343 results about "Electronegativity" patented technology

The invention belongs to the technical field of OLEDs, and provides a polycyclic compound containing triphenyl silicon and a polyalkyl substituent group and an organic electroluminescent device containing the polycyclic compound. The structural general formula of the polycyclic compound is as shown in formula I in the specification. Benzofuran with higher electronegativity is introduced to a ring structure composed of nitrogen atoms and boron atoms, triphenyl silicon is introduced to the para-position of boron, and the synergistic effect of benzofuran and triphenyl silicon can significantly enhance the multiple resonance of a light-emitting core and reduce vibration relaxation. Due to simultaneous use of the benzofuran and the triphenyl silicon, the problems of vibration relaxation increase, spectrum widening and the like caused by introduction of the polyalkyl substituent are remarkably improved, the luminous efficiency of the material is remarkably improved, and the color purity is improved, so that the requirement of BT.2020 wide color gamut display standard on a luminescent spectrum is met. I

The invention discloses a high-entropy perovskite oxide catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalysts. The chemical general formula of the high-entropy perovskite oxide catalyst is La (MMN) O3, and M is a transition metal element with high electronegativity. M is a mixture of Ni, Cu, Co and Fe elements. The molar ratio of La to Ni to Cu to Co to Fe to Mn is (0.9 to 1): (0.15 to 0.25): (0.15 to 0.25): (0.15 to 0.25): (0.15 to 0.25): (0.15 to 0.25): (0.15 to 0.25). The La (MMN) O3 catalyst is of a rod-shaped structure formed by stacking particles. According to the high-entropy perovskite oxide catalyst as well as the preparation method and the application thereof, the B site of perovskite is doped by the high-electronegativity transition metal element, so that the Mn-O covalence is enhanced, and the catalytic performance is improved; the catalyst is prepared in an electrostatic spinning and calcining mode, a rod-shaped structure with accumulated nano-particles is obtained, the surface area of the catalyst is increased, and the catalytic effect is improved.

A modified nickel-based positive electrode material comprises a nickel-based positive electrode material matrix and a doping element doped in the nickel-based positive electrode material matrix, the electronegativity of the doping element is higher than that of lithium and transition metal elements in the nickel-based positive electrode material matrix, and the porosity of the material is 10%-20%. The preparation method comprises the following steps: mixing and sintering a positive electrode material precursor, a lithium source and a doping agent to obtain a sintered product; washing and drying the sintered product to obtain a washed product; and mixing the washed product with a coating agent, and sintering to obtain the modified nickel-based positive electrode material. The invention also discloses a lithium ion battery. In the modified nickel-based positive electrode material, a part of doped elements enter a lattice body of a nickel-based positive electrode material matrix, the electronegativity of the doped elements is larger than that of lithium and transition metal elements, the doped elements have higher covalence, higher bond strength and higher oxidation potential, lattice oxygen in the structure is stabilized, precipitation of the lattice oxygen is reduced, and therefore the structural stability of the material is improved.

The present invention relates to a coating method for a high-nickel layered oxide positive electrode material, comprising the following steps: dissolving the high-nickel layered oxide positive electrode material, a high-valent metal halide, and an alkaline lithium source in a solvent, mixing them evenly, centrifuging, and filtering, and then calcining the obtained mixed powder to obtain a high-nickel layered oxide positive electrode material with a coated structure. The present invention utilizes an acid-base neutralization reaction to coat the high-nickel layered oxide positive electrode material, and the coated components include three elements: a high-valent metal, a halogen element (F or Cl) with a high electronegativity, and a Li element. The purpose of coating the former two is to improve the structural stability of the high-nickel layered oxide, and the latter provides a lithium source for the positive electrode material, while avoiding contact between the high-nickel layered oxide and the sulfide electrolyte, inhibiting the occurrence of side reactions, and being beneficial to the long-cycle stability of the sulfide all-solid-state lithium battery.

The invention discloses a zinc-bromine flow battery multifunctional negative electrode electrolyte and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, and the method comprises the following steps: uniformly stirring and mixing a solvent, deionized water and a cosolvent, adding an electrolyte, stirring until the electrolyte is completely dissolved, then adding a supporting electrolyte and a negative electrode additive, stirring until the supporting electrolyte and the negative electrode additive are completely dissolved, and obtaining the zinc-bromine flow battery multifunctional negative electrode electrolyte. The multifunctional negative electrode electrolyte of the zinc-bromine flow battery is obtained; the negative electrode cosolvent is dimethylformamide; and the negative electrode additive is at least one of saponin and cinnamyl aldehyde. Saponin molecules are adsorbed on the surface of the zinc electrode, and electronegative carboxyl groups of the saponin molecules form an electrostatic repulsion net in an electric double layer, so that zinc ions are forced to be uniformly dispersed, local ion concentration hot spots are eliminated, and dendritic crystal nucleation is inhibited from the source. In cinnamyl aldehyde, the strong electronegativity of oxygen atoms and the electronegativity of aldehyde oxygen are far higher than those of hydrogen, so that electrons are strongly attracted, adjacent carbon atoms are positively charged, polar adsorption sites are formed, the hydrogen evolution reaction is effectively inhibited, and the stability and the cycle life of the battery are greatly improved.

The invention discloses TiO2-x (F) powder, a preparation method thereof and application of the TiO2-x (F) powder in strengthening the performance of a solid hydrogen storage material, and belongs to the technical field of hydrogen storage materials and preparation of the hydrogen storage materials. The problems that an existing magnesium-based solid hydrogen storage material is high in hydrogen desorption temperature, slow in low-temperature dynamics and the like are solved. According to the preparation method, the fluorinated transition metal Ti oxide additive doped with the oxygen vacancies is prepared, electrons of Mg are captured by utilizing the strong electronegativity of F atoms on the surfaces of transition metal Ti atoms, MgF2 active catalytic species are generated in the hydrogen absorption and desorption process, and the hydrogen storage performance of MgH2 is further improved. Meanwhile, the construction of oxygen vacancies on the surface of the transition metal Ti atom can provide active sites for Mg / MgH2 nucleation growth, can greatly accelerate the flow of electrons in the hydrogen absorption / desorption process, improves the thermal / dynamic performance, and realizes the reversible hydrogen absorption / desorption of the magnesium-based hydrogen storage material at low temperature.

The invention relates to the technical field of quantum computing and molecular electronic devices, in particular to a probabilistic bit device based on polyfluoroaryl methyl free radicals and a preparation method of the probabilistic bit device. According to the probabilistic bit device, the coupling efficiency of molecules and electrodes is improved by virtue of the characteristic that the paramagnetic unpaired electron spin state of tri (polyfluoroaryl) methyl free radical molecules can be used as a random expansion physical entropy source and high electronegativity and stability formed by modification of a plurality of strong electron-withdrawing fluorine atoms in the molecules. During the operation period of the device, the spin fluctuation can efficiently regulate and control tunneling current passing through molecules, promote random conversion between output high and low current states, show excellent random binary fluctuation characteristics, and simultaneously have high sensitivity and long coherence time. Compared with the prior art, the device has remarkable advantages in the aspects of device stability, energy efficiency ratio and external field controllability. The preparation method is simple and convenient to operate, mild in reaction condition and beneficial to large-scale production.

The invention provides a positive quantum dot light-emitting diode and a preparation method thereof, and belongs to the technical field of photoelectric materials. The invention provides a positive quantum dot light-emitting diode. The positive quantum dot light-emitting diode comprises an anode, a hole injection layer, a hole transport layer, a quantum dot light-emitting layer, an electron transport layer and a cathode from bottom to top, the electron transport layer is a ZnMgO thin film modified by halogen amine salt. According to the invention, the ZnMgO thin film is modified by using the halogen amine salt, so that the conduction band energy level of the ZnMgO electron transport layer can be moved upwards, the interface potential barrier between the electrode and the electron transport layer is increased, excessive electron injection can be blocked, and the carrier injection balance in the device is promoted. Meanwhile, amino cations in the halogen amine salt can passivate a hydroxyl defect state on the surface of ZnMgO, and high-electronegativity halogen ions enter ZnMgO crystal lattices to passivate oxygen vacancy defects, so that interface exciton quenching is reduced, and the radiation recombination efficiency of the device is improved.

A semiconductor device includes a dielectric layer, a conductive layer formed over the dielectric layer, and a reduction sacrificial layer formed between the dielectric layer and the conductive layer, wherein the reduction sacrificial layer includes a first reduction sacrificial material having higher electronegativity than the dielectric layer, and a second reduction sacrificial material having higher electronegativity than the first reduction sacrificial material.

The invention relates to the technical field of positive electrode materials, and discloses a preparation method of a carbon-coated fluorine-doped sodium ferric sulfate positive electrode material, which comprises the following steps: step 1, adding an iron source, a sodium source, a sulfur source, a carbon source and a fluorine source into deionized water, and heating and stirring to completely dissolve the raw materials to obtain a solution A; 2, converting the solution A into precursor powder B by using a spray drying method; and 3, calcining the precursor powder B in an inert atmosphere, and crushing and grinding the obtained product to obtain the carbon-coated fluorine-doped Na2Fe2 (SO4) 3 positive electrode material. The F element with higher electronegativity than the S element is introduced, so that the overall electron distribution of the material is changed, the structural stability is improved, and the high-conductivity carbon protection layer is coated on the surface of the active material to form a conductive network, so that the resistance is reduced, the volume expansion is relieved, and the battery capacity and the cycling stability can be obviously improved.

The invention discloses a rare earth compound flocculant and a preparation method and application thereof.The rare earth compound flocculant is composed of a gluconic acid rare earth compound, a pyrithione rare earth compound and water, the content of the gluconic acid rare earth compound is 5-15 wt%, and the gluconic acid rare earth compound is prepared by reacting sodium gluconate with first chlorinated rare earth salt in water; the content of the pyrithione rare earth compound is 0.4-0.6 wt%, and the pyrithione rare earth compound is prepared by reacting sodium pyrithione with second chlorinated rare earth salt in water. According to the invention, rare earth ions have positive electricity, and show extremely strong coordination ability and high coordination number. Meanwhile, the surface of phaeodactylum tricornutum has electronegativity; therefore, when the rare earth ions are in contact with the phaeodactylum tricornutum, the rare earth ions and the phaeodactylum tricornutum can rapidly generate charge interaction, so that the phaeodactylum tricornutum is rapidly agglomerated and forms a lump, and then the lump

The invention belongs to the technical field of solid electrolytes, and relates to a selenium-doped sulfide solid electrolyte as well as a preparation method and application thereof. The general chemical formula of the sulfide solid electrolyte is Li < 6 + / -iP < 1-x > MxS < 5-y > SeyX, i is greater than or equal to 0 and less than 1, x is greater than 0 and less than 1, y is greater than 0 and less than 1, M is one or more of Zr, Ta, Nb, Mo, Bi, In and Y, and X is one or more of Cl, Br and F. According to the invention, the selenium element with larger ionic radius and lower electronegativity is introduced to replace the sulfur element, and Zr, Ta, Nb, Mo, Bi, In or Y elements are introduced, so that the doped sulfide solid electrolyte system has excellent stability to air, organic solvents and lithium while ensuring high ionic conductivity, and the assembled all-solid-state battery shows excellent cycle stability.

The invention discloses a protruding conductive microsphere and a pretreatment method thereof. The pretreatment method specifically comprises the steps of roughening treatment, protruding and interface activity treatment, sensitization treatment, activating treatment and chemical plating. In the protruding and interfacial activity treatment, by adding an interfacial agent, the electronegativity of the surfaces of the microspheres is enhanced, electrostatic adsorption with positively charged nickel nanoparticles is generated, and meanwhile, agglomeration of the nickel nanoparticles on the surfaces of the polymer microspheres is effectively prevented through the steric hindrance effect; therefore, a nickel nanoparticle bulge structure which is high in density, uniform in distribution and firm in combination is formed on the surface of the polymer microsphere. The method effectively solves the problems that a traditional conductive microsphere coating is prone to cracking and falling off, poor in dispersity and the like, the prepared protruding conductive microspheres have the outstanding advantages of being high in coating binding force, excellent in conductivity, good in dispersity, not prone to agglomeration and the like, the technological process is simple, mass production is easily expanded, and the method is suitable for large-scale production. The anisotropic conductive adhesive film has a wide commercial application prospect in the field of electronic packaging such as anisotropic conductive adhesive films.

The invention discloses an ultralow-thermal-conductivity high-entropy rare earth disilicate ceramic material and a preparation method thereof, and belongs to the technical field of high-performance ceramics. Through a high-entropy engineering strategy, aiming at the problems of poor phase stability, high thermal conductivity and insufficient calcium-magnesium-aluminum silicate corrosion resistance of a traditional rare earth bisilicate material, a Ho-Yb-Lu-X multi-element rare earth composite system high-entropy effect regulation and control component strategy is innovatively adopted, and based on atomic radius difference, electronegativity matching and a mixed entropy effect, the high-entropy composite material is prepared. The high-entropy ceramic with the beta-type RE2Si2O7 phase structure is successfully prepared, generation of impure phases is effectively inhibited, and a compact material is obtained. The obtained material shows the ultralow thermal conductivity of 0.841 W / m.K at the temperature of 1400 DEG C, wherein the thermal conductivity is reduced by about 46% compared with that of traditional Yb2Si2O7. According to the preparation process, the sintering temperature is reduced by 50 DEG C through high-entropy component design, no complex post-treatment procedure is needed, the preparation process has the advantages of simplified process, high yield and the like, and an ideal candidate material is provided for a new generation of aero-engine thermal barrier coating.

The invention discloses a sodium ion battery negative electrode material heterostructure, a construction method and a performance prediction method, and belongs to the technical field of electrochemical energy storage, Nb atoms are replaced by Ge or Sn to obtain Nb < 1-x > AxCO2, and then the Nb < 1-x > AxCO2 is compounded with 2D SiC to construct a SiC / Nb < 1-x > AxCO2 heterostructure, so that a sodium ion battery negative electrode material with improved electrochemical performance is obtained. The single-layer Nb2CO2 MXene provides good electronic conductivity and structural stability for the negative electrode material, and the introduction of SiC ensures excellent structural stability and high theoretical capacity; a heterostructure interface formed by SiC and Nb < 1-x > A < x > CO2 plays an important role in promoting electron conductivity and Na ion transfer. Due to the fact that Ge and Sn are close to C in electronegativity, the strength of A-C bonds formed between alloy elements and C is larger than that of Nb-C bonds, the stability of the heterostructure is enhanced, and the integrity of the electrode structure is kept.

The invention relates to the field of covalent organic framework materials and photocatalytic organic reactions, in particular to a COF material for improving photo-generated charge separation and a preparation method and application of the COF material. According to the present invention, 1, 3, 5-tri (4-aminophenyl) benzene (TAPB) is adopted as a donor unit, and a novel D-A type multi-bibenzothiadiazole TPAB-DTT-COF covalent organic framework material using a conjugated unit 2, 1, 3-benzothiadiazole as an acceptor unit is prepared; tAPB is an excellent electron donor unit which is widely used at present, polybiphenyl thiadiazolyl is an electron withdrawing group, the combination and matching of TAPB and polybiphenyl thiadiazolyl enhance the electronegativity difference value in molecules, reduce the exciton binding energy, promote the transfer of electrons from TAPB to a DTT unit, enhance the in-plane transmission and exciton separation efficiency, dissociate excitons under illumination, and improve the efficiency of electron transfer. The TAPB-DTT-COF material has the advantages that the TAPB-DTT-COF material has obvious photocurrent response signal, more obvious charge transfer performance and good photocatalytic performance;

The invention provides a design and application of a power type electrolyte of a double-electric-layer capacitor, and the electrolyte comprises an organic solvent, an electrolyte salt and an additive. Wherein the additive has a general formula structure as shown in Figure 1: the additive has a strong electronegativity part and a strong electropositivity part, a proper chain length is adjusted between the two parts, so that the whole molecular size of the additive can be matched with the micropore diameter of the activated carbon, adsorption and desorption are facilitated, bond breaking is easy, and when part of pseudocapacitance is contributed through oxidation bond breaking, the performance of the additive is improved. According to the present invention, the positive electrode and the negative electrode can be preferentially adsorbed to the positive electrode and the negative electrode so as to form the regulation and the low polarity and high density interface, such that the ion association of the salt ions at the double electrode layer is reduced, the reduction of the liquid phase transmission internal resistance is achieved, the excellent power performance is further represented, and the capacity retention rate in the 125A large-rate cycle (the conventional current is 25A) is increased to 90.1% from 76.3%. In addition, the silicon-containing part formed by broken bonds can also synergistically remove HF generated by hydrolysis of salt anions BF4 <-> in the electrolyte, passivate Al foil and reduce the contact internal resistance of the aluminum conducting bar. The configuration of the additive introduced into the electrolyte is shown in the specification.

The invention relates to the technical field of hydrogen storage alloys, in particular to a Ti-based hydrogen storage alloy and a preparation method and application thereof. The chemical formula of the Ti-based hydrogen storage alloy is TibZr (1.02b) CrcMn (1.6 c) Fe 0.4, b is larger than or equal to 0.92 and smaller than or equal to 0.95, and c is larger than or equal to 1.0 and smaller than or equal to 1.2. According to the invention, Ti or Cr is doped into a Ti0. 92Zr0. 1Cr1. 0Mn0. 6Fe0. 4 alloy matrix, and regulation and control of unit cell parameters and electronegativity are realized by means of alloying, so that the hydrogen compression material has a higher compression ratio, and the alloy crystal structure is stable, and has more excellent activation performance, longer cycle life and higher cycle stability.

The invention discloses a high-strength and high-tensile-plasticity titanium-based light high-temperature alloy as well as preparation and application thereof. The chemical formula of the titanium-based light-weight high-temperature alloy is TiaVbNbcAldCreZriSij, the titanium-based light-weight high-temperature alloy with high strength and high tensile plasticity disclosed by the invention is designed by regulating and controlling the content of each element and the valence electron concentration and electronegativity of the alloy according to the intrinsic characteristics of each element, and a nano-scale precipitated phase is introduced into the alloy in combination with the addition of a non-alloy element Si, so that the high-strength and high-tensile plasticity titanium-based light-weight high-temperature alloy is obtained. The nano-particles are uniformly distributed in an alloy matrix, interact with dislocation in an alloy deformation process, and play a role in strengthening a second phase. According to the alloy design thought, the alloy has low density, good room-temperature strength and tensile plasticity and excellent high-temperature tensile property at the same time; and the method has the advantages of simple operation, easy implementation, no pollution in the process, low energy consumption, low cost and the like.

The invention discloses saturation magnetic induction prediction and component design of an iron-based amorphous alloy and an ultrahigh saturation magnetic induction iron-based amorphous / nanocrystalline alloy. The core effects of ferromagnetic element content, alloy mixing enthalpy and poor electronegativity are disclosed by combining a machine learning model XGBoost with SHAP analysis, the amorphous forming ability is not deteriorated while the high ferromagnetic element content is kept, extremely low coercive force can be obtained after annealing, and collaborative optimization of high saturation magnetic induction, the amorphous forming ability and the coercive force is realized. Parameters used by the component design criterion provided by the invention do not need experimental data, and can be directly calculated from alloy components. High-performance components are rapidly screened in combination with a machine learning model, the research and development period and cost of a traditional trial and error method are remarkably reduced, systematic theoretical guidance is provided for development of high-performance soft magnetic materials, and industrial feasibility is improved.

The invention provides application of a silver modified AFX molecular sieve in xenon and krypton gas separation, and belongs to the technical field of gas separation. According to the invention, silver ions with electronegativity are introduced into AFX molecular sieve pores through ion exchange, selective adsorption of xenon is realized through the AFX topological molecular sieve subjected to Ag exchange so as to enrich xenon, and excellent separation of xenon and krypton is finally realized. The xenon and krypton adsorption isotherm of the silver modified AFX molecular sieve under the condition of 25 DEG C is tested, and the IAST (ideal adsorption solution theoretical value) of the molecular sieve is analyzed to be 36.5 through a static adsorption curve; according to the method disclosed by the invention, a dynamic penetration test is carried out under trace Xe and Kr concentrations by simulating the waste gas subjected to UNF post-treatment, and the dynamic capacity of Xe is calculated to be 104 mmol kg <-1 >, which is superior to that of other reported materials.

The invention provides a p-type bismuth telluride-based material and a preparation method and application thereof, and belongs to the technical field of thermoelectric energy conversion materials. The p-type bismuth telluride-based material comprises a base material and a Bi element doped into crystal lattices of the base material; the base material comprises BiaSb1. 45Te3, and a is greater than or equal to 0.55 and less than or equal to 0.58. The thermoelectric performance and the mechanical performance of the material are improved by introducing the Bi element (electronegativity 2.02) which has a small electronegativity difference with the Te element (electronegativity 2.1), and the small electronegativity difference enables the Bi element in a matrix to have higher solubility, so that the carrier concentration (the doping of the Bi element mainly optimizes the carrier concentration) and the density of the material are improved; and the increase of the carrier concentration can improve the conductivity, so that the thermoelectric performance is improved.

The invention discloses a preparation method of nano silicone rubber core-shell particles and application of the nano silicone rubber core-shell particles in 3D printing, copolymer shells of the nano silicone rubber core-shell particles contain electronegative groups, so that the surfaces of the core-shell particles are negatively charged, and charge repulsive force is formed between the particles; and moreover, side groups with large steric hindrance are provided, so that agglomeration among nano particles is effectively prevented. Epoxy groups are contained in a copolymer shell layer, so that the nano silicone rubber core-shell particles have good compatibility when being applied to 3D printing photosensitive resin, and long-term quality stability of the 3D printing photosensitive resin is facilitated.

The invention discloses a surface-modified high-entropy lithium-rich manganese positive electrode material as well as a preparation method and application thereof, and the surface-modified high-entropy lithium-rich manganese positive electrode material is represented by a general formula Li1 + xNi0. 13Co0. 13Mn0. 54MyNzO2-wAw. The specific preparation method comprises the following steps: respectively weighing a nickel-cobalt-manganese compound, a lithium salt, an additive I and an additive II, uniformly mixing, carrying out high-temperature calcination in a muffle furnace, cooling, crushing, crushing, and screening to obtain the surface-modified high-entropy lithium-rich manganese positive electrode material. And mixing with an additive III, and carrying out secondary sintering to prepare the surface high-entropy lithium-rich manganese positive electrode material. According to the method, different electrostatic fields are generated through co-doping of a high-d-state orbital element and a low-electronegativity element, an O2p band is expanded, overlapping between the O2p band and a (TM-O) * band is enhanced, an energy band gap is reduced, and anion oxidation reduction reversibility is promoted; by constructing a surface high-entropy change energy band structure, the diversity and distortion energy of a Mn < 4 + > local structure are increased, and the formation energy of oxygen vacancies and the migration energy of transition metal ions are improved. Through accurate design and controllable preparation of the lithium-rich manganese material and multi-strategy coordinated regulation and control of an energy band structure, the cycle performance and the voltage attenuation phenomenon of the lithium-rich manganese-based positive electrode material are improved.

The invention relates to a prepreg and a composite board, the prepreg comprises plant fiber cloth and a resin composition attached to the plant fiber cloth, the resin composition comprises thermoplastic resin, thermosetting resin and a curing agent, and the electronegativity difference value of atoms in polar groups at the tail end of a main chain of the thermoplastic resin is 0.4-1.7. The composite board prepared from the prepreg can be recycled, and has excellent mechanical properties and damp-heat aging resistance at the same time.

The invention provides a fluorine-doped Fe-N-C composite material as well as a preparation method, application and regeneration thereof, and belongs to the technical field of water pollution. The preparation method comprises the following steps: firstly, mixing an iron precursor, zinc salt, an organic ligand and an organic solvent to synthesize a Fe-doped metal organic framework Fe (at) ZIF-8 material, and then carbonizing the Fe-doped metal organic framework Fe (at) ZIF-8 material into a Fe-N-C material; and then Fe-N-C and a fluorine source are mixed and subjected to secondary carbonization, and the fluorine-doped Fe-N-C composite material is obtained. Fluorine atoms are introduced into the Fe-N-C material and generate axial coordination with Fe in the center of FeN4, the fluorine element with high electronegativity can effectively improve the isoelectric point of the Fe-N-C material, the reaction activity of the material is enhanced, Fe leaching of the material in the reaction process is inhibited, and the stability of the material is improved. In addition, the prepared fluorine-doped Fe-N-C composite material can continue to be recycled through fluorine doping regeneration, and high reduction activity and stability are kept.

The present invention provides an electrolyte additive and a preparation method thereof, an electrolyte and a lithium ion battery. The S atoms in the structure of the electrolyte additive of the present invention have low electronegativity and low binding energy with lithium ions, which can reduce the desolvation energy of lithium ions and significantly improve the rate performance and cycle life of the battery at low temperatures. Moreover, the O atoms in its structure can significantly improve the solubility of the additive to compensate for the defect of poor solubility caused by the S atoms. In addition, the additive contains unsaturated bonds, which can form a dense SEI film containing S, which is beneficial to the migration of lithium ions at the electrode / electrolyte interface at low temperatures, and the SEI film containing S can effectively inhibit the generation of lithium dendrites at low temperatures, further improving the rate performance and cycle life of the battery at low temperatures.

The invention relates to a friction nano-generator connected with an electron cloud potential well to realize high output current. A conductive network-reduced graphene oxide (rGO) capable of being connected with various dielectric polymer segment electron cloud potential wells is embedded into two dielectric layers of ethyl cellulose (EC) and polydimethylsiloxane (PDMS), wherein the electronegativity difference of the two dielectric layers is large. Results show that in the operation process of TENG, more charges can be transferred from one triboelectric material to another material. The TENG based on the model shows a recorded 3000 [mu] A high output current in a contact separation mode. In addition, the TENG shows excellent durability in a high-humidity environment, which is a huge challenge for the traditional TENG. The invention provides a novel and promising strategy for manufacturing the TENG with ultrahigh output current and water resistance, which is crucial for further development and practical application of the TENG.

The invention discloses a preparation method and application of a framework nucleic acid synergistic enhanced click chemistry and DNAzyme catalytic electrode. According to the present invention, the azide group modified split G-quadruplex fragment A is assembled on the double-stranded DNA (dsDNA) edge of the DNA tetrahedron through the Hoogsteen hydrogen bond, such that the reasonable spatial distribution of the reactants is achieved, and the click chemical reaction efficiency on the interface is improved; under the catalytic condition of Cu (I), the alkyne group modified split G-quadruplex fragment B and the fragment A assembled on the tetrahedral scaffold form a complete G-quadruplex through a click chemical reaction. And further, the compound is compounded with Hemin, so that the formed G-quadruplex / hemin compound has peroxidase-like activity. Meanwhile, the nucleic acid framework with the strong electronegativity characteristic further enhances the response current of catalytic oxidation TMB, and sensitive detection of Cu < 2 + > and alkaline phosphatase is achieved.

According to the invention, a stable Zn negative electrode is realized by forming an in-situ constructed zinc-loving and hydrophobic interface through simple soaking, and a unique carbonyl functional interface layer is formed in situ by soaking zinc foil in a glyoxal solution. On the basis of strong electronegativity of carbonyl, obvious interaction can be generated on zinc ions. And moreover, the hydrophobicity of the Zn negative electrode is improved by the unique particle morphology formed in situ. Through reconstruction of a negative electrode interface by glyoxal, a contact angle result shows that the unique morphology of glyoxal formed on the surface of the Zn negative electrode can increase the hydrophobicity of the Zn negative electrode. Therefore, a compact granular unique morphology is formed in situ on the surface of the Zn negative electrode through simple soaking, so that the Zn negative electrode becomes hydrophobic, and side reactions such as hydrogen evolution and by-products at an electrolyte / electrode interface are slowed down. As a result, symmetric cells exhibit more than 3200 hours at 1 mA cm <-2 > and 1 mAh cm <-2 >. Various types of positive electrodes can be matched, and excellent cycling stability is realized; for example, when matched with a MnVO positive electrode, it can be stably cycled for 2000 times.