened, the low-temperature discharge capacity can be remarkably increased, and the high-temperature cycle life can be prolonged.

The invention discloses a negative pole piece, a negative pole piece and a secondary battery, and belongs to the technical field of electrochemical energy storage, the product takes porous carbon in which an aromatic heterocyclic polymer and a carbon nanotube are arranged as a matrix, a silicon carbon material is arranged on the surface, and meanwhile, the pore volume and crushing force of the negative pole material are regulated and controlled, so that relatively high capacity contribution can be reserved, and the service life of the negative pole piece is prolonged. And the volume expansion rate is obviously reduced in the lithium deintercalation process, and the cycle performance is excellent when the lithium ion battery is applied to a secondary battery.

The invention provides a self-assembled hypha flexible carbon electrode material and a preparation method and application thereof, and belongs to the technical field of battery packs. The preparation method of the self-assembled hypha flexible carbon electrode material comprises the following steps: treating basswood with white rot fungus mycelia, crushing and roasting to obtain porous basswood / hypha composite carbon powder; and putting the porous basswood / hypha composite carbon powder and a carbon nanotube into a sterilized conical flask containing a potato glucose culture solution, inoculating gloeophyllum trabeum, performing activation culture, adding a dopamine hydrochloride aqueous solution, performing polymerization after ultraviolet irradiation, taking out and tabletting to obtain the self-assembled hypha flexible carbon electrode material. In the preparation process of the self-assembled hypha flexible carbon electrode material, the flexible carbon electrode material is synthesized by taking porous basswood / hypha composite carbon powder as a matrix, taking gloeophyllum trabeum hypha as an adhesive, taking polydopamine as a reinforcing agent and adding carbon nanotubes as a conductive reinforcing material, so that the technical problem of poor cycle performance of a lithium ion battery is solved.

The invention relates to a positive plate, a battery comprising the positive plate and an electric device, and belongs to the technical field of batteries. According to the invention, the element M is doped in and / or coated on the surface of the nickel cobalt lithium manganate particles, the bond energy of the element M and O is controlled to be greater than the bond energy of Ni and O, and the ratio of the Fd3m phase thickness in the nickel cobalt lithium manganate particles and the ratio of the mass ratio of M to the relative mass ratio of Ni in the positive electrode material meet a specific relationship, so that the structural stability of the nickel cobalt lithium manganate is remarkably improved; the lithium ion transmission efficiency is higher, the fast charging performance is better, and the higher capacity performance can be realized.