1635 results about "Battery electrolyte" patented technology

The invention discloses a preparation method for commercial vanadium battery electrolyte. According to the preparation method, vanadium electrolyte is prepared by one step through a chemical method; the preparation method comprises the following steps: dissolving raw materials containing vanadium by using an alkali; adjusting a pH (Potential of Hydrogen) value by acid-alkali regulation; repeatedly precipitating the vanadium to remove impurity elements; then roasting to obtain an oxide of the vanadium; finally, dissolving the oxide of the vanadium by using concentrated sulfuric acid to obtain the vanadium electrolyte. With the adoption of the method, impurities including iron, chrome, silicon, manganese and the like can be removed effectively and a process flow is shortened; the vanadium yield is improved, the impurity content is reduced and the process flow is shortened; the product purity can also be improved. The preparation method for the commercial vanadium battery electrolyte has important meanings on production technology levels and market competitiveness of the vanadium electrolyte; the method has good economic benefits and social benefits.

A lithium battery with improved safety that utilizes one or more additives in the battery electrolyte solution wherein a lithium salt is dissolved in an organic solvent, which may contain propylene, carbonate. For example, a blend of 2 wt % triphenyl phosphate (TPP), 1 wt % diphenyl monobutyl phosphate (DMP) and 2 wt % vinyl ethylene carbonate additives has been found to significantly enhance the safety and performance of Li-ion batteries using a LiPF₆ salt in EC/DEC electrolyte solvent. The invention relates to both the use of individual additives and to blends of additives such as that shown in the above example at concentrations of 1 to 4-wt % in the lithium battery electrolyte. This invention relates to additives that suppress gas evolution in the cell, passivate graphite electrode and protect it from exfoliating in the presence of propylene carbonate solvents in the electrolyte, and retard flames in the lithium batteries.

The invention relates to a preparation method of a vanadium battery electrolyte solution with high purity and high concentration. The vanadium battery electrolyte solution is different from a traditional vanadium electrolyte solution with vanadium pentoxide as raw material; through the method, a qualified vanadium solution produced by a vanadium factory is adopted as raw material, steps of removing impurities, precipitating vanadium, reducing, extracting and removing oil are carried out, after carrying out processes of four-step impurity removal and one-step reduction, the impurities in the electrolyte solution are effectively removed, and the all-vanadium solution flow battery vanadyl sulfate electrolyte solution with high purity and high concentration and with the concentration of 1-4 M is obtained. The method adopts the initial vanadium solution as the raw material, has the advantages of low cost, simple preparing procedures, and mild reaction conditions, allows the obtained electrolyte solution product to have high purity, and is suitable for application in an all-vanadium solution flow battery.

The invention discloses an electronic cigarette comprising a cigarette-shaped outer shell. A sucking opening is formed in the rear end of the outer shell. A battery and an electronic atomizer are respectively arranged at the front portion inside the outer shell and at the rear portions inside the outer shell, an air stream sensing switch is further arranged in the outer shell, an air stream inlet is formed in the position, corresponding to the air stream sensing switch, of the outer shell, and an absorbing layer and/or a sealing layer preventing battery electrolyte from flowing back are/is arranged between the battery and the electronic atomizer. In the using process, once the battery electrolyte of the battery leaks, the absorbing layer and/or the sealing layer preventing the battery electrolyte from flowing back can absorb or separate leaked battery electrolyte, the battery electrolyte is prevented from flowing back to the electronic atomizer along with air steam and even being sucked by a user, product using safety is guaranteed, and accidents are avoided.

The invention discloses a high-capacity lithium-ion battery electrolyte of considering high-and-low temperature performance. The electrolyte comprises a non-aqueous solvent, lithium hexafluorophate, a negative film-forming additive, an inflatable inhibition additive and a low-impedance additive, wherein the negative film-forming additive is prepared from fluoroethylene carbonate which accounts for 3%-15% of total mass of the electrolyte; the inflatable inhibition additive is prepared from one or two of 1,3-propene sultone or anhydride compounds which account for 0.3%-5% of total mass of the electrolyte; and the low-impedance additive is prepared from one or two of lithium difluorophosphate and difluoride phosphate lithium oxalate which account for 0.2%-3% of total mass of the electrolyte. The electrolyte is suitable for a high-nickel positive electrode and silicon-carbon composite negative electrode lithium-ion battery; the high-temperature storage performance and the low-temperature discharge performance of the lithium-ion battery are improved while the room-temperature cycle performance is considered; and meanwhile, the invention further provides a preparation method of the electrolyte and the high-capacity lithium-ion battery of using the electrolyte.

The present invention relates to a method to produce high concentration full vanadium ion oxidation and reduction liquid flow battery (vanadium battery) electrolyte, which produces 5-6mol/L vanadium battery electrolyte by proportionally adding organic-inorganic compound stabilizing agents. The present invention has the advantages of simple technical method, convenient operation and easy raw material acquisition, produces stable high-concentration vanadium battery electrolyte with excellent electrochemical reversibility and electrical conductivity approximate to conventional 2mol/L electrolyte and realizes battery charge and discharge.

An electrolyte membrane having a porous base material having pores filled with a first polymer capable of conducting a proton, wherein the porous base material comprises at least one second polymer selected from the group consisting of polyimides and polyamides; and a fuel cell, particularly a solid polymer fuel cell, more specifically a direct methanol polymer fuel cell, using the electrolyte membrane. The electrolyte membrane is excellent in the inhibition of permeation of methanol, exhibits no or reduced change in its area, and is excellent in proton conductivity.

The invention provides an electrolyte material (LiaPbScMd) for an all solid-state lithium secondary battery and a preparation method for the electrolyte material. The electrolyte material, shown in a formula (I) LiaPbScMd, for the all solid-state lithium secondary battery is prepared from Li2S, P2S5 and a dopant, wherein the dopant is selected from one or more of compounds of nonmetal elements in main groups III, IV, V, VI and VII of lithium and compounds formed from at least two of the nonmetal elements in the main groups III, IV, V, VI and VII; in the formula (I), M is selected from one or more of the nonmetal elements in the main groups III, IV, V, VI and VII, a is more than 0 and less than or equal to 10, b is more than 0 and less than or equal to 5, c is more than 0 and less than or equal to 15, and d is more than 0 and less than 1. The electrolyte material for the all solid-state lithium secondary battery has high electrical conductivity, high electrochemical stability and the like, and is favorable for application. The invention also provides the all solid-state lithium secondary battery.

A method of purifying lithium hexafluorosphate that allows to purify lithium hexafluorophosphate, useful as lithium secondary cell electrolyte, organic synthesis medium or the like, to an extremely high purity is provided. Lithium hexafluorophosphate containing harmful impurities such as oxyfluoride, lithium fluoride is purified by adding phosphoric chloride. The purification is performed in the presence of phosphoric chloride and hydrogen fluoride of the quantity equal or superior to the equivalent amount for reacting them, and then by converting lithium fluoride to lithium hexafluorophosphate with generated phosphor pentafluoride.

The invention relates to the technical field of battery electrolytes, and in particular discloses a novel electrolyte for a power battery, which comprises the following raw materials in percent by weight: 8-15 percent of conductive lithium salt as a component A, 73-90 percent of organic solvent as a component B and 1-10 percent of additive as a component C. A sulphonate organic compound as the additive is added in the electrolyte of the common lithium ion battery, the addition of the sulphonate organic compound accounts for 1-10 percent of the weight of the electrolyte of the lithium ion power battery and is chemically compounded with 8-15 percent of conductive lithium and 75-90 percent of organic solvent to prepare the novel electrolyte for the power battery, which has better high-temperature circulating performance and is suitable for the power battery. A power battery especially using lithium manganese oxide as a cathode material can prevent Mn smelted at high temperature from being attracted on the surface of the cathode, thereby inhibiting the impedance rise, effectively improving the circulating periodicity and greatly prolonging the circulating service life.

The invention belongs to the technical field of lithium-ion battery electrolytes, and particularly relates to a high-voltage lithium-ion battery electrolyte. The high-voltage lithium-ion battery electrolyte comprises non-aqueous solvents, lithium salt and additives, wherein the additives comprise the mixture of fluoro phosphonitrile, fluoro-ether and unsaturated olefinic sultone. A lithium-ion battery using the high-voltage lithium-ion battery electrolyte is long in cycle life under the high voltage and small in internal resistance change. The high-voltage lithium-ion battery electrolyte is simple in preparing technique, easy to realize, and broad in market prospect.

The invention relates to the technical field of lithium ion electrolytes, and in particular relates to a lithium-ion battery electrolyte with both high and low temperature performances. The electrolyte comprises lithium hexafluorophosphate, mixed organic solvents, filming additives, additives for improving the dielectric constant and the low temperature infiltration capability, and a lithium salt type additive, wherein the mixed organic solvents comprise a carbonic ester solvent and a linear carboxylic ester solvent; the linear carboxylic ester solvent in the mixed organic solvents is one or a mixture of more than two of ethyl propionate, propionic acid n-propyl ester, n-propyl acetate, acetic acid n-butyl ester and isobutyl acetate; and the additives for improving the dielectric constant and the low temperature infiltration capability are one or a mixture of more than two of fluoro ethylene carbonate, difluoro ethylene carbonate and 4-trifluoromethyl ethylene carbonate. A battery prepared from the lithium-ion battery electrolyte with both high and low temperature performances is long in service life, and both the good low temperature discharge performance of the battery is ensured, and the storage performance of the battery at the high temperature of 60 DEG C is effectively considered.

The present invention relates to additives for electrolytes of lithium ion secondary batteries that include one or more of the following: 1,3-propane sultone, succinic anhydride; ethenyl sulfonyl benzene, and halobenzene. It can also include biphenyl, cyclohexylbenzene; and vinylene carbonate. The weight of said 1,3-propane sultone is between 0.5 wt. % and 96.4 wt. %, said succinic anhydride is between 0.5 wt. % and 96.4 wt. %; said ethenyl sulfonyl benzene is between 0.5 wt. % and 95.2 wt. %; and said halobenzene is between 0.5 wt. % and 95.2 wt. % of the weight of the additive. Batteries with electrolytes containing said additives have improved over-charge characteristics and low temperature properties, and reduced gas generation during charging and discharging.

Electrolyte compositions for batteries such as lithium ion and lithium air batteries are described. In some embodiments the compositions are liquid compositions comprising (a) a homogeneous solvent system, said solvent system comprising a perfluropolyether (PFPE) and polyethylene oxide (PEO); and (b) an alkali metal salt dissolved in said solvent system. In other embodiments the compositions are solid electrolyte compositions comprising: (a) a solid polymer, said polymer comprising a crosslinked product of a crosslinkable perfluropolyether (PFPE) and a crosslinkable polyethylene oxide (PEO); and (b) an alkali metal ion salt dissolved in said polymer. Batteries containing such compositions as electrolytes are also described.

The invention discloses polymer electrolyte and a preparation method and application thereof. The provided polymer electrolyte consists of a high polymer matrix, lithium salt, an organic small molecular plasticizer and/or inorganic superfine nanoparticles. The provided polymer electrolyte has high ionic conductivity, high toughness and high-temperature resistance, and when the polymer electrolyte is used as lithium ion secondary battery electrolyte, the structure of a commercial lithium ion secondary battery is simplified, the structure of the lithium ion secondary battery is enriched, and simultaneously the potential safety hazard in the traditional lithium ion secondary battery can be effectively avoided. Meanwhile, in the process of preparing a lithium battery from the provided polymer electrolyte, the conventional commercial micron-sized graphite anode can be replaced by a metal lithium foil, so the prepared novel lithium ion battery has higher energy density and power density.

The invention generally encompasses phosphonium ionic liquids and compositions and their use in many applications, including but not limited to: as electrolytes in electronic devices such as memory devices including static, permanent and dynamic random access memory, as battery electrolytes, as a heat transfer medium, fuel cells and electrochromatic devices, among other applications. In particular, the invention generally relates to phosphonium ionic liquids, compositions and molecules possessing structural features, wherein the molecules exhibit superior combination of thermodynamic stability, low volatility, wide liquidus range and ionic conductivity. The invention further encompasses methods of making such phosphonium ionic liquids, compositions and molecules, and operational devices and systems comprising the same.

The invention discloses a battery electrolyte additive and electrolyte which give consideration to high and low temperature properties as well as a nickelic ternary lithium ion battery. The additive disclosed by the invention contains a fluorine-containing phenyl sulfonate type compound additive A with a structure shown in a formula I, an annular sulfonate type additive B with a structure shown ina formula II and the conventional anode film formation additives, and the battery electrolyte giving consideration to high and low temperature properties comprises electrolyte lithium salt, a nonaqueous organic solvent and the additive disclosed by the invention. The electrolyte disclosed by the invention can effectively improve performance of a nickelic ternary lithium ion power battery by virtue of synergistic effect produced by joint use of the three kinds of additives and by combining the advantages of electrolyte additives of different components and respectively has good electrochemicalperformances such as cycle performance, rate capability, storage performance and safety performance under high temperature and low temperature conditions, so that the problem that an existing batterycan not give consideration to high and low temperature properties is solved.

The invention relates to a method for electrolyte-injecting a battery, which comprises the steps that: a battery shell is vacuumized; then non-aqueous electrolyte is injected into the battery shell by a filling machine; after a first electrolyte-injection is finished, the electrolyte content of the first electrolyte-injection is above 60 percent of the total weight of the electrolyte injected; the battery shell is sealed to carry out centrifugal sinking; then the seal is taken to vacuumize; a second electrolyte-injection is carried out; the electrolyte content of the second electrolyte-injection is the content which injects the battery shell full. By using the method of the second electrolyte injection, the invention largely enhances the electrolyte injection volume, which enhances by 15 percent-25 percent of the electrolyte injection volume compared with the prior art.

A modified vanadium compound characterized in that vanadium sulfate (III), or a mixed vanadium compound of vanadium sulfate (III) and vanadyl sulfate (IV) contains excessive sulfuric acid other than sulfate group composing the vanadium sulfate (III) or the vanadyl sulfate (IV), and when the modified vanadium compound is used, a redox flow battery electrolyte can be prepared easily.

The invention relates to the technical field of lithium ion batteries, and particularly discloses a high-temperature high-voltage safety lithium ion battery electrolyte and a lithium ion battery. Thelithium ion battery electrolyte comprises a lithium salt, a non-aqueous organic solvent and an additive, wherein the additive includes an isocyanate additive, a film forming additive and a fluorinatedflame-retardant additive. According to the lithium ion battery electrolyte, by adding the first type of the isocyanate additive and the second type of the film forming additive, a stable SEI film canbe formed on the surface of an electrode material, so that the ion conduction can be facilitated, and the decomposition of the electrolyte can be inhibited; and by adding the third type of the fluorinated flame-retardant additive, F atoms can form a film on an electrode interface, so that the intermolecular force can be reduced, the viscosity of the electrolyte can be reduced, and the conductivity of the electrolyte can be improved. All the components cooperate, so that the battery has good high-temperature storage performance, normal temperature cycling performance and high-temperature cycling performance under a high voltage, and does not have potential safety hazards.