98results about How to "Suppress gas production" patented technology

The present invention provides: (i) a nonaqueous electrolyte for batteries, which is characterized by containing halogen; (ii) a nonaqueous electrolyte for batteries, which is characterized by containing pyrrol or its derivative and halogen; and (iii) a lithium secondary battery which is characterized by including the nonaqueous electrolyte (i) or (ii). The inventive lithium secondary battery has improvements in charge / discharge and cycle life characteristics at ambient and high temperatures, and / or storage characteristics and safety at high temperature.

An electrolyte for a lithium secondary battery which has a non-aqueous organic solvent including a γ-butyrolactone and optionally a cyclic carbonate, an ester compound having an electron withdrawing group, and at least two salts. The lithium secondary battery including the electrolyte has good safety and good storage characteristics at high temperature.

An object is to provide a non-aqueous electrolyte solution that can improve the capacity deterioration and gas generation associated with the high-temperature storage of non-aqueous electrolyte batteries. A further object is to provide a non-aqueous electrolyte battery that uses this non-aqueous electrolyte solution. These objects can be achieved by using a non-aqueous electrolyte solution that incorporates, in prescribed contents, (A) a compound having at least two isocyanate groups per molecule and a compound having at least two cyano groups per molecule.

Disclosed is a glass laminate comprising a thin glass substrate having a first main surface and a second main surface, a supporting glass substrate having a first main surface and a second main surface, and a resin layer and an outer frame layer arranged between the thin glass substrate and the supporting glass substrate. The resin layer is fixed to the first main surface of the supporting glass substrate and is in close contact with the first main surface of the thin glass substrate, while having easy releasability from the first main surface of the thin glass substrate. The outer frame layer surrounds the resin layer on the first main surface of the supporting glass substrate so that the outside air does not come into contact with the resin layer.

A nonaqueous electrolyte secondary battery includes an electrode group having a positive electrode and a negative electrode wound flatly by way of an interposed separator, a positive electrode tab electrically connected to the positive electrode, and projecting from a spiral winding surface of the electrode group, a negative electrode tab electrically connected to the negative electrode, and projecting from the spiral winding surface, and a nonaqueous electrolyte, wherein the nonaqueous solvent contains sultone compound including a ring having at least one double bond, and a distance between the positive electrode tab and the negative electrode tab is 6 mm to 18 mm.

A method for producing an LPG fraction, a gasoline fraction, a kerosene fraction, a gas oil fraction, monocyclic aromatic hydrocarbon and a non-aromatic naphtha fraction from hydrocracked oil includes hydrocracking hydrocarbon oil containing polycyclic aromatic hydrocarbon to convert into a light hydrocarbon fraction, and efficiently and selectively producing monocyclic aromatic hydrocarbon with higher valuable alkylbenzenes. The method for producing hydrocarbon fraction comprises subjecting hydrocarbon feedstock containing polycyclic aromatic hydrocarbon and in which the ratio of carbons constituting an aromatic ring to the total carbons in the hydrocarbon oil (the aromatic ring-constituting carbon ratio) is 35 mole % or more to catalytic cracking in the presence of hydrogen. 40% or more of a fraction with a boiling point of 215° C. or higher in the hydrocarbon feedstock is converted into a fraction with a boiling point lower than 215° C., producing hydrocracked oil containing 30 vol % or more of monocyclic aromatic hydrocarbon.

A negative electrode active material particle and a method for preparing the same are provided. The negative electrode active material particle includes SiOx (0<x≦2) and Li2Si2O5, and includes less than 2 wt % of Li2SiO3 and Li4SiO4.

An electrode active material further comprising an amphoteric compound, an alkali metal sulfide or an alkali metal oxide, and lithium secondary batteries using the electrode active material, are disclosed. The lithium secondary batteries neutralize acids generating around electrode active material so that it can inhibit the reduction in battery capacity. In addition, the lithium secondary batteries are excellent in its charge-discharge characteristics, cycle life and thermal stability. A method for preparing the electrode active material for lithium secondary batteries is also provided.

The present invention relates to high-purity zirconium or hafnium with minimal impurities, particularly where the content of alkali metal elements such as Na, K; radioactive elements such as U, Th; transitional metals or heavy metals or high melting point metal elements such as Fe, Ni, Co, Cr, Cu, Mo, Ta, V; and gas components such as C, O, etc. is extremely reduced, as well as to an inexpensive manufacturing method of such high-purity zirconium or hafnium, thereby reducing the impurities hindering the guarantee of the operational performance of semiconductors. The present invention further relates to an inexpensive and safe manufacturing method of high-purity zirconium or hafnium powder from hydrogenated high-purity zirconium or hafnium powder.

Disclosed are a positive active material for a rechargeable lithium battery including a nickel-containing lithium transition metal composite oxide and a coating layer positioned on the surface of the lithium transition metal composite oxide, wherein the coating layer includes vanadium oxide, lithium vanadium oxide, or a combination thereof, a method of manufacturing the same, and a rechargeable lithium battery including the same.

Crystalline polyglycolic acid wherein a difference between the melting point Tm and the crystallization temperature Tc2 is not lower than 35° C., and a difference between the crystallization temperature Tc1 and the glass transition temperature Tg is not lower than 40° C. A production process of polyglycolic acid modified in crystallinity, comprising applying heat history to crystalline polyglycolic acid at a temperature of not lower than (the melting point Tm of the crystalline polyglycolic acid+38° C.). A polyglycolic acid composition comprising crystalline polyglycolic acid and a heat stabilizer, wherein a difference (T2-T1) between the temperature T2 at 3%-weight loss on heating of the polyglycolic acid composition and the temperature T1 at 3%-weight loss on heating of the crystalline polyglycolic acid is not lower than 5° C.

An ultrasonic flow meter is equipped with a housing through which a liquid flows, and a pair of detection units disposed on opposite ends of the housing and including acoustic wave transmitting and receiving units capable of transmitting and receiving acoustic wave signals. Paired connecting plugs are connected respectively to both ends of the housing. In addition, a supply passage of one of the connecting plugs, a conduit of the housing, and a discharge passage of another of the connecting plugs are disposed on a straight line. A liquid supplied to the supply passage flows through a passage of the conduit and to the discharge passage. Consequently, a flow rate of the liquid is measured based on the propagation time of the acoustic wave signals, which are transmitted and received by the acoustic wave transmitting and receiving units.

The present invention provides a highly-reliable non-aqueous electrolyte secondary battery excellent in safety. The non-aqueous electrolyte secondary battery includes an electrode group, a non-aqueous electrolyte and a case accommodating the electrode group and the non-aqueous electrolyte. The non-aqueous electrolyte contains a specific bromine compound having an aromatic ring.

The present invention provides a liquid crystalline polyester composition comprising a terphenyl and a liquid crystalline polyester, wherein the terphenyl substantially consists of p-terphenyl, and the p-terphenyl is contained in the composition in the amount of 0.3 to 15 parts by weight on the basis of 100 parts by weight of the liquid crystalline polyester. The liquid crystalline polyester composition has high flowability and low anisotropy, which can also suppress generation of gases when molded.

A double layer capacitor comprises a positive electrode, a negative electrode made of an activated carbon, a separator provided between a positive electrode and a negative electrode, and a nonaqueous electrolysis solution. The positive electrode comprises an alkaline metal complex oxide or an alkaline earth metal complex oxide contained in the activated carbon in a range of from 5 to 40 wt %, and the electrolysis solution comprises an alkaline metal ion or an alkaline earth metal ion in a range of not more than 0.085 mol / l.

In a nonaqueous electrolyte secondary battery including a positive electrode, a negative electrode and a nonaqueous electrolytic solution, the nonaqueous electrolytic solution contains a nitrile compound having a chain saturated hydrocarbon group and a nitrile group, the number of carbon atoms in the nitrile compound is four or more, and the positive electrode contains a positive-electrode active material on the surface of which particles of a rare earth element compound are deposited in dispersed form.

In an electric double-layer capacitor, resistance of a polarizable electrode layer is reduced and gas generation inside a case is suppressed in an attempt to improve reliability. On that account, an electric double-layer capacitor is provided, which is obtained by housing in a case, together with a driving electrolyte, a capacitor element wound with a separator interposed between electrodes being paired anode and cathode electrodes in each of which polarizable electrode layers are formed on and lead wires are fixed to both sides of a current collector made of metallic foil, such that the polarizable electrode layers are opposed to each other. Further, an electric double-layer capacitor is provided in which the lead wire is fixed to a polarizable-electrode-layer-removed section on the electrode where the polarizable electrode layer has been removed, and an area of the polarizable-electrode-layer-removed section is not smaller than 1 and not larger than 2.0 when a project area of a portion where the lead wire is connected with the current collector is set to 1.

Disclosed is a non-aqueous electrolyte secondary battery including a positive electrode including a lithium-containing transition metal composite oxide as a positive electrode active material, a negative electrode including a negative electrode active material, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The positive electrode contains lithium carbonate and lithium hydrogencarbonate in a total amount of 500 ppm or more and 3000 ppm or less, and exhibits a weight loss by temperature increase from 25° C. to 300° C. at 5° C. / min of 70% or less of the total amount and of 1500 ppm or less. The non-aqueous electrolyte includes a non-aqueous solvent and a lithium salt. The non-aqueous solvent may contain a cyclic carbonate and a chain carbonate.

The invention provides lithium-ion battery electrolyte and a lithium-ion battery containing the same. The electrolyte comprises solvent, electrolyte lithium salt and a mixture additive which comprisesa compound A, a compound B and a compound C, wherein R1 in the compound A is straight-chain paraffin of CnH2n+1, and n is more than or equal to 0 and less than or equal to 3; X in the compound B is selected from one of F and Cl; R2 is the straight-chain paraffin of the CnH2n+1, and n is more than or equal to 0 and less than or equal to 3; R3 is straight-chain paraffin of -CnH2n and n is more thanor equal to 1 and less than or equal to 4; R4 is straight-chain paraffin of -CnH2n+1-a Ya, and n is more than or equal to 1 and less than or equal to 4; R5 is -CnH(2n+1-b)Zb, and n is more than or equal to 0 and less than or equal to 3; Y and Z are selected from one of F and Cl; a and b are more than or equal to 0 but are not 0 simultaneously; and the compound C is selected from at least one of glycol sulfite, 1,3-propane sultone and trimethylene sulfite. The electrolyte can greatly improve the safety performance of the lithium-ion battery.

An ultrasonic flow meter is equipped with a housing through which a liquid flows, and a pair of detection units disposed on opposite ends of the housing and including acoustic wave transmitting and receiving units capable of transmitting and receiving acoustic wave signals. Paired connecting plugs are connected respectively to both ends of the housing. In addition, a supply passage of one of the connecting plugs, a conduit of the housing, and a discharge passage of another of the connecting plugs are disposed on a straight line. A liquid supplied to the supply passage flows through a passage of the conduit and to the discharge passage. Consequently, a flow rate of the liquid is measured based on the propagation time of the acoustic wave signals, which are transmitted and received by the acoustic wave transmitting and receiving units.

To provide a cathode active material for a lithium secondary battery, which is low in gas generation and has high safety and excellent durability for charge and discharge cycles even at a high charge voltage. A process for producing a lithium-containing composite oxide represented by the formula LipLqNxMyOzFa (wherein L is at least one element selected from the group of B and P, N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than N, 0.9≦p≦1.1, 1.0≦q<0.03, 0.97≦x<1.00, 0≦y≦0.03, 1.9≦z≦2.1, q+x+y=1 and 0≦a≦0.02), wherein a lithium-containing composite oxide powder containing an N element and, if necessary, an M element and fluorine, is preliminarily prepared; the lithium-containing composite oxide powder is mixed with an aqueous solution containing the L element source; from the obtained mixture, an aqueous medium is removed, followed by the firing in an oxygen-containing atmosphere at from 300 to 1,050° C.

An object is to provide a non-aqueous electrolyte solution that can improve the capacity deterioration and gas generation associated with the high-temperature storage of non-aqueous electrolyte batteries. A further object is to provide a non-aqueous electrolyte battery that uses this non-aqueous electrolyte solution. These objects can be achieved by using a non-aqueous electrolyte solution that incorporates, in prescribed contents, (A) a compound having at least two isocyanate groups per molecule and a compound having at least two cyano groups per molecule.

The present invention has an objective to improve the storage characteristics and pulse discharge characteristics, especially in the high temperature region of 100° C. or more, of a lithium battery comprising a positive electrode including manganese oxide, a negative electrode, and a non-aqueous electrolyte. To achieve this objective, the lithium battery of the present invention includes a positive electrode (3) including manganese oxide in mixed crystal state, a negative electrode (4) desorbing lithium ions during discharging, and a non-aqueous electrolyte having lithium ion conductivity. The aforementioned manganese oxide in mixed crystal state includes at least λ-type manganese oxide and β-type manganese oxide. The aforementioned non-aqueous electrolyte includes at least one additive selected from the group consisting of cyclic sultone compounds and sulfone compounds.

To provide a photomask capable of preventing a foreign matter generation in using the photomask, and an exposure method using this photomask. The photomask includes a transparent substrate 2; a transfer pattern 4 formed in a main region 3 of a center portion of the transparent substrate 2; a light-shading band region 5 provided adjacent to the main region 3 in the outer peripheral region of the main region 3; and a pellicle 6 formed by adhering a pellicle film 6a to a pellicle frame 6b by an adhesive 8a, wherein this pellicle 6 is adhered onto a light-shading region 7 consisting of a light-shading film formed in the outer peripheral region of the main region 3, through an adhesive 8b.

A positive electrode active material of a nonaqueous electrolyte secondary battery is composed of lithium-cobalt composite oxide containing at least one of zirconium, titanium, aluminum, and erbium, and the nonaqueous electrolyte includes an additive expressed by General Formula (1) having an acetylene group and a methylsulfonyl group at each end of the molecule. It has the effect of forming an SEI surface film as with the case of VC or the like, as well as having a higher oxidation resistance than that of VC or the like. Thus the nonaqueous electrolyte secondary battery employing as positive electrode active material a lithium-cobalt composite oxide with a particular dissimilar metallic element added, in which decomposition of the nonaqueous electrolytic solution during storage at high temperature in a charged state is suppressed, and there is little battery swelling is provided.

An additive for a non-aqueous electrolyte solution including a compound represented by the following formula (A1) or (A2).In the formula, Xa represents a group that forms a cyclic group together with a nitrogen atom, Za1 and Za2, Za1 and Za2 each independently represent a sulfonyl or carbonyl group, Ra1 represents an optionally substituted alkylene group of 1 to 4 carbon atoms, an alkenylene group of 3 or 4 carbon atoms or an alkynylene group of 3 or 4 carbon atoms, Ra2 represents a hydrogen atom, a halogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, Ra3 represents oxygen or an optionally substituted alkylene group of 1 to 4 carbon atoms, alkenylene group of 3 or 4 carbon atoms or alkynylene group of 3 or 4 carbon atoms.

In an electric double-layer capacitor, resistance of a polarizable electrode layer is reduced and gas generation inside a case is suppressed in an attempt to improve reliability. On that account, an electric double-layer capacitor is provided, which is obtained by housing in a case, together with a driving electrolyte, a capacitor element wound with a separator interposed between electrodes being paired anode and cathode electrodes in each of which polarizable electrode layers are formed on and lead wires are fixed to both sides of a current collector made of metallic foil, such that the polarizable electrode layers are opposed to each other. Further, an electric double-layer capacitor is provided in which the lead wire is fixed to a polarizable-electrode-layer-removed section on the electrode where the polarizable electrode layer has been removed, and an area of the polarizable-electrode-layer-removed section is not smaller than 1 and not larger than 2.0 when a project area of a portion where the lead wire is connected with the current collector is set to 1.

The lithium-ion secondary battery in which a positive electrode contains Lia(M)b(PO4)cFd (M=VO or V, 0.9≦a≦3.3, 0.9≦b≦2.2, 0.9≦c≦3.3, 0≦d≦2.0) as an active material and 1 to 300 ppm of sulfur is used.