The invention relates to a compound chemical blocking removing agent of an oil field polymer injection well. The compound chemical blocking removing agent is characterized in that a high molecular extending agent with strong electronegativity is used for hydrating and extending condensed and agglomerated polymer macromolecule chains again; peroxide is used as a primary oxidation agent; polybasic carboxylic acid which can slowly and uniformly ionize hydrogen ions is used as controlled-release acid; auxiliary agents such as a corrosion inhibitor, a penetrant, a metal ion chelating agent, a dual-metal coupling agent, an iron ion stabilizer, a bacteriacide, a stratum protective agent, and the like are added at the same time; and macromolecular polymers in blocking substances, which are near the oil field polymer injection well, and are fully extended by the extending agent, are oxidized and degraded by active hydroxyl which is produced from the reaction of the primary oxidation agent and the controlled-release acid, so that blocking of the polymer injection well is removed, and the apparent water injectivity index is improved. The chemical blocking removing agent is non-toxic and environment-friendly, has a wide applicable range of temperature and water quality, and has the advantages of simplicity in construction technique, safety and convenience in use and storage, and the like; and the viscosity-reducing rate of the compound chemical blocking removing agent to polyacrylamide gel can reach above 99%.