156 results about "Propionate" patented technology

The invention discloses piggy creep feed containing composite flavone. The piggy creep feed is prepared from the following raw materials in parts by weight: 13 to 20 parts of expanded corn, 10 to 25 parts of corn, 6 to 13 parts of broken rice, 8 to 12 parts of flour, 8 to 15 parts of whey mist, 3 to 8 parts of soy protein concentrate, 5 to 10 parts of extruded soybean, 0.7 to 3 parts of soya-bean oil, 7 to 12 parts of 46.5-percent bean pulp, 2 to 5 parts of fish meal, 2 to 5 parts of plasma protein powder, 0.3 to 0.7 part of mountain flour, 0.5 to 1.0 part of calcium hydrophosphate, 0.05 to 0.5 part of lysine, 0.05 to 0.3 part of threonine, 0.1 to 0.3 part of sodium chloride, 0.1 to 0.8 part of compound flavone premix compounds, 0.15 to 0.3 part of zinc oxide, 0.03 to 0.06 part of calcium propionate, 0.02 to 0.04 part of ethoxyquin and 1.0 part of suckling pig premix compounds. The invention also discloses a preparation method. The intestinal tract health and the production performance of weaned pigs can be improved.

The invention belongs to the technical field of rubber sealing rings, and particularly discloses a wading rubber sealing ring and a preparation method thereof, the wading rubber sealing ring comprises the following components by weight: 60-70 parts of modified ethylene propylene diene monomer, 35-50 parts of modified white carbon black, 20-30 parts of hydrogenated nitrile rubber, 0-10 parts of fluororubber, 2-5 parts of polyester fiber, 0.5-3 parts of an anti-hydrolysis agent, and 1-3 parts of a hydrophobic agent. 2-4 parts of an antimicrobial agent, 3-5 parts of an anti-aging agent and 1-7 parts of sulfur; the anti-hydrolysis agent is a mixture of tetrakis [beta-(3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid] pentaerythritol ester and a carbodiimide anti-hydrolysis agent; the hydrophobic agent is a mixture of polydimethylsiloxane and perfluorooctyltriethoxysilane, and the hydrophobic agent is a mixture of polydimethylsiloxane and perfluorooctyltriethoxysilane. The wading rubber sealing rubber ring and the preparation method thereof are suitable for fresh water and warm water scenes, and have wide application prospects in ship sealing and sewage treatment equipment in seawater and industrial wastewater scenes.

The invention provides a high-foaming self-thickening amino acid cleaning composition and a preparation method thereof, and relates to the technical field of cosmetics. The high-foaming self-thickening type amino acid cleaning composition is prepared from the following raw materials in percentage by mass: main surfactants: 15%-20% of potassium cocoyl glycinate, 0.5%-2.0% of sodium cocoyl amino propionate and 0.05%-2% of sodium lauroyl glutamate; the auxiliary surfactant comprises the following components in percentage by weight: 1.2%-1.8% of sodium lauroamphoacetate, 1.8%-3.6% of lauryl hydroxyl sulfobetaine, 0.5%-1.5% of sodium methyl cocoyl taurate and 0.5%-1.5% of lauryl glucoside; and 0.5%-1.8% of an acrylic ester copolymer. The cleaning composition is free of fatty acid components, small in irritation, rich and dense in foam, good in foam performance, high in cleaning power, good in flushing performance, free of false slip after flushing and good in stability.

The invention discloses an ethylene-vinyl acetate copolymer, an ethylene-vinyl alcohol copolymer and a preparation method thereof, and belongs to the field of polymers. Comprising the following steps: putting a mixture containing an initiator, a chain transfer agent, a solvent and vinyl acetate into a closed container, introducing ethylene gas, and carrying out pressurized polymerization to obtain the ethylene-vinyl acetate copolymer, the initiator is selected from at least one of lauroyl peroxide, benzoyl peroxide, azodiisobutyronitrile and azobisisoheptonitrile; the chain transfer agent is selected from the group consisting of 2-dimethylaminoethyl acetate and / or 2-dimethylaminoethyl propionate. The preparation method of the low-branching-degree EVA has the characteristics of mild conditions, strong controllability, simplicity in operation and large-scale application prospect. The invention also provides an ethylene-vinyl alcohol copolymer prepared from the prepared EVA through alcoholysis reaction, and the ethylene-vinyl alcohol copolymer has the characteristics of high molecular weight, narrow distribution, good appearance and the like, and meets the application requirements of commercial EVOH.

The invention belongs to the technical field of building materials, and provides an early-strength cement-based grouting material and a preparation method thereof.The early-strength cement-based grouting material is prepared from, by weight, 500-600 parts of sulphoaluminate cement, 200-300 parts of Portland cement, 40-100 parts of lithium slag, 1-3 parts of a coagulant, 0.5-1 part of an early strength agent, 5-8 parts of a water reducing agent, 0.5-2.5 parts of a thickening agent, 0.3-0.9 part of a defoaming agent and 260-310 parts of water; the coagulant is sodium metaaluminate and / or potassium metaaluminate; the early strength agent is selected from one or more than two of lithium carbonate, lithium sulfate, calcium formate, calcium acetate, calcium propionate, calcium butyrate and nano silicon dioxide. According to the technical scheme, the problems of poor dispersion resistance and low early strength of a cement-based grouting material in a flowing water environment in the prior art are solved.

The invention relates to a method for controlling wheat septospora which is resistant to a C14-demethylase inhibitor fungicide. The present invention relates to a method for controlling wheat septospora on a cereal plant, which wheat septospora comprises at least one mutation in the CYP51 gene and is resistant to a C14-demethylase (in sterol biosynthesis) inhibitor fungicide (DMI fungicide), the method comprises applying to these plants, seeds or soil of the plants a fungicidally effective amount of (I) methyl 2-[2-chloro-4-(4-chlorophenoxy) phenyl]-2-hydroxy-3-(1, 2, 4-triazol-1-yl) propionate or (II) 2-[2-chloro-4-(4-chlorophenoxy) phenyl]-2-hydroxy-3-(1, 2, 4-triazol-1-yl) propionic acid.

A polyelectrolyte hydrogel coating with strong substrate binding performance and a method of manufacturing the same are provided. The method includes: 1) activating a substrate by applying oxygen plasma; and 2) dissolving a polycationic polymer, a polymeric monomer, a silane coupling agent and an initiator to obtain a precursor solution, vacuumizing the precursor solution to remove air bubbles, applying the vacuumized precursor solution to a surface of the substrate activated by the oxygen plasma, and performing an in-situ polymerization and curing process under nitrogen or rare gas atmosphere. The polymeric monomer includes at least one of: acrylamide, acrylic acid, hydroxyethyl methacrylamide, 2-acrylamido-2-methyl-1-propanesulfonic acid, polyethylene glycol (diol) diacrylate, 2-methacryloxyethylphosphocholine, 3-[[2-(Methacryloyloxy)ethyl]dimethylammonio]propane-1-sulfonate, and 3-[[2-(methacryloyloxy)ethyl]dimethylammonium] propionate. The silane coupling agent has a carbon-carbon double bond functional group.

A pest control composition includes from about 4 wt % to about 10 wt % of sodium lauryl sulfate; one or more C5 to C9 hydrotropic salt; from about 1 wt % to about 10 wt % of one or more active ingredients selected from the group consisting of corn mint oil, peppermint oil, spearmint oil, rosemary oil, thyme oil, citronella oil, clove oil, cedarwood oil, cinnamon oil, geranium oil, eugenol, 2-phenylethyl propionate, menthol, menthone, thymol, carvone, camphor, methyl salicylate, p-cymene, linalool, geraniol, cinnamyl acetate, cinnamic alcohol, cinnamaldehyde, citronellol, eucalyptol / 1,8-cineole, alpha-pinene, bornyl acetate, gamma-terpinene, and combinations thereof; and from about 60 wt % to about 95 wt % of water. The pest control composition exhibits a water peak in a 2H spectrum having a width encompassing 90% of the area of the entire water signal of about 50 Hz or more, as determined by the 2H NMR Method.

The invention is directed to a crosslinkable polyethylene composition comprising an additive composition consisting of polyethylene glycol and a mixture of 4,4′-thiobis (2-tertbutyl-5-methylphenol) plus thiodiethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate].

The invention relates to the technical field of pesticide production, and particularly discloses a preparation process of glufosinate-ammonium intermediate 3-(methyl hydroxyl phosphonyl) propionaldehyde. The preparation method comprises the following steps: 1, carrying out addition reaction on diethyl methylphosphonite and acrylic acid in absolute ethyl alcohol to generate 3-[ethyoxyl (methyl) phosphonyl] propionate; in the second step, 3-[ethyoxyl (methyl) phosphonyl] propionate is subjected to a hydrosilylation reaction in an oriented mode, and 3-triethyl siloxy-3-ethyoxyl propyl methyl ethyl phosphonate is generated; and 3, carrying out a simple dilute acid hydrolysis reaction to obtain the 3-(methyl hydroxyl phosphonyl) propionaldehyde. According to the method, a three-step reaction route of addition-hydrosilylation-hydrolysis is adopted, and the acrylic acid is used for replacing the traditional high-toxicity raw material acrolein, so that the toxicity risk is avoided from the source, the yield of the target glufosinate-ammonium intermediate is remarkably improved, the total yield of the three-step reaction can reach 95% or above, and the method is suitable for industrial production. And an efficient and green brand-new technical scheme is provided for large-scale production of glufosinate-ammonium.

The invention relates to a preparation method of 3-ethoxy isoamyl propionate, and belongs to the technical field of organic solvent synthesis. The preparation method of the 3-ethoxy isoamyl propionate comprises the following steps: S1, adding ethanol, a polymerization inhibitor and a catalyst A into a reaction kettle, heating to 40-55 DEG C, then dropwise adding ethyl acrylate, preserving heat, and carrying out addition reaction for 1-3 hours to obtain a reaction mixture; s2, adding an acidic material for neutralization, and carrying out vacuum rectification to obtain ethyl 3-ethoxypropionate; s3, adding ethyl 3-ethoxypropionate and a catalyst B into a reaction kettle, heating to 100-120 DEG C, introducing isoamyl alcohol, controlling the reaction temperature to 100-115 DEG C, and carrying out transesterification for 2.5-4 hours to obtain a crude product; and S4, cooling to stop the reaction, separating to remove the catalyst B, and carrying out reduced pressure rectification on the obtained crude product to obtain the 3-ethoxypropionic acid isoamyl ester. The method has the effects of mild process, high conversion rate and high product yield.

An electrochemical apparatus includes a separator, a positive electrode plate, and an electrolyte solution, where the separator includes a porous layer, and an average pore diameter of the porous layer is 0.5 μm to 18 μm; the electrolyte solution includes propyl propionate, and based on a mass of the electrolyte solution, a mass content of propyl propionate is 25% to 55%; and the positive electrode plate includes a positive active material layer, the positive active material layer includes a conductive agent, the conductive agent includes at least one of conductive carbon black or Ketjen black, and a specific surface area of the conductive agent is 600 m2 / g to 1100 m2 / g.

The invention belongs to the technical field of oil exploitation, and particularly relates to a fracturing fluid thickening agent as well as a preparation method and application thereof. The preparation method comprises the following steps: adding aminomethane tripropionic acid, ethanol and allyl chloride into a first reactor, carrying out a heat preservation reaction, and carrying out reduced pressure distillation to obtain a first functional monomer; adding 3-amino-1, 5-naphthalene disulfonic acid disodium salt, ethanol and allyl chloride into a second reactor, carrying out a heat preservation reaction, and carrying out reduced pressure distillation to obtain a second functional monomer; adding acrylamide, 1, 5-hexadiene-3, 4-diol, 3-[(3-acrylamidopropyl) dimethylammonium] propionate, a first functional monomer, a second functional monomer, monopotassium phosphate and water into a third reactor, dropwise adding an initiator, carrying out heat preservation reaction, adding ethanol, separating out precipitate, centrifuging to obtain a solid, and drying overnight to obtain the thickening agent. The thickening agent provided by the invention has the advantages of high apparent viscosity, strong shear resistance and strong antibacterial ability.

The invention relates to the field of polyethylene composite fibers, and discloses an antibacterial halogen-free flame-retardant reinforced cross-linked polyethylene composite fiber and a preparation method thereof.The composite fiber is prepared from linear low-density polyethylene resin, modified magnesium hydroxide, a silver-loaded zirconium phosphate inorganic antibacterial agent, tetra [beta-(3, 4, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, the composite material is prepared from the following components: 1, 3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid] pentaerythritol ester antioxidant, dicumyl peroxide cross-linking agent, hydrogenated castor oil dispersing agent and industrial white oil solvent. The modified magnesium hydroxide is prepared from magnesium hydroxide, deionized water, stearic acid and a sodium hydroxide solution. The composite fiber disclosed by the invention has relatively good mechanical property, antibacterial property and flame retardance.

The invention relates to phosphine ligands and their use in the carbonylation of acetylene / ethylene for the synthesis of acrylate / propionate. The phosphine ligands according to the invention are represented by formulas I to VIII. The invention describes the use of these phosphine ligands in combination with palladium catalysts for carbonylation reactions of acetylene or ethylene for the production of acrylate or propionate compounds. The processes are characterized by high catalytic efficiency, excellent product yields, outstanding selectivity, and ease of implementation. Particular advantages include improved reaction kinetics due to the optimized ligand structures, economical process control due to high catalyst productivity, and a broad range of applications for various acrylate and propionate derivatives. The invention is particularly suitable for industrial synthesis processes in fine chemical production.

This invention discloses a method for eliminating moss growth on macadamia nut leaves, relating to the field of agricultural planting technology. The specific method involves spraying a moss-removing agent onto the macadamia nut leaves during the moss occurrence period, applying moss inhibitor I to the main stem, and applying moss inhibitor II to the soil surface around the main stem. The moss-removing agent comprises the following raw materials in parts by weight: 40-50 parts of allicin, 15-24 parts of urea, 5-18 parts of calcium propionate, 20-27 parts of calcium sulfate, 10-17 parts of calcium chloride, 20-35 parts of vegetable oil, 1-10 parts of titanium dioxide, 1-5 parts of glutathione, and 1-3 parts of dispersant. This invention solves the problems of slow effectiveness, short duration of action, and low plant safety in current macadamia nut leaf moss control methods, achieving highly efficient control.

This invention discloses a single-component moisture-curing conductive and thermally conductive adhesive and its preparation process, comprising the following raw materials in parts by weight: 100 parts SMP adhesive; 15-30 parts flake silver powder; 500-900 parts spherical silver-coated copper powder; 0-400 parts dendritic silver-coated copper powder; 10-20 parts decamethyltetrasiloxane; 1-1.5 parts β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate isooctyl ester; 7.5-10 parts N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane; and 1-1.5 parts vinyltrimethoxysilane. This invention allows the adhesive to cure at room temperature / low temperature using moisture in the air, eliminating the need for temperatures above 120°C. This completely avoids thermal stress damage to heat-sensitive substrates such as plastics, flexible circuit boards, and PET / PI films, making it perfectly suited for low-temperature processing scenarios such as flexible electronics manufacturing, wearable devices, and flexible sensors.

This invention discloses a strain of *Propionibacterium freundii* and its application in propionic acid production. The strain was deposited at the China Center for Type Culture Collection on October 22, 2025, with accession number CCTCC M 20252289. This invention obtains a high-propionic acid-producing *Propionibacterium freundii* strain through screening from nature. Its 16S RNA was identified as *Propionibacterium freundii*. This strain is a safe edible strain approved by the Ministry of Health. Through optimization of its culture and fermentation conditions, the final propionic acid yield can reach over 50 g / L, the glucose conversion rate can reach 60%, and there is no lactic acid accumulation, meeting the requirements of industrial production. Furthermore, through fermentation optimization, the content of other acids can be effectively controlled, resulting in propionate products of different specifications that meet market demands.

The application discloses a polyacid zeolite imidazolate framework loaded monatomic catalyst and a preparation method and application thereof, and belongs to the technical field of catalysts. The preparation method of the catalyst is as follows: (1) preparing a zeolite imidazolate framework material; (2) mixing the dried zeolite imidazolate framework material and a metal salt in a solvent and stirring; then adding a heteropoly acid, controlling the pH in the system to be 5-7, and performing a solvothermal reaction under the condition of 80-120 DEG C; after the reaction is completed, cooling and centrifugal separation are performed to obtain a precipitate; and (3) performing calcination treatment on the precipitate to obtain the polyacid zeolite imidazolate framework loaded monatomic catalyst. The polyacid zeolite imidazolate framework loaded monatomic catalyst prepared by the method has high catalytic activity, high selectivity and good cycle stability, and has a good application prospect in acetyl propionate esterification reaction.

This invention belongs to the field of chemical pharmaceutical technology, and particularly relates to a method for preparing an anti-puncture flash evaporation material. Addressing the issue that the hydrophilicity of the molecular structure in existing technologies needs improvement, this invention provides a maleic methylamine polyethylene glycol activated ester and its preparation method, comprising a reaction condensation of 3-maleimide propionic acid and tert-butyl methylamine polyethylene glycol propionate, followed by acid hydrolysis of the ester, and then adding the activated ester for a catalytic reaction to obtain the final product Mal-CH2CH2COO-N(CH3)-(PEG). n -CH2CH2COONHS. This invention creatively designs a maleic methylamine polyethylene glycol activated lipid structure. The methylamine structure can increase solubility in aqueous media, making it more hydrophilic than the existing Mal-CH2CH2COO-PEG-COONHS molecular structure, which is more conducive to the binding of drugs to the human body environment.

The invention discloses a chiral P, N, N-tridentate ligand based on a ferrocene skeleton as shown in a formula I, a preparation method of an iridium catalyst containing the ligand and application of the ligand in preparation of a carbon-nitrogen axial chiral compound and a diltiazem intermediate. According to the present invention, the chiral P, N, N-tridentate ligand based on the ferrocene skeleton and the metal iridium precursor [Ir (COD) Cl] 2 are subjected to complexation to obtain the complex as the iridium catalyst, and the catalyst can be used as the iridium catalyst with characteristics of high yield (up to 99%), high enantioselectivity (up to gt; 99% ee) and high diastereoselectivity (up to gt; according to the method, N-aryl indolal or N-aryl indolone is subjected to asymmetric hydrogenation by using N-aryl indolal or N-aryl indolone (R1, R2, R3, R4, R5, R6, R7, R7, R8, R9, R9, R9, the catalyst can also be applied to asymmetric synthesis of diltiazem intermediate (2R, 3S)-3-(4-methoxyphenyl)-2, 3-epoxidized propionate, has the advantages of short synthesis route, high yield, good stereoselectivity (as high as 99% ee, 97 / 3dr) and the like, and has better economic and social benefits.

The invention relates to an adhesive composition comprising: a) At least one polymer P, b) A stabilizer S comprising b1) At least one first stabilizer S1 and b2) At least one second stabilizer S2, which is different from the at least one stabilizer S1 wherein the first stabilizer S1 is a non-sulfur containing compound having at least two phenolic groups selected from ethylenebis(oxyethylene) bis[3-(5-tert-butyl-4-hydroxy-m- tolyl)propionate] and pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionate)the second stabilizer S2 is a sulfur containing compound selected from thiodiethylene bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)propionate] and dilauryl 3,3'-thiodipropionate; wherein the at least one polymer P is selected from at 25 °C solid non-functionalized and functionalized polyolefins;

The invention discloses a method for preparing a perovskite solar cell based on n-amyl propionate, and the method comprises the steps: preparing N, N-dimethylformamide and n-amyl propionate into a mixed solvent according to the volume ratio of (5.6-19): 1, and respectively adding lead iodide, iodoformamidine and chloromethylamine into the mixed solvent according to the molar ratio of 1: (0.8-1.2): (4.5-6.5) to prepare a perovskite precursor solution; spin-coating an electron transport layer material on the surface of ITO glass, annealing for 20-40 minutes under the condition of 120-180 DEG C to obtain an electron transport layer, blade-coating the perovskite precursor solution on the surface of the electron transport layer of the ITO glass, vacuumizing for 60-120 minutes, and annealing for 5-15 minutes under the condition of 120-160 DEG C to obtain a perovskite layer; and spin-coating a hole transport layer material on the surface of the perovskite layer, and carrying out vacuum evaporation on a modification layer and a metal electrode on the surface of the hole transport layer. According to the scheme, the problem that preparation of the titanium ore thin film through a traditional solvent must be carried out in a water-free and oxygen-free environment is solved; and the preparation process is low in cost, simple to operate and not easily influenced by environmental factors.

The invention discloses a method for producing bio-based dihydric alcohol. According to the method, bio-based methyl 2-tetrahydrofuroate, tetrahydrofurfuryl propionate and methyl 2-(tetrahydrofuran-2-yl) acetate are used as precursors for dihydric alcohol synthesis, Cu-Ga-Mn / SiO2 or Cu-Ga-Mn / SiO2-Al2O3 is used as a hydrogenation catalyst, cyclic ether ester structures are synchronously activated in a fixed bed reactor, ester group hydrogenation and tetrahydrofuran ring opening are synergistically carried out, and the high-purity tetrahydrofuran is obtained. The reaction path is shortened. The hydrogenation catalyst is prepared by combining a sol-gel method and hydrothermal synthesis through roasting and reduction, active components are uniformly distributed, and the hydrogenation catalyst has excellent hydrogenation activity and structural stability.

The application belongs to the technical field of electrochemistry and relates to a secondary battery and an electronic device comprising the secondary battery. The secondary battery comprises a positive electrode, a negative electrode, a separator and an electrolyte; the negative electrode active material of the negative electrode comprises a silicon-carbon material; the electrolyte comprises ethyl propionate and propyl propionate, the mass percentage content of the ethyl propionate is a% and the mass percentage content of the propyl propionate is b% based on the total mass of the electrolyte, wherein 1.7<=a / b<=5.7; the electrolyte further comprises at least one of vinylene carbonate, a boron-containing lithium salt and a compound comprising a structure shown in Formula I; wherein A in Formula I is selected from C2 to C5 alkylene. The secondary battery, by improving the used electrolyte system, reduces the gas generated by the secondary battery containing the electrolyte system at high temperature, and further improves the high-rate discharge performance of the secondary battery.

The invention relates to aqueous adhesive compositions which contain at least the following components: (a) 1 to 95 wt. %, calculated as the solids content of a base component, containing: (a1) at least one polymeric organic binder, selected from acrylate, styrene, vinyl acetate, vinyl propionate and / or urethane homopolymers or copolymers, or any mixture thereof, and / or (a2) at least one polysaccharide thickener, selected from the group consisting of cellulose ethers, such as methyl cellulose, carboxyalkyl cellulose, in particular carboxymethyl cellulose, hydroxyalkyl cellulose, alkyl hydroxyalkyl cellulose, starch, in particular potato starch, starch ethers, in particular modified amylose and / or amylopectin, guar ethers, dextrins and mixtures of said compounds; (b) water; and (c) 0.03 to 1.4 wt. % guanidine and / or at least one salt of guanidine, wherein the proportion by weight refers to the content of guanidine in the total aqueous adhesive composition.

A pest control composition having from about 4 wt % to about 10 wt % of sodium lauryl sulfate, one or more C5 to C9 hydrotropic salt, from about 1 wt % to about 10 wt % of an active ingredient selected from the group consisting of corn mint oil, peppermint oil, spearmint oil, rosemary oil, thyme oil, citronella oil, clove oil, cedarwood oil, cinnamon oil, geranium oil, eugenol, 2-phenylethyl propionate, menthol, menthone, thymol, carvone, camphor, methyl salicylate, p-cymene, linalool, geraniol, cinnamyl acetate, cinnamic alcohol, cinnamaldehyde, citronellol, eucalyptol / 1,8-cineole, alpha-pinene, bornyl acetate, gamma-terpinene, and combinations thereof, and from about 60 wt % to about 95 wt % water. The pest control composition can exhibit a tan delta-1 value at a frequency of 1 Hz of from about 0.1 to about 2.

This invention belongs to the field of polymer materials and relates to a method for preparing a multifunctional emulsion antioxidant and its application, specifically to an emulsion antioxidant that also absorbs ultraviolet light and its application. A multifunctional emulsion-type antioxidant comprises the following components: a phenolic primary antioxidant, wherein the phenolic primary antioxidant comprises a mixture of p-cresol and dicyclopentadiene copolymer (TH-CPL) and triethylene glycol bis[β-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate] (antioxidant 245); a thioester secondary antioxidant; a UV absorber; a light stabilizer; a nonionic surfactant; and deionized water; wherein the UV absorber is N-(ethoxycarbonylphenyl)-N'-methyl-N'-phenylformamidinium (UV-1), and the light stabilizer is a mixture of bis(1,2,2,6,6-pentamethyl-4-piperidine) sebacate and 1-methyl-8-(1,2,2,6,6-pentamethyl-4-piperidine) sebacate (292).

The invention discloses zwitter-ion-based hydrogel and a preparation method and application thereof.The preparation method includes the steps that zwitter-ion monomers are stirred and dissolved in water under the ice-water bath condition, and a zwitter-ion monomer solution is obtained; injecting the obtained zwitter-ion solution into a mold, and placing in a water bath kettle at 37-60 DEG C for 24-72 hours to obtain zwitter-ion-based hydrogel; wherein the zwitter-ions are selected from at least one of [2-(methacryloyloxy) ethyl] dimethyl-(3-sulfonic acid propyl) ammonium hydroxide, 2-methacryloyloxyethyl phosphorylcholine and 3-[[2-(methacryloyloxy) ethyl] dimethyl ammonium] propionate. The zwitter-ion hydrogel material provided by the invention has a compression elastic modulus of 22.2-47.8 kPa, which is matched with the elastic modulus of breast tissues, and the hydrogel material has good self-repairing property, and it is found that the compression modulus after compression is equivalent to an initial state value; in addition, the hydrogel also has good tensile property and can bear the action of tensile force.

The invention relates to the field of antioxidant synthesis, and discloses a method for catalytically synthesizing pentaerythritol tetra (3-lauryl thiopropionate) by using a composite acid-loaded molecular sieve, which comprises the following steps: by using an olefin compound, a mercaptopropionate compound and pentaerythritol as raw materials, selecting the composite acid-loaded molecular sieve as a catalyst, and synthesizing pentaerythritol tetra (3-lauryl thiopropionate) by using the composite acid-loaded molecular sieve as a catalyst; and under a relatively mild condition, the pentaerythritol tetra (3-lauryl thiopropionate) antioxidant is catalytically synthesized. The catalyst for catalytic synthesis of the pentaerythritol tetra (3-lauryl thiopropionate) antioxidant by using the molecular sieve loaded with the composite acid is high in catalytic activity and relatively high in yield; the selected molecular sieve catalyst loaded with the composite acid is relatively mild in preparation condition, can react at low temperature, is convenient to operate and separate, and can be repeatedly used; and the problems of equipment corrosion, environmental pollution and the like do not exist, the production process is green and environment-friendly, and the investment cost is low.