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57results about How to "Improve interface resistance" patented technology

All-solid-state battery with low interface resistance and preparation method of all-solid-state battery

The invention discloses an all-solid-state battery with low interface resistance and a preparation method of the all-solid-state battery, the all-solid-state battery comprises an integrated battery cell, and the integrated battery cell comprises a positive electrode current collector layer, a positive electrode layer, a buffer layer, an organic-inorganic composite electrolyte membrane, a negativeelectrode layer and a negative electrode current collector layer which are arranged in sequence; the organic-inorganic composite electrolyte membrane comprises a high-molecular polymer matrix, a lithium salt and an inorganic filler, the high-molecular polymer matrix is selected from polyvinylidene fluoride or a polyvinylidene fluoride-hexafluoropropylene copolymer; the lithium salt is selected from at least one of LiTFSI, LiFSI, LiClO4, LiPF6, LiBF4, LiBOB, LiDFOB and LiPF2O2. According to the invention, a layer of soft contact is formed between hard interfaces of the positive electrode and the negative electrode, multiple layers of films are integrally formed, different component film structures are seamlessly interconnected, and the interface problem of the solid-state battery is effectively improved. The solid-state battery provided by the invention has excellent capacity exertion and cycling stability, and the preparation method is high in efficiency and low in cost.
Owner:SHANGHAI INST OF SPACE POWER SOURCES

Membrane compounded by polyolefin porous membrane and aramid nano-fibers as well as compounding method and application of membrane

The invention belongs to the technical field of membrane materials of chemical power sources or chemical energy storage elements and discloses a membrane which has high size stability and is compounded by a polyolefin porous membrane and aramid nano-fibers, a compounding method of the membrane and application of the membrane to a lithium ion battery or other chemical energy storage elements. The compounding method comprises the following steps: introducing positive charges to the surface of the polyolefin porous membrane, soaking the polyolefin porous membrane with aramid nano-fiber dispersion liquid, taking out the polyolefin porous membrane, washing and drying, and soaking, washing and drying in a cyclic manner to obtain the compound membrane with a plurality of layers of aramid nano-fibers which are adsorbed on the surface of the polyolefin porous membrane. The compound membrane has low-temperature pore-closing property and high-temperature resistance and is suitable for electrochemical devices working at relatively high temperature; the compound membrane has relatively high ionic conductivity; the bonding force between the aramid nano-fibers and the polyolefin porous membrane is improved; the aramid nano-fibers are unlikely to be peeled from the polyolefin porous membrane in charging and discharging cycles; the interface resistance is unlikely to be increased along with the increase of the battery cycle number, so that the cycle performance of the battery is improved.
Owner:GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI

Method for efficiently preparing integrated electrode of flow battery

The invention discloses a method for efficiently preparing an integrated electrode of a flow battery, which comprises the following steps of: S1, well mixing plastic, a conductive auxiliary agent and an auxiliary agent, and processing a bipolar plate from the mixture; S2, pretreating graphite felts; S3, attaching a layer of volatile solvent to the surface of the bipolar plate; S4, tightly attaching the two pretreated graphite felts to the two sides of the bipolar plate with the volatile solvent attached to the surface to form a graphite felt / bipolar plate / graphite felt sandwich structure; and S5, stacking multiple layers of the graphite felt / bipolar plate / graphite felt sandwich structure, tightly laminating the multiple layers through a tablet press, introducing a direct current or an alternating current, and embedding graphite felt carbon fibers into the bipolar plate to form an integrated electrode. The flow battery integrated electrode is prepared in a current mode, the internal resistance in the finished integrated electrode can be remarkably reduced, and the efficiency of the flow battery is improved. The preparation method is simple, multiple integrated electrodes can be produced at a time, the production time is short, the efficiency is high, energy is saved, environment friendliness is achieved, and mass production is facilitated.
Owner:杭州德海艾科能源科技有限公司

Non-enzymatic biosensor based on carbon material/boron-doped diamond composite electrode as well as preparation method and application of non-enzymatic biosensor

The invention relates to a non-enzymatic biosensor based on a carbon material/boron-doped diamond composite electrode as well as a preparation method and application of the non-enzymatic biosensor. Aworking electrode of the non-enzyme biosensor is a carbon material/boron-doped diamond composite electrode; the carbon material/boron-doped diamond composite electrode comprises a substrate, a boron-doped diamond layer arranged on the surface of the substrate and a carbon material arranged on the surface of the boron-doped diamond layer, the carbon material is selected from at least one of microcrystalline graphite, carbon nanotubes, carbon nanofibers and graphene, the carbon nanotubes are carbon nanotubes growing at the bottom end, the boron-doped diamond film is of a surface porous structure, and meanwhile the surface of the boron-doped diamond film is further modified with nickel nanoparticles. By combining chemical vapor deposition, magnetron sputtering and annealing, nickel catalyticpreparation of different composite material electrodes is realized. The prepared composite carbon material electrode has the characteristics of high sensitivity, high stability, high resolution and high selectivity, and can be widely applied to the construction of glucose sensors.
Owner:CENT SOUTH UNIV

Production method for nb3sn superconducting wire rod, precursor for nb3sn superconducting wire rod, and nb3sn superconducting wire rod using same

The present invention provides: a Nb3Sn superconducting wire rod that is produced by the internal tin process and that has a number of useful functions in such aspects as promotion of Nb3Sn layer generation, mechanical strength (and increase in interfacial resistance) of superconducting filaments, critical temperature (magnetic field), miniaturization of crystal grains, etc.; and a production method therefor. The Nb3Sn superconducting wire rod production method according to one embodiment of the present invention comprises: a step for providing a rod material 10 which has an alloy compositionrepresented by Cu-xZn-yM (where, x is 0.1-40 mass%; M=Ge, Ga, Mg or Al, provided that x is 0-40 mass% for Mg), and a central part of which is provided with a Sn insertion hole 12, and which has a plurality of Nb insertion holes 14 that are discretely disposed along the outer peripheral surface of the Sn insertion hole 12; a step for installing an alloy bar having an alloy composition of Sn-zQ (Q=Ti, Zr, Hf) in the Sn insertion hole 12, and inserting a Nb core in the Nb insertion holes 14; a step for reducing the diameter of the rod material 10 so as to prepare a Cu-xZn-yM / Nb / Sn-zQ composite multicore wire having a prescribed outer diameter; and a step for subjecting the composite multicore wire to a heat treatment for generating a Nb3Sn phase.
Owner:NAT INST FOR MATERIALS SCI

High-voltage-resistant composite solid electrolyte, preparation method thereof and all-solid-state lithium battery

The invention discloses a high-voltage-resistant composite solid electrolyte, a preparation method of the high-voltage-resistant composite solid electrolyte and an all-solid-state lithium battery, and relates to the technical field of lithium ion batteries, and the high-voltage-resistant composite solid electrolyte is formed by hot pressing of a first composite solid electrolyte layer and a second composite solid electrolyte layer; the first composite solid electrolyte layer comprises a COFs matrix and a polymer electrolyte A loaded on the surface of the COFs matrix, and the polymer electrolyte A comprises polyoxyethylene, bismuth trioxide, a lithium salt and polyvinylidene fluoride; the second composite solid electrolytic layer comprises a COFs matrix and a polymer electrolyte B loaded on the surface of the COFs matrix; and the polymer electrolyte B comprises polymethyl methacrylate, bismuth trioxide, lithium salt and polyvinylidene fluoride. According to the composite solid electrolyte, the electrochemical window of the solid electrolyte is widened, the interface resistance is reduced, the interface stability of the positive electrode and the negative electrode and the lithium ion transmission performance are improved, the composite solid electrolyte can be simultaneously suitable for a lithium metal negative electrode and a high-voltage ternary positive electrode, and the cycle performance of a battery is improved.
Owner:WANXIANG 123 CO LTD

Separation film for lithium secondary battery having adhesive layer

The present invention relates to a coating composition, comprising a solvent, inorganic particles, a dispersant, and a binder, for coating at least one surface of a porous substrate having a plurality of pores. The binder comprises binder B and binder A, wherein the binder B and the binder A both contain a vinylidene fluoride (VDF)-derived unit and a hexafluoropropylene (HFP)-derived unit. The HFP-derived unit accounts for 8% to 50% by weight of the binder B, and in the binder A, the HFP-derived unit is not more than 80% of the proportion thereof in the binder B and is not less than 5% by weight of the binder A. The total number average molecular weight of the binder B is 200,000 to 2,000,000, and the total number average molecular weight of the binder A is 70% or less of that of the binder B. The weight ratio of binder A: binder B in the total coating composition is 0.1 to 10: 1. The present invention has resolved the problem that when a binder is thinned from 4 to 3 , the binder is dried before being sufficiently phase-separated and thus a sufficient electrode adhesive force cannot be obtained, and also in terms of a manufacturing method, the present invention has provided a coating composition in which sufficient phase separation occurs even in a low-humidity condition.
Owner:LG ENERGY SOLUTION LTD
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