917 results about "Lithium hexafluorophosphate" patented technology

The invention discloses an electrolyte solution for a high-capacity lithium-ion battery. The electrolyte solution includes non-aqueous solvent, lithium hexafluorophosphate, negative electrode film forming additive, positive electrode surface activity inhibiting additive and transition metal ion complexant; the negative electrode film forming additive includes organic ester negative electrode film forming additive of 1 to 10wt% of the total electrolyte solution and inorganic lithium salt negative electrode film forming additive of 0.5 to 2wt% of the total electrolyte solution; the positive electrode surface activity inhibiting additive includes fluorinated ether additive of 1 to 5wt% of the total electrolyte solution and nitrile additive of 0.1 to 5wt% of the total electrolyte solution; the transition metal ion complexant is of 0.1 to 1.0wt% of the total electrolyte solution. The electrolyte solution is adaptive to the high-capacity lithium-ion battery and is capable of optimizing the circulating performance and high-temperature storage performance of the lithium-ion battery. The invention further provides a preparation method of the electrolyte solution and the high-capacity lithium-ion battery adopting the electrolyte solution.

The invention relates to a non-aqueous electrolyte for high-voltage lithium ion batteries, which is prepared from the following raw materials in percentage by weight: 70-85% of carbonate, 3-20% of functional additive and 11-17% of lithium hexafluorophosphate. The carbonate is one or mixture of more of ethylene carbonate, propylene carbonate, butylene carbonate, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, methylethyl carbonate, methyl propyl carbonate and methyl butyl carbonate; and the functional additive is one or mixture of more of 0.5-10% of negative pole film-forming additive, 0.5-10% of high-temperature additive, 0.5-10% of positive pole film-forming additive, 0.5-10% of high-voltage additive and 0.001-2% of stability additive. The invention solves the problem of adaptation of the lithium ion battery electrolyte to the 4.35V high-voltage battery positive/negative pole, and provides an electrolyte for high-voltage batteries, which has the advantages of high cycle life, low inflation rate and favorable high-temperature properties.

The invention discloses a high-capacity lithium-ion battery electrolyte of considering high-and-low temperature performance. The electrolyte comprises a non-aqueous solvent, lithium hexafluorophate, a negative film-forming additive, an inflatable inhibition additive and a low-impedance additive, wherein the negative film-forming additive is prepared from fluoroethylene carbonate which accounts for 3%-15% of total mass of the electrolyte; the inflatable inhibition additive is prepared from one or two of 1,3-propene sultone or anhydride compounds which account for 0.3%-5% of total mass of the electrolyte; and the low-impedance additive is prepared from one or two of lithium difluorophosphate and difluoride phosphate lithium oxalate which account for 0.2%-3% of total mass of the electrolyte. The electrolyte is suitable for a high-nickel positive electrode and silicon-carbon composite negative electrode lithium-ion battery; the high-temperature storage performance and the low-temperature discharge performance of the lithium-ion battery are improved while the room-temperature cycle performance is considered; and meanwhile, the invention further provides a preparation method of the electrolyte and the high-capacity lithium-ion battery of using the electrolyte.

A difluorophosphate effective as an additive for a nonaqueous electrolyte for secondary battery is produced by a simple method from inexpensive common materials.

The difluorophosphate is produced by reacting lithium hexafluorophosphate with a carbonate in a nonaqueous solvent. The liquid reaction mixture resulting from this reaction is supplied for providing the difluorophosphate in a nonaqueous electrolyte comprising a nonaqueous solvent which contains at least a hexafluorophosphate as an electrolyte lithium salt and further contains a difluorophosphate. Also provided is a nonaqueous-electrolyte secondary battery employing this nonaqueous electrolyte.

A method of purifying lithium hexafluorosphate that allows to purify lithium hexafluorophosphate, useful as lithium secondary cell electrolyte, organic synthesis medium or the like, to an extremely high purity is provided. Lithium hexafluorophosphate containing harmful impurities such as oxyfluoride, lithium fluoride is purified by adding phosphoric chloride. The purification is performed in the presence of phosphoric chloride and hydrogen fluoride of the quantity equal or superior to the equivalent amount for reacting them, and then by converting lithium fluoride to lithium hexafluorophosphate with generated phosphor pentafluoride.

The invention discloses an all-solid polymer electrolyte, and a preparation method and an application of the all-solid polymer electrolyte, and belongs to the field of lithium ion batteries. The all-solid polymer electrolyte comprises polyethylene oxide, lithium salt, inorganic nano particles and ion liquid, wherein a mass ratio of the lithium salt to polyethylene oxide is 0.1-0.5; the mass sum of the inorganic nano particles and the ion liquid is 10-30% of the mass of the all-solid polymer electrolyte; the lithium salt comprises one or several of bistrifluoromethane sulfonimide lithium salt, lithium tetrafluoroborate, lithium perchlorate, lithium hexafluorophosphate, lithium hexafluoroarsenate, lithium trifluoromethanesulfonate and lithium bis borate; and the inorganic nano particles comprise one or several of nano aluminum oxide, nano silicon oxide, nano zirconium oxide and nano barium titanate. The all-solid polymer electrolyte has better mechanical strength and higher ion conductivity. The method is simple in technology and low in cost; and raw materials are easy to obtain.

The invention discloses a method for comprehensively recycling waste lithium ion batteries, and belongs to the field of recycling of regeneration resource. The method comprises the following steps: a, performing discharging processing on waste lithium ion batteries; b, fragmenting waste lithium ion batteries into sheets with a diameter of 10-20 mm in a closed shearing-type crusher, and spraying during fragmentation to dissolve lithium hexafluorophosphate in the waste lithium ion batteries into a spraying solution; c, peeling carbon powder on the surface of aluminium foils through stirring, dissolving electrolyte into the spraying solution, and recovering carbon powder; d, sending the sheets into a sodium hydroxide solution, peeling lithium cobalt oxide powder on the surface of aluminium foils through stirring, and recovering lithium cobalt oxide powder; e, cleaning the sheets, and recovering lithium cobalt oxide powder; and f, separating and recovering plastic and a copper-aluminium mixture. The method realizes recovery of carbon powder, lithium cobalt oxide powder, the copper-aluminium mixture and plastic through a simple environment-friendly process, and has certain economic benefit and social benefit.

The invention relates to the technical field of lithium ion electrolytes, and in particular relates to a lithium-ion battery electrolyte with both high and low temperature performances. The electrolyte comprises lithium hexafluorophosphate, mixed organic solvents, filming additives, additives for improving the dielectric constant and the low temperature infiltration capability, and a lithium salt type additive, wherein the mixed organic solvents comprise a carbonic ester solvent and a linear carboxylic ester solvent; the linear carboxylic ester solvent in the mixed organic solvents is one or a mixture of more than two of ethyl propionate, propionic acid n-propyl ester, n-propyl acetate, acetic acid n-butyl ester and isobutyl acetate; and the additives for improving the dielectric constant and the low temperature infiltration capability are one or a mixture of more than two of fluoro ethylene carbonate, difluoro ethylene carbonate and 4-trifluoromethyl ethylene carbonate. A battery prepared from the lithium-ion battery electrolyte with both high and low temperature performances is long in service life, and both the good low temperature discharge performance of the battery is ensured, and the storage performance of the battery at the high temperature of 60 DEG C is effectively considered.

The invention discloses a lithium-ion battery with fast charge property, which comprises an anode, a cathode, a diaphragm sandwiched between the anode and the cathode and an organic electrolyte, wherein, sub micrometer lithium titanate is used as the active substance of the cathode; one or several materials of lithium manganate (LiMn2O4), lithium iron phosphate (LiFePO4), lithium nickel cobalt oxide (LiNixCoyMzO2), ternary substance(LiNixMnxCo1-2xO2) are used as active materials of the anode, or a mixture of lithium cobalt (LiCoO2) and one of lithium manganate (LiMn2O4), lithium iron phosphate (LiFePO4), lithium nickel cobalt oxide (LiNixCoyMzO2), ternary substance(LiNixMnxCo1-2xO2) is adopted as the active materials of the anode; lithium hexafluorophosphate (LiPF6) is adopted as the electrolyte, and a multicomponent mixture of ethylene carbonate (EC), dimethylcarbonate(DMC), Ethyl Methyl Carbonate (EMC) is used as a solution. The invention also discloses a preparation method of the lithium-ion battery with fast charged property. The lithium-ion battery of the invention has excellent fast charging and discharging performance.

The invention relates to a preparation method of lithium hexafluorophosphate. The preparation method comprises the following steps of: (1) distilling to obtain hydrogen fluoride liquid of which the purity is over 99.99 weight percent; (2) reacting the high-purity hydrogen fluoride liquid with phosphorus pentachloride to obtain mixed gas of the phosphorus pentafluoride and hydrogen chloride; (3) introducing the mixed gas of the phosphorus pentachloride and the hydrogen chloride into hydrogen fluoride and lithium fluoride, reacting at a certain temperature and under certain pressure to obtain solution of lithium hexafluorophosphate, exhausting hydrogen chloride gas at regular time, and absorbing by using water to prepare byproduct hydrochloric acid; and (4) crystallizing and separating, namely filtering the solution of lithium hexafluorophosphate, delivering filtrate into a crystallizing slot, separating the lithium hexafluorophosphate out at the temperature of between -70 and 80 DEG C, filtering, and performing primary drying and secondary drying to obtain a lithium hexafluorophosphate product, wherein the residual hydrogen fluoride gas is displaced by nitrogen. The preparation method has readily available raw materials and is easy to operate, the purity of the obtained lithium hexafluorophosphate product is over 99.9 percent, the moisture is lower than 10ppm, and the production requirements of lithium ion electrolytic cells are met.

A preparation method of phosphorus pentafluoride gas comprises a step of causing phosphorus pentachloride to react with anhydrous hydrogen fluoride, wherein, the reaction occurs in the presence of a solvent. A preparation method of lithium hexaflourophosphate comprises a contact reaction between solid lithium fluoride and phosphorus pentafluoride gas, wherein the phosphorus pentafluoride gas is prepared by the method of the invention. Compared with the preparation method of the lithium hexaflourophosphate with the phosphorus pentafluoride gas as the raw material in the prior art, the phosphorus pentafluoride gas prepared by the preparation method of the invention has higher purity and lower cost. The yield of the lithium hexaflourophosphate prepared by the method of the invention is higher than 93%, and the purity thereof is up to 99.95%.

The invention provides a ternary positive electrode material lithium ion battery electrolyte, and relates to the technical field of a lithium ion battery. The ternary positive electrode material lithium ion battery electrolyte comprises a carbonate ester organic solvent, a lithium salt and an additive, wherein the lithium salt is lithium hexafluorophate, the lithium hexafluorophate accounts for 12-18% of the total mass of the lithium salt and the carbonate ester organic solvent, and the additive accounts for 5-15% of the total mass of the lithium salt and the carbonate ester organic solvent. The carbonate ester organic solvent is used, so that the solvent is high in solubility of the lithium salt and low in viscosity; and meanwhile, fluoroethylene carbonate is used as a low-temperature additive, the electrolyte is compatible with the electrochemical performance such as capacity and internal resistance, the ternary positive electrode material battery also has excellent cycle property, and the cycle time of the battery under a low-temperature condition is prolonged.

The invention discloses a method for separating and recovering valuable components of waste power lithium batteries. The method is that the waste power lithium batteries are electrified and crushed, the organic solvent is volatilized and recovered, the lithium hexafluorophosphate is innocuously treated, and the light material, the heavy material and the intermediate weight material are sorted by amulti-component screening wind separator. Recovering diaphragm from light material, pyrolyzing intermediate weight material and powder, recovering pyrolysis oil and pyrolysis gas generated from pyrolysis as auxiliary fuel, separating aluminum foil and copper foil by color separation after pyrolysis residue is separated by intelligent kneading and washing machine, and separating shell, pile head and plastic from heavy material. The waste water and waste gas in the whole process of the method are treated centrally, no pollutants are discharged, and the whole component in the waste power lithiumbattery can be recovered efficiently. At the same time, the method fully realizes waste rebenefit, reduces energy consumption, reduces environmental pollution, and the process is simple and applicable to a wide range of batteries.

The invention discloses high voltage electrolyte considering high and low temperature performance and a lithium ion battery using the electrolyte. The high voltage electrolyte comprises a non-aqueous organic solvent, an electrolyte lithium salt, an ether nitrile compound and a low impedance additive, wherein the non-aqueous organic solvent comprises a carbonate solvent and a linear carboxylic acid ester solvent with a wide liquid range; the electrolyte lithium salt is a combination of lithium hexafluorophate and lithium triflurosulfimide according to a molar ratio of 0.01-0.5; and the low impedance additive is a cyclic sulfate compound. The linear carboxylic acid ester solvent for perfecting the electrode/ electrolyte interface is contained in the high voltage electrolyte, by means of the optimized combination of the ether nitrile compound, the lithium triflurosulfimide and the cyclic sulfate compound and other additives, a high voltage battery can be guaranteed to have excellent circulation performance, and meanwhile, the excellent high and low temperature performance of the high voltage battery of storage for 18 h in a full charge state at 85 DEG C and no lithium separation in the full charge state at 0 DEG C is considered.

The invention relates to the technical field of a secondary power (a chargeable battery) which can be reused, in particular to a 26650 type lithium ion battery which is safe and has high capacity and a preparation method thereof. Lithium ferrous phosphate is used as cathode material; graphite materials are adopted as anode materials; mixture of EC (ethylene carbonate), DMC (Di Methyl Carbonate), EMC (methyl ethyl carbonate) (based on volume ratio of 1: 1: 1) is used as electrolyte solution, and LiPF6 (lithium hexafluorophosphate ) with molar ration 1.0 to 1.4 mol/L is adopted as electrolyte; multi-porous PP (polypropylene) and PE (polyethylene) are used as separating membrane, and a metal tank is used as a shell, thus the 26650 type battery is made with the diameter of 26mm and the height of 65mm; the capacity of the battery can reach 3200mAh, the internal resistance is within 30mOmega, and the cycle life thereof is more than 1000 times. The 26650 type lithium ion battery mainly solves the limitation problem of the existing lithium ion battery in the respect of safe and large size, and develops towards large size, has longer service life and higher safety and belongs to an environment protection chemical power with wider application.

The invention discloses a process for the continuous preparation of lithium hexafluorophosphate and a device thereof. The process comprises the following steps that: a fluorine hydride solution A of lithium fluoride and phosphorus pentafluoride or a mixed gas of the phosphorus pentafluoride and other gases are subjected to raw material mixing; the raw material mixture undergoes a multistage synthetic reaction; the product of the multistage synthetic reaction enters a gas-liquid separator to remove unreacted gases; the liquid product of the multistage reaction undergoes a consequent hybrid reaction and the product of the consequent hybrid reaction is reacted with the additionally introduced phosphorus pentafluoride gas B to remove a micro amount of possibly unreacted lithium fluoride in the solution; the product of the reaction is then subjected to evaporation, cooling, crystallization, filtration and drying to form lithium hexafluorophosphate crystal with a purity of 99.9 percent; and a parent solution obtained after separation and crystallization is added with the lithium fluoride to form the raw material solution A for cycle use. The invention adopts a multistage tubular reactor which has excellent mass and heat transfer performance and can realize full gas-liquid contact, continuous material feeding and discharging and the like and consequently realize the continuous operation of a production process.

An electrolyte for rechargeable batteries with a negative electrode of lithium or lithium containing alloys comprising: one or several non-aqueous organic solvents, one or several lithium salts and one or several additives increasing the cycle life of the lithium electrode. The electrolyte solution may comprise one or several solvents selected from the group comprising: tetrahydrofurane, 2-methyltetrahydrofurane, dimethylcarbonate, diethylcarbonate, ethylmethylcarbonate, methylpropylcarbonate, methylpropylpropyonate, ethylpropylpropyonate, methylacetate, ethylacetate, propylacetate, dimetoxyethane, 1,3-dioxalane, diglyme (2-methoxyethil ether), tetraglyme, ethylenecarbonate, propylencarbonate, γ-butyrolactone, and sulfolane. The electrolyte solution may further comprise at least one salt or several salts selected from the group consisting of lithium hexafluorophosphate (LiPF₆), lithium hexafluoroarsenate (LiAsF₆), lithium perchlorate (LiClO₄), lithium sulfonylimid trifluoromethane (LiN(CF₃SO₂)₂)) and lithium trifluorosulfonate (CF₃SO₃Li) or other lithium salts or salts of another alkali metal or a mixture thereof. Also disclosed is an electrochemical cell or battery with an anode of metallic lithium or a lithium-containing alloy, and such an electrolyte.

The invention relates to Li ion battery technique, a lithium hexafluoro- phosphate preparing method, characterized in comprising the process steps of: using easy sublimation property of phosphorus pentachloride, heating and sublimating it to remove nonvolatile components, refining industrial anhydrous hydrogen fluoride to remove water and heavy metal impurities; reacting them with each other to prepare mixed gas of phosphorus pentachloride and hydrogen chloride; leading the mixed gas into anhydrous hydrogen fluoride of lithium fluoride, reacting, crystallizing and separating and drying to obtain pure lithium hexafluoro-phosphate.

The invention discloses a method for preparing difluoro-lithium phosphate and a lithium-ion battery non-aqueous electrolyte.The method includes the steps that under protection of inert gas, an organic solvent serves as a reaction medium, lithium hexafluorophosphate and an ether compound are reacted in a reaction vessel with an inner layer containing a PFA protective layer or a PTFE protective layer, wherein the reacting temperature is 50 DEG C-150 DEG C, and the reacting time is 5 h-20 h; after reaction is finished, a product is filtered and dried to obtain the difluoro-lithium phosphate product.The invention further relates to the lithium-ion battery non-aqueous electrolyte of the difluoro-lithium phosphate prepared with the method.The lithium-ion battery non-aqueous electrolyte comprises 0.5%-2.0% of difluoro-lithium phosphate, 15%-20% of electrolyte salt and 80%-85% of organic solvent.The method for preparing the difluoro-lithium phosphate is easy to operate, mild in condition and convenient to purify, and the high-purity difluoro-lithium phosphate can be obtained.

A nonaqueous electrolyte battery includes a negative electrode composed of a metallic lithium foil and a positive electrode, the negative electrode and the positive electrode being arranged so as to face each other with an ion-conducting medium therebetween. The positive electrode is formed by a method in which a conductive agent and a binder are mixed, and then the mixture is press-formed onto a current collector. The ion-conducting medium contains, in addition to a lithium salt such as lithium hexafluorophosphate, a halogen such as iodine, and a halogen compound (e.g., lithium iodide). Furthermore, the positive electrode may contain a lithium halide.

To provide a method for recovering lithium, that is capable of efficiently recovering lithium without containing impurities, such as phosphorus and fluorine, from a lithium-containing solution containing lithium hexafluorophosphate and separated from a lithium ion battery. In the present invention, alkali hydroxide is added to the lithium-containing solution and the solution is made to have pH 9 or more, a precipitate of a phosphate and a fluoride salt is formed, the formed precipitate is separated and removed, and then lithium is recovered from filtrate.

The invention discloses a resource recycling method for waste lithium batteries. The resource recycling method comprises the following steps: soaking in a solution for discharging, breaking shells and distilling an electrolyte under a vacuum condition or an inert atmosphere protection condition, mechanically smashing, separating current collectors and electrode materials by using difference of density, adding acid to dissolve filtered and separated carbon material, adding base to recycle transition metal elements in cathodes, adding salt to recycle lithium element, and carrying out evaporation-recrystallization to recycle byproducts. The manner that a dry method is combined with a wet chemical technology realizes separation recycling of battery materials, the method is low in invested cost and few in energy consumption, a recycling method for environmentally hazardous lithium hexafluorophate and inflammable carbonic ester is highlighted particularly, and secondary pollution cannot be caused in the recycling process; and moreover, no organic solvent is used in the process, zero emission of waste liquid is realized, and the method is suitable for large-scale recycling production.