2122 results about "Oil phase" patented technology

The application belongs to the technical field of daily chemical industry, and particularly relates to an emulsion and a preparation method thereof. The emulsion provided in the application comprises an emulsifier, glycerol, oil-phase active substance, pentaerythritol tetra(ethylhexanoate) and water; the emulsifier is a lipopeptide; the weight percentage of the lipopeptide and the glycerol is not less than 3%; the weight ratio of the oil-phase active substance and the pentaerythritol tetra(ethylhexanoate) is 1:3-10; the ratio of the sum of the weights of the lipopeptide and the glycerol to the sum of the weights of the oil-phase active substance and the pentaerythritol tetra(ethylhexanoate) is 1:3-10; and the ratio of the sum of the weights of the lipopeptide, the glycerol, the oil-phase active substance and the pentaerythritol tetra(ethylhexanoate) to the weight of the water is 1:1-4. The emulsion is prepared by using sodium bacillomycin, glycerol and pentaerythritol tetra(ethylhexanoate), can effectively inhibit the diffusion of the oil-phase active substance at the interface of the emulsion, reduce the oxidative degradation of the oil-phase active substance, and greatly prolong the effective action time of the oil-phase active substance in the emulsion.

The invention discloses an ultra-low-density high-strength resin proppant capable of being carried by clear water or low-viscosity slickwater. The proppant is prepared by dispersing, polymerizing and curing a mixture comprising 15 to 50 weight percent of vinyl monomer, 5 to 10 weight percent of acrylate monomer and 50 to 70 weight percent of unsaturated resin. The preparation method comprises the following steps: controlling the resin composition in a water phase by virtue of a dispersing agent and a rotating speed to form spherical liquid drops with the particle size of 12-140 meshes and the sphericity of nearly 100%; then, the temperature ranges from 30 DEG C to 80 DEG C; the propping agent provided by the invention has ultra-low density, can be carried by clear water or low-viscosity slickwater, is suitable for low-viscosity fracturing fluid, low-displacement construction and small-scale fracturing, can realize ultra-far-end seam net support, and greatly increases the oil and gas drainage area. The breaking rate under the closing pressure of 20-90 MPa is lower than 2%, the surface is weakly lipophilic, and the oil-phase flow conductivity is higher than the water-phase flow conductivity.

The utility model discloses reaction equipment with high crude methyl ester yield, which comprises a stirring kettle and a material circulating system, the material circulating system comprises a circulating pump, a spray pipe arranged in the stirring kettle and a mixing nozzle arranged on the spray pipe, and a bottom outlet of the stirring kettle is connected with a feed port of the circulating pump through a first pipeline. An outlet of the circulating pump is connected with the spray pipe through a second pipeline; the mixing nozzle comprises a first sprayer and a second sprayer, and an outer flaring in the lower portion of the second sprayer is in clearance fit with the conical head through a connecting piece. The material circulating system can realize bottom-out and top-in of materials, so that the mixing of an oil phase and an enzyme water phase is promoted through the reciprocating circulation. In addition, the material circulating system is provided with a plurality of mixing nozzles, the flow speed of spraying of the first spray head is large, so that a negative pressure suction gap is formed at the joint of the second spray head and the first spray head, materials in the stirring kettle can enter the mixing nozzles under the action of negative pressure, an oil phase and an enzyme water phase are intensively mixed, and the yield of fatty acid methyl ester is improved.

The invention belongs to the technical field of functional finishing of textiles, and particularly relates to microcapsule emulsion with a pH indicating function, preparation of the microcapsule emulsion and application of the microcapsule emulsion in a textile finishing agent. The invention provides a preparation method of a microcapsule emulsion with a pH indication function, which comprises the following steps: reacting isocyanate with polyol to obtain a polyurethane prepolymer, mixing and dissolving the polyurethane prepolymer with a pH indicator solution, an acrylate monomer and an initiator to obtain an oil phase, and taking an aqueous solution of a polymer emulsifier as a water phase; then mixing and emulsifying the oil phase and the water phase, adding a chain extender, heating to carry out chain extension reaction, cross-linking to a certain degree to form a polyurethane-polyurea-polyacrylate hybrid shell layer on an oil-water interface, and coating a core material pH indicator to obtain the microcapsule emulsion with the pH indication function. According to the invention, the pH indicator is coated in the form of microcapsules for the first time, and industrial production and processing can be carried out.

The application belongs to the technical field of oil and gas field development, and provides a phase permeability improver, a fracturing fluid system containing the same, and respective preparation methods and applications. The phase permeability improver is obtained by copolymerization and hydrolysis of acrylamide AM, a functional monomer 2-acrylamido-2-methylpropanesulfonic acid AMPS, and cationic hydrophobic monomers A and B; the cationic hydrophobic monomer A is at least one of tetradecyl dimethyl allyl ammonium chloride, hexadecyl dimethyl allyl ammonium chloride, and octadecyl dimethyl allyl ammonium chloride; the cationic hydrophobic monomer B is at least one of methacryloyloxyethyl trimethyl ammonium chloride, acryloyloxyethyl trimethyl ammonium chloride, and acryloyloxyethyldimethyl benzyl ammonium chloride; the phase permeability improver and the fracturing fluid system containing the same can significantly reduce the water phase permeability after fracturing operation, while having a smaller influence on the oil phase permeability, and have a significant effect of stabilizing oil and controlling water, and can significantly improve the stable production effect of fracturing operation in a low-permeability oil reservoir.

The invention discloses a method for improving water flux and anti-pollution capacity of a polyamide reverse osmosis membrane and application of the method, and belongs to the technical field of water treatment membranes.The method comprises the steps that a water-phase solution containing polyamine monomers and an oil-phase solution containing polyacyl chloride monomers are respectively subjected to droplet formation into a water-phase solution containing polyamine monomers and an oil-phase solution containing polyacyl chloride monomers through a droplet generator, and the water-phase solution containing polyamine monomers and the oil-phase solution containing polyacyl chloride monomers have the particle size of 10-200 microns; water phase solution droplets and oil phase solution droplets with the specific surface area of 3 * 10 < 4 >-6 * 10 < 5 > m < 2 > / m < 3 > are sequentially sprayed on the ultrafiltration substrate membrane through a moving spray head system, so that the water phase solution droplets and the oil phase solution droplets are fully contacted to generate an interfacial polymerization reaction, and after the spraying process is finished, heat treatment is performed to obtain the polyamide reverse osmosis membrane. According to the method disclosed by the invention, the traditional interfacial polymerization method is improved, a new additive is not introduced, and the water flux and the anti-pollution capacity of the polyamide reverse osmosis membrane are further improved on the basis of reducing the solvent dosage.

The invention discloses application of a particle stabilizer, an oil-in-oil Pickering emulsion as well as a preparation method and application of the oil-in-oil Pickering emulsion, and relates to the technical field of emulsion preparation. The particle stabilizer is used for preparing the oil-in-oil Pickering emulsion, and the particle stabilizer is solid insoluble nanoparticles and is selected from one or more of inorganic nanoparticles, organic nanoparticles, composite oleophobic nanoparticles and stimuli-responsive nanoparticles. The preparation method of the oil-in-oil Pickering emulsion comprises the following steps: mixing the first oil phase, the second oil phase and the particle stabilizer, and carrying out an emulsification technology to obtain the oil-in-oil Pickering emulsion. According to the emulsion system prepared by the invention, the oil phase components with different polarity differences are reasonably matched, and the oil phase type is flexibly selected according to specific requirements of target application, so that the environmental adaptability and the function application range of the emulsion can be remarkably improved, and the emulsion system has a good application prospect.

The invention belongs to the technical field of semipermeable membrane preparation, and particularly relates to a preparation method of a nanofiltration membrane. The preparation method comprises the following steps: (1) cleaning the supporting layer for later use; the preparation method comprises the following steps: blending diamine, an amino beta-cyclodextrin derivative, an inorganic hybridizing agent, a zwitterionic compound and water to obtain a water phase for later use; blending aromatic acyl chloride, a cosolvent and an organic solvent to obtain an oil phase for later use; and (2) sequentially carrying out primary impregnation in a water phase, membrane scraping, secondary impregnation in an oil phase and heating curing on the supporting layer, and finally carrying out post-treatment to obtain the nanofiltration membrane. The nanofiltration membrane is prepared by introducing the amino beta-cyclodextrin derivative, the inorganic hybridization agent and other components into polyamide, so that the water flux of the polyamide nanofiltration membrane and the capability of effectively separating ions with different valence states are further improved.

The present disclosure relates to a method for processing of liquefied waste plastics (LWP). The method includes subjecting a liquefied waste plastic-based feedstock to heat treatment (HT processing) in an aqueous solution containing alkali metal hydroxide and / or alkaline earth metal hydroxide to form a heat treated effluent, transferring the heat treated effluent to a separator, subjecting the heat treated effluent to phase separation to isolate at least an oil phase including treated LWP and an aqueous phase including contaminated material, and recycling at least a part of the aqueous phase back to the HT processing.

The invention relates to a water shutoff profile control agent and a preparation method thereof, and belongs to the technical field of oilfield chemicals. The water shutoff profile control agent is prepared by inverse emulsion polymerization reaction, and is prepared from the following raw materials: a water phase solution, an oil phase solution and an initiator, the water-phase solution comprises acrylamide, an anionic monomer, a cationic monomer, a temperature-resistant salt-resistant monomer, a cross-linking agent, a silane coupling agent modified carbon nanotube, a reinforcing agent, modified tannic acid and water; the oil phase solution comprises base oil and an emulsifier. The water shutoff and profile control agent prepared by adding the silane coupling agent modified carbon nanotubes, the reinforcing agent and the modified tannic acid in inverse emulsion polymerization is good in injectivity, high in strength after water absorption and swelling, controllable in swelling time, capable of achieving secondary crosslinking under the high-temperature and high-salt condition, and good in water shutoff and profile control effect. The plugging agent not only can be matched with oil layers with different permeability and heterogeneous stratums, but also can be well adapted to plugging of deep well ducts with higher pressure and higher depth, and the plugging effect is more excellent.

The invention provides a stabilizer for Pickering emulsion and application of the stabilizer, and relates to the technical field of Pickering emulsion preparation. The stabilizing agent for the Pickering emulsion is obtained by compounding 6 '-O-caffeoyl arbutin and cellulose nanocrystals. In specific application, the 6'-O-caffeoyl arbutin and the cellulose nanocrystals are prepared into a water phase, and then the water phase is mixed with an oil phase to prepare the Pickering emulsion. According to the preparation method, the defects in the prior art are overcome, the stability of the Pickering emulsion is effectively improved, meanwhile, the oxidation resistance effect of the Pickering emulsion is further enhanced, and the application value of the Pickering emulsion is improved.

The invention belongs to the technical field of cosmetics, and particularly relates to a water-in-oil-in-water three-phase coated microbead as well as a preparation method and application thereof. The water-in-oil-in-water three-phase coated microbead is of a spherical structure and sequentially comprises an outer water phase, an inner oil phase and an inner water phase from outside to inside, the outer water phase comprises sodium alginate, agarose, cyclodextrin, glycerin and other components, the inner oil phase comprises caprylic / capric triglyceride, grape seed oil, olive squalane, tocopherol and other components, and the inner water phase comprises sodium alginate, agarose, cyclodextrin, glycerin and other components. And the inner water phase comprises ampelopsis grossedentata extract, astragalus membranacus root extract and other components. According to the invention, an easily oxidized and unstable active matter is fully and firmly protected by adopting a droplet microfluidic coating technology, so that the active matter is free from external stimulation, active ingredients with different effects play multiple roles, and the composition has good anti-inflammatory, soothing and oil-controlling effects and can be applied to the field of cosmetics.

The invention relates to a recyclable easily-degradable macromolecular surfactant for cleaning oily sludge and application of the recyclable easily-degradable macromolecular surfactant. The macromolecular surfactant is prepared by taking acrylamide, methacrylic acid long-chain alkyl ester and tertiary amino substituted methacrylate as raw materials through free radical polymerization. The macromolecular surfactant is dissolved in water to prepare a cleaning solution, and oily sludge can be efficiently eluted. CO2 and N2 are sequentially introduced into the oil-containing emulsion after the oil-containing sludge is cleaned, or diluted hydrochloric acid and a diluted alkali aqueous solution are sequentially added, the hydrophilic-hydrophobic property of the macromolecular surfactant is changed through pH regulation and control, separation of the macromolecular surfactant and an oil phase is achieved, petroleum resources are recycled, and recycling of the cleaning solution containing the macromolecular surfactant is achieved. The residual macromolecular surfactant in the cleaned deoiled sludge can be degraded under the action of environmental microorganisms.

The invention relates to a photo-crosslinkable water-based polyolefin emulsion as well as a preparation method and application thereof. The emulsion comprises modified polyolefin and water, the modified polyolefin is prepared from raw materials including polyolefin resin, maleic anhydride, a grafted photo-initiation monomer and a free radical initiator through graft polymerization; the grafted photo-initiation monomer contains vinyl and a photo-initiation group. The emulsion is prepared by melting the modified polyolefin to form an oil phase; dissolving an emulsifier in part of water to obtain a water phase; and adding the water phase into the oil phase while stirring, and then adding the rest of water to prepare the oil-in-water composite oil-in-water composite oil-in-water composite oil-in-water composite. The emulsion can be subjected to photo-crosslinking, and after photo-crosslinking, a coating film has excellent water resistance, solvent resistance, hardness and adhesive force.

The invention discloses a nanometer fiber yarn-based phytosterol Pickering emulsion as well as a preparation method and application thereof, and the nanometer fiber yarn-based phytosterol Pickering emulsion comprises the following components in parts by weight: 0.5-1 part of nanometer fiber yarn; 1 to 10 parts of phytosterol / phytosterol ester; 95 to 105 parts of a water phase component; 95 to 105 parts of an oil phase component; the nanofibers are extracted from agricultural wastes; according to the invention, the nanofiber is used as the only or main stabilizer of the phytosterol Pickering emulsion, so that the problems of solubility, emulsion stability and bioaccessibility of phytosterol can be solved at the same time; and efficient interface stability and steric hindrance stability are realized by utilizing a unique nano network structure of the nano fiber yarns, and a natural, safe and efficient phytosterol delivery system is provided.

The invention discloses a preparation method of a lignosulfonate controlled-release drug-loaded capsule. The invention constructs a pH controlled release type lignin-based drug-loaded capsule around a three-stage delivery strategy of emulsion construction-electrostatic self-assembly-metal chelation. The preparation method specifically comprises the following steps: dissolving pesticide active ingredients and an emulsifier in an organic solvent to serve as an oil phase; dissolving lignosulfonate and a dispersing agent in water to serve as a water phase; mixing the oil phase and the water phase under stirring and homogenizing conditions to form O / W type emulsion; cationic monomers are added into the O / W type emulsion, a prototype of a shell layer is formed by means of electrostatic acting force, then the shell layer is cured by means of chelation of metal ions, and the lignosulfonate-based drug-loaded capsule loaded with pesticide is formed. The drug-loaded capsule prepared by the invention can shield ultraviolet light through the lignosulfonate metal complexing layer, has sensitive acid-base response performance, can realize the response controlled release process of encapsulated drugs, and effectively reduces the dosage of pesticides.

The invention discloses a method for preparing acid sophorolipid, and belongs to the technical field of biological fermentation. According to the method, candida is used as a fermentation strain, a composite carbon source culture medium containing a water-soluble carbon source and an oil-soluble carbon source is adopted, and the content of residual oil is monitored in real time in the fermentation process; when the residual oil content exceeds a threshold value of 5g / L, the emulsifying agent of 0.1 g / L-0. 5g / L is supplemented, and the stirring rotating speed is increased by 20-50rpm, so that the emulsification of an oil phase and the utilization of the thalli on the oil-soluble carbon source are promoted. By accurately controlling the residual oil content in the fermentation process, the proportion of the acidic sophorolipid and the carbon source conversion rate are remarkably increased, the proportion of the acidic sophorolipid is increased to 60% from 30% of a traditional process, the carbon source conversion rate is increased to 65% from 40%, the problems that the increasing means of the proportion of the acidic sophorolipid is single, and the carbon source is wasted are effectively solved, and the method is suitable for industrial production. The method has the advantages of simple process, low cost, environmental protection and the like.

According to the water-in-oil type glossy lip cosmetic and the preparation method thereof disclosed by the invention, a water-in-oil emulsification technology can be successfully integrated into a traditional lip gloss / lip glaze system by using a high-gloss grease composition with a specific formula, an emulsification composition with a specific ratio and a film-forming composition with specific viscosity and a specific ratio, so that a synergistic interaction effect is achieved; while the high oil phase content is ensured to realize high glossiness like that of a whole oil system, the stability problem of high-content difficult-to-emulsify grease and a water phase is solved by utilizing the emulsifying composition; through synergistic film formation of the film-forming composition and the high-content phenyl silicone oil, the interference of water to the film-forming property is effectively resisted, so that the non-stick-to-cup effect is comparable and even superior to that of a whole-oil formula, meanwhile, the water-feeling moisturizing advantage of an oil-in-water system is achieved, and the obtained water-in-oil system cosmetic has excellent stability and non-stick-to-cup performance.

The invention discloses diglyceride prepared by an enzymic method as well as a preparation method and application thereof, and belongs to the technical field of deep processing of grease. The method comprises the following steps: adding fatty acid into a choline chloride-glycerol-urea ternary eutectic solvent, uniformly mixing, and then adding candida antarctica lipase B for esterification reaction to obtain a reaction mixture; separating the reaction mixture, and recovering an upper-layer oil phase; and separating and purifying the upper-layer oil phase to obtain the diglyceride. According to the method, the reaction rate is high, the selectivity of the diglyceride in the esterification process is high, the yield of the diglyceride can reach 65% or above by reacting for 1 h, the selectivity of the diglyceride is 75% or above, and the purity of the separated and purified diglyceride is 90% or above; in addition, the method is simple to operate, and the reaction product and the eutectic solvent can be separated through simple centrifugation after the reaction is finished; in addition, the monoglyceride content in the product is low, and the subsequent separation and purification difficulty is greatly reduced.

The invention belongs to the field of animal feed additives, and particularly relates to a microcapsule preparation containing origanum vulgare essential oil as well as a preparation method and application of the microcapsule preparation. The preparation method of the microcapsule preparation containing origanum vulgare essential oil comprises the following steps: S1, dissolving modified beta-cyclodextrin and modified starch in water to obtain a wall material solution; s2, uniformly mixing oregano essential oil to prepare a core material solution, and dissolving an emulsifier in the core material solution to form an oil phase; s3, mixing the wall material solution with an oil phase, and homogenizing to obtain a solution A; and S4, adding a stabilizer into the solution A, uniformly mixing, and spray-drying to obtain the microcapsule preparation containing the origanum vulgare essential oil. The oregano essential oil entrapped microcapsule preparation is prepared by adopting the modified beta-cyclodextrin as a wall material and the modified montmorillonite as a stabilizer, so that the stability and the entrapment efficiency of the oregano essential oil are remarkably improved, the intestinal targeted release of the oregano essential oil is also realized, and the growth and development of animals are promoted.

The invention discloses a preparation method of an adsorption material for catalytic combustion of VOCs, and belongs to the technical field of environment-friendly catalytic materials. The method comprises the following steps: mixing silica sol, kaolin and an HZSM-5 molecular sieve according to a mass ratio of 1: (0.6-0.8): (0.4-0.5), and pulping to form slurry with the solid content of 25%-40%; adding polyethylene glycol (the molecular weight is 300-600) which accounts for 1-5% of the mass of the slurry, and uniformly dispersing; dripping into an oil phase at the temperature of more than or equal to 70 DEG C through a 0.5-1 mm dropper to form a 1-2 mm gel bead; pre-drying for 2-4 hours at the temperature of 80-120 DEG C, heating to 600-750 DEG C at the speed of 3-5 DEG C / min, and roasting for 2-5 hours; and the roasted pellets, sodium metaaluminate, a guiding agent and water are subjected to dynamic crystallization according to the mass ratio of 1: (0.1-0.3): (0.05-0.15): (5-10), and finally metal is loaded. The sphericity of the carrier is gt under the synergistic effect of oil column forming and polyethylene glycol; the compressive strength is not less than 40 N; the kaolin enhances the mechanical performance, and the HZSM-5 constructs hierarchical pore channels (the pore volume is 0.3-0.5 cm / g, and the specific surface area is gt and 300 m / g), so that the VOCs adsorption capacity is improved.

The invention relates to the technical field of preparation of food additives, in particular to a betacyanin microcapsule as well as a preparation method and application thereof. The preparation method comprises the following steps: jointly dissolving sodium alginate and soybean protein isolate in water to obtain an SA-SPI compound; the SA-SPI compound, CaCO3 and betacyanin are mixed, and a water phase is formed; mixing liquid paraffin, glacial acetic acid and Tween 80 to obtain an acetic acid-containing oil phase; mixing the water phase with the acetic acid-containing oil phase to form a water-in-oil emulsion, and standing to form calcium alginate gel beads; the calcium alginate gel beads are subjected to pre-freezing-freeze-drying treatment, and the betacyanin microcapsules are obtained. The prepared betacyanin microcapsule has the characteristics of controllable particle size, high stability and easiness in industrialization, and the application range of betacyanin is widened. In addition, the preparation method disclosed by the invention is safe and simple to operate, has the advantages of low cost and high benefit, and can be directly applied to large-scale production.

The invention discloses a method for efficiently extracting phenol from coal tar and primarily separating crude phenol oil, and relates to the technical field of chemical separation. Carrying out multi-stage cross-flow or counter-flow extraction on the extracting agent and the coal tar to obtain a raffinate phase and a high-concentration extraction phase; and mixing the raffinate with condensate at the top of the regeneration device and supplemented fresh water, and recovering residual organic amine through a reverse extraction device to obtain a dephenolized oil product and backwashing water. Mixing and diluting the extract phase with backwashing water, and standing for phase splitting to obtain a high-grade crude phenol oil phase and a low-concentration extract phase; the low-concentration extraction phase absorbs CO2 in the industrial tail gas for acidification to obtain a low-grade crude phenol oil phase and an amine salt aqueous solution; and desorbing the amine salt aqueous solution to obtain a regenerated extraction agent (circularly used for extraction), tower top condensate (circularly used for reverse extraction) and water-containing industrial-grade CO2 gas (recycled or sealed after drying). According to the method, high-efficiency extraction of the phenolic compounds in the coal tar and primary separation of crude carbolic oil are realized by utilizing the extraction performance differences of extraction capacities, selectivity and the like of the extraction agents with different concentrations on the phenolic compounds, and the production economy is improved.

The invention provides tranexamic acid-glutathione-containing compound emulsifiable paste and a preparation method thereof.W1 / O / W double emulsion phase structural design is adopted, reduced glutathione is encapsulated in an acidic inner water core, an oil phase is stabilized through hydrogenated lecithin and sorbitan sesquioleate, an outer water phase contains tranexamic acid, a layered gel network is constructed, and the tranexamic acid-glutathione-containing compound emulsifiable paste is prepared. A submicron dispersion system with the particle size D50 of 0.30-0.80 microns, the polydispersity index of 0.15-0.25 and the viscosity of 2.0-8.0 Pa seconds is realized, the encapsulation efficiency of glutathione is not lower than 70%, the oxygen content of a head space is not higher than 1.0%, and the encapsulation efficiency of glutathione is not lower than 70%. The three technical contradictions of coupling conflict between a high-yield viscoelastic structure and low-shear damage kernel integrity, coexistence of fresh and cool low-viscosity skin feeling and high-barrier anti-oxidation and anti-leakage and opposite low-surface-activity sensitive skin compatibility and submicron low-PDI dispersion stability are solved; the traditional Chinese medicine composition has wide application values of improving skin color unevenness, fading color spots, brightening skin color, soothing and repairing.

The invention provides a composite immersed cooling liquid as well as a preparation method and application thereof. Comprising a dispersion phase, a continuous phase, an emulsifier and an additive, the dispersion phase is fluorine cooling liquid, the continuous phase is oil cooling liquid, the emulsifier is one or more compounded nonionic surfactants, and the HLB value of the emulsifier is 4-9 or 10-18; according to the composite immersed cooling liquid disclosed by the invention, the advantages of high heat conductivity of the oil phase and high safety (non-combustibility and high dielectric strength) of the fluorine phase are ingeniously combined, and 1 + 1gt is realized; 2, the effect is achieved; the oil phase with high cost performance is used for replacing most expensive fluorine phases, and the overall material cost is reduced by 40%-60% compared with that of pure fluorine cooling liquid; the nano-scale microemulsion is formed through the specific emulsifier, the fundamental problem that a traditional mixed solution is inevitably layered is solved, and the shelf life is long; the cooling liquid disclosed by the invention has good material compatibility, and the problem that a pure fluorine liquid swells some sealing materials is avoided.

A composite oil phase and composite emulsion matrix for site-mixed emulsion explosive and preparation methods therefor. The composite oil phase is divided into material A and material B, wherein in the material A, a high-viscosity polyisobutylene maleic anhydride amine esterification derivative is used as a primary emulsifier to increase the strength and thickness of an emulsification film of an emulsion matrix, thereby improving the stability of the emulsion matrix; in the material B, a low-viscosity polyisobutylene maleic anhydride amine esterification derivative and SP-80 are used as primary emulsifiers to regulate the ammonium nitrate dissolution rate of the emulsion matrix, thereby improving the sensitization characteristic of the emulsion matrix; and the emulsion matrix prepared from two composite oil phases can effectively improve the water resistance of the emulsion matrix while the problems of high-temperature over-sensitization and low-temperature insensitivity are solved, so that the explosion quality is guaranteed.

The invention provides a self-healing-shape memory phase change microcapsule for cooling drilling fluid as well as a preparation method and application of the self-healing-shape memory phase change microcapsule, and belongs to the technical field of cooling of the drilling fluid and underground heat management. The preparation method of the phase change microcapsule comprises the following steps: fully dispersing a polyurethane prepolymer, a polyimide solution and hydrophobic nanocellulose in an organic solvent to obtain an oil phase; dissolving a phase change material in deionized water to obtain a water phase; under a shearing condition, dropwise adding the oil phase into the water phase, and emulsifying to form a stable oil-in-water type Pickering emulsion; and adding an aqueous solution of a chain extender, and carrying out interfacial polymerization reaction, centrifugation, washing and drying. The phase change microcapsule disclosed by the invention shows excellent cyclic service performance under the underground high-temperature and high-shear conditions, and structure repair and morphology recovery can still be realized by virtue of self-healing and shape memory effects even if a shell layer is damaged, so that the service life of the phase change microcapsule is prolonged, and the cooling persistence of the drilling fluid is improved.

The invention provides a bridge anti-disturbance concrete material and a preparation method thereof, and belongs to the technical field of building materials, the bridge anti-disturbance concrete material comprises a gel material, a reinforcing material and a functional additive; the reinforcing material comprises fibers, modified styrene butadiene rubber particles and self-repairing capsules; the self-repairing capsule comprises a water phase and an oil phase, the water phase contains nano calcium oxide, and the oil phase contains an HDI-ethylenediamine copolymer. The invention provides a bridge anti-disturbance concrete material and a preparation method thereof. The adaptability of concrete to high-frequency vibration and extremely low-temperature environments is improved.

The invention discloses an emulsifier for preparing a Pickering emulsion, the Pickering emulsion as well as a preparation method and application of the Pickering emulsion. The emulsifier of the Pickering emulsion is obtained by dissolving distearoyl phosphatidylcholine, cholesterol and distearoyl phosphatidyl ethanolamine-polyethylene glycol 2000 in ethanol, carrying out rotary evaporation to remove ethanol, then adding an antigen aqueous solution containing an antigen, continuing rotary evaporation to obtain liposome nanoparticles, heating the liposome nanoparticles with mannose in a water bath, and carrying out freeze drying. The Pickering emulsion is obtained by dispersing an emulsifier in water as a water phase, taking squalene as an oil phase, mixing the water phase and the oil phase, and homogenizing. The Pickering emulsion disclosed by the invention is prepared by taking antigen presenting cell targeted liposome nanoparticles as a raw material; and the antigen has excellent ion concentration characteristic, pH stability, temperature stability and storage stability, and can protect the integrity of the antigen.

The invention discloses a core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule, the microstructure is of a spherical structure, the core-shell structure is adopted, the core structure is hexadecane, the shell structure is a methyl methacrylate (MMA) and N, N-methylene bisacrylamide (MBA) copolymer, the emulsifier is lauryl sodium sulfate (SDS), the initiator is potassium persulfate, and the pH value of the core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule is 7-8. And the coating efficiency is 70-75%. The preparation method comprises the following steps: 1, preparing an oil phase and a water phase; and 2, polymerization reaction of the microcapsule. A phase change cement material based on a core-shell structure P (MMA-MBA) copolymer heat storage phase change microcapsule is prepared by compounding the P (MMA-MBA) copolymer heat storage phase change microcapsule and a cement matrix, and has hydrophobicity; obvious weightlessness exists in two times.