755 results about "Polycyclic aromatic hydrocarbon" patented technology

The invention provides a photosensitive resin composition containing a photobleaching aminomethyl anthracene photosensitizer and application thereof.The structural main body anthracene ring of the photosensitizer introduces an aminomethyl functional group to the 9th and / or 10th site: through introduction of the aminomethyl functional group, while the electron cloud density of polycyclic aromatic hydrocarbon is maintained, the maximum absorption wavelength is subjected to red shift, and the photosensitive resin composition is especially suitable for a 405nm illumination system; the initiation efficiency is obviously improved; the exposure energy is reduced; compared with an existing DBA type photoinitiator, the problem of alkoxy carbon-oxygen bond breakage caused by p-pi conjugation of DBA is avoided, generation of small molecule fragments is effectively inhibited, defects are reduced, and the yield is increased. In addition, compared with DPHA and DAcOA, the photosensitizer also shows better solubility and formula compatibility. The preparation method has the characteristics of simple preparation process and low cost, and can be widely applied to the photocuring fields of dry films, paints, coatings, printing inks, forming materials and the like.

The invention discloses an underground water pollutant migration simulation method coupled with a physical mechanism and data driving, which comprises the following steps: establishing a statistical model through a machine learning method to correct the structural error of an underground water model, and expressing the output of the underground water model as the sum of a physical mechanism model, a structural error model and an observation error. According to the method, underground water pollutant migration simulation under complex conditions can be carried out, structural errors existing in the model are effectively corrected based on a data driving method, the defect that a traditional underground water model is poor in simulation precision under the complex conditions is overcome, and the application scene of underground water pollutant migration simulation is expanded; according to the method, underground water pollution migration simulation can be carried out aiming at novel and macromolecular organic pollutants such as polycyclic aromatic hydrocarbon, the defect that a traditional underground water model cannot accurately describe pollutant and colloid co-migration behaviors is overcome, the uncertainty of a model prediction result is remarkably reduced, the accuracy and reliability of the model prediction result are improved, and the method is suitable for popularization and application. And the model prediction performance is improved.

The invention relates to the technical field of environmental restoration, in particular to a slow-release material for synergistically restoring heavy metal and organic compound contaminated soil based on modified biochar and microorganisms and an application method thereof.The slow-release material is prepared from, by weight, 50-80 parts of modified biochar, 30-40 parts of sodium alginate, 10-20 parts of gelatin, 5-10 parts of glycerin and 3-5 parts of calcium carbonate. The multi-modified biochar is prepared from, by weight, 300-400 parts of a functional flora mixed solution and 5-10 parts of mixed nutrient elements of glucose, yeast extract and KHPO, and through the synergistic effect of the multi-modified biochar and the functional flora, efficient immobilization (the immobilization rate gt is 60%) of heavy metal (lead, cadmium and chromium) and efficient degradation (the degradation rate gt is 70%) of organic pollutants (polycyclic aromatic hydrocarbon and petroleum hydrocarbon) are achieved.

The invention belongs to the technical field of asphalt pavement repairing, and particularly relates to a local repairing technology of an asphalt pavement, which comprises the following specific contents: detecting a disease range by adopting ground three-dimensional laser scanning or ground penetrating radar, determining a repairing boundary, sampling and detecting the aging degree, the moisture content and the grading type of the asphalt of the original pavement, and determining the repairing quality of the asphalt pavement. According to the method, the bonding strength of the repairing material and the asphalt layer of the original pavement is enhanced by heating and activating the interface of the original pavement and emulsifying the asphalt bonding layer, and matching the repairing material with the shrinkage coefficient of the original pavement and reinforcing and compacting the edge, so that the condition that the repaired position is cracked, loosened and damaged in a short time is avoided; warm-mixed asphalt is adopted, the heating temperature is reduced by 40-60 DEG C, cold-mixed emulsified asphalt is popularized, and the asphalt does not need to be heated, so that release of a large amount of volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAHs) and dust is effectively avoided, and air pollution is avoided.

The invention relates to a modified binder for a dry-method electrode, a dry-method electrode pole piece and a preparation method of the dry-method electrode pole piece. Polycyclic aromatic hydrocarbon is dissolved in an aprotic polar solvent, alkali metal is added, and a polycyclic aromatic hydrocarbon alkali metal reagent is generated; and adding polytetrafluoroethylene into the polycyclic aromatic hydrocarbon alkali metal reagent to obtain the modified polytetrafluoroethylene. Alkali metal ions in the polycyclic aromatic hydrocarbon alkali metal reagent can destroy C-F bonds in the PTFE, remove some fluorine atoms on the surface of the PTFE and leave a carbonized layer and some polar groups such as hydroxyl groups, carbonyl groups and unsaturated bonds, and the groups can increase the surface energy, reduce the contact angle and improve the wettability, so that the cohesiveness of the modified PTFE is improved, and the service life of the PTFE is prolonged. The binding force between the PTFE and the conductive agent and the current collector is enhanced, and the problem that the viscoelasticity of the PTFE in the dry-method pole piece is insufficient is solved. Through modification, part of C-F bonds in PTFE are destroyed in advance, so that generation of interface side reaction products is reduced, the problem of initial effect reduction of a dry-method electrode is improved, and the cycle stability of a battery is improved.

According to the microbial flora culture method for efficiently degrading the organic pollutants, three continuous culture stages of enrichment, domestication and optimization are adopted, parameters such as the temperature, the pH value, the rotating speed and the ventilatory capacity are accurately controlled in each stage, and growth of microorganisms with degradation capacity is promoted. Through multi-stage culture and domestication, the obtained flora has efficient degradation capability on organic pollutants such as petroleum hydrocarbons, pesticides and polycyclic aromatic hydrocarbons, and has strong adaptability to pollutants with different concentrations. The 16S rRNA gene is used for sequencing and identifying the flora, and composition and dominant strains are clear. The flora is prepared into a microbial inoculum, and the microbial inoculum is preserved by freeze drying or liquid nitrogen, so that the activity can be effectively maintained. The flora can be widely applied to the fields of polluted soil and water body remediation, industrial wastewater treatment and the like, is green and environment-friendly, is relatively low in cost, avoids secondary pollution, conforms to the concept of sustainable development, and has relatively high economic and environmental values.

The invention relates to a petroleum polluted soil polycyclic aromatic hydrocarbon migration path simulation experiment system, which comprises a main reaction cabin, a mechanical arm collaborative operation module, a multi-mode sensing module, a whole natural environment regulation and control module and an edge intelligent decision-making platform, an annular magnetic suspension track is arranged at the top of the main reaction cabin, and a soil sample chamber is arranged at the bottom of the main reaction cabin; the multi-modal sensing module comprises an EIT (electrical impedance tomography) module, an LIBS (laser-induced breakdown spectroscopy) module and a terahertz time-domain spectroscopy module and is used for measuring global conductivity distribution of soil in a soil sample chamber, inverting the porosity of the soil sample and a pollutant concentration field in pore water, analyzing the concentration of carbon, hydrogen and oxygen elements of pollutants and specifically detecting polycyclic aromatic hydrocarbon molecules; the edge intelligent decision-making platform interacts with the multi-mode sensing module, the full-natural-environment regulation and control module and the mechanical arm collaborative operation module to actively adjust system parameters, and repair intervention is carried out on soil body degradation. And automatic preparation of the polluted soil can be realized, and migration monitoring under different practical engineering application working conditions can be realized.

The present invention discloses an alkali-resistant microbial bacterium PDC-1 and its application. The present invention screens and isolates PDC-1 strain from the soil of a coal gangue stockpile in a coal mine in Shandong, China, which can utilize naphthalene, phenanthrene, anthracene or pyrene as the sole carbon source and has tolerance to heavy metals. The strain of the present invention is capable to degrade various PAHs with the presence of heavy metals. The strain is alkali resistant, simple to cultivate, and has a good application in the bioremediation of polycyclic aromatic hydrocarbons and heavy metal contaminated sites.

The invention discloses a preparation method and application of a magnetic biochar-loaded bacterium composite functional material, magnetic biochar (MBC) is used as a carrier to load and fix Achromobacter denitrificans BP1 (Achromobacter denitrificans BP1, the NCBI login number is CP154792), and a magnetic biochar-loaded functional bacterium (MBC-coated BP1) is obtained. The invention relates to a water and soil purifying agent which is used for removing pollutants in water and / or soil, the pollutants comprise polycyclic aromatic hydrocarbons (PAHs) and / or heavy metals (HM) and the like, benzo [a] pyrene (BaP) and phenanthrene (Phe) in the soil can be efficiently degraded, Cr (VI) is removed, nitrate (NO3 <->) is metabolized, the soil nutrient level (organic matters, nitrogen, phosphorus and the like) can be increased, the diversity and structural functions of soil microbial communities are improved, and the water and soil purifying agent can be used for purifying water and / or soil. And a green and efficient repairing material and a technical support are provided for a compound pollution complex site.

The invention discloses a method for repairing a phenanthrene-cadmium co-polluted environment by using a biochar-based immobilized microbial inoculum, the method is characterized in that the phenanthrene-cadmium co-polluted environment is treated by using the biochar-based immobilized microbial inoculum, and the biochar-based immobilized microbial inoculum is prepared by using modified peanut shell biochar as a carrier. The modified peanut shell biochar is loaded with a phenanthrene efficient degrading flora SMP, and the phenanthrene efficient degrading flora SMP is obtained by domesticating coking plant sludge as a raw material and polycyclic aromatic hydrocarbon as a carbon source. The method has the advantages of being high in treatment efficiency, good in remediation effect, simple in process, convenient to operate, low in treatment cost and the like, phenanthrene in the soil can be effectively removed, cadmium in the soil can be effectively fixed, the use value is high, the application prospect is good, and a green and environment-friendly biological way is provided for remediation of the phenanthrene-cadmium co-polluted environment.

The invention belongs to the technical field of environmental protection, and discloses a method for rapidly and efficiently removing and recycling polycyclic aromatic hydrocarbon in water and a carbon-based adsorbent, the method comprises the following steps: S1, preparing a modified carbon-based adsorbent; s2, treating the polycyclic aromatic hydrocarbon pollutant wastewater; and S3, recycling the polycyclic aromatic hydrocarbon. According to the preparation method, H3PO4 or ZnCl2 is taken as an activating agent, and an activated carbon base material and an activating process are controlled, so that nano-micron multi-scale modified carbon-based adsorbent particles which are mainly prepared from a large number of long-strip-shaped gap mesopores which are communicated with one another and are approximately distributed in parallel and are auxiliary from a small number of discrete irregular groove-shaped mesopores are obtained; the long and narrow long-strip-shaped gap mesopores of the particle are matched with the irregular groove-shaped mesoporous structure, so that large-size polycyclic aromatic hydrocarbon can be quickly adsorbed and desorbed, and the balance of adsorption and desorption efficiency can be realized; on one hand, the adsorption and desorption efficiency of pollutants is improved, and on the other hand, the dosage of the adsorbent is greatly reduced.

The invention provides a preparation method of a double-ligand MOF photocatalyst, and belongs to the technical field of organic metal hybrid nano materials, and the prepared double-ligand MOF photocatalyst has excellent visible light response and photochemical conversion properties, and can realize efficient conversion of NADH under visible light. According to the technical scheme, the method comprises the following steps: (1) adding tetravalent zircon salt, a porphyrin compound and a polycyclic aromatic hydrocarbon compound into an organic solvent; after dissolving, introducing organic acid and carrying out ultrasonic treatment to dissolve the organic acid; and transferring the obtained solution to a reaction kettle, heating to react for a certain time, cooling, washing with an organic solvent, and drying to obtain the MOF photocatalyst with double ligands. The obtained composite photocatalyst can be applied to efficient regeneration of NADH (Nicotinamide Adenine Dinucleotide).

The invention relates to the field of electrochemical energy storage electrode materials, in particular to a method for preparing a coal-based carbon material through chemical crosslinking coupling high-temperature carbonization and application of the coal-based carbon material. The method comprises the following steps: crushing and deliming raw material coal to obtain ultra-pure coal powder; then dissolving the ultra-pure coal powder and a cross-linking agent in an organic solvent, under the action of a catalyst, inducing methyl, ethyoxyl, aldehyde and other groups to uniformly introduce polycyclic aromatic hydrocarbon molecules, and finally forming a super-cross-linked structure; and performing high-temperature carbonization to recombine the coal into closed pores, thereby forming the disordered coal-based carbon material with small microcrystal size. The method has the advantages that the raw material source is stable, the cost is low, the carbon yield is high, the treatment process is simple, large-scale preparation of the high-performance coal-based carbon material is easy to realize, and the like; and the prepared coal-based carbon material shows excellent electrochemical performance as a sodium ion / lithium ion battery negative electrode.

The invention discloses a Raman spectrum joint classification and quantification method based on a prior fusion double-flow network, and belongs to the technical field of spectral analysis and chemometrics. The method comprises the following steps: acquiring Raman spectrum original data, and preprocessing to obtain standardized spectrum data; raman spectrum prior information is extracted, and a prior information double-flow network containing classification and quantitative flow sub-networks is constructed; standardized data and prior information are input, classification preheating-combined fine tuning training is adopted, conflict is relieved by combining dynamic weighting and PCGrad, and samples are expanded through a physical consistency strategy synchronously; processing unknown samples by using the trained network, and outputting categories and component contents; according to the method, weak peak information is mined through double-flow architecture and cross-flow attention, derivative noise is suppressed, classification-quantification performance is balanced through double-task optimization, and small sample overfitting is solved through physical expansion; on a polycyclic aromatic hydrocarbon data set, classification and regression indexes are superior to those of a traditional method, the low-concentration / weak-peak scene precision and robustness are better, and the engineering application prospect is good.

The invention discloses a method for preparing humic acid by graded oxidation and depolymerization of lignite, which comprises the following steps: weighing lignite, adding hydrogen peroxide for oxidation pretreatment, filtering and vacuum drying to obtain primarily oxidized lignite named as PTSL; and carrying out a deep oxidation experiment on the obtained PTSL by using a mixed gas of ozone and oxygen, after the oxidation reaction is finished, carrying out centrifugal filtration on the mixture, and collecting a liquid sample. The lignite is subjected to gradient oxidation depolymerization in a graded oxidation mode, the green oxidant hydrogen peroxide firstly oxidizes and breaks weak bridge bonds and side chain structures in the lignite without damaging aromatic ring structures, then the lignite is further deeply oxidized through the strong oxidant ozone, polycyclic aromatic hydrocarbon structures in the lignite are gradually damaged, and the content of the polycyclic aromatic hydrocarbon in the lignite is reduced. The step-by-step oxidative depolymerization of the organic matters in the coal is realized. According to the method, the organic matter conversion rate and the humic acid yield of the lignite can be improved, and the impurity content in the humic acid is reduced.

The invention discloses preparation of a polycyclic aromatic hydrocarbon-based pre-sodium modification agent and application of the pre-sodium modification agent in a hard carbon negative electrode, and belongs to the technical field of negative electrodes of sodium-ion batteries. The chemical property of polycyclic aromatic hydrocarbon is adjusted by virtue of induction and conjugation effects, and the pre-sodium-modification agent with controllable chemical reaction rate is prepared and applied to the hard carbon negative electrode. Firstly, in an ether-based solvent, polycyclic aromatic hydrocarbon molecules are selected to be grafted with functional groups with different electronegativity to serve as electron acceptors, the electron acceptors and metal sodium are subjected to free radical reaction, and a pre-sodium agent is obtained and used for efficient pre-sodium. By selectively adjusting the reducibility of the pre-sodium modification agent and assisting the generation of a high-stability interface film, the damage to the internal structure of the negative electrode and the excessive sodium modification are avoided. According to the preparation process, the pre-sodium modification agent can be obtained only through one-step stirring, and the electrode is soaked to achieve pre-sodium modification. The method has the advantages of simplified steps, simple equipment and good repeatability, and is suitable for large-scale production.

The invention discloses a plant-microorganism enhanced multiphase extraction organic pollution remediation method. The method comprises the steps of site evaluation, phytoremediation system construction, microbial remediation system construction, multiphase extraction enhancement, remediation process monitoring and adjustment, pollutant removal and ecological restoration. According to the method, a plant-microorganism enhanced multiphase extraction synergistic effect remediation system is constructed, the problem that the efficiency of a single plant remediation or microorganism remediation technology is low is effectively solved, degradation and removal of organic pollutants are accelerated, efficient treatment of refractory pollutants such as polycyclic aromatic hydrocarbons, polychlorinated biphenyls and organophosphorus pesticides is achieved, and the method has the advantages of being simple in process, low in cost and good in application prospect. In the remediation process, the influence on the ecological environment is small, secondary pollution is not likely to be generated, and the method has both economical efficiency and environmental friendliness and is suitable for treatment of multiphase pollutants in complex contaminated sites including soil, water and solid waste.

The invention discloses a Pseudomonas nicosulfurones bacterial strain and an application of the Pseudomonas nicosulfurones bacterial strain in degradation of phenanthrene and benzopyrene. According to the invention, a degradation strain Pseudomonas nicosulfurensis DY-8, which takes phenanthrene and benzopyrene as carbon sources, is obtained by domestication, separation and identification from petroleum-polluted soil in Ningbo. The invention also relates to a method for preparing the degradation strain Pseudomonas nicosulfurensis DY-8 with phenanthrene and benzopyrene as carbon sources. The DY-8 can utilize phenanthrene and benzopyrene as carbon sources, and after the DY-8 is cultured in an inorganic salt culture solution with the initial concentration of phenanthrene and benzopyrene being 50 mg.L <-1 > and 25 mg.L <-1 > respectively for 7 days, the degradation rates of phenanthrene and benzopyrene can reach 70% or above. Therefore, the strain has good application potential in the aspect of bioremediation of polycyclic aromatic hydrocarbon.

The invention belongs to the technical field of biological culture, and particularly relates to a chlorella extracellular fluid and a preparation method and application thereof.The preparation method of the chlorella extracellular fluid comprises the following steps that a BG11 culture medium is inoculated with a chlorella solution cultured to the logarithmic phase, oxcarbazepine is added, and the chlorella extracellular fluid is obtained; the preparation method comprises the following steps: placing chlorella in an intermittent illumination environment with the temperature of 20-30 DEG C and the rotating speed of 100-200 rpm for growth, centrifuging the chlorella to obtain supernate after the chlorella grows to the 10th-16th day, filtering, sub-packaging, and performing cryopreservation to obtain the chlorella extracellular fluid. By adding oxcarbazepine, the chlorella extracellular fluid prepared in a specific culture medium and a specific growth environment has high oxidation activity, excellent stability and excellent degradation capacity, and a new thought is provided for solving the pollution treatment problem of current environmental pollutants such as pharmaceutical products, polycyclic aromatic hydrocarbons and dyes.

The invention discloses a long-afterglow material based on waste PET and a preparation method and application thereof.Organic luminescent substance crown alkene serves as luminescent molecules and is fused and doped into recycled waste PET, the waste PET is upgraded and reconstructed into a persistent luminescent polymer element, PET macromolecular chains are folded front and back to form regular lamellas, and the lamellas are uniformly distributed on the surface of the waste PET, so that the long-afterglow material based on the waste PET is obtained. Excitons are stabilized, and oxygen in the atmosphere is prevented from being quenched. Due to the planar and rigid structure of the polycyclic aromatic hydrocarbon, intramolecular movement can be inhibited, so that non-radiative decay channels are reduced, and the ultra-long afterglow effect is realized. According to the long-afterglow material, pollution of waste materials is reduced, upgrading and recycling of resources are achieved, upgrading and recycling steps are simple and convenient, cost is low, the preparation process is easy to scale, economical and efficient, and the long-afterglow material has good industrial popularization prospects and has important application value in the technical field of plastic upgrading and recycling.

The invention provides a red light and infrared light-emitting compound based on a boron-nitrogen fused ring and application thereof. The invention provides a boron-nitrogen polycyclic aromatic hydrocarbon material of a fused naphthalene ring, and a specific strong electron withdrawing group is introduced to a boron atom para-position. Compared with a compound disclosed in the prior art, the compound provided by the invention introduces a strong electron withdrawing group to a boron atom para-position of boron-nitrogen polycyclic aromatic hydrocarbon of a fused naphthalene ring, so that the emission spectrum of the material can be subjected to significant red shift (red shift from a yellow light band to a red light band and even an infrared band), and red light and even infrared light emission with high luminous efficiency and a narrow band can be realized. An electroluminescent device prepared from the compound provided by the invention shows relatively high luminescent color purity and relatively excellent luminous efficiency, and can meet the requirements of current enterprise production on high-performance luminescent materials.

A preparation method of high-conductivity carbon fiber paper comprises the following steps: performing surface oxidation modification, washing, filtering and drying on carbon fibers, adding the carbon fibers into an aqueous solution of a dispersing agent, forming through a papermaking process to obtain carbon fiber pre-formed paper, impregnating the carbon fiber pre-formed paper into a resin solution, and drying to obtain the high-conductivity carbon fiber paper. And carrying out hot-pressing curing and high-temperature treatment to obtain the carbon fiber paper. Asphalt resin and phenolic resin are used as binders, in the hot-pressing curing stage, the asphalt resin is heated and melted, carbon fibers are uniformly impregnated, a three-dimensional network structure formed by curing and crosslinking of the phenolic resin is fully filled, and a good conductive network is formed; in the high-temperature treatment stage, the asphalt resin and the phenolic resin are co-carbonized, a polycyclic aromatic hydrocarbon structure of the asphalt resin is combined with free radicals generated by pyrolysis of the phenolic resin to generate dehydrogenation reaction, a wider conjugated carbon network is formed, the graphitization degree of the carbon paper is improved, and the conductivity and mechanical strength of the carbon paper are improved; therefore, the composite membrane has a good effect in the proton exchange membrane fuel cell.

The invention relates to a nitrogen-containing bowl-shaped conjugated pH-responsive fluorescent probe and a preparation method and application thereof, the nitrogen-containing bowl-shaped conjugated pH-responsive fluorescent probe is characterized in that the structural formula of the nitrogen-containing bowl-shaped conjugated pH-responsive fluorescent probe is # imgabs0 #, and R is hydrogen, acetyl or p-toluenesulfonyl. Compared with the prior art, the nitrogen-containing bowl-shaped conjugated molecule provided by the invention shows a highly sensitive response characteristic in an acid-base medium. Due to the introduction of nitrogen atoms, the electronic structure of molecules is obviously changed, lone pair electrons of the nitrogen atoms can participate in the reaction, and the protonation behavior is obvious under the acidic condition. After protonation, the fluorescence intensity of the molecule is obviously enhanced, and the emission wavelength has obvious red shift, so that the probe has important application value in the aspect of developing a high-sensitivity acid-base sensor. In addition, the nitrogen-containing polycyclic aromatic hydrocarbon compound also shows application prospects in the fields of organic light-emitting diodes, information safety, biological imaging and the like.

The present invention discloses a method for cultivating activated sludge for efficiently treating coking wastewater. The present invention adopts bio-fortified strains and rice husk biochar to prepare a microbial immobilization carrier, and the carrier is added to a simulated coking wastewater activated sludge treatment system to form bio-fortified activated sludge, which is successively added to simulated coking wastewater with gradually increasing phenol concentration, simulated coking wastewater with gradually increasing nitrogen-containing heterocyclic compound concentration, and simulated coking wastewater with gradually increasing polycyclic aromatic hydrocarbon concentration for three times of acclimation to obtain activated sludge after the third acclimation, and the activated sludge is applied to treat simulated coking wastewater. The activated sludge after the third acclimation of the present invention can simultaneously and efficiently degrade multiple target pollutants in the simulated coking wastewater.

The present invention provides a composite bacterial community for degrading polycyclic aromatic hydrocarbons and its application, belonging to the field of microbial technology. The composite bacterial community of the present invention comprises Fusarium solani E1 and Rhodococcus erythroxysporum E2; the preservation number of Fusarium solani E1 is CGMCC No: 41063, and the preservation number of Rhodococcus erythroxysporum E2 is CGMCC No: 29266. The present invention combines fungi and bacteria to synergistically degrade PAHs in the repair of PAHs. The composite bacterial community has better PAHs degradation effect and composite bacterial growth status than single bacteria, and has good effects on the degradation of high- and low-ring PAHs.

The invention provides a soil remediation method for jointly degrading polycyclic aromatic hydrocarbon by zoysia sinensis-degrading flora, which comprises the following steps: S1, carrying out shake culture on a soil sample in a shaking table, and then culturing in a liquid culture medium to obtain an enriched bacteria solution; s2, adding PAHs into a liquid culture medium, inoculating the enriched bacterial liquid into the liquid culture medium, and gradually increasing the concentration of the PAHs to obtain a culture solution; s3, centrifuging the culture solution, collecting thalli, performing enrichment culture again, adding the bacterial solution into glycerol, and mixing to obtain a degrading flora bacterial solution; s4, mixing the polycyclic aromatic hydrocarbon contaminated soil with nutrient soil to obtain composite soil; s5, sowing the zoysia sinensis seeds in the composite soil to obtain plants, and culturing the plants in a plant culture room; and step S6, adding activated degrading flora bacterial liquid into the plants on the 15th day and the 30th day after sowing. Through the combined degradation effect of plants and microorganisms, the content of PAHs in soil is reduced.

The invention discloses a hydroxyl polycyclic aromatic hydrocarbon Raman spectrum detection method based on a dynamic weighted voting fusion network, relates to the technical field of hydroxyl polycyclic aromatic hydrocarbon detection, and provides an effective method which is rapid, accurate and free of chromatographic separation. Spectral information of OH-PAHs is obtained by using surface enhanced Raman spectroscopy SERS, and a Raman spectrum is obtained through density functional theory DFT calculation. A dynamic weighted voting fusion network DWVF-Net model is constructed, wherein the model comprises two core parts of cross-modal attention fusion (CMAF) and dynamic weighted voting (DWV). The CMAF dynamically weights key areas of SERS and DFT Raman spectrums through cosine similarity to realize feature fusion; and the DWV adaptively adjusts the weight of the model according to the real-time performance of the model, and optimizes an integration decision. Through the synergistic effect of CMAF and DWV, complementary information of SERS and DFT Raman spectrums is effectively fused, and the adaptability advantage of a dynamic weighting mechanism in the aspect of processing a complex data environment is verified.

The invention relates to the technical field of water treatment, in particular to a method for treating degradation-resistant organic pollution underground water based on a micro-interface strengthening technology. According to the technical scheme, the method comprises the steps that an underground water sample is collected and subjected to pollution characteristic analysis, composite material slurry is injected into a water-containing layer to construct an interface-enhanced in-situ reaction system, and the slurry is composed of nanoscale iron-based metal particles, graphene oxide derivatives, modified biochar, a surfactant and the like; meanwhile, a low-pressure gas injection system is arranged to form a micro-aerobic environment so as to improve the interface reaction efficiency, dominant microbial communities are synchronously injected, a slow-release carbon source carrier is added so as to strengthen the biological synergistic degradation effect, and the operation state of the system is regulated and controlled through multi-parameter monitoring. According to the method, a micro-interface synergistic system integrating physical adsorption, chemical reduction and biological metabolism is constructed, refractory organic pollutants such as aryl halide and polycyclic aromatic hydrocarbon in underground water can be efficiently and stably removed, and the method has the advantages of being high in remediation efficiency, high in operation stability and wide in environmental adaptability.

The invention relates to an aza-polycyclic aromatic hydrocarbon organic ligand and a preparation method thereof, an aza-polycyclic aromatic hydrocarbon assembled molecular cage and a preparation method and application thereof, the organic ligand takes dimethyl methylene bridged triphenylamine as a core, a benzene ring is modified by an R group, and the molecular cage is prepared from the organic ligand, the organic ligand and the aza-polycyclic aromatic hydrocarbon. A metal organic caged compound obtained by a coordination reaction with a metal complex; the molecular cage is of a truncated tetrahedral structure of twelve metals and eight ligands; each organic ligand is provided with three equal side arms which are wrapped and stacked together in a curved surface manner to form a pseudo six-section ligand; the organic ligands and the metal nodes are self-assembled to form a molecular cage with a hydrophobic cavity for recognizing guest molecules in the center. Compared with the prior art, the organic ligand has flexibility and is combined with metal to construct a novel water-soluble metal organic double-wall knotted flexible molecular cage, a size-adjustable cavity exists in the molecular cage, and selective recognition of nucleotide negative electricity biomolecules in a water phase is achieved.

The invention discloses a bacterial strain for reducing dissimilatory nitrate into ammonia nitrogen through anaerobic biodegradation of polycyclic aromatic hydrocarbon and application of the bacterial strain, the bacterial strain is named as PheICNA, and the bacterial strain belongs to Intraporum calvum. The strain is preserved in the China General Microbiological Culture Collection Center (CGMCC), and the preservation number is CGMCC No.40686. The strain can degrade polycyclic aromatic hydrocarbons such as phenanthrene under anaerobic conditions and completely metabolize the polycyclic aromatic hydrocarbons into carbon dioxide. Meanwhile, nitrate radicals are reduced into ammonium nitrogen, and the generated ammonium nitrogen can be used for growth of microorganisms and can be used as a nitrogen source for plants. The strain can be used for biologically repairing polycyclic aromatic hydrocarbon pollutants such as phenanthrene in soil, can convert nitrate nitrogen in the soil into ammoniacal nitrogen at the same time, achieves the effect of nitrogen maintenance, and has good application prospects in the aspects of polluted soil treatment and the like.