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80 results about "Dimethyl sulfide" patented technology

Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH₃)₂S. Dimethyl sulfide is a flammable liquid that boils at 37 °C (99 °F) and has a characteristic disagreeable odor. It is a component of the smell produced from cooking of certain vegetables, notably maize, cabbage, beetroot and seafoods. It is also an indication of bacterial contamination in malt production and brewing. It is a breakdown product of dimethylsulfoniopropionate (DMSP), and is also produced by the bacterial metabolism of methanethiol.

Inversion method of methane sulfonic acid particles in marine droplet aerosol based on box-type model

The invention relates to the technical field of environmental science, in particular to a box-type model-based inversion method for methane sulfonic acid particles in marine droplet aerosol, which comprises the following steps of: 1, acquiring satellite remote sensing data, ground observation data and laboratory simulation data, and carrying out data standardization processing; 2, dividing the target sea area into a plurality of sub-areas as independent box bodies; 3, calculating the discharge flux of the marine droplet aerosol based on the dimethyl sulfide concentration and the wind speed, and updating the spatial and temporal distribution of the discharge source; 4, embedding a chemical reaction path for oxidizing dimethyl sulfide on the surface of the aerosol into the box-type model to generate methanesulfonic acid, and introducing the specific surface area of the aerosol to correct the reaction rate; and step 5, outputting spatio-temporal distribution of the concentration of the methane sulfonic acid, and comparing measured data for verification. The accuracy of aerosol source item estimation is improved, the fusion efficiency of multi-source data is improved, and the adaptive capacity of the model in a complex environment is enhanced.
Owner:BEIHAI FORECASTING CENT OF STATE OCEANIC ADMINISTRATION ((QINGDAO MARINE FORECASTING STATION OF STATE OCEANIC ADMINISTRATION) (QINGDAO MARINE ENVIRONMENT MONITORING CENT OF STATE OCEANIC ADMINISTRATION)) +1

Asphalt-based hard carbon, preparation method thereof and sodium ion battery negative electrode material

The invention discloses asphalt-based hard carbon, a preparation method thereof and a sodium-ion battery negative electrode material, and relates to the technical field of sodium-ion batteries. The preparation method of the asphalt-based hard carbon comprises the following steps: S1, mixing an asphalt precursor, a sulfur source and a cross-linking agent, and performing cross-linking vulcanization treatment at a first temperature to obtain a primary product; s2, performing carbonization treatment on the primary product at a second temperature to obtain asphalt-based hard carbon; the sulfur source is any one of elemental sulfur, thiourea, dimethyl sulfide and sulfide, or any two of elemental sulfur, concentrated sulfuric acid, thiourea, dimethyl sulfide and sulfide. By adopting the method, the type of the sulfur source is controlled, and the sulfur source and the cross-linking agent are added, so that the reversible capacity and the rate capability of the asphalt-based negative electrode material can be effectively improved, and the application field of the asphalt-based negative electrode material is widened.
Owner:CHINA SHENHUA COAL TO LIQUID & CHEM CO LTD +1

Method for synthesizing and refining DMS and DMSO embedded into methanol plant

PendingCN120923390AOrganic compound preparationSulfide preparationOrganic sulfide compoundSulfide
The invention relates to the technical field of organic sulfide preparation, in particular to a method for synthesizing and refining dimethyl sulfide (DMS) and dimethyl sulfoxide (DMSO) embedded into a methanol plant, which mainly utilizes high-purity oxygen of an air separation unit of the methanol plant, a high-concentration hydrogen sulfide product of low-temperature methanol washing and part of top gas-phase refined methanol of a pressurizing tower of a methanol rectification device. The production cost of the product is reduced, the added value of the product is improved, and the hydrogen sulfide product of a methanol plant is effectively utilized.
Owner:TIANJIN UNIV

Temperature interference resistant core-sheath structure strain sensing fiber and preparation method thereof

The invention provides an anti-temperature interference core-sheath structure strain sensing fiber and a preparation method thereof, and relates to the technical field of composite materials, the fiber comprises a flexible core layer and a conductive shell layer coating the flexible core layer; wherein the flexible core layer is prepared by mixing thermoplastic polyurethane and DMF (Dimethyl Formamide); the conductive shell layer is prepared by mixing thermoplastic polyurethane, DMF (Dimethyl Formamide), a silver nanowire and a multi-walled carbon nanotube, and the mass ratio of the silver nanowire to the multi-walled carbon nanotube is (0.12-0.15): (0.05-0.1). The excellent temperature interference resistance is realized in a wide temperature range (0-60 DEG C) by regulating silver nanowires with positive resistance temperature coefficients and multi-walled carbon nanotube materials with negative resistance temperature coefficients, the resistance temperature coefficients reach 300 ppm / DEG C, and meanwhile, the fiber is endowed with excellent elasticity by the core-sheath structure. Continuous production is achieved through wet spinning, efficiency is high, and cost is low.
Owner:JIANGSU TEXTILE PROD QUALITY SUPERVISION & INSPECTION INST

Thin film evaporation device for removing dimethyl sulfide

The utility model discloses a thin film evaporation device for removing dimethyl sulfide, which comprises a thin film evaporation container main body, the top of the thin film evaporation container main body is provided with a feed port, and the top of the right side of the thin film evaporation container main body is provided with a steam heating external connection pipe used for being externally connected with a steam heater; and a film mesh is arranged in the film evaporation container main body. According to the utility model, the dimethyl sulfide material is spread on the film mesh through the rotating scraper blade to form a film so as to promote evaporation, and the thickness of the film scraped by the scraper blade can be adjusted according to the viscosity of the material and the change of the raw material, so that the situation that the evaporation efficiency is influenced by the too thick or too thin dimethyl sulfide material in the prior art is avoided; and the structure is simple, and adjustment is convenient, so that the scraper blade can flexibly adjust the thickness of the film according to actual changes, the adaptability in evaporation use is improved, and the use requirement for accurate removal of dimethyl sulfide is greatly met.
Owner:YANCHENEG HUIHUANG CHEM

Electrolyte, preparation method thereof, injection method and lithium ion battery

The present invention relates to the field of lithium-ion battery technology, and more particularly to an electrolyte, a preparation method thereof, an injection method, and a lithium-ion battery. The electrolyte comprises a first electrolyte for a first injection and a second electrolyte for a second injection. The first electrolyte comprises a first solvent, a first lithium salt, and a first additive, and the second electrolyte comprises a second solvent, a second lithium salt, and a second additive. The second electrolyte accounts for 5% to 20% of the electrolyte by mass, the first additive comprises dimethyl sulfide and vinylene carbonate, and the second additive comprises triphenyl phosphite and vinylene carbonate. By including dimethyl sulfide in the first additive and triphenyl phosphite in the second additive, the electrolyte improves the problems of high-temperature gassing and black spots at the negative electrode interface during use of lithium-rich material lithium supplements.
Owner:XIAOGAN CORNEX NEW ENERGY INNOVATION TECHNOLOGY CO LTD

Production device for producing dimethyl sulfoxide by using micro-channel reactor and application of production device

The invention discloses a production device for producing dimethyl sulfoxide by using a micro-channel reactor and application of the production device, and belongs to the technical field of dimethyl sulfoxide production. The production device for producing dimethyl sulfoxide by using the micro-channel reactor comprises a refined thioether buffer tank and a hydrogen peroxide buffer tank, the refined thioether buffer tank is connected with a sulfoxide reaction device through a pipeline, a rectified ether feeding pump is mounted on the pipeline between the refined thioether buffer tank and the sulfoxide reaction device, and the hydrogen peroxide buffer tank is connected with the refined thioether buffer tank through a pipeline between the refined thioether buffer tank and the sulfoxide reaction device. The hydrogen peroxide buffer tank is connected with the sulfoxide reaction device through a pipeline, and a hydrogen peroxide feeding pump is mounted on the pipeline between the hydrogen peroxide buffer tank and the sulfoxide reaction device. According to the production device for producing dimethyl sulfoxide by using the micro-channel reactor, mixing, heat exchange and reaction are integrated by using the micro-channel reactor, so that dimethyl sulfide and hydrogen peroxide are fully mixed, reaction heat is removed while the reaction is rapid, and the reaction is better controlled.
Owner:LIAONING LIGHT IND DESIGN INST CO LTD

Combined structure of small-diameter tower plates

The invention relates to a combined structure of small-diameter tower plates, which is mainly used for liquid collection, distribution and mass transfer processes, and is particularly suitable for synthesis and refining processes of dimethyl sulfide (DMS) and dimethyl sulfoxide (DMSO). The device comprises a tray (1), an upper flange (2), a clamping piece (3), a lower flange (4), a tubular distributor (5) and a packed bed layer limiter / distribution guide plate (6) from top to bottom, the tower tray (1) adopts a radial flow design, and liquid descends from the middle to flow towards the periphery and then flows from the periphery to the middle; and the tubular distributor (5) and the packed bed layer limiter / distribution guide plate (6) are combined into a whole. According to the small-diameter tower plate structure, the mass transfer efficiency is remarkably improved.
Owner:TIANJIN UNIV

Deodorizing spirit distillation equipment

The utility model relates to the technical field of wine liquid production, in particular to deodorizing spirit distillation equipment which comprises a distillation copper pot, a condenser and at least one maintaining pipe. The distillation copper pot is used for distilling the wine liquid into wine liquid steam. The condenser is arranged outside the distillation copper pot and located on the downstream portion of the distillation copper pot so as to be used for receiving and condensing wine steam in the distillation copper pot. The maintaining pipe is located between the distillation copper pot and the condenser and used for conveying wine steam in the distillation copper pot to the condenser. The maintaining pipe made of the copper-containing material is arranged between the distillation copper pot and the condenser, and the maintaining pipe is arranged upwards in the vertical direction in a winding manner, so that the reaction time between the wine steam and the copper material is prolonged, the odor carried by components such as dimethyl sulfide in the wine steam is better purified, and the quality of the wine is improved. And various flavor sensory characteristics are added to the spirit.
Owner:CIMC ANRELYL (NANTONG) TECH CO LTD

Tetra-coordinated boron-oxygen heterocyclic compound and preparation method thereof

The invention discloses a tetra-coordinated boron-oxygen heterocyclic compound and a preparation method thereof, and belongs to the technical field of pharmaceutical and chemical intermediates and related chemistry. The method comprises the following steps: by taking a bis (pentafluorophenyl) borane dimethyl sulfide complex [(C6F5) 2BHSMe2] as a boron source, firstly carrying out hydroboronation reaction on the bis (pentafluorophenyl) borane dimethyl sulfide complex [(C6F5) 2BHSMe2] and an eneyne compound to generate a three-coordination alkenyl boron dienophile intermediate in situ, and then carrying out reverse electron demand Diels-Alder reaction on the three-coordination alkenyl boron dienophile intermediate and an acetylenic ketone compound to synthesize a series of tetra-coordination boron-oxygen heterocyclic compounds. The method has the advantages of mild reaction conditions, good selectivity, high yield, wide substrate application range, environmental friendliness, simplicity and convenience in operation and the like, opens up a new way for synthesis of the tetra-coordinated organoboron compound, and has higher application value and social and economic benefits.
Owner:DALIAN UNIV

Hexafluoropropylene oxide and synthesis method and synthesis device thereof

PendingCN120607498AOrganic chemistryPhysical chemistryHexafluoropropylene oxide
The invention belongs to the technical field of organic fluorine chemical industry, and particularly relates to hexafluoropropylene oxide as well as a synthesis method and a synthesis device thereof. The synthetic method of the hexafluoropropylene oxide comprises the following processes: firstly, heating dimethyl sulfide and monochlorodifluoromethane in a solvent for reaction, then adding the obtained intermediate into a sodium hydride solution at 30-50 DEG C for reaction to obtain a reaction solution, finally, adding trifluoroacetyl fluoride into the reaction solution for reaction at 15-30 DEG C, treating the obtained reaction solution, and finally, separating and purifying to obtain the hexafluoropropylene oxide. The hexafluoropropylene oxide is obtained. And recovering the solvent and dimethyl sulfide. The synthesis method of hexafluoropropylene oxide provided by the invention is mild in reaction condition and stable in reaction, the synthesized hexafluoropropylene oxide is high in yield and high in purity, and the invention also provides a synthesis device of hexafluoropropylene oxide, which is low in energy consumption.
Owner:ZIBO FEIYUAN CHEM CO LTD

Synthesis method of high-abundance C-13 ethylene oxide compound

The invention discloses a synthesis method of a high-abundance C-13 ethylene oxide compound, which comprises the following steps: (1) carrying out reaction on 13CH3I and diphenyl sulfide to obtain [13C] diphenylmethyl iodide; and (2) reacting the [13C] diphenylmethyl iodide with a carbonyl compound to obtain the high-abundance [13C] ethylene oxide compound. Diphenyl sulfide is adopted to replace dimethyl sulfide, the obtained [13C] methyl diphenyl sulfonium iodide avoids C-13 loss in the subsequent reaction process, and the abundance of C-13 is effectively improved.
Owner:JIANGSU JINBOQI ISOTOPE TECHNOLOGY CO LTD

Method for producing compound

ActiveUS12428387B2Organic compound preparationPreparation from ortho-estersArylCompound a
A method by which an intermediate product of an azole derivative can be produced at a lower cost than known production methods is provided. A method for producing a compound represented by General Formula (IV) includes converting a compound represented by General Formula (II) into the compound represented by General Formula (IV) using (a) dimethyl sulfide and / or dimethyl sulfoxide, and (b) a methyl-LG (an LG is a nucleophilically substitutable leaving group and is selected from the group consisting of a halogen group, an alkoxysulfonyloxy group, an aryloxysulfonyloxy group, an alkylsulfonyloxy group, a haloalkylsulfonyloxy group, and an arylsulfonyloxy group) in the presence of an inorganic base.
Owner:KUREHA CORPORATION

Preparation method and application of magnetic cellulose carbon aerogel composite electrode material

The present invention relates to the field of carbon aerogel technology, specifically disclosing a method for preparing a magnetic cellulose-carbon aerogel composite electrode material and its application. Using natural pulp as a precursor, the cellulose hydrogel is prepared via a sol-gel process. This hydrogel is then impregnated with ferric chloride, freeze-dried, and finally pyrolyzed in a tubular furnace to produce a magnetic cellulose-carbon aerogel (CA@Fe3O4) composite material. The magnetic cellulose-carbon aerogel prepared in this invention exhibits high specific surface area, good electrical conductivity, and excellent biocompatibility. Used in microbial fuel cell anodes, it can degrade dimethyl sulfide while converting chemical energy into electrical energy, enabling the renewable utilization of organic matter.
Owner:ZHEJIANG UNIV OF TECH

Quantitative analysis method for measuring trace dimethyl sulfide impurities in dimethyl disulfide product

The invention relates to a quantitative analysis method for determining trace dimethyl sulfide impurities in a dimethyl disulfide product, a high performance liquid chromatograph-variable wavelength detector is adopted for analysis, and the specific analysis method comprises the following steps: preparing a standard solution and a sample to be detected; and detecting the components of the sample to be detected by adopting a liquid chromatography system-variable wavelength detector (VWD). Wherein the detection conditions are as follows: a C18 chromatographic column, a quaternary pump and an automatic sampling system are adopted, a mobile phase A is ultrapure water, a mobile phase B is acetonitrile, the flow velocity is 0.8-1.2 mL / min, and the column temperature is 30-40 DEG C. According to the present invention, the strong ultraviolet response of DMDS is inhibited by using the high water phase environment, and the retention behavior and the peak shape of DMS are improved by using the solvation effect of the synergist so as to achieve the efficient separation of the main component and the trace impurity; in actual sample determination, the method successfully detects the residual trace DMS in the industrial grade disulfide, the result is stable and reliable, and the method is suitable for product quality control and process optimization.
Owner:新疆兴发化工有限公司

Preparation method of composite roasted peanut essence

PendingCN121489116AFood ingredient as taste affecting agentFood ingredient as flavour affecting agentTetramethyl pyrazineIsovaleraldehyde
The invention discloses a preparation method of composite roasted peanut essence, which belongs to the technical field of essence, and comprises the following steps: preheating peanut oil and caprylic / capric triglyceride; the preparation method comprises the following steps: dissolving ethyl maltol, vanillin, methyl cyclopentenolone, 2, 3, 5-trimethylpyrazine and 2-acetylpyrazine; vanillin propylene glycol acetal, isovaleraldehyde propylene glycol acetal, triethyl citrate, delta-decalactone, delta-dodecalactone and 5-hydroxyethyl-4-methylthiazole are fused to obtain a mixture; dispersing the roasted peanut extract; 2, 3-dimethylpyrazine, 2-methoxyl-5-methylpyrazine and 4-methylthiazole are fused, and then the mixture is subjected to a reaction; the preparation method comprises the following steps: fusing cocaal, dimethyl sulfide, 2-ethyl-3, 5, 6-dimethylpyrazine, 2, 3, 5, 6-tetramethylpyrazine, 2-methylpyrazine, 2-acetylpyridine, 2-methoxy-3. 5. 6-isopropyl pyrazine, 2-methylthio-3-methylpyrazine, isovaleric acid, 1-octylene-3-alcohol, 5-methylfurfural and 3, 4-dimethyl-1, 2-cyclopentanedione; standing is performed; filtering is performed; the fragrance of the roasted peanuts is closer to that of the roasted peanuts which are just taken out of a furnace, and the natural flavor of the roasted peanut essence is increased.
Owner:GUANGZHOU FENMAN BIOTECHNOLOGY CO LTD

Carbon-coated nickel-chromium catalyst with external sulfur source as well as preparation method and application of carbon-coated nickel-chromium catalyst

The invention provides a carbon-coated nickel-chromium catalyst with an external sulfur source and a preparation method and application thereof, and the preparation method comprises the following steps: A) dissolving and mixing a nickel source, a chromium source and a carbon source in water, and removing a solvent to obtain a precursor; b) pyrolyzing the precursor in a protective atmosphere to obtain a catalyst precursor; and C) mixing the catalyst precursor with a sulfur source solution to obtain the carbon-coated nickel-chromium catalyst with the additional sulfur source, a sulfur source in the sulfur source solution comprises one or more of dimethyl sulfoxide, thioacetamide, thiourea, dimethyl disulfide, dimethyl sulfide and p-fluorothiophenol. According to the invention, a pre-sulfurization strategy of adding an organic sulfur source is innovatively adopted, so that the catalyst is endowed with low-temperature high efficiency, high selectivity and strong engineering suitability, and a bottom layer support is provided for kiloton-level industrial amplification.
Owner:EAST CHINA ENGINEERING SCIENCE AND TECHNOLOGY CO LTD +1

Preparation method of eprinomectin intermediate oxide

The invention discloses a preparation method of an eprinomectin intermediate oxide. The eprinomectin intermediate oxide is obtained by taking an abamectin hydroxyl protection substance as a starting raw material through oxidation reaction and post-treatment. According to the invention, active manganese dioxide is adopted as an oxidizing reagent, the operation is simple, the generation of peculiar smell of a by-product dimethyl sulfide during dimethyl sulfoxide oxidation in the prior art is avoided, the yield reaches 98.0% or more, the purity of the oxide can reach 95.0% or more, and the content of double-oxide impurities can be controlled to be 0.2% or less.
Owner:CHANGZHOU YABANG QH PHARMACHEM +1

Calcium dodecahydrododecaborate as well as synthesis method and application thereof

The invention belongs to the technical field of material synthesis, and particularly relates to calcium dodecahydrododecaborate as well as a synthesis method and application thereof. According to the synthesis method of calcium dodecahydrododecaborate provided by the invention, calcium hydride CaH2, a borane dimethyl sulfide complex and an ether mixed organic solvent react in a reaction kettle to obtain a product, and monoethylene glycol dimethyl ether and tetrahydrofuran cyclic ether are compounded to obtain the ether mixed organic solvent; according to the method, the yield and purity of the product calcium dodecahydrododecaborate are improved, meanwhile, deionized water is used for carrying out solvent exchange on the product and drying is carried out, the purity of the product calcium dodecahydrododecaborate is further improved, efficient synthesis of calcium dodecahydrododecaborate is achieved, industrial preparation is facilitated, high-purity calcium dodecahydrododecaborate is provided, and the method is suitable for industrial production. The method is expected to meet the requirement of solid electrolyte battery commercialization on electrolyte, and solves the technical problem of lack of an efficient synthesis process of calcium dodecahydrododecaborate at present.
Owner:SUN YAT SEN UNIV

Sulfur-containing polyethylene glycol derivatives, preparation methods thereof, and applications in selective oxidation of alcoholic hydroxyl groups

The present invention discloses a class of sulfur-containing polyethylene glycol derivatives, a preparation method thereof, and an application thereof in the selective oxidation of alcoholic hydroxyl groups. The derivatives are bis-methylthio polyethylene glycol and bis-methylsulfinyl polyethylene glycol, which are polyethylene glycol-supported methylthio and methylsulfinyl groups. The bis-methylthio polyethylene glycol can replace dimethyl sulfide as an activator in the Corey-Kim oxidation, and an important intermediate compound 2'-benzyloxycarbonyl-4"-oxoazithromycin A for the synthesis of tulathromycin is obtained with a yield of 78.8%; and 2'-benzyloxycarbonyl-4"-oxoazithromycin A is obtained with a yield of 90.3%. 5-O-(tert-butyldiphenylsilyl)-23-oxonimoctine, an important intermediate compound in the synthesis of moxidectin, is prepared using bis(methylsulfinyl)polyethylene glycol (PEG) as an oxidant in the Swern oxidation, replacing dimethyl sulfoxide. The sulfur-containing PEG derivatives of the present invention are low-cost to prepare and can be used in Corey-Kim and Swern oxidations, avoiding the use or production of foul-smelling dimethyl sulfide and providing a green environment for these reactions.
Owner:SHAANXI NORMAL UNIV

A MOFs derived N-rich doped three-dimensional porous Co / NC-D composite material and a preparation method thereof

The application discloses a MOFs derived N-rich doped three-dimensional porous Co / NC-D composite material and a preparation method thereof. The method comprises the following steps: adding an organic ligand into methanol and ultrasonically dissolving to obtain an organic ligand solution; adding Co(NO3)2.6H2O, Zn(NO3)2.6H2O and dicyandiamide (DCDA) into methanol and ultrasonically dissolving to obtain a metal salt solution; adding the organic ligand solution into the metal salt solution, stirring, centrifuging, washing and drying to obtain a ZIF-67-D or ZnCo-ZIF-D material; and performing calcination, acid washing, filtering, drying and vacuum drying to obtain the material. Compared with Co / AC, Co / rGO and a material obtained by directly calcining ZIF-67, the material has good dispersity and small Co nanoparticles and a synergistic effect between Co and N species, exhibits excellent performance in catalyzing dimethyl sulfide oxidation under mild conditions and has recyclability and a good application prospect.
Owner:SOUTH CHINA UNIV OF TECH

Process for preparation of triazole compound

Processes for preparation of a high purity cyproconazole, i.e., (2RS,3RS;2RS,3SR)-2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl) butan-2-ol; and its compound i.e., 2-(4-chlorophenyl)-2-(1-cyclopropylethyl) oxirane generally includes reacting a ketone of formula (II) with a sulfonium salt in the presence of a base to obtain the oxirane compound of formula (III);wherein the sulfonium salt is obtained by reacting dimethyl sulfide and dimethyl sulfate in the presence of water; followed by reacting the oxirane compound of formula (III) with 1,2,4-triazole or its alkali metal salt to obtain a crude cyproconazole; and treating the crude cyproconazole with an aqueous alcohol to obtain a higher purity cyproconazole.
Owner:UPL LTD

Karl Fischer moisture determination method for sulfur-containing organic compound

The invention discloses a Karl Fischer moisture determination method for sulfur-containing organic compounds, and belongs to the technical field of chemical analysis. The method comprises the following steps: adding absolute methanol, imidazole and an inhibitor (selected from N-substituted maleimide or acrylate compounds) into a titration system, then adding a sample, and titrating with a pyridine-containing Karl-Fischer reagent to the end point. The inhibitor can effectively capture reducing sulfur species and eliminate interference of the reducing sulfur species on iodine. Experiments show that for sulfur-containing samples such as 2, 2-dimethylthiopropane, dimethyl sulfide, dimethyl disulfide and the like, the deviation reduction rate of the method is more than 60% compared with that of a traditional method; the method is easy and convenient to operate, high in accuracy and suitable for moisture analysis of sulfur-containing organic matter in the fields of petrifaction, pharmacy and the like.
Owner:WUHENG CHEMICAL (PINGDINGSHAN) CO LTD

Solid composition containing dimethyl sulfide and dextrin

A solid composition comprises dimethyl sulfide and dextrin. The solid composition includes dimethyl sulfide in an amount of at least 2.1 μg per gram of the solid composition (2.1 μg / g). The dextrin present in the composition has a molecular weight of 50,000 or more. The solid composition comprises linear dextrin and cyclic dextrin, wherein the cyclic dextrin is one or more cyclodextrin(s) selected from the group consisting of α-cyclodextrin and γ-cyclodextrin.
Owner:SUNTORY HLDG LTD

Method for preparing methyl mercaptan and dimethyl sulfide by reducing SO2 with methanol

The invention relates to a method for preparing methyl mercaptan and dimethyl sulfide by reducing SO2 with methanol, which comprises the following steps: 1) deoxidizing, purifying and concentrating metallurgical flue gas to obtain high-concentration SO2 gas as raw material gas, preheating, and feeding into a main reactor; preheating methanol raw material gas and hydrogen sulfide gas, and introducing the preheated gas into the main reactor; (2) carrying out reduction reaction on each raw material gas under the action of a catalyst in the main reactor to generate methyl mercaptan; (3) enabling gas flow flowing out of the main reactor to enter a condensing heat exchanger, recovering generated methyl mercaptan in a liquid form through condensation, and enabling non-condensable gas to enter a hydrogen sulfide absorption and separation unit; 4) desorbed and regenerated hydrogen sulfide gas is returned to the main reactor; and 5) purifying methyl mercaptan, and then carrying out a synthetic reaction in the secondary reactor to obtain dimethyl sulfide (DMS). Compared with the prior art, the method has the advantages that the reduction reaction temperature of SO2 is obviously reduced, the reaction rate and the yield of methyl mercaptan are obviously increased, and the method has better application and popularization prospects.
Owner:SHANGHAI JIAOTONG UNIV

Online detection method for dimethyl sulfide synthesis gas

The invention relates to the technical field of dimethyl sulfide detection, and particularly discloses a dimethyl sulfide synthesis gas on-line detection method, which comprises the following steps of: filtering synthesis gas from a sampling port of a synthesis device, feeding the filtered synthesis gas into a gas inlet of a six-way valve, and analyzing and testing by adopting a gas chromatograph; the method can effectively separate various components in the dimethyl sulfide synthesis gas, has the characteristics of high analysis speed and accurate and reliable result, can adapt to the dynamic change of the synthesis gas components in the synthesis reaction process, and provides powerful data support for process control.
Owner:HUBEI XINGFA CHEM GRP CO LTD +1

Composite livestock and poultry manure deodorant as well as preparation method and application thereof

The invention relates to the technical field of foul smell treatment in livestock and poultry breeding, in particular to a compound livestock and poultry manure deodorant as well as a preparation method and application thereof. The deodorant comprises a compound microorganism culture solution, a plant compound extracting solution and a chemical absorbent, the compound microorganism culture solution comprises a culture solution of sulfur oxidizing bacteria, a culture solution of dimethyl sulfide degrading bacteria, a culture solution of trimethylamine degrading bacteria and a culture solution of ammonia oxidizing bacteria; the plant composite extracting solution comprises a plant extracting solution and a surfactant; the raw materials of the plant extracting solution are selected from one or more of honeysuckle, raspberry and clove; the chemical absorbent comprises zinc diricinoleate. The composite livestock and poultry manure deodorant provided by the invention is simple in process and relatively low in cost, has the characteristics of fast deodorization effect and lasting effect, and is suitable for popularization and application in production practice.
Owner:ZHEJIANG OCEAN UNIV

Foamed asphalt mixture as well as preparation method and application thereof

The invention discloses a foamed asphalt mixture as well as a preparation method and application thereof, and relates to the technical field of asphalt preparation. The foamed asphalt mixture prepared by the preparation method disclosed by the invention is prepared from modified asphalt, pure water, aggregate, cement, modified zeolite, pentaerythritol tetra-3-mercaptopropionate and a nucleophilic reagent. The modified asphalt is obtained by mixing modified SBS and matrix asphalt; the modified SBS is obtained by reacting chlorosulfonated SBS with [(4-aminophenyl) (hydroxyl) methyl] diethyl phosphonate, brominating and reacting with dimethyl sulfide; the modified zeolite is obtained by reacting pretreated zeolite with carbon dioxide, grafting 2, 2, 6, 6-tetramethylpiperidine-4-yl 4-aminobenzoate, and then reacting with methacrylic anhydride. The foamed asphalt mixture prepared by the preparation method disclosed by the invention has good flame retardance, ageing resistance and mechanical properties.
Owner:HUBEI FUJIALI BUILDING MATERIALS CO LTD

Walnut essence and preparation method thereof

The invention discloses walnut essence and a preparation method thereof. The essence comprises furanone, methyl cyclopentenolone, 2-acetylpyrazine and benzaldehyde acetal compounds as core components, and the four components synergistically provide vivid and stable roasted walnut characteristic aroma; preferably, the formula also contains auxiliary materials such as butanedione, ethyl maltol, ethyl 2-methylbutyrate, dimethyl sulfide and the like, and ethanol and propylene glycol are used as solvents. According to the invention, benzaldehyde acetal (such as benzaldehyde PGA) is adopted to replace free benzaldehyde, so that the stability of the essence in high-temperature processing is remarkably improved. The prepared essence is rich in fragrance level and lasting in fragrance, and can be widely applied to foods, beverages and daily chemical products.
Owner:SHENGHUA FLAVORS HANGZHOU CO LTD

Corn tea beverage

We offer a corn tea beverage that reduces the scratchy feeling in the throat. [Solution] In a corn tea beverage, guaiacol and dimethyl sulfide at a concentration of 300 ppb or more are added, and the ratio of dimethyl sulfide content to guaiacol content (by mass) is set to 10 or more.
Owner:SUNTORY HLDG LTD