The invention belongs to functional material technology and glass processing field, concretely discloses a permanent self-cleaning glass with visible light response and method for making it. Firstly, sputtering silica dioxide film on the surface of glass, sputtering a layer of titanium oxide film with anion and cation codoping on the surface of silica dioxide film, annealing the glass with twin layer films at 500-600 DEG C, cooling by radiation in sintering stove, to get the product. The self-cleaning glass has good photocatalysis property and photo-induced hydrophilicity, stable performance, almost perpetual availability, high light transmittance ratio and transparency. It is widly used in glass curtain wall of skyscrapers, automobile glass, road lamp shade, kitchen galss and antifog glass, avoiding artificial cleaning indoor and outdoor glass of skyscrapers, saving manual power and material, reducing corrosion destruction of cleaning agent to glass and building machinery, embodying environment protection notion.