2569 results about "Polycyclic aromatic hydrocarbon" patented technology

Disclosed is a novel compound of Formula 1 and an organic electroluminescent device using the same. In Formula 1, X and Y independently represents a hydrogen, an aromatic or a hetero aromatic hydrocarbon having C5 to C10 carbons; X and Y may be the same or different; Ar₁ to Ar₂ each represent a hydrogen, an unsubstituted or substituted aromatic hydrocarbon having C4 to C12 carbons, or an unsubstituted or substituted condensed polycyclic aromatic hydrocarbon having C4 to C12 carbons; Ar₁ to Ar₂ can form a fused aromatic ring system with the adjacent aromatic hydrocarbons. The compound of Formula 1 is present in the electron injection or a transport material, or an exciton blocking layer in the organic light emitting device, and thereby improving the device stability, lowering the operational voltage.

An OLED device including a cathode, an anode, one or more light-emitting layers disposed between the anode and cathode to produce white light and a layer disposed between the light-emitting layer(s) and the cathode. The layer includes a polycyclic aromatic hydrocarbon compound that has the lowest LUMO value of the compounds in the layer, in an amount greater than or equal to 10% by volume and less than 100% by volume of the layer; at least one second compound exhibiting a higher LUMO value than the polycyclic aromatic hydrocarbon compound, where at least one of the second compounds is a low voltage electron-transporting material, and the total amount of such second compounds(s) is less than or equal to 90% by volume of the layer; and a metallic material based on a metal having a work function less than 4.2 eV.

A method for extracting a polycyclic aromatic hydrocarbon from a material such as tobacco or tobacco extracts or other materials comprises treating the material with a molecularly imprinted polymer selective for the hydrocarbon in the presence of a low polarity medium.

The invention discloses a method for biologically remediating a water body and soil comprehensively utilizing resources. The method comprises the steps: (1), determining main pollutants in a selected land area or water body area; (2), selecting to plant and/or cultivate fast-growing herbaceous plants, fast-growing alga, trees, bushes, fungi or microorganisms with high remediation efficiency in the selected land area or water body area; (3), harvesting or collecting the fast-growing herbaceous plants and the fast-growing alga after growing to reach a suitable height or size; (4), concentratedly processing the harvested or collected fast-growing herbaceous plants and the fast-growing alga, and comprehensively utilizing to prevent the pollutants from dispersing; (5), remediating an eutrophic water body by adopting an artificial floating island; (6), remediating a heavy metal polluted water body by confining floating plants; (7), repairing cadmium and zinc polluted soil by mixed-cropping festuca arundinacea and bluegrass; (8), remediating polycyclic aromatic hydrocarbons (PAHs) polluted soil by mixed-cropping alfalfa and italian ryegrass; and (9), extracting and recovering silver from silver-containing wastewater remediation plants.

The invention discloses an environmentally friendly biochar-based fertilizer and an application method thereof. The preparation of the biochar-based fertilizer comprises the following steps of: drying and crushing forestry and agricultural residues, then performing oxygen limited pyrolysis on the crushed materials for 1-5 hours at 300 to 700 DEG C, and sieving, thereby obtaining biochar; and after the biochar is fixed with persistent organic pollutant degrading bacteria, mixing the biochar with a fertilizer, stirring the two thoroughly, and adding a binder accounting for 1wt%-4wt% of the total weight, thus obtaining the environmentally friendly biochar-based fertilizer. For application, the prepared environmentally friendly biochar-based fertilizer is applied to soil by 100-1000 kg per hectare; the surface layer of soil, to which the biochar-based fertilizer is applied previously, is turned over by 0-20 cm, so that the biochar-based fertilizer is mixed with the soil thoroughly, and then the soil can be used for planting crops. The environmentally friendly biochar-based fertilizer provided by the invention overcomes the shortcoming that present biochar-based fertilizers contain organic pollutants such as polycyclic aromatic hydrocarbon, the influence of the fertilizer on soil and environment is alleviated, and the safety risk of agricultural products is reduced; moreover, the environmentally friendly biochar-based fertilizer has the advantages of simple and practicable preparation process, low cost and the like.

The invention discloses slow-release fertilizer with the effect of soil remediation, which is prepared by polyhydroxyalkanoates which can be completely biodegraded, organic and inorganic nutrients and other substances, by slow-releasing the organic and inorganic nutrients, microorganism propagation and sustained and rapid growth of plants can be promoted, the bioactivity and water solubility of polycyclic aromatic hydrocarbons are quickened, and simultaneously, the defects of fertilizer loss and repeated fertilization can be avoided, thereby saving the cost and enhancing the soil remediation efficiency. The invention also discloses a soil pollution remediation method by utilizing the slow-release fertilizer, plants with the remediation effect are planted in the soil with the slow-release fertilizer, and efficient, environment-friendly and sustained remediation of the soil polluted by the polycyclic aromatic hydrocarbons (PAHs) can be realized by utilizing the microorganism-plant remediation technology.

The invention provides a catalytic conversion method for producing gasoline containing rich aromatic hydrocarbon. The catalytic conversion method comprises the following steps: cutting catalytic cracking light cycle oil to obtain a light fraction and a heavy fraction, performing hydrogenation treatment on the heavy fraction to obtain a hydrogenated heavy fraction, singly and respectively conveying the light fraction and the heavy fraction into different riser reactors of catalytic cracking devices, performing a cracking reaction in the presence of a catalytic cracking catalyst, and separating reaction products to obtain a product containing the gasoline which contains rich aromatic hydrocarbon and the light cycle oil. According to the method, single catalytic cracking devices are used for processing the light fraction and the hydrogenated heavy fraction of the light cycle oil to satisfy harsh conditions necessary for the catalytic cracking reaction of different fractions of the light cycle oil to the maximum, so as to produce catalytic gasoline containing rich benzene, toluene and xylene to the maximum.

The invention relates to a composite fiber. The composite fiber comprises a fiber carrier, and a graphene aerogel layer covering the outer side of the fiber carrier. According to the composite fiber provided by the invention, the relatively thin graphene aerogel layer covers the surface of the composite fiber, and a self surface shielding effect of existing graphene aerogel is overcome; the adsorption speed and adsorption efficiency of the graphene aerogel of the unit volume are improved; the fiber carrier of the composite fiber provided by the invention provides a bracket for the graphene aerogel and the mechanical strength is enhanced; when the composite fiber is used as an adsorption material, the composite fiber can be in seamless butt joint with an existing cigarette production process directly, and replaces an existing adsorption fiber so that the specific adsorption on benzopyrene polycyclic aromatic hydrocarbon type harmful substances can be realized; and meanwhile, other aromatic substances in smoke are kept so that the flavor and aroma of cigarettes are not influenced.

The invention discloses a water soluble copolymer with high viscosity and salt resistance, and a preparation method and an application thereof. The preparation method comprises the steps of: adding acrylamide 20 weight parts, an anionic monomer or/and a cationic monomer 0.1-15 weight parts,, a vinyl polycyclic aromatic hydrocarbon 0.05-4 weight parts,, a surfactant 0.5-90 weight parts,, and deionized water 70-900 weight parts, into a three-neck reaction bottle, adjusting the solution pH to 2.5-9, introducing N2 for 30min, adding an initiator persulfate 0.001-0.2 weight parts, at 20-70DEG C, and reacting for 6-36 hours to obtain a low-molecular weight water soluble copolymer with molecular association ability, high viscosity and salt resistance, which can be used in intermediate-permeability oil reservoir and low-permeability oil reservoir development. An associated water soluble polymer oil displacement agent is obtained by preparing the copolymer into an aqueous solution with copolymer concentration of 0.3-3 g/L and surfactant concentration of 0.01-4 mmol/L, adding into a mixer with a stirring device, and stirring uniformly at room temperature; and the obtained oil displacement agent has high viscosity, salt resistance, temperature resistance and shear resistance, and can be used in intermediate-permeability oil reservoir and the low-permeability oil reservoir development.

The invention relates to an organic material and an organic light-emitting device containing the material. The structural formula of the material is shown in the right, wherein, Ar is chosen from sub-polycyclic aromatic hydrocarbon with 6-30 of carbon atoms or is chosen from sub-fused heterocyclic aromatic hydrocarbon with 6-30 of carbon atoms; R1-R8 are respectively and independently chosen from alkyl with 1-4 of hydrogen atoms and carbon atoms, aromatic group with 6-24 carbon atoms, heterocyclic aryl with 6-24 carbon atoms; and n is chosen from integers of 2 to 4. The organic material can be used as electronic transmission matrix in the organic light-emitting device.

A method for producing an LPG fraction, a gasoline fraction, a kerosene fraction, a gas oil fraction, monocyclic aromatic hydrocarbon and a non-aromatic naphtha fraction from hydrocracked oil includes hydrocracking hydrocarbon oil containing polycyclic aromatic hydrocarbon to convert into a light hydrocarbon fraction, and efficiently and selectively producing monocyclic aromatic hydrocarbon with higher valuable alkylbenzenes. The method for producing hydrocarbon fraction comprises subjecting hydrocarbon feedstock containing polycyclic aromatic hydrocarbon and in which the ratio of carbons constituting an aromatic ring to the total carbons in the hydrocarbon oil (the aromatic ring-constituting carbon ratio) is 35 mole % or more to catalytic cracking in the presence of hydrogen. 40% or more of a fraction with a boiling point of 215° C. or higher in the hydrocarbon feedstock is converted into a fraction with a boiling point lower than 215° C., producing hydrocracked oil containing 30 vol % or more of monocyclic aromatic hydrocarbon.

The invention discloses a method for producing light aromatic hydrocarbons and high-quality oil products from catalytically cracked diesel. The method comprises the following steps of 1, carrying out extraction of catalytically cracked diesel by an extraction solvent to obtain polycyclic aromatic hydrocarbon-rich extract oil and alkane-rich raffinate oil, 2, carrying out hydrofining and hydrocracking of the polycyclic aromatic hydrocarbon-rich extract oil under the hydrogenation reaction conditions to obtain light aromatic hydrocarbons and a high-octane number gasoline fraction. The method can realize production of light aromatic hydrocarbons, high-cetane number diesel and high-octane number gasoline.

The invention relates to a carbon-sulfur-shell matter composite material having a network dual-core shell structure and a preparation method thereof. The carbon-sulfur-shell matter composite material has a carbon-sulfur-shell three layer structure, a central core (inner core) is nano carbon particles, sulfur elemental or a polysulfide containing-Sm-structure (m>2) is directly deposited on the nano carbon particles, or functional groups are introduced onto the nano carbon particles by use of polycyclic aromatic hydrocarbon like reaction capacity of the carbon material and through an irreversible chemical reaction, polymeric chains are introduced in, a crosslinked network structure is formed through stretching, bending and crosslinking of the polymeric chains on the surface of the nano carbon particles, the sulfur elemental or the polysulfide containing the-Sm-structure (m>2) is composited onto the crosslinked network structure to form a nano sulfur layer having a network structure, then a mono-core shell nano composite material having a network structure is obtained and is used as a second layer (outer core) of the carbon-sulfur-polymer composite material having the network dual-core shell structure, an outermost layer is a shell matter layer, electronic and/or ionic conductivity of the material are/is improved, dissolving loss of discharge products can be further inhibited, and structural stability of the material is improved. The material is suitable for positive poles of lithium sulfur batteries, and has a prominent effect on improvement of cycle stability of the lithium sulfur batteries.

The invention relates to a method for producing environment-friendly rubber filling oil, which comprises the following steps: performing extraction through back flow and sufficient contact in an extraction tower by using the specific gravity difference of raw oil and a solvent; dissolving polycyclic aromatic hydrocarbon in the raw oil into the solvent, and depositing the polycyclic aromatic hydrocarbon to the bottom area of the tower automatically; raising the raw oil after the extraction to the top of the tower automatically; performing solvent recovery through a steam stripping process; and removing the carried solvent to obtain the environment-friendly rubber filling oil. The method has the advantages that the environmental protection of an oil product meets European Union requirements, the oil product has good compatibility with rubber, and the adopted solvent recovery process has the advantages of high solvent recovery rate, easily achieved conditions and the like.

The invention discloses a method for preparing a graphene composite material adsorbing polycyclic aromatic hydrocarbon pollutants. The graphene composite material is prepared by dispersing the graphene in a precursor solution of a support body material and enabling the precursor of the support body material to generate cure reaction. The specific preparation steps and adsorption process are as follows: (1) preparing a graphene dispersion solution; (2) preparing the precursor solution of the support body material; (3) mixing the graphene dispersion solution and the precursor solution of the support body material; (4) initializing the precursor solution of the support body material for cure reaction, and adding graphene to obtain the graphene composite material; and (5) soaking the prepared graphene composite adsorption material in a polycyclic aromatic hydrocarbon solution, wherein the polycyclic aromatic hydrocarbon is adsorbed on the surface of graphene due to pi-pi mutual action between the graphene and the polycyclic aromatic hydrocarbon. According to the invention, the enrichment and adsorption capacities of the graphene on the polycyclic aromatic hydrocarbon are improved by means of large pi system and super large specific surface area.

The invention relates to a catalyst for converting polycyclic aromatic hydrocarbons into monocyclic aromatic hydrocarbons and a preparation method thereof, mainly solving the problems in the prior art that the conversion level of polycyclic aromatic hydrocarbons is low, the monocyclic aromatic hydrocarbon yield and selectivity are low and the catalyst deactivation rate is high. The problems are better solved by adopting the catalyst and the preparation method thereof. The catalyst comprises 34.5-60wt% of mixture of FAU type zeolite and at least one molecular sieve from MOR, BEA, MFI and MCM-22, 39.5-65wt% of at least one of gamma-alumina, eta-alumina and pseudo-boehmite as a binder and 0.05-0.9wt% of at least one metal from Pt, Pd and Ir. The catalyst can be used in the industrial production of converting heavy polycyclic aromatic hydrocarbons into monocyclic aromatic hydrocarbons.

An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “E^T_b>E^T_h” (where, E^T_h is the triplet energy of the host material, and E^T_b is the triplet energy of the barrier material).

The present invention relates to a catalyst of a metal oxide compound used for organic exhaust gas purification, and a preparation method for the catalyst. The catalyst uses the cordierite honeycomb ceramic intensively pretreated with the nitric acid as a carrier, and an active aluminum oxide coating modified by a mixed oxide of cerium, lanthanum and zirconium, and an active component comprising a plurality of metallic oxide mixtures are loaded on the carrier in a lump. For the catalyst preparation method, heat treatment is conducted on the carrier with the nitric acid, the concentration of which is 5 to 15 percent; after a specific surface area of the carrier is increased, the coating, which comprises and is loaded with the mixed oxide active component, is immersed in a lump. The catalyst is provided with the large specific surface area. The active component is a transition metal oxide mixture, which comprises no noble metal. Moreover, the catalyst is provided with the excellent performance and the low cost, and can be spread and applied easily. The catalyst is provided with the high catalytic combustion efficiency for the organic exhaust gas comprising benzene, toluene, dimethybenzene, polycyclic aromatic hydrocarbon and so on, and the ignition temperature is low. Thus, the catalyst is widely applicable for purification of the industrial organic exhaust gas. The technique of one-time immersion, drying and calcination is adopted, so the manufacture equipment needed is simple.

The invention discloses a two-stage method coal tar hydro-upgrading method. Coal tar is subject to the atmospheric distillation and/or the reduced pressure distillation and is cut into coal tar light cut and coal tar heavy cut; after the coal tar light cut and optional distillate oil are mixed with hydrogen, the mixture enters a first hydrogeneration reaction zone and performs the contact reaction with hydrorefining catalyst; gas phase impurities of a reaction effluent is removed through an intermediate flash distillation column or a high-pressure stripping tower, and then the reaction effluent enters a second hydrogeneration reaction zone to perform the contact reaction with the hydro-upgrading catalyst or the hydrocracking catalyst; and the obtained reaction effluent is cooled, separated and fractionated to produce diesel fraction and naphtha cut. The invention provides a clean and effective coal tar processing and utilizing method, the coal tar light cut is hydro-upgraded to produce diesel oil for vehicles, the sulfur content of the obtained diesel product is less than 50 mu g/g, the content of polycyclic aromatic hydrocarbon is less than 11 weight percent, and the diesel oil cetane number of the product is improved by not less than 20.

Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.

A Rhodococcus ruber Em (CGMCC No.0868) features that its cells, cell suspension, or immobilized cells can degradate the paraffin and polycyclic arylhydrocarbon because the paraffin and polycyclic arylhydrocarbon are used as its only carbon source and energy source for growing to generate the bioemulsifier of ester. Said emulsifier can obviously decrease the surface tension of aqueous solution, has strong emulsifying power to ester substance, and can increase the solubility of paraffin and polycyclic arylhydrocarbon in water, so it can be used for treating the oil-contained sewage and repairing the petroleum polluted soil.

Systems and methods for forming conductive materials. The conductive materials can be applied using a printer in single or multiple passes onto a substrate. The conductive materials are composed of electrical conductors such as carbon nanotubes (including functionalized carbon nanotubes and metal-coated carbon nanotubes), grapheme, a polycyclic aromatic hydrocarbon (e.g. pentacene and bisperipentacene), metal nanoparticles, an inherently conductive polymer (ICP), and combinations thereof. Once the conductive materials are applied, the materials are dried and sintered to form adherent conductive materials on the substrate. The adherent conductive materials can be used in applications such as damage detection, particle removal, and smart coating systems.

The invention relates to a combined restoring method of polycyclic aromatic hydrocarbon contaminated soil, comprising the following restoring steps of: planting lucerne as perennial leguminous plants in the polycyclic aromatic hydrocarbon contaminated soil; inoculating a mixed bacterial inoculum comprising arbuscular mycorrhizal fungi, bacillus and flavobacterium; and meanwhile, adding rhamnolipid as a biosurfactant. By rhizosphere effect generated by plant root exudates, the number and the metabolic activity of soil microorganisms are increased; and by inoculating the arbuscular mycorrhizal fungi, the plant growth is promoted, and the root exudates are increased, thereby increasing the root accumulation of organic pollutants and the number of root soil microorganisms. The inoculated high-efficiency polycyclic aromatic hydrocarbon degrading bacteria use plant root secretions as a carbon source and an energy source and can quickly grow and propagate. The polycyclic aromatic hydrocarbon is stripped from soil grains by the biosurfactant, and the bioavailability and the degradability of the organic pollutants are increased.