607 results about "Photoelectrochemistry" patented technology

A bias-free driven ion-based photoelectrochemical wastewater treatment system and method is disclosed. Through an ion-coupled photogenerated electron-assisted photocatalytic oxidation-reduction pathway, the system achieves efficient treatment of high-salinity wastewater. The system employs electron-ion receptor materials as the counter electrode, providing reaction sites to drive the coupling of photogenerated electrons and cation transfer. Additionally, the voltage generated by the system directly drives hole oxidation to produce strong oxidizing free radicals. Furthermore, this ion-based photoelectrochemical system demonstrates excellent degradation performance in high-concentration chloride media. This indicates that, in addition to cations (such as Na+) helping to accelerate the electron transfer rate, the presence of Cl− further enables efficient and sustainable wastewater treatment. The concept proposed in this invention emphasizes the potential for using abundant sodium chloride in seawater as an inexpensive additive for wastewater treatment.

The invention relates to the technical field of food safety detection, in particular to a Bi2WO6 / AuNPs / Ni-MOF composite material, a sensor and application of the Bi2WO6 / AuNPs / Ni-MOF composite material. The composite material is prepared from Bi2WO6 / Ni-MOF and AuNPs, can be used as a sensing substrate for modification, and is combined with a CRISPR / Cas12a system, so that an electrochemical and photoelectrochemical dual-mode combined aptamer sensor is constructed, and the composite material can be used for detecting 0.1 pg / mL to 100 ng / mL of OTA. Results obtained by different detection modes can be mutually verified, errors caused by external environment, instruments and parameter changes are reduced or eliminated, and therefore the detection reliability is improved. Meanwhile, the dual-mode sensor which is combined with the CRISPR / Cas12a system and adopts the Bi2WO6 / AuNPs / Ni-MOF composite material to modify the substrate also shows good selectivity and reproducibility, and has a wide application value.

The present invention discloses a CMO / SO / BVO photoanode and a preparation method and application thereof, and relates to the field of photoelectrochemical technology. The method comprises the following steps in sequence: electrodepositing a BiOI film on a substrate material, and then dripping a dimethyl sulfoxide solution containing vanadium acetylacetonate to obtain a BVO electrode; placing in a NaOH solution containing tetraethyl orthosilicate to obtain a SO / BVO electrode; placing in a CoMoO4 precursor solution, hydrothermally reacting, calcining, and obtaining a CMO / SO / BVO photoanode. The CMO / SO / BVO of the present invention exhibits superior photocurrent and charge separation efficiency compared to the CMO / BVO photoanode under 1.23V vs.RHE conditions. The present invention solves the problem of poor photoelectrochemical performance of the photoanode in the prior art.

The invention discloses a preparation method and application of a nickel-cobalt oxide modified molybdenum-doped bismuth vanadate composite photo-anode, and belongs to the application field of hydrogen production through water decomposition in photoelectrochemical reaction engineering. The preparation method comprises the following steps: obtaining a Mo-BiVO4 photo-anode through an electro-deposition and calcination combined method, preparing a precursor solution containing bimetallic nickel and cobalt by using cobalt nitrate hexahydrate, nickel nitrate hexahydrate and boric acid, immersing the Mo-BiVO4 photo-anode into the precursor solution, and growing a nickel-cobalt oxide (NiCoOx) cocatalyst on the surface of Mo-BiVO4 by using a photo-assisted electro-deposition method, thereby obtaining the Mo-BiVO4 photocatalyst. According to the NiCoOx cocatalyst modified Mo-BiVO4 composite photoanode and the preparation method thereof, the photocurrent density of the optimal NiCoOx cocatalyst modified Mo-BiVO4 composite photoanode obtained by the preparation method disclosed by the invention is 5.2 times that of pure bismuth vanadate. The preparation method has the advantages of simple operation method, easily available raw materials, low economic cost and good stability.

The invention belongs to the technical field of immunoassay and biosensing, and provides a novel construction mode of a heterojunction dual-photoelectrode photoelectric sensing strategy and a preparation method of an in-situ heterojunction MIO photocathode. The invention relates to a preparation method of a heterojunction dual-photoelectrode type photoelectrochemical sensor based on multi-ball cascade DNA reaction amplification. Specifically, the design is composed of an In2O3 / CdS photoanode and an in-situ formed MIL-68 / In2O3 (MIO) photocathode. The heterojunction dual-photoelectrode sensing strategy effectively prolongs an electron-hole transmission path, enhances photo-generated charge separation, and realizes' super-open 'PEC signal output, thereby providing a steady baseline for signal conversion. Meanwhile, a multi-sphere cascade DNA reaction is combined to output a three-dimensional DNA net structure to provide a large number of sites for embedding of a PEC quenching probe doxorubicin-ferrocene carboxylic acid (DOX-FcCOOH), obvious PEC signal quenching is realized by utilizing the efficient competitive electron transfer capability of the three-dimensional DNA net structure, and finally, a signal conversion system with'opening-super opening-closing 'multistage response characteristics is constructed. The detection of the nucleic acid marker Pax-5a gene of the B cell acute lymphatic leukemia is realized by detecting target objects with different concentrations.

The invention provides a preparation method of a TiO2 / Au-C3N4 heterojunction photoelectrochemical biosensor and an application of the TiO2 / Au-C3N4 heterojunction photoelectrochemical biosensor. Comprising the following steps: step 1, preparing TiO2 / FTO; step 2, preparation of TiO2 / Au-C3N4 (titanium dioxide / Au-C3N4); step 3, preparing a nucleic acid aptamer; and step 4, using the confining liquid mercaptohexanol. The preparation method comprises the following steps: firstly, preparing a TiO2 thin film by an electrophoretic deposition method, and then combining the TiO2 thin film with graphite phase carbon nitride (g-C3N4) doped with high-conductivity noble metal gold nanoparticles (Au NPs) to form a heterojunction; under an illumination condition, Au NPs and photons interact to generate a regional surface plasma resonance phenomenon, and a strong electromagnetic field and high-concentration high-energy carriers are formed on the surface of the nano structure in the process, so that the photocurrent response of the composite material is remarkably enhanced; besides, the introduced Au NPs can also form an Au-S bond with the DNA aptamer containing the-SH group, and more binding sites are provided, so that the capture capability of the aptamer is enhanced.

The invention provides a preparation method of a nanofiltration membrane for regulating and controlling interfacial polymerization reaction by utilizing carbon nitride photogenerated charge, and belongs to the technical field of water treatment membranes. The preparation method comprises the following steps: (1) adding carbon nitride film-making sol into an aqueous solution of a polyamine monomer, and carrying out ultrasonic dispersion to obtain a mixed dispersion liquid; (2) preparing an organic phase monomer solution; (3) adding an ultrafiltration support base membrane into the mixed dispersion liquid, infiltrating, then taking out, adding into the organic phase monomer solution, and carrying out interfacial polymerization reaction to obtain a high-permeability membrane containing an ultrathin polyamide separation layer; wherein the infiltration and the interfacial polymerization reaction are carried out under illumination; and (4) carrying out heat treatment on the high-permeability membrane containing the ultrathin polyamide separation layer to obtain the nanofiltration membrane. According to the preparation method disclosed by the invention, the photoelectrochemical characteristics of carbon nitride are utilized, and electrostatic repulsion exists between positive charges on the surface of carbon nitride and piperazine molecules under illumination, so that the interfacial polymerization rate is regulated and controlled, and the high-permeability nanofiltration membrane with an ultrathin polyamide separation layer is further prepared.

The invention relates to a photoelectrochemical system for synthesizing urea through co-reduction of carbon dioxide (CO2) and nitrate ions (NO3 <->). The system comprises a solar power supply system, a photoelectrocatalysis (PEC) reaction system, a raw material pretreatment system and a product recovery system. The PEC reaction system is communicated with the raw material pretreatment system and the product recovery system in series; and an integrated coupling reaction system is formed. According to the system, solar energy is used as a main energy source, and a co-reduction reaction of CO2 and NO3 <-> is realized through a novel PEC flow cell device, so that urea is directly synthesized. The reaction liquid is conveyed to a product recovery system through a pipeline, and a high-purity urea product is obtained through evaporative crystallization; unreacted CO2 and NO3 <-> can be circulated to the raw material pretreatment system through the reflux device and are further utilized. The method provided by the invention realizes efficient and green synthesis of urea, optimizes the whole process, reduces energy consumption and system complexity, has good economical efficiency and environmental friendliness, and is suitable for the fields of agricultural fertilizers, waste gas and wastewater resourceful treatment and the like.

The invention relates to the technical field of functional materials, and discloses a bionic hydrophobic anti-corrosion coating construction method which comprises the following steps: S1, substrate pretreatment: performing ultrasonic cleaning on a metal substrate to remove surface oil stains and oxides; s2, laser-electrochemical composite texturing: manufacturing a micron-nano hierarchical structure on the surface of the base material by adopting femtosecond laser, and then growing a metal organic framework layer on the nano structure in situ by adopting an electrochemical method; s3, plasma activation: bombarding the surface of the metal organic framework layer by adopting Ar / O2 mixed plasma; s4, carrying out gradient fluorosilane grafting; s5, filling the dynamic covalent network; and S6, roll-to-roll continuous coating is carried out. Through a laser-electrochemical composite texturing technology and a gradient fluorosilane grafting technology, the problems that a traditional hydrophobic coating is single in structure and poor in binding force are solved, and the effects that a micron-nano hierarchical structure is constructed on the surface of a metal base material, molecular gradient arrangement is formed, the hydrophobic performance is improved, and the interface binding strength is enhanced are achieved.

The invention belongs to the technical field of immunoassay and biosensing, and provides a preparation method of a photoelectrochemical sensor based on CuO-induced photocurrent polarity reversal. The invention provides a preparation method of the photoelectrochemical sensor based on CuO-induced photocurrent polarity reversal. Specifically, hollow polyhedral flower-shaped CuO with a unique inner cavity structure is adopted as a polarity induction factor, so that multiple light refraction and scattering effects are remarkably enhanced, and the light capture efficiency is improved. Besides, when CuO is introduced to the surface of the In2O3 / ZnCdS electrode as a photocurrent polarity reversal factor, due to the energy band structure difference between CuO and In2O3 / ZnCdS, the migration path of a photon-generated carrier is changed, and the photocurrent polarity is reversed from an anode to a cathode photocurrent, so that the detection specificity of the gastrin-releasing peptide is improved. The photocurrent polarity reversal strategy effectively eliminates potential false positive signal interference, and the accuracy and sensitivity of detection are remarkably improved. According to different photoelectrochemical signal intensities of to-be-detected substances with different concentrations, the gastrin-releasing peptide is detected.

The utility model discloses a photoelectrochemistry-based organic matter-rich wastewater hydrolysis device which comprises a hydrolysis acid production tank, a water inlet and a gas outlet are arranged on the hydrolysis acid production tank, the water inlet is connected with a water inlet pipe, the water inlet pipe is connected with a reservoir, a water delivery pump is arranged in the reservoir, the gas outlet is connected with a gas outlet pipe, and the gas outlet pipe is connected with a gas collection tank; a photoelectrochemical integrated device for accelerating the hydrolysis acid production process is arranged on the inner wall of the hydrolysis acid production tank, and a stirring device is arranged in the hydrolysis acid production tank; the hydrolysis acid production tank is provided with a main feed port and an auxiliary feed port, the bottom of the hydrolysis acid production tank is provided with a liquid outlet and a slag outlet, the liquid outlet is connected with a liquid outlet pipe, and the slag outlet is connected with a slag outlet pipe. The method is convenient, fast and high in feasibility, proliferation and metabolism of microorganisms are promoted through the photoelectrochemical integrated device, the reaction speed can be greatly increased, then the treatment effect and treatment efficiency of the wastewater are integrally improved, and the technical problems that existing organic matter-rich wastewater is poor in treatment effect and low in treatment efficiency are effectively solved.

An X-ray photoelectron spectroscopy in-situ test sample table for high-temperature electrochemistry comprises a base, a gasket, a lower electrode, a lower gold ring, an upper gold ring and an upper electrode which are sequentially arranged from bottom to top. A sample is positioned between the upper gold ring and the lower gold ring; the lower electrode and the upper electrode are arranged in an annular structure, and the upper gold ring and the lower gold ring are located at the annular structure; the annular structure extends outwards and is provided with a contact part, so that the annular structure can be conveniently connected with an instrument sample injection support and a thermocouple; a gap is formed in the inner circumference of the annular structure of the upper electrode so that the upper gold ring can be exposed. The X-ray photoelectron spectroscopy in-situ testing device can be used for in-situ testing of the X-ray photoelectron spectroscopy of a sample under the conditions of high temperature, certain atmosphere and pressure intensity and external voltage or current, so that deep research can be better carried out in the subject fields of solid electrochemistry, photoelectrochemistry, film preparation and the like.

The embodiment of the invention provides a preparation method of a photoelectric biosensor and the photoelectric biosensor, and relates to the technical field of photoelectric sensing, and the preparation method comprises the following steps: preparing a biomass derived hierarchical porous carbon PBAC material, preparing PBAC interface blending adsorption layer carbon slurry according to the biomass derived hierarchical porous carbon PBAC material, and preparing working electrode slurry; performing chemical etching on ITO conductive glass to prepare an electrode substrate, printing the working electrode slurry on the electrode substrate by using a screen printing technology, and printing PBAC interface blending adsorption layer carbon slurry on the electrode substrate to obtain a working electrode; a colloidal gold solution is dropwise added to the working electrode, after drying, a probe solution is dropwise added to the surface of the working electrode again, incubation is conducted in a constant-temperature box, and the photoelectrochemical biosensor is obtained after the reaction is completed. According to the invention, the biocompatibility of the photoelectric biosensor is enhanced, and the stability and sensitivity of the sensor are improved.

The invention belongs to the technical field of food safety sensing detection, adsorption and degradation, and particularly relates to an MIP / MOF / COF hybrid material and a preparation method and application thereof. Aiming at the defects and bottleneck problems of the existing patulin detection and removal technology, the preparation method comprises the following steps: firstly preparing an MOF / COF composite material, and then preparing an MIP / MOF / COF hybrid material by a sol-gel method, so that the photoelectrochemical sensor based on the MIP / MOF / COF hybrid material is constructed and is used for detecting patulin; meanwhile, based on the MIP / MOF / COF hybrid material, an attachment and degradation test platform is constructed. The prepared photoelectrochemical sensor can successfully detect trace patulin, and the hybrid material has good adsorption and degradation performance on patulin.

The invention discloses construction and application of a confinement enhanced photoelectrochemistry-electrochemiluminescence dual-mode biosensor, and relates to the technical field of biosensing and analytical chemistry. The preparation method of the biosensor comprises the following steps: taking a CdS (at) SiO2 (at) NaYF4: Yb / Tm nano composite material as a substrate to obtain a confinement enhanced photoelectrochemistry (PEC) and electrochemiluminescence (ECL) sensing interface; in combination with a DNA wheel nanostructure triggered by target acetamiprid, signal amplification is realized; and synchronous dual-mode quenching detection of PEC and ECL signals is realized by virtue of peroxidase-like catalytic precipitation and wide-spectrum absorption characteristics of the PtPd-CoSnO3 nanocube. The biosensor prepared by the invention has the advantages of high sensitivity, strong reliability, good selectivity and the like, can be applied to accurate detection of acetamiprid in samples such as agricultural products and the like, and has important application value in the aspects of environmental monitoring and food safety control.

This disclosure relates to magnetic microgel beads, and in particular to magnetic microgel beads for biofunctionalization and methods of making and uses thereof, for example, in biosensing assays. In an embodiment, a magnetic microparticle comprising a magnetic nanoparticle encapsulated by a polymer hydrogel. In another embodiment, an assay for detecting the presence of a target analyte in a sample comprising a) the magnetic microparticle disclosed herein, wherein the biorecognition agent further comprises a reporter moiety; b) an electrochemical chip comprising a working electrode, a counter electrode and a reference electrode; and c) a capture probe functionalized on the working electrode; wherein binding of the biorecognition agent to the target analyte results in production of an electrochemical, electroluminescent or photoelectrochemical signal.

The invention discloses a monoclinic-phase molybdenum-doped bismuth vanadate photoelectrode and a preparation method and application thereof, and belongs to the technical field of photoelectrochemical degradation of pollutants and hydrogen production. The monoclinic-phase molybdenum-doped bismuth vanadate photoelectrode is synthesized through a hydrothermal-annealing method, the monoclinic-phase molybdenum-doped bismuth vanadate photoelectrode stands in a sodium hydroxide solution before a tetragonal phase is converted into a monoclinic phase, then the monoclinic-phase molybdenum-doped bismuth vanadate photoelectrode is coated with a molybdenum salt solution, finally phase transformation is achieved through annealing, and the monoclinic-phase molybdenum-doped bismuth vanadate photoelectrode is obtained. The photoelectrode has a columnar structure composed of nanoparticles, has a large specific surface area, is beneficial to carrier separation, and has better performance of photoelectrochemically degrading amino acid and producing hydrogen. And the photoelectrochemical hydrogen production performance of the photoelectrode can be greatly improved and the degradation of the amino acid can be completed by dissolving the amino acid with a certain concentration in water.

The present invention relates to a perovskite photoanode and, more specifically, to a perovskite photoanode comprising: an oxygen generation part comprising a first lower electrode, a first electron transport layer formed on the first lower electrode, a perovskite first light absorbing layer formed on the first electron transport layer, a first hole transport layer formed on the first light absorbing layer, a first upper electrode formed on the first hole transport layer, a first Ni thin-film layer formed on the first upper electrode, and an oxygen evolution reaction catalyst layer formed on the first Ni thin film layer; and a passivation part comprising a second lower electrode, a second electron transport layer formed on the second lower electrode layer, a perovskite second light absorbing layer formed on the second electron transport layer, a second hole transport layer formed on the second light absorbing layer, a second upper electrode formed on the second hole transport layer, and a second Ni thin-film layer formed on the second upper electrode, wherein the first lower electrode and the second upper electrode are electrically connected to each other.

The invention discloses a preparation method and application of an ultrathin large-size hexagonal boron nitride nanosheet capable of being produced on a large scale, and belongs to the technical field of two-dimensional material preparation. The method comprises the following steps: 1, preparing a boron nitride dispersion solution; 2, performing ultrasonic oscillation on the boron nitride dispersion liquid by using an ultrasonic processor; 3, stirring the boron nitride dispersion liquid subjected to ultrasonic pretreatment at an ultra-high speed by using a wall breaking machine; and 4, centrifuging the stirred boron nitride, taking supernate, washing and drying to obtain the ultrathin large-size boron nitride nanosheet. The preparation method disclosed by the invention has the characteristics of simplicity, high efficiency, economy, environmental protection, high yield, high reliability, large-scale preparation and the like, and the prepared boron nitride nanosheet has the advantages of large sheet diameter, small thickness, uniform particles, high lattice integrity and the like, and can be applied to the fields of thermal management, energy storage and photoelectrochemistry of electronic devices.

The invention discloses a seawater chemical oxygen demand determination method based on bias voltage photoelectric oxidation, and relates to the technical field of water quality monitoring. The method comprises the following steps: collecting seawater and performing pretreatment to obtain a seawater sample; adding supporting electrolyte into the seawater sample to obtain an electrolytic water sample; the method comprises the following steps: injecting an electrolysis water sample into a photoelectrochemical reaction tank, applying bias voltage to a working electrode by taking Ag / AgCl as a reference electrode, and turning on a light source with a specific wavelength for irradiation; carrying out an oxidation reaction in the photoelectrochemical reaction tank, and after the oxidation reaction of the organic matter is complete, obtaining a steady-state photocurrent with a stable current signal; according to a preset steady-state light current-COD concentration curve, a COD measured value is obtained, the COD standard concentration value is corrected according to the water temperature and the salinity, and a COD corrected value is obtained. An adjustable tiny external bias voltage is introduced to cooperate with light source irradiation, so that rapid, accurate and high-anti-interference measurement of COD in seawater is realized.

The invention discloses a carboxymethyl beta-cyclodextrin modified D-A COF material and a preparation method and application thereof.Benzotrithiophene is used as an electron donor, triazine is used as an electron withdrawing unit, imine-connected D-A COFs are successfully synthesized through a solvothermal method, the imino COFs and carboxymethyl beta-cyclodextrin are treated through a Ugi multi-component reaction, and the COF material is prepared. And the COFBTT-TAPT photoactive material containing the beta-cyclodextrin group is obtained through preparation. COFBTT-TAPT-beta-CD and Mxene form a heterojunction to further enhance the photoelectric conversion efficiency of the photoactive material, and the photoactive material is used for preparing a photoelectrochemical sensor, so that high-sensitivity field screening of PFOS (perfluorooctane sulfonate) can be carried out in a low concentration range.

The invention provides a wide-spectrum dual-photoelectrode-based photoelectrochemical sensor and a preparation method and application thereof, and belongs to the technical field of photoelectrochemical sensors. According to the photoelectrochemical sensor provided by the invention, a BCN / ITO electrode is used as a photoanode, a CuInS2 / ITO electrode is used as a photocathode, BCN is Bi2S3 / C3N4, and ITO is indium tin oxide. The sensor is used for detecting enrofloxacin and ciprofloxacin pollution. According to the present invention, the surface is modified with the aptamer having the specific recognition function, the specific binding effect of the aptamer with the enrofloxacin and the ciprofloxacin is utilized to form the complex of the aptamer and the target object, and the influence of the caused steric hindrance effect on the photoelectric signal and the dual-channel strategy are utilized to achieve the simultaneous detection of the residual marker; the linear ranges for detecting enrofloxacin and ciprofloxacin are 0.1 nM to 1 mu M and 50 pM to 0.5 mu M respectively, the detection limits are 24 pM and 15.5 pM respectively, and the method is successfully applied to simultaneous detection of residual markers in water. The method has the advantages of greenness, environmental protection, wide detection range, high sensitivity, good selectivity and high stability.

The invention discloses a cyromazine concentration detection and analysis method and system, and relates to the technical field of pesticide residue detection.The method comprises the specific steps that a cyromazine detection chip is prepared, an integrated signal probe is prepared, a detection reaction system is constructed, triple cooperative response signals are collected, multiple signals are fused, and the cyromazine concentration is calculated; the cyromazine detection chip and the integrated signal probe are prepared, the fluorescence, electrochemistry and SERS triple synergistic response signal acquisition technology is combined, the accuracy of cyromazine concentration detection is improved, the gold nanoparticle modified substrate and the gold nanorod loaded fluorescence and electrochemical active substances are utilized, the response strength of the signal probe is enhanced, and the sensitivity of the signal probe is improved. The fluorescence spectrophotometer can detect cyromazine with lower concentration, meanwhile, the electrochemical workstation and the Raman spectrometer are introduced, so that the electrochemical peak current and SERS characteristic peak displacement are accurately acquired, signals from different sources are normalized, and errors existing among single signals are eliminated.

The invention belongs to the technical field of electrochemical detection sensors, and particularly relates to a photoelectrochemical sensor for dopamine concentration detection and a preparation method and application thereof. The photoelectrochemical sensor comprises a working electrode, a counter electrode and a reference electrode, and specifically, the working electrode, the counter electrode and the reference electrode are sequentially connected to an electrochemical workstation to obtain the photoelectrochemical sensor. The working electrode is an indium tin oxide electrode; a Bi4O5Br2 / g-C3N4 / Au composite material is deposited on the surface of the indium tin oxide electrode. The sensor provided by the invention is excellent in detection performance, has the advantages of simple preparation process, low cost, good environmental stability and the like, provides a reliable new method for clinical dopamine detection, and has an important application prospect in early diagnosis of neurodegenerative diseases such as Parkinson's disease and the like.

The invention discloses a construction method and application of an electrochemical luminescence (ECL) biosensor based on a cell membrane hydrogel antifouling interface, and belongs to the technical fields of photo / electrochemical analysis, interface antifouling and biosensing. According to the invention, the cell membrane hydrogel is used as an efficient antifouling interface, so that non-specific adsorption of interfering proteins in a sample to be detected is hindered, and the service life of the biosensor is prolonged. Meanwhile, a luminophor copper nanosheet and a quencher MnO2 nanosheet are both introduced into the cell membrane hydrogel, in the presence of alkaline phosphatase (ALP), L-ascorbic acid-2-trisodium phosphate is catalyzed and hydrolyzed into ascorbic acid, and then MnO2 is reduced to recover ECL emission of the copper nanosheet. Therefore, the ECL signal of the biosensor is in a rising trend along with the rising of the ALP concentration. Based on this, the constructed ECL biosensor realizes sensitive detection of ALP, the linear range is 10 <-5 >-10 < 4 > U / L, and the detection limit is as low as 3.4 * 10 <-6 > U / L, which indicates that the ECL biosensor has potential application in clinical diagnosis.

The invention discloses a defect layer modified TiO2 nanowire array photo-anode and a preparation method thereof, and belongs to the technical field of photoelectrochemistry. The Ti thin film is deposited on the surface of TiO2 NWAs growing on the substrate in a magnetron sputtering mode, then annealing treatment is conducted in the N2 atmosphere, Ti can capture O atoms in TiO2 crystal lattices in the annealing process, a TiO2 defect layer containing oxygen vacancies is formed on the surface, the lower Fermi energy level is helped to be obtained, the Fermi energy level tends to be balanced when the Ti thin film and a main body TiO2 nanowire form a homojunction, and therefore the TiO2 defect layer with the oxygen vacancies is formed. Therefore, a built-in electric field is generated, migration of photon-generated carriers is promoted, and the utilization rate of light is enhanced. The surface defect state concentration is regulated and controlled by further regulating and controlling conditions such as Ti film deposition time and annealing temperature, so that the prepared photo-anode has better PEC performance; the invention provides an effective means for regulating and controlling the photoelectrocatalytic performance of TiO2, and also provides a theoretical basis for related applications.

The invention provides a cascade amplification-based photoelectrochemical biosensor and application thereof in ultra-sensitive detection of cardiac troponin, and belongs to the technical field of biosensing. A nuclear track membrane containing a plurality of nano-pore channels is used as a base material, Z-type heterojunction g-C3N4 (at) CdS quantum dots are modified to the inner walls of the nano-pore channels of the nuclear track membrane, then an aptamer Apt1 and ssDNA1 double-chain heterocomplex is sequentially fixed to the inner walls of the nano-pore channels of the nuclear track membrane through an amidation reaction, and then ssDNA2-MB is modified to the inner walls of the pore channels to form a double-lock recognition interface. H1 and H2 hairpin DNA are respectively modified with Fe3O4 (at) Pt nano-enzyme and are pre-assembled in a nano-pore channel, and then non-specific sites are closed to obtain the cascade amplification-based photoelectrochemical biosensor, so that ultrasensitive (0.02 fmol / mL) and high-specificity detection of cTnI is realized, and the detection sensitivity of cTnI is greatly improved. Meanwhile, the operation process is simplified, and the anti-interference performance is improved. The invention further discloses the application of the photoelectrochemical biosensor in cardiac troponin ultra-sensitive detection.

This invention discloses a copper-based ternary chalcogenide semiconductor material, its preparation method, and its applications. The material is prepared by mixing CuSn(OH)6 nanomaterials, thioacetamide, ethylenediaminetetraacetic acid, and water and carrying out a hydrothermal reaction to obtain Cu3SnS4 nanomaterials. This semiconductor material exhibits excellent photoelectrochemical properties. Photoelectrochemical sensors constructed based on this material demonstrate high detection accuracy, fast response speed, low detection limit, and strong stability, enabling rapid and accurate real-time detection of microplastic content. The preparation method is simple, low-cost, and suitable for industrial production.

The invention discloses a detection method for high-sensitivity detection of chlorpyrifos based on OPECT and application, a prepared TiO2 / CdS / CPF gate electrode, an OECT transistor, a reaction chamber and a PBS buffer solution are assembled into a biosensor, an object to be detected is dropped on the surface of the gate electrode and irradiated by an LED light source, OPECT detection is carried out, and high-sensitivity and high-specificity detection of chlorpyrifos (CPF) is successfully realized. According to the detection method, a traditional gate electrode is replaced with a TiO2 / CdS heterojunction, the TiO2 / CdS heterojunction serves as a photosensitive gate to be introduced into an organic photoelectrochemical transistor (OPECT) system, the light absorption capacity and the charge separation efficiency are remarkably improved through the narrow-band gap synergistic effect of the heterojunction, and the bottleneck that traditional TiO2 is low in photoelectric conversion efficiency is solved.

The invention provides an organic photoelectrochemical synaptic transistor and a preparation method and a regulation and control method thereof, and belongs to the technical field of transistors. The transistor comprises a substrate, a gate electrode, a source electrode, a drain electrode, an organic semiconductor channel layer and an electrolyte layer; according to the invention, various synaptic plasticity functions can be realized on a single synaptic transistor device through a simple and efficient preparation process; the method has the advantages of simplicity, high efficiency and convenience in large-scale integration. The synergistic effect of photons, electrons and ions is used as a regulation and control mechanism, a single-component n-type organic semiconductor is used as a channel layer material, voltage programming pulses are applied to a grid electrode, light irradiation is applied to a channel layer to simulate biological synaptic stimulation, output current is obtained at a source electrode and a drain electrode to simulate post-biological synaptic current, and the potential safety hazard is eliminated. Information encryption, compiling, hiding and recovery of the Morse code are simulated based on the output pulse current, and the method can be widely applied to the brain-like intelligence field of cognitive judgment with information double anti-counterfeiting encryption.