198 results about "Electronegativity" patented technology

The invention belongs to the technical field of OLEDs, and provides a polycyclic compound containing triphenyl silicon and a polyalkyl substituent group and an organic electroluminescent device containing the polycyclic compound. The structural general formula of the polycyclic compound is as shown in formula I in the specification. Benzofuran with higher electronegativity is introduced to a ring structure composed of nitrogen atoms and boron atoms, triphenyl silicon is introduced to the para-position of boron, and the synergistic effect of benzofuran and triphenyl silicon can significantly enhance the multiple resonance of a light-emitting core and reduce vibration relaxation. Due to simultaneous use of the benzofuran and the triphenyl silicon, the problems of vibration relaxation increase, spectrum widening and the like caused by introduction of the polyalkyl substituent are remarkably improved, the luminous efficiency of the material is remarkably improved, and the color purity is improved, so that the requirement of BT.2020 wide color gamut display standard on a luminescent spectrum is met. I

The invention discloses a zinc-bromine flow battery multifunctional negative electrode electrolyte and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, and the method comprises the following steps: uniformly stirring and mixing a solvent, deionized water and a cosolvent, adding an electrolyte, stirring until the electrolyte is completely dissolved, then adding a supporting electrolyte and a negative electrode additive, stirring until the supporting electrolyte and the negative electrode additive are completely dissolved, and obtaining the zinc-bromine flow battery multifunctional negative electrode electrolyte. The multifunctional negative electrode electrolyte of the zinc-bromine flow battery is obtained; the negative electrode cosolvent is dimethylformamide; and the negative electrode additive is at least one of saponin and cinnamyl aldehyde. Saponin molecules are adsorbed on the surface of the zinc electrode, and electronegative carboxyl groups of the saponin molecules form an electrostatic repulsion net in an electric double layer, so that zinc ions are forced to be uniformly dispersed, local ion concentration hot spots are eliminated, and dendritic crystal nucleation is inhibited from the source. In cinnamyl aldehyde, the strong electronegativity of oxygen atoms and the electronegativity of aldehyde oxygen are far higher than those of hydrogen, so that electrons are strongly attracted, adjacent carbon atoms are positively charged, polar adsorption sites are formed, the hydrogen evolution reaction is effectively inhibited, and the stability and the cycle life of the battery are greatly improved.

The invention relates to the technical field of quantum computing and molecular electronic devices, in particular to a probabilistic bit device based on polyfluoroaryl methyl free radicals and a preparation method of the probabilistic bit device. According to the probabilistic bit device, the coupling efficiency of molecules and electrodes is improved by virtue of the characteristic that the paramagnetic unpaired electron spin state of tri (polyfluoroaryl) methyl free radical molecules can be used as a random expansion physical entropy source and high electronegativity and stability formed by modification of a plurality of strong electron-withdrawing fluorine atoms in the molecules. During the operation period of the device, the spin fluctuation can efficiently regulate and control tunneling current passing through molecules, promote random conversion between output high and low current states, show excellent random binary fluctuation characteristics, and simultaneously have high sensitivity and long coherence time. Compared with the prior art, the device has remarkable advantages in the aspects of device stability, energy efficiency ratio and external field controllability. The preparation method is simple and convenient to operate, mild in reaction condition and beneficial to large-scale production.

The invention discloses a protruding conductive microsphere and a pretreatment method thereof. The pretreatment method specifically comprises the steps of roughening treatment, protruding and interface activity treatment, sensitization treatment, activating treatment and chemical plating. In the protruding and interfacial activity treatment, by adding an interfacial agent, the electronegativity of the surfaces of the microspheres is enhanced, electrostatic adsorption with positively charged nickel nanoparticles is generated, and meanwhile, agglomeration of the nickel nanoparticles on the surfaces of the polymer microspheres is effectively prevented through the steric hindrance effect; therefore, a nickel nanoparticle bulge structure which is high in density, uniform in distribution and firm in combination is formed on the surface of the polymer microsphere. The method effectively solves the problems that a traditional conductive microsphere coating is prone to cracking and falling off, poor in dispersity and the like, the prepared protruding conductive microspheres have the outstanding advantages of being high in coating binding force, excellent in conductivity, good in dispersity, not prone to agglomeration and the like, the technological process is simple, mass production is easily expanded, and the method is suitable for large-scale production. The anisotropic conductive adhesive film has a wide commercial application prospect in the field of electronic packaging such as anisotropic conductive adhesive films.

The invention provides a design and application of a power type electrolyte of a double-electric-layer capacitor, and the electrolyte comprises an organic solvent, an electrolyte salt and an additive. Wherein the additive has a general formula structure as shown in Figure 1: the additive has a strong electronegativity part and a strong electropositivity part, a proper chain length is adjusted between the two parts, so that the whole molecular size of the additive can be matched with the micropore diameter of the activated carbon, adsorption and desorption are facilitated, bond breaking is easy, and when part of pseudocapacitance is contributed through oxidation bond breaking, the performance of the additive is improved. According to the present invention, the positive electrode and the negative electrode can be preferentially adsorbed to the positive electrode and the negative electrode so as to form the regulation and the low polarity and high density interface, such that the ion association of the salt ions at the double electrode layer is reduced, the reduction of the liquid phase transmission internal resistance is achieved, the excellent power performance is further represented, and the capacity retention rate in the 125A large-rate cycle (the conventional current is 25A) is increased to 90.1% from 76.3%. In addition, the silicon-containing part formed by broken bonds can also synergistically remove HF generated by hydrolysis of salt anions BF4 <-> in the electrolyte, passivate Al foil and reduce the contact internal resistance of the aluminum conducting bar. The configuration of the additive introduced into the electrolyte is shown in the specification.

The invention relates to the technical field of hydrogen storage alloys, in particular to a Ti-based hydrogen storage alloy and a preparation method and application thereof. The chemical formula of the Ti-based hydrogen storage alloy is TibZr (1.02b) CrcMn (1.6 c) Fe 0.4, b is larger than or equal to 0.92 and smaller than or equal to 0.95, and c is larger than or equal to 1.0 and smaller than or equal to 1.2. According to the invention, Ti or Cr is doped into a Ti0. 92Zr0. 1Cr1. 0Mn0. 6Fe0. 4 alloy matrix, and regulation and control of unit cell parameters and electronegativity are realized by means of alloying, so that the hydrogen compression material has a higher compression ratio, and the alloy crystal structure is stable, and has more excellent activation performance, longer cycle life and higher cycle stability.

The invention provides application of a silver modified AFX molecular sieve in xenon and krypton gas separation, and belongs to the technical field of gas separation. According to the invention, silver ions with electronegativity are introduced into AFX molecular sieve pores through ion exchange, selective adsorption of xenon is realized through the AFX topological molecular sieve subjected to Ag exchange so as to enrich xenon, and excellent separation of xenon and krypton is finally realized. The xenon and krypton adsorption isotherm of the silver modified AFX molecular sieve under the condition of 25 DEG C is tested, and the IAST (ideal adsorption solution theoretical value) of the molecular sieve is analyzed to be 36.5 through a static adsorption curve; according to the method disclosed by the invention, a dynamic penetration test is carried out under trace Xe and Kr concentrations by simulating the waste gas subjected to UNF post-treatment, and the dynamic capacity of Xe is calculated to be 104 mmol kg <-1 >, which is superior to that of other reported materials.

The application provides a Sn-doped Fe-N-C catalyst, a preparation method and application thereof. The catalyst comprises a carrier and Sn atoms and Fe atoms supported on the carrier, and the carrier is an N-doped carbon material. The application dopes the p-block metal Sn with stronger electronegativity into the Fe-N-C catalyst, forms an electron-withdrawing environment around the FeN4 site, reduces the electronegativity of the FeN4 site, and weakens the adsorption strength of the FeN4 site on the oxygen reduction intermediate. Meanwhile, the metal Sn is weaker in reactivity with hydrogen peroxide produced by the reaction of oxygen via a two-electron process than Fe, reduces the concentration of free radicals produced by the reaction, improves the stability of the carrier and active sites, and can effectively prevent the shedding of Fe. The application uses the catalyst as a cathode catalyst of a proton exchange membrane fuel cell, is low in cost, and can simultaneously meet the requirements of high catalytic activity and good stability.

To improve cell performance.SOLUTION: An electrochemical cell comprises a first electrode layer, a second electrode layer, and a solid electrolyte layer. The solid electrolyte layer is located between the first electrode layer and the second electrode layer and has oxide ion conductivity. The first electrode layer includes an electron conductive material, and a first material including, as a main component, a first element having a smaller electronegativity than that of zirconium.SELECTED DRAWING: Figure 3

The application provides a fluorine-doped Fe-N-C composite material and a preparation method and application and regeneration thereof, and belongs to the technical field of water pollution. In the application, an iron precursor, a zinc salt, an organic ligand and an organic solvent are mixed to synthesize Fe-doped metal organic framework Fe@ZIF-8 material, and then the Fe@ZIF-8 material is carbonized into Fe-N-C material; then the Fe-N-C material is mixed with a fluorine source and subjected to secondary carbonization to obtain the fluorine-doped Fe-N-C composite material. In the application, fluorine atoms are introduced into the Fe-N-C material to produce axial coordination with Fe of the FeN4 center, the fluorine element with high electronegativity can effectively improve the isoelectric point of the Fe-N-C material, the reaction activity of the material is enhanced, the Fe leaching of the material in the reaction process is inhibited, and the stability of the material is improved. In addition, the prepared fluorine-doped Fe-N-C composite material can be reused through fluorine-doping regeneration, and high reduction activity and stability can be maintained.

The invention discloses a synthesis method and application of a non-condensed ring electron acceptor, which are different from a traditional condensed ring structure or a single alkyl chain side chain, and a dichlorobenzene unit is introduced as a conformation regulating group. As chlorine atoms have strong electronegativity and proper atomic radius, remarkable non-covalent interaction such as Cl-S and Cl-pi can be generated among molecules. The interaction is similar to a set of precise molecular guide rails, molecules are guided to perform highly ordered pi-pi accumulation, so that electron cloud overlapping is remarkably enhanced, and an efficient electron transmission channel is constructed. According to the organic solar cell prepared based on the non-condensed ring electron acceptor material designed by the invention, the electron mobility is remarkably improved, and meanwhile, the charge recombination loss of a device is effectively reduced.

The application is a divisional application of Chinese patent application No. 202011250638.2 entitled "Structure of steric hindrance adjustable weak base light stabilizer and preparation method and application thereof". The present application belongs to the field of new compounds and their synthesis methods, and specifically relates to a steric hindrance adjustable weak base light stabilizer and a preparation method and application thereof. The innovative light stabilizer of the present application adjusts the steric hindrance by establishing the size of the substituent group that produces steric hindrance around the nitrogen atom in the general structure. In addition, by adjusting the distance of the polar group, the electronegativity of the nitrogen atom can be affected, thereby adjusting its basicity or nucleophilic property. By adjusting the steric hindrance and nucleophilic property or basicity of the nitrogen atom in the environment, the desired effect is obtained, and the application range of the innovative light stabilizer is widened, so that it is widely applicable to PC, polyester, PU, PVC and other acidic or electrophilic polymer materials as a light stability protection aid.

The invention relates to the field of application of dielectric energy storage materials, and discloses application of a polyimide film in a dielectric energy storage material. The polyimide is prepared by copolymerizing bis [4-(4-aminophenoxy) phenyl] sulfone and 4, 4 '-(hexafluoroisopropene) diphthalic anhydride, or copolymerizing bis [4-(3-aminophenoxy) phenyl] sulfone and 4, 4'-(hexafluoroisopropene) diphthalic anhydride, or copolymerizing bis [4-(3-aminophenoxy) phenyl] sulfone and 4, 4 '-(hexafluoroisopropene) diphthalic anhydride. Ether bonds are introduced to two sides of diphenyl sulfone to destroy a continuous conjugated structure between an imide ring and diphenyl sulfone, hexafluoroisopropylene with high electronegativity is introduced into a dianhydride unit, and high-temperature insulativity is improved through interaction of the three. When the prepared polyimide film is used as a dielectric medium energy storage material, the high-temperature insulation property is improved while the heat resistance and the relatively high dielectric constant are maintained, so that the energy storage property of a capacitor is improved. The discharge energy density of 7.25 J / cm < 3 > and 4.79 J / cm < 3 > is realized at 200 DEG C and 250 DEG C respectively, and the efficiency is greater than 90%.

The invention relates to the technical field of organic photoelectric materials and photovoltaic devices, in particular to a fluorine-substituted benzimidazolyl aniline compound and a synthesis method and application thereof. The structural general formula of the compounds is as shown in a formula I in the specification. The compound is introduced into a perovskite precursor solution as an additive and is used for preparing a perovskite thin film and a trans-perovskite solar cell. According to the compound provided by the invention, synergistic passivation of multi-site defects such as uncoordinated Pb < 2 + > and iodine vacancies is realized through aniline amino and benzimidazole ring N atoms in molecules, and non-radiative recombination is remarkably reduced; the strong electronegativity of fluorine atoms can enhance the electrostatic interaction between molecules and a perovskite Pb-I skeleton, meanwhile, a large conjugated system promotes pi-pi accumulation, and experimental results show that the photoelectric conversion efficiency of a champion device based on the additive can reach 23.3%; .

The invention relates to the technical field of gas production materials, and discloses preparation and application of a high-nitrogen energetic gas production material, triazole has high-energy and multi-nitrogen characteristics, nitryl compounds have high energy, and the combination of triazole and nitryl compounds enables the gas production material to have the characteristics of large gas production rate, low-temperature combustion, less harmful gas and the like; the molecular structure contains a large number of N-N, C-N and C = N bonds and has high enthalpy of formation, meanwhile, the content of C and H in the molecule is low, the density of the energetic material can be improved, the electronegativity of nitrogen and oxygen atoms in the structure is high, and the energetic material is a painful energetic material and has high safety in the using process; compared with similar gas production materials, the prepared gas production material has the advantages that the gas production rate is greatly increased, the amount of solid residues is greatly reduced, the added adhesive has no corrosivity, the prepared gas production material is good in fluidity, the external additive can play a role in slagging, and the residues are not prone to being sprayed out.

The application belongs to the technical field of industrial flue gas purification treatment, and particularly relates to a manganese-cadmium bimetallic denitration catalyst and a preparation method and application thereof. The manganese-cadmium bimetallic denitration catalyst has a pore diameter of 4.4-27 nm, a pore volume of 0.25-0.35 cm 3 / g, and a specific surface area of 75-85 m 2 / g. The number ratio of medium acid and strong acid sites contained in the manganese-cadmium bimetallic denitration catalyst is (7-8):1. The manganese-cadmium bimetallic denitration catalyst has the advantages that the manganese-cadmium bimetallic denitration catalyst utilizes the unique synergistic effect of the moderate difference in electronegativity between manganese and cadmium, realizes one-way transfer of electrons from cadmium to manganese, gives the catalyst a moderate SO2 adsorption energy, avoids sulfation of active sites, the difference in radius between Cd 2+ and Mn 2+ induces the skeleton to produce an expansion and cracking type defect, forms a 4.4-27 nm wide distribution mesoporous structure, reduces deposition of sulfate and ammonium salt, and presents a hierarchical porous structure, which enhances gas transfer in the reaction process and significantly improves the catalytic efficiency.

This invention discloses a heterostructure of sodium-ion battery anode material, its construction method, and its performance prediction method. It belongs to the field of electrochemical energy storage technology, and obtains Nb by substituting Nb atoms with Ge or Sn. 1‑ x A x CO2, then combined with 2D SiC to construct SiC / Nb 1‑x A x A CO2 heterostructure was developed to obtain a sodium-ion battery anode material with improved electrochemical performance. The monolayer Nb2CO2 MXene provided good electronic conductivity and structural stability for the anode material, while the introduction of SiC ensured excellent structural stability and high theoretical capacity. The combination of SiC and Nb... 1‑x A x The heterostructure interface formed by CO2 plays an important role in promoting electronic conductivity and Na ion transport. Due to the similar electronegativity of Ge and Sn to C, the A-C bond formed between the alloying elements and C is stronger than the Nb-C bond, thus enhancing the stability of the heterostructure and maintaining the integrity of the electrode structure.

A contact separation mode triboelectric soft X-ray emission device comprises a motion structure used for providing power for reciprocating linear motion; the contact structure is arranged in a vacuum environment and comprises an active contact unit and a passive contact unit which can move relatively to perform periodic contact and separation, and the active contact unit is connected with the moving structure; the contact surface of the active contact unit and the contact surface of the passive contact unit are respectively covered with materials with different electronegativity. The contact force measuring unit is used for measuring the contact pressure between the active contact unit and the passive contact unit in real time; wherein the motion structure is configured to adjust a driving parameter of the motion structure according to the contact pressure of the contact force measuring unit, so as to control the output characteristic of the soft X-ray.

The invention discloses a preparation method of a nitrogen-sulfur co-doped modified layered double-oxide material, and belongs to the technical field of water treatment.The preparation method comprises the following steps that 1, a carbon felt substrate is pretreated and dried, the treated substrate is placed in a uniform solution containing Fe (NO3) 3.9 H2O and Ni (NO3) 2.6 H2O to be subjected to a hydrothermal reaction, and after the hydrothermal reaction is completed, the substrate is taken out and dried; carrying out ultrasonic treatment and washing with deionized water to obtain a NiFe-LDH precursor; and (2) drying the obtained precursor, dipping the dried precursor in an ethanol solution of ammonium persulfate, and then carrying out high-temperature carbonization treatment in an inert gas atmosphere to prepare the nitrogen-sulfur co-doped modified nickel-iron layered double-oxide material. The difference of nitrogen and sulfur in atomic radius, electronegativity and doping form enables the co-doped structure to effectively regulate and control the electronic structure of the material: nitrogen doping improves conductivity, and sulfur doping promotes exposure and stability of active sites. The co-doping synergistically optimizes the electronic structure and catalytic activity of the material, so that the material has excellent capacitive deionization removal performance and electrocatalytic activity at the same time.

The present disclosure provides an organic electronic material containing a nitrogen heterocycle and a preparation method and use thereof, and relates to the technical field of organic electroluminescence. Nitrogen-containing heterocycles such as pyridine, triazine or pyrimidine are introduced into a main structure of phenanthrene, such that the electronegativity of the material is enhanced, and the electron transport performance and the thermal stability of a compound are improved. The organic electron transport material provided by the present disclosure has a relatively good thermal stability, a high luminous efficiency and a high luminous purity. An organic light-emitting device prepared from the organic electronic material has effects of reducing a driving voltage, improving a luminous efficiency, enabling color purity to be excellent and prolonging a service life.

The invention discloses a photoelectric device, a preparation method thereof and a display device, the photoelectric device comprises an anode, a luminescent layer, an electronic function layer and a cathode which are stacked in sequence, the electronic function layer comprises N-type metal oxide particles and a dopant, and the electronegativity of the dopant is 2.50-5.00. The photoelectric device disclosed by the invention is relatively long in service life.

This invention discloses a method for preparing Co-P3 / S-TiO2 nanowire array materials, along with their products and applications. Through a hydrothermal-etching-phosphating method, Co single atoms coordinated with P were successfully anchored on the surface of a TiO2 nanowire array rich in step defects, resulting in the Co-P3 / S-TiO2 nanowire array material. Under the dual regulation of the special step structure and the suitable electronegativity of P, the Co metal atom becomes an electron-rich center, exhibiting superior adsorption capacity and a unique coordination environment, thus possessing excellent electrocatalytic hydrogen evolution performance. The preparation process is simple, and the raw materials are inexpensive. This invention provides inspiration for the design and synthesis of single-atom catalysts and their application in the field of electrocatalytic water electrolysis.

The invention relates to a multi-principal-element alloy strength prediction and design method driven by experimental data. The method comprises the following steps: data acquisition, feature engineering, model construction, component design, solving of yield strength of different alloys by multiple analytical formulas, and screening of alloy components with large product of electronegativity difference and shear modulus. And determining a single-phase FCC component window through phase diagram calculation. According to the method, the component design efficiency is improved; a quantitative design tool is provided for high-strength material development in the fields of aerospace, nuclear energy and the like, and the research and development period is shortened.

The invention relates to the technical field of ocean energy sensing equipment, in particular to a self-powered sensor and method for wave height monitoring. The self-energized sensor comprises a first shell with two open ends, a sealed second shell and a plurality of power generation units. The upper end of the first shell is fixedly installed on one side of the second shell, and the lower end of the first shell is bent outwards. The multiple power generation units are sequentially arranged in the axis direction of the second shell. The power generation unit comprises a rotating part, a first substrate and a second substrate, a dielectric layer and an electrode layer which are different in electronegativity are arranged on the two opposite side walls of the first substrate and the second substrate, the rotating part rotates to drive the second substrate to rotate relative to the first substrate, and then the dielectric layer and the electrode layer are driven to move relatively to generate current. The self-energized sensor provided by the invention not only can monitor the wave height based on the electric signal output by the power generation unit, but also can supply power to the sensor by the generated electric signal, so that the self-energized sensor provided by the scheme can stably run for a long time.

The invention provides anion exchange resin, a preparation method thereof and an anion exchange membrane. The anion exchange resin has a structure as shown in a formula (1). Carbonyl is introduced into the formula (1), the carbonyl has strong electronegativity and conjugation ability, the carbonyl can disperse positive charges of nitrogen-containing heterocyclic cations and weaken the electron withdrawing effect of the nitrogen-containing heterocyclic cations on a skeleton structure, the polarization degree of chemical bonds of the skeleton structure is reduced, then the stability of the skeleton structure is improved, and the skeleton structure is not prone to breakage; and the structural stability of the anion exchange resin and the continuity of an ion transmission channel are ensured. Besides, carbonyl is used as a strong polar group, the carbonyl and a skeleton structure form a remarkable polarity difference, and the polarity difference can induce polymer molecules to realize nanoscale phase separation, promote the formation of a high-speed ion transmission channel, reduce the ion transmission resistance and improve the ion transmission performance of the anion exchange membrane.

The embodiment of the invention discloses a physical embedded closed-loop high-entropy alloy laser additive manufacturing performance oriented intelligent design method. By constructing a high-entropy alloy mechanical property database, training a multi-algorithm collaborative integrated agent model and fusing thermodynamic and physical laws and a multi-target Bayesian optimization algorithm, combined reverse design of high-entropy alloy components and LDED process parameters is realized, the applicability, accuracy and robustness of performance prediction are improved, and the performance prediction efficiency is improved. The research and development period of new materials is shortened, and the test cost is reduced. By embedding physical constraints such as valence electron concentration, mixing enthalpy, mixing entropy, electronegativity difference and atomic size difference and comprehensively considering the influence of process factors such as laser power, scanning speed and powder feeding rate, an optimal Pareto component-process scheme is obtained under the support of finite element simulation closed-loop verification and an incremental learning mechanism; and the tensile strength and the yield strength of the high-entropy alloy under different conditions are accurately predicted and reflected.

The present application relates to a kind of covalent organic framework film preparation based on biomimetic mineralization strategy and its application in ion separation.In the process of monovalent ion separation, methoxy forms stable interaction with monovalent ion through its unique coordination characteristics and electronegativity, significantly improves the transmission rate of monovalent ion. At the same time, the introduction of functionalized methoxy can also effectively inhibit the passage of divalent ion, so as to realize efficient ion separation. Biomimetic mineralization strategy can significantly improve the mechanical strength and chemical stability of COF membrane by compounding organic polymer with COF. Compared with traditional separation membrane, the biomimetic mineralized COF membrane provided by the present application exhibits higher separation efficiency, more excellent selectivity and longer service life, and is suitable for efficient extraction of lithium and other monovalent ion resources, battery material preparation and ion separation application in related industrial production process. The functionalized methoxy COF membrane material of the present application has the advantages of adjustable structure, simple preparation and potential for large-scale production.

The application belongs to the technical field of display, and particularly relates to an IGZO thin film transistor based on gradient gallium doping and hydrogen plasma treatment and a preparation method thereof. The application adopts ALD technology to construct a three-section linear gradient Ga-doped active layer, the bottom low Ga area ensures efficient carrier transport, the migration rate can reach 58.7 cm 2 Vs, the top high Ga area uses the high electronegativity of Ga-O bond and the wide band gap characteristics to inhibit the back channel defects, the Delta Vth under NBITS test is as low as 2.2 V, and the stability is improved by more than 5 times compared with the undoped device. In-situ hydrogen / oxygen plasma composite treatment is carried out in the ALD chamber, the saturation dangling bond is compensated, the interface state density is controlled to be ≤10 12 cm ‑2 eV ‑1 , and the sub-threshold swing is optimized. Periodic pauses are introduced in the active layer deposition, the film surface roughness is ≤0.5 nm; a two-step method is used for contact hole etching, and the top high Ga layer is ≥5 nm. The comprehensive performance meets the high-end application requirements such as high-resolution display and flexible display, and the application value and market competitiveness are remarkable.

The invention provides a modified glass fiber membrane, a preparation method and application thereof, and a zinc-iodine battery, and belongs to the technical field of zinc-iodine batteries. The modified glass fiber membrane provided by the invention comprises a glass fiber membrane matrix and a halogen-containing polymer bonded on the surface of the glass fiber membrane matrix through a binder. Halogen atoms in the halogen-containing polymer are elements with extremely high electronegativity, and can strongly attract electrons in a polymer chain of a high polymer material, so that electron cloud shift is caused, and negative charges are enriched on the surface of the high polymer material; when the glass fiber membrane adhered with the halogen-containing polymer is assembled into the zinc-iodine battery, due to the electrostatic repulsion effect, iodide ions on the positive electrode side are limited on the surface of the positive electrode, shuttling of the iodide ions is limited, and the cycling stability of the zinc-iodine battery is improved.

The invention belongs to the technical field of fuel cells, and particularly relates to a gas diffusion layer structure with durability and high conductivity and a preparation method and application thereof. The prepared gas diffusion layer comprises a metal ion capture layer, a substrate layer and a microporous layer which are sequentially stacked, the metal ion capture layer contains a metal ion capture material, and the metal ion capture material is selected from one or more of polyethyleneimine, polyacrylic acid, polyvinyl alcohol, chitosan and a perfluorosulfonic acid ionomer; specifically, a metal ion capture layer is constructed on a substrate layer close to one side of a flow channel, the conductivity of the gas diffusion layer is improved by using a method of strong interaction force between a high electronegativity chemical group and metal ions, and meanwhile, the metal ions are efficiently captured in a broad-spectrum manner, so that the gas diffusion layer has a wide application prospect.