838 results about "Polymethyl methacrylate" patented technology

The invention provides a SiO2 / TiO2 / PMMA radiation refrigeration film and a preparation method thereof, and relates to the technical field of passive daytime radiation refrigeration films. The radiation refrigeration film is prepared from the following raw materials: N, N-dimethylformamide, polymethyl methacrylate, silicon dioxide and titanium dioxide. The invention relates to a preparation method of a SiO2 / TiO2 / PMMA radiation refrigeration film. The preparation method comprises the steps of preparing silicon dioxide, preparing titanium dioxide, synthesizing composite sol and preparing the SiO2 / TiO2 / PMMA radiation refrigeration film. The SiO2 / TiO2 / PMMA radiation refrigeration film prepared by the invention has high reflectivity in the ultraviolet-visible-near infrared band and high emissivity in the infrared band, can realize 8.4 DEG C sub-environment refrigeration, and is low in cost and simple in process flow.

The invention discloses a high-RAP-doping-amount cold-mixed asphalt regenerant, and particularly relates to the technical field of asphalt regenerant, the high-RAP-doping-amount cold-mixed asphalt regenerant comprises the following raw materials: hydrogenated extract oil, acetyl tributyl citrate, a low-temperature penetrant, pre-swelling SEBS master batch, a crosslinking catalyst and a microcapsule antioxidant. Molecular-level branched-chain alkyl sodium sulfonate can be wedged into aged asphalt microcracks at the temperature of 65 DEG C, lost light components are balanced and supplemented through hydrogenated extract oil, an SEBS micro-crosslinking network forms an in-situ reinforcement effect at the temperature of 90 DEG C, the triple regeneration effect of regenerated asphalt is achieved, and the service life of the regenerated asphalt is prolonged. Nano-zinc oxide is treated by a silane coupling agent and then is modified by using methyl methacrylate and potassium persulfate, so that the nano-zinc oxide is coated with polymethyl methacrylate, the compatibility of the microcapsule antioxidant and the recycled asphalt can be improved, and the anti-aging performance of the recycled asphalt is improved.

The invention relates to the technical field of BOPP (biaxially-oriented polypropylene) films, in particular to a scratch-resistant adhesive-free matt film and a preparation method thereof, and the scratch-resistant adhesive-free matt film comprises a matt layer, a core layer and a thermal composite layer which are sequentially arranged, the matt layer comprises co-polypropylene, high-density polyethylene, 2.0-2.5 wt% of linear alkyl silicone (the weight-average molecular weight is 12-150 thousands, and the surface tension is 42-45 mN / m) taking maleic anhydride modified aziridine as a terminal group, and 2000-4000 ppm of spherical polymethyl methacrylate (the particle size D50 is 4.0-5.0 microns); the core layer comprises homo-polypropylene; and the thermal composite layer comprises an ethylene-vinyl acetate copolymer and 2000 to 4000 ppm of a spherical anti-blocking agent. According to the scratch-resistant adhesive-free matt film, through collaborative design of the components of the matt layer and the thermal composite layer, balance of scratch resistance, high surface tension (printing applicability) and winding and unwinding smoothness of the surface of the matt layer is achieved, and a solution for the scratch-resistant generality problem of the matt surface of the high-end BOPP matt film is provided.

The invention discloses a batch processing technology of micro-fluidic chips, and relates to the technical field of chip processing. The method comprises the following steps: firstly, providing at least two layers of polymer coiled materials, namely a first coiled material for forming a micro-channel structure and a second coiled material for closing a micro-channel, the coiled materials are continuous coiled materials selected from polyethylene glycol terephthalate (PET), cycloolefin polymer (COP), polycarbonate (PC) or polymethyl methacrylate (PMMA), and the coiled materials are continuous coiled materials selected from polyethylene glycol terephthalate (PET), cycloolefin polymer (COP), polycarbonate (PC) or polymethyl methacrylate (PMMA); the thickness of the coiled material is 50-500 microns; secondly, carrying out continuous compression molding processing on the surface of the first coiled material through a roll-to-roll processing platform; through a roll-to-roll continuous process, micro-channel mold pressing, functional deposition, precise alignment bonding and online cutting are integrated, high-efficiency, high-consistency and high-integration-level batch manufacturing of the micro-fluidic chip is realized, and manual intervention and production cost are remarkably reduced.

The invention discloses a waterproof long-lasting oil-control gel composition and a preparation method thereof, and belongs to the technical field of cosmetics. The composition comprises 4-6 parts of an oil absorption compound A, 9-13 parts of an oil absorption compound B and 70-95 parts of a gel matrix, wherein the oil absorption compound A is prepared from mesoporous silica and poloxamer 407, and the aperture of the oil absorption compound A is 5-10 nm; the oil absorption compound B is prepared from polymethyl methacrylate microspheres, isododecane and polyglycerol-3 diisostearate, and the pore diameter of the oil absorption compound B is 150 to 300 nm. According to the invention, through dual mechanisms of temperature response and volatilization driving, a dynamic gradient structure of bottom layer small aperture-surface layer large aperture is formed at skin temperature, and directional migration of grease is realized; meanwhile, the surface property transformation of the material after oil absorption is creatively utilized, a hydrophobic membrane is formed on the surface of the polymethyl methacrylate microsphere, a self-enhanced waterproof barrier is constructed, the unique effect that the more oil is absorbed, the more water is resisted is achieved, the problem of makeup removal caused by sebum and sweat can be effectively solved, and the makeup lasting time is remarkably prolonged.

The invention discloses a preparation method and an application method of a catalyst for producing aromatic aldehyde by oxidizing agricultural waste lignin, and belongs to the field of lignin resource utilization. The preparation method of the catalyst for producing aromatic aldehyde through lignin oxidation comprises the following steps: mixing lanthanum salt, B-site metal salt and citric acid in a solvent to obtain a precursor solution; and soaking a polymethyl methacrylate template in the precursor solution, reacting, and calcining to obtain the catalyst for producing aromatic aldehyde by lignin oxidation. The catalyst for producing aromatic aldehyde through lignin oxidation, provided by the invention, has the advantages of low cost, adjustable electronic structure, high oxygen mobility, excellent oxidation-reduction performance and the like, has good catalytic performance, and is suitable for being used as a lignin alkali-free oxidation catalyst. The prepared porous catalytic material with micropores, mesopores and macropores is beneficial to mass transfer of lignin macromolecules and the catalyst, beta-O-4 bonds of lignin can be efficiently broken, and alkali-free oxidation production of value-added aromatic aldehyde chemicals is facilitated.

To provide a composition capable of controlling thermal decomposability of molded articles, and polymers, cured products, and molded articles obtained using this composition, and a method for producing polymethyl methacrylate.SOLUTION: Provided is a composition containing methyl methacrylate, methyl pivalate, and methyl isobutyrate, wherein the concentration of methyl pivalate is more than 0 mass ppm and 50000 mass ppm or less in the composition, and the concentration of methyl isobutyrate is more than 0 mass ppm and 2000 mass ppm or less in the composition. Provided are a polymer, a cured product, and a molded article obtained by employing the composition, and a method for producing polymethyl methacrylate by polymerizing methyl methacrylate in the composition.SELECTED DRAWING: None

The invention relates to the technical field of ceramic materials, in particular to a preparation method of a diatomite-based porous ceramic material and application of the diatomite-based porous ceramic material in wastewater pollutant treatment. The preparation method of the diatomite-based porous ceramic material comprises the following steps: mixing a basic raw material, a sintering aid, a pore forming agent and a binder, performing compression molding to obtain a green body, and sintering the green body, the basic raw materials comprise 80-85% of diatomite, 5-10% of kaolin, 0-5% of feldspar and 5-10% of sodium silicate; the mass of the sintering aid is 5% higher than that of the basic raw material; the mass of the pore-forming agent is 25-45% of that of the basic raw material, and the pore-forming agent is selected from one or more than two of crystalline flake graphite, polymethyl methacrylate and spherical graphite. By controlling the composition and dosage of the basic raw materials, the sintering aid and the pore-forming agent, a micro-nano hierarchical pore structure is formed, mechanical properties and permeability are improved at the same time, and good filtration and interception performance on pollutants in wastewater is achieved.

The invention belongs to the technical field of concrete, and particularly relates to green high-strength concrete and a preparation method thereof.The preparation method comprises the steps that an organic phase-change material with the phase-change temperature being 0-10 DEG C is taken and packaged with a polymethyl methacrylate shell, and organic microcapsules are prepared; taking an inorganic phase-change material with the phase-change temperature of 50-95 DEG C, and packaging the inorganic phase-change material with a urea-formaldehyde resin shell to prepare an inorganic microcapsule; the organic microcapsules and the inorganic microcapsules are mutually combined to form microcapsule pairs; coating the micro-capsule exterior with a silicon dioxide shell to obtain phase change particles; and mixing the phase change particles into the concrete to obtain the high-strength concrete. The green high-strength concrete disclosed by the invention contains two phase change materials with different phase change temperatures, so that heat can be stored during internal temperature rise, and the temperature rise rate in the concrete is effectively reduced; meanwhile, the low temperature of the outer wall needs to be relieved, the freezing damage influence is relieved, the internal and external temperature difference is reduced, caused thermal stress is reduced, and therefore the cracking risk is reduced.

The invention belongs to the field of cosmetics, and discloses a preparation method of a sunscreen synergistic composition, which specifically comprises the following steps: 1, dissolving isostearic acid in a first solvent, adding polymethyl methacrylate into the first solvent, and carrying out ultrasonic or homogeneous dispersion to obtain a mixture; step 2, carrying out solvent removal treatment on the mixture obtained in the step 1; and 3, dissolving trimethylsiloxy silicate ester in a second solvent, adding the product obtained in the step 2 into the second solvent, and uniformly mixing to obtain the sunscreen synergistic composition, the mass ratio of the polymethyl methacrylate to the isostearic acid to the trimethylsiloxy silicate ester is 1: (0.1-0.3): (0.2-0.9). According to the sunscreen synergistic composition prepared by the preparation method disclosed by the invention, the components of the sunscreen synergistic composition can be better compatible, so that the skin feeling of the sunscreen synergistic composition is more velvet, meanwhile, polymethyl methacrylate is firmer and is not easy to migrate or fall off, and the sunscreen effect of the product is favorably improved.

The invention relates to a renewable industrial flue gas carbon dioxide adsorbent and a preparation method thereof. The method comprises the following steps: S1, mixing alkali metal, an aluminum oxide precursor, silicon oxide and a first solvent, or mixing an alkali metal solution, the aluminum oxide precursor, the silicon oxide and an optional second solvent, and then molding the mixed material to obtain microsphere particles; s2, mixing the microsphere particles and organic amine, and carrying out first loading treatment and drying treatment to obtain an organic amine loaded material; s3, roasting the organic amine-loaded material, mixing the obtained roasted material with a carrier material, and carrying out second loading treatment, so as to obtain the carbon dioxide adsorbent, the carrier material is selected from at least one of polystyrene-polyacrylic acid-polyethylene oxide, polymethyl methacrylate-b-polystyrene, zirconium oxide and a porous ceramic material. The carbon dioxide adsorbent is relatively high in adsorption capacity and relatively good in selectivity, reproducibility and stability; and large-scale industrial production and application are facilitated.

The invention relates to a preparation method and application of a black high-transmittance resin composite board, and belongs to the technical field of advertising materials. The resin is formed by compounding a black light-transmitting layer, a light guide layer and a diffusion layer, wherein the high-transmittance layer is prepared by modifying a carboxylated carbon nanotube with a silane coupling agent, polymerizing with a methyl methacrylate monomer, and directionally arranging in a magnetic field, so that high light transmittance and pure black appearance are realized; the light guide layer takes polycarbonate as a matrix, SiO2 microspheres are added, and the light transverse propagation efficiency is improved through hot press molding; the diffusion layer takes polymethyl methacrylate as a matrix, ZnO nanoparticles are added, a periodic microprism structure is processed on the surface, and uniform diffusion of light is realized. When applied to a lamp box, the light source is turned off to present a pure black appearance, and when turned on, the light source has high light transmittance and no mixed color, and is suitable for high-end advertisement display screens, vehicle-mounted lamp boxes and other scenes.

The invention provides a composite acrylic acid low-surface-energy antifouling coating, a preparation method and application, and belongs to the technical field of marine antifouling materials, the composite acrylic acid low-surface-energy antifouling coating comprises a three-layer composite structure, the three-layer composite structure comprises a bottom layer, a middle layer and a surface layer from bottom to top, the bottom layer is capsaicin-loaded polymethyl methacrylate, and the middle layer is a polymethyl methacrylate surface layer. The bottom layer is made of capsaicin, the middle layer is made of pressure-sensitive adhesive activated by oxygen plasma, the surface layer is made of dihydroxyl-terminated polydimethylsiloxane, the mass ratio of the bottom layer to the middle layer to the surface layer is (23-25): 1: (23-25), and the mass content of capsaicin in the bottom layer accounts for 5.82-5.75% of the total mass; based on the bonding strength change of the pressure-sensitive adhesive generated by oxygen plasma jet and the capsaicin for effectively inhibiting biological growth, polyacrylic acid is used as a self-polishing reservoir to continuously release an environment-friendly antifouling agent; the pressure-sensitive adhesive adheres to the polydimethylsiloxane layer through the adhesive force change generated by oxygen plasma to achieve the low-surface-energy antifouling effect, synergistic gain is achieved, the composite material intervenes into the biological fouling process from multiple aspects, and the composite material copes with the marine biological fouling process jointly.

The invention belongs to the technical field of high-molecular compounds, and particularly discloses a method for preparing polymethyl methacrylate (PMMA) based on a bulk polymerization method, which comprises the following steps: S1, taking methyl methacrylate as a monomer, and mixing the monomer with an initiator under the protection of inert gas to form a homogeneous solution; s2, partially polymerizing the homogeneous solution at 60-80 DEG C until the monomer conversion rate reaches 10-30% to obtain a prepolymer; s3, continuing to polymerize the prepolymer at 80-100 DEG C until the monomer conversion rate exceeds 90%; and S4, carrying out devolatilization treatment at 100-120 DEG C under a vacuum condition to obtain PMMA with the molecular weight of more than 100,000. The problems that the polymerization process is not easy to control, the product performance is unstable, the molecular weight distribution is wide and the like in the prior art are solved, and efficient preparation of the PMMA material with high purity, narrow molecular weight distribution and high transparency can be realized.

The invention relates to an alcohol-resistant and heat-resistant PMMA (polymethyl methacrylate) composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The alcohol-resistant and heat-resistant PMMA composite material is prepared from the following components in parts by weight: 30 to 60 parts of acrylonitrile-acrylate-styrene copolymer, 30 to 60 parts of polymethyl methacrylate resin, 1 to 5 parts of compatilizer, 1 to 3 parts of carbon black, 0.1 to 1.5 parts of antioxidant, 0.1 to 2 parts of lubricant, 1 to 5 parts of modified heat-resistant agent and 1 to 3 parts of modified flame retardant, the alcohol-resistant and heat-resistant PMMA composite material prepared by the invention not only has good heat-resistant and aging-resistant effects, but also has an excellent flame-retardant effect.

The invention relates to a preparation method of a water electrolysis hydrogen production composite electrode based on a zwitterionic polymer binder. According to the method, a traditional ionic binder Nafion is replaced with a zwitterionic polymer polysulfobetaine methacrylate, an electrode-electrolyte interface is optimized through a unique electrically neutral hydration layer structure, the rapid desorption behavior of bubbles is enhanced, and efficient transmission of reaction ions is also promoted; and regulating and controlling the mass ratio of the PSBMA binder to the catalyst by using a spraying process. The invention aims to overcome the defects of high cost, insufficient mass transfer and poor interface stability of the existing Nafion binder, and provides the composite electrode taking PSBMA as the binder and the preparation method of the composite electrode, and the provided composite electrode is simple in preparation process and controllable in cost, and has good popularization and application prospects.

The invention relates to the technical field of ceramic antifouling agents, and mainly relates to a high-hardness wear-resistant matte ceramic antifouling agent and a preparation method thereof. The high-hardness wear-resistant matte ceramic antifouling agent is prepared from the following raw materials in parts by weight: 50 to 60 parts of waterborne acrylic resin, 3 to 5 parts of tetraethoxysilane, 0.5 to 1.5 parts of citric acid, 0.1 to 0.5 part of a catalyst, 0.5 to 3 parts of fluorine-containing acrylate, 1 to 10 parts of polymethyl methacrylate microspheres, 20 to 30 parts of water, 1 to 5 parts of titanium dioxide sol and 1 to 5 parts of organic silicon modified polyvinyl alcohol. The organic silicon modified polyvinyl alcohol is obtained by carrying out modification treatment on polyvinyl alcohol by using KH-570. The high-hardness wear-resistant matte ceramic antifouling agent provided by the invention can be used for carrying out good antifouling treatment on the ceramic surface and enhancing the wear resistance.

The invention discloses a high-strength polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-strength polyethylene film. The high-density polyethylene composite material comprises the following raw materials in parts by weight: 40-60 parts of high-density polyethylene, 13-25 parts of low-density polyethylene, 5-10 parts of an ethylene-vinyl alcohol copolymer, 10-15 parts of modified nano calcium carbonate, 3-5 parts of modified lignin fibers, 0.5-1 part of an antioxidant 1010, 0.3-0.7 part of a light stabilizer 770, 1-2 parts of zinc stearate and 2-3 parts of maleic anhydride grafted polyethylene. The coating comprises, by weight, 20-30 parts of polyethylene glycol terephthalate, 3-5 parts of poly (butylene adipate-co-butylene terephthalate), 2-4 parts of talcum powder, 1-3 parts of polymethyl methacrylate and 30-45 parts of deionized water. The high-strength polyethylene film is scientific in raw material ratio, and contains various modified components to enhance the performance; the modified nano calcium carbonate and lignin fiber technology is advanced, and compatibility and stability are improved; the preparation method is reasonable, and the film has the characteristics of high strength, good toughness, oxidation resistance, light resistance and the like and is wide in application through two-way stretching and other procedures.

The application discloses a kind of composite flexible transparent electromagnetic shielding film, including substrate, conductive film layer, MXene layer, protective layer in turn;Conductive film layer, MXene layer is arranged with interval;Substrate is PET polyester film, conductive film layer is silver nanowire, MXene layer is two-dimensional sheet MXene with multilayer structure, and protective layer is made of polymethyl methacrylate.The application further discloses a kind of preparation method of composite flexible transparent electromagnetic shielding film and its application in electronic touch screen.The preparation condition of the application is simple, and operability is strong, by regulating the alternate coating layer of silver nanowire layer and MXene layer, the transmittance and shielding effectiveness of electromagnetic shielding film are adjusted, and the more the layer is, the transmittance and shielding effectiveness are gradually smaller.

The invention belongs to the technical field of electrocatalytic nitrate reduction catalysts, and particularly relates to a graded porous hollow carbon fiber catalyst with synergistic monatomic iron and ferric oxide clusters as well as a preparation method and application of the graded porous hollow carbon fiber catalyst. The preparation method specifically comprises the following steps: stirring polyacrylonitrile and polymethyl methacrylate in an organic solvent to obtain a spinning precursor solution; the preparation method comprises the following steps: taking ferrous sulfate heptahydrate and 1, 10-phenanthroline as ligands, and stirring in an organic solvent to obtain a metal organic ligand; the preparation method comprises the following steps: stirring a spinning precursor solution and a metal organic ligand, obtaining a metal precursor-loaded composite fiber through an electrostatic spinning technology, and then carrying out pre-oxidation and high-temperature pyrolysis to obtain the composite fiber. The prepared carbon fiber has good conductivity and a unique hollow hierarchical porous structure, transmission of reactants is greatly promoted while more active sites are exposed, the carbon fiber serves as a monatomic synergistic cluster catalyst carrier, rapid transmission of electrons is facilitated, and the electro-catalysis efficiency is effectively improved.

The invention is applied to the technical field of oral implant bridges, and particularly discloses a bionic oral implant bridge which comprises a lower abutment, the lower abutment is of an arc-shaped structure and is supported by a carbon fiber reinforced resin matrix composite, an upper abutment is fixedly embedded in the upper surface of the lower abutment, and a lower abutment is fixedly embedded in the lower surface of the upper abutment. The upper abutment is of a blocky structure made of a carbon fiber reinforced resin-based composite material. According to the bionic oral implant bridge, a multi-layer bionic structure composed of the inner supporting layer, the middle filling layer and the outer functional layer is arranged in the outer connecting part connected with the dental crown, the inner supporting layer is composed of the inner supporting part made of metal titanium and the arc-shaped protruding blocks, and the structural strength of the outer connecting part is improved through the inner supporting part; local stress during chewing can be dispersed through the annular distribution design of the protruding blocks made of the titanium material, single-point stress overload of the inner supporting part is avoided, the middle filling layer is made of polymethyl methacrylate, meshing impact force is buffered, and damage to the structure caused by direct transmission of hard force is reduced.

The invention discloses heat-resistant polymethyl methacrylate, a preparation method thereof and an optical film. The heat-resistant polymethyl methacrylate comprises a methyl methacrylate repetitive unit, a glutarimide repetitive unit and an N-methyl methacrylamide repetitive unit, and the sum of the number of the glutarimide constitutional unit and the number of the N-methyl methacrylamide constitutional unit is 1-20 mol% of the total number of the constitutional units. The glutarimide structural unit can be obtained by further cyclization reaction of an N-methyl methacrylamide structural unit, and the cyclization rate can be increased to 80-90% by adding a cyclization accelerator such as triethylamine, so that the thermal stability of the resin is improved, and the water absorption rate is reduced. The material can be used for preparing an optical film, has excellent heat resistance and moisture resistance, and is suitable for the field of optical display.

The invention discloses a modified inorganic filler, which comprises an inorganic filler core and a coating layer coated outside the inorganic filler core, the surface of the inorganic filler core is subjected to graft modification by mercaptoethanol and dodecyl trimethoxysilane, the coating layer comprises a titanium dioxide layer and a polymethyl methacrylate layer; the titanium dioxide layer is coated outside the inorganic filler core; the polymethyl methacrylate layer is grafted outside the titanium dioxide layer. The invention also provides a preparation method of the modified inorganic filler, polyimide wire enamel and a preparation method thereof, and an enameled wire. According to the invention, a modified inorganic filler with a three-layer core-shell structure is designed, and a spherical inorganic filler core is used as a core, so that high doping amount and high corona resistance effect of a filler system in wire enamel are ensured; the introduction of the intermediate TiO2 layer and the introduction of the PMMA outer layer cooperate with the inorganic filler core, so that the corona resistance is improved.

The invention relates to the technical field of new energy automobile power battery thermal management, in particular to a hydrated salt phase change microcapsule for a power battery and a preparation method of the hydrated salt phase change microcapsule. According to the specific technical scheme, hydrated salt serves as a core material, methyl methacrylate serves as a shell material monomer, the monomers are polymerized on the surfaces of hydrated salt liquid drops to form a polymethyl methacrylate shell layer through an interfacial polymerization method, effective packaging of a phase change material (hydrated salt) is achieved, and the microcapsule with high phase change latent heat, low leakage rate and long cycle life is obtained. In addition, other doped auxiliary materials are deposited on an oil-water interface to improve the heat conductivity of the microcapsule. And mixing the microcapsules with heat-conducting oil to prepare suspension liquid, and driving the suspension liquid to circularly flow between the power battery packs by a peristaltic pump. According to the invention, microcapsules and liquid cooling heat dissipation are combined to provide a new thought and practical and effective temperature control and heat dissipation effects for a heat management scheme of the power battery pack.

This invention discloses an ultrafine polyethylene / polyester composite fiber and its preparation method, belonging to the field of composite fiber technology. It solves the problems of poor compatibility between the core and sheath layers, excessive fineness of PE / PET fibers, and difficulties in achieving ultrafine fiber production in existing technologies. The method involves preparing ultrafine polyethylene / polyester composite fibers using a core-sheath composite spinning process. The single filament fineness of the ultrafine polyethylene / polyester composite fiber is 0.6~0.8 dtex. The ultrafine polyethylene / polyester composite fiber has a core-sheath structure, with the sheath material being polyethylene and the core material being a blend of modified polyester and a compatibilizer. The modified polyester molecular chain consists of terephthalic acid segments, ethylene glycol segments, and isophthalic acid segments. The compatibilizer is a graft copolymer of polyethylene and poly(ethylene-co-glycidyl methacrylate)-g-polymethyl methacrylate. The preparation method of this invention is simple and easy to implement, with excellent core-sheath compatibility, which is beneficial for achieving ultrafine fiber production. The composite fiber exhibits excellent performance and can meet the demands of the high-end market.

The invention discloses an ethanol-resistant, spraying-free and high-brightness black ASA / PMMA material and a preparation method thereof. The preparation method of the material comprises the following steps: 1) weighing 50-60% of polymethyl methacrylate resin, 10-20% of styrene-acrylonitrile resin, 0.5-1.5% of an antioxidant and 0.1-0.5% of a lubricant, adding into a high-speed mixer, uniformly mixing, and adding the mixed material into a main feeding port; 2) weighing 20%-30% of acrylonitrile-styrene-acrylate resin, 5%-15% of flexibilizer, 1%-2% of light stabilizer and 1%-2% of toner; and quantitatively adding from a side feeding port of an extruder, and melting, homogenizing, extruding and granulating by the extruder to obtain a final product. The alcohol-resistant, spraying-free and high-brightness black ASA / PMMA resin prepared by the invention has high-brightness black appearance and alcohol resistance, can be used as an outer part without paint spraying, has alcohol resistance, can be used for ornaments which can be in contact with various alcohol-containing cleaning agents, such as bumper decoration strips, rearview mirror shells, grilles, automobile lamp peripheral decoration strips, side skirt ornaments and the like, and has the advantages of simple preparation process and low cost. The material can also be used for shells of electronic and electrical equipment such as kitchen appliances.

The invention relates to the technical field of polymer optical materials, in particular to an optical-grade polymethyl methacrylate material and a preparation method thereof, and the optical-grade polymethyl methacrylate material comprises the following raw materials in parts by weight: 95-105 parts of methyl methacrylate, 200-240 parts of a composite liquid medium, 1.5-2.5 parts of a composite additive and 0.08-0.12 part of an initiator. According to the invention, the composite additive is used as a main material and the composite liquid medium is used as an auxiliary material, so that the heat resistance and the size stability of the material are synergistically improved, powder in the composite additive is uniformly dispersed in a methyl methacrylate matrix to form a compact physical support skeleton, and the powder is matched with a treating agent and a methyl methacrylate molecular chain to form strong chemical bond combination; the composite liquid medium optimizes the flowability of a polymerization system, reduces polymerization internal stress residues, avoids material deformation caused by internal stress release at high temperature, and enhances high-temperature stability.

The application discloses a quinoline small molecule blended modified polymer dielectric material and a preparation method and application thereof, and belongs to the technical field of capacitor films. The preparation raw materials comprise quinoline derivatives, polymethyl methacrylate, styrene-methyl methacrylate copolymer, polyetherimide, polypropylene and N-methyl pyrrolidone solution, and the preparation steps comprise blending and film preparation. The blending solution or eutectic mixture is prepared through blending, and the polymer dielectric film is prepared through a flow casting method or bidirectional stretching. The prepared quinoline small molecule blended modified polymer dielectric film has excellent electrical properties, can reduce the leakage current of the polymer material, has high DC breakdown field strength, high energy storage density and low energy loss, and is easy to realize large-scale production.

The invention relates to a silicon dioxide composite abrasive with a hydrophilic core-shell structure and a preparation method and application of the silicon dioxide composite abrasive in chemical mechanical polishing, the silicon dioxide composite abrasive is composed of SiO2 serving as a core and polymethyl methacrylate wrapping the periphery of the SiO2, the particle size of the SiO2 ranges from 100 nm to 300 nm, and the particle size of the composite abrasive ranges from 200 nm to 350 nm. The preparation method comprises the following steps: preparing SiO2 microspheres by using a template agent and a silicon source through a template method, taking the SiO2 microspheres as an inner core of a core-shell structure, enabling the silicon spheres to be hydrophobic by using a modifier, introducing double bonds through a silane coupling agent, adding MMA and an initiator, adding a PMMA outer layer on the surface of the silicon spheres, and synthesizing the composite abrasive SiO2 coated PMMA with a hydrophilic core-shell structure after hydrophobic modification. Compared with the prior art, the composite abrasive can be used as a chemical polishing solution for chemical polishing of silicon wafers, scratches on the silicon wafers are reduced, and meanwhile the polishing rate and efficiency can be guaranteed.

The invention provides a thermoplastic bistable tube and a preparation method thereof, and belongs to the technical field of high polymer materials. The preparation method of the thermoplastic bistable tube comprises the following steps: mixing PMMA (polymethyl methacrylate) and MMA (methyl methacrylate) monomers to obtain a binary resin solution, and adding an oxidizing agent and a reducing agent into the binary resin solution for secondary mixing to obtain a solution for filling; and compounding the solution for perfusion and the continuous fibers through a vacuum or high-pressure flow guide forming method, and then curing to obtain the thermoplastic bistable-state tube. The PMMA / MMA binary resin mixed solution is adopted, implosion cannot occur, the performance of the composite material cannot be damaged, electric energy does not need to be consumed for heating, the design cost and the machining cost of the composite material mold are reduced, and double cost saving and efficiency increasing are achieved.